CN105500182B - A kind of environment-friendly and energy-efficient high-performance multiple grinding piece - Google Patents

A kind of environment-friendly and energy-efficient high-performance multiple grinding piece Download PDF

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CN105500182B
CN105500182B CN201510832861.0A CN201510832861A CN105500182B CN 105500182 B CN105500182 B CN 105500182B CN 201510832861 A CN201510832861 A CN 201510832861A CN 105500182 B CN105500182 B CN 105500182B
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parts
composition
weight
coupling agent
following components
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CN105500182A (en
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王荣生
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Nantong Fengmang composite material technology Co.,Ltd.
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JIANGSU FENGMANG COMPOSITE MATERIAL S&T GROUP CO Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B37/00Lapping machines or devices; Accessories
    • B24B37/11Lapping tools
    • B24B37/12Lapping plates for working plane surfaces
    • B24B37/14Lapping plates for working plane surfaces characterised by the composition or properties of the plate materials

Abstract

The present invention is a kind of environment-friendly and energy-efficient high-performance multiple grinding piece, including substrate, adhesive and abrasive material, and the abrasive material is attached in substrate by adhesive, and adhesive is mixed by weight than the composition A and 35 43% composition B for 57 65%;Composition A includes phenolic resin, trimethylolpropane trimethacrylate, filler, surfactant, diluent, coupling agent, fire retardant, ethylene-vinyl acetate copolymer, LLDPE, high density polyethylene (HDPE);Composition B includes:Phenolic resin, polyphenylene oxide resin powder, sodium carbonate, epoxy resin, methyl methacrylate, butyl acrylate, filler, coupling agent, diluent, antistatic additive, catalyst;Sharp quick, the service life length of abrasive sheet in the present invention, polishing high heat resistance, splendid moisture resistance, its preparation method can effectively prevent deformation, and product tensile strength is big, and adhesive property is good, and grinding performance is strong.

Description

A kind of environment-friendly and energy-efficient high-performance multiple grinding piece
Technical field
The invention belongs to coated abrasive tool field, it is related to a kind of environment-friendly and energy-efficient high-performance multiple grinding piece.
Background technology
Abrasive sheet refers to utilize ultraprecise coating technique, by selected micron or nanoscale abrasive micropowder(Diamond, carbonization Silicon, aluminum oxide, silica, cerium oxide etc.)With high performance adhesive it is dispersed after, substrate surface is coated on, then through too high Precision cuts technique and processed.Abrasive sheet with field widely, such as lead by optical communication field, micromachine field, hard disk Domain etc..Such as vulcan fibre emery disc that uses on the market at present, vulcan fibre emery disc is also known as vulcanized paper sanding discs, at a high speed grinding, abrasive disk, it be with Vulcan fibre is base material, a kind of plate-like coated abrasive tool being made by binding agent of synthetic resin.Its tensile strength is big, wearability extra-heavy, Can be arranged on electronic or pneumatic electric angle grinder metal and the various type faces of nonmetallic materials are derusted, deburring, coating removal, Polishing welding seams, are the ideal tools that are ground, polish, polish in Furniture manufacture and repair of machine work, are widely used in timber, family Tool, shipbuilding, metallurgy, automobile, machinery, instrument, bridge and building trade.
The domestic emery disc used is generally red steel paper emery disc, i.e. base material for red steel paper at present, but red steel paper emery disc When in use particularly in the summer meeting moisture absorption so that the emery disc toughness reduction of red steel paper ultimately results in emery disc cracking, thus a lot The toughness of emery disc improves in the form of glass fiber mesh is added in centre in producer, and such as patent CN201420209Y proposes one kind New waterleaf paper for velcanized fiber, has been mainly in vulcan fibre surface even spread the strong fibrous layer that one layer is made up of cotton fiber so that body paper Water imbibition is strong, and patent CN201276524Y proposes a kind of resin laminated board grinding sheet, the mainly ring by setting tool to be of five storeys On oxygen tree fat glass fiber laminate, improve the performances such as deformation, mechanical strength, impact strength, toughness with this, but it is this Increased glass fiber mesh can produce many dusts during polishing, simultaneously because the increase of hardness easily flies in polishing The red steel paper splashed can cause the injury of staff.
In addition, the problem of people are directed in emery disc is corresponding to propose a specific solution, such as CN201419364Y is carried Go out a kind of high strength steel cardboard, with zinc chloride gel layer mainly in vulcanized fiber board basic unit so that its use time is longer, Grinding effect is more preferably.CN101180159A is by effectively being handled vulcan fibre backing, it will be apparent that improve vulcan fibre emery disc Deformation condition, while improving service life.CN200939582Y proposes a kind of enhancing silencing steel-paper sand disk, mainly passes through Increase well-regulated open-work and curved grooves on emery disc, improve aerodynamic profile when being ground application, reach obvious reduction It is ground the effect of noise.CN101235261A proposes a kind of preparation method of aerodux, is bonded using this phenolic aldehyde The vulcan fibre emery disc of agent manufacture, significantly improves adhesive property, shear strength and moisture resistance energy.
Although the problem of existing from different perspectives to vulcan fibre emery disc above proposes specific solution, vulcan fibre emery disc Inherently one comprehensive problem of use, it is still necessary to those skilled in the art continue to research and develop to play vulcan fibre emery disc at it The maximum use value of application field.
The content of the invention
The technical problems to be solved by the invention are that the shortcoming existed for above prior art proposes a kind of environmental protection section Energy type high-performance multiple grinding piece, can effectively prevent deformation, and tensile strength is big, and adhesive property is good, and grinding performance is strong, produces Sharp quick, the service life length of abrasive sheet, polishing high heat resistance, splendid moisture resistance.
The present invention solve above technical problem technical scheme be:
A kind of environment-friendly and energy-efficient high-performance multiple grinding piece, including substrate, adhesive and abrasive material, the abrasive material passes through gluing Agent is attached in substrate;
Composition B of the adhesive by weight than composition A and 35-43% for 57-65% is mixed;
Composition A includes following components by weight:Phenolic resin:36-40 parts, trimethylolpropane trimethacrylate: 11-25 parts, filler:15-17 parts, surfactant:3-5 parts, diluent:10-13 parts, coupling agent:4-6 parts, fire retardant:2-8 Part, ethylene-vinyl acetate copolymer:5-7 parts, LLDPE:2-5 parts, high density polyethylene (HDPE):5-7 parts;
Composition B includes following components by weight:Phenolic resin:57-60 parts, polyphenylene oxide resin powder:23-25 parts, carbon Sour sodium 5-7 parts, epoxy resin:5-7 parts, methyl methacrylate:11-13 parts, butyl acrylate:15-17 parts, filler:20-23 Part, coupling agent:5-7 parts, diluent:10-13 parts, antistatic additive:5-7 parts, catalyst:13-15 parts;
Catalyst includes following components by weight:Epoxy resin:31-36 parts, polyphenylene oxide resin powder:20-24 parts, butylbenzene Rubber:10-14 parts, toluene:5-8 parts, ammonium phosphate:4-7 parts.
The technical scheme that further limits of the present invention is:
Foregoing environment-friendly and energy-efficient high-performance multiple grinding piece, wherein, filler be coarse whiting, fine particle calcium carbonate, chalky soil, diatomite or At least one of wollastonite powder;Surfactant is aliphatic sulfonic compound, alkyl aryl sulphonic acid compound, Span At least one of or polyoxyethylene sorbitan fatty acid ester;Diluent is methanol, acetone, ethyl acetate, ethylene glycol list At least one of ether, diethylene glycol ether or water;Coupling agent is at least one of silane coupler or zirconium class coupling agent; The fire retardant is phosphotriester;Antistatic additive is anionic antistatic agent, cationic antistatic agent or non-ionic anti- At least one of electrostatic agent.
Foregoing environment-friendly and energy-efficient high-performance multiple grinding piece, wherein adhesive by weight than the composition A for 57% and 43% composition B is mixed;Composition A includes following components by weight:Phenolic resin:36 parts, trimethylolpropane tris Acrylate:11 parts, filler:15 parts, surfactant:3 parts, diluent:10 parts, coupling agent:4 parts, fire retardant:2 parts, second Alkene-acetate ethylene copolymer:5 parts, LLDPE:2 parts, high density polyethylene (HDPE):5 parts;Composition B is wrapped by weight Include following components:Phenolic resin:57 parts, polyphenylene oxide resin powder:23 parts, 5 parts of sodium carbonate, epoxy resin:5 parts, methacrylic acid Methyl esters:11 parts, butyl acrylate:15 parts, filler:20 parts, coupling agent:5 parts, diluent:10 parts, antistatic additive:5 parts, catalysis Agent:13 parts;Catalyst includes following components by weight:Epoxy resin:31 parts, polyphenylene oxide resin powder:20 parts, butadiene-styrene rubber: 10 parts, toluene:5 parts, ammonium phosphate:4 parts.
Foregoing environment-friendly and energy-efficient high-performance multiple grinding piece, wherein adhesive by weight than the composition A for 60% and 40% composition B is mixed;Composition A includes following components by weight:Phenolic resin:38 parts, trimethylolpropane tris Acrylate:20 parts, filler:16 parts, surfactant:4 parts, diluent:12 parts, coupling agent:5 parts, fire retardant:5 parts, second Alkene-acetate ethylene copolymer:6 parts, LLDPE:3 parts, high density polyethylene (HDPE):6 parts;Composition B is wrapped by weight Include following components:Phenolic resin:58 parts, polyphenylene oxide resin powder:24 parts, 6 parts of sodium carbonate, epoxy resin:6 parts, methacrylic acid Methyl esters:12 parts, butyl acrylate:16 parts, filler:22 parts, coupling agent:6 parts, diluent:12 parts, antistatic additive:6 parts, catalysis Agent:14 parts;Catalyst includes following components by weight:Epoxy resin:33 parts, polyphenylene oxide resin powder:22 parts, butadiene-styrene rubber: 13 parts, toluene:7 parts, ammonium phosphate:5 parts.
Foregoing environment-friendly and energy-efficient high-performance multiple grinding piece, wherein adhesive by weight than the composition A for 65% and 35% composition B is mixed;Composition A includes following components by weight:Phenolic resin:40 parts, trimethylolpropane tris Acrylate:25 parts, filler:17 parts, surfactant:5 parts, diluent:13 parts, coupling agent:6 parts, fire retardant:8 parts, second Alkene-acetate ethylene copolymer:7 parts, LLDPE:5 parts, high density polyethylene (HDPE):7 parts;Composition B is wrapped by weight Include following components:Phenolic resin:60 parts, polyphenylene oxide resin powder:25 parts, 7 parts of sodium carbonate, epoxy resin:7 parts, methacrylic acid Methyl esters:13 parts, butyl acrylate:17 parts, filler:23 parts, coupling agent:7 parts, diluent:13 parts, antistatic additive:7 parts, catalysis Agent:15 parts;Catalyst includes following components by weight:Epoxy resin:36 parts, polyphenylene oxide resin powder:24 parts, butadiene-styrene rubber: 14 parts, toluene:8 parts, ammonium phosphate:7 parts.
The beneficial effects of the invention are as follows:
The present invention adds trimethylolpropane trimethacrylate, polyphenylene oxide resin powder, carbonic acid by the mixing of each composition Sodium, epoxy resin, methyl methacrylate, butyl acrylate makes product have adhesion strength high, water-fast, antiacid, good weatherability etc. Advantage, and cause the more soft folding of sand paper product.
Fire retardant is added with the adhesive components of the present invention, because aluminum oxide flame retardant effect is poor, in polishing, grinding The heat-resisting quantity of piece directly affects its performance, increases phosphotriester fire retardant, improves heat-resisting quantity while enhancing mill Cut performance.
Catalyst is added in invention adhesive, preferably improves the water resistance and adhesive property of grinding tool, it is possible to make Abrasive surface is kept as more smooth, rationally can effectively control internal stresses release, reduce product deformation;Simultaneously as urging The presence of agent, can improve the rate of drying of grinding tool production process, so as to greatly improve production efficiency, serve imaginary Less than technique effect.
Sharp quick, the service life length of abrasive sheet in the present invention, polishing high heat resistance, splendid moisture resistance, are being manufactured In can effectively prevent deformation, product tensile strength is big, and adhesive property is good, and grinding performance is strong.
Embodiment
Embodiment 1
The present embodiment is a kind of environment-friendly and energy-efficient high-performance multiple grinding piece, wherein adhesive by weight than the group for 57% Compound A and 43% composition B is mixed;Composition A includes following components by weight:Phenolic resin:36 parts, three hydroxyl first Base propane triacrylate:11 parts, filler:15 parts, surfactant:3 parts, diluent:10 parts, coupling agent:4 parts, fire retardant: 2 parts, ethylene-vinyl acetate copolymer:5 parts, LLDPE:2 parts, high density polyethylene (HDPE):5 parts;Composition B is by weight Measuring part includes following components:Phenolic resin:57 parts, polyphenylene oxide resin powder:23 parts, 5 parts of sodium carbonate, epoxy resin:5 parts, methyl Methyl acrylate:11 parts, butyl acrylate:15 parts, filler:20 parts, coupling agent:5 parts, diluent:10 parts, antistatic additive:5 Part, catalyst:13 parts;Catalyst includes following components by weight:Epoxy resin:31 parts, polyphenylene oxide resin powder:20 parts, fourth Benzene rubber:10 parts, toluene:5 parts, ammonium phosphate:4 parts.
Wherein, filler is at least one of coarse whiting, fine particle calcium carbonate, chalky soil, diatomite or wollastonite powder;Surfactant is fat In fat race azochlorosulfonate acid compound, alkyl aryl sulphonic acid compound, Span or polyoxyethylene sorbitan fatty acid ester It is at least one;Diluent is at least one in methanol, acetone, ethyl acetate, ethylene glycol monoethyl ether, diethylene glycol ether or water Kind;Coupling agent is at least one of silane coupler or zirconium class coupling agent;The fire retardant is phosphotriester;Antistatic additive is At least one of anionic antistatic agent, cationic antistatic agent or non-ionic antistatic agent.
Embodiment 2
The present embodiment is a kind of environment-friendly and energy-efficient high-performance multiple grinding piece, wherein adhesive by weight than the group for 60% Compound A and 40% composition B is mixed;Composition A includes following components by weight:Phenolic resin:38 parts, three hydroxyl first Base propane triacrylate:20 parts, filler:16 parts, surfactant:4 parts, diluent:12 parts, coupling agent:5 parts, fire retardant: 5 parts, ethylene-vinyl acetate copolymer:6 parts, LLDPE:3 parts, high density polyethylene (HDPE):6 parts;Composition B is by weight Measuring part includes following components:Phenolic resin:58 parts, polyphenylene oxide resin powder:24 parts, 6 parts of sodium carbonate, epoxy resin:6 parts, methyl Methyl acrylate:12 parts, butyl acrylate:16 parts, filler:22 parts, coupling agent:6 parts, diluent:12 parts, antistatic additive:6 Part, catalyst:14 parts;Catalyst includes following components by weight:Epoxy resin:33 parts, polyphenylene oxide resin powder:22 parts, fourth Benzene rubber:13 parts, toluene:7 parts, ammonium phosphate:5 parts.
Wherein, filler is at least one of coarse whiting, fine particle calcium carbonate, chalky soil, diatomite or wollastonite powder;Surfactant is fat In fat race azochlorosulfonate acid compound, alkyl aryl sulphonic acid compound, Span or polyoxyethylene sorbitan fatty acid ester It is at least one;Diluent is at least one in methanol, acetone, ethyl acetate, ethylene glycol monoethyl ether, diethylene glycol ether or water Kind;Coupling agent is at least one of silane coupler or zirconium class coupling agent;The fire retardant is phosphotriester;Antistatic additive is At least one of anionic antistatic agent, cationic antistatic agent or non-ionic antistatic agent.
Embodiment 3
The present embodiment is a kind of environment-friendly and energy-efficient high-performance multiple grinding piece, wherein adhesive by weight than the group for 65% Compound A and 35% composition B is mixed;Composition A includes following components by weight:Phenolic resin:40 parts, three hydroxyl first Base propane triacrylate:25 parts, filler:17 parts, surfactant:5 parts, diluent:13 parts, coupling agent:6 parts, fire retardant: 8 parts, ethylene-vinyl acetate copolymer:7 parts, LLDPE:5 parts, high density polyethylene (HDPE):7 parts;Composition B is by weight Measuring part includes following components:Phenolic resin:60 parts, polyphenylene oxide resin powder:25 parts, 7 parts of sodium carbonate, epoxy resin:7 parts, methyl Methyl acrylate:13 parts, butyl acrylate:17 parts, filler:23 parts, coupling agent:7 parts, diluent:13 parts, antistatic additive:7 Part, catalyst:15 parts;Catalyst includes following components by weight:Epoxy resin:36 parts, polyphenylene oxide resin powder:24 parts, fourth Benzene rubber:14 parts, toluene:8 parts, ammonium phosphate:7 parts.
Wherein, filler is at least one of coarse whiting, fine particle calcium carbonate, chalky soil, diatomite or wollastonite powder;Surfactant is fat In fat race azochlorosulfonate acid compound, alkyl aryl sulphonic acid compound, Span or polyoxyethylene sorbitan fatty acid ester It is at least one;Diluent is at least one in methanol, acetone, ethyl acetate, ethylene glycol monoethyl ether, diethylene glycol ether or water Kind;Coupling agent is at least one of silane coupler or zirconium class coupling agent;The fire retardant is phosphotriester;Antistatic additive is At least one of anionic antistatic agent, cationic antistatic agent or non-ionic antistatic agent.
In addition to the implementation, the present invention can also have other embodiment.All use equivalent substitution or equivalent transformation shape Into technical scheme, all fall within the protection domain of application claims.

Claims (5)

1. a kind of environment-friendly and energy-efficient high-performance multiple grinding piece, including substrate, adhesive and abrasive material, the abrasive material pass through adhesive It is attached in substrate, it is characterised in that:
Composition B of the adhesive by weight than composition A and 35-43% for 57-65% is mixed;
The composition A includes following components by weight:Phenolic resin:36-40 parts, trimethylolpropane trimethacrylate: 11-25 parts, filler:15-17 parts, surfactant:3-5 parts, diluent:10-13 parts, coupling agent:4-6 parts, fire retardant:2-8 Part, ethylene-vinyl acetate copolymer:5-7 parts, LLDPE:2-5 parts, high density polyethylene (HDPE):5-7 parts;
The composition B includes following components by weight:Phenolic resin:57-60 parts, polyphenylene oxide resin powder:23-25 parts, carbon Sour sodium 5-7 parts, epoxy resin:5-7 parts, methyl methacrylate:11-13 parts, butyl acrylate:15-17 parts, filler:20-23 Part, coupling agent:5-7 parts, diluent:10-13 parts, antistatic additive:5-7 parts, catalyst:13-15 parts;
The catalyst includes following components by weight:Epoxy resin:31-36 parts, polyphenylene oxide resin powder:20-24 parts, butylbenzene Rubber:10-14 parts, toluene:5-8 parts, ammonium phosphate:4-7 parts.
2. environment-friendly and energy-efficient high-performance multiple grinding piece as claimed in claim 1, it is characterised in that:The filler be coarse whiting, At least one of fine particle calcium carbonate, chalky soil, diatomite or wollastonite powder;The surfactant is aliphatic sulfonic compound, alkyl virtue At least one of base azochlorosulfonate acid compound, Span or polyoxyethylene sorbitan fatty acid ester;The diluent It is at least one of methanol, acetone, ethyl acetate, ethylene glycol monoethyl ether, diethylene glycol ether or water;The coupling agent is silicon At least one of alkane coupling agent or zirconium class coupling agent;The fire retardant is phosphotriester;The antistatic additive is anionic At least one of antistatic additive, cationic antistatic agent or non-ionic antistatic agent.
3. environment-friendly and energy-efficient high-performance multiple grinding piece as claimed in claim 1 or 2, it is characterised in that:The adhesive by Weight is mixed than the composition B of the composition A and 43% for 57%;
The composition A includes following components by weight:Phenolic resin:36 parts, trimethylolpropane trimethacrylate:11 Part, filler:15 parts, surfactant:3 parts, diluent:10 parts, coupling agent:4 parts, fire retardant:2 parts, ethene-vinyl acetate is common Polymers:5 parts, LLDPE:2 parts, high density polyethylene (HDPE):5 parts;
The composition B includes following components by weight:Phenolic resin:57 parts, polyphenylene oxide resin powder:23 parts, sodium carbonate 5 Part, epoxy resin:5 parts, methyl methacrylate:11 parts, butyl acrylate:15 parts, filler:20 parts, coupling agent:5 parts, dilution Agent:10 parts, antistatic additive:5 parts, catalyst:13 parts;
The catalyst includes following components by weight:Epoxy resin:31 parts, polyphenylene oxide resin powder:20 parts, butadiene-styrene rubber: 10 parts, toluene:5 parts, ammonium phosphate:4 parts.
4. environment-friendly and energy-efficient high-performance multiple grinding piece as claimed in claim 1 or 2, it is characterised in that:The adhesive by Weight is mixed than the composition B of the composition A and 40% for 60%;
The composition A includes following components by weight:Phenolic resin:38 parts, trimethylolpropane trimethacrylate:20 Part, filler:16 parts, surfactant:4 parts, diluent:12 parts, coupling agent:5 parts, fire retardant:5 parts, ethene-vinyl acetate is common Polymers:6 parts, LLDPE:3 parts, high density polyethylene (HDPE):6 parts;
The composition B includes following components by weight:Phenolic resin:58 parts, polyphenylene oxide resin powder:24 parts, sodium carbonate 6 Part, epoxy resin:6 parts, methyl methacrylate:12 parts, butyl acrylate:16 parts, filler:22 parts, coupling agent:6 parts, dilution Agent:12 parts, antistatic additive:6 parts, catalyst:14 parts;
The catalyst includes following components by weight:Epoxy resin:33 parts, polyphenylene oxide resin powder:22 parts, butadiene-styrene rubber: 13 parts, toluene:7 parts, ammonium phosphate:5 parts.
5. environment-friendly and energy-efficient high-performance multiple grinding piece as claimed in claim 1 or 2, it is characterised in that:The adhesive by Weight is mixed than the composition B of the composition A and 35% for 65%;
The composition A includes following components by weight:Phenolic resin:40 parts, trimethylolpropane trimethacrylate:25 Part, filler:17 parts, surfactant:5 parts, diluent:13 parts, coupling agent:6 parts, fire retardant:8 parts, ethene-vinyl acetate is common Polymers:7 parts, LLDPE:5 parts, high density polyethylene (HDPE):7 parts;
The composition B includes following components by weight:Phenolic resin:60 parts, polyphenylene oxide resin powder:25 parts, sodium carbonate 7 Part, epoxy resin:7 parts, methyl methacrylate:13 parts, butyl acrylate:17 parts, filler:23 parts, coupling agent:7 parts, dilution Agent:13 parts, antistatic additive:7 parts, catalyst:15 parts;
The catalyst includes following components by weight:Epoxy resin:36 parts, polyphenylene oxide resin powder:24 parts, butadiene-styrene rubber: 14 parts, toluene:8 parts, ammonium phosphate:7 parts.
CN201510832861.0A 2015-11-26 2015-11-26 A kind of environment-friendly and energy-efficient high-performance multiple grinding piece Active CN105500182B (en)

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CN107127686A (en) * 2017-05-31 2017-09-05 江苏省江南新型复合研磨材料及制品工程技术研究中心有限公司 A kind of environment-friendly and energy-efficient multiple grinding piece of high service life
CN107236341A (en) * 2017-06-09 2017-10-10 江苏省江南新型复合研磨材料及制品工程技术研究中心有限公司 A kind of antistatic adhesive of high bond strength for coated abrasive tool
CN107418457A (en) * 2017-06-09 2017-12-01 江苏省江南新型复合研磨材料及制品工程技术研究中心有限公司 A kind of high bond strength high-temperature resistance adhesive for coated abrasive tool
CN113231919A (en) * 2021-05-10 2021-08-10 南通瑞景光电科技有限公司 Environment-friendly grinding process for optical element

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