CN105524543B - A kind of arc welding transformer for saving electromagnetic wire - Google Patents

A kind of arc welding transformer for saving electromagnetic wire Download PDF

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Publication number
CN105524543B
CN105524543B CN201510492285.XA CN201510492285A CN105524543B CN 105524543 B CN105524543 B CN 105524543B CN 201510492285 A CN201510492285 A CN 201510492285A CN 105524543 B CN105524543 B CN 105524543B
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parts
nano
transformer
diluent
coating
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CN105524543A (en
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徐若本
苏永义
刘斐
隋树法
贾瑞亮
杜明
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Nantong Hai Guo Machinery Co Ltd
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STATE GRID SHANDONG FEIXIAN POWER SUPPLY Co
State Grid Corp of China SGCC
Linyi Power Supply Co of State Grid Shandong Electric Power Co Ltd
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Abstract

The invention belongs to power supply fields, a kind of arc welding transformer for saving electromagnetic wire are disclosed, including magnetic core, coil and Stainless Steel Shell;It is characterized in that, the stainless steel case coats coating in vitro;The preparation method of the coating includes the following steps:It will be modified poly-(3,4 ethene dioxythiophenes)Polystyrolsulfon acid, which is placed in high speed dispersor, to be dissipated, then talcum powder, sodium alginate, nanometer titanium dioxide, organobentonite, nanometer silicon carbide, nano-silicon nitride, nano-silver powder, magnesium chloride, graphene, levelling agent, Triallyl isocyanurate, diluent, dimethylaminoethyl acrylate, organic siliconresin, aromatic urethane acrylate are added successively, is stirred to obtain the final product.The corrosion-resistant Antistatic radiation-proof performance of transformer shell of the present invention is good.

Description

A kind of arc welding transformer for saving electromagnetic wire
Technical field
The invention belongs to power supply fields, and in particular to a kind of arc welding transformer for saving electromagnetic wire.
Background technology
Transformer(Transformer)It is the device for changing alternating voltage using the principle of electromagnetic induction, main member It is primary coil, secondary coil and iron core(Magnetic core).Major function has:Voltage transformation, impedance transformation, is isolated, is steady at current transformation Pressure(Magnetic saturation transformer)Deng.It can be divided into, according to use,:Distribution transformer, power transformer, full-sealed transformer, combined variable Depressor, dry-type transformer, oil-immersed transformer, single-phase transformer, furnace transformer, rectifier transformer etc..
Arc-welding is that the heat melts weldment joint generated by electric arc is welded to realize.In order to ensure welding quality and electricity The stability of arc, arc welding transformer must have dropping characteristic.Transformer case is mainly used for the peace at operating transformer scene Full protection.It avoids because the foreign matters such as toy, rainwater enter transformer and cause interruption of service, can effectively protect personal safety simultaneously rises Certain electromagnetic shielding action.It is divided by structural material difference:Aluminium alloy grinds card transformer case, stainless steel transformer case With spraying steel plate transformer case three categories.By use occasion difference:It is divided to indoor transformer case and outdoor two kinds of depressor shell. The prior art is less to the research of transformer case, but because security risk caused by the damage of shell is more and more;For Ensure the safety of people's production and life, it would be desirable to which a kind of corrosion-resistant, antistatic, mechanical strength of research is big and with electricity The transformer case of magnetic screen function.
Invention content
Present invention aim to address many defects of transformer in the prior art, by a large number of experiments and exploration, externally Shell is transformed, it is made to have preferable corrosion-resistant, antistatic, mechanical strength greatly and with electro-magnetic screen function.
To achieve these goals, technical scheme of the present invention is realized in the following way:
A kind of arc welding transformer for saving electromagnetic wire, including magnetic core, coil and Stainless Steel Shell;It is characterized in that, The stainless steel case coats coating in vitro;The coating is prepared by the raw material of following parts by weight:
0.1-0.2 parts of talcum powder, 0.1-0.2 parts of sodium alginate, 0.5-1 parts of nanometer titanium dioxide, organobentonite 0.5-1 Part, 2-3 parts of nanometer silicon carbide, 3-5 parts of nano-silicon nitride, 5-7 parts of nano-silver powder, 6-8 parts of magnesium chloride, 15-18 parts of graphene, stream Flat agent 0.7-0.9 parts, 1-2 parts of Triallyl isocyanurate, 50-60 parts of diluent, dimethylaminoethyl acrylate 10-15 Part, 12-15 parts of organic siliconresin, 16-22 parts of aromatic urethane acrylate are modified and gather(3,4- ethene dioxythiophenes)It is poly- 9-12 parts of styrene sulfonic acid.
The modification gathers(3,4- ethene dioxythiophenes)The preparation method of polystyrolsulfon acid is as follows:
Under conditions of temperature is 35 DEG C, sulfonated graphene, 3,4-rthylene dioxythiophene and polyethylene glycol are dispersed in In ionized water, make a concentration of 0.05wt% of contained polyethylene glycol in the mixed system to be formed, and sulfonated graphene, 3,4- ethylene Dioxy thiophene, the mass ratio of polyethylene glycol is 2:3:0.1, then the pH value of the mixed system is adjusted to 4.5, and with 500 turns/ The speed of min is stirred, while adds in oxidant and catalyst, wherein the mass ratio of oxidant and 3,4-rthylene dioxythiophene It is 1:2, the mass ratio 0.01 of catalyst and 3,4-rthylene dioxythiophene:1,10-72h is then persistently stirred to react, is removed later Foreign ion in reaction product mixture to get;The oxidant is sodium peroxydisulfate, and the catalyst is ferric trichloride.
The diluent is:Water:Isopropanol:Ethyl alcohol(Volume ratio)=1:7:1;
The levelling agent is:Dimethyl silicone polymer;
Preparation method includes the following steps:
It will be modified poly-(3,4- ethene dioxythiophenes)Polystyrolsulfon acid, which is placed in high speed dispersor, to be dissipated, and 1000 turns of rotating speed/ Min stirs 60min, then adds talcum powder successively, sodium alginate, nanometer titanium dioxide, organobentonite, nanometer silicon carbide, receives Rice silicon nitride, nano-silver powder, magnesium chloride, graphene, levelling agent, Triallyl isocyanurate, diluent, acrylic acid diformazan ammonia Base ethyl ester, organic siliconresin, aromatic urethane acrylate, 1500 turns/min stir 15-30min to get.
Advantageous effect of the present invention mainly includes the following aspects:
The present invention has good collective effect, and an effect stability using graphene anti-corrosion, with photocuring system, during effect Effect length;The present invention has stronger antibacterial effect using nano-silver powder, and the duration is long, has with photocuring system good Compatibility;The combinations such as nanometer titanium dioxide, nano-silicon nitride and nanometer silicon carbide have preferable radiation-resistant corrosion function;This Modification prepared by invention gathers(3,4- ethene dioxythiophenes)Polystyrolsulfon acid can not only meet wanting for Antistatic radiation-proof It asks, and there is good compatibility, dilution oligomer, regulation system viscosity with photocuring system.Each component material of the present invention Between it is mutually coordinated, be the applicant by big change of variable condition, parameter, by single factor experiment, factorial experiment obtains, this Apply for that operating parameter is operated for inventor through creative work to obtain that there is self assembly spy after the coating film forming curing of preparation Property, can freely spread in substrate, and build high-effective conductive network, make coating surface have high transparency, high conductivity and Stability, while can also make that there is better mechanical property after curing of coatings, it is particularly resistance to activeness and quietness effect and height The characteristics of mill property, better Antistatic radiation-proof durability is made it have, while there is excellent corrosion resistance.
Specific embodiment
Embodiment 1
A kind of arc welding transformer for saving electromagnetic wire, including magnetic core, coil and Stainless Steel Shell;The stainless steel case External coating coating;The coating is prepared by the raw material of following parts by weight:
0.1 part of talcum powder, 0.1 part of sodium alginate, 0.5 part of nanometer titanium dioxide, 0.5 part of organobentonite, nanometer silicon carbide 2 Part, 3 parts of nano-silicon nitride, 5 parts of nano-silver powder, 6 parts of magnesium chloride, 15 parts of graphene, 0.7 part of levelling agent, triallyl isocyanide urea 1 part of acid esters, 50 parts of diluent, 10 parts of dimethylaminoethyl acrylate, 12 parts of organic siliconresin, aromatic urethane acrylate 16 parts, it is modified poly-(3,4- ethene dioxythiophenes)9 parts of polystyrolsulfon acid.
The modification gathers(3,4- ethene dioxythiophenes)The preparation method of polystyrolsulfon acid is as follows:
Under conditions of temperature is 35 DEG C, sulfonated graphene, 3,4-rthylene dioxythiophene and polyethylene glycol are dispersed in In ionized water, make a concentration of 0.05wt% of contained polyethylene glycol in the mixed system to be formed, and sulfonated graphene, 3,4- ethylene Dioxy thiophene, the mass ratio of polyethylene glycol is 2:3:0.1, then the pH value of the mixed system is adjusted to 4.5, and with 500 turns/ The speed of min is stirred, while adds in oxidant and catalyst, wherein the mass ratio of oxidant and 3,4-rthylene dioxythiophene It is 1:2, the mass ratio 0.01 of catalyst and 3,4-rthylene dioxythiophene:1,10h is then persistently stirred to react, removes mixing later Foreign ion in reaction product to get;The oxidant is sodium peroxydisulfate, and the catalyst is ferric trichloride.
The diluent is:Water:Isopropanol:Ethyl alcohol(Volume ratio)=1:7:1;
The levelling agent is:Dimethyl silicone polymer;
Preparation method includes the following steps:
It will be modified poly-(3,4- ethene dioxythiophenes)Polystyrolsulfon acid, which is placed in high speed dispersor, to be dissipated, and 1000 turns of rotating speed/ Min stirs 60min, then adds talcum powder successively, sodium alginate, nanometer titanium dioxide, organobentonite, nanometer silicon carbide, receives Rice silicon nitride, nano-silver powder, magnesium chloride, graphene, levelling agent, Triallyl isocyanurate, diluent, acrylic acid diformazan ammonia Base ethyl ester, organic siliconresin, aromatic urethane acrylate, 1500 turns/min stir 15min to get.
After brushing paint, transformer shell surface of the present invention is without skinning and lump phenomenon, energy rapid curing drying, environmentally friendly nothing Poison, not tacky, do not return viscous, scratch resistance is wear-resisting;Antistatic property is excellent and lasting stability, coating surface resistance are 6.4 × 105 Ω/sq, coating surface resistance 6.9 × 10 after placing 1 year5Ω/sq, antistatic property are lasting.Coating hardness 5H, adhesive force 1 Grade, impact strength 58kg.cm.
Corrosion resistance is tested:Paint film uniform hue, it is smooth;
Salt water resistance(3% sodium chloride, for 24 hours)It is not blistering, do not fall off, without whitening;
X-ray shield rate can reach more than 80%.
Embodiment 2
A kind of arc welding transformer for saving electromagnetic wire, including magnetic core, coil and Stainless Steel Shell;It is characterized in that, The stainless steel case coats coating in vitro;The coating is prepared by the raw material of following parts by weight:
0.2 part of talcum powder, 0.2 part of sodium alginate, 1 part of nanometer titanium dioxide, 1 part of organobentonite, 3 parts of nanometer silicon carbide, 5 parts of nano-silicon nitride, 7 parts of nano-silver powder, 8 parts of magnesium chloride, 18 parts of graphene, 0.9 part of levelling agent, Triallyl isocyanurate 2 parts, 60 parts of diluent, 15 parts of dimethylaminoethyl acrylate, 15 parts of organic siliconresin, aromatic urethane acrylate 22 Part is modified and gathers(3,4- ethene dioxythiophenes)12 parts of polystyrolsulfon acid.
The modification gathers(3,4- ethene dioxythiophenes)The preparation method of polystyrolsulfon acid is as follows:
Under conditions of temperature is 35 DEG C, sulfonated graphene, 3,4-rthylene dioxythiophene and polyethylene glycol are dispersed in In ionized water, make a concentration of 0.05wt% of contained polyethylene glycol in the mixed system to be formed, and sulfonated graphene, 3,4- ethylene Dioxy thiophene, the mass ratio of polyethylene glycol is 2:3:0.1, then the pH value of the mixed system is adjusted to 4.5, and with 500 turns/ The speed of min is stirred, while adds in oxidant and catalyst, wherein the mass ratio of oxidant and 3,4-rthylene dioxythiophene It is 1:2, the mass ratio 0.01 of catalyst and 3,4-rthylene dioxythiophene:1,72h is then persistently stirred to react, removes mixing later Foreign ion in reaction product to get;The oxidant is sodium peroxydisulfate, and the catalyst is ferric trichloride.
The diluent is:Water:Isopropanol:Ethyl alcohol(Volume ratio)=1:7:1;
The levelling agent is:Dimethyl silicone polymer;
Preparation method includes the following steps:
It will be modified poly-(3,4- ethene dioxythiophenes)Polystyrolsulfon acid, which is placed in high speed dispersor, to be dissipated, and 1000 turns of rotating speed/ Min stirs 60min, then adds talcum powder successively, sodium alginate, nanometer titanium dioxide, organobentonite, nanometer silicon carbide, receives Rice silicon nitride, nano-silver powder, magnesium chloride, graphene, levelling agent, Triallyl isocyanurate, diluent, acrylic acid diformazan ammonia Base ethyl ester, organic siliconresin, aromatic urethane acrylate, 1500 turns/min stir 30min to get.
After brushing paint, transformer shell surface of the present invention is without skinning and lump phenomenon, energy rapid curing drying, environmentally friendly nothing Poison, not tacky, do not return viscous, scratch resistance is wear-resisting;Antistatic property is excellent and lasting stability, coating surface resistance are 6.5 × 105 Ω/sq, coating surface resistance 7.1 × 10 after placing 1 year5Ω/sq, antistatic property are lasting.Coating hardness 5H, adhesive force 1 Grade, impact strength 60kg.cm.
Corrosion resistance is tested:Paint film uniform hue, it is smooth;
Salt water resistance(3% sodium chloride, for 24 hours)It is not blistering, do not fall off, without whitening;
X-ray shield rate can reach more than 80%.
The present invention is done it is noted that although the description of front has been carried out by the example of the present invention certainly Go out will be apparent to those skilled in the science it is such and other improvement and change be deemed to fall such as set forth herein Broad range of the present invention in.Therefore, although the present invention reference has been made to preferred embodiment and be described, meaning It is not that the product of tool novelty is made to be restricted therefrom, on the contrary, it is intended to include to meet part disclosed above, claim Broad range within various improvement and equivalent modifications.

Claims (1)

1. a kind of arc welding transformer for saving electromagnetic wire, including magnetic core, coil and Stainless Steel Shell;It is characterized in that, institute It states stainless steel case and coats coating in vitro;The coating is prepared by the raw material of following parts by weight:
0.1-0.2 parts of talcum powder, 0.5-1 parts of nanometer titanium dioxide, 0.5-1 parts of organobentonite, is received 0.1-0.2 parts of sodium alginate 2-3 parts of silicon carbide of rice, 3-5 parts of nano-silicon nitride, 5-7 parts of nano-silver powder, 6-8 parts of magnesium chloride, 15-18 parts of graphene, levelling agent 0.7-0.9 parts, 1-2 parts of Triallyl isocyanurate, 50-60 parts of diluent, 10-15 parts of dimethylaminoethyl acrylate, have It is 12-15 parts of machine silicones, 16-22 parts of aromatic urethane acrylate, 9-12 parts polymer-modified;
The preparation method of the coating includes the following steps:
Polymer-modified be placed in high speed dispersor is dissipated, 1000 turns/min of rotating speed stirs 60min, then adds talcum successively Powder, sodium alginate, nanometer titanium dioxide, organobentonite, nanometer silicon carbide, nano-silicon nitride, nano-silver powder, magnesium chloride, graphite Alkene, levelling agent, Triallyl isocyanurate, diluent, dimethylaminoethyl acrylate, organic siliconresin, fragrant adoption ammonia Ester acrylate, 1500 turns/min stir 15-30min to get;
The polymer-modified preparation method includes the following steps:
Under conditions of temperature is 35 DEG C, sulfonated graphene, 3,4-rthylene dioxythiophene and polyethylene glycol are dispersed in deionization In water, make a concentration of 0.05wt% of contained polyethylene glycol in the mixed system to be formed, and sulfonated graphene, 3,4- ethylene dioxies Thiophene, the mass ratio of polyethylene glycol is 2:3:0.1, then the pH value of the mixed system is adjusted to 4.5, and with 500 turns/min's Speed is stirred, while adds in oxidant and catalyst, and the mass ratio of wherein oxidant and 3,4-rthylene dioxythiophene is 1: 2, the mass ratio 0.01 of catalyst and 3,4-rthylene dioxythiophene:1, be then persistently stirred to react 10-72h to get;The oxidation Agent is sodium peroxydisulfate, and the catalyst is ferric trichloride;
The diluent is water:Isopropanol:Ethyl alcohol is according to 1:7:1 volume ratio mixes to obtain the final product;The levelling agent is poly dimethyl Siloxanes.
CN201510492285.XA 2015-08-12 2015-08-12 A kind of arc welding transformer for saving electromagnetic wire Active CN105524543B (en)

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Application Number Priority Date Filing Date Title
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CN105524543B true CN105524543B (en) 2018-07-06

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Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201616333U (en) * 2009-12-15 2010-10-27 梁佑平 Arc welding transformer capable of saving magnet wires
CN102558772B (en) * 2011-12-15 2013-03-06 河海大学 Poly(3,4-ethylenedioxythiophene)/sulfonated graphene composite hydrogel and preparation method thereof
CN103788859B (en) * 2014-01-08 2016-06-08 华东理工大学 A kind of antistatic coating for ultra-violet curing and preparation method thereof
CN104263229B (en) * 2014-09-09 2016-05-18 广州申威新材料科技有限公司 The film build method of a kind of preparation method of antistatic UV coating and this antistatic UV coating

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Effective date of registration: 20190517

Address after: 226300 Xiting Residential Committee Group 11, Xiting Town, Tongzhou District, Nantong City, Jiangsu Province

Patentee after: Nantong Hai Guo Machinery Co., Ltd.

Address before: 276001 No. 130, Jin Shan Shan Road, Lanshan District, Linyi, Shandong

Co-patentee before: State Grid Corporation of China

Patentee before: Linyi Electric Power Company of Guo Wang Shandong Province Utilities Electric Co.

Co-patentee before: STATE GRID SHANDONG FEIXIAN POWER SUPPLY COMPANY

TR01 Transfer of patent right