CN105503149A - Floor tile and preparation method thereof - Google Patents
Floor tile and preparation method thereof Download PDFInfo
- Publication number
- CN105503149A CN105503149A CN201511015582.1A CN201511015582A CN105503149A CN 105503149 A CN105503149 A CN 105503149A CN 201511015582 A CN201511015582 A CN 201511015582A CN 105503149 A CN105503149 A CN 105503149A
- Authority
- CN
- China
- Prior art keywords
- parts
- floor tile
- potassium
- preparation
- clay
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000010881 fly ash Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052900 illite Inorganic materials 0.000 claims abstract description 11
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 claims abstract description 11
- 239000004927 clay Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 16
- 229910052656 albite Inorganic materials 0.000 claims description 16
- 229910052700 potassium Inorganic materials 0.000 claims description 16
- 239000011591 potassium Substances 0.000 claims description 16
- 238000000498 ball milling Methods 0.000 claims description 12
- 239000011505 plaster Substances 0.000 claims description 12
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 12
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 12
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 12
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 12
- 239000004576 sand Substances 0.000 claims description 11
- 239000002023 wood Substances 0.000 claims description 10
- -1 25 parts Substances 0.000 claims description 8
- 238000005245 sintering Methods 0.000 claims description 7
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- 238000005520 cutting process Methods 0.000 claims description 5
- 238000010304 firing Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 238000001694 spray drying Methods 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical group O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 7
- 239000002699 waste material Substances 0.000 abstract description 6
- 239000010433 feldspar Substances 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 2
- 239000002440 industrial waste Substances 0.000 abstract description 2
- 238000006477 desulfuration reaction Methods 0.000 abstract 2
- 230000023556 desulfurization Effects 0.000 abstract 2
- 229910052602 gypsum Inorganic materials 0.000 abstract 2
- 239000010440 gypsum Substances 0.000 abstract 2
- 238000004134 energy conservation Methods 0.000 abstract 1
- 238000005265 energy consumption Methods 0.000 abstract 1
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000011449 brick Substances 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 235000019256 formaldehyde Nutrition 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000005686 electrostatic field Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000002631 hypothermal effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/135—Combustion residues, e.g. fly ash, incineration waste
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Combustion & Propulsion (AREA)
- Processing Of Solid Wastes (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention provides a floor tile and a preparation method thereof. The floor tile is prepared from the following components in parts by weight: 26-32 parts of illite, 13-18 parts of potassium-sodium feldspar, 22-28 parts of clay, 28-42 parts of fly ash, 10-16 parts of sawdust, 5-12 parts of desulfurization gypsum, 15-30 parts of pottery and 20-30 parts of water. By adopting the floor tile provided by the invention, waste materials are well utilized, and a very good energy saving effect is achieved; the floor tile has very good anti-skidding and wear-resisting effects, and is environmental-friendly. A large amount of industrial waste such as the fly ash and the desulfurization gypsum is taken as raw materials for making an ecological environment-friendly floor tile with zero formaldehyde release, so that waste is turned into treasure, the energy consumption is low, and sustainable development is realized. The floor tile is a novel low-carbon, economical and rare floor tile facilitating energy conservation and emission reduction.
Description
Technical field
The invention belongs to building material technical field, be specifically related to a kind of floor tile and preparation method thereof.
Background technology
Floor tile, also known as a kind of floor decorative material of floor tile, fire with clay and form, specification is multiple.Be used for the ground and floor of public building and covil construction.In numerous floor decorative materials, floor tile becomes the first-selection of human consumer.Especially the selection of building tile is focused on more, it is tightly round the association durable consumer goods of house property, therefore very typical immobility consumption feature is just presented when consumption, that is, once form purchase, also paving is good in the building tile consumption of common people, so unless it is absolutely necessary, be usually can not be gently easily changeable, even until this house changes hands just can again fit up.So more and more higher to the requirement of floor tile, require floor tile have quality solid, be convenient to cleaning, heat-resisting, wear-resisting, acid and alkali-resistance, the advantage such as do not seep water, and requires to have environmental protection and energy-saving effect now.But traditional floor tile over-all properties is not good, do not have an energy saving, and have certain pollution, so require further improvement.
At present, be main material production openpore floor tile or red base floor tile at existing ceramic floor brick on the market mainly with feldspar, weathered feldspar, high temperature sand, hypothermia grait, white clay and black mud etc., this manufacture method and selection, to environment and vegetation deterioration serious, and waste resource, national relevant policies are advocated and are wanted efficent use of resources, utilize resources synthetically, as much as possible waste recycling for this reason.And the poor quality of the ceramic floor brick taking above-mentioned material to manufacture, also there is certain pollution to environment in manufacturing processed.Therefore, people wish that the ceramic floor brick that a kind of safety can be had free from environmental pollution replaces the floor tile of prior art always.
Summary of the invention
The object of the invention is to make full use of existing resource, select the industrial waste such as flyash, desulfurated plaster as raw materials for production, provide a kind of technique simple, with low cost, there is floor tile of well anti-skidding, abrasion resistant effect and preparation method thereof.
For achieving the above object, the technical solution adopted in the present invention is:
A kind of floor tile, it is characterized in that, prepared by the component of following weight part: illite 26-32 part, potassium albite 13-18 part, clay 22-28 part, flyash 28-42 part, wood chip 10-16 part, desulfurated plaster 5-12 part, pottery sand 15-30 part, water 20-30 part.
Preferably, prepared by the component of following weight part: illite 29 parts, potassium albite 15 parts, clay 25 parts, 35 parts, flyash, wood chip 13 parts, desulfurated plaster 8 parts, pottery 23 parts, sand, 25 parts, water.
Further, in described potassium albite, the mass content of potassium oxide and sodium oxide is greater than 11%, and the mass ratio of potassium oxide and sodium oxide is greater than 3.
Preferably, described clay is kaolin or wilkinite.
A preparation method for above-mentioned floor tile, is characterized in that, comprises the following steps: above-mentioned each component is weighed by (1) in proportion, joins ball milling 20-30 minute in ball mill, the slurry that must mix; (2) raw material good for ball milling is sent into spray-drying tower dry, pour dried powder into mould and strike off; (3) sinter in continuous tunnel kiln, sintering temperature is 1120-1160 DEG C, insulation 0.5-2 hour; (4) cool, the goods firing gained are processed into required size through cutting, finishing.
Preferably, the Ball-milling Time in step (1) is 25 minutes.
Preferably, the sintering temperature in step (3) is 1130 DEG C, and soaking time is 1 hour.
The advantage that the present invention has and positively effect are:
Floor tile provided by the invention, well make use of rejected material, reaches good energy-saving effect, has well anti-skidding, abrasion resistant effect, and does not pollute.The present invention utilizes the trade wastes such as a large amount of flyash, desulfurated plaster as raw material, manufacture the ecological, environmental protective floor tile of zero burst size of methanal, turn waste into wealth, do not need to consume the too many energy, Sustainable development develops the rare floor tile of energy-saving and emission-reduction low-carbon economy, once apply, obvious advantage will be given play to, produced significant economic results in society.
Below by embodiment the present invention be specifically described and illustrate:
Embodiment 1
A kind of floor tile, is prepared by the component of following weight part: illite 26 parts, potassium albite 13 parts, wilkinite 22 parts, 28 parts, flyash, wood chip 10 parts, desulfurated plaster 5 parts, pottery 15 parts, sand, 20 parts, water.
Embodiment 2
A kind of floor tile, is prepared by the component of following weight part: illite 32 parts, potassium albite 18 parts, kaolin 28 parts, 42 parts, flyash, wood chip 16 parts, desulfurated plaster 12 parts, pottery 30 parts, sand, 30 parts, water.
Embodiment 3
A kind of floor tile, is prepared by the component of following weight part: illite 29 parts, potassium albite 15 parts, wilkinite 25 parts, 35 parts, flyash, wood chip 13 parts, desulfurated plaster 8 parts, pottery 23 parts, sand, 25 parts, water.Wherein, in potassium albite, the mass content of potassium oxide and sodium oxide is greater than 11%, and the mass ratio of potassium oxide and sodium oxide is greater than 3.
Embodiment 4
A kind of floor tile, is prepared by the component of following weight part: illite 27 parts, potassium albite 14 parts, wilkinite 24 parts, 31 parts, flyash, wood chip 12 parts, desulfurated plaster 7 parts, pottery 19 parts, sand, 23 parts, water.Wherein, in potassium albite, the mass content of potassium oxide and sodium oxide is greater than 11%, and the mass ratio of potassium oxide and sodium oxide is greater than 3.
Embodiment 5
A kind of floor tile, is prepared by the component of following weight part: illite 31 parts, potassium albite 17 parts, kaolin 26 parts, 39 parts, flyash, wood chip 15 parts, desulfurated plaster 10 parts, pottery 27 parts, sand, 28 parts, water.Wherein, in potassium albite, the mass content of potassium oxide and sodium oxide is greater than 11%, and the mass ratio of potassium oxide and sodium oxide is greater than 3.
Embodiment 6
A kind of floor tile, is prepared by the component of following weight part: illite 28 parts, potassium albite 17 parts, wilkinite 23 parts, 40 parts, flyash, wood chip 14 parts, desulfurated plaster 9 parts, pottery 28 parts, sand, 26 parts, water.Wherein, in potassium albite, the mass content of potassium oxide and sodium oxide is greater than 11%, and the mass ratio of potassium oxide and sodium oxide is greater than 3.
Being below the preparation method of floor tile in embodiment 1-6 is:
The preparation method of floor tile described in embodiment 1-2 is:
Comprise the following steps: above-mentioned each component is weighed by (1) in proportion, to join in ball mill ball milling 20 minutes, the slurry that must mix; (2) raw material good for ball milling is sent into spray-drying tower dry, pour dried powder into mould and strike off; (3) sinter in continuous tunnel kiln, sintering temperature is 1120 DEG C, is incubated 0.5 hour; (4) cool, the goods firing gained are processed into required size through cutting, finishing.
The preparation method of floor tile described in embodiment 3-4 is:
Comprise the following steps: above-mentioned each component is weighed by (1) in proportion, to join in ball mill ball milling 25 minutes, the slurry that must mix; (2) raw material good for ball milling is sent into spray-drying tower dry, pour dried powder into mould and strike off; (3) sinter in continuous tunnel kiln, sintering temperature is 1130 DEG C, is incubated 1 hour; (4) cool, the goods firing gained are processed into required size through cutting, finishing.
The preparation method of floor tile described in embodiment 5-6 is:
Comprise the following steps: above-mentioned each component is weighed by (1) in proportion, to join in ball mill ball milling 30 minutes, the slurry that must mix; (2) raw material good for ball milling is sent into spray-drying tower dry, pour dried powder into mould and strike off; (3) sinter in continuous tunnel kiln, sintering temperature is 1160 DEG C, is incubated 2 hours; (4) cool, the goods firing gained are processed into required size through cutting, finishing.
Floor tile sample made by the present invention, through pressing the test of GB/T11718-2009 method, MOR >=14.5MPa, two-dimensional electrostatic fields >=0.45MPa, thickness swelling rate≤2.0%, burst size of methanal does not detect, and index of correlation reaches and is better than the performance of national standard.
Claims (7)
1. a floor tile, it is characterized in that, prepared by the component of following weight part: illite 26-32 part, potassium albite 13-18 part, clay 22-28 part, flyash 28-42 part, wood chip 10-16 part, desulfurated plaster 5-12 part, pottery sand 15-30 part, water 20-30 part.
2. floor tile according to claim 1, is characterized in that, is prepared by the component of following weight part: illite 29 parts, potassium albite 15 parts, clay 25 parts, 35 parts, flyash, wood chip 13 parts, desulfurated plaster 8 parts, pottery 23 parts, sand, 25 parts, water.
3. floor tile according to claim 1, is characterized in that, in described potassium albite, the mass content of potassium oxide and sodium oxide is greater than 11%, and the mass ratio of potassium oxide and sodium oxide is greater than 3.
4. floor tile according to claim 1, is characterized in that, described clay is kaolin or wilkinite.
5. a preparation method for the floor tile described in any one of claim 1-4, is characterized in that, comprises the following steps: above-mentioned each component is weighed by (1) in proportion, joins ball milling 20-30 minute in ball mill, the slurry that must mix; (2) raw material good for ball milling is sent into spray-drying tower dry, pour dried powder into mould and strike off; (3) sinter in continuous tunnel kiln, sintering temperature is 1120-1160 DEG C, insulation 0.5-2 hour; (4) cool, the goods firing gained are processed into required size through cutting, finishing.
6. the preparation method of floor tile according to claim 5, is characterized in that, the Ball-milling Time in step (1) is 25 minutes.
7. the preparation method of floor tile according to claim 5, is characterized in that, the sintering temperature in step (3) is 1130 DEG C, and soaking time is 1 hour.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201511015582.1A CN105503149A (en) | 2015-12-31 | 2015-12-31 | Floor tile and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201511015582.1A CN105503149A (en) | 2015-12-31 | 2015-12-31 | Floor tile and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN105503149A true CN105503149A (en) | 2016-04-20 |
Family
ID=55711528
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201511015582.1A Pending CN105503149A (en) | 2015-12-31 | 2015-12-31 | Floor tile and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105503149A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107840644A (en) * | 2017-11-29 | 2018-03-27 | 柳州市闽贵砖厂 | A kind of mosquito repellent floor tile and preparation method thereof |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20040026744A (en) * | 2002-09-26 | 2004-04-01 | 우성세라믹스공업 주식회사 | Ceramic clay brick and pavers and method for producing it using kaoline, feldspar and black granule |
CN101921098A (en) * | 2010-08-23 | 2010-12-22 | 马鞍山科达机电有限公司 | Environment-friendly, high-intensity and desulfurated plaster wall brick and manufacture method thereof |
CN104058724A (en) * | 2014-07-01 | 2014-09-24 | 李兆源 | Ceramic floor tile |
CN104710156A (en) * | 2015-03-04 | 2015-06-17 | 安徽建筑大学 | Rail shield muck unburned and non-autoclaved ceramsite and preparation method thereof |
CN105040955A (en) * | 2015-06-30 | 2015-11-11 | 青岛精石通精密机械制造有限公司 | Energy-saving environment-friendly composite floor tile |
CN105130324A (en) * | 2015-08-19 | 2015-12-09 | 铜陵铜冠建安新型环保建材科技有限公司 | Manufacture method for autoclaved fly-ash aerated concrete block |
-
2015
- 2015-12-31 CN CN201511015582.1A patent/CN105503149A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20040026744A (en) * | 2002-09-26 | 2004-04-01 | 우성세라믹스공업 주식회사 | Ceramic clay brick and pavers and method for producing it using kaoline, feldspar and black granule |
CN101921098A (en) * | 2010-08-23 | 2010-12-22 | 马鞍山科达机电有限公司 | Environment-friendly, high-intensity and desulfurated plaster wall brick and manufacture method thereof |
CN104058724A (en) * | 2014-07-01 | 2014-09-24 | 李兆源 | Ceramic floor tile |
CN104710156A (en) * | 2015-03-04 | 2015-06-17 | 安徽建筑大学 | Rail shield muck unburned and non-autoclaved ceramsite and preparation method thereof |
CN105040955A (en) * | 2015-06-30 | 2015-11-11 | 青岛精石通精密机械制造有限公司 | Energy-saving environment-friendly composite floor tile |
CN105130324A (en) * | 2015-08-19 | 2015-12-09 | 铜陵铜冠建安新型环保建材科技有限公司 | Manufacture method for autoclaved fly-ash aerated concrete block |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107840644A (en) * | 2017-11-29 | 2018-03-27 | 柳州市闽贵砖厂 | A kind of mosquito repellent floor tile and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103332905B (en) | Decorative heat insulation foam ceramic composite plate and preparation method thereof | |
CN101186519B (en) | Porous ceramic material and preparation method thereof | |
CN104291788B (en) | A kind of high strength hollow brick and preparation method thereof | |
CN103626471B (en) | A kind of steamed brick utilizing phosphorus mine tailing and phosphorus slag to produce and preparation method thereof | |
CN104310949B (en) | A kind of Boccaro shale hollow brick | |
CN102417343B (en) | Production method of sandstone-like porcelain exterior wall tile | |
CN101696100A (en) | High-performance base mortar | |
CN102584176B (en) | Method for preparing ceramic wall and floor tile by utilizing construction waste | |
CN103159450A (en) | Production method of foamed concrete block manufactured from steel slag | |
CN106380179A (en) | Hollow brick strong in water absorbability, and preparation method thereof | |
CN104310973A (en) | High-heat-conductivity functional ceramic sheet and preparation method thereof | |
CN105272338A (en) | Method for preparing high-strength foaming ceramic material by utilizing fly ash and desert sand | |
CN103396158A (en) | Antibacterial molybdenum mill tailings aerated concrete block and preparation method thereof | |
CN103708811A (en) | Polished tile, and preparation method and application thereof | |
CN102863186B (en) | Ecological slag artificial squared stone brick and preparation method thereof | |
CN102659387B (en) | High-temperature far infrared radiation energy-saving composite coating and preparation method thereof | |
CN104291789B (en) | A kind of bibulous perforated brick and preparation method thereof | |
CN107473713B (en) | Preparation method for square bricks | |
CN103524108A (en) | Raw material ratio for producing energy-saving bricks by coal gangue as well as preparation method of energy-saving bricks | |
CN111348894B (en) | Preparation method for producing ceramic foam board by using lepidolite tailings | |
CN105503149A (en) | Floor tile and preparation method thereof | |
CN102219548B (en) | Environment-friendly lightweight ceramic tile foaming agent and preparation method thereof | |
CN103496948A (en) | Home-decoration ceramic decorative material and preparation method thereof | |
CN104529309B (en) | A kind of non-bearing heat insulation building block and preparation method thereof | |
CN108997018A (en) | A kind of green building refractory material |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160420 |
|
RJ01 | Rejection of invention patent application after publication |