CN105532695A - Pesticide composition containing zhongshengmycin, pyraclostrobin and fluensulfone - Google Patents
Pesticide composition containing zhongshengmycin, pyraclostrobin and fluensulfone Download PDFInfo
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- CN105532695A CN105532695A CN201510969788.1A CN201510969788A CN105532695A CN 105532695 A CN105532695 A CN 105532695A CN 201510969788 A CN201510969788 A CN 201510969788A CN 105532695 A CN105532695 A CN 105532695A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
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Abstract
The invention discloses a pesticide composition containing zhongshengmycin, pyraclostrobin and fluensulfone. The effective components of the composition are zhongshengmycin, pyraclostrobin and fluensulfone. The weight percentages of zhongshengmycin in the composition is 0.5-15%. The weight percentage of pyraclostrobin in the composition is 1-20%. The weight percentage of fluensulfone in the composition is 5-35%. The balance is auxiliary components allowed and acceptable in pesticides. The pesticide composition is mainly used for controlling crop soil-borne diseases, and has the advantages of wide controlling spectrum, slow pathogen resistance development, significant synergistic effect, good environment compatibility, low controlling cost, and the like.
Description
Technical field
The present invention relates to composition pesticide and application thereof, specifically a kind of composition pesticide that is active ingredient with Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone, is mainly used in the control of crops soil-borne disease.
Background technology
Zhongshengmycin (zhongshengmycin): be a kind of novel agricultural antibiotic, has good activity to the bacterial disease of crops and some fungi venereal disease evil, has certain production-increasing function simultaneously.Its mechanism of action is by suppressing the peptide bond of pathogenetic bacteria protein to generate, finally causing bacterial death; There is strong inhibition effect to the sprouting of fungal pathogens spore, cause protoplasm cohesion in hyphal cell, change mycelium shape, play the effect of control fungal disease.
Pyraclostrobin (pyraclostrobin): belong to methoxy acrylic bactericide, the mechanism of action is mitochondrial respiratory function inhibitor, there is protection, treat, root out, permeate, strong in inhale and resistance of rainwater washing against effect.Fungicidal spectrum is wide, is widely used in preventing and treating the disease that wheat, barley, soybean, peanut, grape, vegetables, potato, banana, lemon, coffee, fruit tree, walnut, tea tree, tobacco, ornamental plants, lawn and other field crops are caused by the fungal pathogens of nearly all types such as sac fungi, basidiomycetes, imperfect fungus and oomycetes.
Fluorine alkene line sulfone (fluensulfone): belong to non-stifling novel nematocide, all have good control efficiency to the nematode of each vegetative stage.The mode of action of usual non-fumigating nematicide makes nematode lose ability to act, but after a period of time, nematode can recover, and fluorine alkene line sulfone is then thoroughly killed by nematode.The time that fluorine thiophene worm sulfone enters soil is only 12 hours, and the time that other nematocides enter soil is generally about 5 days.
Soil-borne disease refers to lives in pathogene in soil as fungi, bacterium and nematode etc., the disease that will cause from crop root or stem infringement crop when condition is suitable for.Common soil-borne disease has: the club root of Cruciferae, stalk break, soft rot, the damping off of solanaceous vegetables, the crop such as melon, damping off, epidemic disease, root rot, fusarium wilt and verticillium wilt, the bacterial wilt and root knot nematode disease etc. of tomato, cucumber and sweet (peppery) green pepper.The root of the general damage to crops of soil-borne disease and stem, plant growth early stage, seedling will soon be dead, has a strong impact on crop production once there is disease, seedling root rot or stem rot is rotten dampings off; Plant growth deuterogenesis disease, general time underproduction 20-30%, serious time underproduction 50-60%, even has no harvest.In agricultural production, the various soil-borne diseases caused by pathogene such as fungi, bacterium and nematodes respectively often mix generation, but, the selectivity that current great majority prevent and treat the medicament of soil-borne disease is comparatively strong, cannot can both reach the object of effectively control to the various soil-borne diseases caused by pathogene such as fungi, bacterium and nematodes respectively simultaneously.Therefore, the use of single medicament obviously fundamentally can not solve causing harm of various soil-borne disease in crops, is also faced with the problems such as pathogen-resistance increases the weight of, use cost is high, environmental pollution is large.
Summary of the invention
The object of the invention is for above-mentioned Problems existing, a kind of composition pesticide containing Zhongshengmycin and pyraclostrobin and fluorine alkene line sulfone is provided, for preventing and treating the soil-borne disease in crops, a drug can solve the various soil-borne diseases caused by pathogene such as fungi, bacterium and nematodes respectively, simplify farming, save medicine cost, decrease environmental pollution, improve control efficiency.
Technical solution of the present invention: a kind of composition pesticide containing Zhongshengmycin and pyraclostrobin and fluorine alkene line sulfone, active ingredient is Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone, Zhongshengmycin percentage by weight is in the composition 0.5% ~ 15%, pyraclostrobin percentage by weight is in the composition 1% ~ 20%, fluorine alkene line sulfone percentage by weight is in the composition 5% ~ 35%, and all the other are allow in agricultural chemicals to use and acceptable auxiliary element.
Described auxiliary element comprises solvent, emulsifier, wetting agent, dispersant, antifreezing agent, thickener, disintegrant, binding agent, bleeding agent, defoamer, stabilizing agent, macromolecule cyst material, pH adjusting agent, synergist, liquid-carrier and solid carrier etc., it is all composition that is conventional in pesticidal preparations or permission use, be not particularly limited, concrete composition and consumption are determined by simple test according to recipe requirements.
Composition pesticide of the present invention can be prepared into the multiple application forms being applicable to agriculturally using, and reasonable formulation has suspending agent, aqueous emulsion, microemulsion, water dispersible granules, wetting powder, microcapsule suspending agent and granule.
The production technology of the various application forms of described composition pesticide all belongs to existing known technology, does not repeat them here.
The frequency of administration of the present composition and amount of application change with crops, insect, weather condition and have small variations, can by the object using suitable dosage reach effectively control.
Compared with prior art, the invention has the advantages that:
1, Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone ternary built have significant synergistic function, the control efficiency significantly improved soil-borne disease in crops is used alone than single dose, expand control spectrum, a drug can solve the various soil-borne diseases caused by pathogene such as fungi, bacterium and nematodes respectively.
2, Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone ternary built, the service life decreasing Pesticide use amount, reduce use cost, alleviate pollution to environment, delayed the drug-fast generation of pathogene, extended agricultural chemicals.
Embodiment
In order to understand essence of the present invention better; below in conjunction with embodiment, content of the present invention is described further; but can not limitation of the present invention be considered as; the following stated is only for explaining the present invention; for not departing from amendment that the present invention's spirit and principle make, replacement or improvement, all belong to the scope of protection of present invention.
Embodiment one
Following material is all weight percentage: Zhongshengmycin 0.5%, pyraclostrobin 1%, fluorine alkene line sulfone 23.5%, the many toluene diisocyanates 20% of polymethylene, solvent naphtha S-20010%, dimethyl carbonate 10%, diphenyl phenol polyethenoxy polyethenoxy ether 5%, sodium methylene bis-naphthalene sulfonate 3%, sodium hydroxide 1%, deionized water complements to 100%.By above-mentioned active ingredient, macromolecule cyst material, solvent, make to be dissolved into homogeneous oil phase, in a shear condition, oil phase is joined in the aqueous phase solution containing emulsifier, dispersant, pH adjusting agent, surplus deionized water is supplied, bi-material reacts at oil-water interfaces, forms macromolecule cyst wall, can obtain 25% Zhongshengmycin pyraclostrobin fluorine alkene line sulfone microcapsule suspending agent.
This embodiment is for preventing and treating the soil-borne diseases such as fusarium wilt, bacterial wilt and root knot nematode disease on watermelon: 25% Zhongshengmycin pyraclostrobin fluorine alkene line sulfone microcapsule suspending agent is by 2000ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to fusarium wilt, bacterial wilt and root knot nematode disease is respectively 97.31%, 95.28% and 94.69%; 50ga.i./ha thin up root irrigation pressed by 5% Zhongshengmycin wetting powder, and after medicine, the preventive effect of 30d to fusarium wilt, bacterial wilt and root knot nematode disease is respectively 41.72%, 73.89% and 14.51%; 100ga.i./ha thin up root irrigation pressed by 250 grams per liter pyraclostrobin missible oil, and after medicine, the preventive effect of 30d to fusarium wilt, bacterial wilt and root knot nematode disease is respectively 76.63%, 35.48% and 25.51%; 2500ga.i./ha thin up root irrigation pressed by 480g/l fluorine alkene line sulfone missible oil, and after medicine, the preventive effect of 30d to fusarium wilt, bacterial wilt and root knot nematode disease is respectively 23.29%, 26.98% and 76.13%.Visible, obvious synergy after Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone ternary built, lasting period is long, expand control spectrum, the preventive effect of the soil-borne diseases such as the fusarium wilt on watermelon, bacterial wilt and root knot nematode disease is used alone significantly better than single dose, meanwhile, in process of the test, do not find that medicament produces poisoning to watermelon.
Embodiment two
Following material is all weight percentage: Zhongshengmycin 0.5%, pyraclostrobin 1%, fluorine alkene line sulfone 35%, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate 5%, acrylate homopolymer sodium salt 10%, triphenoethyl benzene phenol polyoxyethylene polyoxypropylene block polymer 5%, polyethylene glycol 2%, xanthans 1%, polyethers emulsion 0.1%, azone 1%, Sodium Benzoate 0.1%, deionized water supplies 100%.By above-mentioned active ingredient, wetting agent, dispersant, antifreezing agent, thickener, defoamer, synergist and preservative sand milling in high speed shear dispersion, sand mill, the high dispersive formed in water-medium, stable suspension system, can obtain 36.5% Zhongshengmycin pyraclostrobin fluorine alkene line sulfone suspending agent.
This embodiment is for preventing and treating the soil-borne diseases such as damping off, bacterial wilt and root knot nematode disease on tomato: 36.5% Zhongshengmycin pyraclostrobin fluorine alkene line sulfone suspending agent is by 2000ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to damping off, bacterial wilt and root knot nematode disease is respectively 94.17%, 93.82% and 96.91%; 50ga.i./ha thin up root irrigation pressed by 5% Zhongshengmycin wetting powder, and after medicine, the preventive effect of 30d to damping off, bacterial wilt and root knot nematode disease is respectively 47.73%, 72.58% and 16.93%; 100ga.i./ha thin up root irrigation pressed by 250 grams per liter pyraclostrobin missible oil, and after medicine, the preventive effect of 30d to damping off, bacterial wilt and root knot nematode disease is respectively 78.43%, 38.51% and 22.36%; 2500ga.i./ha thin up root irrigation pressed by 480g/l fluorine alkene line sulfone missible oil, and after medicine, the preventive effect of 30d to damping off, bacterial wilt and root knot nematode disease is respectively 27.54%, 21.32% and 78.06%.Visible, obvious synergy after Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone ternary built, lasting period is long, expand control spectrum, the preventive effect of the soil-borne diseases such as the damping off on tomato, bacterial wilt and root knot nematode disease is used alone significantly better than single dose, meanwhile, in process of the test, do not find that medicament produces poisoning to tomato.
Embodiment three
Following material is all weight percentage: Zhongshengmycin 1%, pyraclostrobin 1.5%, fluorine alkene line sulfone 42.5%, trimethylbenzene 10%, fatty acid methyl ester 10%, ethylene oxide-propylene oxide block copolymer 10%, polycarboxylate 5%, the formaldehyde condensation products 5% of methyl naphthalene sulfonic acid sodium, epoxidized soybean oil 1%, glycerine 1%, deionized water supplies 100%.Above-mentioned active ingredient, solvent, emulsifier, dispersant and stabilizing agent are mixed to form oil phase, antifreezing agent dissolves and forms aqueous phase in water, slowly oil phase is added in aqueous phase under clipper effect, and continue to shear about 30 minutes, obtained 45% Zhongshengmycin pyraclostrobin fluorine alkene line sulfone aqueous emulsion.
This embodiment is for preventing and treating the soil-borne diseases such as club root, soft rot and root knot nematode disease on Chinese cabbage: 45% Zhongshengmycin pyraclostrobin fluorine alkene line sulfone aqueous emulsion is by 2000ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to club root, soft rot and root knot nematode disease is respectively 95.87%, 96.24% and 92.33%; 50ga.i./ha thin up root irrigation pressed by 5% Zhongshengmycin wetting powder, and after medicine, the preventive effect of 30d to club root, soft rot and root knot nematode disease is respectively 39.45%, 73.78% and 16.13%; 100ga.i./ha thin up root irrigation pressed by 250 grams per liter pyraclostrobin missible oil, and after medicine, the preventive effect of 30d to club root, soft rot and root knot nematode disease is respectively 77.15%, 36.24% and 23.59%; 2500ga.i./ha thin up root irrigation pressed by 480g/l fluorine alkene line sulfone missible oil, and after medicine, the preventive effect of 30d to club root, soft rot and root knot nematode disease is respectively 24.38%, 28.89% and 74.19%.Visible, obvious synergy after Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone ternary built, lasting period is long, expand control spectrum, the preventive effect of the soil-borne diseases such as the club root on Chinese cabbage, soft rot and root knot nematode disease is used alone significantly better than single dose, meanwhile, in process of the test, do not find that medicament produces poisoning to Chinese cabbage.
Embodiment four
Following material is all weight percentage: Zhongshengmycin 0.7%, pyraclostrobin 1.3%, fluorine alkene line sulfone 38%, trimethylbenzene 10%, fatty acid methyl ester 10%, triphen ethyl phenol polyoxyethylene groups ether phosphate 10%, pyrogallic acid 2%, organosilicon 1%, azone 2%, deionized water supplies 100%.Active ingredient solvent is dissolved completely, and then add emulsifier, stabilizing agent, bleeding agent, synergist mix, finally add deionized water, after fully stirring, 40% Zhongshengmycin pyraclostrobin fluorine alkene line sulfone microemulsion can be obtained.
This embodiment is for preventing and treating the soil-borne diseases such as root rot, bacterial wilt and root knot nematode disease on capsicum: 40% Zhongshengmycin pyraclostrobin fluorine alkene line sulfone microemulsion is by 2000ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to root rot, bacterial wilt and root knot nematode disease is respectively 98.12%, 94.67% and 93.43%; 50ga.i./ha thin up root irrigation pressed by 5% Zhongshengmycin wetting powder, and after medicine, the preventive effect of 30d to root rot, bacterial wilt and root knot nematode disease is respectively 36.93%, 72.18% and 19.26%; 100ga.i./ha thin up root irrigation pressed by 250 grams per liter pyraclostrobin missible oil, and after medicine, the preventive effect of 30d to root rot, bacterial wilt and root knot nematode disease is respectively 79.57%, 31.29% and 23.59%; 2500ga.i./ha thin up root irrigation pressed by 480g/l fluorine alkene line sulfone missible oil, and after medicine, the preventive effect of 30d to root rot, bacterial wilt and root knot nematode disease is respectively 28.63%, 21.14% and 71.35%.Visible, obvious synergy after Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone ternary built, lasting period is long, expand control spectrum, the preventive effect of the soil-borne diseases such as the root rot on capsicum, bacterial wilt and root knot nematode disease is used alone significantly better than single dose, meanwhile, in process of the test, do not find that medicament produces poisoning to capsicum.
Embodiment five
Following material is all weight percentage: Zhongshengmycin 1%, pyraclostrobin 2.5%, fluorine alkene line sulfone 51.5%, sldium lauryl sulfate 10%, diisobutyl sodium naphthalene sulfonate 10%, PAA and propionamide copolymer 5%, sodium phosphate 5%, white carbon 5%, attapulgite supplies 100%.Above-mentioned active ingredient, wetting agent, dispersant, disintegrant and filler are mixed, pulverize with micro jet, through mediating, then adding in fluidized-bed granulation dryer and carrying out granulation, drying, screening, 55% Zhongshengmycin pyraclostrobin fluorine alkene line sulfone water dispersible granules can be obtained.
This embodiment is for preventing and treating the soil-borne diseases such as base rot disease, bacterial wilt of ginger and root knot nematode disease on ginger: 55% Zhongshengmycin pyraclostrobin fluorine alkene line sulfone water dispersible granules is by 2000ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to base rot disease, bacterial wilt of ginger and root knot nematode disease is respectively 91.89%, 96.73% and 98.07%; 50ga.i./ha thin up root irrigation pressed by 5% Zhongshengmycin wetting powder, and after medicine, the preventive effect of 30d to base rot disease, bacterial wilt of ginger and root knot nematode disease is respectively 23.58%, 76.47% and 17.15%; 100ga.i./ha thin up root irrigation pressed by 250 grams per liter pyraclostrobin missible oil, and after medicine, the preventive effect of 30d to base rot disease, bacterial wilt of ginger and root knot nematode disease is respectively 73.32%, 35.68% and 27.12%; 2500ga.i./ha thin up root irrigation pressed by 480g/l fluorine alkene line sulfone missible oil, and after medicine, the preventive effect of 30d to base rot disease, bacterial wilt of ginger and root knot nematode disease is respectively 26.44%, 23.48% and 78.59%.Visible, obvious synergy after Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone ternary built, lasting period is long, expand control spectrum, the preventive effect of the soil-borne diseases such as the base rot disease on ginger, bacterial wilt of ginger and root knot nematode disease is used alone significantly better than single dose, meanwhile, in process of the test, do not find that medicament produces poisoning to ginger.
Embodiment six
Following material is all weight percentage: Zhongshengmycin 1%, pyraclostrobin 1%, fluorine alkene line sulfone 60%, butyl naphthalene sulfonate 5%, alkyl phenol resin polyoxyethylene ether sulfate 5%, dispersing agent MF 5%, white carbon 5%, kaolin supplies 100%.By above-mentioned, active ingredient, wetting agent, dispersant and filler are mixed, again through air-flow crushing after mechanical crushing, mix, 62% Zhongshengmycin pyraclostrobin fluorine alkene line sulfone wetting powder can be obtained.
This embodiment is for preventing and treating the soil-borne diseases such as root black rot, bacterial wilt and root knot nematode disease on tobacco: 62% Zhongshengmycin pyraclostrobin fluorine alkene line sulfone wetting powder is by 2000ga.i./ha thin up root irrigation, and after medicine, the preventive effect of 30d to root black rot, bacterial wilt and root knot nematode disease is respectively 93.81%, 95.26% and 97.34%; 50ga.i./ha thin up root irrigation pressed by 5% Zhongshengmycin wetting powder, and after medicine, the preventive effect of 30d to root black rot, bacterial wilt and root knot nematode disease is respectively 21.18%, 73.42% and 18.71%; 100ga.i./ha thin up root irrigation pressed by 250 grams per liter pyraclostrobin missible oil, and after medicine, the preventive effect of 30d to root black rot, bacterial wilt and root knot nematode disease is respectively 76.98%, 31.47% and 22.53%; 2500ga.i./ha thin up root irrigation pressed by 480g/l fluorine alkene line sulfone missible oil, and after medicine, the preventive effect of 30d to root black rot, bacterial wilt and root knot nematode disease is respectively 26.32%, 22.45% and 75.68%.Visible, obvious synergy after Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone ternary built, lasting period is long, expand control spectrum, the preventive effect of the soil-borne diseases such as root black rot, bacterial wilt and the root knot nematode disease on tobacco is used alone significantly better than single dose, meanwhile, in process of the test, do not find that medicament produces poisoning to tobacco.
Embodiment seven
Following material is all weight percentage: Zhongshengmycin 0.15%, pyraclostrobin 0.3%, fluorine alkene line sulfone 9.55%, neopelex 5%, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 5%, ethyl cellulose 5%, triphenyl phosphite 3%; kaolin supplies 100%; above-mentioned active ingredient and auxiliary agent are mediated through mixing and water adding; pinch-out granulator is used to pinch out and be shaped; afterwards by particle fluid-bed drying, screening, 10% Zhongshengmycin pyraclostrobin fluorine alkene line sulfone granule can be obtained.
This embodiment is for preventing and treating the soil-borne diseases such as verticillium wilt, bacterial wilt and root knot nematode disease on eggplant: 10% Zhongshengmycin pyraclostrobin fluorine alkene line sulfone granule spreads fertilizer over the fields process by 2000ga.i./ha, and after medicine, the preventive effect of 30d to verticillium wilt, bacterial wilt and root knot nematode disease is respectively 96.17%, 94.28% and 92.31%; 50ga.i./ha thin up root irrigation pressed by 5% Zhongshengmycin wetting powder, and after medicine, the preventive effect of 30d to verticillium wilt, bacterial wilt and root knot nematode disease is respectively 23.76%, 74.47% and 16.21%; 100ga.i./ha thin up root irrigation pressed by 250 grams per liter pyraclostrobin missible oil, and after medicine, the preventive effect of 30d to verticillium wilt, bacterial wilt and root knot nematode disease is respectively 74.59%, 26.35% and 23.42%; 2500ga.i./ha thin up root irrigation pressed by 480g/l fluorine alkene line sulfone missible oil, and after medicine, the preventive effect of 30d to verticillium wilt, bacterial wilt and root knot nematode disease is respectively 19.86%, 21.44% and 73.67%.Visible, obvious synergy after Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone ternary built, lasting period is long, expand control spectrum, the preventive effect of the soil-borne diseases such as the verticillium wilt on eggplant, bacterial wilt and root knot nematode disease is used alone significantly better than single dose, meanwhile, in process of the test, do not find that medicament produces poisoning to eggplant.
Embodiment eight
In order to understand the synergy type that Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone are active component ternary built further, the present inventor has carried out Toxicity Determination test to Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone ternary built.
1, Zhongshengmycin, pyraclostrobin and the composite Toxicity Determination to watermelon blight of fluorine alkene line sulfone
Carry out statistical analysis with DPS statistical analysis software, calculate the EC of each medicament
50, adopt Wadley method, calculate the interactional synergism value of mixture (SR): when SR≤0.5, be antagonism; 0.5 < SR < 1.5 is summation action; SR>=1.5 are synergistic effect.
The composite Toxicity Determination result to watermelon blight of table 1, Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone
| Medicament | EC 50(ob) | EC 50(th) | SR |
| Zhongshengmycin (A) | 26.03 | - | - |
| Pyraclostrobin (B) | 1.51 | - | - |
| Fluorine alkene line sulfone (C) | 69.37 | - | - |
| A:B:C(0.5:1:5) | 2.89 | 8.63 | 2.98 |
| A:B:C(0.5:1:35) | 8.46 | 30.78 | 3.64 |
| A:B:C(0.5:20:5) | 1.01 | 1.91 | 1.89 |
| A:B:C(0.5:20:35) | 2.32 | 4.03 | 1.74 |
| A:B:C(15:1:5) | 7.38 | 16.02 | 2.17 |
| A:B:C(15:1:35) | 9.51 | 29.26 | 3.08 |
| A:B:C(15:20:5) | 1.39 | 2.88 | 2.07 |
| A:B:C(15:20:35) | 2.17 | 4.89 | 2.25 |
As can be seen from Table 1, when Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone are composite in a certain proportion of scope, synergism value (SR) is all greater than 1.5, shows synergistic function to watermelon blight; Especially composite with 0.5:1:35 (by quality), synergistic function is the most remarkable, and synergism value (SR) is 3.64.Visible, Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone is composite has reasonability and feasibility.
2, Zhongshengmycin, pyraclostrobin and the composite Toxicity Determination to bacterial wilt of tomato of fluorine alkene line sulfone
Carry out statistical analysis with DPS statistical analysis software, calculate the EC of each medicament
50, adopt Wadley method, calculate the interactional synergism value of mixture (SR): when SR≤0.5, be antagonism; 0.5 < SR < 1.5 is summation action; SR>=1.5 are synergistic effect.
The composite Toxicity Determination result to bacterial wilt of tomato of table 2, Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone
As can be seen from Table 2, when Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone are composite in a certain proportion of scope, synergism value (SR) is all greater than 1.5, shows synergistic function to bacterial wilt of tomato; Especially composite with 0.5:1:35 (by quality), synergistic function is the most remarkable, and synergism value (SR) is 4.24.Visible, Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone is composite has reasonability and feasibility.
3, Zhongshengmycin, pyraclostrobin and the composite Toxicity Determination to tobacco root-knot of fluorine alkene line sulfone
Carry out statistical analysis with DPS statistical analysis software, calculate the EC of each medicament
50, adopt Wadley method, calculate the interactional synergism value of mixture (SR): when SR≤0.5, be antagonism; 0.5 < SR < 1.5 is summation action; SR>=1.5 are synergistic effect.
The composite Toxicity Determination result to tobacco root-knot of table 3, Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone
| Medicament | EC 50(ob) | EC 50(th) | SR |
| Zhongshengmycin (A) | 86.27 | - | - |
| Pyraclostrobin (B) | 62.39 | - | - |
| Fluorine alkene line sulfone (C) | 4.34 | - | - |
| A:B:C(0.5:1:5) | 3.13 | 5.54 | 1.77 |
| A:B:C(0.5:1:35) | 1.65 | 4.51 | 2.74 |
| A:B:C(0.5:20:5) | 8.31 | 17.25 | 2.08 |
| A:B:C(0.5:20:35) | 3.92 | 6.61 | 1.69 |
| A:B:C(15:1:5) | 8.17 | 15.65 | 1.92 |
| A:B:C(15:1:35) | 2.56 | 6.18 | 2.41 |
| A:B:C(15:20:5) | 10.64 | 24.29 | 2.28 |
| A:B:C(15:20:35) | 3.82 | 8.18 | 2.14 |
As can be seen from Table 3, when Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone are composite in a certain proportion of scope, synergism value (SR) is all greater than 1.5, shows synergistic function to tobacco root-knot; Especially composite with 0.5:1:35 (by quality), synergistic function is the most remarkable, and synergism value (SR) is 2.74.Visible, Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone is composite has reasonability and feasibility.
In sum, a kind of composition pesticide containing Zhongshengmycin and pyraclostrobin and fluorine alkene line sulfone provided by the invention, obvious synergy, a drug can solve the various soil-borne diseases caused by pathogene such as fungi, bacterium and nematodes respectively.Compared with existing single dose, the soil-borne disease successful in control crops improves, and the lasting period is long, to crop safety, is worth applying in agricultural production.
Claims (3)
1. one kind contains the composition pesticide of Zhongshengmycin and pyraclostrobin and fluorine alkene line sulfone, it is characterized in that: active ingredient is Zhongshengmycin, pyraclostrobin and fluorine alkene line sulfone, Zhongshengmycin percentage by weight is in the composition 0.5% ~ 15%, pyraclostrobin percentage by weight is in the composition 1% ~ 20%, fluorine alkene line sulfone percentage by weight is in the composition 5% ~ 35%, and all the other are allow in agricultural chemicals to use and acceptable auxiliary element.
2. a kind of composition pesticide containing Zhongshengmycin and pyraclostrobin and fluorine alkene line sulfone according to claim 1, is characterized in that: the formulation of described composition pesticide can be the one in suspending agent, aqueous emulsion, microemulsion, water dispersible granules, wetting powder, microcapsule suspending agent and granule.
3. a kind of application of composition pesticide in control crops soil-borne disease containing Zhongshengmycin and pyraclostrobin and fluorine alkene line sulfone according to claim 1.
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| CN114916540A (en) * | 2022-05-17 | 2022-08-19 | 浙江工业大学 | Preparation method and application of soil-borne nematode disease prevention polymer hydrogel |
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| CN101843248A (en) * | 2003-05-02 | 2010-09-29 | 马克特辛姆化学工厂有限公司 | Active substance combinations that have nematicidal, insecticidal, and fungicidal properties and are based on trifluorobutenyl compounds |
| CN102302026A (en) * | 2011-03-12 | 2012-01-04 | 陕西汤普森生物科技有限公司 | Bactericidal composition containing pyraclostrobin and antibiotic compounds |
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| CN101843248A (en) * | 2003-05-02 | 2010-09-29 | 马克特辛姆化学工厂有限公司 | Active substance combinations that have nematicidal, insecticidal, and fungicidal properties and are based on trifluorobutenyl compounds |
| CN102302026A (en) * | 2011-03-12 | 2012-01-04 | 陕西汤普森生物科技有限公司 | Bactericidal composition containing pyraclostrobin and antibiotic compounds |
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| CN114916540A (en) * | 2022-05-17 | 2022-08-19 | 浙江工业大学 | Preparation method and application of soil-borne nematode disease prevention polymer hydrogel |
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