CN105565756A - Wall insulation antifouling flame-retardant material - Google Patents

Wall insulation antifouling flame-retardant material Download PDF

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Publication number
CN105565756A
CN105565756A CN201510949142.7A CN201510949142A CN105565756A CN 105565756 A CN105565756 A CN 105565756A CN 201510949142 A CN201510949142 A CN 201510949142A CN 105565756 A CN105565756 A CN 105565756A
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China
Prior art keywords
parts
mud
water
powder
retardant material
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Pending
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CN201510949142.7A
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Chinese (zh)
Inventor
高芳
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Hefei Jieming New Material Technology Co Ltd
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Hefei Jieming New Material Technology Co Ltd
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Priority to CN201510949142.7A priority Critical patent/CN105565756A/en
Publication of CN105565756A publication Critical patent/CN105565756A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/004Sludge detoxification
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • C02F11/04Anaerobic treatment; Production of methane by such processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/06Sludge reduction, e.g. by lysis
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a wall insulation antifouling flame-retardant material which is prepared from the following raw materials in parts by weight: 1-2 parts of white mineral oil, 5-6 parts of starch, 4-5 parts of coal gangue powder, 5-6 parts of coarse aggregate, 3-4 parts of rutile nano titanium dioxide, 12-14 parts of carbide slag, 210-250 parts of sludge, 4-5 parts of Vac/E dispersible latex powder, 2.5-3 parts of polyacrylamide, 1.7-2.4 parts of sodium dodecyl sulfate, 120-130 parts of alpha-semi-hydrated gypsum, 7.4-8.9 parts of cement, 1-2 parts of eucalyptus oil, 4.9-5.6 parts of fly ash, 4-5 parts of activated carbon, 5-6 parts of aluminum silicate fiber, 8-9 parts of kieselguhr and appropriate water.

Description

A kind of wall thermal insulating scrubbing fire retardant material
Technical field
The present invention relates to wall heat insulation material technical field, particularly relate to a kind of wall thermal insulating scrubbing fire retardant material.
Background technology
Along with the national economy that China day by day increases, and urban population continuing to increase in recent years, China is more and more higher for the processing efficiency of municipal effluent, causes the output of the by product-mud produced in sewage treatment process constantly to increase.Containing a large amount of soluble flocks in the mud produced in sewage treatment process, organic substance also containing large quantity of moisture, kind complexity, simultaneously also containing the objectionable impurities such as various heavy toxic substance and pathogenic bacteria, if stacked its any landfill, do not processed, not only can cause severe contamination for environment, also have ignored the use value that these mud have simultaneously, cause the waste to resource.Traditional method for sludge treatment, the not only resource of at substantial, and can pollute surrounding enviroment, through the mud of the mode such as physics, biological chemistry process, effectively can reduce its poisonous and hazardous material, and processed after mud also there is the function such as heat-insulation and heat-preservation, sound absorption, be a kind of excellent functional construction material.Therefore but the recycling of mud is one of sludge treatment the road of supervention exhibition.In recent years, development at full speed is obtained to the recycling of mud, wherein topmost Land use systems, exactly mud is applied in material of construction, if develop a kind of lagging material containing mud on this basis, so these unmanageable mud just obtain effective utilization, are a kind of effective means that recycling sludge utilizes, also have found a kind of new environment protecting thermal insulating material simultaneously, improve the environmental protection and energy saving of material of construction.
Application number is in 200810171725.1 " sludge foaming lightweight concrete that method for sludge treatment and the method are produced and purposes " patent, also be with undressed mud and unslaked lime stirring reaction, form sludge hydrated lime, again by itself and cement, water and whipping agent are mixed to get foaming lightweight concrete, there is a lot of purposes, the performance of each side is all better than normal concrete, but in sludge handling process, waterproof and organism process are not carried out to it, have the health of people's health and affect greatly, because mud has water-absorbent, the external moisture of easy absorption, time one is long, safety coefficient can be reduced, critical people's security of the lives and property.The present invention is by certain physics, chemical mode process; reach nontoxic; the objects such as heat insulating, thermal conductivity are lower; make it as good lagging material; also have good sound-proof sound-absorbing effect simultaneously; give full play to the advantage on sludge quality, while utilization of waste material, taken into account environment protection, really realize the green hope turned waste into wealth.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides a kind of wall thermal insulating scrubbing fire retardant material.
The present invention is achieved by the following technical solutions:
A kind of wall thermal insulating scrubbing fire retardant material, is made up of the raw material of following weight part: white mineral oil 1-2, starch 5-6, colliery powder 4-5, coarse aggregate 5-6, gold redrock nano-titanium dioxide 3-4, carbide slag 12-14, mud 210-250, Vac/E polymer dispersion powder 4-5, polyacrylamide 2.5-3, sodium lauryl sulphate 1.7-2.4, alpha-semi water plaster stone 120-130, cement 7.4-8.9, Oil of Eucalyptus 1-2, flyash 4.9-5.6, gac 4-5, aluminum silicate fiber 5-6, diatomite 8-9, water are appropriate.
A kind of wall thermal insulating scrubbing fire retardant material, be made up of following concrete steps:
(1) gac and diatomite are added in mud stir, under natural condition, mix 5-6 days, then by mud thermal pretreatment, temperature is 170-175 ° of C, time is 30-35min, be added to after naturally cooling in anaerobic pond, under anaerobic, temperature is 35-40 ° of C, pH value remains on 7.0-7.4 anaerobic digestion reaction 10-13 days, carry out drying treatment after reaction terminates, under 140-150 ° of C, process 6-7h, after naturally cooling, milled 300-400 mesh sieve is for subsequent use;
(2) water of starch by 10-13 times amount is diluted, gold redrock nano-titanium dioxide ultrasonic disperse is added even after low-grade fever, add mud powder mixing and stirring prepared by step (1) again, then carbide slag and colliery powder mixture surface is coated on, be placed in baking oven to dry, be finally in the Vac/E polymer dispersion powder solution of 15-18% in concentration by impregnation mixture, evaporation removing moisture post-drying is for subsequent use;
(3) product prepared by step (2), alpha-semi water plaster stone powder mixing and stirring, stir according to water paste ratio 1:1.2-1:1.4 and form gypsum slurries, again sodium lauryl sulphate is mixed at room temperature mechanical stirring with the water of 4-5 times amount and form the slurries that foam, then the slurries that will foam mix with gypsum slurries, Keep agitation also adds other surplus materialss such as flyash, cement, finally slurry is poured in mould, be put in room ventilated place naturally shaping.
Advantage of the present invention is: the present invention adopts gac and diatomite to carry out deodorizing to mud, Anaerobic Digestion greatly reduces organic content in mud afterwards, the effect of disinfection is played in pyroprocessing, treated mud is coated on filling surface, dispersible latax with Vac/E again and do WATER REPELLENT, improve intensity greatly, moistureproof, waterproof, insulation, the effect of the aspect such as heat insulation, the present invention adopts material based on alpha-semi water plaster stone, there is very high intensity, crushing resistance, water tolerance and easy casting, whipping agent is added in gypsum slurries, being uniformly mixed of short period of time gets final product casting, without the need to special casting equipment, technique is simple, with short production cycle, efficiency is high, also have a large amount of tiny in Foamed Gypsum material, uniform bubble, not only play good insulation effect, can also the mechanical property of reinforcement material, the present invention can reach the heat insulation effect of expection, meets again the requirement of energy-saving and emission-reduction, economic benefit and environmental benefit high.
Embodiment
A kind of wall thermal insulating scrubbing fire retardant material, is made up of the raw material of following weight part (kilogram): white mineral oil 1, starch 5, colliery powder 4, coarse aggregate 5, gold redrock nano-titanium dioxide 3, carbide slag 12, mud 210, Vac/E polymer dispersion powder 4, polyacrylamide 2.5, sodium lauryl sulphate 1.7, αsemiwatergypsum 120, cement 7.4, Oil of Eucalyptus 1, flyash 4.9, gac 4, aluminum silicate fiber 5, diatomite 8, water are appropriate.
A kind of wall thermal insulating scrubbing fire retardant material, be made up of following concrete steps:
(1) gac and diatomite are added in mud stir, under natural condition, mix 5 days, then by mud thermal pretreatment, temperature is 170 ° of C, time is 30min, be added to after naturally cooling in anaerobic pond, under anaerobic, temperature is 35 ° of C, pH value remains on 7.0 anaerobic digestions and reacts 10 days, carry out drying treatment after reaction terminates, under 140 ° of C, process 6h, after naturally cooling, milled 300 mesh sieves are for subsequent use;
(2) water of starch by 10 times amount is diluted, gold redrock nano-titanium dioxide ultrasonic disperse is added even after low-grade fever, add mud powder mixing and stirring prepared by step (1) again, then carbide slag and colliery powder mixture surface is coated on, be placed in baking oven to dry, be finally in the Vac/E polymer dispersion powder solution of 15% in concentration by impregnation mixture, evaporation removing moisture post-drying is for subsequent use;
(3) product prepared by step (2), αsemiwatergypsum powder mixing and stirring, stir according to water paste ratio 1:1.2:1.4 and form gypsum slurries, again sodium lauryl sulphate is mixed at room temperature mechanical stirring with the water of 4 times amount and form the slurries that foam, then the slurries that will foam mix with gypsum slurries, Keep agitation also adds other surplus materialss such as flyash, cement, finally slurry is poured in mould, be put in room ventilated place naturally shaping.
Experimental data: water-intake rate :≤1.3%, ultimate compression strength: >=12.6MPa, sound absorbing power: >=0.18%, thermal conductivity :≤0.15W/mK.

Claims (2)

1. a wall thermal insulating scrubbing fire retardant material, it is characterized in that, be made up of the raw material of following weight part: white mineral oil 1-2, starch 5-6, colliery powder 4-5, coarse aggregate 5-6, gold redrock nano-titanium dioxide 3-4, carbide slag 12-14, mud 210-250, Vac/E polymer dispersion powder 4-5, polyacrylamide 2.5-3, sodium lauryl sulphate 1.7-2.4, alpha-semi water plaster stone 120-130, cement 7.4-8.9, Oil of Eucalyptus 1-2, flyash 4.9-5.6, gac 4-5, aluminum silicate fiber 5-6, diatomite 8-9, water are appropriate.
2. a wall thermal insulating scrubbing fire retardant material, is characterized in that, is made up of following concrete steps:
(1) gac and diatomite are added in mud stir, under natural condition, mix 5-6 days, then by mud thermal pretreatment, temperature is 170-175 ° of C, time is 30-35min, be added to after naturally cooling in anaerobic pond, under anaerobic, temperature is 35-40 ° of C, pH value remains on 7.0-7.4 anaerobic digestion reaction 10-13 days, carry out drying treatment after reaction terminates, under 140-150 ° of C, process 6-7h, after naturally cooling, milled 300-400 mesh sieve is for subsequent use;
(2) water of starch by 10-13 times amount is diluted, gold redrock nano-titanium dioxide ultrasonic disperse is added even after low-grade fever, add mud powder mixing and stirring prepared by step (1) again, then carbide slag and colliery powder mixture surface is coated on, be placed in baking oven to dry, be finally in the Vac/E polymer dispersion powder solution of 15-18% in concentration by impregnation mixture, evaporation removing moisture post-drying is for subsequent use;
(3) product prepared by step (2), alpha-semi water plaster stone powder mixing and stirring, stir according to water paste ratio 1:1.2-1:1.4 and form gypsum slurries, again sodium lauryl sulphate is mixed at room temperature mechanical stirring with the water of 4-5 times amount and form the slurries that foam, then the slurries that will foam mix with gypsum slurries, Keep agitation also adds other surplus materialss such as flyash, cement, finally slurry is poured in mould, be put in room ventilated place naturally shaping.
CN201510949142.7A 2015-12-18 2015-12-18 Wall insulation antifouling flame-retardant material Pending CN105565756A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110357542A (en) * 2019-08-31 2019-10-22 郑州恒博环境科技股份有限公司 A kind of fire-retardant wall body brick and preparation method thereof containing desulfurization wastewater sludge

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102887724A (en) * 2012-09-03 2013-01-23 蚌埠爱民汽车服务有限公司五河新型环保建材厂 Aerated brick produced by modified kaolin and processing method of aerated brick

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102887724A (en) * 2012-09-03 2013-01-23 蚌埠爱民汽车服务有限公司五河新型环保建材厂 Aerated brick produced by modified kaolin and processing method of aerated brick

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
刘吉主编: "《新时期基层环境保护管理工作研究与探索 第3卷》", 31 January 2007 *
周春山,熊兴安: "《新编实用化工小商品产品规格及检验方法》", 31 December 1995 *
夏寿荣: "《最新混凝土外加剂生产配方精选400例》", 31 January 2014 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110357542A (en) * 2019-08-31 2019-10-22 郑州恒博环境科技股份有限公司 A kind of fire-retardant wall body brick and preparation method thereof containing desulfurization wastewater sludge
CN110357542B (en) * 2019-08-31 2021-12-07 郑州恒博环境科技股份有限公司 Flame-retardant wall brick containing desulfurization wastewater sludge and preparation method thereof

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Application publication date: 20160511