CN105523776A - Aluminum oxide and titanium oxide aerogel foamed cement - Google Patents

Aluminum oxide and titanium oxide aerogel foamed cement Download PDF

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Publication number
CN105523776A
CN105523776A CN201511028410.8A CN201511028410A CN105523776A CN 105523776 A CN105523776 A CN 105523776A CN 201511028410 A CN201511028410 A CN 201511028410A CN 105523776 A CN105523776 A CN 105523776A
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China
Prior art keywords
parts
aluminum oxide
titania aerogel
cement
water
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Pending
Application number
CN201511028410.8A
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Chinese (zh)
Inventor
杨卓舒
刘建波
刘国强
邝清林
冯强
张磊
陈赓
车君超
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Zhuoda New Material Technology Group Co Ltd
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Zhuoda New Material Technology Group Co Ltd
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Priority to CN201511028410.8A priority Critical patent/CN105523776A/en
Publication of CN105523776A publication Critical patent/CN105523776A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/10Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • C04B2111/343Crack resistant materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/52Sound-insulating materials

Abstract

The present invention provides aluminum oxide and titanium oxide aerogel foamed cement which comprises the following components in parts by mass: 30 to 65 parts of Portland cement; 5 to 15 parts of aluminum oxide aerogel; 5 to 15 parts of titanium oxide aerogel; 4 to 10 parts of silica fume; 2 to 4 parts of a coagulation accelerator; 2 to 4 parts of a water reducing agent; 4 to 8 parts of a foam stabilizer; 5 to 15 parts of a foaming agent and 5 to 25 parts of fly ash. Compared with the prior art, the thermal conductivity of the aluminum oxide and titanium oxide aerogel foamed cement is 0.085-0.095W / (m.K), the sound absorbing capacity is 0.05-0.25%, dry bulk density is 250-450kg / m<3>, compressive strength is 3.0-5.0Mpa, and the aluminum oxide and titanium oxide aerogel foamed cement also has good water resistance, low shrinkage rate, long life, simple construction and easy operation.

Description

A kind of aluminum oxide and titania aerogel foam cement
Technical field
The present invention relates to a kind of jelling agent, specifically relate to a kind of aerogel foam cement.
Background technology
Foam cement is mechanically fully foamed by whipping agent by the foamed system of foaming machine, and by foam and grout Homogeneous phase mixing, then the pumping system through foaming machine carries out cast-in-place construction or mould molding, a kind of novel light lagging material containing a large amount of sealed porosity that natural curing is formed.Foam cement belongs to air bubble-shaped thermal insulation material, and outstanding feature forms closed foam hole at inside concrete, makes concrete light and thermal insulation separation thermalization.
Aerogel is a kind of solid matter form, and its product high porosity, low density, the Specific surface area that silica aerogel is very thin effectively limit the propagation of local thermal excitation.Nanometer micropore hole has large specific surface area and high hole ratio, good dispersiveness and suspension and thickening, thixotroping, strengthening action is all had in water-based and solvent-based adhesive, inhibit gas molecule to heat conducting contribution, be applied in building energy-saving.
The present inventor finds foam cement through long-term observation, research, analysis, and its fire prevention, waterproof, heat-insulating property still can not meet the requirement of people.
Aluminum oxide and titania aerogel are applied to foam cement, and its fire prevention of solution that can be desirable, waterproof, heat-insulating property are not very desirable problems, and the present invention is non-fire material, and fire-protection rating is A; Environmentally safe, and there is good heat-insulating property.
Summary of the invention
The object of this invention is to provide the foam cement that a kind of fire resistance is excellent, heat-insulating property is good, waterproof, cracking resistance, soundproof effect are good.
The invention provides a kind of aluminum oxide and the titania aerogel foam cement that are applicable to material of construction, this aluminum oxide and titania aerogel foam cement are non-fire material, and fire-protection rating is A; Environmentally safe, and there is good heat-insulating property, and manufacture craft is simple, the prices of raw and semifnished materials are cheap, is applicable to scale operation.
Realize the object of the invention technical scheme as follows:
Aluminum oxide provided by the invention and titania aerogel foam cement comprise the following component by mass parts: ordinary Portland cement, 30 ~ 65 parts; Alumina aerogels, 5 ~ 15 parts; Titania aerogel, 5 ~ 15 parts; SILICA FUME, 4 ~ 10 parts; Setting accelerator, 2 ~ 4 parts; Water reducer, 2 ~ 4 parts; Suds-stabilizing agent, 4 ~ 8 parts; Whipping agent, 5 ~ 15 parts; Flyash, 5 ~ 25 parts.
In first optimal technical scheme of the present invention, ordinary Portland cement, 30 ~ 60 parts; Alumina aerogels, 10 ~ 15 parts; Titania aerogel, 10 ~ 15 parts; Flyash, 15 ~ 25 parts.
In second optimal technical scheme of the present invention, ordinary Portland cement, 40 ~ 55 parts; Alumina aerogels, 5 ~ 10 parts; Titania aerogel, 10 ~ 15 parts; Flyash, 20 ~ 25 parts.
In 3rd optimal technical scheme of the present invention, described setting accelerator is water glass; Described water reducer is sodium lignosulfonate.
In 4th optimal technical scheme of the present invention, described suds-stabilizing agent is silicone amide; Described whipping agent is rosined soap or Sodium dodecylbenzene sulfonate.
In 5th optimal technical scheme of the present invention, described SILICA FUME is neutral SILICA FUME, and it comprises following component by mass percentage: silicon-dioxide 95.8%, aluminium sesquioxide 1.0%, ferric oxide 0.9%, magnesium oxide 0.7%, calcium oxide 0.3% and sodium oxide 1.3%.
With immediate prior art ratio, technical scheme provided by the invention has following excellent effect:
1, heat-insulating property is excellent: thermal conductivity is 0.085 ~ 0.095W/mK, and thermal resistance is about 20 ~ 30 times of normal concrete.
2, soundproof effect is good: containing a large amount of separated foams in foamed concrete, and be evenly distributed, sound absorbing power is 0.05 ~ 0.20%, is 5 times of normal concrete, possesses the function of effective sound insulation.
3, good integrity: cast-in-site is constructed, and is combined closely, Bu Xuliu circle space and permeability cell with main construction.
4, density is low: dry volume density is 250 ~ 450kg/m3, is 1/5 ~ 1/8 of normal concrete density, can alleviates whole building load.
5, ultimate compression strength is higher: ultimate compression strength is 3.0 ~ 5.0Mpa.
6, good water-repellancy: independent intensive bubble and good globality, make it have very strong water resistance.
7, cracking resistance line: shrinking percentage is low, splitting resistance is 7 times of normal concrete.
8, the life-span is long: identical with the main construction life-span.
9, working procedure is simple: flat roof deck separately need not do sloping layer.
Embodiment
Further be clearly and completely described technical scheme below in conjunction with the embodiment of the present invention, obviously, described embodiment is only a part of embodiment of the present invention, instead of whole embodiments.Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art obtain, all belongs to the scope of protection of the invention.
Embodiment 1: take ordinary portland cement 50 parts, alumina aerogels 5 parts, titania aerogel 5 parts, SILICA FUME 6 parts, 5 parts, flyash, be dry mixed stirring and all use; Take suitable quantity of water, water is heated to 42 DEG C, powder is added to the water, and add setting accelerator water glass 4 parts, water reducer sodium lignosulfonate 2 parts, suds-stabilizing agent silicone amide 6 parts, stir, add whipping agent rosined soap 10 parts, micro-ly stir, pour mould into, after 6 hours, the demoulding obtains foam cement sample.
Embodiment 2: take ordinary portland cement 35 parts, alumina aerogels 10 parts, titania aerogel 10 parts, SILICA FUME 4 parts, 10 parts, flyash, be dry mixed stirring and all use; Take suitable quantity of water, water is heated to 42 DEG C, powder is added to the water, and add setting accelerator water glass 4 parts, water reducer sodium lignosulfonate 2 parts, suds-stabilizing agent silicone amide 5 parts, stir, add whipping agent Sodium dodecylbenzene sulfonate 15 parts, micro-ly to stir, pour mould into, after 6 hours, the demoulding obtains foam cement sample.
Embodiment 3: take ordinary portland cement 55 parts, alumina aerogels 5 parts, titania aerogel 10 parts, SILICA FUME 6 parts, 20 parts, flyash, be dry mixed stirring and all use; Take suitable quantity of water, water is heated to 42 DEG C, powder is added to the water, and add setting accelerator water glass 4 parts, water reducer sodium lignosulfonate 2 parts, suds-stabilizing agent silicone amide 4 parts, stir, add whipping agent rosined soap 10 parts, micro-ly stir, pour mould into, after 6 hours, the demoulding obtains cement sample.
Embodiment 4: take ordinary portland cement 50 parts, alumina aerogels 10 parts, titania aerogel 10 parts, SILICA FUME 6 parts, 20 parts, flyash, be dry mixed stirring and all use; Take suitable quantity of water, water is heated to 42 DEG C, powder is added to the water, and add setting accelerator water glass 4 parts, water reducer sodium lignosulfonate 2 parts, suds-stabilizing agent silicone amide 4 parts, stir, add whipping agent Sodium dodecylbenzene sulfonate 10 parts, micro-ly to stir, pour mould into, after 6 hours, the demoulding obtains cement sample.
Embodiment 5: take ordinary portland cement 45 parts, alumina aerogels 5 parts, titania aerogel 10 parts, SILICA FUME 5 parts, 25 parts, flyash, be dry mixed stirring and all use; Take suitable quantity of water, water is heated to 42 DEG C, powder is added to the water, and add setting accelerator water glass 4 parts, water reducer sodium lignosulfonate 2 parts, suds-stabilizing agent silicone amide 4 parts, stir, add whipping agent rosined soap 10 parts, micro-ly stir, pour mould into, after 6 hours, the demoulding obtains cement sample.
Embodiment 6: take ordinary portland cement 60 parts, alumina aerogels 15 parts, titania aerogel 5 parts, SILICA FUME 5 parts, 20 parts, flyash, be dry mixed stirring and all use; Take suitable quantity of water, water is heated to 42 DEG C, powder is added to the water, and add setting accelerator water glass 3 parts, water reducer sodium lignosulfonate 3 parts, suds-stabilizing agent silicone amide 5 parts, stir, add whipping agent Sodium dodecylbenzene sulfonate 9 parts, micro-ly to stir, pour mould into, after 6 hours, the demoulding obtains cement sample.
Embodiment 7: take ordinary portland cement 35 parts, alumina aerogels 10 parts, titania aerogel 10 parts, SILICA FUME 8 parts, 20 parts, flyash, be dry mixed stirring and all use; Take suitable quantity of water, water is heated to 42 DEG C, powder is added to the water, and add setting accelerator water glass 3 parts, water reducer sodium lignosulfonate 3 parts, suds-stabilizing agent silicone amide 5 parts, stir, add whipping agent Sodium dodecylbenzene sulfonate 12 parts, micro-ly to stir, pour mould into, after 6 hours, the demoulding obtains cement sample.
Embodiment 8: take ordinary portland cement 45 parts, alumina aerogels 10 parts, titania aerogel 15 parts, SILICA FUME 10 parts, 25 parts, flyash, be dry mixed stirring and all use; Take suitable quantity of water, water is heated to 42 DEG C, powder is added to the water, and add setting accelerator water glass 4 parts, water reducer sodium lignosulfonate 4 parts, suds-stabilizing agent silicone amide 8 parts, stir, add whipping agent Sodium dodecylbenzene sulfonate 15 parts, micro-ly to stir, pour mould into, after 6 hours, the demoulding obtains cement sample.
Embodiment 9: take ordinary portland cement 55 parts, alumina aerogels 10 parts, titania aerogel 10 parts, SILICA FUME 8 parts, 22 parts, flyash, be dry mixed stirring and all use; Take suitable quantity of water, water is heated to 42 DEG C, powder is added to the water, and add setting accelerator water glass 4 parts, water reducer sodium lignosulfonate 4 parts, suds-stabilizing agent silicone amide 6 parts, stir, add whipping agent rosined soap 12 parts, micro-ly stir, pour mould into, after 6 hours, the demoulding obtains cement sample.
Embodiment 10: take ordinary portland cement 55 parts, alumina aerogels 15 parts, titania aerogel 5 parts, SILICA FUME is neutral SILICA FUME, comprise following component by mass percentage: silicon-dioxide 95.8%, aluminium sesquioxide 1.0%, ferric oxide 0.9%, magnesium oxide 0.7%, calcium oxide 0.3% and sodium oxide 1.3%, then SILICA FUME 10 parts, 22 parts, flyash, is dry mixed stirring and all uses; Take suitable quantity of water, water is heated to 42 DEG C, powder is added to the water, and add setting accelerator water glass 4 parts, water reducer sodium lignosulfonate 4 parts, suds-stabilizing agent silicone amide 6 parts, stir, add whipping agent rosined soap 8 parts, micro-ly stir, pour mould into, after 6 hours, the demoulding obtains cement sample.
Gained sample in above-described embodiment is carried out performance test respectively, obtains data as shown in table 1 below.
Table 1
Above embodiment is only in order to illustrate that technical scheme of the present invention is not intended to limit; those of ordinary skill in the field are to be understood that; can modify to the specific embodiment of the present invention with reference to above-described embodiment or equivalent to replace, these do not depart from any amendment of spirit and scope of the invention or equivalently to replace within the claims that all awaits the reply in application.

Claims (6)

1. aluminum oxide and a titania aerogel foam cement, is characterized in that, described foam cement comprises the following component by mass parts: ordinary Portland cement, 30 ~ 65 parts; Alumina aerogels, 5 ~ 15 parts; Titania aerogel, 5 ~ 15 parts; SILICA FUME, 4 ~ 10 parts; Setting accelerator, 2 ~ 4 parts; Water reducer, 2 ~ 4 parts; Suds-stabilizing agent, 4 ~ 8 parts; Whipping agent, 5 ~ 15 parts; Flyash, 5 ~ 25 parts.
2. a kind of aluminum oxide as claimed in claim 1 and titania aerogel foam cement, is characterized in that, ordinary Portland cement, 30 ~ 60 parts; Alumina aerogels, 10 ~ 15 parts; Titania aerogel, 10 ~ 15 parts; Flyash, 15 ~ 25 parts.
3. a kind of aluminum oxide as claimed in claim 1 and titania aerogel foam cement, is characterized in that, ordinary Portland cement, 40 ~ 55 parts; Alumina aerogels, 5 ~ 10 parts; Titania aerogel, 10 ~ 15 parts; Flyash, 20 ~ 25 parts.
4. a kind of aluminum oxide as claimed in claim 3 and titania aerogel foam cement, is characterized in that, ordinary Portland cement, 40 ~ 55 parts; Alumina aerogels, 5 ~ 10 parts; Titania aerogel, 10 ~ 15 parts; Described setting accelerator is water glass; Described water reducer is sodium lignosulfonate.
5. a kind of aluminum oxide as claimed in claim 4 and titania aerogel foam cement, is characterized in that, described suds-stabilizing agent is silicone amide; Described whipping agent is rosined soap or Sodium dodecylbenzene sulfonate.
6. a kind of aluminum oxide as claimed in claim 1 and titania aerogel foam cement, it is characterized in that, described SILICA FUME is neutral SILICA FUME, and it comprises following component by mass percentage: silicon-dioxide 95.8%, aluminium sesquioxide 1.0%, ferric oxide 0.9%, magnesium oxide 0.7%, calcium oxide 0.3% and sodium oxide 1.3%.
CN201511028410.8A 2015-12-31 2015-12-31 Aluminum oxide and titanium oxide aerogel foamed cement Pending CN105523776A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111232991A (en) * 2020-04-08 2020-06-05 天津纳科世纪新材料有限公司 Silica aerogel spherical powder with special structure and preparation method thereof
CN113045335A (en) * 2021-04-28 2021-06-29 绍兴职业技术学院 Method for preparing prefabricated heat-insulation board for assembled interior wall by utilizing urban solid waste garbage

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CN103865097A (en) * 2014-03-06 2014-06-18 山东圣泉化工股份有限公司 Phenolic foam plate containing nanometer aerogel and production method of phenolic foam plate
WO2014136073A1 (en) * 2013-03-06 2014-09-12 Ecole Polytechnique Federale De Lausanne (Epfl) Titanium oxide aerogel composites
CN104445217A (en) * 2014-11-18 2015-03-25 北京科技大学 Preparation method of nanopore SiO2 doped foaming cement
CN104876497A (en) * 2015-03-04 2015-09-02 南京倍立达新材料***工程股份有限公司 Aerogel GRC surface layer dry-mixed mortar material and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013118940A1 (en) * 2012-02-08 2013-08-15 Photo & Environmental Technology Co. Porous composite, preparation method thereof, and cement composition containing porous composite
CN102659351A (en) * 2012-04-10 2012-09-12 太原理工大学 Thermal-insulation loading recycled concrete
WO2014136073A1 (en) * 2013-03-06 2014-09-12 Ecole Polytechnique Federale De Lausanne (Epfl) Titanium oxide aerogel composites
CN103865097A (en) * 2014-03-06 2014-06-18 山东圣泉化工股份有限公司 Phenolic foam plate containing nanometer aerogel and production method of phenolic foam plate
CN104445217A (en) * 2014-11-18 2015-03-25 北京科技大学 Preparation method of nanopore SiO2 doped foaming cement
CN104876497A (en) * 2015-03-04 2015-09-02 南京倍立达新材料***工程股份有限公司 Aerogel GRC surface layer dry-mixed mortar material and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111232991A (en) * 2020-04-08 2020-06-05 天津纳科世纪新材料有限公司 Silica aerogel spherical powder with special structure and preparation method thereof
CN111232991B (en) * 2020-04-08 2022-05-20 天津纳科世纪新材料有限公司 Silicon dioxide aerogel spherical powder with special structure and preparation method thereof
CN113045335A (en) * 2021-04-28 2021-06-29 绍兴职业技术学院 Method for preparing prefabricated heat-insulation board for assembled interior wall by utilizing urban solid waste garbage
CN113045335B (en) * 2021-04-28 2022-05-17 绍兴职业技术学院 Method for preparing prefabricated heat-insulation board for assembled interior wall by utilizing urban solid waste garbage

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