CN105548070B - A kind of apple soluble solid near infrared detection position compensation method and system - Google Patents

A kind of apple soluble solid near infrared detection position compensation method and system Download PDF

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CN105548070B
CN105548070B CN201511031809.1A CN201511031809A CN105548070B CN 105548070 B CN105548070 B CN 105548070B CN 201511031809 A CN201511031809 A CN 201511031809A CN 105548070 B CN105548070 B CN 105548070B
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apple
soluble solid
near infrared
spectrum
predetermined patterns
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CN105548070A (en
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黄文倩
樊书祥
王庆艳
李江波
张保华
王超鹏
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Beijing Research Center of Intelligent Equipment for Agriculture
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Beijing Research Center of Intelligent Equipment for Agriculture
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/359Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light using near infrared light
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/3563Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing solids; Preparation of samples therefor

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Abstract

The present invention provides a kind of apple soluble solid near infrared detection position compensation method and system, which comprises obtains the absorbance spectrum of the predetermined patterns of apple;Obtain the soluble solid content of the predetermined patterns of the apple;According to the absorbance spectrum and the soluble solid content, characteristic wavelength relevant to apple soluble solid is selected out of all band spectral region using characteristic wavelength filtering algorithm, establishes apple soluble solid near infrared spectrum detection model.The spectral information that the present invention passes through the fusion multiple positions of apple, binding characteristic wavelength filtering algorithm, establish apple soluble solid near infrared spectrum detection model, overcome influence of the variation at spectral detection position to apple soluble solid near infrared spectrum detection model, the stability of model is improved, has established theoretical basis for the portable detection and on-line checking of apple soluble solid content in actual production.

Description

A kind of apple soluble solid near infrared detection position compensation method and system
Technical field
The present invention relates to fruit quality detection field more particularly to a kind of apple soluble solid near infrared detection positions Compensation method and system.
Background technique
Soluble solid refers to the general name of all compounds for being dissolved in water in liquid or fluid food, including sugar, acid, Vitamin, minerals etc..The soluble solid content of apple is the important indicator of measuring apple internal quality, and influences to disappear The determinant of the person's of expense purchase intention.
Currently, near-infrared spectrum technique is obtained with the advantage of its quick nondestructive in apple soluble solid context of detection It is widely applied.However, the stability of model is often by the temperature change of apple, the shadow of the factors such as the place of production, kind, seasonal variation It rings.In addition, the soluble solid content of apple surface is unevenly distributed, distribution trend is gradually risen along carpopodium to calyx direction Height, accordingly, it is possible to cause to have differences between the spectrum of different parts.
In the prior art, the research about the detection of apple soluble solid near infrared spectrum is mostly to be directed to equator position, By acquiring the spectral information at apple equator position, apple soluble solid near infrared spectrum detection model is established.Therefore, when When removing the soluble solid content of prediction other positions of apple such as carpopodium with the model, precision of prediction will be affected.
Summary of the invention
For the defects in the prior art, the present invention provides a kind of apple soluble solid near infrared detection position compensation Method and system, by merging the spectral information at the multiple positions of apple, binding characteristic wavelength filtering algorithm establishes apple solubility Solid content near infrared spectrum detection model overcomes the variation at spectral detection position to apple soluble solid near infrared spectrum The influence of detection model improves the stability of model.
In a first aspect, the present invention provides a kind of apple soluble solid near infrared detection position compensation method, the side Method includes:
Obtain the absorbance spectrum of the predetermined patterns of apple;
Obtain the soluble solid content of the predetermined patterns of the apple;
According to the absorbance spectrum and the soluble solid content, binding characteristic wavelength filtering algorithm establishes apple Fruit soluble solid near infrared spectrum detection model;
Wherein, the apple predetermined patterns include carpopodium, equator and the calyx of apple.
Preferably, the absorption spectrum degree of the predetermined patterns for obtaining apple, comprising:
By integrating sphere diffusing reflection method, the absorbance light of the predetermined patterns of the apple in default wave band section is obtained Spectrum.
Preferably, the absorbance spectrum of the predetermined patterns for obtaining apple, comprising:
Acquire the absorbance spectrum of the predetermined patterns of multiple apples;
Second dervative processing is carried out to the absorbance spectrum of the predetermined patterns of the multiple apple, acquisition is multiple, and treated Absorbance spectrum.
Preferably, described according to the absorbance spectrum and the soluble solid content, the screening of binding characteristic wavelength Algorithm establishes apple soluble solid near infrared spectrum detection model, comprising:
Binding characteristic wavelength filtering algorithm is selected solvable with apple from all band absorbance spectrum of the predetermined patterns The property relevant characteristic wavelength of solid content;
According to the absorbance spectrum and its corresponding solubility under the characteristic wavelength of the predetermined number apple predetermined patterns Solid content establishes apple soluble solid near infrared spectrum detection model using partial least squares algorithm.
Preferably, the apple soluble solid near infrared spectrum detection model, specifically:
Y=∑ Akλk+B;
Wherein, Y is the estimated value of apple soluble solid content, and k is the characteristic wavelength selected, λkFor under k wavelength Absorbance spectrum, AkFor λkRegression coefficient, B is constant.
Preferably, which is characterized in that the method also includes:
It tests to the apple soluble solid near infrared spectrum detection model.
It is preferably, described to test to the apple soluble solid near infrared spectrum detection model, comprising:
Obtain the measured value of the trap spectrum and soluble solid content of examining apple;
It is closely red using the apple soluble solid according to the trap spectrum under the characteristic wavelength for examining apple External spectrum detection model obtains the estimated value of soluble solid content;
The estimated value of the measured value of the soluble solid content and the soluble solid content is compared, Detection evaluation index is obtained, the detection evaluation index is for judging the apple soluble solid near infrared spectrum detection mould The estimated performance of type.
Second aspect, the present invention provide a kind of apple soluble solid near infrared detection position compensation system, the system System includes:
First acquisition unit, the absorbance spectrum of the predetermined patterns for obtaining apple;
Second acquisition unit, the soluble solid content of the predetermined patterns for obtaining the apple;
What modeling unit, the absorbance spectrum obtained according to the first acquisition unit and the second acquisition unit obtained Soluble solid content, binding characteristic wavelength filtering algorithm establish apple soluble solid near infrared spectrum detection model;
Wherein, the apple predetermined patterns include carpopodium, equator and the calyx of apple.
Preferably, the first acquisition unit, is specifically used for,
Acquire the absorbance spectrum of the predetermined patterns of multiple apples;
Second dervative processing is carried out to the absorbance spectrum of the predetermined patterns of the multiple apple, acquisition is multiple, and treated Absorbance spectrum.
Preferably, the modeling unit, is specifically used for,
Binding characteristic wavelength filtering algorithm is selected solvable with apple from all band absorbance spectrum of the predetermined patterns The property relevant characteristic wavelength of solid content;
According to the absorbance spectrum and its corresponding solubility under the characteristic wavelength of the predetermined number apple predetermined patterns Solid content establishes apple soluble solid near infrared spectrum detection model using partial least squares algorithm.
As shown from the above technical solution, the present invention provides a kind of apple soluble solid near infrared detection position compensation side Method and system, by merging the spectral information of the multiple positions of apple such as carpopodium, equator and calyx, the screening of binding characteristic wavelength is calculated Method, establishes apple soluble solid near infrared spectrum detection model, and the variation for overcoming spectral detection position is solvable to apple Property solid content near infrared spectrum detection model influence, improve the stability of model, be that apple solubility is solid in actual production The portable detection of shape object content and on-line checking have established theoretical basis.
Detailed description of the invention
In order to illustrate more clearly of the embodiment of the present disclosure or technical solution in the prior art, to embodiment or will show below There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Disclosed some embodiments for those of ordinary skill in the art without creative efforts, can be with Other attached drawings are obtained according to these figures.
Fig. 1 is a kind of apple soluble solid near infrared detection position compensation method that one embodiment of the invention provides Flow diagram;
Fig. 2 be another embodiment of the present invention provides a kind of apple soluble solid near infrared detection position compensation method Flow diagram;
Fig. 3 is a kind of apple soluble solid near infrared detection position compensation method that one embodiment of the invention provides Structure is intended to;
Fig. 4 is the apple spectra collection position schematic diagram that one embodiment of the invention provides;
Fig. 5 is the scatter diagram for the forecast set sample predictions result that one embodiment of the invention provides.
Specific embodiment
With reference to the accompanying drawings and examples, specific embodiments of the present invention will be described in further detail.Implement below Example is not intended to limit the scope of the invention for illustrating the present invention.
Fig. 1 shows a kind of apple soluble solid near infrared detection position compensation side of one embodiment of the invention offer The flow diagram of method, as shown in Figure 1, a kind of apple soluble solid near infrared detection position compensation side of the present embodiment Method, which comprises
S11, obtain apple predetermined patterns absorbance spectrum.
It is understood that the apple predetermined patterns include carpopodium, equator and the calyx of apple.
Specifically, apple is obtained using InGaAs detector by Antaris II ft-nir spectrometer The carpopodium of fruit, equator and calyx absorbance spectrum.
S12, obtain the apple predetermined patterns soluble solid content.
It is understood that the measurement of apple soluble solid content, which refers to, uses the semi-automatic Abbe of 500 type of Arias Refractometer (Reichert Inc., USA).
Specifically, after the completion of spectra collection, and then using traditional destructive test successively from the carpopodium of apple, red Road and calyx are adopted part and are cut with arillate surface layer pulp, and gauze for filtering is placed on, and squeeze out juice 1~2 and drip, measure apple Soluble solid content.
S13, according to the absorbance spectrum and the soluble solid content, binding characteristic wavelength filtering algorithm is built Vertical apple soluble solid near infrared spectrum detection model.
The present embodiment passes through the spectral information at the fusion multiple positions of apple, and binding characteristic wavelength filtering algorithm establishes apple Soluble solid near infrared spectrum detection model, the variation for overcoming spectral detection position are closely red to apple soluble solid The influence of external spectrum detection model improves the stability of model, just for apple soluble solid content in actual production It takes detection and on-line checking has established theoretical basis.
Fig. 2 shows another embodiment of the present invention provides a kind of compensation of apple soluble solid near infrared detection position The flow diagram of method, as shown in Fig. 2, a kind of apple soluble solid near infrared detection position compensation side of the present embodiment Method, which comprises
S21, obtain apple predetermined patterns absorbance spectrum.
It is understood that obtaining the default of the apple in default wave band section by integrating sphere diffusing reflection method The absorbance spectrum at position.Wherein, scanning times are 32 times, resolution ratio 4cm-1, the default wave band section is 10000- 4000cm-1
Above-mentioned step S21 can be following step S211-S212 being not shown in the figure:
S211, the multiple apples of acquisition predetermined patterns absorbance spectrum.
It is understood that sample of multiple apples as modeling should be chosen in order to improve the accuracy of modeling.
S212, second dervative processing is carried out to the absorbance spectrum of the predetermined patterns of the multiple apple, obtains multiple places Absorbance spectrum after reason.
It is understood that collected absorbance spectrum, often containing the random noise of instrument, in addition, baseline drift, The spuious introducing for the information such as penetrating of light, also will affect the corresponding relationship between near infrared spectrum and soluble solid content, causes The reliability and stability of model built reduce.
Specifically, in the present embodiment, second dervative processing, application are carried out by the absorbance spectrum to acquired original Leading that treated through second order, spectroscopic data carries out subsequent modeling analysis.
S22, obtain the apple predetermined patterns soluble solid content.
It is understood that the measurement of apple soluble solid content, which refers to, uses the semi-automatic Abbe of 500 type of Arias Refractometer (Reichert Inc., USA).
Specifically, after the completion of spectra collection, and then using traditional destructive test successively from the carpopodium of apple, red Road and calyx are adopted part and are cut with arillate surface layer pulp, and gauze for filtering is placed on, and squeeze out juice 1~2 and drip, measure apple Soluble solid content.
S23, according to the absorbance spectrum and the soluble solid content, binding characteristic wavelength filtering algorithm is built Vertical apple soluble solid near infrared spectrum detection model.
Above-mentioned step S23 can be following step S231-S232 being not shown in the figure:
S231, binding characteristic wavelength filtering algorithm, are selected and apple from all band absorbance spectrum of the predetermined patterns The relevant characteristic wavelength of fruit soluble solid.
It is understood that there are a large amount of redundancy and colinearity informations between spectral variables, to spectral effective information The problems such as extraction produces biggish interference, causes model complicated, computationally intensive.
Preferably, in the present embodiment, the spectroscopic data based on above-mentioned multiple detection positions, using competitive adaptive weight Weighting algorithm, from all band 10000-4000cm-1The characteristic wavelength for picking out apple soluble solid content, for establishing apple Fruit soluble solid near infrared spectrum detection model.
S232, according under the characteristic wavelength of the predetermined number apple predetermined patterns absorbance spectrum and its it is corresponding can Dissolubility solid content establishes apple soluble solid near infrared spectrum detection model using partial least squares algorithm.
Specifically, the apple soluble solid near infrared spectrum detection model are as follows:
Y=∑ Akλk+B;
Wherein, Y is the estimated value of apple soluble solid content, and k is the characteristic wavelength selected, λkFor under k wavelength Absorbance spectrum, AkFor λkRegression coefficient, B is constant.
S24, it tests to the apple soluble solid near infrared spectrum detection model.
Above-mentioned step S24 can be following step S241-S243 being not shown in the figure:
S241, the measured value for obtaining the trap spectrum and soluble solid content of examining apple.
It is understood that can choose and build respectively to verify the precision of prediction and stability of above-mentioned established model Apple used in mould and new apple obtain the trap spectrum for examining apple as apple is examined, and utilize the method for step S22 Obtain the measured value of its corresponding soluble solid content.
S242, according to it is described examine apple trap spectrum, utilize the apple soluble solid near infrared spectrum Detection model obtains the estimated value of soluble solid content.
It is understood that utilizing model Y=∑ A according to the trap spectrum for examining applekλk+ B is obtained solvable The estimated value of property solid content.
S243, the estimated value of the measured value of the soluble solid content and the soluble solid content is carried out Compare, obtains detection evaluation index, the detection evaluation index is for judging the apple soluble solid near infrared spectrum The estimated performance of detection model.
It is understood that detection evaluation index includes related coefficient and root-mean-square error.
The present embodiment passes through the spectral information at the fusion multiple positions of apple, and binding characteristic wavelength filtering algorithm establishes apple Soluble solid near infrared spectrum detection model, the variation for overcoming spectral detection position are closely red to apple soluble solid The influence of external spectrum detection model improves the stability of model, just for apple soluble solid content in actual production It takes detection and on-line checking has established theoretical basis.
Fig. 3 show another embodiment of the present invention provides a kind of apple soluble solid near infrared detection position compensation The structural schematic diagram of system, as shown in figure 3, a kind of apple soluble solid near infrared detection position of the present embodiment compensates system System 30, comprising:
First acquisition unit 31, the absorbance spectrum of the predetermined patterns for obtaining apple;
Second acquisition unit 32, the soluble solid content of the predetermined patterns for obtaining the apple;
Modeling unit 33, the absorbance spectrum obtained according to the first acquisition unit 31 and the second acquisition unit 32 The soluble solid content of acquisition, binding characteristic wavelength filtering algorithm establish the inspection of apple soluble solid near infrared spectrum Survey model;
Wherein, the apple predetermined patterns include carpopodium, equator and the calyx of apple.
Another embodiment of the present invention provides a kind of apple soluble solid near infrared detection position compensation system in,
The first acquisition unit 31, is specifically used for,
Acquire the absorbance spectrum of the predetermined patterns of multiple apples;
Second dervative processing is carried out to the absorbance spectrum of the predetermined patterns of the multiple apple, acquisition is multiple, and treated Absorbance spectrum.
The modeling unit 33, is specifically used for,
Binding characteristic wavelength filtering algorithm is selected solvable with apple from all band absorbance spectrum of the predetermined patterns The property relevant characteristic wavelength of solid content;
According to the absorbance spectrum and its corresponding solubility under the characteristic wavelength of the predetermined number apple predetermined patterns Solid content establishes apple soluble solid near infrared spectrum detection model using partial least squares algorithm.
The present embodiment passes through the spectral information at the fusion multiple positions of apple, and binding characteristic wavelength filtering algorithm establishes apple Soluble solid near infrared spectrum detection model, the variation for overcoming spectral detection position are closely red to apple soluble solid The influence of external spectrum detection model improves the stability of model, just for apple soluble solid content in actual production It takes detection and on-line checking has established theoretical basis.
In one particular embodiment of the present invention, as described below:
95 apples are chosen as calibration set, for establishing model;35 apples are chosen as forecast set, for being modeled The inspection of type.
At room temperature, as shown in figure 4, to all 130 apples, successively from the carpopodium of each apple, equator and 3, calyx Part acquisition absorbance spectrum.
After the completion of spectra collection, and then using traditional destructive test successively from the carpopodium of apple sample, equator and Calyx is adopted part and is cut with arillate surface layer pulp, and the soluble solid content of apple is measured.
Second dervative processing is carried out to the absorbance spectrum of acquisition, using treated that spectroscopic data carries out through second dervative Subsequent modeling analysis.
Binding characteristic wavelength filtering algorithm selects characteristic wave relevant to apple soluble solid out of full band range It is long, particularly, in this example, using competitive adaptive weight weighting algorithm, from all band 10000-4000cm-1Pick out 66 It is solvable to establish the apple based on selected characteristic wavelength using partial least squares algorithm for the characteristic wavelength of a apple soluble solid Property solid content near infrared spectrum detection model.
Model expression is as follows:
Y=-56525.898 λ4078.7-22856.338λ4182.8-36943.720λ4269.6+56956.642λ4271.5+ 154815.334λ4313.9+113330.183λ4398.8+129408.255λ4504.8-117514.829λ4539.6-121295.514 λ4541.5-121564.421λ4545.3-84672.852λ4636.0-90901.481λ4637.9-82541.703λ4703.5-89625.552 λ4707.3-104470.820λ4738.2-105405.841λ4769.0-106029.872λ4786.4-108989.175λ4788.3- 107924.008λ4796.0-104129.292λ4988.9-103529.299λ4990.8-111549.708λ5085.3-115909.981 λ5490.3-106618.822λ5496.1-116337.682λ5498.0+106438.398λ5688.9+96029.676λ5810.4+ 115032.826λ5814.3+107935.301λ5957.0-91748.438λ5958.9-88456.837λ5960.8-95833.780λ5962.8+ 199904.1549λ5966.6+189393.5788λ5968.6+160175.552λ6190.3+142319.686λ6196.1+126593.009 λ6198.0+116570.457λ7135.3+122100.435λ7225.9+207595.089λ7239.4-83566.187λ7241.3- 67547.235λ7291.5-63108.673λ7293.4-70816.081λ7320.4-89420.384λ7322.3+171940.532λ7357.1+ 175047.273λ7359.0-60733.900λ7362.8-91592.019λ7364.8-85493.596λ7386.0-177139.329λ7387.9- 206453.142λ7391.8-115512.261λ8342.5-129283.029λ8572.0-153976.382λ8573.9-150740.715 λ8575.8-117422.490λ8629.8-114922.986λ8631.8-127950.490λ8633.7+54391.231λ8755.2- 105707.858λ8757.1+242191.880λ8826.5+147387.742λ9513.1+80160.282λ9601.8-159513.138 λ9605.6-220245.358λ9744.5+7.124;
Wherein, Y is the estimated value of apple soluble solid content, and unit is ° Brix.λ4078.7It is for wave number 4078.7cm-1It is corresponding through second order spectral value of leading that treated, 56525.898 be λ4078.7Regression coefficient, 7.124 be constant.
In order to verify the precision of prediction and stability of above-mentioned model built, using above-mentioned model to calibration set, and comprising There is the soluble solid content of the forecast set sample of 3 different parts spectral informations to be detected, and result is evaluated. Evaluation index lieutenant colonel's positive correlation coefficient (rc), prediction related coefficient (rp) bigger, correction root-mean-square error (RMSEC), prediction are square Root error more (RMSEP) is small, illustrates that model prediction performance is better.Prediction result is as shown in table 1 below:
Table 1
Related coefficient between calibration set and the predicted value and measured value of forecast set is all larger than 0.95, and root-mean-square error is small In 0.5 ° of Brix, satisfied precision of prediction is obtained.Meanwhile preferable prediction is achieved to the forecast set of 3 groups of different parts As a result, illustrating that the model is insensitive for the variation at spectral detection position.
As shown in figure 5, sample has good linear prediction effect close to regression straight line two sides are distributed in.The above results Illustrate that the variation at spectral detection position can be reduced to apple soluble solid near infrared spectrum using the method for the present embodiment The influence of detection model.
In order to verify the validity of selected characteristic wavelength in the spectral information obtained by multiple acquisition positions, with equator position Spectrum be calibration set, establish the apple soluble solid calibration model based on selected characteristic wavelength, still through contain 3 The prediction the set pair analysis model of different parts spectral information is verified.Modeling and prediction result are as shown in table 2 below.Meanwhile in order to say The validity of bright characteristic wavelength gives the result of the model based on equator position all band establishment of spectrum in table 2.
Table 2
Compare above-mentioned two model, it can be seen that the apple soluble solid established based on all band equator position is close Infrared spectroscopy detection model can be generated when being different from the position such as soluble solid content at calyx position for detecting Fairly obvious error.And the model established based on 66 characteristic wavelengths, while the precision of prediction of model is improved, to 3 A forecast set is without there is biggish prediction error.Therefore, by 66 validity feature wavelength of screening, it can reduce spectrum Detect the influence for the model that change in location establishes the spectral information based on single position such as equator.
Those of ordinary skill in the art will appreciate that: the above embodiments are only used to illustrate the technical solution of the present invention., and It is non-that it is limited;Although present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art It is understood that it is still possible to modify the technical solutions described in the foregoing embodiments, either to part of or All technical features are equivalently replaced;And these are modified or replaceed, it does not separate the essence of the corresponding technical solution this hair Bright claim limited range.

Claims (6)

1. a kind of apple soluble solid near infrared detection position compensation method, which is characterized in that the described method includes:
Acquire the absorbance spectrum of the predetermined patterns of multiple apples;
Second dervative processing is carried out to the absorbance spectrum of the predetermined patterns of the multiple apple, obtains multiple treated extinctions Spend spectrum;
Obtain the soluble solid content of the predetermined patterns of the apple;
Binding characteristic wavelength filtering algorithm is selected solid with apple solubility from all band absorbance spectrum of the predetermined patterns The relevant characteristic wavelength of shape object;
According under the characteristic wavelength of predetermined number apple predetermined patterns absorbance spectrum and its corresponding soluble solid contain Amount, establishes apple soluble solid near infrared spectrum detection model using partial least squares algorithm;
Wherein, the apple predetermined patterns include carpopodium, equator and the calyx of apple.
2. the method according to claim 1, wherein it is described obtain apple predetermined patterns absorbance spectrum, Include:
By integrating sphere diffusing reflection method, the absorbance spectrum of the predetermined patterns of the apple in default wave band section is obtained.
3. the method according to claim 1, wherein the apple soluble solid near infrared spectrum detects mould Type, specifically:
Y=∑ Akλk+B;
Wherein, Y is the estimated value of apple soluble solid content, and k is the characteristic wavelength selected, λkFor the absorbance under k wavelength Spectrum, AkFor λkRegression coefficient, B is constant.
4. method according to claim 1-3, which is characterized in that the method also includes:
It tests to the apple soluble solid near infrared spectrum detection model.
5. according to the method described in claim 4, it is characterized in that, described to the apple soluble solid near infrared spectrum Detection model is tested, comprising:
Obtain the measured value of the absorbance spectrum and soluble solid content of examining apple;
According to the absorbance spectrum under the characteristic wavelength for examining apple, the apple soluble solid near infrared light is utilized Detection model is composed, the estimated value of soluble solid content is obtained;
The estimated value of the measured value of the soluble solid content and the soluble solid content is compared, is obtained Evaluation index is detected, the detection evaluation index is for judging the apple soluble solid near infrared spectrum detection model Estimated performance.
6. a kind of apple soluble solid near infrared detection position compensation system, which is characterized in that the system comprises:
First acquisition unit, the absorbance spectrum of the predetermined patterns for obtaining apple;
Second acquisition unit, the soluble solid content of the predetermined patterns for obtaining the apple;
Modeling unit, the absorbance spectrum obtained according to the first acquisition unit and the second acquisition unit obtain solvable Property solid content, binding characteristic wavelength filtering algorithm establish apple soluble solid near infrared spectrum detection model;
Wherein, the apple predetermined patterns include carpopodium, equator and the calyx of apple;
The first acquisition unit, is specifically used for,
Acquire the absorbance spectrum of the predetermined patterns of multiple apples;
Second dervative processing is carried out to the absorbance spectrum of the predetermined patterns of the multiple apple, obtains multiple treated extinctions Spend spectrum;
The modeling unit, is specifically used for,
Binding characteristic wavelength filtering algorithm is selected solid with apple solubility from all band absorbance spectrum of the predetermined patterns The relevant characteristic wavelength of shape object;
According under the characteristic wavelength of predetermined number apple predetermined patterns absorbance spectrum and its corresponding soluble solid contain Amount, establishes apple soluble solid near infrared spectrum detection model using partial least squares algorithm.
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