CN105506812B - A kind of graphene intelligence dress ornament - Google Patents
A kind of graphene intelligence dress ornament Download PDFInfo
- Publication number
- CN105506812B CN105506812B CN201511025777.4A CN201511025777A CN105506812B CN 105506812 B CN105506812 B CN 105506812B CN 201511025777 A CN201511025777 A CN 201511025777A CN 105506812 B CN105506812 B CN 105506812B
- Authority
- CN
- China
- Prior art keywords
- graphene
- substrate
- graphene film
- dress ornament
- sputtering
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 249
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 176
- 239000000758 substrate Substances 0.000 claims abstract description 110
- 239000002103 nanocoating Substances 0.000 claims abstract description 39
- 238000004544 sputter deposition Methods 0.000 claims abstract description 36
- 206010037660 Pyrexia Diseases 0.000 claims abstract description 31
- 238000012545 processing Methods 0.000 claims abstract description 28
- 238000012544 monitoring process Methods 0.000 claims abstract description 22
- 238000013480 data collection Methods 0.000 claims abstract description 18
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 16
- 239000004744 fabric Substances 0.000 claims abstract description 15
- -1 polypropylene Polymers 0.000 claims abstract description 11
- 239000007787 solid Substances 0.000 claims abstract description 8
- 239000004952 Polyamide Substances 0.000 claims abstract description 7
- 239000004743 Polypropylene Substances 0.000 claims abstract description 7
- 229920002647 polyamide Polymers 0.000 claims abstract description 7
- 229920000728 polyester Polymers 0.000 claims abstract description 7
- 229920005594 polymer fiber Polymers 0.000 claims abstract description 7
- 229920001155 polypropylene Polymers 0.000 claims abstract description 7
- 238000009941 weaving Methods 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims description 70
- 229910002804 graphite Inorganic materials 0.000 claims description 65
- 239000010439 graphite Substances 0.000 claims description 65
- 230000008569 process Effects 0.000 claims description 47
- 239000002994 raw material Substances 0.000 claims description 41
- 239000000463 material Substances 0.000 claims description 35
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 28
- 239000004020 conductor Substances 0.000 claims description 27
- 238000011065 in-situ storage Methods 0.000 claims description 22
- 239000000835 fiber Substances 0.000 claims description 19
- 238000005119 centrifugation Methods 0.000 claims description 15
- 229910052802 copper Inorganic materials 0.000 claims description 15
- 239000010949 copper Substances 0.000 claims description 15
- 239000000725 suspension Substances 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 239000000654 additive Substances 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 9
- 239000004094 surface-active agent Substances 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 238000007599 discharging Methods 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 230000009467 reduction Effects 0.000 claims description 8
- 230000012010 growth Effects 0.000 claims description 7
- 239000011261 inert gas Substances 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 238000005477 sputtering target Methods 0.000 claims description 7
- 238000001755 magnetron sputter deposition Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000013077 target material Substances 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 5
- 230000003750 conditioning effect Effects 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 5
- 230000006698 induction Effects 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 238000005411 Van der Waals force Methods 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 238000007596 consolidation process Methods 0.000 claims description 2
- 230000008878 coupling Effects 0.000 claims description 2
- 238000010168 coupling process Methods 0.000 claims description 2
- 238000005859 coupling reaction Methods 0.000 claims description 2
- 238000005538 encapsulation Methods 0.000 claims description 2
- 238000011068 loading method Methods 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 238000005520 cutting process Methods 0.000 claims 1
- 238000000151 deposition Methods 0.000 claims 1
- 238000010304 firing Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 abstract description 4
- 230000036760 body temperature Effects 0.000 abstract description 3
- 230000005855 radiation Effects 0.000 abstract description 3
- 230000004060 metabolic process Effects 0.000 abstract description 2
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 230000008821 health effect Effects 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 21
- 239000011889 copper foil Substances 0.000 description 13
- 238000001035 drying Methods 0.000 description 9
- 239000012528 membrane Substances 0.000 description 8
- 238000007639 printing Methods 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
- 239000004065 semiconductor Substances 0.000 description 7
- 150000001721 carbon Chemical group 0.000 description 6
- 230000005611 electricity Effects 0.000 description 6
- 238000000926 separation method Methods 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 230000009471 action Effects 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 230000005670 electromagnetic radiation Effects 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000001856 Ethyl cellulose Substances 0.000 description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
- 206010053615 Thermal burn Diseases 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 238000003486 chemical etching Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 229920001249 ethyl cellulose Polymers 0.000 description 2
- 235000019325 ethyl cellulose Nutrition 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000013307 optical fiber Substances 0.000 description 2
- 238000000554 physical therapy Methods 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 210000001519 tissue Anatomy 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- 201000002481 Myositis Diseases 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical group OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 208000004210 Pressure Ulcer Diseases 0.000 description 1
- 206010043189 Telangiectasia Diseases 0.000 description 1
- 206010052428 Wound Diseases 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 230000000202 analgesic effect Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 230000036772 blood pressure Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 210000005056 cell body Anatomy 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 239000002305 electric material Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000007603 infrared drying Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 1
- 229940039790 sodium oxalate Drugs 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000007920 subcutaneous administration Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 208000009056 telangiectasis Diseases 0.000 description 1
- 230000005619 thermoelectricity Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/06—Thermally protective, e.g. insulating
- A41D31/065—Thermally protective, e.g. insulating using layered materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
- B32B9/007—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/18—Metallic material, boron or silicon on other inorganic substrates
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/02—Details
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
- H05B3/14—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
- H05B3/145—Carbon only, e.g. carbon black, graphite
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
- H05B3/34—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater flexible, e.g. heating nets or webs
- H05B3/36—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater flexible, e.g. heating nets or webs heating conductor embedded in insulating material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/106—Carbon fibres, e.g. graphite fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Thermal Sciences (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The present invention relates to a kind of graphene intelligence dress ornament, it is characterised in that the intelligent dress ornament includes temperature monitoring portion, the graphene fever tablet prepared using polyester, polypropylene or polyamide polymer fiber weaving cloth as substrate and Data Collection processing unit；Graphene fever tablet includes the graphene film generated through solid carbon source sputtering mode on the basis of the small pieces graphene film through mechanical stripping set in flexible substrate and and by the graphene film nanoscale coating circuit through generating in a manner of sputtering or imprinting that is substrate；The control data control graphene fever tablet heating of Monitoring Data and Data Collection processing unit of the intelligent dress ornament based on temperature monitoring portion.The intelligent dress ornament of the present invention, which has, uses light feature, the characteristics of can carrying out detecting and controlling in real time to human body temperature, and the far-infrared radiation of graphene fever tablet transmitting does not injure not only to human body, also there is the good medical health effect for improving body microcirculqtory system and enhancing metabolism.
Description
Technical field
The present invention relates to a kind of body temperature monitoring with compensating intelligent dress ornament, more particularly to a kind of graphene intelligence dress ornament.
Background technology
Intelligent clothing is long-standing, is initially mainly used in the leading-edge fields such as aviation and military affairs.1989, Japanese Gao Mu
Person of outstanding talent preferably teaches is melted into material property and function by information science, proposes the concept of intellectual material first.The 1990s MIT
The wearable multimedia of (Massachusetts Institute of Technology, the Massachusetts Institute of Technology) Media Lab
Since computer comes out, domestic and foreign scholars start the research of gradually concern wearable technology and intelligent clothing.
With the improvement of living standards, requirement of the people for clothes is no longer limited to comfortableness and fashion, but it is uncommon
Personal health care, amusement or the purpose exchanged with other people can be reached by wearing clothes by hoping.Modern electronic technology, biography simultaneously
The development of sense technology and material science etc. also provides multi-disciplinary technical support for the progress of intelligent clothing.The skill of different field
The research that art develops into intelligent clothing provides various method, but still few for the research of intelligent clothing design general modfel
See.Intelligent clothing is electronics and the combination of fashion industry, but the two has disequilibrium again, and the design of existing intelligent clothing is past
It is past to bias toward electronic technology, and possess poor aesthetic property and comfortableness, this has with intelligent clothing design pattern not yet maturation
Compared with Important Relations.
The realization of the intelligent functions for the intelligent clothing developed at present mainly passes through 3 kinds of approach:(1) by some intelligent fibers
Or modified fibre is incorporated into fabric or woven into fabric and clothes is had intelligent characteristic；(2) by some SMART MATTER microencapsulations, use
The methods of dyeing and finishing processing or coating, is worked on fabric；(3) electronic component is made mutually to be tied with fabric by the method for being woven into or being embedded in
Close, intelligent clothing is made.
A kind of temperature-regulation garment (application number of patent of invention：201310358761.X) be related to it is a kind of based on can variable resistance temperature adjustment
Clothes, including the garment surface bed of material, flexible semiconductor thermoelectric, garment lining layer, converter, tunable load, controller and outer
Connect mains connection.Flexible semiconductor thermoelectric is placed between garment surface bed of material kimonos fitted lining nexine, flexible semiconductor thermoelectricity battle array
Row connect tunable load by converter or are sequentially connected controller and external power supply connector, and converter realizes annexation
Switching.The invention temperature adjustment strong adaptability, a range of alternating temperature are changed based on clothes itself thermal resistance, are consumed without the energy
Take, but the heater element flexible semiconductor focus array of the invention is made up of semi-conductor thermoelectric material.The semiconductor heat
Electric material is generated heat based on electromagnetic radiation mode, is heated by electromagnetic radiation, exist electrothermal calefactive rate it is slow, with body contact range
The shortcomings of small；And electromagnetic radiation can cause high-intensity microwave Continuous irradiation to make one heart rate, blood pressure raises, breathing adds
It hurry up, pant, perspire, dress for a long time occurs there is the problem of side effect to human body on the contrary.
The content of the invention
For the deficiency of prior art, the invention provides a kind of graphene intelligence dress ornament, it is characterised in that the intelligence
Dress ornament includes temperature monitoring portion, generated heat by graphene prepared by substrate of polyester, polypropylene or polyamide polymer fiber weaving cloth
Piece and Data Collection processing unit；
Graphene fever tablet in flexible substrate including setting on the basis of the small pieces graphene film through mechanical stripping
Through the solid carbon source graphene film that generates of sputtering mode and by graphene film being substrate, the nanoscale through generating in a manner of sputtering plates
Layer circuit；The intelligent dress ornament data collection process portion is based on the hygrosensor in the fixed structure on the substrate
Monitoring Data controls the graphene fever tablet of the intelligent dress ornament to generate heat, wherein, for positioning temperature monitoring portion temperature
Conductive and adhesive force the microstructure that is used to improve of the fixed structure of detector and the substrate is the shape in same procedure
Into.
According to a preferred embodiment, the graphene film generated through solid carbon source sputtering mode is from advance through machine
A small pieces graphene film is chosen in the small pieces graphene film for the generation that tool is peeled off, by described small pieces graphene film
The starting point as induction graphene film growth on temporary flexible substrate is transferred to, it is thin with small pieces graphene on described substrate
Film is that starting point generates graphene film using solid carbon source through sputtering mode.
According to a preferred embodiment, the production procedure of the small pieces graphene film through mechanical stripping generation is：
High-temperature process portion is connected with in-situ reducing portion, treatment temperature be 200 DEG C~1200 DEG C under the conditions of add nitrogen or
Inert gas carries out high-temperature process to graphite raw material；
The in-situ reducing portion is connected by the first feed pipe with mechanical stripping portion, is received through at the high-temperature process portion
Graphite raw material after reason, under 200 DEG C~1200 DEG C temperature conditionss, add at least one of nitrogen or hydrogen and be situated between as reduction
Matter, reduction treatment is carried out to graphene raw material, and the raw material after processing is sent into mechanical stripping portion；
The dosing portion is connected by the second feed pipe with the mechanical stripping portion, and the dosing portion is used to deposit surface
Active additive, and in the mechanical stripping portion in graphite raw material progress stripping process, continuing the cylinder to mechanical stripping portion
Shape chamber dosing；
The cylindrical chamber in the mechanical stripping portion is connected by the first feeding-passage with in-situ reducing portion, the machinery stripping
Cylindrical chamber from portion is connected by the second feeding-passage with dosing portion, and rotary shaft is hung down in cylindrical cavity room with rotating horizontal pole
Direct-connected to connect, abrading-ball is placed in the cylindrical cavity room, and the abrading-ball is the pearl that 50 μm~100 μm of diameter and hardness are more than graphite
Son；The cylindrical chamber in the mechanical stripping portion is connected by discharging channel with centrifugation portion；
Graphite raw material and the dosing portion (304) are added to the circle to the cylindrical chamber in the in-situ reducing portion
After cylindrical chamber adds surfactant additive, the rotary shaft drives square with the axis connected rotating horizontal pole in fixed cylinder
Stir in shape chamber, rotating horizontal pole drives abrading-ball in cavity and graphite raw material mutually to collide and rub in agitation, graphite original
Material is under the shear action of the abrading-ball frictional force, and the Van der Waals force of each graphite layers is disintegrated in graphite, obtains graphene and stone
The suspension of ink；
The suspension of graphene and graphite is sent into and centrifuged by the cylindrical chamber in the mechanical stripping portion by discharging channel
Separation unit, through centrifugation portion centrifugal treating, graphene suspension is obtained, and be sent into drying section and processing is dried, obtained
To small pieces graphene film.
According to a preferred embodiment, the nanoscale coating circuit is that will be adhered to flexible liner with circuit die
Graphene film on bottom is put into magnetron sputtering apparatus as base material and carries out nanoscale coating sputtering.
According to a preferred embodiment, the nanoscale coating circuit is：Graphene on flexible substrate is adhered to
Sputtering generation copper film on film, then by imprinting mode, generate nanoscale coating circuit.
According to a preferred embodiment, the coating sputter procedure magnetic control sputtering device sputtering operating pressure control exists
0.13Pa~0.20Pa, base material temperature target and base material distance 5cm~10cm, sputter 5 °~8 ° of angle, sputtering power less than 50 DEG C
100W~200W, sputtering zinc coat thickness control are 50nm~300nm, using base material upper sputtering target material structure.
According to a preferred embodiment, plasma processor is put into the graphene film for being adhered to flexible substrate,
Using oxygen, sputter process is carried out after carrying out pretreatment in 60 seconds under conditions of 50 watts of power, sputtering target material includes metallic aluminium, copper
Or silver.
According to a preferred embodiment, conductive fiber is made by yarn using the method for cored and looping, is woven into
In polyester, polypropylene or polyamide polymer fiber weaving cloth fabric.
According to a preferred embodiment, the temperature monitoring portion includes hygrosensor and distributed A/D acquisition modules,
The temperature monitoring portion is connected by the optical fiber conductive fiber with data collection process portion；Data processing division include single-chip microcomputer,
Wireless data transmitter, mobile terminal, distributed digital input/output module and power conditioning module, the data processing division lead to
The optic fibre wire is crossed with graphene fever tablet to be connected.
According to a preferred embodiment, epoxy is used to graphene fever tablet, temperature detecting part, data collection process portion
Resin-encapsulated, conductive fiber and temperature monitoring portion, data collection process portion and graphene fever tablet coupling part rubber or modeling
Material reinforces waterproof.
The graphene intelligence dress ornament of the present invention at least has following advantage：
(1) because graphene fever tablet possesses ultra-thin, light characteristic, therefore it is to the Intellectual garment that is heated based on graphene
The outward appearance of decorations will not have an impact.
(2) infra-red radiation caused by graphene fever tablet, there is good medical treatment and physiotherapy function.Grapheme material can be sent out
Far infrared life light wave is penetrated, has almost identical frequency spectrum with human body, it is raw can effectively to activate soma nucleic acid, protein etc.
Thing molecule, reaching improves blood circulation, anti-inflammatory, analgesic activity.
(3) graphene fever tablet programming rate is fast.Heat energy caused by the mutual frictional impact of carbon atom of graphene can make
Graphene fever tablet was brought rapidly up in 3 seconds, only needed that 35 DEG C can be warming up within 10 seconds, therefore while it is put on can just experience
To warm.
Brief description of the drawings
Fig. 1 is the intelligent dress ornament high-level schematic functional block diagram of the present invention；
Fig. 2 is graphene fever tablet structural representation of the present invention；
Fig. 3 is mechanical stripping legal system small pieces graphene film schematic flow sheet of the present invention；
Fig. 4 is the mechanical stripping portion structural representation of mechanical stripping legal system small pieces graphene film of the present invention；
Fig. 5 shows the graphene film being adhered in flexible substrate for covering copper film being put into forcing press；
Fig. 6 is shown by Fig. 5 moulding process and graphene film that is caused, being provided with three-dimensionally shaped printed conductor.
Reference numerals list
101：Hygrosensor 102：Distributed A/D acquisition modules 103：Single-chip microcomputer
104：Wireless data transmitter 105：Mobile terminal 106：Distributed digital input/output module
107：Power conditioning module 108：Graphene fever tablet 201：Overcoat
202：Nanoscale coating circuit 203：Graphene film 204：Adhensive membrane
205：Flexible substrate 301：Graphite raw material 302：High-temperature process portion
303：In-situ reducing portion 304：Dosing portion 305：Centrifugation portion
306：Drying section 307：Graphene film 400：Mechanical stripping portion
401：Cylindrical chamber 402：First feeding-passage 403：Second feeding-passage
404：Rotary shaft 405：Rotating horizontal pole 406：Abrading-ball
407：Discharging channel 501：Substrate 502：Micro-structural
503：Copper film 504：Impressing mould 505：Stamping structure
506：Forcing press 507：Printed conductor 508：Printed conductor plane
509：Printed conductor side wall 510：Substrate trenches 511：Substrate trenches bottom
512：Raised substrate plane 513：Substrate side wall 514：Fixed structure
Embodiment
It is described in detail with reference to the accompanying drawings and examples.
As shown in figure 1, the functional module of graphene intelligence dress ornament of the present invention includes：Temperature detecting part, graphene
Fever tablet 108 and data processing division.Wherein described temperature monitoring portion includes hygrosensor 101 and distributed A/D acquisition modules
102；Data processing division includes single-chip microcomputer 103, wireless data transmitter 104, mobile terminal 105, distributed digital input and output
Module 106 and power conditioning module 107.The hygrosensor 101 is connected with distributed A/D acquisition modules 102, for real-time
Human body temperature data are gathered, and the temperature data of collection is sent to distributed A/D acquisition modules 102.The distributed A/D is adopted
Collection module 102 is connected with single-chip microcomputer 103, and the temperature data of collection is transmitted to single-chip microcomputer 103.The single-chip microcomputer 103 passes through
Distributed digital input/output module is connected with heating power adjustment module 107, and passes through wireless data transmitter 104 and movement
Terminal 105 is connected.The heating-up temperature that the single-chip microcomputer 103 sets the temperature data collected and mobile terminal 105 is carried out pair
Than analysis, when temperature is less than the heating-up temperature that the mobile terminal 105 is set, single-chip microcomputer 103 is defeated by distribution input
Go out module and transmit heating signal to power conditioning module 107 to control graphene fever tablet 108 to be heated.Meanwhile the list
Piece machine 103 sends human body real time temperature to mobile terminal 105 through wireless data transmitter 104.User can also be according to body
Body real-time condition controls graphene fever tablet 108 to heat by mobile terminal 105.
The intelligent dress ornament of the present invention uses polyester, polypropylene or polyamide polymer fiber weaving cloth fabric, and uses cored
And yarn is made in conductive fiber by the method for looping, polyester, polypropylene or polyamide polymer fiber weaving cloth fabric are woven into
In.The temperature monitoring portion is connected by the optical fiber conductive fiber with data collection process portion；The data processing division passes through
The optic fibre wire is connected with graphene fever tablet 108.And to graphene fever tablet 108, temperature detecting part, data collection process
Portion uses epoxy encapsulation.Conductive fiber and temperature monitoring portion, data collection process portion and the connecting portion of graphene fever tablet 108
Divide and use rubber or plastic consolidation waterproof.
With reference to shown in Fig. 1 and Fig. 2, graphene fever tablet 108 of the invention includes flexible substrate 205, the flexible substrate
Graphene film 203 is set on 205, and graphene film 203 is arranged in flexible substrate 205 by adhensive membrane 204, the graphene
Film 203 is provided with the nanoscale coating circuit 202 through sputtering generation, the nanoscale coating circuit 202 and the electricity of graphene film 203
Connection；The nanoscale coating circuit 202 electrically connects with conductive fiber, and is connected by conductive fiber and data collection process portion
Connect.On graphene film 203 and nanoscale coating circuit 202 nanometer is covered covered with overcoat 201, the overcoat 201 simultaneously
The junction of level coating and conductive fiber.
The structure of the electrical-heating film of said structure, it can be prepared by following techniques, specifically included：There is provided soft
Property substrate 205, and the coated with adhesive film 204 in the flexible substrate 205；It is thin that the material of the flexible substrate 205 includes PET
Film, in order to improve the adhesive force that printing surface is formed needed for flexible substrate 205, electricity is carried out on the printing surface of flexible substrate 205
Dizzy processing or chemical attack frosted processing, then again by printing surface of the adhensive membrane 204 coated in flexible substrate 205.By institute
State graphene film 203 to be transferred in flexible substrate 205, graphene film 203 is connected by adhensive membrane 204 with flexible substrate 205；
The sputtering generation nanoscale coating circuit 202 on above-mentioned graphene film 203；Electricity is printed on above-mentioned nanoscale coating circuit 202
Pole, the electrode are used to realize that nanoscale coating circuit 202 electrically connects with conductive fiber.In above-mentioned printed on electrodes overcoat
201, the overcoat 201 is covered on electrode, and is covered on graphene film 203 and nanoscale coating circuit 202.It is described anti-
Sheath 201 has anti-scratch ability.
Flexible substrate 205 is installed on unwinding equipment in a manner of entire volume, it is continuous, equidistant to be moved to printing position
Put, exactitude position is realized by color mark sensor, the chromatography of multiple patterns can be carried out, after printing, flexible substrate 205 enters
Rotary drying, winding is carried out after sufficient infra-red drying and is used to be used as intelligent dress ornament fever tablet.
Because graphene fever tablet 108 possesses ultra-thin, light characteristic, therefore it is to the Intellectual garment that is heated based on graphene
The outward appearance of decorations will not have an impact.Infra-red radiation caused by graphene fever tablet 108, there is good medical treatment and physiotherapy function.
Grapheme material can launch far infrared life light wave, after far infrared is absorbed by the body, internal water can be made to produce resonance, made
Water molecule activation, strengthen its intermolecular adhesion, so as to large biological molecules such as activation of protein, biological cell is in most
High vibration energy level.Because biological cell produces resonance effects, far infrared heat energy can be delivered to the subcutaneous deeper part of human body, with
Lower deep layer temperature rises, and caused warm distributes from inside to outside.This action intensity, make telangiectasis, promote blood to follow
Ring, strengthen the metabolism between each tissue, increase the power of regeneration of tissue, improve the immunocompetence of body, adjust spirit
Exaltation state, so as to play a part of health care.In general, the releasing such as fuel combustion, electric heating appliance thermal source is red
Outside line belongs near infrared ray more, because wavelength is shorter, therefore produces substantial amounts of fuel factor, can produce and burn after long-term irradiation human body
Skin and eyes crystalline etc. injure.The shorter other electromagnetic waves of wavelength such as ultraviolet, X ray and gamma-rays etc., can make atom
On electronics produce free, more have injury effect to human body.Far infrared is quite different, and because wavelength is longer, energy is relatively low,
So use when relatively fewer scald harm.
Far infrared is also different with the low-frequency electromagnetic wave that household electrical appliance are radiated, the low frequency electromagnetic that household electrical appliance are disengaged
Ripple transmural through walls and can change the characteristic of body current, and by its harmfulness of people's strong suspicion.Far infrared is in human body skin
Penetration power only have 0.01 to 0.1 centimetre, human body can also release the far infrared of about 9 microns of wavelength in itself, so and low-frequency electrical
Magnetic wave can not lump together.Far infrared is used in the auxiliary treatment of many diseases, for example, bones muscle is ached, myotenositis,
Bedsore, scald and wound such as are not easy to heal the disease, may be by the characteristic that far infrared stimulates circulation, and reach auxiliary
The purpose for the treatment of.
The preparation method of large-area graphene film is used from advance through being selected in graphene film caused by mechanical stripping
A small pieces graphene film 307 is selected, the small pieces graphene film 307 of selection is positioned over and is adapted to graphene film application-specific
On the substrate of technology, using coming from the carbon atom discharged in the solid-state carbon source material containing carbon atom on temporary flexible substrate
Grow graphene film 203.
Described small pieces graphene film 307 is selected in the graphene film generated by micromechanics stripping means.Make
The graphene film piece grown for induction graphene film is shaped as square, rectangle, circle, ellipse or irregular
Type；The number of plies as the graphene film piece for inducing graphene film growth is 1 layer to 200 layers, and optimal is 1 layer to 20 layers, most
Optimal is 1 layer to 5 layers；Area as the small pieces graphene film 307 for inducing graphene film growth is 1nm2Extremely
50000cm2, optimal is 1nm2To 1000cm2, optimal is 1nm2To 100 μm2.Described backing material is suitable for graphene
Inorganic or organic conductor, semiconductor, insulator or its composite of film particular application technology.It is described in Grown
Graphene film the number of plies be 1 layer to 200 layers, optimal is 1 layer to 20 layers, and optimal is 1 layer to 5 layers.
The nanoscale coating circuit 202 is by the graphene film being adhered in flexible substrate 205 with circuit die
203 are put into magnetron sputtering apparatus as base material carries out nanoscale coating sputtering.To described flexibility is adhered to circuit die
Substrate 205 is put into plasma processor, using oxygen, under conditions of 50 watts of power pre-process within 60 seconds.The coating splashes
The sputtering operating pressure control of process magnetic control sputtering device is penetrated in 0.13Pa~0.20Pa, base material temperature is less than 50 DEG C, target and base material away from
From 5cm~10cm, 5 °~8 ° of angle is sputtered, sputtering power 100W~200W, sputtering zinc coat thickness control is 50nm~300nm, is adopted
With base material upper, sputtering target material structure.The material of nanoscale coating circuit 202 includes aluminium, copper or silver, nanoscale coating electricity
The frame structure that road 202 is formed by some lines.The electrothermal film material that nanoscale coating circuit 202 and graphene film 203 form,
With the characteristics of thickness is small, pliability is high.Graphene film 203 is two with cellular hexagon of the carbon atom composition of individual layer
Crystal structure is tieed up, the nanoscale coating circuit 202 good with pliability is combined, and nanoscale coating circuit 202 strengthens graphite and stone
The connectivity of ink, the grid filled up between all blank, can guarantee that the good electric conductivity of electrothermal film material, light weight, price
It is cheap.The material of flexible substrate 205 includes PET (Polyethylene terephthalate).Graphene film 203 and nanoscale
Coating circuit 202 heats heat needed for producing.
As shown in Figure 3 and Figure 4, the device of mechanical stripping method of the invention generation graphene film includes high-temperature process portion
302, in-situ reducing portion 303, dosing portion 304, mechanical stripping portion 400, centrifugation portion 305, drying section 306.At the high temperature
Reason portion 302 is connected with in-situ reducing portion 303, and high-temperature process portion 302 carries out high-temperature process to the graphite raw material 301 being added thereto,
And the graphite raw material 301 after processing is delivered into in-situ reducing portion 303.High-temperature process temperature is 200 DEG C~1200 DEG C, processing environment
Remain air, vacuum, nitrogen or inert gas.One preferred embodiment is that processing environment is kept in high-temperature process
For inert gas environment.Graphite raw material 301 is heated to 200 DEG C~1200 DEG C under inert gas shielding, and oxygen-containing functional group is stable
Property decline, left in the form of vapor, carbon dioxide etc..In-situ reducing portion 103 and high-temperature process portion 302 and mechanical stripping portion
400 are connected.In-situ reducing portion 303 receives the graphite raw material 301 after high-temperature process portion 302 is handled, and also original place is carried out to it
Reason, the graphite raw material 301 after processing deliver to mechanical stripping portion 400.In the original location in reduction portion 303, in 200 DEG C~1200 DEG C temperature
Under the conditions of, add at least one of nitrogen or hydrogen and be used as reducing medium, reduction treatment is carried out to graphite raw material 301, enters one
Step removes the oxygen-containing functional group in graphite raw material 301.Dosing portion 304 is connected with mechanical stripping portion 400.Dosing portion 304 is used to deposit
Surfactant additive is put, and in the mechanical stripping portion 400 in the progress stripping process of graphite raw material 301, continuing to machinery
The dosing of stripping portion 400.Surfactant additive is lauryl sodium sulfate, methyl anyl alcohol, sodium oxalate, sodium carboxymethylcellulose pyce, poly-
One or more in acrylamide, guar gum, fatty acid polyethylene glycol ester.Mechanical stripping portion 400 and the phase of centrifugation portion 105
Even.The graphite raw material 301 and dosing portion 304 that mechanical stripping portion 400 is used to receive after the reduction treatment in in-situ reducing portion 303 provide
Surfactant, and the graphite raw material 301 of reception is carried out stirring ball milling and peeled off, and by the graphene after lift-off processing
Centrifugation portion 305 is sent into the mixing suspension of graphite.Centrifugation portion 305 is connected with drying section 306.Centrifugation portion
The mixing suspension of 305 pairs of entrance graphene therein and graphite carries out centrifugal treating, arrive graphene suspension, and be sent into and do
Dry portion 306.Drying section 306 finally gives graphene film 307 to processing is dried into graphene suspension therein.
Fig. 4 is mechanical stripping portion of the present invention structural representation.Referring to shown in 2, mechanical stripping portion 400 includes cylindrical chamber
401st, the first feeding-passage 402, the second feeding-passage 403, rotary shaft 404, rotating horizontal pole 405 and abrading-ball 406.Mechanical stripping portion
400 cylindrical chamber 401 is connected by the first feeding-passage 402 with in-situ reducing portion 303, the mechanical stripping portion 400
Cylindrical chamber 401 is connected by the second feeding-passage 403 with dosing portion 304, rotary shaft 404 in the cylindrical chamber 401 with
The vertical connection of rotating horizontal pole 405, abrading-ball 406 are placed in the cylindrical chamber 401, and the abrading-ball 406 is diameter 50 μm~100
μm and hardness be more than graphite pearl.The cylindrical chamber 401 in the mechanical stripping portion 400 passes through discharging channel 407 and centrifugation
Separation unit 305 is connected.Cylindrical chamber 401 of the in-situ reducing portion 303 by the first feeding-passage 402 to mechanical stripping portion 400
Add graphite raw material 301.Dosing portion 304 is added by second charging aperture 403 to the cylindrical chamber 401 in mechanical stripping portion 400
Surfactant additive.Rotary shaft 404 drives the rotating horizontal pole 405 being vertically connected with rotary shaft 204 in cylindrical chamber 401
Agitation.Rotating horizontal pole 405 drives abrading-ball 406 in cylindrical chamber 401 and graphite raw material 301 mutually to collide and rub in agitation
To wipe, graphite raw material 301 is under the shear action of the frictional force of abrading-ball 406, and the Van der Waals force of each graphite layers is disintegrated in graphite,
Obtain the suspension of graphene and graphite.
Embodiment 1
Illustrate the production process of the mechanical stripping method production graphene film of the present invention with reference to Fig. 3 and Fig. 4.High-temperature process portion
302 are connected with in-situ reducing portion 303, and high-temperature process portion 302 is under 1000 DEG C of high temperature and inert gas treatment environment to adding it
In graphite raw material 301 carry out 1 hour high-temperature process, and the graphite raw material 301 after processing is delivered into in-situ reducing portion 303.Stone
Black raw material 301 is heated to 1000 DEG C under inert gas shielding, and oxygen-containing functional group stability declines, with vapor, carbon dioxide
Graphene raw material 301 is left etc. form.In-situ reducing portion 303 is connected with high-temperature process portion 302, and passes through the first feeding-passage
402 are connected with the cylindrical chamber 401 in mechanical stripping portion 400.In-situ reducing portion 303 receives after being handled through high-temperature process portion 302
Graphite raw material 301, and under 1000 DEG C of temperature conditionss, add at least one of nitrogen or hydrogen and be used as reducing medium, it is right
It carries out reduction treatment in 1 hour, and the graphite raw material 301 after processing delivers to the cylindrical chamber 401 in mechanical stripping portion 400.Graphite
Raw material 301 carries out reduction treatment, by the further oxygen-containing functional group removed in graphite raw material 301.Dosing portion 304 is entered by second
Material passage 403 is connected with the cylindrical chamber 401 in mechanical stripping portion 400.Dosing portion 304 is used to deposit surfactant additive,
And in the mechanical stripping portion 400 in the progress stripping process of graphite raw material 301, continuing to add 12 to mechanical stripping portion 400
Sodium alkyl sulfate is made into the slurry that concentration is 80.0% with water.The rotary shaft 404 in mechanical stripping portion 400 is in cylindrical chamber 401
Interior to be placed in the vertical connection of rotating horizontal pole 405, abrading-ball 406 in the cylindrical chamber 401, in-situ reducing portion 303 passes through first
Feeding-passage 402 adds graphite raw material 301 to the cylindrical chamber 201 in mechanical stripping portion 200.Dosing portion 304 is entered by second
Material mouth 403 adds surfactant additive to the cylindrical chamber 401 in mechanical stripping portion 400.Rotary shaft 404 drives and rotary shaft
404 rotating horizontal poles 405 being vertically connected stir in cylindrical chamber 401.Rotating horizontal pole 405 drives cylindrical cavity in agitation
Abrading-ball 406 and graphite raw material 401 mutually collision and friction in room 401, graphite raw material 301 is in the frictional force of abrading-ball 406
Under shear action, the Van der Waals force of each graphite layers is disintegrated in graphite, obtains the suspension of graphene and graphite.The abrading-ball
406 be the pearl that 50 μm~100 μm of diameter and hardness are more than graphite.The abrading-ball 406 of the present embodiment is with a diameter of 50 μm~100 μm
Abrading-ball be ball-milling medium, during graphite mechanical stripping, relative to diameter more than for 100 μm of ball-milling medium, graphite
Lamella is peeled off number and dramatically increased repeatedly, improves mechanical stripping efficiency.And gained graphite flake layer thickness distribution is concentrated,
More than 50% graphite flake layer thickness is all in below 4nm.
The cylindrical chamber 401 in the mechanical stripping portion 400 is connected by discharging channel 407 with centrifugation portion 305.Machine
The mixing suspension of graphene after lift-off processing and graphite is sent into and centrifuged by tool stripping portion 400 by discharging channel 407
Separation unit 305.Centrifugation portion 305 is connected with drying section 306.Centrifugation portion 305 is to entering graphene therein and graphite
Mixing suspension carry out centrifugal treating, arrive graphene suspension, and be sent into drying section 306.Drying section 306 is to entering wherein
Graphene suspension processing is dried, finally give graphene film 307.
Embodiment 2
With reference to shown in Fig. 2 Fig. 3, induction graphene large area life is used as by the use of single-layer graphene prepared by mechanical stripping method
Long grapheme platelet, small pieces graphene film 307 is transferred on interim growth flexible substrate copper foil and induces graphene film
203 growths.The copper foil substrate for there are graphene film small pieces is placed in sputtering chamber, using laser pulse by carbon atom from solid carbon source
It is splashed in target on copper foil substrate, so as to be starting point in copper foil Grown graphene film using graphene film small pieces
203。
Graphene film 203 is transferred in flexible substrate 205 using chemical etching and printing transferring method again, for by graphene film
203 processes separated with temporary substrates, the adhensive membrane 204 in flexible substrate 205 include PVB or ethyl cellulose etc., will
Graphene film 203 on temporary substrates overlaps with the adhensive membrane 204 in flexible substrate 205, forms temporary adhesion body；In removal
Temporary substrates are stated, to obtain the graphene film 203 in flexible substrate 205.Graphene film 203 bonds with flexible substrate 205
, it is necessary to using as the copper foil of temporary substrates or nickel foil separation after together, graphene film 203 on copper foil is so grown in just
Completely it is transferred on target flexibility substrate 205.High, the area by the purity of graphene film 203 obtained by methods described
Greatly.
The nanoscale coating circuit 202 is by the graphene film being adhered in flexible substrate 205 with circuit die
203 are put into magnetron sputtering apparatus as base material carries out nanoscale coating sputtering.To described flexibility is adhered to circuit die
Graphene film 203 on substrate 205 is put into plasma processor, using oxygen, carried out under conditions of 50 watts of power 60 seconds it is pre-
Processing.In 0.13Pa, base material temperature is 25 DEG C for the coating sputter procedure magnetic control sputtering device sputtering operating pressure control, target and base
Material distance 5cm, 8 ° of angle is sputtered, sputtering power 100W, sputtering target material is metallic copper, and sputtering zinc coat thickness control is 50nm-
300nm, using base material upper, sputtering target material structure, sputtering removes circuit die after completing, and coating circuit has been prepared
Into.Printed electrode on above-mentioned nanoscale coating circuit 202, the electrode is used to realize nanoscale coating circuit 202 and conduction
Fiber electrically connects.In above-mentioned printed on electrodes overcoat 201, the overcoat 201 is epoxy resin, has waterproof, anti-scratch
Ability.The overcoat 201 is covered on electrode, and is covered on graphene film 203 and nanoscale coating circuit 202.
Embodiment 3
It is big by the use of single-layer graphene prepared by mechanical stripping method as induction graphene with reference to Fig. 2, Fig. 3, Fig. 5 and Fig. 6
The grapheme platelet of area development, small pieces graphene film 307 is transferred on interim growth flexible substrate copper foil and induces graphite
Alkene film 203 grows.The copper foil substrate for there are graphene film small pieces is placed in sputtering chamber, using laser pulse by carbon atom from admittedly
Be splashed in body carbon source target on copper foil substrate, so as to small pieces graphene film 307 be starting point in copper foil Grown stone
Black alkene film 203.
Graphene film 203 is transferred in flexible substrate 205 using chemical etching and printing transferring method again, for by graphene film
203 processes separated with temporary substrates, the adhensive membrane 204 in flexible substrate 205 include PVB or ethyl cellulose etc., will
Graphene film 203 on temporary substrates overlaps with the adhensive membrane 204 in flexible substrate 205, forms cohesive body；Remove above-mentioned face
When substrate copper foil, to obtain the graphene film 203 in the flexible substrate 205.Graphene film 203 bonds with flexible substrate 205
, it is necessary to using as the copper foil separation of temporary substrates after together, the graphene film 203 being so grown on copper foil is just complete
It is transferred on target flexibility substrate 205.High by the purity of graphene film 203 obtained by methods described, area is big.
The manufacturing process of nanoscale coating circuit 202 is：The graphene film 203 being adhered in flexible substrate 205 is made
Magnetron sputtering apparatus is put into for a substrate 501 and carries out nanoscale coating sputtering, the substrate of copper film 503 will be covered through sputtering
501 are sent into forcing press 506, and in the presence of impressing mould 504, two spaced apart from each other, sizes have been laminated on the substrate 501
Different copper films 503.The impressing mould 504 not only sets a stamping structure 505 in the region on copper film 503, and
Also there is a stamping structure 505 in the region outside the film 503, can be the micro-structural 502 shown in Fig. 6, outstanding
It is that a kind of fluid micro-structural 502 is incorporated into substrate 501.The impressing mould 504 forms one admittedly on a substrate 501 simultaneously
Determine structure 514, the fixed structure 514 can be used for the hygrosensor 101 of fixed temperature monitoring portion, the intelligent dress ornament data
The Monitoring Data of hygrosensor 101 that processing unit gone out based on fixed structure 514 is collected to control the graphite of the intelligent dress ornament
Alkene fever tablet 108 is generated heat, wherein, for positioning the fixed structure 514 in the temperature monitoring portion and the microcosmic knot of the substrate 501
Structure 502 is formed in same procedure, and the forming process of the fixed structure 514 and the microstructure 502 is to press
Formed in moulding process of stamp tool 504, this causes in commercial process, realizes the fixed structure 514
With the Quick-forming of the microstructure 502, nanoscale coating circuit 202 is improved into production speed.As shown in fig. 6, the copper film
503 form three-dimensionally shaped, mutually insulated printed conductor or circuit.Each printed conductor 507 have one it is flat, close
In micro-structural 502 is raised setting and extends to inside drawing printed conductor plane 508 and at least one and printing
The angled printed conductor side wall 509 set of wire plane 508., it can be seen that according to printed conductor 507 on the substrate 501
Arrangement depending on, more specifically according to impressing micro-structural 502 arrangement depending on, a unique printed conductor plane
508 either with a unilateral printed conductor side wall 509 or with two Longitudinal extendings for being transverse to printed conductor 507
Direction and printed conductor side wall 509 spaced apart from each other.The printed conductor side wall 509 extends to the substrate trenches 510 of micro-structural 502
In (namely on impressing mould direction), but do not reach respective substrate channel bottom 511.As shown in fig. 6, each two phase
Adjacent printed conductor plane 508 is at least approximately arranged in identical height or plane, and by horizontal interval and mutual
Electric insulation.
As shown in fig. 6, the micro-structural has multiple (raised substrates of substrate plane 512 spaced apart from each other, flat, raised
Section), wherein in the raised upper part of the substrate plane 512 impressing printed conductor plane 508 (raised printed conductor section).
On the side of raised substrate plane 512, backwards to impressing mould extension, difference is connected with the direction for entering substrate 501
Substrate trenches 510 with two substrate side walls 513.Corresponding two adjacent substrate side walls 513 are in affiliated substrate trenches bottom 511
Place is intersecting.Substrate side wall 513 is used as the loading end of printed conductor side wall 509, wherein substrate side wall 513 from the printed conductor side wall
509 start to upwardly extend in the side of substrate trenches bottom 511 belonging to.
In region between two adjacent, mutually relative printed conductor side walls 509, do not have on the substrate 501
There is remaining copper film 503.This will not cause to remove residual copper film section 503 from the substrate 501 after the moulding process.So as to
Whole copper films 503 are all that electricity is available, the increase of printed conductor section, and current capacity improves.
Printed electrode on above-mentioned printed conductor and form nanoscale coating circuit 202, more precisely, above by electricity
Extremely connected printed conductor forms a nanoscale coating parallel circuit, and by the electrode for realizing nanoscale coating
Circuit 202 electrically connects with conductive fiber.In above-mentioned printed on electrodes overcoat 201, the overcoat 201 is epoxy resin, tool
There are insulation, waterproof, anti-scratch ability.The overcoat 201 is covered on electrode, and is covered in graphene film 203 and nanoscale
On coating circuit 202.Because the micro-structural 502 that graphene film 203 has, expands the surface area of graphene film 203, increases
The adhesive strength of overcoat 201 and graphene film, improves protection effect, while improve nanoscale coating circuit 202 and stone
The contact compactness of black alkene film 203, increase the electric conductivity of graphene film 203.
It should be noted that above-mentioned specific embodiment is exemplary, those skilled in the art can disclose in the present invention
Various solutions are found out under the inspiration of content, and these solutions also belong to disclosure of the invention scope and fall into this hair
Within bright protection domain.It will be understood by those skilled in the art that description of the invention and its accompanying drawing are illustrative and are not
Form limitations on claims.Protection scope of the present invention is limited by claim and its equivalent.
Claims (10)
1. a kind of graphene intelligence dress ornament, it is characterised in that the intelligent dress ornament includes temperature monitoring portion, with polyester, polypropylene
Or polyamide polymer fiber weaving cloth is graphene fever tablet (108) and Data Collection processing unit prepared by substrate；
Graphene fever tablet (108) in flexible substrate (205) including setting in the small pieces graphene film through mechanical stripping
(307) through the solid carbon source graphene film (203) that generates of sputtering mode and with graphene film (203) it is substrate warp on the basis of
The nanoscale coating circuit (202) that sputtering mode generates；
The intelligent dress ornament data collection process portion is based on the temperature sensing in the fixed structure (514) on substrate (501)
The Monitoring Data of device (101) controls the graphene fever tablet (108) of the intelligent dress ornament to generate heat, wherein, it is described for positioning
The fixed structure (514) of temperature monitoring portion hygrosensor (101) is conductive and adhesive force micro- for improving with substrate (501)
Structure (502) is formed in same procedure；
Wherein, the micro-structural (502) has multiple raised substrate planes (512) spaced apart from each other, flat, wherein described convex
Substrate plane (512) upper part impressing printed conductor plane (508) is played, on the side of the raised substrate plane (512),
Substrate backwards to impressing mould extension, that there is two substrate side walls (513) respectively is connected with into the direction of substrate (501)
Groove (510), corresponding two adjacent substrate side walls (513) are intersected at affiliated substrate trenches bottom (511) place, the substrate side wall
(513) be used as printed conductor side wall (509) loading end, the substrate side wall (513) since printed conductor side wall (509)
Substrate trenches bottom (511) just upwardly extends belonging to.
2. graphene intelligence dress ornament as claimed in claim 1, it is characterised in that described to sputter what mode generated through solid carbon source
Graphene film (203) is thin to choose a small pieces graphene from the small pieces graphene film of the generation through mechanical stripping in advance
Film (307), described small pieces graphene film (307) is transferred on temporary flexible substrate as induction graphene film (203)
The starting point of growth, solid carbon source is used through sputtering for starting point with small pieces graphene film (307) on the temporary flexible substrate
Mode generates graphene film (203).
3. graphene intelligence dress ornament as claimed in claim 1 or 2, it is characterised in that the small pieces generated through mechanical stripping
The production procedure of graphene film (307) is：
High-temperature process portion (302) is connected with in-situ reducing portion (303), is added under the conditions of being 200 DEG C~1200 DEG C in treatment temperature
Nitrogen or inert gas carry out high-temperature process to graphite raw material (301)；
The in-situ reducing portion (303) is connected by the first feeding-passage (402) with mechanical stripping portion (400), is received described in warp
Graphite raw material (301) after high-temperature process portion (302) processing, under 200 DEG C~1200 DEG C temperature conditionss, add nitrogen or hydrogen
At least one of be used as reducing medium, to graphene raw material (301) carry out reduction treatment, and by after processing raw material be sent into machine
Tool stripping portion (400)；
Dosing portion (304) is connected by the second feeding-passage (403) with the mechanical stripping portion (400), the dosing portion (304)
For depositing surfactant additive, and in the mechanical stripping portion (400) carries out stripping process to graphite raw material (301),
Continue cylindrical chamber (401) dosing to mechanical stripping portion (400)；
The cylindrical chamber (401) of the mechanical stripping portion (400) passes through the first feeding-passage (402) and in-situ reducing portion
(303) it is connected, the cylindrical chamber (401) of the mechanical stripping portion (400) passes through the second feeding-passage (403) and dosing portion
(304) it is connected, rotary shaft (404) is placed in cylindrical chamber (401) with rotating horizontal pole (405) vertical connection, abrading-ball (406)
In the cylindrical chamber (401), the abrading-ball (406) is the pearl that 50 μm~100 μm of diameter and hardness are more than graphite；It is described
The cylindrical chamber (401) in mechanical stripping portion (400) is connected by discharging channel (407) with centrifugation portion (305)；
In the in-situ reducing portion (303) graphite raw material (301) and the dosing portion are added to the cylindrical chamber (401)
(304) after adding surfactant additive to the cylindrical chamber (401), the rotary shaft (404) drives square with the axis phase
Rotating horizontal pole (405) even stirs in fixed cylindrical chamber (401), and rotating horizontal pole (405) drives cavity in agitation
Interior abrading-ball (406) and graphite raw material (301) mutually collision and friction, graphite raw material (301) cutting in the abrading-ball frictional force
Cut under effect, the Van der Waals force of each graphite layers is disintegrated in graphite, obtains the suspension of graphene and graphite；
The cylindrical chamber (401) of the mechanical stripping portion (400) is by discharging channel (407) by the suspended of graphene and graphite
Liquid is sent into centrifugation portion (365), through centrifugation portion (305) centrifugal treating, obtains graphene suspension, and be sent into dry
Processing is dried in dry portion (306), obtains small pieces graphene film (307).
4. graphene intelligence dress ornament as claimed in claim 1, it is characterised in that the nanoscale coating circuit (202) is will
The graphene film (203) being adhered in flexible substrate (205) with circuit die is put into magnetron sputtering apparatus as base material and entered
Row nanoscale coating sputters.
5. graphene intelligence dress ornament as claimed in claim 1, it is characterised in that the nanoscale coating circuit (202) is：
Sputtering generation copper film on the graphene film (203) in flexible substrate (205) is adhered to, then by imprinting mode, generates nanoscale
Coating circuit (202).
6. the graphene intelligence dress ornament as described in claim 4 or 5, it is characterised in that the coating sputter procedure magnetron sputtering
In 0.13Pa~0.20Pa, base material temperature target and base material distance 5cm~10cm, splashes less than 50 DEG C for instrument sputtering operating pressure control
5 °~8 ° of firing angle, sputtering power 100W~200W, sputtering zinc coat thickness control is 50nm~300nm, using base material in upper sputtering
Target structure.
7. the graphene intelligence dress ornament as described in claim 4 or 5, it is characterised in that be adhered to flexible substrate (205) to described
Graphene film (203) be put into plasma processor, using oxygen, it is laggard under conditions of 50 watts of power to carry out pretreatment in 60 seconds
Row sputter process, sputtering target material include metallic aluminium, copper or silver.
8. graphene intelligence dress ornament as claimed in claim 1, it is characterised in that will be conductive fine using the method for cored and looping
Yarn is made in dimension, is woven into polyester, polypropylene or polyamide polymer fiber weaving cloth fabric.
9. graphene intelligence dress ornament as claimed in claim 1, it is characterised in that the temperature monitoring portion includes hygrosensor
(101) it is connected with distributed A/D acquisition modules (102), the temperature monitoring portion by conductive fiber with data collection process portion；
It is defeated that data collection process portion includes single-chip microcomputer (103), wireless data transmitter (104), mobile terminal (105), distributed digital
Enter output module (106) and power conditioning module (107), the data collection process portion is generated heat by conductive fiber and graphene
Piece (108) is connected.
10. graphene intelligence dress ornament as claimed in claim 1, it is characterised in that examined to graphene fever tablet (108), temperature
Survey portion, data collection process portion use epoxy encapsulation, conductive fiber and temperature monitoring portion, data collection process portion and graphite
Alkene fever tablet (108) coupling part rubber or plastic consolidation waterproof.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511025777.4A CN105506812B (en) | 2015-12-31 | 2015-12-31 | A kind of graphene intelligence dress ornament |
| CN201710937950.0A CN107734722B (en) | 2015-12-31 | 2015-12-31 | Graphene heating sheet and preparation method thereof |
| CN201710939461.9A CN107675137B (en) | 2015-12-31 | 2015-12-31 | A kind of graphene film and preparation method thereof with three-dimensionally shaped printed conductor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511025777.4A CN105506812B (en) | 2015-12-31 | 2015-12-31 | A kind of graphene intelligence dress ornament |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710937950.0A Division CN107734722B (en) | 2015-12-31 | 2015-12-31 | Graphene heating sheet and preparation method thereof |
| CN201710939461.9A Division CN107675137B (en) | 2015-12-31 | 2015-12-31 | A kind of graphene film and preparation method thereof with three-dimensionally shaped printed conductor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105506812A CN105506812A (en) | 2016-04-20 |
| CN105506812B true CN105506812B (en) | 2018-01-23 |
Family
ID=55715099
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511025777.4A Active CN105506812B (en) | 2015-12-31 | 2015-12-31 | A kind of graphene intelligence dress ornament |
| CN201710937950.0A Active CN107734722B (en) | 2015-12-31 | 2015-12-31 | Graphene heating sheet and preparation method thereof |
| CN201710939461.9A Active CN107675137B (en) | 2015-12-31 | 2015-12-31 | A kind of graphene film and preparation method thereof with three-dimensionally shaped printed conductor |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710937950.0A Active CN107734722B (en) | 2015-12-31 | 2015-12-31 | Graphene heating sheet and preparation method thereof |
| CN201710939461.9A Active CN107675137B (en) | 2015-12-31 | 2015-12-31 | A kind of graphene film and preparation method thereof with three-dimensionally shaped printed conductor |
Country Status (1)
| Country | Link |
|---|---|
| CN (3) | CN105506812B (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105962704A (en) * | 2016-04-28 | 2016-09-28 | 李仕会 | Far-infrared photo-thermal blanket |
| CN105901780A (en) * | 2016-05-04 | 2016-08-31 | 曾新民 | Manufacturing method for uterus warming healthcare briefs containing graphene and used for women |
| CN105898907A (en) * | 2016-06-12 | 2016-08-24 | 杭州白熊科技有限公司 | Graphene heating film and preparation method thereof |
| CN106473251A (en) * | 2016-06-29 | 2017-03-08 | 龙彩霞 | The electroluminescent health clothing of Graphene |
| CN108260887A (en) * | 2017-12-30 | 2018-07-10 | 东莞市明骏智能科技有限公司 | A kind of carbon nanotube electric heating assembly, electric heating insole and Electrothermal shoes |
| CN109089339A (en) * | 2018-07-24 | 2018-12-25 | 董哲源 | A kind of glass deicing demister |
| CN109246869A (en) * | 2018-08-06 | 2019-01-18 | 利辛县飞亚强磁性软纱门有限公司 | Electric heat generating fiber film and the preparation method and application thereof |
| CN109275210B (en) * | 2018-10-12 | 2021-02-09 | 重庆墨希科技有限公司 | High-reliability heating film based on graphene and preparation method thereof |
| TWI689225B (en) * | 2018-11-21 | 2020-03-21 | 國立清華大學 | Micro-scale wireless heater and fabrication method and applications thereof |
| CN109600866B (en) * | 2018-12-27 | 2024-05-28 | 中国科学院山西煤炭化学研究所 | Graphene infrared heating plate |
| CN110027272B (en) * | 2019-04-18 | 2021-02-02 | 五邑大学 | Intelligent textile based on thermal positioning |
| CN111276295A (en) * | 2020-02-20 | 2020-06-12 | 上海超碳石墨烯产业技术有限公司 | Preparation method of graphene primary coated copper wire |
| CN112804775A (en) * | 2021-01-18 | 2021-05-14 | 安徽宇航派蒙健康科技股份有限公司 | Method for preparing electrothermal film by adopting transparent graphene |
| CN113104809A (en) * | 2021-04-08 | 2021-07-13 | 德州学院 | Method for preparing graphene nano-net by utilizing patterned substrate for imprinting |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100469220C (en) * | 2007-06-14 | 2009-03-11 | 江南大学 | A method for making elastic circuit with the non-weaving cloth as base |
| DE102008040882A1 (en) * | 2008-07-31 | 2010-02-04 | Robert Bosch Gmbh | Method for hot embossing at least one printed conductor on a substrate, substrate with at least one printed conductor and embossing stamp |
| CN101913598B (en) * | 2010-08-06 | 2012-11-21 | 浙江大学 | Method for preparing graphene membrane |
| CN102796991B (en) * | 2011-05-27 | 2014-08-20 | 清华大学 | Method for preparing graphene carbon nanotube composite membrane structure |
| CN102897750B (en) * | 2011-07-29 | 2014-09-10 | 浙江大学 | PrPrearation method for graphene film |
| KR101436911B1 (en) * | 2012-04-25 | 2014-09-02 | 그래핀스퀘어 주식회사 | Patterning method of graphene using hot embossing imprinting |
| CN102659096A (en) * | 2012-04-27 | 2012-09-12 | 湖南大学 | Preparation methods of graphene dispersion solution and thin film of graphene |
| CN102883486B (en) * | 2012-09-28 | 2014-09-24 | 江苏物联网研究发展中心 | Graphene based transparent electric heating film and production method thereof |
| WO2014171030A1 (en) * | 2013-04-19 | 2014-10-23 | 株式会社インキュベーション・アライアンス | Carbon fiber and method for producing same |
| US9546294B2 (en) * | 2013-04-19 | 2017-01-17 | Incubation Alliance, Inc. | Carbon fiber and method for producing same |
| CN104176727B (en) * | 2013-05-28 | 2016-04-06 | 安炬科技股份有限公司 | Graphene aaerosol solution and preparation method thereof |
| CN103393237B (en) * | 2013-08-19 | 2015-05-13 | 青岛大学 | Thermoregulation garment |
| CN104585913B (en) * | 2013-11-01 | 2016-07-06 | 武汉飞恩微电子有限公司 | There is the human body air conditioner intelligent wear of infrared stealth function and waterproof and breathable |
| CN103991868B (en) * | 2014-06-13 | 2016-04-27 | 广东石油化工学院 | A kind of preparation method of Graphene |
| CN104498902B (en) * | 2014-12-12 | 2016-10-19 | 中国科学院重庆绿色智能技术研究院 | A kind of preparation method of aumospheric pressure cvd graphene film |
| CN104739403B (en) * | 2015-04-10 | 2017-08-25 | 中国科学院重庆绿色智能技术研究院 | Graphene nano wall flexibility electrocardioelectrode and preparation method thereof |
| CN104902594B (en) * | 2015-06-01 | 2017-01-18 | 深圳烯旺新材料科技股份有限公司 | Intelligent temperature control thermal underwear |
-
2015
- 2015-12-31 CN CN201511025777.4A patent/CN105506812B/en active Active
- 2015-12-31 CN CN201710937950.0A patent/CN107734722B/en active Active
- 2015-12-31 CN CN201710939461.9A patent/CN107675137B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN107734722A (en) | 2018-02-23 |
| CN105506812A (en) | 2016-04-20 |
| CN107734722B (en) | 2021-04-06 |
| CN107675137B (en) | 2019-03-19 |
| CN107675137A (en) | 2018-02-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105506812B (en) | A kind of graphene intelligence dress ornament | |
| CN208572471U (en) | A kind of graphene electrical heating bag | |
| CN108848586A (en) | A kind of wearable heating sheet of far-infrared flexible, preparation method and application | |
| CN105727451A (en) | Far infrared therapeutic device system | |
| CN204864563U (en) | Electrode paster of utensil complex function | |
| CN110418444A (en) | A kind of graphene electrical heating bag | |
| CN201114783Y (en) | Heating body structure with remote infrared function | |
| CN208783122U (en) | A kind of wearable heating sheet of far-infrared flexible and intelligent heating clothes | |
| CN106350998A (en) | Graphene far-infrared magnet therapy base cloth preparation technology | |
| CN106714344A (en) | Graphene electric heating fabric provided with magnet | |
| CN204121608U (en) | A kind of nano-far-infrared Intelligent physiotherapeutic device | |
| CN201862151U (en) | Far infrared heating membrane | |
| CN210169166U (en) | Sterilization and heating physiotherapy insole made of graphene composite material | |
| CN210960459U (en) | Intelligence far infrared physiotherapy brassiere | |
| CN209732734U (en) | Graphite alkene far infrared shoe-pad that generates heat | |
| CN107280959A (en) | Infrared paster for human acupuncture points | |
| CN206342002U (en) | A kind of waist support with the electric heating fabric of graphene | |
| CN109567314B (en) | Graphite alkene far infrared intelligence wireless charging shoe-pad that generates heat | |
| CN201585153U (en) | Infrared ray heating plate | |
| CN112004274A (en) | Titanium nano sheet/graphene-based heating film | |
| CN219595406U (en) | Intelligent wearable breast pump with physiotherapy effect | |
| CN112021893A (en) | Palladium nanosheet/graphene-based hot compress medicine pillow | |
| CN208770694U (en) | A kind of wear-type far infrared device | |
| CN205142554U (en) | Far infrared electric floor heating leather | |
| CN205180951U (en) | Physiotherapy quilt |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |