CN105525314A - Novel nickel chloride/iron chloride system electroplating solution - Google Patents
Novel nickel chloride/iron chloride system electroplating solution Download PDFInfo
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- CN105525314A CN105525314A CN201511009510.6A CN201511009510A CN105525314A CN 105525314 A CN105525314 A CN 105525314A CN 201511009510 A CN201511009510 A CN 201511009510A CN 105525314 A CN105525314 A CN 105525314A
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- chloride
- iron
- novel
- plating solution
- nickelous
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/562—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of iron or nickel or cobalt
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
The invention relates to a novel nickel chloride/iron chloride system electroplating solution. The novel nickel chloride/iron chloride system electroplating solution is prepared from the following components: 630-640 parts of octyl-3-methyl glyoxaline choloride, 310-319 parts of nickel chloride, 25-29 parts of iron chloride, 4-6 parts of ethanediol,1-3 parts of dextrin, and 15-20 parts of sodium chloride. The novel nickel chloride/iron chloride system electroplating solution disclosed by the invention has a wide electrochemical window, and can obtain metal and alloys at low temperature, wherein the metal and the alloys can be obtained through electrodeposition in high temperature fused salt, but the novel nickel chloride/iron chloride system electroplating solution does not have strong corrosivity as the high temperature fused salt; besides, metal of which most is obtained in water solutions can be obtained through electrodeposition, and side effects do not exist; therefore, the obtained metal is good in quality. The novel nickel chloride/iron chloride system electroplating solution with the characteristics, favorable conductivity, and low steam pressure becomes a brand new electroplating solution in the research of the electrodeposition.
Description
Technical field
The present invention relates to a kind of electroplate liquid, a kind of novel nickelous chloride/iron(ic) chloride system plating solution.
Background technology
The magnetic alloy plated research and development such as ferronickel always come into one's own, and existing a large amount of research report and application report.It is directed with exploitation and vertically remember grade and be developed to quinary alloy coating that the nickel cobalt coating of magnetic comprises soft magnetism.The feeding scheme utilizing different additives, adopt the superposition of pulse or current of comuntation and alternating current-direct current etc. different, effectively can regulate structure and the orientation of coating.Therefore magnetics is prepared with electro-plating method not difficult, the characteristic that the mechanism of its Abnormal Codeposition, various additive and electrode such as, adsorb and impact, current waveform and parameter comprise the effect of pulse and commutation and pulsation, and the preparation of extremely very thin ferronickel film etc.
For achieving the above object, the technical solution used in the present invention is: a kind of formula of novel nickelous chloride/iron(ic) chloride system plating solution:
Chlorination 1-octyl group-3-Methylimidazole: 630 ~ 640gkg
-1
Nickelous chloride: 310 ~ 319gkg
-1
Iron(ic) chloride: 25 ~ 29gkg
-1
Ethylene glycol: 4 ~ 6gkg
-1
Dextrin: 1 ~ 3gkg
-1
Sodium-chlor: 15 ~ 20gkg
-1.
Ferronickel itself has been good magneticsubstance, is first want control texture, because the behavior of the physical propertys such as magnetic, magnetic domain etc. are in close relations with material structure.The feeding scheme utilizing different additives, adopt the superposition of pulse or current of comuntation and alternating current-direct current etc. different, effectively can regulate structure and the orientation of coating.Therefore magnetics is prepared with electro-plating method not difficult, the characteristic that the mechanism of its Abnormal Codeposition, various additive and electrode such as, adsorb and impact, current waveform and parameter comprise the effect of pulse and commutation and pulsation, and the preparation of extremely very thin ferronickel film etc.
The present invention has wider electrochemical window, read lower can to obtain in high-temperature molten salt compared with low temperature could the metal that obtains of galvanic deposit and alloy, but the severe corrosive not having high-temperature molten salt such; Meanwhile, galvanic deposit can obtain the metal that great majority obtain in aqueous, and not side reaction, the metal quality thus obtained is better.Above-mentioned characteristic and good electric conductivity thereof, low vapour pressure make it to become electroplate liquid brand-new in galvanic deposit research.
Embodiment
Use raw material: chlorination 1-octyl group-3-Methylimidazole, nickelous chloride, iron(ic) chloride, ethylene glycol, dextrin, sodium-chlor.
Embodiment 1:
Chlorination 1-octyl group-3-Methylimidazole: 630gkg
-1
Nickelous chloride: 317gkg
-1
Iron(ic) chloride: 28gkg
-1
Ethylene glycol: 6gkg
-1
Dextrin: 3gkg
-1
Sodium-chlor: 16gkg
-1
Get said components, be mixed into a kind of novel nickelous chloride/iron(ic) chloride system plating solution of 1000 grams.
Embodiment 2:
Chlorination 1-octyl group-3-Methylimidazole: 632gkg
-1
Nickelous chloride: 318gkg
-1
Iron(ic) chloride: 29gkg
-1
Ethylene glycol: 5gkg
-1
Dextrin: 1gkg
-1
Sodium-chlor: 15gkg
-1
Get said components, be mixed into a kind of novel nickelous chloride/iron(ic) chloride system plating solution of 1000 grams.
Embodiment 3:
Chlorination 1-octyl group-3-Methylimidazole: 632gkg
-1
Nickelous chloride: 315gkg
-1
Iron(ic) chloride: 25gkg
-1
Ethylene glycol: 6gkg
-1
Dextrin: 2gkg
-1
Sodium-chlor: 20gkg
-1
Get said components, be mixed into a kind of novel nickelous chloride/iron(ic) chloride system plating solution of 1000 grams.
Embodiment 4:
Chlorination 1-octyl group-3-Methylimidazole: 634gkg
-1
Nickelous chloride: 313gkg
-1
Iron(ic) chloride: 28gkg
-1
Ethylene glycol: 5gkg
-1
Dextrin: 3gkg
-1
Sodium-chlor: 17gkg
-1
Get said components, be mixed into a kind of novel nickelous chloride/iron(ic) chloride system plating solution of 1000 grams.
Embodiment 5:
Chlorination 1-octyl group-3-Methylimidazole: 635gkg
-1
Nickelous chloride: 311gkg
-1
Iron(ic) chloride: 26gkg
-1
Ethylene glycol: 6gkg
-1
Dextrin: 2gkg
-1
Sodium-chlor: 20gkg
-1
Get said components, be mixed into a kind of novel nickelous chloride/iron(ic) chloride system plating solution of 1000 grams.
Embodiment 6:
Chlorination 1-octyl group-3-Methylimidazole: 636gkg
-1
Nickelous chloride: 313gkg
-1
Iron(ic) chloride: 27gkg
-1
Ethylene glycol: 4gkg
-1
Dextrin: 1gkg
-1
Sodium-chlor: 19gkg
-1
Get said components, be mixed into a kind of novel nickelous chloride/iron(ic) chloride system plating solution of 1000 grams.
Embodiment 7:
Chlorination 1-octyl group-3-Methylimidazole: 637gkg
-1
Nickelous chloride: 312gkg
-1
Iron(ic) chloride: 28gkg
-1
Ethylene glycol: 5gkg
-1
Dextrin: 3gkg
-1
Sodium-chlor: 15gkg
-1
Get said components, be mixed into a kind of novel nickelous chloride/iron(ic) chloride system plating solution of 1000 grams.
Embodiment 8:
Chlorination 1-octyl group-3-Methylimidazole: 638gkg
-1
Nickelous chloride: 314gkg
-1
Iron(ic) chloride: 26gkg
-1
Ethylene glycol: 4gkg
-1
Dextrin: 2gkg
-1
Sodium-chlor: 16gkg
-1
Get said components, be mixed into a kind of novel nickelous chloride/iron(ic) chloride system plating solution of 1000 grams.
Embodiment 9:
Chlorination 1-octyl group-3-Methylimidazole: 640gkg
-1
Nickelous chloride: 310gkg
-1
Iron(ic) chloride: 25gkg
-1
Ethylene glycol: 5gkg
-1
Dextrin: 1gkg
-1
Sodium-chlor: 19gkg
-1
Get said components, be mixed into a kind of novel nickelous chloride/iron(ic) chloride system plating solution of 1000 grams.
When electroplating with the present invention, require pH value of solution: 4.0 ~ 4.4, solution temperature (DEG C): 100 ~ 109, current density (A/dm
2): 3.7 ~ 4.6.
Claims (10)
1. novel nickelous chloride/iron(ic) chloride system plating solution, is characterized in that: a kind of formula of novel nickelous chloride/iron(ic) chloride system plating solution is made up of following:
Chlorination 1-octyl group-3-Methylimidazole: 630 ~ 640gkg
-1
Nickelous chloride: 310 ~ 319gkg
-1
Iron(ic) chloride: 25 ~ 29gkg
-1
Ethylene glycol: 4 ~ 6gkg
-1
Dextrin: 1 ~ 3gkg
-1
Sodium-chlor: 15 ~ 20gkg
-1.
2. a kind of novel nickelous chloride/iron(ic) chloride system plating solution as claimed in claim 1, is characterized in that: a kind of formula of novel nickelous chloride/iron(ic) chloride system plating solution is made up of following:
Chlorination 1-octyl group-3-Methylimidazole: 630gkg
-1
Nickelous chloride: 317gkg
-1
Iron(ic) chloride: 28gkg
-1
Ethylene glycol: 6gkg
-1
Dextrin: 3gkg
-1
Sodium-chlor: 16gkg
-1.
3. a kind of novel nickelous chloride/iron(ic) chloride system plating solution as claimed in claim 1, is characterized in that: a kind of formula of novel nickelous chloride/iron(ic) chloride system plating solution is made up of following:
Chlorination 1-octyl group-3-Methylimidazole: 632gkg
-1
Nickelous chloride: 318gkg
-1
Iron(ic) chloride: 29gkg
-1
Ethylene glycol: 5gkg
-1
Dextrin: 1gkg
-1
Sodium-chlor: 15gkg
-1.
4. a kind of novel nickelous chloride/iron(ic) chloride system plating solution as claimed in claim 1, is characterized in that: a kind of formula of novel nickelous chloride/iron(ic) chloride system plating solution is made up of following:
Chlorination 1-octyl group-3-Methylimidazole: 632gkg
-1
Nickelous chloride: 315gkg
-1
Iron(ic) chloride: 25gkg
-1
Ethylene glycol: 6gkg
-1
Dextrin: 2gkg
-1
Sodium-chlor: 20gkg
-1.
5. a kind of novel nickelous chloride/iron(ic) chloride system plating solution as claimed in claim 1, is characterized in that: a kind of formula of novel nickelous chloride/iron(ic) chloride system plating solution is made up of following:
Chlorination 1-octyl group-3-Methylimidazole: 634gkg
-1
Nickelous chloride: 313gkg
-1
Iron(ic) chloride: 28gkg
-1
Ethylene glycol: 5gkg
-1
Dextrin: 3gkg
-1
Sodium-chlor: 17gkg
-1.
6. a kind of novel nickelous chloride/iron(ic) chloride system plating solution as claimed in claim 1, is characterized in that: a kind of formula of novel nickelous chloride/iron(ic) chloride system plating solution is made up of following:
Chlorination 1-octyl group-3-Methylimidazole: 635gkg
-1
Nickelous chloride: 311gkg
-1
Iron(ic) chloride: 26gkg
-1
Ethylene glycol: 6gkg
-1
Dextrin: 2gkg
-1
Sodium-chlor: 20gkg
-1.
7. a kind of novel nickelous chloride/iron(ic) chloride system plating solution as claimed in claim 1, is characterized in that: a kind of formula of novel nickelous chloride/iron(ic) chloride system plating solution is made up of following:
Chlorination 1-octyl group-3-Methylimidazole: 636gkg
-1
Nickelous chloride: 313gkg
-1
Iron(ic) chloride: 27gkg
-1
Ethylene glycol: 4gkg
-1
Dextrin: 1gkg
-1
Sodium-chlor: 19gkg
-1.
8. a kind of novel nickelous chloride/iron(ic) chloride system plating solution as claimed in claim 1, is characterized in that: a kind of formula of novel nickelous chloride/iron(ic) chloride system plating solution is made up of following:
Chlorination 1-octyl group-3-Methylimidazole: 637gkg
-1
Nickelous chloride: 312gkg
-1
Iron(ic) chloride: 28gkg
-1
Ethylene glycol: 5gkg
-1
Dextrin: 3gkg
-1
Sodium-chlor: 15gkg
-1.
9. a kind of novel nickelous chloride/iron(ic) chloride system plating solution as claimed in claim 1, is characterized in that: a kind of formula of novel nickelous chloride/iron(ic) chloride system plating solution is made up of following:
Chlorination 1-octyl group-3-Methylimidazole: 638gkg
-1
Nickelous chloride: 314gkg
-1
Iron(ic) chloride: 26gkg
-1
Ethylene glycol: 4gkg
-1
Dextrin: 2gkg
-1
Sodium-chlor: 16gkg
-1.
10. a kind of novel nickelous chloride/iron(ic) chloride system plating solution as claimed in claim 1, is characterized in that: a kind of formula of novel nickelous chloride/iron(ic) chloride system plating solution is made up of following:
Chlorination 1-octyl group-3-Methylimidazole: 640gkg
-1
Nickelous chloride: 310gkg
-1
Iron(ic) chloride: 25gkg
-1
Ethylene glycol: 5gkg
-1
Dextrin: 1gkg
-1
Sodium-chlor: 19gkg
-1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511009510.6A CN105525314A (en) | 2015-12-29 | 2015-12-29 | Novel nickel chloride/iron chloride system electroplating solution |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511009510.6A CN105525314A (en) | 2015-12-29 | 2015-12-29 | Novel nickel chloride/iron chloride system electroplating solution |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105525314A true CN105525314A (en) | 2016-04-27 |
Family
ID=55767829
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511009510.6A Pending CN105525314A (en) | 2015-12-29 | 2015-12-29 | Novel nickel chloride/iron chloride system electroplating solution |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105525314A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110670096A (en) * | 2019-11-17 | 2020-01-10 | 沈阳师范大学 | Novel practical electroplating solution for plating nickel iron |
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| JPH05129497A (en) * | 1991-10-30 | 1993-05-25 | Nisshin Steel Co Ltd | Al-plated lead frame |
| CN101270490A (en) * | 2008-04-11 | 2008-09-24 | 沈阳师范大学 | Dissipated metal indium chloride/chloridization 1-methyl-3-butyl imidazole system plating solution |
| CN101876082A (en) * | 2010-05-13 | 2010-11-03 | 沈阳师范大学 | Ionic liquid gallium chloride/1-methyl-3-ethylimidazole chloride system electroplating solution |
| CN101988210A (en) * | 2010-12-03 | 2011-03-23 | 沈阳师范大学 | Ionic liquid indium chloride/n-butyl pyridine chloride system electroplating solution |
| CN101994139A (en) * | 2010-12-08 | 2011-03-30 | 沈阳师范大学 | Scattered metal gallium chloride/1-methyl-3-butyliminazole chloride system electroplating solution |
| CN102061492A (en) * | 2010-12-09 | 2011-05-18 | 沈阳师范大学 | Electroplate liquid based on room temperature ion liquid indium chloride/fluoboric acid 1-methyl-3-butylimidazole system |
| CN104313655A (en) * | 2014-10-16 | 2015-01-28 | 昆明理工大学 | Method for electroplating Ni-Fe alloy with ionic liquid |
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-
2015
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Patent Citations (9)
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|---|---|---|---|---|
| JPH05129497A (en) * | 1991-10-30 | 1993-05-25 | Nisshin Steel Co Ltd | Al-plated lead frame |
| CN101270490A (en) * | 2008-04-11 | 2008-09-24 | 沈阳师范大学 | Dissipated metal indium chloride/chloridization 1-methyl-3-butyl imidazole system plating solution |
| CN101876082A (en) * | 2010-05-13 | 2010-11-03 | 沈阳师范大学 | Ionic liquid gallium chloride/1-methyl-3-ethylimidazole chloride system electroplating solution |
| CN101988210A (en) * | 2010-12-03 | 2011-03-23 | 沈阳师范大学 | Ionic liquid indium chloride/n-butyl pyridine chloride system electroplating solution |
| CN101994139A (en) * | 2010-12-08 | 2011-03-30 | 沈阳师范大学 | Scattered metal gallium chloride/1-methyl-3-butyliminazole chloride system electroplating solution |
| CN102061492A (en) * | 2010-12-09 | 2011-05-18 | 沈阳师范大学 | Electroplate liquid based on room temperature ion liquid indium chloride/fluoboric acid 1-methyl-3-butylimidazole system |
| CN104313655A (en) * | 2014-10-16 | 2015-01-28 | 昆明理工大学 | Method for electroplating Ni-Fe alloy with ionic liquid |
| CN105018975A (en) * | 2015-07-23 | 2015-11-04 | 珠海元盛电子科技股份有限公司 | Method for electroplating printed circuit with nickel through ionic liquid |
| CN105112962A (en) * | 2015-09-29 | 2015-12-02 | 哈尔滨工业大学 | Method of preparing nickel gallium alloy by ionic liquid electrodeposition |
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| Title |
|---|
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110670096A (en) * | 2019-11-17 | 2020-01-10 | 沈阳师范大学 | Novel practical electroplating solution for plating nickel iron |
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Application publication date: 20160427 |