CN105544222A - Chitosan and polyester-polyether copolymer hydrophilic finishing method of dacron fabric - Google Patents
Chitosan and polyester-polyether copolymer hydrophilic finishing method of dacron fabric Download PDFInfo
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- CN105544222A CN105544222A CN201610047997.5A CN201610047997A CN105544222A CN 105544222 A CN105544222 A CN 105544222A CN 201610047997 A CN201610047997 A CN 201610047997A CN 105544222 A CN105544222 A CN 105544222A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0024—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid beta-D-Glucans; (beta-1,3)-D-Glucans, e.g. paramylon, coriolan, sclerotan, pachyman, callose, scleroglucan, schizophyllan, laminaran, lentinan or curdlan; (beta-1,6)-D-Glucans, e.g. pustulan; (beta-1,4)-D-Glucans; (beta-1,3)(beta-1,4)-D-Glucans, e.g. lichenan; Derivatives thereof
- C08B37/0027—2-Acetamido-2-deoxy-beta-glucans; Derivatives thereof
- C08B37/003—Chitin, i.e. 2-acetamido-2-deoxy-(beta-1,4)-D-glucan or N-acetyl-beta-1,4-D-glucosamine; Chitosan, i.e. deacetylated product of chitin or (beta-1,4)-D-glucosamine; Derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/11—Oleophobic properties
Abstract
The invention discloses a chitosan and polyester-polyether copolymer hydrophilic finishing method of dacron fabric, and belongs to the technical field of textile finishing methods. The finishing process is completed through the four steps of preparing a chitosan degradation solution, preparing a polyester-polyether copolymer solution, compounding the finishing solutions and carrying out hydrophilic finishing on the dacron fabric. According to the method, in the finishing process, sodium hydroxide and hydrogen peroxide are added to carry out activating treatment on chitosan, and treated chitosan is then compounded with the polyester-polyether-organosilicone terpolymer hydrophilic finishing agent solution, so that the obtained finishing solution has high activity, and an excellent finishing effect is achieved by adding a small quantity of the finishing solution; the adding quantity of chitosan is small, the operating cost is low, the technology is simple, easy and convenient to implement and low in toxicity and pollution, and the finished fabric has good washability and hydrophilicity and has good industrial popularization prospects.
Description
Technical field:
The invention discloses a kind of shitosan-polyester-polyether block copolymer hydrophilic finiss method of dacron, belong to textile finishing process technical field.
Background technology:
Terylene is the trade name of polyethylene terephthalate (PET) fiber, is one of the large main force of three in synthetic fiber fiber.Because terylene linear macromolecule is symmetry benzene ring structure, good linearity and molecular chain structure stereoregular, it is had, and intensity is high, good springiness and the rigidity superior physical and mechanical properties such as large, and weak acid, alkali are stablized, there is excellent DIMENSIONAL STABILITY and good corrosion resistance, it is a kind of ideal textile fabric, but, terylene is a kind of typical hydrophobic fibre, only respectively there is a hydroxyl at its molecule two ends, and without other hydrophilic radical, molecular structure is close-packed arrays, degree of crystallinity is high, and hygroscopicity is poor.In normal conditions (20 DEG C of relative humidity 65%), the hydroscopicity of terylene only has about 0.4% (cotton 7-8%, polyamide fibre 4%, acrylic fibers 1-2%), and under the condition of 100% relative humidity, hydroscopicity is also only 0.6-0.8%.Therefore its hygroscopicity poor, easily produce electrostatic, easily stain, affect its snugness of fit.
Hydrophilic finiss, is referred to as water suction (or absorbing sweat) at first and arranges, and is to be suggested for the advanced motion clothes based on dacron or training clothes.Endowing terylene fiber or fabric hydrophilic mainly contain two kinds of methods: one is spinning modification: in the spinning process of fiber, utilize the synthetic technology of fiber to carry out modification to Structure of PET Fiber, make polyster fibre itself have hydrophilicity, thus improve the wearability of terylene; The method process routes relative complex, operability is more weak.Two is arrange modification: mostly at fiber surface modification, utilize dacron afterfinish technology and reach modification object.Namely on terylene macromolecular chain, introduce hydrophilic radical, make fabric face form hydrophilic layer, thus change fiber surface performance.
The method of spinning modification mainly contains at present: polymer molecular structure hydrophiling, hydrophilic component graft copolymerization, microporous, heteromorphosis etc. with hydrophilic component compound co-spun yarn and fibre structure.
Polymer molecular structure hydrophiling: by polymerization or the mode of copolymerization, introduce hydrophilic radical in the macromolecular basic structure of terylene, improves the hydrophily of terylene.But it is very limited to improve hydrophilic degree, and the copolymerization efficiency of polar compound and terylene is very low.Polymerization process also can weaken the crystallizing power of terylene greatly, reduces its fusing point, affects its spinning, have harmful effect to the physical and mechanical properties of fiber, therefore strictly will control the consumption of hydrophilic monomer.
Hydrophilic component graft copolymerization: hydrophilic component will be had as side chain, and polyester macromolecule carry out grafting, obtains modified polyester fibre, endowing terylene hydrophilicity.
Hydrophilic component compound co-blended spinning: before spinning, hydrophilic compounds or the modified poly ester containing hydrophilic radical are mixed into high polymer molten, and spin processes carries out spinning routinely, can obtain a kind of Hydrophilic Polyester Fiber fiber, thus promotes the hydrophily of fiber.Though the research improving terylene hydrophilicity about compound co-blended spinning method is many, spinning solution is unstable mostly, and spinning process is influenced, and the washability of the Hydrophilic Polyester Fiber fiber of spinning is also bad.
The microporous of fibre structure, heteromorphosis: the microporous of fibre structure is for the purpose of the morphosis changing fiber, makes fibre structure fibrillation, have the inside and outside through micropore of the natural fabric such as many picture hairs or cotton, utilize capillarity to make fibrous absorbent.But this method can only improve water absorbing properties, the hygroscopicity of fiber can not be improved.
Arrange modification: carry out hydrophilic modifying on the surface of polyster fibre or fabric, its essence is and form one deck hydrophilic film on the surface of fiber or fabric, improve the hydrophilicity of PET fiber surface.The method technique is simple, but not durable, therefore also should promote the durability of polyster fibre hydrophilicity.Arrange method mainly hydrophilic monomer or polymer surfaces graft polymerization method, other process (plasma modification and Silk Fibroin Coating Finishing etc.) of fiber surface and the absorption set method etc. of hydrophilic finish agent of modification.
Current hydrophilic finishing agent has a variety of, is generally divided into polyesters (polyester polyethers, sulfonated polyester and mixed type polyester), polysiloxane-based, the type such as polyurethanes, polyacrylate, polyamine class and shitosan class.
Although polysiloxane-based hydrophilic finishing agent is applicable to dacron etc. close arrangement that is fine and BLENDED FABRIC, hydrophilic durability is poor; Though polyurethanes hydrophilic finishing agent is good to the impregnability of dacron and wettability, it has low temperature dissociative, can be few for kind; Polyacrylate hydrophilic finishing agent is difficult to balance between the hydrophilicity and feel of fabric, and resultant effect is bad; During polyamine class hydrophilic finishing agent processing fabric, washability is poor, easy yellowing, is mainly used in acrylic fibers and BLENDED FABRIC thereof; Although shitosan class hydrophilic finishing agent asepsis environment-protecting, the hydrophilicity of finish fabric is better, and its operating cost is higher, complex procedures, and washability is poor.And polyester polyethers hydrophilic finishing agent can to get both good hydrophily and washability when arranging dacron, but the polymer molecular structure of synthesis is regular, degree of crystallinity is higher, poorly water-soluble, easily assemble in water, affect use and the effect of finishing agent, therefore need in use first will carry out emulsification, the rear method finish fabric adopting dipping or pad, but its poorly water-soluble causes dyeing together, and bath effect is bad.
The people such as Sui Yanling disclose the document of a section by name " shitosan-polyester polyether-type hydrophilic finishing agent " in " printing and dyeing " magazine disclosed in 2010: by polyester polyether-type hydrophilic finishing agent KL-WPS and shitosan composite, hydrophilic finiss is carried out to polyester textile.Result of the test shows, hydrophilic finishing agent consumption 60g/L, both compound proportions are 1:1, the hygroscopicity of polyester textile, wet guilding, pollution resistance and antistatic behaviour etc., the effect of all single than use polyester polyethers hydrophilic finishing agent will be well of the present invention closest to prior art, but shitosan use amount is larger in this invention, because shitosan cost is higher, process operation high expensive, hydrophily and the washability effect of the rear dacron of its arrangement of the method are simultaneously excellent not, especially resistance to water effect is not ideal enough, has much room for improvement.
Summary of the invention:
The object of the invention is to for the deficiencies in the prior art, overcome polyether polyester class hydrophilic finiss and, complex procedures, washability and poorly water-soluble high with shitosan class finishing agent operating cost in hydrophilic finiss process, the dissatisfactory shortcoming of hydrophilic effect, a kind of shitosan-polyester-polyether block copolymer hydrophilic finiss method of dacron is provided, the method operating cost is low, technique is simple to operation, low toxicity low stain, after arranging, fabric has good washability and hydrophily.
The invention provides following technical scheme:
Shitosan-polyester-polyether block copolymer hydrophilic finiss method of dacron, comprises following operating procedure:
The first step: preparation degradation of chitosan liquid:
The sodium hydrate aqueous solution of 30 times of chitosan masses will be added in shitosan, add the hydrogen peroxide of 10 times of chitosan masses after stirring and dissolving, be warming up to 35 DEG C of clock reaction 2-3h;
Second step: prepare polyester-polyether block copolymer solution:
The deionized water of 1 times of quality will be added in polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent, be warming up to 70-75 DEG C and stir 15-20min;
3rd step: dressing liquid is composite:
Degradation of chitosan liquid is mixed according to weight ratio 1:10-15 with polyester-polyether block copolymer solution, stirs and obtain dressing liquid;
4th step: the hydrophilic finiss of dacron:
Adopt two leaching two roll process, bath raio is 1:20-30, and the addition of dressing liquid is 3-6%;
Process from 40 DEG C, be warming up to 120 DEG C with the speed of 3-4 DEG C/min, insulation 30-40min; 50 DEG C are cooled to, insulation 10-15min with 2-3 DEG C/min;
Preliminary drying twice, preliminary drying temperature is 90-105 DEG C, and preliminary drying time is 2-3min;
Cure twice, stoving temperature is 120-130 DEG C, and the time of curing is 1-2min;
Cold wash, dries.
Preferably, in the described first step, the mass concentration of sodium hydrate aqueous solution is 50-55%;
Described hydrogen peroxide is AR, H
2o
2active constituent content is 30%.
Preferably, described shitosan is cm-chitosan, its active principle content >=99%, viscosity≤100mpa.s, carboxylation degree >=60%, deacetylation >=85%, content of beary metal≤10ppm, and solution ph is 6.0-8.0.
Preferably, described polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent are purchased from Zhangjiagang Debao Chemical Co., Ltd., and name of product is for washing easypro precious DP-9993, its active constituent content >=96%.
Preferably, adopt two leaching two roll process in described 4th step, bath raio is 1:25, and the addition of dressing liquid is 5%; Process from 40 DEG C, be warming up to 120 DEG C with the speed of 3 DEG C/min, insulation 30min; 50 DEG C are cooled to, insulation 15min with 3 DEG C/min.
Preferably, preliminary drying twice in described 4th step, preliminary drying temperature is 100 DEG C, and preliminary drying time is 3min; Stoving temperature is 120 DEG C, and the time of curing is 2min.
Cm-chitosan is a kind of water-solubility chitosan derivative, has numerous characteristics, and as antibiotic property is strong, having preservation, is a kind of polyampholyte etc.Cosmetics, fresh-keeping, medical etc. in have multiple application, be also that Recent study obtains one of more chitosan derivatives.Cm-chitosan obtains with monoxone and chitosan reaction in the presence of base, but the carboxymethyl of carboxymethyl chitin replaces on the C6-OH of saccharide residue, has a small amount of carboxymethyl to replace on C3-OH, generation be O-carboxymethyl chitin.
The replacement activity of carboxymethyl on hydroxyl is higher than amino in the basic conditions, therefore, when substitution value is less than 1, the replacement of carboxymethyl is mainly on hydroxyl instead of on amino, only have substitution value close to 1 and higher than 1 time, just can there is carboxymethyl on amino to replace simultaneously, form O, N-cm-chitosan.Cm-chitosan water-soluble, except because it be a kind of carboxylic acid sodium salt and water-soluble except, also have a reason to be the importing of carboxymethyl, destroy the secondary structure of chitosan molecule, its degree of crystallinity is reduced greatly, almost become amorphous.The present invention adopts in cm-chitosan and adds high-concentration sodium hydroxide, then hydrogen peroxide solution is added, carboxymethyl chitosan solution is demoted, obtain a large amount of active molecular species, a large amount of hydroxyls and carboxylic are by Van der Waals force and hydrogen bond action, be adsorbed onto fabric face, amino generation covalent cross-linking in the amino on dacron surface and carboxymethyl chitosan glycan molecule, improve hygroscopicity and the hydrophilicity of fabric, the electrostatic charge of fabric face can be spread rapidly simultaneously, thus makes dacron have good antistatic property.
The model that Zhangjiagang Debao Chemical Co., Ltd. produces is that hydrophilic finishing agent for washing easypro precious DP-9993 is applicable to hydrophilic, the perspire of the fabrics such as terylene, cotton synthetic fibre blending and cotton synthetic fibre, antistatic, easy decontamination and hand feel finishing, can give some characteristics of polyester and BLENDED FABRIC natural fabric thereof.The present invention is by this hydrophilic finishing agent and shitosan is composite obtains composite dressing liquid, and its finishing effect is better than both and is used alone, and reduces use amount simultaneously, reduces production cost, has higher economic benefit.
Textiles is in dyeing and printing process, when carrying out the item special finishings such as soft, crease-resistant, antistatic, fire-retardant, antibacterial, waterproof, after having padded treatment fluid, first the preliminary drying lower than 100 DEG C will be carried out, and then according to the concrete resin that applies and chemical attack requirement, then go to carry out 140-160 DEG C bake.The object of carrying out preliminary drying be prevent fabric from absorbing treatment fluid at too high a temperature, too quickly to fabric face migration, thus cause surface resin, the washing fastness that impact arranges, present invention optimizes hydrophilic finiss technique, the finishing effect of composite finishing liquid for dacron can be improved; Reduce preliminary drying temperature and stoving temperature, energy efficient simultaneously, raise the efficiency.
Beneficial effect of the present invention:
1. the present invention adopts in cm-chitosan and adds high-concentration sodium hydroxide, then hydrogen peroxide solution is added, carboxymethyl chitosan solution is degraded, obtain a large amount of active molecular species, a large amount of hydroxyls and carboxylic are by Van der Waals force and hydrogen bond action, be adsorbed onto fabric face, amino generation covalent cross-linking in the amino on dacron surface and carboxymethyl chitosan glycan molecule, improve hygroscopicity and the hydrophilicity of fabric, the electrostatic charge of fabric face can be spread rapidly simultaneously, thus makes dacron have good antistatic property.
2. the present invention is by this hydrophilic finishing agent and shitosan is composite obtains composite dressing liquid, and its finishing effect is better than both and is used alone, and simultaneously by the composite use amount that can reduce finishing agent, reduces production cost, has higher economic benefit.
3. present invention optimizes hydrophilic finiss technique, the finishing effect of composite finishing liquid for dacron can be improved; Reduce preliminary drying temperature and stoving temperature, energy efficient simultaneously, raise the efficiency.
4. the inventive method shitosan addition is few, and operating cost is low and simple process list is easy to operate, low toxicity low stain, and after arranging, fabric has good washability and hydrophily, has good commercial introduction prospect.
Detailed description of the invention:
Be described in detail embodiments of the invention below, the present embodiment is implemented under premised on invention technical scheme, give detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following embodiment.The experimental program of unreceipted actual conditions in embodiment, the condition that conveniently condition or manufacturer advise usually is implemented.
Embodiment one
Shitosan-polyester-polyether block copolymer hydrophilic finiss method of dacron, comprises following operating procedure:
The first step: preparation degradation of chitosan liquid:
The sodium hydrate aqueous solution (mass concentration is 50%) of 30 times of chitosan masses will be added in shitosan, after stirring and dissolving, add the hydrogen peroxide (H of 10 times of chitosan masses
2o
2active constituent content is 30%), be warming up to 35 DEG C of clock reaction 2h;
Second step: prepare polyester-polyether block copolymer solution:
The deionized water of 1 times of quality will be added in polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent, be warming up to 70 DEG C and stir 15min;
3rd step: dressing liquid is composite:
Degradation of chitosan liquid is mixed according to weight ratio 1:10 with polyester-polyether block copolymer solution, stirs and obtain dressing liquid;
4th step: the hydrophilic finiss of dacron:
Adopt two leaching two roll process, bath raio is 1:20, and the addition of dressing liquid is 3%;
Process from 40 DEG C, be warming up to 120 DEG C with the speed of 3 DEG C/min, insulation 30min; 50 DEG C are cooled to, insulation 10min with 2 DEG C/min;
Preliminary drying twice, preliminary drying temperature is 90 DEG C, and preliminary drying time is 2min;
Cure twice, stoving temperature is 120 DEG C, and the time of curing is 1min;
Cold wash, dries.
Embodiment two
Shitosan-polyester-polyether block copolymer hydrophilic finiss method of dacron, comprises following operating procedure:
The first step: preparation degradation of chitosan liquid:
The sodium hydrate aqueous solution (mass concentration is 55%) of 30 times of chitosan masses will be added in shitosan, after stirring and dissolving, add the hydrogen peroxide (H of 10 times of chitosan masses
2o
2active constituent content is 30%), be warming up to 35 DEG C of clock reaction 3h;
Second step: prepare polyester-polyether block copolymer solution:
The deionized water of 1 times of quality will be added in polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent, be warming up to 75 DEG C and stir 20min;
3rd step: dressing liquid is composite:
Degradation of chitosan liquid is mixed according to weight ratio 1:15 with polyester-polyether block copolymer solution, stirs and obtain dressing liquid;
4th step: the hydrophilic finiss of dacron:
Adopt two leaching two roll process, bath raio is 1:30, and the addition of dressing liquid is 6%;
Process from 40 DEG C, be warming up to 120 DEG C with the speed of 4 DEG C/min, insulation 40min; 50 DEG C are cooled to, insulation 15min with 3 DEG C/min;
Preliminary drying twice, preliminary drying temperature is 105 DEG C, and preliminary drying time is 3min;
Cure twice, stoving temperature is 130 DEG C, and the time of curing is 2min;
Cold wash, dries.
Embodiment three
Shitosan-polyester-polyether block copolymer hydrophilic finiss method of dacron, comprises following operating procedure:
The first step: preparation degradation of chitosan liquid:
The sodium hydrate aqueous solution (mass concentration is 50%) of 30 times of chitosan masses will be added in shitosan, after stirring and dissolving, add the hydrogen peroxide (H of 10 times of chitosan masses
2o
2active constituent content is 30%), be warming up to 35 DEG C of clock reaction 3h;
Second step: prepare polyester-polyether block copolymer solution:
The deionized water of 1 times of quality will be added in polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent, be warming up to 70 DEG C and stir 15-20min;
3rd step: dressing liquid is composite:
Degradation of chitosan liquid is mixed according to weight ratio 1:15 with polyester-polyether block copolymer solution, stirs and obtain dressing liquid;
4th step: the hydrophilic finiss of dacron:
Adopt two leaching two roll process, bath raio is 1:20, and the addition of dressing liquid is 6%;
Process from 40 DEG C, be warming up to 120 DEG C with the speed of 3 DEG C/min, insulation 40min; 50 DEG C are cooled to, insulation 15min with 2 DEG C/min;
Preliminary drying twice, preliminary drying temperature is 90 DEG C, preliminary drying time 3min;
Cure twice, stoving temperature is 120 DEG C, and the time of curing is 2min;
Cold wash, dries.
Embodiment four
Shitosan-polyester-polyether block copolymer hydrophilic finiss method of dacron, comprises following operating procedure:
The first step: preparation degradation of chitosan liquid:
The sodium hydrate aqueous solution (mass concentration is 55%) of 30 times of chitosan masses will be added in shitosan, after stirring and dissolving, add the hydrogen peroxide (H of 10 times of chitosan masses
2o
2active constituent content is 30%), be warming up to 35 DEG C of clock reaction 2h;
Second step: prepare polyester-polyether block copolymer solution:
The deionized water of 1 times of quality will be added in polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent, be warming up to 75 DEG C and stir 15min;
3rd step: dressing liquid is composite:
Degradation of chitosan liquid is mixed according to weight ratio 1:10 with polyester-polyether block copolymer solution, stirs and obtain dressing liquid;
4th step: the hydrophilic finiss of dacron:
Adopt two leaching two roll process, bath raio is 1:30, and the addition of dressing liquid is 3%;
Process from 40 DEG C, be warming up to 120 DEG C with the speed of 4 DEG C/min, insulation 30min; 50 DEG C are cooled to, insulation 10min with 3 DEG C/min;
Preliminary drying twice, preliminary drying temperature is 105 DEG C, and preliminary drying time is 2min;
Cure twice, stoving temperature is 130 DEG C, and the time of curing is 1min;
Cold wash, dries.
Embodiment five
Shitosan-polyester-polyether block copolymer hydrophilic finiss method of dacron, comprises following operating procedure:
The first step: preparation degradation of chitosan liquid:
The sodium hydrate aqueous solution (mass concentration is 50%) of 30 times of chitosan masses will be added in shitosan, after stirring and dissolving, add the hydrogen peroxide (H of 10 times of chitosan masses
2o
2active constituent content is 30%), be warming up to 35 DEG C of clock reaction 2h;
Second step: prepare polyester-polyether block copolymer solution:
The deionized water of 1 times of quality will be added in polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent, be warming up to 75 DEG C and stir 20min;
3rd step: dressing liquid is composite:
Degradation of chitosan liquid is mixed according to weight ratio 1:10 with polyester-polyether block copolymer solution, stirs and obtain dressing liquid;
4th step: the hydrophilic finiss of dacron:
Adopt two leaching two roll process, bath raio is 1:25, and the addition of dressing liquid is 5%; Process from 40 DEG C, be warming up to 120 DEG C with the speed of 3 DEG C/min, insulation 30min; 50 DEG C are cooled to, insulation 15min with 3 DEG C/min;
Preliminary drying twice, preliminary drying temperature is 90 DEG C, and preliminary drying time is 2min;
Cure twice, stoving temperature is 130 DEG C, and the time of curing is 2min;
Cold wash, dries.
Embodiment six
Shitosan-polyester-polyether block copolymer hydrophilic finiss method of dacron, comprises following operating procedure:
The first step: preparation degradation of chitosan liquid:
The sodium hydrate aqueous solution (mass concentration is 55%) of 30 times of chitosan masses will be added in shitosan, after stirring and dissolving, add the hydrogen peroxide (H of 10 times of chitosan masses
2o
2active constituent content is 30%), be warming up to 35 DEG C of clock reaction 3h;
Second step: prepare polyester-polyether block copolymer solution:
The deionized water of 1 times of quality will be added in polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent, be warming up to 70 DEG C and stir 15min;
3rd step: dressing liquid is composite:
Degradation of chitosan liquid is mixed according to weight ratio 1:15 with polyester-polyether block copolymer solution, stirs and obtain dressing liquid;
4th step: the hydrophilic finiss of dacron:
Adopt two leaching two roll process, bath raio is 1:30, and the addition of dressing liquid is 3%;
Process from 40 DEG C, be warming up to 120 DEG C with the speed of 4 DEG C/min, insulation 40min; 50 DEG C are cooled to, insulation 10min with 2 DEG C/min;
Preliminary drying twice, preliminary drying temperature is 100 DEG C, and preliminary drying time is 3min;
Cure twice, stoving temperature is 120 DEG C, and the time of curing is 2min.
Cold wash, dries.
Comparative example one:
Dacron does not arrange.
Comparative example two:
With embodiment six same procedure, difference is: 1. omit the first step and prepare degradation of chitosan liquid; 2. in the 3rd step, deionized water is mixed according to weight ratio 1:15 with polyester-polyether block copolymer solution, stir and obtain dressing liquid.
Comparative example three:
With embodiment six same procedure, difference is: 1. omit second step and prepare polyester-polyether block copolymer solution; 2. in the 3rd step, degradation of chitosan liquid is mixed according to weight ratio 1:15 with deionized water, stir and obtain dressing liquid.
Shitosan is cm-chitosan, its active principle content >=99%, viscosity≤100mpa.s, carboxylation degree >=60%, deacetylation >=85%, content of beary metal≤10ppm, and solution ph is 6.0-8.0.
Described polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent are purchased from Zhangjiagang Debao Chemical Co., Ltd., and name of product is for washing easypro precious DP-9993, its active constituent content >=96%.
In the embodiment of the present invention use fabric for dacron (being 67.5dtex/96F through tram).
Method of testing:
Hydrophily water droplet wetting time (by the test of AATCC-79 method) reflection;
Antistatic behaviour measures electrostatic pressure and electrostatic half-life by " GB-T12703-1991 textiles static electricity testing method ";
Water-wash resistance: washing 5min with 5g/L standard synthetic detergent at bath raio 1:30 temperature 40 DEG C in shaking bath pot is 1 time, terylene is hung nature for several times and dries by continuous washing, in order to carrying out fabric hydrophilic and antistatic property test.
Wherein washing times to be for 0 time after arrangement dacron hydrophilic and anti-electrical impact, wash 10 times and inquires into the water-wash resistance arranging rear dacrons 50 times.
Table one: method for sorting of the present invention is on the impact of dacron hydrophilic, antistatic behaviour
Method for sorting described in the embodiment of the present invention all has good hydrophily to dacron, antistatic behaviour is effect improved, and after being arranged by shitosan and the composite dressing liquid obtained of polyester-polyether block copolymer, effect is all better than being used alone shitosan and polyester-polyether block copolymer finishing agent.And we can draw according to table one, in washing process, the wetting time of dripping of finish fabric increases along with the increase of washing times, but comparatively comparative example increasing degree is little, and anlistatig durability is also relatively better, has higher economic benefit.
Experiment one: polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent extension rate affect for dacron hydrophilic.
Experimental technique: adopt the preparation of the method described in embodiment six to obtain degradation of chitosan liquid, adopting the hydrophilic finiss method of the dacron described in embodiment six simultaneously, obtaining preparing the impact of variable concentrations polyester-polyether block copolymer solution for dacron hydrophilic by adding the dilution of different quality deionized water quality in polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent.
Wherein dilute the deionized water that 1 times refers to add polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent weight 1 times, dilute the deionized water that 0.5 times refers to add polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent weight 0.5 times, dilute the deionized water that 2 times refer to add polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent weight 2 times, by that analogy.
Table two: polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent extension rate affect for dacron hydrophilic
| Extension rate | MEBO ribbon gauze (s) |
| 0 | 25 |
| 0.5 | 26 |
| 1 | 26 |
| 1.5 | 35 |
| 2 | 43 |
| 5 | 50 |
According to table two, we can find out, along with the increase of extension rate, wetting time is along with increase, and namely along with by polyester, polyethers, organosilicon terpolymer hydrophilic finiss dilution agent, it reduces the hydrophilic finiss effect of dacron.We can experimentally result find out simultaneously, when extension rate by do not dilute be increased to dilution 0.5 times, 1 times time, the reduction amplitude of its hydrophilic finiss effect is extremely slow, consider from the angle of economic benefit, the present invention adopts and will add the deionized water of 1 times of quality in polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent, namely to by polyester, polyethers, the 1 times of process of organosilicon terpolymer hydrophilic finiss dilution agent.
Experiment two: degradation of chitosan liquid and polyester-polyether block copolymer solution compound proportion affect for dacron hydrophilic.
Experimental technique: adopt the preparation of the method described in embodiment six to obtain degradation of chitosan liquid and polyester-polyether block copolymer solution, adopt the hydrophilic finiss method of dacron described in embodiment six simultaneously, inquire into the impact for dacron hydrophilic of the degradation of chitosan liquid of dressing liquid and polyester-polyether block copolymer solution compound proportion.
Table three: degradation of chitosan liquid and polyester-polyether block copolymer solution compound proportion are for the hygroscopic impact of dacron
| Degradation of chitosan liquid: polyester-polyether block copolymer solution | MEBO ribbon gauze (s) |
| 1:0 | 42 |
| 1:1 | 40 |
| 1:5 | 36 |
| 1:10 | 24 |
| 1:15 | 26 |
| 1:20 | 40 |
| 0:1 | 58 |
| 5:1 | 47 |
| 10:1 | 44 |
| 15:1 | 44 |
| 20:1 | 43 |
According to table three, we can find out, single use degradation of chitosan liquid and polyester-polyether block copolymer solution arrange dacron, the wetting time of fabric can be reduced, when both are public, its effect obtains larger improvement, when degradation of chitosan liquid: time polyester-polyether block copolymer solution is 1:10-15, its hydrophilic effect is optimum, simultaneously because shitosan cost is higher, adopt degradation of chitosan liquid: polyester-polyether block copolymer solution is 1:10-15, economic effect is more excellent, has higher economic benefit.
Experiment three: dressing liquid use amount affects for dacron hydrophilic.
Experimental technique: adopt the preparation of the method described in embodiment six to obtain composite dressing liquid and method for sorting, inquire into the impact of addition for dacron hydrophilic of dressing liquid.
Table four: dressing liquid consumption is for the hygroscopic impact of dacron
| Dressing liquid consumption (%) | 0 | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 |
| MEBO ribbon gauze (s) | 469 | 233 | 127 | 36 | 34 | 32 | 30 | 34 | 37 | 40 | 44 |
According to table four, we can find out, along with the increase of dressing liquid consumption, the water droplet MEBO ribbon gauze of fabric significantly shortens, when consumption reaches 3% time, its MEBO ribbon gauze is about 34s, continue the consumption increasing finishing agent, its MEBO ribbon gauze keeps in a basic balance, is about 32s, when dressing liquid consumption is more than 6%, its MEBO ribbon gauze increases on the contrary to some extent, this may be because polyster fibre is limited in one's ability with linking of finishing agent, when both link after combination reaches capacity, then increases its consumption, fabric feeling can be made on the contrary coarse, and wettability power reduces.The present invention adopts the consumption of dressing liquid to be 3-6%, has higher economic benefit.
Above content is only better embodiment of the present invention, and for those of ordinary skill in the art, according to thought of the present invention, all will change in specific embodiments and applications, this description should not be construed as limitation of the present invention.
Claims (6)
1. shitosan-polyester-polyether block copolymer hydrophilic finiss method of dacron, is characterized in that, comprise following operating procedure:
The first step: preparation degradation of chitosan liquid:
The sodium hydrate aqueous solution of 30 times of chitosan masses will be added in shitosan, add the hydrogen peroxide of 10 times of chitosan masses after stirring and dissolving, be warming up to 35 DEG C of clock reaction 2-3h;
Second step: prepare polyester-polyether block copolymer solution:
The deionized water of 1 times of quality will be added in polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent, be warming up to 70-75 DEG C and stir 15-20min;
3rd step: dressing liquid is composite:
Degradation of chitosan liquid is mixed according to weight ratio 1:10-15 with polyester-polyether block copolymer solution, stirs and obtain dressing liquid;
4th step: the hydrophilic finiss of dacron:
Adopt two leaching two roll process, bath raio is 1:20-30, and the addition of dressing liquid is 3-6%;
Process from 40 DEG C, be warming up to 120 DEG C with the speed of 3-4 DEG C/min, insulation 30-40min; 50 DEG C are cooled to, insulation 10-15min with 2-3 DEG C/min;
Preliminary drying twice, preliminary drying temperature is 90-105 DEG C, and preliminary drying time is 2-3min;
Cure twice, stoving temperature is 120-130 DEG C, and the time of curing is 1-2min;
Cold wash, dries.
2. shitosan-polyester-polyether block copolymer hydrophilic finiss the method for a kind of dacron according to claim 1, is characterized in that:
In the described first step, the mass concentration of sodium hydrate aqueous solution is 50-55%;
Described hydrogen peroxide is AR, H
2o
2active constituent content is 30%.
3. shitosan-polyester-polyether block copolymer hydrophilic finiss the method for a kind of dacron according to claim 1, it is characterized in that: described shitosan is cm-chitosan, its active principle content >=99%, viscosity≤100mpa.s, carboxylation degree >=60%, deacetylation >=85%, content of beary metal≤10ppm, solution ph is 6.0-8.0.
4. shitosan-polyester-polyether block copolymer hydrophilic finiss the method for a kind of dacron according to claim 1, it is characterized in that: described polyester, polyethers, organosilicon terpolymer hydrophilic finishing agent are purchased from Zhangjiagang Debao Chemical Co., Ltd., name of product is for washing easypro precious DP-9993, its active constituent content >=96%, its addition is in active constituent content.
5. shitosan-polyester-polyether block copolymer hydrophilic finiss the method for a kind of dacron according to claim 1, is characterized in that: adopt two leaching two roll process in described 4th step, bath raio is 1:25, and the addition of dressing liquid is 5%; Process from 40 DEG C, be warming up to 120 DEG C with the speed of 3 DEG C/min, insulation 30min; 50 DEG C are cooled to, insulation 15min with 3 DEG C/min.
6. shitosan-polyester-polyether block copolymer hydrophilic finiss the method for a kind of dacron according to claim 1, it is characterized in that: preliminary drying twice in described 4th step, preliminary drying temperature is 100 DEG C, and preliminary drying time is 3min; Stoving temperature is 120 DEG C, and the time of curing is 2min.
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