CN105505492B - 一种高效稳定的生物柴油复合添加剂 - Google Patents

一种高效稳定的生物柴油复合添加剂 Download PDF

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CN105505492B
CN105505492B CN201610002732.3A CN201610002732A CN105505492B CN 105505492 B CN105505492 B CN 105505492B CN 201610002732 A CN201610002732 A CN 201610002732A CN 105505492 B CN105505492 B CN 105505492B
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biodiesel
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车春玲
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Linyi Xinghuo Intellectual Property Service Co.,Ltd.
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Abstract

本发明属于燃料油添加剂领域，特别涉及一种高效稳定的生物柴油复合添加剂。所述的高效稳定的生物柴油复合添加剂是由助溶剂、油酸、环氧硬脂酸丁酯、双烷基磷酸、抗氧化剂、分散剂、清洁剂、助燃剂组成。本发明可以使生物柴油凝固温度降低很多度，使生物柴油保持良好的低温流动性能，方便柴油的储运和使用；也可有效清洁柴油机上的积碳，保持油路畅通，从而提高柴油机的燃烧性能和经济性能，具有环保节能效果。本发明原料易得，制备工艺简单，操作方便，成本低廉。

Description

一种高效稳定的生物柴油复合添加剂
技术领域
本发明属于燃料油添加剂领域，尤其涉及一种高效稳定的生物柴油复合添加剂。
背景技术
随着我国现代化建设步伐的加快，对能源的需求快速上升，受我国煤炭、石油等资源储量及开采能力的限制，我国正面临着能源供应短缺的局面，与此同时，我国的经济发展模式延续了以大量消耗能源为基础的传统发展模式，使经济活动索取资源的速度远远超过资源本身的再生速度。柴油作为一种重要的燃料，由于其本身具有动力大，价格低等优点，已成为大型设备的主要动力燃料。目前应用的柴油主要是从石油中提炼的石油柴油，石油柴油在应用过程中相对于其它燃料存在着燃烧性能低，二氧化碳排放量比较大，空气污染严重等问题。随着柴油需求量的不断增大，矿物能源的日益枯竭和环保意识的逐步提高，新型环保燃料受到人们的重视和关注。
生物柴油（Biodiesel），是指由动植物油脂（主要指脂肪酸甘油三酯）通过不同的化学反应得到的反应得到的脂肪酸单烷基酯，最典型的是脂肪酸甲酯。生物柴油的物理和化学性质与传统的石化柴油非常相似；同时与传统的石化柴油相比，生物柴油的硫及芳烃含量低、闪点高、十六烷值高、具有良好的润滑性等优点，是传统石化燃料的理想替代能源，并已经在世界范围内得到广泛应用。目前市场上通常所述的生物柴油，大多是在油酸甲酯主体基础上添加助燃剂而成，存在凝点高、冷滤点高、腐蚀性强及性价比不足的缺陷，急需一种可改善其燃烧性能尤其是压燃性能、提高其综合性价比，高效稳定的添加剂。
发明内容
本发明的目的在于：针对上述存在的问题，提供一种可改善其燃烧性能尤其是压燃性能、提高其综合性价比，高效稳定清洁的添加剂，其特征在于，有以下重量份数的原料组成：
助溶剂 40—60份
油酸10—20份
环氧硬脂酸丁酯 5—8份
双烷基磷酸 5—15份
抗氧化剂 1—5份
分散剂 5—15份
清洁剂 5—15份
助燃剂 10—15份
上述配比中所述的助溶剂由异丁醇：丙酮：正己烷=5:3:2质量配比组成。
上述配比中所述的抗氧剂由N,N'-二亚水杨基丙二胺：2,6-二叔丁基-4-甲酚=2:1质量配比组成。
上述配比中所述的分散剂为乙烯基双硬脂酰胺、硬脂酸单甘油酯、三硬脂酸甘油酯中的一种或几种。
上述配比中所述的清洁剂由石油磺酸钡：乙二醇烷基苯醚=1:1质量配比组成。
上述配比中所述的助燃剂由多乙烯多胺醇胺：二异丙基醚∶混合轻芳烃＝2:3:5质量配比组成。
本发明具有如下有益效果：（1）本发明制备的添加剂可以使生物柴油凝固温度降低很多度，使生物柴油保持良好的低温流动性能，方便柴油的储运和使用；（2）本发明制备的添加剂燃烧后不会产生有毒烟气，可有效清洁柴油机上的积碳，保持油路畅通，从而提高柴油机的燃烧性能和经济性能；具有环保节能效果；（3）本发明制备工艺简单，操作方便，成本低廉。
具体实施方式
实施例1
助溶剂40份
油酸 20份
环氧硬脂酸丁酯 5份
双烷基磷酸 5份
抗氧化剂 5份
分散剂 5份
清洁剂 5份
助燃剂 15份
称取质量配比为异丁醇：丙酮：正己烷=5:3:2助溶剂40份、油酸20份、环氧硬脂酸丁酯5份、双烷基磷酸5份、由N,N'-二亚水杨基丙二胺：2,6-二叔丁基-4-甲酚=2:1质量配比组成抗氧化剂5份、乙烯基双硬脂酰胺5份、由石油磺酸钡：乙二醇烷基苯醚=1:1质量配比组成清洁剂5份、由多乙烯多胺醇胺：二异丙基醚∶混合轻芳烃＝2:3:5质量配比组成助燃剂15份，，将原料依次加入反应釜中，进行加热，待组分加热至30℃时，搅拌30 分钟，搅拌均匀后即得。
实施例2
助溶剂40份
油酸15份
环氧硬脂酸丁酯8份
双烷基磷酸5份
抗氧化剂2份
分散剂10份
清洁剂5份
助燃剂15份
称取质量配比为异丁醇：丙酮：正己烷=5:3:2助溶剂40份、油酸15份、环氧硬脂酸丁酯8份、双烷基磷酸5份、由N,N'-二亚水杨基丙二胺：2,6-二叔丁基-4-甲酚=2:1质量配比组成抗氧化剂2份、硬脂酸单甘油酯10份、由石油磺酸钡：乙二醇烷基苯醚=1:1质量配比组成清洁剂5份、由多乙烯多胺醇胺：二异丙基醚∶混合轻芳烃＝2:3:5质量配比组成助燃剂15份，，将原料依次加入反应釜中，进行加热，待组分加热至30℃时，搅拌30 分钟，搅拌均匀后即得。
以上述依据本发明的理想实施例为启示，通过上述的说明内容，相关工作人员完全可以在不偏离本项发明技术思想的范围内，进行多样的变更以及修改。本项发明的技术性范围并不局限于说明书上的内容，必须要根据权利要求范围来确定其技术性范围。

Claims (4)

1.一种高效稳定的生物柴油复合添加剂，其特征在于，有以下重量份数的原料组成：
助溶剂 40—60份
油酸 10—20份
环氧硬脂酸丁酯 5—8份
双烷基磷酸 5—15份
抗氧化剂 1—5份
分散剂 5—15份
清洁剂 5—15份
助燃剂 10—15份；
所述的清洁剂由石油磺酸钡：乙二醇烷基苯醚＝1:1质量配比组成；
所述的助燃剂由多乙烯多胺醇胺：二异丙基醚∶混合轻芳烃＝2:3:5质量配比组成。
2.根据权利要求1所述的一种高效稳定的生物柴油复合添加剂，其特征在于所述的助溶剂由异丁醇：丙酮：正己烷＝5:3:2质量配比组成。
3.根据权利要求1所述的一种高效稳定的生物柴油复合添加剂，其特征在于所述的抗氧剂由N,N'-二亚水杨基丙二胺：2,6-二叔丁基-4-甲酚＝2:1质量配比组成。
4.根据权利要求1所述的一种高效稳定的生物柴油复合添加剂，其特征在于所述的分散剂为乙烯基双硬脂酰胺、硬脂酸单甘油酯、三硬脂酸甘油酯中的一种或几种。
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