For method and the special equipment of refuse plastic harmless treatment and recovery energy
Technical field
The present invention relates to a kind of processing method and equipment of plastic refuse, relate to specifically a kind of for rubbishThe method of the harmless treatment of rubbish plastics and recovery energy and special equipment.
Background technology
The processing method of waste plastic is mainly divided into landfill method, burning method, melting method of reproduction and chemistry time at presentReceipts method etc. Landfill and fundamentally contaminated solution problem of burning, cause again the wasting of resources, melting regenerationMethod treatment of waste plastics, although process route is shorter, is cross-linked owing to easily sneaking into impurity in process and degrading, and causesThe physical property of regenerated plastics goods is reduced again and again, lose gradually value, finally become unrenewableRefuse plastic, but the chemical energy of these refuse plastics do not disappear, and still has great value.
Summary of the invention
The object of the invention is to solve the deficiencies in the prior art, a kind of skill that environment is not being polluted is providedUnder art condition, refuse plastic is carried out to complete harmless treatment and its chemical energy is carried out quantizing utilizingMethod.
It is a kind of for refuse plastic harmless treatment and recovery energy that another object of the present invention is to provideSpecial equipment.
The technical solution adopted for the present invention to solve the technical problems is:
For the method for refuse plastic harmless treatment and recovery energy, it comprises heating and removing rubbish mouldsPernicious gas in material, plastics are carried out to catalytic pyrolysis, isolate gasoline, diesel oil, combustion gas in lysateWith carbon black the operation such as collection respectively, concrete steps are as follows:
(1) first by washing or do not need washing pulverize after refuse plastic by adding feeder to material conveying device,Pushed the spiral-tube of helical feed formula degasser by feeder, combustor adds screw feeding type degasserHeat, to technological temperature, removes pernicious gas by refuse plastic in the process of carrying;
(2) continue to push the moving bed cracking of being heated by combustor and fill removing molten plastic after pernicious gasPut, carry out cracking under technological temperature and pressure, generate cracking gas and carbon black, carbon black is discharged through slag-draining device;Cracking gas is being kept under the situation of temperature, send into catalytic tower, in the effect of catalyst and catalytic temperature to crackingGas carries out catalytic reforming and generates miscella vapour, and miscella vapour is continued to be fed into fractionating column, slips out diesel oil and sends into bavinOil interceptor;
(3) more remaining mixed oil and gas is conveyed into by the water-cooled condensing tower of cooling tower, isolate gasoline andTail gas, sends gasoline into gasoline collector, and tail gas is delivered to liquefaction system by compressor and made liquefied gas and pack intoStorage tank; Pernicious gas gas is delivered to neutralizing tower and alkaline reaction, after the solution of generation salt and water, passes through valveDoor device for transferring.
For the special equipment of refuse plastic harmless treatment and recovery energy, it comprise to material conveying device,Feed arrangement, helical feed formula degasser, neutralizing tower, moving bed cracker, slag-draining device, catalysisTower, fractionating column, condensing tower, compressor, liquefaction system, combustor, circulating water cooling system and control systemSystem;
Be connected to material conveying device, feed arrangement by conveyer belt, helical feed formula degasser, moving bed splitSolution device, slag-draining device axially connect, neutralizing tower, catalytic tower, fractionating column, condensing tower, compressor, liquidChange system, combustor, circulating water cooling system are connected with pipeline;
Control system respectively with give material conveying device, feed arrangement, helical feed formula degasser, neutralizing tower,Moving bed cracker, slag-draining device, catalytic tower, fractionating column, condensing tower, compressor, liquefaction system,Combustor, circulating water cooling system are connected, by the control of control system realize charging, degassed, cracking,In catalysis, fractionation, deslagging, condensation process the automatic detection of inlet amount, transporting velocity, temperature, pressure andManagement.
Further, adopt chain-plate type elevator to pay-off, feeder adopts fork type rotation pusher;
Further, helical feed formula degasser, moving bed cracker, slag-draining device be different-diameter,The helical axis of different pitch and the spiral-tube matching thereof comprise the pipeline composition that gas is drawn, and neutralizing tower adoptsGas and liquid phase reactor, catalytic tower adopt gas-solid phase reaction device, fractionating column to adopt from backflow packed tower, condensing towerAdopt shell-and-tube water condensation tower;
Further, compressor, liquefaction system adopt scroll compressor, are driven combustor by variable-frequency motorAdopt temperature automatically controlled gas fuel combustion machine, circulating water cooling system is added by water spray type air heat-exchange water cooling towerWater circulating pump composition;
Further, described control system comprise industrial control computer, pressure sensor, temperature sensor,Speed probe, flow sensor, monitor and execution electrical equipment, it is each that control system collects sensorKind of data show in real time the line item of going forward side by side on monitor, simultaneously by these data and computer settingsAfter data are compared, send instruction to carrying out electrical equipment, automatic calibration implementation deviation amount, begins special equipmentKeep eventually running well, in the time that special equipment breaks down, control system will be reported to the police and be started voluntarily safety dressPut or autostop.
Further, described control system also adds wireless network remote monitoring control device.
Below in conjunction with professional equipment, the process of disposal of refuse plastics of the present invention is further set forth: control systemSystem respectively with give material conveying device, feeder and helical feed formula degasser, moving bed cracker, rowSlag device, combustor, neutralizing tower, catalytic tower, fractionating column, condensing tower, compressor, liquefaction system, followRing water cooling system is connected; The principle of utilizing ribbon conveyer under the control of computer by the rubbish crushingRubbish plastics uniformity is sent into feeder and helical feed formula degasser, utilizes the former of spiral pipeline conveyerReason, under the control of computer to refuse plastic helical feed formula degasser, moving bed cracker,In the continuous moving of slag-draining device, heat respectively and remove pernicious gas, carry out cracking and make vapour, admittedly separate,Utilize Catalysis Principles, fractionation principle and condensation principle under the control of computer to cracking vapour catalytic tower, pointHeat up in a steamer in tower, condensing tower system, carry out catalytic reforming, oily vapour separates, by each active section temperature, pressureMeasure, computer realization is to conveying worm rotating speed, compressor rotary speed, combustor temperature, condenser temperatureControl, the pressure that ensures feed quantity, gas flow rate, the temperature of each bringing-up section, each conversion zone all inOptimum state; When the degas chamber of refuse plastic by helical feed formula degasser middle part, be heated to290 DEG C~300 DEG C become molten condition, and the pernicious gas in molten plastic is separated and enters under spiral stirsNeutralizing tower reacts generation salt with nertralizer and then water be discharged from equipment; Molten plastic after exhaust enters movementAfter bed cracker, be heated to 500 DEG C~550 DEG C, carry out heat scission reaction in promotion with under stirring, movingIn process, generate cracking gas with carbon black and separate, carbon black is carried out entering slag-draining device in cracker bottom backwardDevice for transferring, cracking gas moves forward at cracker top, from the outlet quilt of movable bed cracking device front topImport catalytic tower, then utilize the waste heat gas of combustor after heating pyrolyze device by the catalyst in catalytic towerBe heated to 380 DEG C~420 DEG C, cracking gas is generated air-fuel mixture by further catalytic cracking when by catalystGas; Fuel-air mixture is admitted to fractionating column and fractionates out diesel oil at the temperature of 160 DEG C~185 DEG C, is then admitted toCondensing tower is isolated gasoline at 20 DEG C, remaining tail gas by compressor and liquefaction system 1.6MP pressure,After liquefying under the condition of 20~25 DEG C of temperature, pack storage tank into.
The invention has the beneficial effects as follows: the present invention can carry out final innoxious place to unrenewable refuse plasticReason also reclaims the chemical energy of wherein containing completely, and environment is not polluted. The fuel oil reclaiming after treatmentCan be used as industrial fuel, combustion gas is except as the also exportable clean fuel of living be used as of equipment heating, carbon blackAfter processing, can make the raw material of rubber industry.
Brief description of the drawings
Fig. 1 is the structural principle schematic diagram of refuse plastic treatment system.
Fig. 2 is that refuse plastic is innoxious, energy processing technological flow schematic diagram.
In figure: 1-control system, 2-is to material conveying device, 3-feed arrangement, 4-helical feed formula degasser,5-neutralizing tower, 6-moving bed cracker, 7-catalytic tower, 8-fractionating column, 9-condensing tower, 10-air-introduced machine, 11-Compressor, 12-liquefaction system, 13-pressure reducer, 14-combustor, 15-slag-draining device, 16-diesel oil collecting tank,17-gasoline collecting tank, 18-circulating water cooling system.
Detailed description of the invention
Below by specific embodiment, and by reference to the accompanying drawings, technical scheme of the present invention is done further concreteExplanation.
Embodiment 1
Consult Fig. 1 and Fig. 2, technique of the present invention comprises the removing of contained pernicious gas in refuse plastic, rubbishThe operations such as rubbish plastics catalytic pyrolysis, fuel oil cut, condensation and liquefied gas is produced, carbon black collection; Concrete stepRapid as follows:
(1) first by washing or do not need washing only pulverize after refuse plastic by adding charging to material conveying deviceDevice, rotates refuse plastic the spiral-tube that pushes helical feed formula degasser, combustion by the shift fork of feed arrangementBurning machine heating helical feed formula degasser spiral-tube also will pass through from helical feed formula degasser spiral-tubeRefuse plastic be heated to 290~300 DEG C of meltings, pernicious gas is overflowed gradually from refuse plastic, effusionPernicious gas gas enters neutralizing tower by the fairlead of helical feed formula degasser spiral-tube and alkali lye is anti-Should, the solution of generation salt and water, discharges by valve;
(2) removing molten plastic after pernicious gas continues to push moving bed by helical feed formula degasser and splitsSeparate the spiral-tube of device, combustor heats by moving bed cracker spiral-tube with through molten plastic whereinTo 500 DEG C~550 DEG C, and continued to advance by the spiral of moving bed cracker, molten plastic in propelling graduallyCracking, generates cracking gas and carbon black, and carbon black enters slag-draining device spiral-tube under spiral promotes, through deslagging spiral shellRevolve and promote to discharge; And cracking gas is at the spiral-tube fairlead keeping under the situation of temperature by moving bed crackerIntroduce catalytic tower, catalyst carries out catalytic reforming to cracking gas and generates miscella at the temperature of 380 DEG C~420 DEG CVapour, oily vapour gaseous mixture, is slipped out diesel oil and sends into diesel oil collector by pipeline from catalytic tower enters fractionating column;
(3) remaining mixed oil and gas is conveyed into condensing tower by fractionating column output pipe from fractionating column, isolatesGasoline and tail gas, the pipeline of condensing tower bottom is sent gasoline into gasoline collector, and tail gas is by condensing towerThe pipeline of portion enters compressor, is pressed into after liquefaction system is made liquefied gas and packs storage tank into, condensing tower by compressorWith compressor by the circulating water in water cooling tower.
Realizing in above process, by controlling the setup parameter of each system, realize raw material in charging, de-Inlet amount in the processes such as gas, cracking, catalysis, fractionation, deslagging, transporting velocity, temperature, pressure automaticallyDetect and automatic management, make whole technical process without any hazardous emission, to can not regenerationRefuse plastic has been accomplished final harmless treatment, and the chemical energy being contained is as the energy and the raw material of industryRecycle completely.
Embodiment 2
With reference to accompanying drawing 1, for the special equipment of refuse plastic harmless treatment and recovery energy, comprise feedConveying device, feed arrangement, helical feed formula degasser, neutralizing tower, movable bed cracking device, deslagging dressPut, catalytic tower, fractionating column, condensing tower, compressor, liquefaction system, combustor, circulating water cooling systemAnd control system, described control system comprises industrial control computer, sensor, functions and structureAs follows:
(1) give material conveying device: utilize the principle of ribbon conveyer, defeated with what set under the control of computerSend speed by the refuse plastic crushing quantity in accordance with regulations, uniformity is sent into feeder;
(2) feed arrangement: feed arrangement is made up of the rotor shape blade on can shift fork and the shift fork of axial-rotation,When shift fork rotation, stir refuse plastic and promote refuse plastic downwards by rotor shape blade, ensure to make to enter chargingThe refuse plastic of device enters the spiral-tube of helical feed formula degasser completely;
(3) helical feed formula degasser: helical feed formula degasser has fairlead by helical axis and middle partSpiral-tube composition, the refuse plastic that enters spiral-tube is continued to advance by the helical axis of helical feed formula degasserAnd be heated to after 290~300 DEG C of meltings, pernicious gas is overflowed gradually from refuse plastic, harmful gas of effusionBody gas is drawn by the fairlead of top, spiral-tube middle part, and molten plastic is by the helical axis in spiral-tubeContinue to promote to enter moving bed cracker;
(4) neutralizing tower: neutralizing tower adopts gas-liquid phase principle of peactor, and nertralizer is soluble in water, pernicious gasFrom the aqueous solution by time and solution in nertralizer react, generate harmless Yan Heshui, from neutralizing towerIn the mouth of pipe valve of bottom, be discharged from neutralizing tower;
(5) moving bed cracker: the spiral group that moving bed cracker rotates by spiral-tube with in spiral-tubeBecome, its one end is import, and spiral-tube is drawn the mouth of pipe near the top of anterior import, and molten plastic enters and movesAfter the spiral-tube of movable bed cracker, under the promotion of spiral, constantly move, be heated to by spiral-tube simultaneouslyThe temperature of 500 DEG C~550 DEG C cracking gradually, become cracking gas and carbon black, and cracking gas is by moving bed crackerThe fairlead of spiral-tube front upper is drawn, and carbon black is discharged from the outlet of the spiral-tube other end under spiral promotes;
(6) slag-draining device: the spiral that slag-draining device rotates by spiral-tube with in spiral-tube forms, spiral-tubeOne end is import, and the other end is slag notch, and spiral-tube device has cooling jacket, and slag notch is equipped with can be automaticAdjust the control device of quantity of slag size, the carbon black entering from moving bed cracker is here by cooling quiltThe spiral squeezing slag-draining device rotating in spiral-tube;
(7) catalytic tower: catalytic tower adopts gas-solid phase reaction device, the cage of being born in the year of mouse radial flow catalytic tower, its center isAir inlet pipe, has oil gas collection pipe on circumference barrel, between barrel and central tube, have heating tube, and heating tube adoptsThe hot exhaust gas of heating pyrolyze device heats, and approximately 380 DEG C~420 DEG C of heating-up temperatures, by moving bed cracker spiral shellRevolve a cracking gas that front upper fairlead is drawn mind-set circumference from catalytic tower and disperse to flow out, work as cracked gas streamCatalytic cracking reaction occurs in the time of heated catalyst, generate fuel-air mixture, fuel-air mixture is by barrelOn oil gas collection pipe collect after send into fractionating column;
(8) fractionating column. Fractionating column adopts from backflow packed tower, 35~55 DEG C of tower top chilling temperatures, and filler temperature is approximatelyRemain on 160~185 DEG C, filler adopts stainless steel rectangular saddle ring, after fractionating column slips out diesel oil from tower bottom oil pipeSend, the mixed oil and gas of gasoline and tail gas is sent into condensing tower from the tracheae on tower top;
(9) condensing tower: condensing tower adopts shell and tube water condensation tower, and condensation temperature is at 20~30 DEG C, and mixed oil and gas entersAfter entering condensing tower, gasoline condensation is sent from tower bottom oil pipe, and tail gas enters compressor from tower top tracheae is sent;
(10) compressor: compressor adopts scroll compressor, is driven by variable-frequency motor, and compressor adds tail gasBe depressed into 0.8MP/cm2After send into liquefaction system;
(11) liquefaction system: liquefaction system adopts scroll compressor group, and propane is made cold-producing medium, by variable-frequency motorDrive, air is cooling, and the tail gas that enters liquefaction system is continued to be forced into 1.6MP/cm in system2, and quiltAfter being cooled to 20~25 DEG C to be in a liquid state, send into storage tank for subsequent use;
(12) combustor: combustor adopts temperature automatically controlled gas fuel combustion machine separately to add distribute type warm-air pipe, simultaneouslyTo the heat supply respectively of helical feed formula degasser, moving bed cracker and catalytic tower;
(13) circulating water cooling system: circulating water cooling system adds water circulating pump by water spray type air heat-exchange cooling towerComposition, in fractionating column, condensing tower, slag-draining device, compressor and liquefaction system cooling water supply,The hot water of again fractionating column, condensing tower, slag-draining device, compressor and liquefaction system being discharged is drawn back to carry out coldBut after, send again these places back to and recycle, saved water resource;
(14) control system: control system comprise industrial control computer, pressure sensor, temperature sensor,The compositions such as speed probe, flow sensor, monitor and execution electrical equipment, control system is by sensor collectionTo various data on monitor, show in real time the line item of going forward side by side, simultaneously by these data and computerAfter the data of setting are compared, send instruction to carrying out electrical equipment, automatic calibration implementation deviation amount, makes deviceRemain normal operation, in the time that device breaks down, control system is by warning and start voluntarily safety deviceOr autostop, has ensured equipment safety, and realize the intelligent management of overall process.
Embodiment 3
Control system of the present invention also comprises wireless network remote monitoring control device, by computer and communication groupPart, monitor composition, wireless network remote monitoring control device can be at global anywhere to the work of installingDo time, working condition, service data and carry out whole process monitoring and carry out record simultaneously, and can to the opening of device,Shutdown is controlled, and consults Fig. 1, and all the other structures are with above-described embodiment 2.
Above-described embodiment is preferably scheme of one of the present invention, not the present invention is done to any shapeRestriction in formula, under the prerequisite that does not exceed the technical scheme that claim records, also have other variant andRemodeling.