CN105585879A - Acrylic resin paint capable of being quickly cured - Google Patents
Acrylic resin paint capable of being quickly cured Download PDFInfo
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- CN105585879A CN105585879A CN201510961019.7A CN201510961019A CN105585879A CN 105585879 A CN105585879 A CN 105585879A CN 201510961019 A CN201510961019 A CN 201510961019A CN 105585879 A CN105585879 A CN 105585879A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Abstract
The invention discloses acrylic resin paint capable of being quickly cured. The paint is a double-component curing system. Modified acrylic resin and alpha-(methyl)alkyl cyanoacrylate have good intersolubility and good adhesion, alpha-(methyl)alkyl cyanoacrylate can accelerate curing of a coating. The paint system can be quickly cured, and the environment-friendly coating which is good in weather resistance and high in adhesion can be obtained. The technology is simple, operation is easy, coating efficiency can be improved, and the good paint can be used for solar cell backplanes.
Description
Technical field
The present invention relates to one can quick-setting acrylic resin paint, belongs to material surface resist technology neckTerritory.
Background technology
Solar module in photovoltaic generation must meet above outdoor instructions for use in 25 years, backboard positionIn the outermost layer of photovoltaic cell component, cell piece is played to protection and supporting role, need have reliably electric exhaustedEdge, hinder moist and good weatherability.
The fluoropolymer backboards that use when China manufactures photovoltaic module at present more, one is gluing combined-type backing plate,At the compound fluorine film in the polyester film two sides such as PET or EVA glued membrane, three-decker, common are TPT, TPE,The structures such as KPK. The type backboard need to need to apply adhesive and adopt solid between fluoropolymer membrane and PETMetallization processes, not only fluoropolymer membrane cost costliness but also process-cycle need tens hours. It is another kind of for applying backboard,At polyester film coated on both sides fluororesin such as PET, drying film-forming. This method is not only saved adhesive layer,Also foreshortening to a few minutes hardening time.
But above backboard contains the halogen such as fluorine, chlorine, after assembly is scrapped, the recycling of assembly is metFace difficulty, the problem of environmental pollution bringing is thus highlighting in the future. Patent CN201310740044Middle employing acrylic resin does coating and has improved the water vapor transmittance of the polyester films such as PET. But acrylic resinCompared with fluorocarbon resin etc., it is more easily aging. In patent CN201410576506, acrylic resin is used for tooIn sun energy battery back-sheet, but it improves the anti-yellowing property of coating by adding a large amount of ultraviolet auxiliary agents. AsWhere on molecular structure, design ageing-resistant acrylic resin and still have to be solved for the problem of solar energy backboard.
Summary of the invention
The object of this invention is to provide one can quick-setting acrylic resin paint. This coating system can be fastTachy steroling, and can obtain good weatherability, the good environment-friendly coating that adhesive force is high. Technique of the present invention is simple,Processing ease, and can improve coating efficiency, be a kind of good coating that can be used for solar cell backboard.
Realize the technical scheme of the object of the invention:
One can quick-setting acrylic resin paint, comprising: component A and B component, wherein, componentA consists of the following composition:
B component is isocyanates.
Further, when use, component A and B component are mixed according to a certain percentage, make in B componentThe mol ratio of the oh group in the isocyanate group of isocyanates and component A in modified hydroxyl acrylic resinBe 0.8～1.2, after mixing, curing of coatings condition is: dry 0.5～1.5min at 120～150 DEG C.
Further, α-(methyl) alkyl cyanoacrylate by α-(methyl) Methyl 2-cyanoacrylate, α-(methyl) cyanacrylate, α-(methyl) alpha-cyanoacrylate propyl ester, α-(methyl) alpha-cyanoacrylateOne in isopropyl ester, α-(methyl) Tisuacryl, α-(methyl) isobutylcyanoacrylate etc.Or multiple according to any proportioning composition.
Further, the molecular weight of modified hydroxyl acrylic resin is 10000～25000, is 50～60% Gu contain,Glass transition temperature is-20～50 DEG C, and hydroxyl value is 10～60mgKOH/g.
Further, modified hydroxyl acrylic resin is by (methyl) alkyl acrylate, (methyl) acrylic acidHydroxy alkyl ester, (methyl) acrylic acid, acrylonitrile polymerization form.
Further, silane coupler is by vinyltrimethoxy silane, vinyl three (b-methoxy ethoxy)Silane, vinyl silane triisopropoxide, VTES, γ-methacryloxypropylOne or more in trimethoxy silane, vinyltriacetoxy silane form according to any proportioning.
Further, described filler is by titanium dioxide, carbon black, nano silicon, nano-calcium carbonate, nanometerOne or more in barium sulfate or nano aluminium oxide etc. form according to any proportioning.
Further, described stabilizing agent is cyano group penta 2 by sulfur dioxide or hydroquinones, described crosslinking coagentOne or more in alkene dibasic acid esters, dicyanogen methyl isophorone acrylate, alpha-cyanoacrylate allyl ester are according to any proportioning groupBecome. Described drier is organic tin drier.
Further, described solvent is by acetone, butanone, dimethylbenzene, ethyl acetate, butyl acetate, the third twoOne or more in alcohol methyl ether acetate etc. form according to any proportioning.
Further, described isocyanates is by hexamethylene diisocyanate trimer, hexa-methylene two isocyanidesAcid esters addition product, isophorone diisocyanate trimer, IPDI addition product, hydrogenationA kind of in XDI tripolymer or hydrogenation of benzene dimethylene diisocyanate addition product orMultiple according to any proportioning composition.
Beneficial effect of the present invention:
The present invention is by introduce the cyano group of strong polarity at acrylic resin, with α-(methyl) cyano group propyleneAcid alkyl esters etc. have extraordinary intersolubility, and have improved the adhesive force of acrylic resin at base materials such as PET,α-(methyl) alpha-cyanoacrylate alkyl can be accelerated the curing speed of coating, improves and applies speed, the silicon that contains two keysThe introducing of alkane coupling agent can further improve α-(methyl) alpha-cyanoacrylate alkyl and filler, modified acroleic acidThe active force of interlaminar resin. The coating that the present invention prepares contains environmental protection, good weatherability, high excellent of adhesive forcePoint. This acrylate paint can be applicable to photovoltaic component encapsulating with in the industrial production on backboard.
Specific embodiments
In the present invention, the preparation method of component A is free radical solution polymerization method conventional in this area, makesUsed time, the proportionate relationship of component A and B component is also that those skilled in the art can determine according to formula general knowledge, as preferably, the ratio of component A and B component is: in B component the isocyanate group of isocyanates withThe mol ratio of the oh group in component A in modified hydroxyl acrylic resin is 0.8～1.2, curing of coatings conditionFor: dry 0.5～1.5min at 120～150 DEG C.
It should be noted that, the modified hydroxyl acrylic resin adopting in the present invention, can comprise following weightThe raw material reaction of part obtains: 60～80 parts of (methyl) alkyl acrylates, 5～20 parts of (methyl) acrylic acidHydroxy alkyl ester, 0.5～5 part of (methyl) acrylic acid, 5～25 parts of acrylonitrile, 1～5 part of initator, and 1～5Part chain-transferring agent. Acrylic resin modified employing solution polymerization process is implemented, and preferably above-mentioned raw materials is organic moltenIn agent, react, the consumption of organic solvent is 80～100 weight portions. (methyl) alkyl acrylate whereinBase ester specifically comprise (methyl) methyl acrylate, (methyl) ethyl acrylate, (methyl) butyl acrylate,(methyl) 2-EHA, (methyl) acrylic acid cyclohexyl ester, (methyl) acrylic acid isoborneolEster etc. (methyl) acrylic acid hydroxy alkyl ester specifically comprises, (methyl) HEA, (methyl)Acrylic acid 2-hydroxypropyl ester, (methyl) acrylic acid 3-hydroxypropyl ester, acrylic acid 4-hydroxyl butyl ester etc.
Initator is the compound that contains weak bond in a class chemical constitution, under certain condition (heat, light, heightEnergy ray) decompose generation reactive intermediate (free radical, anion or cation) with initiated polymerization or crosslinkedReaction; Specifically can adopt ammonium sulfate, sodium peroxydisulfate, potassium peroxydisulfate, peroxidized t-butyl perbenzoate, mistakeOxidation di-t-butyl, peroxidating two tertiary pentyls, azodiisobutyronitrile, ABVN; Chain-transferring agent isCan effectively make the material of propagating radical generation radical transfer, in order to the average molecular of telomerized polymerAmount, can adopt n-dodecyl mercaptan (nDM), lauryl methyl mercaptan, mercaptoethanol etc. Reaction dissolventCan be butanone, toluene, dimethylbenzene, ethyl acetate, butyl acetate.
Below in conjunction with example, the present invention is further described in detail, but is not limited to this.
Example 1:
In reactor, add 80 parts of dimethylbenzene by weight, be warmed up to 140 DEG C; At the shape of solvent refluxingUnder state, slowly constant speed drips 20 parts of methyl methacrylates, 40 parts of butyl acrylates, 15 part third in 1hOlefin(e) acid-2-Octyl Nitrite, 12 parts of hydroxy-ethyl acrylates, 13 acrylonitrile, 3 parts of di-t-butyl peroxides, 3 partsThe mixture of sulfydryl mercaptan; Continue reaction 2 hours after, in 0.5h, added 1 part of di-t-butyl peroxide,The mixture of 20 parts of dimethylbenzene, and continue insulation reaction and after 1 hour, react end, be cooled to below 70 DEG C,Discharging, filtration, obtain the Hydroxylated acrylic resin a (physical parameter is in table one) of embodiment 1.
Component A:
B component:
25 parts of curing agent Z4470 (Bayer Bitterfeld GmbH)
In the container that agitating device is housed, add 100 parts of acrylic resin modified a and start and stir, successivelyAdd 171,30 parts of filler titanium dioxide R960 of 4 parts of silane coupling A, 2 parts of dibutyl tin laurates, 40 partsSolvent xylene, with 1000r/min high speed dispersion 0.5 hour, adds 0.1 part of stabilizing agent hydroquinones again,1 part of crosslinking coagent cyano group pentadiene dibasic acid esters, 40 parts of α-(methyl) cyanacrylates, stirring at low speed 5min,Prepare component A.
After component A and B component are uniformly mixed and filter, use scraper for coating method that coating fluid is coated on to 250 μ mOn thick PET basement membrane, by 120 DEG C of heated-air drying 1.5min film forming, obtain having the thick resin of 15 μ mCoating, carries out film performance detection and evaluation as follows, and film performance is in table 1.
Example 2:
In reactor, add 75 parts of butyl acetates by weight, be warmed up to 120 DEG C; At solvent refluxingUnder state, slowly constant speed drips 15 parts of methyl methacrylates, 35 parts of butyl acrylates, 30 parts in 1hAcrylic acid-2-ethyl caproite, 10 parts of acrylic acid 4-hydroxyl butyl esters, 5 parts of acrylonitrile, 2.5 parts of benzoyl peroxide firstThe mixture of tert-butyl acrylate, 2 parts of sulfydryl mercaptan; Continue reaction after 2 hours, in 0.5h, added 0.5The mixture of part peroxidized t-butyl perbenzoate, 5 parts of butyl acetates, and continue insulation reaction and react after 1 hourFinish, be cooled to below 70 DEG C, discharging, filtration, obtain the Hydroxylated acrylic resin b (thing of embodiment 1Property parameter is in table one).
Component A:
B component:
20 parts of curing agent N3390 (Bayer Bitterfeld GmbH)
In the container that agitating device is housed, add 100 parts of acrylic resin modified b and start and stir, successivelyAdd 171,1 parts of dibutyl tin laurates of 2 parts of silane coupling A, 20 parts of solvent butyl acetates, with1000r/min high speed dispersion 0.5 hour, adds 0.1 part of stabilizing agent sulfur dioxide again, 0.5 part of crosslinking coagentCyano group pentadiene dibasic acid esters, 20 parts of α-(methyl) Tisuacryls, stirring at low speed 5min, prepares groupDivide A.
After component A and B component are uniformly mixed and filter, use scraper for coating method that coating fluid is coated on to 250 μ mOn thick PET basement membrane, by 150 DEG C of heated-air drying 1.5min film forming, obtain having the thick resin of 15 μ mCoating, carries out film performance detection and evaluation as follows, and film performance is in table 1.
Example 3:
In reactor, add 70 parts of butanone by weight, be warmed up to 80 DEG C; Under the state of solvent refluxing,In 1h, slowly constant speed drips 30 parts of methyl methacrylates, 15 parts of butyl acrylates, 25 parts of acrylic acid secondEster, 5 parts of hydroxypropyl acrylates, 25 parts of acrylonitrile, 4 parts of azodiisobutyronitriles, 2 parts of lauryl mercaptans mixedCompound; Continue reaction after 2 hours, in 0.5h, added the mixed of 1 part of azodiisobutyronitrile, 5 parts of butanoneCompound, and continue insulation reaction and after 1 hour, react end, be cooled to below 40 DEG C, discharging, filtration,Obtain the Hydroxylated acrylic resin c (physical parameter is in table one) of embodiment 1.
Component A:
B component:
5 parts of curing agent Z4470 (Bayer Bitterfeld GmbH)
In the container that agitating device is housed, add 100 parts of acrylic resin modified c and start and stir, successivelyAdd 174,50 parts of filler titanium dioxide R996 of 8 parts of silane coupling A, 1 part of dibutyl tin laurate, 80 partsSolvent xylene, with 1000r/min high speed dispersion 0.5 hour, again add 0.2 part of stabilizing agent hydroquinones,1 part of sulfur dioxide, 3 parts of crosslinking coagent alpha-cyanoacrylate allyl esters, 100 parts of α-(methyl) alpha-cyanoacrylatesEthyl ester, stirring at low speed 5min, prepares component A.
After component A and B component are uniformly mixed and filter, use scraper for coating method that coating fluid is coated on to 250 μ mOn thick PET basement membrane, by 120 DEG C of heated-air drying 0.5min film forming, obtain having the thick resin of 15 μ mCoating, carries out film performance detection and evaluation as follows, and film performance is in table 1.
Example 4:
In reactor, add 90 parts of ethyl acetate by weight, be warmed up to 80 DEG C; At the shape of solvent refluxingUnder state, slowly constant speed drips 32 parts of methyl methacrylates, 30 parts of butyl acrylates, 20 part third in 1hOlefin(e) acid-2-Octyl Nitrite, 2 parts of hydroxyethyl methacrylates, 15 parts of acrylonitrile, 4 parts cross azodiisobutyronitrile,The mixture of 2 parts of lauryl mercaptans; Continue reaction after 2 hours, in 0.5h, added 1 part of azo two isobutylThe mixture of nitrile, 10 parts of butanone, and continue insulation reaction and after 1 hour, react end, be cooled to below 40 DEG C,Discharging, filtration, obtain the Hydroxylated acrylic resin d (physical parameter is in table one) of embodiment 1.
Component A:
B component:
15 parts of curing agent TKA100 (Japanese Asahi Chemical Industry)
In the container that agitating device is housed, add 100 parts of acrylic resin modified d and start and stir, successivelyAdd 172,2 parts of filler carbon black M100 of 0.5 part of silane coupling A, 1 part of dibutyl tin laurate, 40 partsSolvent ethyl acetate, with 1000r/min high speed dispersion 0.5 hour, adds 0.2 part of stabilizing agent to benzene two againPhenol, 1 part of crosslinking coagent cyano group pentadiene dibasic acid esters, 50 parts of α-(methyl) Methyl 2-cyanoacrylates, low speed stirsMix 5min, prepare component A.
After component A and B component are uniformly mixed and filter, use scraper for coating method that coating fluid is coated on to 250 μ mOn thick PET basement membrane, by 120 DEG C of heated-air drying 1min film forming, obtain having the resin that 15 μ m are thick and be coated withLayer, carries out film performance detection and evaluation as follows, and film performance is in table 1.
Comparative example 1:
Component A:
B component:
25 parts of curing agent Z4470 (Bayer Bitterfeld GmbH)
In the container that agitating device is housed, add 100 parts of Hydroxylated acrylic resin HF56123 and start and stir,Add successively 171,30 parts of filler titanium dioxide R960 of 4 parts of silane coupling A, 2 parts of dibutyl tin laurates,40 parts of solvent xylenes, with 1000r/min high speed dispersion 0.5 hour, add 0.1 part of stabilizing agent to benzene againDiphenol, 1 part of crosslinking coagent cyano group pentadiene dibasic acid esters, 40 parts of α-(methyl) cyanacrylates, low speedStir 5min, prepare component A.
After component A and B component are uniformly mixed and filter, use scraper for coating method that coating fluid is coated on to 250 μ mOn thick PET basement membrane, by 150 DEG C of heated-air drying 1.5min film forming, obtain having the thick resin of 15 μ mCoating, carries out film performance detection and evaluation as follows, and film performance is in table 1.
Comparative example 2:
Component A:
B component:
25 parts of curing agent Z4470 (Bayer Bitterfeld GmbH)
In the container that agitating device is housed, add 100 parts of acrylic resin modified a and start and stir, successivelyAdd 171,30 parts of filler titanium dioxide R960 of 4 parts of silane coupling A, 2 parts of dibutyl tin laurates, 40 partsSolvent xylene, with 1000r/min high speed dispersion 0.5 hour, prepares component A.
After component A and B component are uniformly mixed and filter, use scraper for coating method that coating fluid is coated on to 250 μ mOn thick PET basement membrane, by 150 DEG C of heated-air drying 1.5min film forming, obtain having the thick resin of 15 μ mCoating, carries out film performance detection and evaluation as follows, and film performance is in table 1.
Test assessment method:
The physical property of acrylic resin detects: as shown in table 1
Admittedly contain: detect by GB/T1725-2007 method.
Molecular weight: press GB/T21863-2008 method and detect. Adopt Waters1525-2414-717GPC inspectionSurvey its molecular weight, eluent is oxolane, proofreaies and correct with Narrow distribution polystyrene standard specimen.
Glass transition temperature: Tg is determined on TAQ200 instrument and carries out, and uses nitrogen atmosphere, withThe heating rate of 10 DEG C/min is heated to 200 DEG C from-80 DEG C.
Hydroxyl in mole * (methyl) acrylic acid hydroxy alkyl ester of hydroxyl value HV=(methyl) acrylic acid hydroxy alkyl esterThe weight of the degree of functionality * 56100/ modified hydroxyl acrylate of base.
The Performance Detection of backboard: as shown in Table 2
Outward appearance: range estimation, zero represents well.
Adhesive force: press ASTMD3359-2009 test, evaluation result is divided 0-5 level, and wherein 0 is best, 5For the poorest.
Hardness: press GB/T6739-2006 method and detect.
The two-way wiping of butanone: press GB/T23989-2009 method and detect. On the wetting absorbent cotton of butanone withThe load of 1000g is wiping back and forth on test board, and the number of times that moves around when exposing substrate layer represents.
Damp and hot experiment: undertaken by the regulation of IEC61215-2005, at 85 DEG C ± 2 DEG C, humidity (85 ± 5) %In the humiture case of RH, carry out accelerated ageing. Record the xanthochromia index (△ YI) of sample after aging 1000hAnd adhesive force grade.
Table 2
Can find out from test data, acrylic resin modified owing to not having in comparative example 1, though can substantially consolidateWhen change, but the adhesive force of α-(methyl) alkyl cyanoacrylate itself is after the damp and hot experiment of 1000hDecline more, in comparative example 2, owing to not adding α-(methyl) alkyl cyanoacrylate, cannot solidify completelyEntirely, hardness declines. And film performance that can quick-setting acrylic resin paint provided by the invention is good,Realize goal of the invention requirement, can be applied in completely on solar energy backboard.
Claims (10)
1. can a quick-setting acrylic resin paint, it is characterized in that, comprising: component A and B component,Wherein, component A consists of the following composition:
B component is isocyanates.
2. acrylic resin paint according to claim 1, is characterized in that, when use, by component AMix according to a certain percentage with B component, make in the isocyanate group and component A of isocyanates in B componentThe mol ratio of the oh group in modified hydroxyl acrylic resin is 0.8～1.2, after mixing, and curing of coatingsCondition is: dry 0.5～1.5min at 120～150 DEG C.
3. acrylic resin paint according to claim 1, is characterized in that, α-(methyl) cyano group thirdOlefin(e) acid Arrcostab is by α-(methyl) Methyl 2-cyanoacrylate, α-(methyl) cyanacrylate, α-(firstBase) alpha-cyanoacrylate propyl ester, α-(methyl) alpha-cyanoacrylate isopropyl ester, α-(methyl) alpha-cyanoacrylate fourthOne or more in ester, α-(methyl) isobutylcyanoacrylate etc. form according to any proportioning.
4. acrylic resin paint according to claim 1, is characterized in that, modified hydroxyl acrylic acid treeThe molecular weight of fat is 10000～25000, Gu containing being 50～60%, glass transition temperature is-20～50 DEG C, hydroxylBase value is 10～60mgKOH/g.
5. acrylic resin paint according to claim 1, is characterized in that, modified hydroxyl acrylic acid treeFat is by (methyl) alkyl acrylate, (methyl) acrylic acid hydroxy alkyl ester, (methyl) acrylic acid, propyleneNitrile is polymerized.
6. acrylic resin paint according to claim 1, is characterized in that, silane coupler is by etheneBase trimethoxy silane, vinyl three (b-methoxy ethoxy) silane, vinyl silane triisopropoxide,VTES, γ-methacryloxypropyl trimethoxy silane, vinyl triacetyl oxygenOne or more in base silane form according to any proportioning.
7. acrylic resin paint according to claim 1, is characterized in that, described filler by titanium dioxide,One in carbon black, nano silicon, nano-calcium carbonate, nano barium sulfate or nano aluminium oxide etc. or manyPlant according to any proportioning composition.
8. acrylic resin paint according to claim 1, is characterized in that, described stabilizing agent is by dioxyChange sulphur or hydroquinones, described crosslinking coagent are cyano group pentadiene dibasic acid esters, dicyanogen methyl isophorone acrylate, cyano group thirdOne or more in olefin(e) acid allyl ester form according to any proportioning. Described drier is organic tin drier.
9. acrylic resin paint according to claim 1, is characterized in that, described solvent by acetone,One or more in butanone, dimethylbenzene, ethyl acetate, butyl acetate, 1-Methoxy-2-propyl acetate etc. are pressedAccording to any proportioning composition.
10. acrylic resin paint according to claim 1, is characterized in that, described isocyanates is by sixMethylene diisocyanate tripolymer, hexamethylene diisocyanate addition product, IPDITripolymer, IPDI addition product, hydrogenation of benzene dimethylene diisocyanate tripolymer or hydrogenOne or more in change XDI addition product form according to any proportioning.
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018022810A1 (en) * | 2016-07-26 | 2018-02-01 | Ppg Industries Ohio, Inc. | Curable compositions containing 1,1-di-activated vinyl compounds and related coatings and processes |
| WO2018022780A1 (en) * | 2016-07-26 | 2018-02-01 | Ppg Industries Ohio, Inc. | Polyurethane coating compositions containing 1,1-di-activated vinyl compounds and related coatings and processes |
| CN108565307A (en) * | 2016-08-18 | 2018-09-21 | 老虎表面技术新材料（苏州）有限公司 | A kind of photovoltaic module encapsulating material |
| CN109337572A (en) * | 2018-08-31 | 2019-02-15 | 浙江帝恒实业有限公司 | A kind of new-energy automobile anti-flaming dope and preparation method thereof |
| CN110368515A (en) * | 2019-08-12 | 2019-10-25 | 浙江派菲特新材料科技有限公司 | A kind of preparation method of the medical N-butyl glue of high bond strength |
| US10934411B2 (en) | 2016-09-30 | 2021-03-02 | Ppg Industries Ohio, Inc. | Curable compositions containing 1,1-di-activated vinyl compounds that cure by pericyclic reaction mechanisms |
| US10961403B2 (en) | 2016-07-26 | 2021-03-30 | Ppg Industries Ohio, Inc. | Electrodepositable coating compositions containing 1,1-di-activated vinyl compounds |
| US10987697B2 (en) | 2016-07-26 | 2021-04-27 | Ppg Industries Ohio, Inc. | Multi-layer curable compositions containing 1,1-di-activated vinyl compound products and related processes |
| US11136469B2 (en) | 2016-07-26 | 2021-10-05 | Ppg Industries Ohio, Inc. | Acid-catalyzed curable coating compositions containing 1,1-di-activated vinyl compounds and related coatings and processes |
| CN113736323A (en) * | 2020-05-28 | 2021-12-03 | 上海乘鹰新材料有限公司 | White photovoltaic backboard coating composition for EVA and preparation method thereof |
| US11466159B2 (en) | 2016-07-26 | 2022-10-11 | Ppg Industries Ohio, Inc. | Particles having surfaces functionalized with 1,1-di-activated vinyl compounds |
| US11613076B2 (en) | 2016-07-26 | 2023-03-28 | Ppg Industries Ohio, Inc. | Three-dimensional printing processes using 1,1-di-activated vinyl compounds |
| US11634524B2 (en) | 2016-07-26 | 2023-04-25 | Ppg Industries Ohio, Inc. | Acid-catalyzed curable coating compositions containing 1,1 di-activated vinyl compounds and related coatings and processes |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102257085A (en) * | 2008-12-17 | 2011-11-23 | 巴斯夫欧洲公司 | Quick-drying coating compounds |
| WO2015003920A1 (en) * | 2013-07-09 | 2015-01-15 | Agfa-Gevaert | A backsheet for photovoltaic modules |
| CN104327568A (en) * | 2014-10-14 | 2015-02-04 | 马鞍山市恒毅机械制造有限公司 | Bacteriostasis, sterilization and air purification type aqueous coating for glass doors, and its preparation method |
| CN105143375A (en) * | 2013-03-15 | 2015-12-09 | 汉高知识产权控股有限责任公司 | Two-part, cyanoacrylate/cationically curable adhesive systems |
-
2015
- 2015-12-18 CN CN201510961019.7A patent/CN105585879B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102257085A (en) * | 2008-12-17 | 2011-11-23 | 巴斯夫欧洲公司 | Quick-drying coating compounds |
| CN105143375A (en) * | 2013-03-15 | 2015-12-09 | 汉高知识产权控股有限责任公司 | Two-part, cyanoacrylate/cationically curable adhesive systems |
| WO2015003920A1 (en) * | 2013-07-09 | 2015-01-15 | Agfa-Gevaert | A backsheet for photovoltaic modules |
| CN104327568A (en) * | 2014-10-14 | 2015-02-04 | 马鞍山市恒毅机械制造有限公司 | Bacteriostasis, sterilization and air purification type aqueous coating for glass doors, and its preparation method |
Non-Patent Citations (1)
| Title |
|---|
| 强亮生等: "《精细化工综合实验》", 31 March 2002, 哈尔滨工业大学出版社 * |
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