A kind of new type power distribution box
Technical field
The invention belongs to distribution box preparation fields, and in particular to a kind of new type power distribution box.
Background technology
Distribution box is the magnanimity parameter in data, usually forms low pressure woods and presses electrical wiring, it is desirable that by switchgear, is surveyed
Amount instrument, protection electric appliance and ancillary equipment are assembled in closing or semiclosed metal safe or in screen width, form low-tension distribution box.Just
It often can be by manual or automatic switch connection or disjunction circuit during operation.Distribution box is convenient to electricity for reasonably distributing electric energy
The switching action on road.There are higher class of safety protection, the conducting state of the intuitive display circuit of energy.
The phenomenon that electrostatic is a kind of accumulation due to the generations such as contact or rub, in daily life, due to weather, ring
Border, physical influence can generate electrostatic, and the presence of electrostatic can bring harm to metal device, even result in stability and decline appearance
The serious harms such as the generations burning such as the defects of instrument failure or metallic oil pipeline or explosion.
Antistatic coating is with conductive and exclusion accumulation electrostatic charge ability functional coating.Antistatic coating is with existing
In generation, is scientific and technical and develops, and there are about the developing histories of over half a century so far.Early in 1948, the U.S. was disclosed silver and epoxy
The patent of conducting resinl is made in resin, this is earliest disclosed conductive coating.The 1950s Japan start production with silver system and
Anti-static coatings based on carbon system.The 1960s American and Britain, Deng states develop antistatic coating in succession.80 years 20th century
Generation external antistatic technique and electric-heating coatings technology are rapidly developed, and China also begins one's study and applies in the 1950s
Antistatic coating.
Antistatic coating is divided into two class of addition type and Intrinsical, and Intrinsical antistatic coating technology is still immature, therefore mesh
The preceding antistatic coating largely used is generally addition type coating.Addition type antistatic coating is in nonconducting binder resin
The function that certain conductive filler realizes static conductive is added, the volume fraction of only conductive filler reaches certain degree could shape
Into conductive network or access, conductive property is embodied.Common conductive filler has:Carbon-based material (carbon black, graphite etc.), metal
Powder (silver powder, copper powder, nickel powder etc.), metal oxide semiconductor (tin oxide, iron oxide, zinc oxide), conducting nanoparticles and
Antistatic auxiliary agent etc..Wherein metal powder density is big, and forming conductive path needs larger volume fraction, and surface layer is oxidizable, meeting
It reduces and even loses electric conductivity, and poor corrosion resistance, so as to influence other performances of coating, therefore metal powder is as conductive
The application of filler is subject to certain restrictions;Antistatic agent temperature tolerance, water resistance, oil resistivity, corrosion resistance, durability are poor, antistatic
Performance is unstable;Early stage antistatic coating is generally using carbon-based material as conductive filler, black conductive graphite and carbon black dispersion
Property is poor, and product color is black, it is not easy to be modulated to other shallower colors;With the development of science and technology, semiconductor gold is gradually appeared
Belong to the novel conductive fillers such as oxide and nanometer conductive powder, and applied in antistatic coating, this kind of material color is shallow, easily
In toning, enrich the colour system of antistatic coating, but additive amount is big when this kind of material is used alone, dispersion stabilization compared with
Difference, can influence coating and and its coating performance, therefore be generally used cooperatively with carbon-based material.Occur in recent years using conductive
Antistatic coating of the fiber as conductive filler, since conductive fiber diameter is small, draw ratio is big, it is only necessary to minimal amount of conductive fiber
Conductive network can be just formed in the coating, can reduce the influence to other performances of coating.
Invention content
Present invention aim to address existing deficiencies, are improved by a large amount of creative works, prepare a kind of new type power
Distribution box.
To achieve these goals, cubicle switch of the present invention including babinet and case lid, contains illumination in the babinet
Device, the case lid side are equipped with push switch, set observation panel on the case lid, the observation panel transparent plastic,
It is characterized in that, coat antistatic coating outside the babinet and case lid;
The antistatic coating is prepared by the raw material of following parts by weight:
It is modified poly-(3,4- ethene dioxythiophenes)6-8 parts of polystyrolsulfon acid, aromatic urethane acrylate 17-20
Part, 10-13 parts of organic siliconresin, 10-15 parts of dimethylaminoethyl acrylate, 45-50 parts of diluent, triallyl isocyanuric acid
1-2 parts of ester, 0.5-0.8 parts of levelling agent, 15-20 parts of graphene, 5-7 parts of magnesium chloride, 5-7 parts of nano-silver powder, organobentonite
0.5-1 parts.
The modification gathers(3,4- ethene dioxythiophenes)The preparation method of polystyrolsulfon acid is as follows:
Under conditions of temperature is 35 DEG C, sulfonated graphene, 3,4-rthylene dioxythiophene and polyethylene glycol are dispersed in
In ionized water, make a concentration of 0.05wt% of contained polyethylene glycol in the mixed system to be formed, and sulfonated graphene, 3,4- ethylene
Dioxy thiophene, the mass ratio of polyethylene glycol is 2:3:0.1, then the pH value of the mixed system is adjusted to 4.5, and with 500 turns/
The speed of min is stirred, while adds in oxidant and catalyst, wherein the mass ratio of oxidant and 3,4-rthylene dioxythiophene
It is 1:2, the mass ratio 0.01 of catalyst and 3,4-rthylene dioxythiophene:1,10-72h is then persistently stirred to react, is removed later
Foreign ion in reaction product mixture to get;
The diluent is:Water:Isopropanol:Ethyl alcohol(Volume ratio)=1:7:1;
The levelling agent is:Dimethyl silicone polymer
It will be modified poly-(3,4- ethene dioxythiophenes)Polystyrolsulfon acid is sheared in high speed dispersor high speed to be disperseed, and is turned
1000 turns/min of speed stirs 60min, successively by aromatic urethane acrylate, organic siliconresin, acrylate second
Ester, diluent, Triallyl isocyanurate, levelling agent, graphene, magnesium chloride, nano-silver powder, organobentonite are added thereto
Be uniformly mixed, stir 15-60min, after 200 mesh filter screen filtrations to get.
The present invention has good collective effect, and an effect stability using graphene anti-corrosion, with photocuring system, during effect
Effect length;
The present invention uses nano-silver powder and nano silver antimicrobials synergy, when having stronger antibacterial effect, and continuing
Between it is long, with photocuring system have good compatibility;
Modification prepared by the present invention gathers(3,4- ethene dioxythiophenes)Polystyrolsulfon acid can not only meet anlistatig
It is required that and there is good compatibility, dilution oligomer, regulation system viscosity with photocuring system.
It is mutually coordinated between each component material of the present invention, pass through big change of variable condition, parameter, by Dan Yin for the applicant
Son experiment, factorial experiment obtain, and the application operating parameter is operated through creative work for inventor and obtained, the coating prepared
There is self assembly characteristic after film forming curing, can freely spread in substrate, and build high-effective conductive network, make coating surface
With high transparency, high conductivity and stability, while it can also make that there is better mechanical property after curing of coatings, particularly
There is activeness and quietness effect and high-wearing feature, make it have better antistatic durability, while have excellent resistance to
Corrosive nature.
Specific embodiment
Embodiment 1
A kind of new type power distribution box including babinet and case lid, contains lighting device, the case lid one in the babinet
Side is equipped with push switch, and observation panel is set on the case lid, and the observation panel is transparent plastic,
It is characterized in that, coat antistatic coating outside the babinet and case lid;
The antistatic coating is prepared by the raw material of following parts by weight:
It is modified poly-(3,4- ethene dioxythiophenes)6 parts of polystyrolsulfon acid, has 17 parts of aromatic urethane acrylate
10 parts of machine silicones, 10 parts of dimethylaminoethyl acrylate, 45 parts of diluent, 1 part of Triallyl isocyanurate, levelling agent
0.5 part, 15 parts of graphene, 5 parts of magnesium chloride, 5 parts of nano-silver powder, 0.5 part of organobentonite.
The modification gathers(3,4- ethene dioxythiophenes)The preparation method of polystyrolsulfon acid is as follows:
Under conditions of temperature is 35 DEG C, sulfonated graphene, 3,4-rthylene dioxythiophene and polyethylene glycol are dispersed in
In ionized water, make a concentration of 0.05wt% of contained polyethylene glycol in the mixed system to be formed, and sulfonated graphene, 3,4- ethylene
Dioxy thiophene, the mass ratio of polyethylene glycol is 2:3:0.1, then the pH value of the mixed system is adjusted to 4.5, and with 500 turns/
The speed of min is stirred, while adds in oxidant and catalyst, wherein the mass ratio of oxidant and 3,4-rthylene dioxythiophene
It is 1:2, the mass ratio 0.01 of catalyst and 3,4-rthylene dioxythiophene:1,10h is then persistently stirred to react, removes mixing later
Foreign ion in reaction product to get;
The diluent is:Water:Isopropanol:Ethyl alcohol(Volume ratio)=1:7:1;
The levelling agent is:Dimethyl silicone polymer
It will be modified poly-(3,4- ethene dioxythiophenes)Polystyrolsulfon acid is sheared in high speed dispersor high speed to be disperseed, and is turned
1000 turns/min of speed stirs 60min, successively by aromatic urethane acrylate, organic siliconresin, acrylate second
Ester, diluent, Triallyl isocyanurate, levelling agent, graphene, magnesium chloride, nano-silver powder, organobentonite are added thereto
Be uniformly mixed, stir 15-60min, after 200 mesh filter screen filtrations to get.
After brushing paint, distribution box surface of the present invention without skinning and lump phenomenon, can rapid curing drying, it is environment-protecting and non-poisonous,
It is not tacky, do not return viscous, scratch resistance is wear-resisting;Antistatic property is excellent and lasting stability, coating surface resistance are 6.8 × 105Ω/
Sq, coating surface resistance 7.2 × 10 after placing 1 year5Ω/sq, antistatic property are lasting.Coating hardness 5H, adhesion 1 grade, punching
Hit intensity 50kg.cm.
Corrosion resistance is tested:Paint film uniform hue, it is smooth;
Salt water resistance(3% sodium chloride, for 24 hours)It is not blistering, do not fall off, without whitening;
Embodiment 2
A kind of new type power distribution box including babinet and case lid, contains lighting device, the case lid one in the babinet
Side is equipped with push switch, and observation panel is set on the case lid, and the observation panel is transparent plastic,
It is characterized in that, coat antistatic coating outside the babinet and case lid;
The antistatic coating is prepared by the raw material of following parts by weight:
It is modified poly-(3,4- ethene dioxythiophenes)8 parts of polystyrolsulfon acid, has 20 parts of aromatic urethane acrylate
13 parts of machine silicones, 15 parts of dimethylaminoethyl acrylate, 50 parts of diluent, 2 parts of Triallyl isocyanurate, levelling agent
0.8 part, 20 parts of graphene, 7 parts of magnesium chloride, 7 parts of nano-silver powder, 1 part of organobentonite.
The modification gathers(3,4- ethene dioxythiophenes)The preparation method of polystyrolsulfon acid is as follows:
Under conditions of temperature is 35 DEG C, sulfonated graphene, 3,4-rthylene dioxythiophene and polyethylene glycol are dispersed in
In ionized water, make a concentration of 0.05wt% of contained polyethylene glycol in the mixed system to be formed, and sulfonated graphene, 3,4- ethylene
Dioxy thiophene, the mass ratio of polyethylene glycol is 2:3:0.1, then the pH value of the mixed system is adjusted to 4.5, and with 500 turns/
The speed of min is stirred, while adds in oxidant and catalyst, wherein the mass ratio of oxidant and 3,4-rthylene dioxythiophene
It is 1:2, the mass ratio 0.01 of catalyst and 3,4-rthylene dioxythiophene:1,72h is then persistently stirred to react, removes mixing later
Foreign ion in reaction product to get;
The diluent is:Water:Isopropanol:Ethyl alcohol(Volume ratio)=1:7:1;
The levelling agent is:Dimethyl silicone polymer
It will be modified poly-(3,4- ethene dioxythiophenes)Polystyrolsulfon acid is sheared in high speed dispersor high speed to be disperseed, and is turned
1000 turns/min of speed stirs 60min, successively by aromatic urethane acrylate, organic siliconresin, acrylate second
Ester, diluent, Triallyl isocyanurate, levelling agent, graphene, magnesium chloride, nano-silver powder, organobentonite are added thereto
Be uniformly mixed, stir 15-60min, after 200 mesh filter screen filtrations to get.
After brushing paint, distribution box surface of the present invention without skinning and lump phenomenon, can rapid curing drying, it is environment-protecting and non-poisonous,
It is not tacky, do not return viscous, scratch resistance is wear-resisting;Antistatic property is excellent and lasting stability, coating surface resistance are 7.1 × 105Ω/
Sq, coating surface resistance 7.4 × 10 after placing 1 year5Ω/sq, antistatic property are lasting.Coating hardness 5H, adhesion 1 grade, punching
Hit intensity 50kg.cm.
Corrosion resistance is tested:Paint film uniform hue, it is smooth;
Salt water resistance(3% sodium chloride, for 24 hours)It is not blistering, do not fall off, without whitening;
Abrasion resistance:5000 times not show-through.
The present invention is done it is noted that although the description of front has been carried out by the example of the present invention certainly
Go out will be apparent to those skilled in the science it is such and other improvement and change be deemed to fall such as set forth herein
Broad range of the present invention in.Therefore, although the present invention reference has been made to preferred embodiment and be described, meaning
It is not that the product of tool novelty is made to be restricted therefrom, on the contrary, it is intended to include to meet part disclosed above, claim
Broad range within various improvement and equivalent modifications.