CN105482298A - High heatproof embossing fancy polyvinyl chloride sheet and preparation method thereof - Google Patents
High heatproof embossing fancy polyvinyl chloride sheet and preparation method thereof Download PDFInfo
- Publication number
- CN105482298A CN105482298A CN201510948004.7A CN201510948004A CN105482298A CN 105482298 A CN105482298 A CN 105482298A CN 201510948004 A CN201510948004 A CN 201510948004A CN 105482298 A CN105482298 A CN 105482298A
- Authority
- CN
- China
- Prior art keywords
- sheet material
- weight ratio
- resisting
- mixture
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B13/00—Conditioning or physical treatment of the material to be shaped
- B29B13/10—Conditioning or physical treatment of the material to be shaped by grinding, e.g. by triturating; by sieving; by filtering
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/22—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
- B29C43/24—Calendering
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/58—Measuring, controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/58—Measuring, controlling or regulating
- B29C2043/5816—Measuring, controlling or regulating temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2427/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2427/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
The invention relates to the technical field of sheets, in particular to a high heatproof embossing fancy polyvinyl chloride sheet and a preparation method thereof. The high heatproof embossing fancy polyvinyl chloride sheet comprises, by weight parts, 70-90 parts of polyvinyl chloride (PVC) resin, 20-40 parts of plasticizer, 2-4 parts of heat stabilizer, 1-5 parts of heat-resistant modifier, 1-5 parts of antioxidant and 5-9 parts of lubricant. By the adoption of the raw materials and strict control of the weight ratio of the raw materials, the manufactured sheet is good in heat-resisting effect and resistant to cold, acid, alkali, high pressure, aging and static electricity, the surface is smooth, and the high heatproof embossing fancy polyvinyl chloride sheet is free of cracks and bubbles, uniform in color, high in three-dimensional performance, soft in texture, comfortable in touch, healthy and environmentally friendly.
Description
Technical field
The present invention relates to sheet technology field, be specifically related to a kind of high heat-resisting embossing folder flower polychlorovinyl sheet material and preparation method thereof.
Background technology
Soft PVC sheet material transparent attractive in appearance, quality is soft, has been widely used in everyday articles field, as the tablecloth, mat applying and table mat etc.This based article is generally enclose transparent film at the another side of printed patterns, when cover furniture especially on glass furniture time, both can show the printed patterns on transparent film, and the pattern of furniture can have been observed again through transparent film, play good decorative effect.But existing sheet material printed patterns is all the surface being printed on plastic basic unit, easily scratches, fade during use, variable color, fade, life cycle is short; And the resistance toheat of sheet material is poor, poor-performing under some hot conditionss.
Summary of the invention
In order to overcome the shortcoming and defect existed in prior art, the object of the present invention is to provide a kind of high heat-resisting embossing folder flower polychlorovinyl sheet material, this sheet material heat-resisting effect is good, and cold-resistant, acidproof, alkaline-resisting, resistant to pressure, anti-aging, antistatic, smooth surface, leakless, bubble-free, uniform color, stereoscopic sensation is strong, quality is soft, hand feel and drape, health environment-friendly.
Another object of the present invention is to the preparation method that a kind of high heat-resisting embossing folder flower polychlorovinyl sheet material is provided.This preparation method's technique is simple, and convenient operation and control, steady quality, production efficiency is high, and production cost is low, can large-scale industrial production.
Object of the present invention is achieved through the following technical solutions: a kind of high heat-resisting embossing folder flower polychlorovinyl sheet material, and described height heat-resisting embossing folder flower polychlorovinyl sheet material comprises the raw material of following weight part:
Polyvinyl chloride resin 70-90 part
Softening agent 20-40 part
Thermo-stabilizer 2-4 part
Heat-proof modifier 1-5 part
Oxidation inhibitor 1-5 part
Lubricant 5-9 part.
Sheet material of the present invention is by adopting above-mentioned raw materials, and the strict weight proportion controlling each raw material, obtained sheet material heat-resisting effect is good, and cold-resistant, acidproof, alkaline-resisting, resistant to pressure, anti-aging, antistatic, smooth surface, leakless, bubble-free, uniform color, stereoscopic sensation is strong, quality is soft, hand feel and drape, health environment-friendly.
Preferably, the mixture that is made up of with weight ratio 1:2-4 calcium carbide process PVC resin and ethylene process polyvinyl chloride resin of described polyvinyl chloride resin.
The present invention adopts calcium carbide process PVC resin and ethylene process polyvinyl chloride resin as the composite use of raw material, and to control its weight ratio be 1:2-4, makes plasticize speed fast, easily processes.
The mixture that described softening agent is made up of with weight ratio 1:0.8-1.2:1.5-2.5 epoxy soybean oil, triethyl citrate and synthesis vegetable esters.
The present invention adopts epoxy soybean oil, triethyl citrate and synthesis vegetable esters as the composite use of softening agent, three kinds of softening agent are environment-friendly plasticizer, the reactive force between PVC molecular chain can be reduced, the fusing point of the second-order transition temperature of PVC plastic, yield temperature and contained crystallite is all reduced, softening agent can improve the plasticity-of resin, makes goods softness, resistance to low temperature good; And when the use composite with weight ratio 1:0.8-1.2:1.5-2.5 of three kinds of softening agent, flexibility and the resistance to low temperature of goods can be improved.
Preferably, the mixture that is made up of with weight ratio 1:0.8-1.2 Ca-Zn composite heat stabilizer and hydrotalcite thermal stabilizer of described thermo-stabilizer.
Ca-Zn composite heat stabilizer not only can replace the poisonous stablizers such as plumbous cadmium salt class and organic tin, and has goodish thermostability, light stability and the transparency and tinting strength.Facts have proved, in polyvinyl chloride resin goods, good processability, heat stabilization is equivalent to lead salt stabilizer, is a kind of good non-toxic stabilizer.
Hydrotalcite stablizer has high thermal stability: distinctive sour absorption mechanism, result in its thermostability of thermostability higher than lead base; High transparent: have identical specific refractory power with PVC; High-insulativity: by anion exchange reaction, absorbed muriate can not discharge, and insulativity is splendid; High security: hydrotalcite can be applicable in the food pack of polymer materials; Good weathering resistance (environmental compatibility is strong), can not produce sulfide staining: can with various thermo-stabilizer with the use of.
The present invention is by adopting Ca-Zn composite heat stabilizer and hydrotalcite thermal stabilizer as the composite use of thermo-stabilizer, and to control its weight ratio be 1:0.8-1.2, can make material in the course of processing, have good dispersiveness, consistency and processing fluidity, make material good heat stability, there is efficient weathering resistance.
The mixture that described Ca-Zn composite heat stabilizer is made up of with weight ratio 0.5-1.5:1:0.5-1.5:0.8-1.2 calcium stearate, ricinolic acid calcium, Zinic stearas and zinc ricinate.
The present invention is by adopting calcium stearate, ricinolic acid calcium, Zinic stearas and zinc ricinate as Ca-Zn composite heat stabilizer, and to control its weight ratio be 0.5-1.5:1:0.5-1.5:0.8-1.2, there is goodish thermostability, light stability and the transparency and tinting strength, and good processability.
Preferably, the mixture that is made up of with weight ratio 1.5-2.5:1 N-phenylmaleimide/fine terpolymer of vinylbenzene/propylene and alpha-methyl styrene/styrene/acrylonitrile terpolymer of described heat-proof modifier.
N-phenylmaleimide/fine terpolymer of vinylbenzene/propylene (PhMI-St-AN), as the heat-proof modifier of polyvinyl chloride, can improve the heat-drawn wire of polyvinyl chloride.Described N-phenylmaleimide/fine terpolymer of vinylbenzene/propylene is the N-phenylmaleimide/fine terpolymer of vinylbenzene/propylene of N-phenylmaleimide unit content 10% ~ 30%, and the resistance toheat of N-phenylmaleimide/fine terpolymer of vinylbenzene/propylene improves with the increase of N-phenylmaleimide content.
The heat-drawn wire of alpha-methyl styrene/styrene/acrylonitrile terpolymer (α-MeST-St-AN) is close to 120 DEG C, the heat resisting temperature of modified resin generally can be made to improve more than 10 DEG C, even more than 30 DEG C can be improved for polyvinyl chloride resin, while improving thermotolerance, also improve the impact property of resin.Described alpha-methyl styrene/styrene/acrylonitrile terpolymer is the alpha-methyl styrene/styrene/acrylonitrile terpolymer of alpha-methyl styrene unit content 40% ~ 60%, within the scope of this, the resistance toheat of alpha-methyl styrene/styrene/acrylonitrile terpolymer improves greatly.
The present invention is by adopting N-phenylmaleimide/fine terpolymer of vinylbenzene/propylene and alpha-methyl styrene/styrene/acrylonitrile terpolymer as the composite use of heat-proof modifier, and to control its weight ratio be to improve the resistance to elevated temperatures of material, the consistency of material, impact and processibility can also be improved.
Preferably, the mixture that is made up of with weight ratio 1-2:1 antioxidant 1010 and irgasfos 168 of described oxidation inhibitor.
The present invention is by adopting antioxidant 1010 and irgasfos 168 as the composite use of oxidation inhibitor, and to control its weight ratio be 1-2:1, can delay or suppress the carrying out of material oxidation process, thus prevention material aging extend its work-ing life.
Preferably, the mixture that is made up of with weight ratio 1.5-2.5:1:0.8-1.2 oxidized polyethlene wax, pentaerythritol stearate and ethylene bis stearic acid amide of described lubricant.
The present invention adopts oxidized polyethlene wax as external lubricant, can reduce the friction of PVC melt and mould, machine barrel; Adopt pentaerythritol stearate and ethylene bis stearic acid amide as internal lubricant, the intermolecular friction of PVC melt can be reduced; Three kinds of lubricants can make material in the course of processing, improve the mobility of material and the release property of goods with the composite use of weight ratio 1.5-2.5:1:0.8-1.2.
Preferably, described height heat-resisting embossing folder flower polychlorovinyl sheet material also comprises weighting agent 10-20 part and impact modifier 1-5 part, and described weighting agent is that particle diameter is at 1-10nm and through the nano-calcium carbonate of silane coupling agent process.
The particle diameter of weighting agent is less, to the tensile strength of packing material and shock strength more useful, the present invention, by adopting nano-calcium carbonate as weighting agent and controlling its particle diameter at 1-10nm, can improve the intensity of material; Weighting agent and the good consistency of resin play its key acting on and control addition, and the present invention adopts the nano-calcium carbonate through silane coupling agent process, can improve the consistency of nano-calcium carbonate and polyvinyl chloride resin, thus the intensity of raising material.
Described impact modifier is the mixture that the chlorinatedpolyethylene of 25%-45% and the ethylene-vinyl acetate copolymer of vinyl acetate between to for plastic unit content 5%-25% form with weight ratio 1.5-2.5:1 by chlorinity.
Chlorinatedpolyethylene (CPE) is a kind of properties-correcting agent of thermoplastics, has good over-all properties.Appropriate CPE is added, the processing characteristics that can reduce the melt viscosity of resin, improve mobility, improve plastics in polyvinyl chloride (PVC) resin; The work-ing life of the shock strength of PVC, resistance to low temperature, weathering performance, prolongation goods can also be improved.CPE is added in calcic-plastic composite material, not only can replace Plasticizer DBP, also contributes to the dispersed of calcium carbonate and polyvinyl chloride resin; And when the chlorinity (weight content) of chlorinatedpolyethylene is for 25%-45%, make the resistance to impact shock of material best.
Ethylene-vinyl acetate copolymer (EVA) can be used as the impact modifying agent of PVC, has good flexibility, obdurability, lower temperature resistance (-58 DEG C still have pliability), weathering resistance, stress cracking resistance, heat sealer, agglutinating value(of coal), the transparency and glossiness; Also there is the elasticity as rubber simultaneously, excellent chemical stability, thermostability (heat decomposition temperature 229 ~ 230 DEG C), ozone resistance, nontoxicity, good processibility and dyeability; Fine with the miscibility of filler, even if fill more filler, also unlikelyly have a strong impact on its physical and mechanical property.
EVA is as the impact modifying agent of PVC, its effect is different with the content of vinyl acetate between to for plastic in multipolymer, when the content of vinyl acetate between to for plastic is low, with the poor compatibility of PVC, reinforced effects is poor, and goods are opaque, along with the increase of vinyl acetate between to for plastic unit content, the consistency of multipolymer and PVC improves, and reinforced effects improves, and the goods transparency is also better; But the content of vinyl acetate between to for plastic also can not be too high, during vinyl acetate between to for plastic unit content 5%-25%, obviously can improve the shock strength of PVC, compared with the impact modifying agent containing carbon-carbon double bond, also there is the good advantage of ageing resistance.
The present invention is by adopting chlorinatedpolyethylene and ethylene-vinyl acetate copolymer as the composite use of impact modifier, and to control its weight ratio be 1.5-2.5:1, the high temperature resistant of material and resistance to low temperature can be improved, the processing characteristics that can also reduce the melt viscosity of material, improve mobility, improve plastics, improves the work-ing life of the shock strength of material, weathering performance, prolongation goods.
Preferably, described height heat-resisting embossing folder flower polychlorovinyl sheet material also comprises fire retardant 1-5 part, slipping agent 0.05-0.15 part and pigment powder 0.01-0.05 part; The mixture that described fire retardant is made up of with weight ratio 0.5-1.5:1 antimonous oxide and zinc borate.
Antimony peroxide and lime borate are inorganic environment-friendly fire retardant, the present invention is by adopting antimonous oxide and zinc borate as the composite use of fire retardant, and to control its weight ratio be 0.5-1.5:1, good flame retardant effect can be reached, Drawing abillity and mechanical property can also be improved.
Described slipping agent is the mixture be made up of with weight ratio 1.5-2.5:0.8-1.2:1 erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide.
The present invention is by adopting erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide is as slipping agent and to control its weight ratio be 1.5-2.5:0.8-1.2:1, mechanical resistant stirring capacity and fingerprinting stress can be strengthened, finished product good forming effect, any surface finish, the extensibility of finished product can also be strengthened, easy-to-draw not easily broken.
Described pigment powder is particle diameter at the titanium dioxide of 1-5 μm; The mixture that described titanium dioxide is made up of with weight ratio 1:1.5-2.5 Rutile type Titanium Dioxide and anatase thpe white powder.
The present invention adopts particle diameter at the titanium dioxide of 1-5 μm as pigment powder, further employing Rutile type Titanium Dioxide and the composite use of anatase thpe white powder, and to control its weight ratio be 1:1.5-2.5, there is superior whiteness, tinting strength, opacifying power, weathering resistance, thermotolerance and chemical stability, particularly there is no toxicity.
Another object of the present invention is achieved through the following technical solutions: a kind of preparation method of high heat-resisting embossing folder flower polychlorovinyl sheet material, comprises the steps:
A, raw material prepare: take each raw material by above-mentioned raw materials composition, mixing;
B, high-speed stirring: mixed raw material is put into high speed blender, stir 8-12min at 110-120 DEG C of temperature, and the rotating speed of stirring is 580-1160RPM;
C, once plasticizing: the raw material after stirring is carried out first time plasticizing through planetary extruder at 140-160 DEG C of temperature, obtains micelle;
D, secondary plasticizing: the micelle after first time plasticizing is carried out second time plasticizing, until evenly through pricking turbine at 130-150 DEG C of temperature;
E, level filter: adopt 20 orders/￠ 323mm, 60 orders/￠ 323mm, 120 orders/￠ 323mm and 150 orders/￠ 323mm stainless steel filter screen to filter successively through filter in the micelle after second time plasticizing, the screw speed of filter is 50-70RPM;
F, calendering formation: by the micelle after filtration through rolling press calendering formation, obtain sheet material;
G, transfer printing laminating: the sheet material after shaping is fitted through laminating transfer machine preheating transfer printing again, pattern is transferred to sheet material from the preheating of OPP transfer film, then another sheet material of fitting; Sheet material after laminating is carried out embossed;
H, cooling rolling: the sheet material after embossed is carried out cooling and shaping through drawing cooling wheel, then carries out rolling through winder, obtain high heat-resisting embossing folder flower polychlorovinyl sheet material.
Preparation method's technique of the present invention is simple, and convenient operation and control, steady quality, production efficiency is high, and production cost is low, can large-scale industrial production.
Preferably, in described step F, rolling press is six roll calendars, and the temperature of each roller is followed successively by: 170-180 DEG C, 170-180 DEG C, 190-200 DEG C, 190-200 DEG C, 178-188 DEG C and 178-188 DEG C; In described step G, hot transfer temperature is 120-135 DEG C, and binding temperature is 130-155 DEG C.
Beneficial effect of the present invention is: sheet material heat-resisting effect of the present invention is good, and cold-resistant, acidproof, alkaline-resisting, resistant to pressure, anti-aging, antistatic, smooth surface, leakless, bubble-free, uniform color, stereoscopic sensation is strong, and quality is soft, hand feel and drape, health environment-friendly.
Preparation method's technique of the present invention is simple, and convenient operation and control, steady quality, production efficiency is high, and production cost is low, can large-scale industrial production.
Embodiment
For the ease of the understanding of those skilled in the art, below in conjunction with embodiment, the present invention is further illustrated, and the content that embodiment is mentioned not is limitation of the invention.
Embodiment 1
A kind of high heat-resisting embossing folder flower polychlorovinyl sheet material, described height heat-resisting embossing folder flower polychlorovinyl sheet material comprises the raw material of following weight part:
Polyvinyl chloride resin 70 parts
20 parts, softening agent
Thermo-stabilizer 2 parts
Heat-proof modifier 1 part
1 part, oxidation inhibitor
Lubricant 5 parts.
The mixture that described polyvinyl chloride resin is made up of with weight ratio 1:2 calcium carbide process PVC resin and ethylene process polyvinyl chloride resin; The mixture that described softening agent is made up of with weight ratio 1:0.8:1.5 epoxy soybean oil, triethyl citrate and synthesis vegetable esters.
The mixture that described thermo-stabilizer is made up of with weight ratio 1:0.8 Ca-Zn composite heat stabilizer and hydrotalcite thermal stabilizer; The mixture that described Ca-Zn composite heat stabilizer is made up of with weight ratio 0.5:1:0.5:0.8 calcium stearate, ricinolic acid calcium, Zinic stearas and zinc ricinate.
The mixture that described heat-proof modifier is made up of with weight ratio 1.5:1 N-phenylmaleimide/fine terpolymer of vinylbenzene/propylene and alpha-methyl styrene/styrene/acrylonitrile terpolymer.
The mixture that described oxidation inhibitor is made up of with weight ratio 1:1 antioxidant 1010 and irgasfos 168.
The mixture that described lubricant is made up of with weight ratio 1.5:1:0.8 oxidized polyethlene wax, pentaerythritol stearate and ethylene bis stearic acid amide.
Described height heat-resisting embossing folder flower polychlorovinyl sheet material also comprises weighting agent 10 parts and impact modifier 1 part, and described weighting agent is that particle diameter is at 1nm and through the nano-calcium carbonate of silane coupling agent process; Described impact modifier is the mixture that the chlorinatedpolyethylene of 25% and the ethylene-vinyl acetate copolymer of vinyl acetate between to for plastic unit content 5% form with weight ratio 1.5:1 by chlorinity.
Described height heat-resisting embossing folder flower polychlorovinyl sheet material also comprises fire retardant 1 part, slipping agent 0.05 part and 0.01 part, pigment powder; The mixture that described fire retardant is made up of with weight ratio 1.1:1 antimonous oxide and zinc borate; Described slipping agent is the mixture be made up of with weight ratio 1.5:0.8:1 erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide; Described pigment powder is particle diameter at the titanium dioxide of 1 μm; The mixture that described titanium dioxide is made up of with weight ratio 1:1.5 Rutile type Titanium Dioxide and anatase thpe white powder.
A preparation method for high heat-resisting embossing folder flower polychlorovinyl sheet material, comprises the steps:
A, raw material prepare: take each raw material by above-mentioned raw materials composition, mixing;
B, high-speed stirring: mixed raw material is put into high speed blender, stir 8min at 110 DEG C of temperature, and the rotating speed of stirring is 580RPM;
C, once plasticizing: the raw material after stirring is carried out first time plasticizing through planetary extruder at 140 DEG C of temperature, obtains micelle;
D, secondary plasticizing: the micelle after first time plasticizing is carried out second time plasticizing, until evenly through pricking turbine at 130 DEG C of temperature;
E, level filter: adopt 20 orders/￠ 323mm, 60 orders/￠ 323mm, 120 orders/￠ 323mm, 150 orders/￠ 323mm stainless steel filter screen to filter successively through filter in the micelle after second time plasticizing, the screw speed of filter is 50RPM;
F, calendering formation: by the micelle after filtration through rolling press calendering formation, obtain sheet material;
G, transfer printing laminating: fitted through laminating transfer machine preheating transfer printing by the sheet material after shaping again, pattern is transferred to sheet material from the preheating of OPP transfer film, then another sheet material of fitting, carry out embossed by the sheet material after laminating;
H, cooling rolling: the sheet material after embossed is carried out cooling and shaping through drawing cooling wheel, then carries out rolling through winder, obtain high heat-resisting embossing folder flower polychlorovinyl sheet material.
In described step F, rolling press is six roll calendars, and the temperature of each roller is followed successively by: 170 DEG C, 170 DEG C, 190 DEG C, 190 DEG C, 178 DEG C and 178 DEG C; In described step G, hot transfer temperature is 120 DEG C, and binding temperature is 130 DEG C.
Embodiment 2
A kind of high heat-resisting embossing folder flower polychlorovinyl sheet material, described height heat-resisting embossing folder flower polychlorovinyl sheet material comprises the raw material of following weight part:
Polyvinyl chloride resin 75 parts
25 parts, softening agent
Thermo-stabilizer 2.5 parts
Heat-proof modifier 2 parts
2 parts, oxidation inhibitor
Lubricant 6 parts.
The mixture that described polyvinyl chloride resin is made up of with weight ratio 1:2.5 calcium carbide process PVC resin and ethylene process polyvinyl chloride resin; The mixture that described softening agent is made up of with weight ratio 1:0.9:1.8 epoxy soybean oil, triethyl citrate and synthesis vegetable esters.
The mixture that described thermo-stabilizer is made up of with weight ratio 1:0.9 Ca-Zn composite heat stabilizer and hydrotalcite thermal stabilizer; The mixture that described Ca-Zn composite heat stabilizer is made up of with weight ratio 0.8:1:0.8:0.9 calcium stearate, ricinolic acid calcium, Zinic stearas and zinc ricinate.
The mixture that described heat-proof modifier is made up of with weight ratio 1.8:1 N-phenylmaleimide/fine terpolymer of vinylbenzene/propylene and alpha-methyl styrene/styrene/acrylonitrile terpolymer.
The mixture that described oxidation inhibitor is made up of with weight ratio 1.2:1 antioxidant 1010 and irgasfos 168.
The mixture that described lubricant is made up of with weight ratio 1.8:1:0.9 oxidized polyethlene wax, pentaerythritol stearate and ethylene bis stearic acid amide.
Described height heat-resisting embossing folder flower polychlorovinyl sheet material also comprises weighting agent 12 parts and impact modifier 2 parts, and described weighting agent is that particle diameter is at 3nm and through the nano-calcium carbonate of silane coupling agent process; Described impact modifier is the mixture that the chlorinatedpolyethylene of 30% and the ethylene-vinyl acetate copolymer of vinyl acetate between to for plastic unit content 10% form with weight ratio 1.8:1 by chlorinity.
Described height heat-resisting embossing folder flower polychlorovinyl sheet material also comprises fire retardant 2 parts, slipping agent 0.08 part and 0.02 part, pigment powder; The mixture that described fire retardant is made up of with weight ratio 1.2:1 antimonous oxide and zinc borate; Described slipping agent is the mixture be made up of with weight ratio 1.8:0.9:1 erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide; Described pigment powder is particle diameter at the titanium dioxide of 2 μm; The mixture that described titanium dioxide is made up of with weight ratio 1:1.8 Rutile type Titanium Dioxide and anatase thpe white powder.
A preparation method for high heat-resisting embossing folder flower polychlorovinyl sheet material, comprises the steps:
A, raw material prepare: take each raw material by above-mentioned raw materials composition, mixing;
B, high-speed stirring: mixed raw material is put into high speed blender, stir 9min at 112 DEG C of temperature, and the rotating speed of stirring is 700RPM;
C, once plasticizing: the raw material after stirring is carried out first time plasticizing through planetary extruder at 145 DEG C of temperature, obtains micelle;
D, secondary plasticizing: the micelle after first time plasticizing is carried out second time plasticizing, until evenly through pricking turbine at 135 DEG C of temperature;
E, level filter: adopt 20 orders/￠ 323mm, 60 orders/￠ 323mm, 120 orders/￠ 323mm, 150 orders/￠ 323mm stainless steel filter screen to filter successively through filter in the micelle after second time plasticizing, the screw speed of filter is 55RPM;
F, calendering formation: by the micelle after filtration through rolling press calendering formation, obtain sheet material;
G, transfer printing laminating: fitted through laminating transfer machine preheating transfer printing by the sheet material after shaping again, pattern is transferred to sheet material from the preheating of OPP transfer film, then another sheet material of fitting, carry out embossed by the sheet material after laminating;
H, cooling rolling: the sheet material after embossed is carried out cooling and shaping through drawing cooling wheel, then carries out rolling through winder, obtain high heat-resisting embossing folder flower polychlorovinyl sheet material.
In described step F, rolling press is six roll calendars, and the temperature of each roller is followed successively by: 172 DEG C, 172 DEG C, 192 DEG C, 192 DEG C, 180 DEG C and 180 DEG C; In described step G, hot transfer temperature is 124 DEG C, and binding temperature is 140 DEG C.
Embodiment 3
A kind of high heat-resisting embossing folder flower polychlorovinyl sheet material, described height heat-resisting embossing folder flower polychlorovinyl sheet material comprises the raw material of following weight part:
Polyvinyl chloride resin 80 parts
30 parts, softening agent
Thermo-stabilizer 3 parts
Heat-proof modifier 3 parts
3 parts, oxidation inhibitor
Lubricant 7 parts.
The mixture that described polyvinyl chloride resin is made up of with weight ratio 1:2 calcium carbide process PVC resin and ethylene process polyvinyl chloride resin; The mixture that described softening agent is made up of with weight ratio 1:1:2 epoxy soybean oil, triethyl citrate and synthesis vegetable esters.
The mixture that described thermo-stabilizer is made up of with weight ratio 1:1 Ca-Zn composite heat stabilizer and hydrotalcite thermal stabilizer; The mixture that described Ca-Zn composite heat stabilizer is made up of with weight ratio 1:1:1:1 calcium stearate, ricinolic acid calcium, Zinic stearas and zinc ricinate.
The mixture that described heat-proof modifier is made up of with weight ratio 2:1 N-phenylmaleimide/fine terpolymer of vinylbenzene/propylene and alpha-methyl styrene/styrene/acrylonitrile terpolymer.
The mixture that described oxidation inhibitor is made up of with weight ratio 1.5:1 antioxidant 1010 and irgasfos 168.
The mixture that described lubricant is made up of with weight ratio 2:1:1 oxidized polyethlene wax, pentaerythritol stearate and ethylene bis stearic acid amide.
Described height heat-resisting embossing folder flower polychlorovinyl sheet material also comprises weighting agent 15 parts and impact modifier 3 parts, and described weighting agent is that particle diameter is at 5nm and through the nano-calcium carbonate of silane coupling agent process; Described impact modifier is the mixture that the chlorinatedpolyethylene of 35% and the ethylene-vinyl acetate copolymer of vinyl acetate between to for plastic unit content 15% form with weight ratio 2:1 by chlorinity.
Described height heat-resisting embossing folder flower polychlorovinyl sheet material also comprises fire retardant 3 parts, slipping agent 0.1 part and 0.03 part, pigment powder; The mixture that described fire retardant is made up of with weight ratio 1.3:1 antimonous oxide and zinc borate; Described slipping agent is the mixture be made up of with weight ratio 2:1:1 erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide; Described pigment powder is particle diameter at the titanium dioxide of 3 μm; The mixture that described titanium dioxide is made up of with weight ratio 1:2 Rutile type Titanium Dioxide and anatase thpe white powder.
A preparation method for high heat-resisting embossing folder flower polychlorovinyl sheet material, comprises the steps:
A, raw material prepare: take each raw material by above-mentioned raw materials composition, mixing;
B, high-speed stirring: mixed raw material is put into high speed blender, stir 10min at 115 DEG C of temperature, and the rotating speed of stirring is 800RPM;
C, once plasticizing: the raw material after stirring is carried out first time plasticizing through planetary extruder at 150 DEG C of temperature, obtains micelle;
D, secondary plasticizing: the micelle after first time plasticizing is carried out second time plasticizing, until evenly through pricking turbine at 140 DEG C of temperature;
E, level filter: adopt 20 orders/￠ 323mm, 60 orders/￠ 323mm, 120 orders/￠ 323mm, 150 orders/￠ 323mm stainless steel filter screen to filter successively through filter in the micelle after second time plasticizing, the screw speed of filter is 60RPM;
F, calendering formation: by the micelle after filtration through rolling press calendering formation, obtain sheet material;
G, transfer printing laminating: fitted through laminating transfer machine preheating transfer printing by the sheet material after shaping again, pattern is transferred to sheet material from the preheating of OPP transfer film, then another sheet material of fitting, carry out embossed by the sheet material after laminating;
H, cooling rolling: the sheet material after embossed is carried out cooling and shaping through drawing cooling wheel, then carries out rolling through winder, obtain high heat-resisting embossing folder flower polychlorovinyl sheet material.
In described step F, rolling press is six roll calendars, and the temperature of each roller is followed successively by: 175 DEG C, 175 DEG C, 195 DEG C, 195 DEG C, 183 DEG C and 183 DEG C; In described step G, hot transfer temperature is 128 DEG C, and binding temperature is 145 DEG C.
Embodiment 4
A kind of high heat-resisting embossing folder flower polychlorovinyl sheet material, described height heat-resisting embossing folder flower polychlorovinyl sheet material comprises the raw material of following weight part:
Polyvinyl chloride resin 85 parts
35 parts, softening agent
Thermo-stabilizer 3.5 parts
Heat-proof modifier 4 parts
4 parts, oxidation inhibitor
Lubricant 8 parts.
The mixture that described polyvinyl chloride resin is made up of with weight ratio 1:3.5 calcium carbide process PVC resin and ethylene process polyvinyl chloride resin; The mixture that described softening agent is made up of with weight ratio 1:1.1:2.2 epoxy soybean oil, triethyl citrate and synthesis vegetable esters.
The mixture that described thermo-stabilizer is made up of with weight ratio 1:1.1 Ca-Zn composite heat stabilizer and hydrotalcite thermal stabilizer; The mixture that described Ca-Zn composite heat stabilizer is made up of with weight ratio 1.2:1:1.2:1.1 calcium stearate, ricinolic acid calcium, Zinic stearas and zinc ricinate.
The mixture that described heat-proof modifier is made up of with weight ratio 2.2:1 N-phenylmaleimide/fine terpolymer of vinylbenzene/propylene and alpha-methyl styrene/styrene/acrylonitrile terpolymer.
The mixture that described oxidation inhibitor is made up of with weight ratio 1.8:1 antioxidant 1010 and irgasfos 168.
The mixture that described lubricant is made up of with weight ratio 2.2:1:1.1 oxidized polyethlene wax, pentaerythritol stearate and ethylene bis stearic acid amide.
Described height heat-resisting embossing folder flower polychlorovinyl sheet material also comprises weighting agent 18 parts and impact modifier 4 parts, and described weighting agent is that particle diameter is at 8nm and through the nano-calcium carbonate of silane coupling agent process; Described impact modifier is the mixture that the chlorinatedpolyethylene of 40% and the ethylene-vinyl acetate copolymer of vinyl acetate between to for plastic unit content 20% form with weight ratio 2.2:1 by chlorinity.
Described height heat-resisting embossing folder flower polychlorovinyl sheet material also comprises fire retardant 4 parts, slipping agent 0.12 part and 0.04 part, pigment powder; The mixture that described fire retardant is made up of with weight ratio 1.4:1 antimonous oxide and zinc borate; Described slipping agent is the mixture be made up of with weight ratio 2.2:1.1:1 erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide; Described pigment powder is particle diameter at the titanium dioxide of 4 μm; The mixture that described titanium dioxide is made up of with weight ratio 1:2.2 Rutile type Titanium Dioxide and anatase thpe white powder.
A preparation method for high heat-resisting embossing folder flower polychlorovinyl sheet material, comprises the steps:
A, raw material prepare: take each raw material by above-mentioned raw materials composition, mixing;
B, high-speed stirring: mixed raw material is put into high speed blender, stir 11min at 118 DEG C of temperature, and the rotating speed of stirring is 900RPM;
C, once plasticizing: the raw material after stirring is carried out first time plasticizing through planetary extruder at 155 DEG C of temperature, obtains micelle;
D, secondary plasticizing: the micelle after first time plasticizing is carried out second time plasticizing, until evenly through pricking turbine at 145 DEG C of temperature;
E, level filter: adopt 20 orders/￠ 323mm, 60 orders/￠ 323mm, 120 orders/￠ 323mm, 150 orders/￠ 323mm stainless steel filter screen to filter successively through filter in the micelle after second time plasticizing, the screw speed of filter is 65RPM;
F, calendering formation: by the micelle after filtration through rolling press calendering formation, obtain sheet material;
G, transfer printing laminating: fitted through laminating transfer machine preheating transfer printing by the sheet material after shaping again, pattern is transferred to sheet material from the preheating of OPP transfer film, then another sheet material of fitting, carry out embossed by the sheet material after laminating;
H, cooling rolling: the sheet material after embossed is carried out cooling and shaping through drawing cooling wheel, then carries out rolling through winder, obtain high heat-resisting embossing folder flower polychlorovinyl sheet material.
In described step F, rolling press is six roll calendars, and the temperature of each roller is followed successively by: 178 DEG C, 178 DEG C, 198 DEG C, 198 DEG C, 185 DEG C and 185 DEG C; In described step G, hot transfer temperature is 132 DEG C, and binding temperature is 150 DEG C.
Embodiment 5
A kind of high heat-resisting embossing folder flower polychlorovinyl sheet material, described height heat-resisting embossing folder flower polychlorovinyl sheet material comprises the raw material of following weight part:
Polyvinyl chloride resin 90 parts
40 parts, softening agent
Thermo-stabilizer 4 parts
Heat-proof modifier 5 parts
5 parts, oxidation inhibitor
Lubricant 9 parts.
The mixture that described polyvinyl chloride resin is made up of with weight ratio 1:4 calcium carbide process PVC resin and ethylene process polyvinyl chloride resin; The mixture that described softening agent is made up of with weight ratio 1:1.2:2.5 epoxy soybean oil, triethyl citrate and synthesis vegetable esters.
The mixture that described thermo-stabilizer is made up of with weight ratio 1:1.2 Ca-Zn composite heat stabilizer and hydrotalcite thermal stabilizer; The mixture that described Ca-Zn composite heat stabilizer is made up of with weight ratio 1.5:1:1.5:1.2 calcium stearate, ricinolic acid calcium, Zinic stearas and zinc ricinate.
The mixture that described heat-proof modifier is made up of with weight ratio 2.5:1 N-phenylmaleimide/fine terpolymer of vinylbenzene/propylene and alpha-methyl styrene/styrene/acrylonitrile terpolymer.
The mixture that described oxidation inhibitor is made up of with weight ratio 2:1 antioxidant 1010 and irgasfos 168.
The mixture that described lubricant is made up of with weight ratio 2.5:1:1.2 oxidized polyethlene wax, pentaerythritol stearate and ethylene bis stearic acid amide.
Described height heat-resisting embossing folder flower polychlorovinyl sheet material also comprises weighting agent 20 parts and impact modifier 5 parts, and described weighting agent is that particle diameter is at 10nm and through the nano-calcium carbonate of silane coupling agent process; Described impact modifier is the mixture that the chlorinatedpolyethylene of 45% and the ethylene-vinyl acetate copolymer of vinyl acetate between to for plastic unit content 25% form with weight ratio 2.5:1 by chlorinity.
Described height heat-resisting embossing folder flower polychlorovinyl sheet material also comprises fire retardant 5 parts, slipping agent 0.15 part and 0.05 part, pigment powder; The mixture that described fire retardant is made up of with weight ratio 1.5:1 antimonous oxide and zinc borate; Described slipping agent is the mixture be made up of with weight ratio 2.5:1.2:1 erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide; Described pigment powder is particle diameter at the titanium dioxide of 5 μm; The mixture that described titanium dioxide is made up of with weight ratio 1:2.5 Rutile type Titanium Dioxide and anatase thpe white powder.
A preparation method for high heat-resisting embossing folder flower polychlorovinyl sheet material, comprises the steps:
A, raw material prepare: take each raw material by above-mentioned raw materials composition, mixing;
B, high-speed stirring: mixed raw material is put into high speed blender, stir 12min at 120 DEG C of temperature, and the rotating speed of stirring is 1160RPM;
C, once plasticizing: the raw material after stirring is carried out first time plasticizing through planetary extruder at 160 DEG C of temperature, obtains micelle;
D, secondary plasticizing: the micelle after first time plasticizing is carried out second time plasticizing, until evenly through pricking turbine at 150 DEG C of temperature;
E, level filter: adopt 20 orders/￠ 323mm, 60 orders/￠ 323mm, 120 orders/￠ 323mm, 150 orders/￠ 323mm stainless steel filter screen to filter successively through filter in the micelle after second time plasticizing, the screw speed of filter is 70RPM;
F, calendering formation: by the micelle after filtration through rolling press calendering formation, obtain sheet material;
G, transfer printing laminating: fitted through laminating transfer machine preheating transfer printing by the sheet material after shaping again, pattern is transferred to sheet material from the preheating of OPP transfer film, then another sheet material of fitting, carry out embossed by the sheet material after laminating;
H, cooling rolling: the sheet material after embossed is carried out cooling and shaping through drawing cooling wheel, then carries out rolling through winder, obtain high heat-resisting embossing folder flower polychlorovinyl sheet material.
In described step F, rolling press is six roll calendars, and the temperature of each roller is followed successively by: 180 DEG C, 180 DEG C, 200 DEG C, 200 DEG C, 188 DEG C and 188 DEG C; In described step G, hot transfer temperature is 135 DEG C, and binding temperature is 155 DEG C.
Above-described embodiment is the present invention's preferably implementation, and in addition, the present invention can also realize by alternate manner, and any apparent replacement is all within protection scope of the present invention without departing from the inventive concept of the premise.
Claims (10)
1. a high heat-resisting embossing folder flower polychlorovinyl sheet material, is characterized in that: described height heat-resisting embossing folder flower polychlorovinyl sheet material comprises the raw material of following weight part:
Polyvinyl chloride resin 70-90 part
Softening agent 20-40 part
Thermo-stabilizer 2-4 part
Heat-proof modifier 1-5 part
Oxidation inhibitor 1-5 part
Lubricant 5-9 part.
2. the high heat-resisting embossing folder flower polychlorovinyl sheet material of one according to claim 1, is characterized in that: the mixture that described polyvinyl chloride resin is made up of with weight ratio 1:2-4 calcium carbide process PVC resin and ethylene process polyvinyl chloride resin; The mixture that described softening agent is made up of with weight ratio 1:0.8-1.2:1.5-2.5 epoxy soybean oil, triethyl citrate and synthesis vegetable esters.
3. the high heat-resisting embossing folder flower polychlorovinyl sheet material of one according to claim 1, is characterized in that: the mixture that described thermo-stabilizer is made up of with weight ratio 1:0.8-1.2 Ca-Zn composite heat stabilizer and hydrotalcite thermal stabilizer; The mixture that described Ca-Zn composite heat stabilizer is made up of with weight ratio 0.5-1.5:1:0.5-1.5:0.8-1.2 calcium stearate, ricinolic acid calcium, Zinic stearas and zinc ricinate.
4. the high heat-resisting embossing folder flower polychlorovinyl sheet material of one according to claim 1, is characterized in that: the mixture that described heat-proof modifier is made up of with weight ratio 1.5-2.5:1 N-phenylmaleimide/fine terpolymer of vinylbenzene/propylene and alpha-methyl styrene/styrene/acrylonitrile terpolymer.
5. the high heat-resisting embossing folder flower polychlorovinyl sheet material of one according to claim 1, is characterized in that: the mixture that described oxidation inhibitor is made up of with weight ratio 1-2:1 antioxidant 1010 and irgasfos 168.
6. the high heat-resisting embossing folder flower polychlorovinyl sheet material of one according to claim 1, is characterized in that: the mixture that described lubricant is made up of with weight ratio 1.5-2.5:1:0.8-1.2 oxidized polyethlene wax, pentaerythritol stearate and ethylene bis stearic acid amide.
7. the high heat-resisting embossing folder flower polychlorovinyl sheet material of one according to claim 1, it is characterized in that: described height heat-resisting embossing folder flower polychlorovinyl sheet material also comprises weighting agent 10-20 part and impact modifier 1-5 part, described weighting agent is that particle diameter is at 1-10nm and through the nano-calcium carbonate of silane coupling agent process; Described impact modifier is the mixture that the chlorinatedpolyethylene of 25%-45% and the ethylene-vinyl acetate copolymer of vinyl acetate between to for plastic unit content 5%-25% form with weight ratio 1.5-2.5:1 by chlorinity.
8. the high heat-resisting embossing folder flower polychlorovinyl sheet material of one according to claim 1, is characterized in that: described height heat-resisting embossing folder flower polychlorovinyl sheet material also comprises fire retardant 1-5 part, slipping agent 0.05-0.15 part and pigment powder 0.01-0.05 part; The mixture that described fire retardant is made up of with weight ratio 0.5-1.5:1 antimonous oxide and zinc borate; Described slipping agent is the mixture be made up of with weight ratio 1.5-2.5:0.8-1.2:1 erucicamide, amine hydroxybenzene and N, N'-ethylene bis stearamide; Described pigment powder is particle diameter at the titanium dioxide of 1-5 μm; The mixture that described titanium dioxide is made up of with weight ratio 1:1.5-2.5 Rutile type Titanium Dioxide and anatase thpe white powder.
9. the preparation method of a kind of high heat-resisting embossing folder flower polychlorovinyl sheet material as described in any one of claim 1-9, is characterized in that: comprise the steps:
A, raw material prepare: take each raw material by above-mentioned raw materials composition, mixing;
B, high-speed stirring: mixed raw material is put into high speed blender, stir 8-12min at 110-120 DEG C of temperature, and the rotating speed of stirring is 580-1160RPM;
C, once plasticizing: the raw material after stirring is carried out first time plasticizing through planetary extruder at 140-160 DEG C of temperature, obtains micelle;
D, secondary plasticizing: the micelle after first time plasticizing is carried out second time plasticizing, until evenly through pricking turbine at 130-150 DEG C of temperature;
E, level filter: adopt 20 orders, 60 orders, 120 orders and 150 mesh filter screens to filter successively through filter in the micelle after second time plasticizing, the screw speed of filter is 50-70RPM;
F, calendering formation: by the micelle after filtration through rolling press calendering formation, obtain sheet material;
G, transfer printing laminating: the sheet material after shaping is fitted through laminating transfer machine preheating transfer printing again, pattern is transferred to sheet material from the preheating of OPP transfer film, then another sheet material of fitting; Sheet material after laminating is carried out embossed;
H, cooling rolling: the sheet material after embossed is carried out cooling and shaping through drawing cooling wheel, then carries out rolling through winder, obtain high heat-resisting embossing folder flower polychlorovinyl sheet material.
10. the preparation method of a kind of high heat-resisting embossing folder flower polychlorovinyl sheet material according to claim 9, it is characterized in that: in described step F, rolling press is six roll calendars, and the temperature of each roller is followed successively by: 170-180 DEG C, 170-180 DEG C, 190-200 DEG C, 190-200 DEG C, 178-188 DEG C and 178-188 DEG C; In described step G, hot transfer temperature is 120-135 DEG C, and binding temperature is 130-155 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510948004.7A CN105482298A (en) | 2015-12-17 | 2015-12-17 | High heatproof embossing fancy polyvinyl chloride sheet and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510948004.7A CN105482298A (en) | 2015-12-17 | 2015-12-17 | High heatproof embossing fancy polyvinyl chloride sheet and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105482298A true CN105482298A (en) | 2016-04-13 |
Family
ID=55669586
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510948004.7A Pending CN105482298A (en) | 2015-12-17 | 2015-12-17 | High heatproof embossing fancy polyvinyl chloride sheet and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105482298A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106009394A (en) * | 2016-06-28 | 2016-10-12 | 江苏金材科技有限公司 | Environment-friendly pvc agricultural film and preparation method thereof |
| CN106496857A (en) * | 2016-11-04 | 2017-03-15 | 广东省汕头市质量计量监督检测所 | A kind of bisphenol-A measure standard substance and preparation method thereof |
| CN106519500A (en) * | 2016-11-09 | 2017-03-22 | 广东省汕头市质量计量监督检测所 | Standard substance for phthalic acid ester plasticizer measurement and preparation method of standard substance |
| CN106977859A (en) * | 2017-05-16 | 2017-07-25 | 佛山市亿翔塑胶有限公司 | A kind of composite transparent embossed film of descendants of royal families pattern |
| CN107043484A (en) * | 2017-05-16 | 2017-08-15 | 佛山市亿翔塑胶有限公司 | A kind of composite transparent embossed film of Hypericum Chinense pattern |
| CN107057161A (en) * | 2017-05-16 | 2017-08-18 | 佛山市亿翔塑胶有限公司 | A kind of composite transparent embossed film of diamond heart pattern |
| CN110754889A (en) * | 2019-11-19 | 2020-02-07 | 东莞市悠悠美居家居制造有限公司 | Production process of cloth-imitated PVC tablecloth |
| CN111393575A (en) * | 2019-05-16 | 2020-07-10 | 佛山市鑫宏美装饰材料有限公司 | Double-sided flame-retardant PVC tablecloth and preparation method thereof |
| CN111471253A (en) * | 2020-05-25 | 2020-07-31 | 江苏大海塑料股份有限公司 | High-temperature-resistant anti-sticking embossed film and preparation method thereof |
| CN113861594A (en) * | 2021-11-19 | 2021-12-31 | 广东冠盛新材料股份有限公司 | Flame-retardant high-temperature-resistant PVC (polyvinyl chloride) film for graphene electrothermal film and preparation method thereof |
| CN115895143A (en) * | 2022-11-30 | 2023-04-04 | 杭州富阳金盾塑业有限公司 | Impact-resistant high-temperature-resistant PVC pipe and production process thereof |
| JP7411229B2 (en) | 2020-12-23 | 2024-01-11 | 竹本油脂株式会社 | Modifier for polyester resin sheets, polyester resin compositions, polyester resin sheets, laminated sheets, and methods for producing molded bodies |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059469A (en) * | 2012-12-25 | 2013-04-24 | 东莞市祺龙电业有限公司 | High temperature resistant environment-friendly polyvinyl chloride (PVC) modified material and preparing method thereof |
| CN104086918A (en) * | 2014-07-09 | 2014-10-08 | 安徽宁国市高新管业有限公司 | High-strength electric protecting tube |
| CN104479252A (en) * | 2014-12-30 | 2015-04-01 | 东莞市悠悠美居家居制造有限公司 | Anti-aging transfer georgette type PVC (Polyvinyl Chloride) sheet and preparation method thereof |
-
2015
- 2015-12-17 CN CN201510948004.7A patent/CN105482298A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059469A (en) * | 2012-12-25 | 2013-04-24 | 东莞市祺龙电业有限公司 | High temperature resistant environment-friendly polyvinyl chloride (PVC) modified material and preparing method thereof |
| CN104086918A (en) * | 2014-07-09 | 2014-10-08 | 安徽宁国市高新管业有限公司 | High-strength electric protecting tube |
| CN104479252A (en) * | 2014-12-30 | 2015-04-01 | 东莞市悠悠美居家居制造有限公司 | Anti-aging transfer georgette type PVC (Polyvinyl Chloride) sheet and preparation method thereof |
Non-Patent Citations (5)
| Title |
|---|
| 张可喜 等: "《材料合成与制备研究》", 30 April 2014, 中国水利水电出版社 * |
| 潘旺林: "《注塑工入门》", 31 January 2008, 安徽科学技术出版社 * |
| 王中平 等: "《表面物理化学》", 30 September 2015, 同济大学出版社 * |
| 环境保护部环境监察局: "《污染源环境监察》", 30 October 2012, 中国环境科学出版社 * |
| 齐贵亮: "《塑料压延成型实用技术》", 31 May 2013, 机械工业出版社 * |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106009394A (en) * | 2016-06-28 | 2016-10-12 | 江苏金材科技有限公司 | Environment-friendly pvc agricultural film and preparation method thereof |
| CN106496857A (en) * | 2016-11-04 | 2017-03-15 | 广东省汕头市质量计量监督检测所 | A kind of bisphenol-A measure standard substance and preparation method thereof |
| CN106519500A (en) * | 2016-11-09 | 2017-03-22 | 广东省汕头市质量计量监督检测所 | Standard substance for phthalic acid ester plasticizer measurement and preparation method of standard substance |
| CN106977859A (en) * | 2017-05-16 | 2017-07-25 | 佛山市亿翔塑胶有限公司 | A kind of composite transparent embossed film of descendants of royal families pattern |
| CN107043484A (en) * | 2017-05-16 | 2017-08-15 | 佛山市亿翔塑胶有限公司 | A kind of composite transparent embossed film of Hypericum Chinense pattern |
| CN107057161A (en) * | 2017-05-16 | 2017-08-18 | 佛山市亿翔塑胶有限公司 | A kind of composite transparent embossed film of diamond heart pattern |
| CN111393575A (en) * | 2019-05-16 | 2020-07-10 | 佛山市鑫宏美装饰材料有限公司 | Double-sided flame-retardant PVC tablecloth and preparation method thereof |
| CN110754889A (en) * | 2019-11-19 | 2020-02-07 | 东莞市悠悠美居家居制造有限公司 | Production process of cloth-imitated PVC tablecloth |
| CN111471253A (en) * | 2020-05-25 | 2020-07-31 | 江苏大海塑料股份有限公司 | High-temperature-resistant anti-sticking embossed film and preparation method thereof |
| JP7411229B2 (en) | 2020-12-23 | 2024-01-11 | 竹本油脂株式会社 | Modifier for polyester resin sheets, polyester resin compositions, polyester resin sheets, laminated sheets, and methods for producing molded bodies |
| CN113861594A (en) * | 2021-11-19 | 2021-12-31 | 广东冠盛新材料股份有限公司 | Flame-retardant high-temperature-resistant PVC (polyvinyl chloride) film for graphene electrothermal film and preparation method thereof |
| CN115895143A (en) * | 2022-11-30 | 2023-04-04 | 杭州富阳金盾塑业有限公司 | Impact-resistant high-temperature-resistant PVC pipe and production process thereof |
| CN115895143B (en) * | 2022-11-30 | 2024-04-16 | 杭州富阳金盾塑业有限公司 | Impact-resistant high-temperature-resistant PVC pipe and production process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105482298A (en) | High heatproof embossing fancy polyvinyl chloride sheet and preparation method thereof | |
| CN105440493A (en) | High-cold-resistant embossed printed polyvinyl chloride sheet and preparation method thereof | |
| CN105440492A (en) | High-soft and high-compression-resistance polyvinyl chloride sheet and preparation method thereof | |
| CN105440505A (en) | PVC (polyvinyl chloride) foam material for sole and preparation method of PVC foam material | |
| CN104558963A (en) | Anti-static two-sided gold-stamped, printed and embossed PVC (polyvinyl chloride) sheet and preparation method thereof | |
| CN105440491A (en) | High-resilience stereo polyvinyl chloride sheet and preparation method thereof | |
| CN105482415A (en) | Antistatic PC/ABS modified material and preparation method thereof | |
| CN106046626A (en) | Polyvinyl chloride electrostatic film and preparation method thereof | |
| CN102492234B (en) | Production method of red mud complexed polyvinyl chloride colorized rigid plastic | |
| CN105482310A (en) | Antistatic PVC (polyvinyl chloride) modified material and preparation method thereof | |
| CN105860324B (en) | A kind of ultrafine zeolite Ca-Zn composite heat stabilizer | |
| CN106947187A (en) | A kind of sunlight fabric is material modified and preparation method thereof with PVC | |
| CN104530601A (en) | High-strength registered embossing composite plastic sheet and preparation method thereof | |
| JP6930528B2 (en) | Vinyl chloride resin composition, vinyl chloride resin molded product, and laminate | |
| CN105419168A (en) | Medical environmental protection PVC modified material and preparation method therefor | |
| JP6760289B2 (en) | Sheet-shaped molded body and laminated body | |
| CN105419167A (en) | Carpet environmental protection PVC modified material and preparation method therefor | |
| CN104479252A (en) | Anti-aging transfer georgette type PVC (Polyvinyl Chloride) sheet and preparation method thereof | |
| CN106221066A (en) | A kind of lace stamp sheet material and double attaching process thereof | |
| CN106046625A (en) | Polyvinyl chloride blowing glue film and calendaring process thereof | |
| CN102344615A (en) | Cable sheath material | |
| CN106977849A (en) | A kind of curtain is material modified and preparation method thereof with PVC | |
| CN104479253A (en) | Foaming composite plastic sheet with high tensile strength and preparation method thereof | |
| JP6750503B2 (en) | Powder moldable vinyl chloride resin composition for real stitch skin, method for producing the same, vinyl chloride resin molded product for real stitch skin, method for producing the same, and laminate | |
| CN103387721A (en) | Environmentally friendly polyvinyl chloride (PVC) plastic particle |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160413 |
|
| RJ01 | Rejection of invention patent application after publication |