CN105504513A - Energy-saving abrasion-resistant sheath plastic for apparatus handle and preparing method of energy-saving abrasion-resistant sheath plastic - Google Patents
Energy-saving abrasion-resistant sheath plastic for apparatus handle and preparing method of energy-saving abrasion-resistant sheath plastic Download PDFInfo
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- CN105504513A CN105504513A CN201610012919.1A CN201610012919A CN105504513A CN 105504513 A CN105504513 A CN 105504513A CN 201610012919 A CN201610012919 A CN 201610012919A CN 105504513 A CN105504513 A CN 105504513A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
Abstract
The invention discloses an energy-saving abrasion-resistant sheath plastic for an apparatus handle. The energy-saving abrasion-resistant sheath plastic is prepared from, by weight, 1.7-2 parts of a silane complex solution, 2-3 parts of sodium citrate, 0.5-1 part of magnesium nitrate, 4-7 parts of milltailings, 3-5 parts of sisal fibers, 1-2 parts of citrus pulp, 2-3 parts of alkyl succinic acid, 0.1-0.2 part of tri-n-butyltin trichloride, 10-13 parts of talcum powder, 6-8 parts of epoxy cotton seed butyl oleate, 100-120 parts of high-density polypropylene, 1-2 parts of vinyl carboxylic ester, 0.3-0.5 part of aluminum sulfate and 10-13 parts of attapulgite. According to the plastic, the cost of the adopted raw materials is low, and the energy-saving performance is good; as the silane complex solution is added, the dispersibility of filler in the plastic can be effectively improved, and the stability of the finished plastic is improved; the plastic has good abrasion resistance and is particularly suitable for the mechanical handle and long in service life.
Description
Technical field
The present invention relates to plastics arts, particularly relate to a kind of instrument handle energy-saving wear-resistant sheathed plastic and preparation method thereof.
Background technology
Plastics take monomer as raw material, by the macromolecular compound of addition polymerization or polycondensation polymerized, be commonly called as plastics or resin, can freely change composition and body styles, be made up of additives such as synthetic resins and filler, softening agent, stablizer, lubricant, colorants, most of plastics light weight, chemical stabilization, can not corrosion; Shock-resistance is good; There is the transparency and wear resistant preferably; Good insulating, thermal conductivity is low; General formability, tint permanence are good, and tooling cost is low; But the plastic prod shortcoming that also ubiquity is much common at present: most of plastics poor heat resistance, coefficient of thermal expansion is large, easy firing; Poor dimensional stability, is easily out of shape; Most plastics lower temperature resistance is poor, becomes fragile under low temperature, easily aging; Plastics different performance determines it in life purposes in the industry, along with the progress of technology, never stops research to modifying plastics.In order to improve constantly the performance of plastic product, making plastics have different characteristics in different fields, meeting different Working environments, modification is targetedly carried out to plastics and just seems particularly necessary.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides a kind of instrument handle energy-saving wear-resistant sheathed plastic and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of instrument handle energy-saving wear-resistant sheathed plastic, it is made up of the raw material of following weight parts:
Silane composite solution 1.7-2, Sodium Citrate 2-3, magnesium nitrate 0.5-1, tailings 4-7, sisal fibers 3-5, citrus pulp 1-2, hydrocarbyl succinimide acid 2-3, tributyl tin trichloride 0.1-0.2, talcum powder 10-13, epoxy cotton seed oil acid butyl ester 6-8, high density poly propylene 100-120, vinyl carboxylate 1-2, Tai-Ace S 150 0.3-0.5, attapulgite 10-13.
Described a kind of instrument handle energy-saving wear-resistant sheathed plastic, described silane composite solution is made up of the raw material of following weight parts:
Silane coupling agent KH5603-5, silane coupling agent KH5701-2, TriMethylolPropane(TMP) 0.01-0.02, oxine 0.6-0.7, dehydrated alcohol 20-37;
Joined by oxine in dehydrated alcohol, stir, add silane coupling agent KH560, silane coupling agent KH570, warming temperature is 60-70 DEG C, adds TriMethylolPropane(TMP), and 800-1000 rev/min is stirred 10-20 minute, to obtain final product.
A preparation method for described instrument handle energy-saving wear-resistant sheathed plastic, comprises the following steps:
(1) by above-mentioned sisal fibers, citrus pulp mixing, stir, join compound weight 60-70 doubly, in the superoxol of 1.7-2%, be uniformly mixed 30-40 minute, obtain liquid a;
(2) above-mentioned attapulgite is joined its weight 60-70%, concentration is in the sulphuric acid soln of 30-40%, add tributyl tin trichloride, be uniformly mixed 10-20 minute, mix with above-mentioned liquid a, add hydrocarbyl succinimide acid, raised temperature is 60-70 DEG C, insulated and stirred 30-40 minute, obtains batch mixing b;
(3) joined in silane composite solution by above-mentioned Tai-Ace S 150, add batch mixing b, stir, add magnesium nitrate, tailings, Sodium Citrate, 700-800 rev/min is stirred 10-15 minute, and suction filtration, by filter cake dry 2-3 hour at 60-70 DEG C, must expect c;
(4) by above-mentioned material c and each raw material of residue, stir, send into twin screw extruder, melt extrude, cooling, to obtain final product.
Advantage of the present invention is:
The raw materials cost that plastics of the present invention adopt is low, and good energy saving property, adds silane composite solution, effectively can improve each filler dispersiveness in the plastic, improve the stability of finished plastic, plastics of the present invention have good wear resistance, be particularly suitable as mechanical handle use, long service life.
Embodiment
A kind of instrument handle energy-saving wear-resistant sheathed plastic, it is made up of the raw material of following weight parts:
Silane composite solution 1.7, Sodium Citrate 2, magnesium nitrate 0.5, tailings 4, sisal fibers 3, citrus pulp 1, hydrocarbyl succinimide acid 2, tributyl tin trichloride 0.1, talcum powder 10, epoxy cotton seed oil acid butyl ester 6, high density poly propylene 100, vinyl carboxylate 1, Tai-Ace S 150 0.3, attapulgite 10.
Described a kind of instrument handle energy-saving wear-resistant sheathed plastic, described silane composite solution is made up of the raw material of following weight parts:
Silane coupling agent KH5603, silane coupling agent KH5701, TriMethylolPropane(TMP) 0.01,8 hydroxyquinoline 0.6, dehydrated alcohol 20;
Join in dehydrated alcohol by 8 hydroxyquinolines, stir, add silane coupling agent KH560, silane coupling agent KH570, warming temperature is 60 DEG C, adds TriMethylolPropane(TMP), and 800 revs/min are stirred 10 minutes, to obtain final product.
A preparation method for described instrument handle energy-saving wear-resistant sheathed plastic, comprises the following steps:
(1) by above-mentioned sisal fibers, citrus pulp mixing, stir, join compound weight 60 times, 1.7% superoxol in, be uniformly mixed 30 minutes, obtain liquid a;
(2) above-mentioned attapulgite is joined its weight 60%, concentration is in the sulphuric acid soln of 30%, add tributyl tin trichloride, be uniformly mixed 10 minutes, mix with above-mentioned liquid a, add hydrocarbyl succinimide acid, raised temperature is 60 DEG C, insulated and stirred 30 minutes, obtains batch mixing b;
(3) joined in silane composite solution by above-mentioned Tai-Ace S 150, add batch mixing b, stir, add magnesium nitrate, tailings, Sodium Citrate, 700 revs/min are stirred 10 minutes, suction filtration, by filter cake at 60 DEG C dry 2 hours, must expect c;
(4) by above-mentioned material c and each raw material of residue, stir, send into twin screw extruder, melt extrude, cooling, to obtain final product.
Performance test:
Tensile strength 28.1MPa;
Elongation at break 364%.
Claims (3)
1. an instrument handle energy-saving wear-resistant sheathed plastic, is characterized in that: it is made up of the raw material of following weight parts:
Silane composite solution 1.7-2, Sodium Citrate 2-3, magnesium nitrate 0.5-1, tailings 4-7, sisal fibers 3-5, citrus pulp 1-2, hydrocarbyl succinimide acid 2-3, tributyl tin trichloride 0.1-0.2, talcum powder 10-13, epoxy cotton seed oil acid butyl ester 6-8, high density poly propylene 100-120, vinyl carboxylate 1-2, Tai-Ace S 150 0.3-0.5, attapulgite 10-13.
2. a kind of instrument handle energy-saving wear-resistant sheathed plastic according to claim 1, it is characterized in that, described silane composite solution is made up of the raw material of following weight parts:
Silane coupling agent KH5603-5, silane coupling agent KH5701-2, TriMethylolPropane(TMP) 0.01-0.02, oxine 0.6-0.7, dehydrated alcohol 20-37;
Joined by oxine in dehydrated alcohol, stir, add silane coupling agent KH560, silane coupling agent KH570, warming temperature is 60-70 DEG C, adds TriMethylolPropane(TMP), and 800-1000 rev/min is stirred 10-20 minute, to obtain final product.
3. a preparation method for instrument handle energy-saving wear-resistant sheathed plastic as claimed in claim 1, is characterized in that, comprise the following steps:
(1) by above-mentioned sisal fibers, citrus pulp mixing, stir, join compound weight 60-70 doubly, in the superoxol of 1.7-2%, be uniformly mixed 30-40 minute, obtain liquid a;
(2) above-mentioned attapulgite is joined its weight 60-70%, concentration is in the sulphuric acid soln of 30-40%, add tributyl tin trichloride, be uniformly mixed 10-20 minute, mix with above-mentioned liquid a, add hydrocarbyl succinimide acid, raised temperature is 60-70 DEG C, insulated and stirred 30-40 minute, obtains batch mixing b;
(3) joined in silane composite solution by above-mentioned Tai-Ace S 150, add batch mixing b, stir, add magnesium nitrate, tailings, Sodium Citrate, 700-800 rev/min is stirred 10-15 minute, and suction filtration, by filter cake dry 2-3 hour at 60-70 DEG C, must expect c;
(4) by above-mentioned material c and each raw material of residue, stir, send into twin screw extruder, melt extrude, cooling, to obtain final product.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610012919.1A CN105504513A (en) | 2016-01-11 | 2016-01-11 | Energy-saving abrasion-resistant sheath plastic for apparatus handle and preparing method of energy-saving abrasion-resistant sheath plastic |
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| CN201610012919.1A CN105504513A (en) | 2016-01-11 | 2016-01-11 | Energy-saving abrasion-resistant sheath plastic for apparatus handle and preparing method of energy-saving abrasion-resistant sheath plastic |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106633309A (en) * | 2016-12-23 | 2017-05-10 | 安徽天元电缆有限公司 | Filler for high wear-resisting cable protective sleeve and preparation process thereof |
| CN108047563A (en) * | 2017-12-25 | 2018-05-18 | 桐城市祥泰塑业有限公司 | A kind of rear-earth-doped polypropylene plastic material and preparation method thereof |
| CN108164818A (en) * | 2017-12-25 | 2018-06-15 | 桐城市祥泰塑业有限公司 | A kind of steering wheel protector for car plastic material and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102757584A (en) * | 2011-04-27 | 2012-10-31 | 合肥杰事杰新材料股份有限公司 | Polyolefin enhanced material and preparation method and application thereof |
-
2016
- 2016-01-11 CN CN201610012919.1A patent/CN105504513A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102757584A (en) * | 2011-04-27 | 2012-10-31 | 合肥杰事杰新材料股份有限公司 | Polyolefin enhanced material and preparation method and application thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106633309A (en) * | 2016-12-23 | 2017-05-10 | 安徽天元电缆有限公司 | Filler for high wear-resisting cable protective sleeve and preparation process thereof |
| CN108047563A (en) * | 2017-12-25 | 2018-05-18 | 桐城市祥泰塑业有限公司 | A kind of rear-earth-doped polypropylene plastic material and preparation method thereof |
| CN108164818A (en) * | 2017-12-25 | 2018-06-15 | 桐城市祥泰塑业有限公司 | A kind of steering wheel protector for car plastic material and preparation method thereof |
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Application publication date: 20160420 |