CN105568426B - A kind of preparation method of Self-cleaning fabric - Google Patents
A kind of preparation method of Self-cleaning fabric Download PDFInfo
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- CN105568426B CN105568426B CN201610153563.3A CN201610153563A CN105568426B CN 105568426 B CN105568426 B CN 105568426B CN 201610153563 A CN201610153563 A CN 201610153563A CN 105568426 B CN105568426 B CN 105568426B
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- 238000004140 cleaning Methods 0.000 title claims abstract description 37
- 239000004744 fabric Substances 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 238000009987 spinning Methods 0.000 claims abstract description 32
- 239000000835 fiber Substances 0.000 claims abstract description 28
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 10
- 229920001400 block copolymer Polymers 0.000 claims abstract description 9
- 229920002678 cellulose Polymers 0.000 claims abstract description 9
- 239000003822 epoxy resin Substances 0.000 claims abstract description 9
- 239000010445 mica Substances 0.000 claims abstract description 9
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 9
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 9
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 9
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 9
- 229920001661 Chitosan Polymers 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 229920001451 polypropylene glycol Polymers 0.000 claims description 8
- 238000004804 winding Methods 0.000 claims description 8
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 4
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims description 4
- 239000013530 defoamer Substances 0.000 claims description 4
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 4
- 235000010413 sodium alginate Nutrition 0.000 claims description 4
- 239000000661 sodium alginate Substances 0.000 claims description 4
- 229940005550 sodium alginate Drugs 0.000 claims description 4
- 239000000080 wetting agent Substances 0.000 claims description 4
- 108090000371 Esterases Proteins 0.000 claims description 3
- 229920002101 Chitin Polymers 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000003373 anti-fouling effect Effects 0.000 description 6
- 239000002689 soil Substances 0.000 description 6
- 239000004753 textile Substances 0.000 description 6
- 239000000428 dust Substances 0.000 description 4
- 238000005202 decontamination Methods 0.000 description 3
- 230000003588 decontaminative effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002074 melt spinning Methods 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 101000938686 Rattus norvegicus Carboxylesterase 1C Proteins 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000009881 electrostatic interaction Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 230000003075 superhydrophobic effect Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000012224 working solution Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/098—Melt spinning methods with simultaneous stretching
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/16—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/18—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/16—Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention relates to a kind of preparation method of Self-cleaning fabric, polyvinyl chloride, polyoxyethylene polyoxypropylene block copolymer, epoxy resin, nano titanium oxide, Sucus Luffae, nano mica powder, PSS are mixed, it is heated into molten condition, add butyl benzyl phthalate, cellulose esters, nano-chitosan and remaining component and mix the spinning melt that must be modified, spinning and post-process and produce superfine Denier fibre, spinning fibre is woven into Self-cleaning fabric.Its surface is produced the hierarchical structure that micrometer structure is combined with nanostructured by the combination raw materials co-blended spinning, improve the roughness of fabric face, the self-cleaning property and water and oil repellant performance for making fabric increase substantially.
Description
Technical field
The present invention relates to fibre self-cleaning finishing method, specially a kind of preparation method of Self-cleaning fabric.
Background technology
Dirt on fabric includes water-soluble dirt, oily pollutant and dust.Water-soluble dirt, oily pollutant are due to dress ornament
Adsorbed with human contact, or contamination is caused by external grease (food oil or lubricant etc.)；Dust is mainly due to electrostatic interaction
Produce.The antifouling concept that to be two with easy decontamination different, there is the contact of inherence again between the two.Textile is in use
Can gradually it stain, it is antifouling to refer to that clothing textile be soaked by water-based soils and oily dirt in use and cause
Stain, also will not be because the dust or particulate that Electrostatic Absorption is done be in fiber or fabric face.Make textile that there is the whole of antifouling property
Reason is referred to as soil resistant finish.
Easy decontamination refers to fabric Yi Dan stain, and dirt is easily cleaned under normal wash conditions, and fabric is being washed
Dirt in cleaning solution will not be adsorbed and graying (dirt to get off be washed from fabric, is transferred to and knitted by cleaning solution by washing in liquid
Other positions of thing, this phenomenon are referred to as wet recontamination, and wet recontamination has summation in repeated washing).Have textile
The arrangement for having soil release performance energy is referred to as soil-releasing finiss.
Simultaneously the textile with antifouling and easy dirt-removing functions both had with self-cleaning function and is not easy to stain, again
Such as it is stained with greasy dirt and does not have to detergent, is rinsed with water.Corresponding finishing agent appellation self-cleaning finishing agent.Come for wearing fabric
For, particularly underwear, shirt etc., often washing, can heavy damage fabric appearance style, assigned using final finishing technology
Its self-cleaning function, can solve this problem, meet the requirement of consumer.But antifouling and easy decontamination dual-use function is uniformly arrived
On same finishing agent, and there is good stability, degree-of-difficulty factor is larger.
When nano inorganic self-cleaning finishing agent can make the dress ornament run into dirt, only seldom a part of spot can be adsorbed onto and knit
On thing, act on, this sub-fraction spot can thoroughly be removed by certain photocatalytic self-cleaning.In addition, in fabric
The harmful bacteria in portion can also decompose, and it is kept cleaning.But the inorganic finishing agent of highly concentrated nano is scattered and applies technically
Have many difficulty, at the same soil resistance particularly dust tightness have it is bigger ageing, i.e., when its self-cleaning function can be with taking
Between lengthening model reduce, but organic finishing agent is added in cleaning system, this problem can be made up.Therefore, combine organic
And inorganic composite self-cleaning finishing agent, there is important application value.
The content of the invention
In view of the shortcomings of the prior art, the technical problem that the present invention intends to solve is a kind of preparation method of Self-cleaning fabric,
Fabric lining is prepared using the spinning material melt spinning of special composition, is easy to meet the need for developing high-grade automatically cleaning textile
Will.Its surface is produced the hierarchical structure that micrometer structure is combined with nanostructured by the combination raw materials co-blended spinning, improve
The roughness of fabric face, the self-cleaning property and water and oil repellant performance for making fabric increase substantially.
The technical solution adopted in the present invention is：A kind of preparation method of Self-cleaning fabric, by the original of following parts by weight meter
Material is made：
Polyvinyl chloride 70-85,
Polyox-yethylene-polyoxypropylene block copolymer 20-33,
Epoxy resin 11-16,
Nano titanium oxide 4-10,
Disodium hydrogen phosphate 3-5,
PSS 2-6,
Cellulose esters 3-10,
Butyl benzyl phthalate 5-15,
Barium stearate 1-5,
Sucus Luffae 10-20,
Nano mica powder 0.5-3,
Defoamer 0.2-0.5,
Nano-chitosan 0.8-1.5,
Coco betaine 1-2,
Wetting agent 0.3-1 is emulsified,
Sodium alginate 2-3,
Esterase 0.4-2；
By polyvinyl chloride, polyox-yethylene-polyoxypropylene block copolymer, epoxy resin, nano titanium oxide, Sucus Luffae,
Nano mica powder, PSS mix, and are heated into molten condition, add butyl benzyl phthalate, cellulose
Ester, nano-chitosan and remaining component mix the spinning melt that must be modified, and modified spinning melt delivers to spinning through screw extruder
Silk machine, each spinning components are pressed into through measuring pump by melt quantitative, by the melt of the intensive aperture material on spinneret with
Filament state is flowed out, and as-spun fibre is obtained through air cooled and solidified；Reoil winding, 3-10 times of filament drafting, and twisting winding will be wound
After produce superfine Denier fibre, spinning fibre is woven into Self-cleaning fabric, wherein, the orifice diameter of spinneret is 0.01-
0.12mm, shape of spinneret are that three leaves are petal-shaped.
Further, the particle diameter of the nano titanium oxide is between 80-120nm.
Further, described spinning-drawing machine spinning speed is 2000-7000m/min.
Further, the fiber linear density of described superfine Denier fibre can reach 4-6 denier.
Beneficial effects of the present invention：
(1) Self-cleaning fabric that the raw material configuration melt spinning for being used to preparing Self-cleaning fabric obtains has preferable
Stability, repeatability；
(2) in fibre application, there is preferable waterproof, antifouling and soil release performance；
(3) needs for developing various fiber top grade automatically cleaning rib-loop knitwear are met.
The present invention prepares for existing nano-titanium dioxide powder dispersion liquid or titanium dioxide Organic Alcohol working solution and should
Various disadvantages, there is provided Self-cleaning fabric the obtained fibre of preparation method, there is the property of super-hydrophobic oleophobic,
Neither get wet and oily dirt free, so as to reach automatically cleaning purpose.The nano self-cleaning technology not only makes fiber or its product more beautiful
See, increase service life, and there is significant society and economic benefit in environmental protection, energy-saving square face.
Embodiment
Below by embodiment, technical scheme is described in further detail.
Embodiment one：
A kind of preparation method of Self-cleaning fabric, it is made up of the raw material of following parts by weight meter：
Polyvinyl chloride 70,
Polyox-yethylene-polyoxypropylene block copolymer 20,
Epoxy resin 11,
Nano titanium oxide 4,
Disodium hydrogen phosphate 3,
PSS 2,
Cellulose esters 3,
Butyl benzyl phthalate 5,
Barium stearate 1,
Sucus Luffae 10,
Nano mica powder 0.5,
Defoamer 0.2,
Nano-chitosan 0.8,
Coco betaine 1,
Wetting agent 0.3 is emulsified,
Sodium alginate 2,
Esterase 0.4；
By polyvinyl chloride, polyox-yethylene-polyoxypropylene block copolymer, epoxy resin, nano titanium oxide, Sucus Luffae,
Nano mica powder, PSS mix, and are heated into molten condition, add butyl benzyl phthalate, cellulose
Ester, nano-chitosan and remaining component mix the spinning melt that must be modified, and modified spinning melt delivers to spinning through screw extruder
Silk machine, is pressed into each spinning components, by aperture intensive on spinneret, spinning melt is with filament through measuring pump by melt quantitative
State is flowed out, and as-spun fibre is obtained through air cooled and solidified；Reoil winding, 4 times of filament drafting will be wound, and produced after twisting winding super
Fine count fiber, spinning fibre is woven into Self-cleaning fabric, wherein, the orifice diameter of spinneret is 0.01mm, spinneret orifice shape
Shape is that three leaves are petal-shaped.The particle diameter of the nano titanium oxide is between 80-120nm.Described spinning-drawing machine spinning speed is
2000m/min.The fiber linear density of described superfine Denier fibre can reach 4 denier.
Embodiment two：
A kind of preparation method of Self-cleaning fabric, it is made up of the raw material of following parts by weight meter：
Polyvinyl chloride 85,
Polyox-yethylene-polyoxypropylene block copolymer 33,
Epoxy resin 16,
Nano titanium oxide 10,
Disodium hydrogen phosphate 5,
PSS 6,
Cellulose esters 10,
Butyl benzyl phthalate 15,
Barium stearate 5,
Sucus Luffae 20,
Nano mica powder 3,
Defoamer 0.5,
Nano-chitosan 1.5,
Coco betaine 2,
Wetting agent 1 is emulsified,
Sodium alginate 3,
Esterase 2；
By polyvinyl chloride, polyox-yethylene-polyoxypropylene block copolymer, epoxy resin, nano titanium oxide, Sucus Luffae,
Nano mica powder, PSS mix, and are heated into molten condition, add butyl benzyl phthalate, cellulose
Ester, nano-chitosan and remaining component mix the spinning melt that must be modified, and modified spinning melt delivers to spinning through screw extruder
Silk machine, is pressed into each spinning components, by aperture intensive on spinneret, spinning melt is with filament through measuring pump by melt quantitative
State is flowed out, and as-spun fibre is obtained through air cooled and solidified；Reoil winding, 8 times of filament drafting will be wound, and produced after twisting winding super
Fine count fiber, spinning fibre is woven into Self-cleaning fabric, wherein, the orifice diameter of spinneret is 0.12mm, spinneret orifice shape
Shape is that three leaves are petal-shaped.The particle diameter of the nano titanium oxide is between 80-120nm.Described spinning-drawing machine spinning speed is
7000m/min.The fiber linear density of described superfine Denier fibre can reach 6 denier.
The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited thereto, any
Those skilled in the art disclosed herein technical scope in, can without the change that creative work is expected or
Replace, should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be limited with claims
Fixed protection domain is defined.
Claims (3)
- A kind of 1. preparation method of Self-cleaning fabric, it is characterised in that：It is made up of the raw material of following parts by weight meter：Polyvinyl chloride 70-85,Polyox-yethylene-polyoxypropylene block copolymer 20-33,Epoxy resin 11-16,Nano titanium oxide 4-10,Disodium hydrogen phosphate 3-5,PSS 2-6,Cellulose esters 3-10,Butyl benzyl phthalate 5-15,Barium stearate 1-5,Sucus Luffae 10-20,Nano mica powder 0.5-3,Defoamer 0.2-0.5,Nano-chitosan 0.8-1.5,Coco betaine 1-2,Wetting agent 0.3-1 is emulsified,Sodium alginate 2-3,Esterase 0.4-2；By polyvinyl chloride, polyox-yethylene-polyoxypropylene block copolymer, epoxy resin, nano titanium oxide, Sucus Luffae, nanometer Mica powder, PSS mix, and are heated into molten condition, add butyl benzyl phthalate, cellulose esters, receive Rice chitin and remaining component mix the spinning melt that must be modified, and modified spinning melt delivers to spinning-drawing machine through screw extruder, Melt quantitative is pressed into each spinning components through measuring pump, by aperture intensive on spinneret, spinning melt is with filament state stream Go out, as-spun fibre is obtained through air cooled and solidified；Reoil winding, 3-10 times of filament drafting will be wound, and produced after twisting winding super Fine count fiber, spinning fibre is woven into Self-cleaning fabric；Wherein, the orifice diameter of spinneret is 0.01-0.12mm, spinneret Hole shape is that three leaves are petal-shaped;The particle diameter of the nano titanium oxide is between 80-120nm.
- A kind of 2. preparation method of Self-cleaning fabric according to claim 1, it is characterised in that：Described spinning-drawing machine spinning Speed is 2000-7000m/min.
- A kind of 3. preparation method of Self-cleaning fabric according to claim 1, it is characterised in that：Described superfine Denier fibre Fiber linear density can reach 4-6 denier.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610153563.3A CN105568426B (en) | 2016-03-17 | 2016-03-17 | A kind of preparation method of Self-cleaning fabric |
| CN201711472736.9A CN108085775A (en) | 2016-03-17 | 2016-03-17 | A kind of preparation method of Self-cleaning fabric |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610153563.3A CN105568426B (en) | 2016-03-17 | 2016-03-17 | A kind of preparation method of Self-cleaning fabric |
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| CN201711472736.9A Division CN108085775A (en) | 2016-03-17 | 2016-03-17 | A kind of preparation method of Self-cleaning fabric |
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| CN105568426A CN105568426A (en) | 2016-05-11 |
| CN105568426B true CN105568426B (en) | 2018-03-02 |
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| CN201711472736.9A Pending CN108085775A (en) | 2016-03-17 | 2016-03-17 | A kind of preparation method of Self-cleaning fabric |
| CN201610153563.3A Active CN105568426B (en) | 2016-03-17 | 2016-03-17 | A kind of preparation method of Self-cleaning fabric |
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| CN109853079A (en) * | 2018-12-31 | 2019-06-07 | 盐城工学院 | A kind of photocatalytic self-cleaning fabric and preparation method thereof |
| CN110042528B (en) * | 2019-04-18 | 2021-04-23 | 宁波先锋新材料股份有限公司 | Sun-shading fabric and preparation method thereof |
| CN111321508B (en) * | 2020-03-20 | 2021-06-29 | 石狮市聚宝针纺织品织造有限责任公司 | Blended elastic knitted fabric and preparation process thereof |
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| CN1126832C (en) * | 2000-07-18 | 2003-11-05 | 上海杰事杰新材料股份有限公司 | Silk-like material and its preparing process |
| DE10118348A1 (en) * | 2001-04-12 | 2002-10-17 | Creavis Tech & Innovation Gmbh | Self-cleaning, water-repellent synthetic polymer fiber, used e.g. for tents, sports clothing and carpets, made by impregnating fiber with a suspension of hydrophobic particles and then removing the solvent |
| CN102851943A (en) * | 2012-08-29 | 2013-01-02 | 昆山铁牛衬衫厂 | Finishing method of automatic-cleaning textiles |
| CN102817100B (en) * | 2012-09-17 | 2013-07-03 | 南通市田园装饰布有限公司 | Processing technique of PET functional fibers |
| CN103408861B (en) * | 2013-07-18 | 2016-04-06 | 苏州富通高新材料科技股份有限公司 | A kind of plastic floor base material and preparation method thereof |
| CN103952792B (en) * | 2014-04-18 | 2016-01-27 | 安徽省中日农业环保科技有限公司 | A kind of magnetic conduction, antistatic tarragon fabric lining and preparation method thereof |
| CN104119621B (en) * | 2014-06-18 | 2016-04-06 | 三门永鼎橡塑有限公司 | A kind of matrix material of multi-functional rubber and plastic automatic foot-mat and preparation method |
| CN104746360B (en) * | 2015-04-13 | 2016-11-30 | 金华知产婺源信息技术有限公司 | A kind of gold stamping slurry of weaving face fabric transfer printing |
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| CN108085775A (en) | 2018-05-29 |
| CN105568426A (en) | 2016-05-11 |
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