CN105473128B - Deodorant or refrigerant cosmetics and non-aerosol sprays product - Google Patents
Deodorant or refrigerant cosmetics and non-aerosol sprays product Download PDFInfo
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- CN105473128B CN105473128B CN201580001646.4A CN201580001646A CN105473128B CN 105473128 B CN105473128 B CN 105473128B CN 201580001646 A CN201580001646 A CN 201580001646A CN 105473128 B CN105473128 B CN 105473128B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/594—Mixtures of polymers
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Abstract
The present invention relates to a kind of deodorant or refrigerant cosmetics, it is characterised in that it contains composition (A):Polyurethane particles, composition (B):Anionic polymer, composition (C):Ethanol and composition (D):Water, the content of the composition (B) is 0.0001~0.008 mass %, and the content of the composition (C) is 30.0~70.0 mass %, and the content of the composition (D) is 20.0~69.0 mass %.The deodorant of the present invention or the main efficacy results of refrigerant cosmetics are as follows：Even if to contain polyurethane particles and using water and ethanol as the deodorant of decentralized medium or refrigerant cosmetics, can also suppress the caking of polyurethane particles, therefore it can easily carry out redisperse.
Description
Technical field
The present invention relates to deodorant or refrigerant cosmetics and non-aerosol sprays product.
Background technology
In the past, from the viewpoint of being coated on after skin and bringing dry and comfortable sense of touch, it is known that one kind is used as deodorant or refrigerantization
The composition of cosmetic (cosmetics for bringing refrigerant sense), it is in the liquid such as water or alcohol containing powder (see, for example patent document 1
With patent document 2).For these compositions, carry out after vibration makes powder scattered, being coated on body to be used.
In addition, above-mentioned composition is filled in automiser spray (sprayer) to be used mostly.In this case, for combination
Thing, further requirement do not produce the characteristic that the jet as caused by powder blocks.
Prior art literature
Patent document
Patent document 1:Japanese Unexamined Patent Publication 2004-262887 publications
Patent document 2:Japanese Unexamined Patent Publication 2003-095906 publications
The content of the invention
The invention problem to be solved
Present inventor has performed conscientiously studying, as a result find in the case of using polyurethane particles as powder, Neng Gouyou
Effect suppresses the blocking of the jet in automiser spray, particularly in the automiser spray of non-aerosol.But the present inventor is also
It was found that in the formula containing polyurethane particles, following problems be present：The polyurethane particles settled during preservation aggegation securely, protect
Even if being also easy to produce " caking " that vibration is not easy to redisperse after depositing, redispersibility is poor.Moreover, in the more formula of ethanol, also
The problem of in the presence of caking can be promoted to produce.
Therefore, problem of the invention is to provide a kind of deodorant or refrigerant cosmetics, its be containing polyurethane particles and
Using water and ethanol as the deodorant of decentralized medium or refrigerant cosmetics, wherein, the redispersibility of polyurethane particles is excellent.
Means for solving the problems
That is, main points of the invention are related to:
[1] a kind of deodorant or refrigerant cosmetics, it is characterised in that it contains composition (A):Polyurethane particles, composition
(B):Anionic polymer, composition (C):Ethanol and composition (D):Water,
The content of mentioned component (B) is 0.0001~0.008 mass %, and the content of mentioned component (C) is 30.0~70.0
Quality %, the content of mentioned component (D) is 20.0~69.0 mass %；
[2] a kind of non-aerosol sprays product, it possesses the automiser spray of non-aerosol and is filled in above-mentioned spraying
The deodorant or refrigerant cosmetics that above-mentioned [1] of container is recorded.
Invention effect
The deodorant of the present invention or the main efficacy results of refrigerant cosmetics are as follows:Even if to contain polyurethane particles, and with water
With deodorant of the ethanol for decentralized medium or refrigerant cosmetics, it can also suppress the cakings of polyurethane particles, therefore can be easy
Ground carries out redisperse.
Embodiment
The deodorant or refrigerant cosmetics of the present invention is at least containing polyurethane particles, anionic polymer, second alcohol and water.
The present invention deodorant or refrigerant cosmetics preferably further contain be selected from by diisopropyl adipate, diisobutyl adipate,
Ester oil (at least one kind of ester oil) in the group of diisopropyl sebacate and ethyl oleate composition.It should be noted that in this specification
In, above-mentioned " deodorant of the invention or refrigerant cosmetics " are referred to as " composition of the invention " sometimes；By above-mentioned " polyurethane
Grain " is referred to as " composition (A) "；Above-mentioned " anionic polymer " is referred to as " composition (B) "；Above-mentioned " ethanol " is referred to as " composition
(C)”；Above-mentioned " water " is referred to as " composition (D) "；" it is selected from above-mentioned by diisopropyl adipate, diisobutyl adipate, the last of the ten Heavenly stems two
Ester oil in the group of sour diisopropyl ester and ethyl oleate composition " is referred to as " composition (E) ".The deodorant or refrigerant cosmetics of the present invention
The composition beyond mentioned component (A)~(E) can further be contained.Contained by the deodorant or refrigerant cosmetics of the present invention
Each composition, such as mentioned component (A), composition (B), composition (E) can be used only a kind respectively, can also use two or more.
Composition (A)
Composition (A) in this specification is polyurethane particles.Pass through application component in the present compositions (A), energy
Enough play following effects:Suppress to block using the jet of spraying during composition of the invention in automiser spray, while energy
It is enough to bring dry feeling to user.Mentioned component (A) can be used only a kind, can also use two or more.
It is not particularly limited for the average grain diameter of mentioned component (A), preferably 1~50 μm, more preferably 2~40 μm,
More preferably 3~25 μm.Set out from a security point, the average grain diameter is preferably more than 1 μm, is blocked up from suppress to spray
From the viewpoint of plug, the average grain diameter is preferably less than 50 μm.Polyurethane particles with various average grain diameters are commercially available, because
This can be readily available the polyurethane particles with required average grain diameter.
Mentioned component (A) can use commercially available product.As the concrete example of the commercially available product of composition (A), it is not particularly limited, can
To enumerate the trade name of such as TOSHIKI PIGMENT Co. Ltd. systems " PLASTIC POWDER the D-800 " (μ of average grain diameter 6
M), trade name " PLASTIC POWDER D-400 " (12.5 μm of average grain diameter) etc..
It is not particularly limited for the content of the composition (A) in the composition of the present invention, is preferably the composition of the present invention
0.05~10.0 mass % in 100 mass %, more preferably 0.10~5.0 mass %, more preferably 0.5~2.0 matter
Measure %.From the viewpoint of band when being coated on skin carrys out the dry feeling as caused by powder, the content be preferably 0.05 mass % with
On, from the viewpoint of whiting (when being coated on skin, phenomenon that coated portion bleaches) is suppressed, the content is preferably 10.0 matter
Measure below %.It should be noted that in the case of containing composition of more than two kinds (A) in the composition of the present invention, above-mentioned " composition
(A) content " refers to the total amount of the content of all the components (A) in composition of the invention.
Composition (B)
Composition (B) in this specification is anionic polymer.Pass through application component in the present compositions
(B) effect of caking supression property (improving redispersibility) can, be played.Mentioned component (B) can be used only a kind, can also
Use two or more.
As mentioned component (B), it is not particularly limited, for example, carboxyl vinyl polymer, alkyl-modified carboxylic
Base polyvinyl, carboxymethyl cellulose, acrylic resin alkanolamine, (hydroxy-ethyl acrylate/acryloyldimethyl taurine
Na) copolymer etc..Wherein, from the viewpoint of caking supression property, the acrylate copolymer of preferred anionic type, more preferably carboxyl
Polyvinyl, alkyl-modified carboxyl group polyvinyl.I.e. composition (B) be more preferably carboxyl vinyl polymer and/or
Alkyl-modified carboxyl group polyvinyl (one kind i.e. in carboxyl vinyl polymer and alkyl-modified carboxyl group polyvinyl
Or two kinds).
Carboxyl vinyl polymer is mainly the polymer of acrylic acid, and alkyl-modified carboxyl group polyvinyl is mainly third
The copolymer of olefin(e) acid and alkyl methacrylate (such as C10~C30).
For carboxyl vinyl polymer and alkyl-modified carboxyl group polyvinyl, can easily be obtained as commercially available product
.As the preferable commercially available product of carboxyl vinyl polymer, for example, trade name:Carbopol 934、
Carbopol 940、Carbopol 941、Carbopol 981、Carbopol 1342、Carbopol 2984、Carbopol
Ultrez 10, Carbopol ETD 2050 (Japanese Lubrizol Co., Ltd.)；Trade name:AQUPEC HV-501、AQUPEC
HV-504, AQUPEC HV-505, HIVISWAKO 104, HIVISWAKO 105 (Wako Pure Chemical Industries, Ltd.) etc..As
The preferable commercially available product of alkyl-modified carboxyl group polyvinyl, for example, trade name:PEMULEN TR-1、
PEMULEN TR-2, Carbopol ETD 2020, Carbopol ULTREZ 20 (Japanese Lubrizol Co., Ltd.) etc..
From the viewpoint of caking supression property, the content of the composition (B) in composition of the invention is combination of the invention
0.0001~0.008 mass % in the mass % of thing 100, preferably 0.001~0.006 mass %, more preferably 0.001~
0.005 mass %.The content of composition (B) is more than 0.0001 mass %, the caking thus, it is possible to suppress composition (A).In addition, will
The content of composition (B) is suppressed to the less amount below 0.008 mass %, after the composition thus, it is possible to suppress the coating present invention
Skin it is sticky, further vibration the present invention composition after, the aggegation of composition (A) tails off, dispersiveness improve.Composition (B)
Content is more than 0.008 mass %, when excessive, vibrates after the composition of the present invention makes its redisperse, composition (A) be also easy to produce aggegation,
Sedimentation.A big feature in the present invention is by adding extremely micro composition (B), it is played the caking for suppressing composition (A)
Effect.It should be noted that in the case of containing composition of more than two kinds (B) in the composition of the present invention, above-mentioned " composition (B)
Content " refer to the present invention composition in all the components (B) content total amount.
For mentioned component (B), particularly carboxyl vinyl polymer, alkyl-modified carboxyl group polyvinyl, do not have
It is particularly limited to, not with alkaline matter and ground in use, further improving caking supression property, therefore preferably.It should be noted that
As above-mentioned alkaline matter, for example, the ethyl alcohol amines such as triethanolamine, MEA；Ammonia, sodium hydroxide, potassium hydroxide
Deng inorganic base；Basic amino acids such as arginine etc..
Composition (C)
Composition (C) in this specification is ethanol.Composition (C) has the composition as the present invention together with composition (D)
Medium effect, and have the function that to skin bring refrigerant sense, improve rapid-drying properties effect.
The content of composition (C) in the composition of the present invention is 30.0~70.0 mass %, preferably 35.0~65.0 matter
Measure %, more preferably 40.0~60.0 mass %.From the viewpoint of rapid-drying properties, the content is preferably more than 30.0 mass %,
From the viewpoint of skin irritation is reduced, the content is preferably below 70.0 mass %.A feature of the present invention is：I.e.
Make for the more composition of ethanol content as described above, can also play to suppress to produce and block or the effect of caking.
Composition (D)
Composition (D) in this specification is water.Composition (D) has the composition as the present invention together with composition (C)
The effect of medium.
The content of composition (D) in the composition of the present invention is 20.0~69.0 mass %, preferably 30.0~64.0 matter
Measure %, more preferably 35.0~59.0 mass %.From the viewpoint of as base, the content be preferably 20.0 mass % with
On, from the viewpoint of sticky suppression and rapid-drying properties, the content is preferably below 69.0 mass %.
Composition (E)
Composition (E) in this specification is selected from by diisopropyl adipate, diisobutyl adipate, decanedioic acid diisopropyl
Ester oil in the group of ester and ethyl oleate composition.Wherein, particularly preferred diisopropyl adipate.Mentioned component (E) can only make
With a kind, two or more can also be used.Preferably further contain mentioned component (E) in the composition of the present invention.By in this hair
Application component (E) in bright composition, can play following effects:It can further suppress to cause due to adding ingredient (B)
It is sticky.Further, the user of the composition of the present invention can be given to bring extremely excellent dry feeling.For composition (E), make
It can be readily available for commercially available product.
The content of composition (E) in the composition of the present invention is preferably 0.01~5.0 mass %, and more preferably 0.1~3.0
Quality %, more preferably 0.5~2.0 mass %.From the viewpoint of suppressing sticky, the content is preferably 0.01 mass %
More than, from the viewpoint of suppressing sticky, the content is preferably below 5.0 mass %.It should be noted that the combination of the present invention
In the case of containing composition of more than two kinds (E) in thing, above-mentioned " content of composition (E) " refers to own in the composition of the present invention
The total amount of the content of composition (E).
Other compositions
The composition of the present invention can contain the composition (other compositions) beyond mentioned component (A)~(E) as needed.Make
For other compositions, it is not particularly limited, for example, the fresheners such as l-menthol, camphor, peppermint oil；P-phenolsulfonic acid
The hidroschesis composition such as zinc, chlorination hydroxyl aluminium；Surfactant, grease, hydrocarbon ils, wax class, higher fatty acids, in addition to above-mentioned (E) composition
Aliphatic acid ester oil, lower alcohol, polyalcohol, sterols, NMF, inorganic pigment, pigment, antioxidant, ultra-violet absorber,
Vitamins, astringent, whitening agent, animals and plants extract, metal ion end-capping reagent etc..
The deodorant or refrigerant cosmetics of the present invention
The composition of the present invention is deodorant or refrigerant cosmetics.The composition of the present invention can have deodorant and refrigerant
Two kinds of functions of cosmetics.Above-mentioned deodorant is the deodorization composition for human body etc..In addition, above-mentioned refrigerant cosmetics is for example
Directly or indirectly it is coated on human body and brings the cosmetics of refrigerant sense.It should be noted that in this manual, " cosmetics " no
" cosmetics " being limited in pharmaceutical business method, can be for example cosmetics, medical exterior-applied article, pharmaceuticals, groceries it is any.
The pH of deodorant or refrigerant cosmetics for the present invention is not particularly limited, and caking supression property is improved from further
From the viewpoint of, it is preferably such as 3.0~6.0, more preferably 3.5~5.5 in 25 DEG C.
The deodorant or refrigerant cosmetics of the present invention can utilize conventional method to manufacture.It is above-mentioned each for example, mixing
Constituent, as known method, it can specifically enumerate method being stirred with mixer for well-distribution etc. etc..
The inventors discovered that by inference due to polyurethane particles (composition (A)) and other powders (such as polystyrene, Buddhist nun
Dragon) compare, it is the high material of flexibility, is applied to spray product as deodorant or refrigerant cosmetics, is especially applicable to
In the case of the spray product of non-aerosol, in the blocking of jet when being not likely to produce injection.But on the other hand, it is known that：
When composition (A) is stood in container, the problem of producing firmer caking be present.Particularly in the formula of mixed ethanol at high proportion
In, the trend for promoting caking be present.
On the other hand, the present inventor is further conscientiously studied, and is as a result found:By in deodorant or refrigerant cosmetics
Middle adding ingredient (B), composition (A) caking can be significantly inhibited, its reason is the particle surface electricity in composition (A) by inference
Adsorption component (B), thus can not close contact between the particle of composition (A).And, it was surprisingly found now that for composition
(B) 0.0001~0.008 mass % denier, is only added in deodorant or refrigerant cosmetics, just gives full play to caking suppression
Effect only.So with denier come play caking damping effect be in the present invention first clearly, be the present invention one
Feature.Addition more than the amount of above range composition (B) when, such as when largely being added more than 0.01 mass %, cosmetics production
Life it is sticky, or promote composition (A) aggegation, therefore by the composition (B) of denier can restrain caking it is extremely effective.
It should be noted that in the field of cosmetics, it is known that composition (B) is used (generally with warp as thickener
The form use of sum), such as the present invention, with do not play the very small amount of the degree of effective thickening effect using, be further used as tying
Block suppresses composition using being also clear and definite first in this manual, is a feature of the present invention.
In addition, by further adding ingredient (E), can further reduce after the composition of the present invention is coated on into skin
It is sticky, therefore the deodorant of higher quality or refrigerant cosmetics can be obtained, therefore preferably.
When the deodorant of the present invention or refrigerant cosmetics are made into product, deodorant or refrigerantization as the filling present invention
The container of cosmetic, is not particularly limited, for example, (aerosol type or non-aerosol) automiser spray, hinge bottle,
Screw bottle, pump receptacle etc..Wherein, from the viewpoint of it can effectively eliminate the conventional blockage problem existing always of composition (A), fill out
Fill in the case of the automiser spray of non-aerosol, can particularly marked degree play the effect of the present invention.I.e. of the invention removes
The spray product of smelly dose or refrigerant cosmetics as non-aerosol, is particularly preferably used.
The non-aerosol sprays product of the present invention
By the way that the deodorant of the present invention or refrigerant cosmetics to be filled in the automiser spray of non-aerosol, this can be made
The non-aerosol sprays product of invention.I.e. non-aerosol sprays product of the invention at least possesses the spraying of non-aerosol
Container and it is filled in the deodorant of the invention of above-mentioned automiser spray or refrigerant cosmetics.
As the automiser spray of above-mentioned non-aerosol, known conventional container can be enumerated, there is no particular limitation as to it,
For example, pump type, the automiser spray of trigger-type.
The automiser spray of non-aerosol has following characteristics：Its internal stream is thinner, therefore is also easy to produce blocking, this
Outside, to be operated manually, therefore it is not easy to eliminate temporarily caused block.But deodorant of the invention or refrigerant cosmetics
Using polyurethane particles as powder, therefore it is not likely to produce blocking.
Embodiment
Hereinafter, the present invention is illustrated in further detail based on embodiment, but the present invention is not limited in these realities
Apply example.It should be noted that combined amount (content) represents " quality % " as long as no statement.In addition, blending constituent all converts
Combined amount is recorded for purity.
[preliminary experiment on the blocking supression property of spraying]
According to the composition described in table 1, composition A~D is prepared according to conventional methods.
By each composition 170ml fill respectively to commercially available trigger-type automiser spray (non-aerosol, discharge opening boreCapacity 200ml), make spray product, there is provided in following evaluations.It should be noted that for each composition, difference
Make 10 spray products.
Each spray product is continuously sprayed, evaluated whetheing there is blocking.
For each composition, 10 spray products are evaluated respectively, the number that blocking is produced in 10 is recorded in
Table 1.From evaluation result, polyurethane particles show excellent blocking supression property.
[table 1]
It should be noted that the average grain diameter of polyurethane particles is 6 μm, the average grain diameter of nylon particles is 5 μm, polyphenyl second
The average grain diameter of alkene particle is 6 μm, and the average grain diameter of hydroapatite particles is 18 μm.
Embodiment 1~12 and comparative example 1~3
According to the composition described in table 2, each combination of embodiment 1~12 and comparative example 1~3 is prepared according to conventional methods
Thing, there is provided in following evaluations.It should be noted that each composition of these embodiments 25 DEG C pH be 4~5.5 scope.
[evaluation]
(1) caking supression property
The composition 170ml prepared in each embodiment and each comparative example is filled in polypropylene (PP) container of cylindrical shape
In (capacity 200ml), 24 hours are stood in the environment of 23 DEG C afterwards.Afterwards, it is above-mentioned with the velocity fluctuation of about reciprocal 3 time/second
Container.By the number of oscillation disperseed to powder without residuing in container bottom, evaluated according to following metewand.It will comment
Valency result is listed in table 2.
<The metewand of caking supression property>
◎ (good):Reciprocal 1~10 time
Zero (can use):Reciprocal 11~30 times
× (bad):Reciprocal more than 31 times
[table 2]
The aggregate value of each composition is the value that the numerical value of the 2nd after decimal point is rounded up and obtained in table 2.
Each composition details in table 2 is as follows.
Polyurethane particles (TOSHIKI PIGMENT Co., Ltd., trade name:PLASTIC POWDER D-8002.0, put down
Equal 6 μm of particle diameter)
Carboxyl vinyl polymer 1 (Japanese Lubrizol Co., Ltd., trade name:Carbopol 941)
Carboxyl vinyl polymer 2 (Wako Pure Chemical Industries, Ltd., trade name:HIVISWAKO 105)
Alkyl-modified carboxyl group polyvinyl (Japanese Lubrizol Co., Ltd., trade name:Carbopol ETD
2020)
Nylon powder (Dongli Ltd., trade name:5 μm of SP-500, average grain diameter)
The description below as shown in Table 2.
It is in example 4 0.0001 mass %, on the other hand, in the ratio of almost identical composition on composition (B) amount
Compared with being 0 mass % in example 1.The amount difference of such composition (B) of the two is small.
Restrain property on the caking of the two, in example 4 be evaluated as zero (usable), specifically reciprocal
20 times, on the other hand, in being evaluated as of comparative example 1 × (bad), specifically reciprocal 300 times.So understand by atomic
The presence of the composition (B) of amount, the caking supression property of composition can be significantly improved.
By embodiment 1~12, during using specific anionic polymer as composition (B), it is able to confirm that caking is restrained
Property.On the other hand, comparative example 2 and 3 is the composition for suppressing composition using previously known caking.The evaluation of these comparative examples is
× (bad).From the result, the amount in ethanol as the present invention is more and using the polyurethane particles easily to lump
In composition, by specific composition (B), excellent caking inhibition is played.
Embodiment 13
In addition, using in potassium hydroxide and carboxyl vinyl polymer, in addition, carry out similarly to Example 10,
Obtain composition.The pH of the composition obtained in embodiment 13 is 6.0, and caking supression property is evaluated as zero (usable).
(2) particle dispersion
The composition 170ml prepared in above-described embodiment 1~13 is filled to polypropylene (PP) container of cylindrical shape and (held
Measure 200ml) in.Afterwards in the environment of 23 DEG C, said vesse is fully vibrated, visually confirms the powder in the container after just vibrating
The dispersity of body, evaluated according to following metewand.
<The metewand of particle dispersion>
◎ (excellent):By vibration, homogeneous differential dissipates, and does not form agglutination body.
Zero (good):By vibration, after dispersed, form weaker agglutination body and microdispersed be mixed system.
△ (insufficient):It is dispersed by vibration, but form obvious agglutination body.
× (bad):Even if dispersed, just powder generation sedimentation after vibration is also failed to by vibration.
Its result understands that the composition described in embodiment 1~13 is the evaluation of zero~◎ (good~excellent), and particle divides
It is good or excellent to dissipate property.
Comparative example 4 and 5
It should be noted that be not listed in above-mentioned table, prepare in the composition of embodiment 1, the mixing quantitative change of composition (B)
The more composition (comparative example 4) of 0.01 mass % composition and by the composition of embodiment 1, the mixing quantitative change of composition (B)
The more composition (comparative example 5) of 0.1 mass % composition, same evaluation is carried out to particle dispersion.Knowable to its result, than
△ (insufficient) is evaluated as compared with example 4, comparative example 5 is evaluated as × (bad).From the result, the combined amount of composition (B)
When (content) is more more than the higher limit (0.008 mass %) of the application, it is found that the particle dispersion of composition produces deterioration
Trend.
(3) whether there is after being coated with sticky
Each composition (about 1ml) prepared in embodiment 1,6,10~12 is coated on to the inner forearm portion of subject, it is right
Sticky evaluated is whether there is after coating.Prepared in the composition and embodiment 1,6,10,11 that are prepared in comparing embodiment 12 each
Composition, compared with the composition (benchmark) prepared in embodiment 12, no sticky number is felt in investigation.Need to illustrate
, evaluation test implemented in the room of 23 DEG C of temperature by 10 subjects.
As a result, compared with the composition prepared in embodiment 12, for each composition prepared in embodiment 1,6,11,
8~10 answers feel not sticky in 10.In addition, compared with the composition prepared in embodiment 12, for embodiment 10
The composition of middle preparation, in 10 6 answers feel not sticky.
Further, each composition prepared in embodiment 1,6,10~12 is put into dispenser container, carries out 2 sprayings
(about 0.25ml) is coated on inner forearm portion, to the dry feeling after coating and whether there is sticky evaluate.To be made in embodiment 12
On the basis of standby composition, to the respective dry feeling of composition prepared in embodiment 1,6,10,11 and sticky comment is whether there is
Valency.It should be noted that evaluation test is implemented in the room of 23 DEG C of temperature by 5 specialty evaluation persons.
As a result, for each composition prepared in embodiment 1,6, dry feeling and whether there is and sticky " be better than embodiment 12
The composition of middle preparation "；For the composition prepared in embodiment 10, dry feeling " is better than the combination prepared in embodiment 12
Thing ", whether there is sticky slightly " better than the composition prepared in embodiment 12 "；For the composition prepared in embodiment 11, dry feeling
With whether there is it is sticky " non-be often better than prepared in embodiment 12 composition ".
(4) rapid-drying properties
The composition prepared in embodiment 1 is put into dispenser container, 1 spraying is carried out in inner forearm portion (about
0.1ml), rate of drying is investigated.
Its result is understood, for the composition prepared in embodiment 1, is dried within 1 minute when extremely contacting and is not felt wet
The degree of the state of profit, excellent rapid-drying properties are shown.
Comparative example 6
The combined amount of ethanol is changed to 25.0 mass %, the combined amount of Purified Water is changed to 73.3 mass %, except this
Outside, carry out similarly to Example 1, make composition.Then, rapid-drying properties are investigated as described above.
Its result is understood, for the composition prepared in comparative example 6, to the state that moistening is not felt when drying and extremely contacting
Degree, it is necessary to more than 5 minutes, compared with the composition of embodiment 1, rapid-drying properties are substantially poor.
Hereinafter, the Formulation Example of the deodorant and refrigerant cosmetics in the present invention is shown.It should be noted that content is matter
Measure %.
(Formulation Example 1:Deodorant)
According to the formula shown in Table 3 below, deodorant is prepared, obtained deodorant is filled to bore 0.4mm non-gas
In the automiser spray of colloidal sol type, non-aerosol sprays product is manufactured.
(Formulation Example 2:Refrigerant cosmetics)
According to the formula shown in Table 3 below, refrigerant cosmetics are prepared, obtained refrigerant cosmetics are filled to bore
In the automiser spray of 0.4mm non-aerosol, non-aerosol sprays product is manufactured.
[table 3]
Above-mentioned Formulation Example 1 and 2 can not produce the blocking of jet and be sprayed.
Industrial applicibility
The present invention deodorant or refrigerant cosmetics can be used as example mitigate due to skin caused by sweat gluing
Greasy, discomfort cosmetics use.By the way that the deodorant of the present invention or refrigerant cosmetics are filled to the spray of non-aerosol
Mist container, using the teaching of the invention it is possible to provide the non-aerosol sprays product for producing caking or blocking can be suppressed.
Claims (3)
1. a kind of deodorant or refrigerant cosmetics, it is characterised in that it contains
Composition (A):Polyurethane particles,
Composition (B):Carboxyl vinyl polymer and/or alkyl-modified carboxyl group polyvinyl,
Composition (C):Ethanol and
Composition (D):Water,
The content of the composition (B) is the mass % of 0.0001 mass %~0.008, and the content of the composition (C) is 30.0 matter
Measure the mass % of %~70.0, the content of the composition (D) is the mass % of 20.0 mass %~69.0.
2. deodorant as claimed in claim 1 or refrigerant cosmetics, it further contains composition (E):Selected from by adipic acid two
Ester oil in the group that isopropyl ester, diisobutyl adipate, diisopropyl sebacate and ethyl oleate form.
3. a kind of non-aerosol sprays product, it possesses:
The automiser spray of non-aerosol and
Fill to the deodorant described in the claim 1 or 2 of the automiser spray or refrigerant cosmetics.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014-069048 | 2014-03-28 | ||
| JP2014069048 | 2014-03-28 | ||
| PCT/JP2015/057179 WO2015146590A1 (en) | 2014-03-28 | 2015-03-11 | Deodorant or refreshing cosmetic material, and non-aerosol type spray product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105473128A CN105473128A (en) | 2016-04-06 |
| CN105473128B true CN105473128B (en) | 2018-01-05 |
Family
ID=54195114
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580001646.4A Expired - Fee Related CN105473128B (en) | 2014-03-28 | 2015-03-11 | Deodorant or refrigerant cosmetics and non-aerosol sprays product |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP5812556B1 (en) |
| CN (1) | CN105473128B (en) |
| WO (1) | WO2015146590A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6960806B2 (en) * | 2017-06-30 | 2021-11-05 | ポーラ化成工業株式会社 | Cosmetics |
| JP7256602B2 (en) * | 2018-03-01 | 2023-04-12 | 花王株式会社 | mist cosmetics |
| WO2019187702A1 (en) * | 2018-03-29 | 2019-10-03 | 株式会社マンダム | Powder-containing external preparation for skin |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1118249A (en) * | 1994-02-22 | 1996-03-13 | 赫里尼·柯蒂斯公司 | Antiperspirant deodorant compositions |
| CN1530094A (en) * | 2003-03-12 | 2004-09-22 | 花王株式会社 | Deodorization spraying composition |
| CN102333519A (en) * | 2009-01-15 | 2012-01-25 | 小西株式会社 | Cosmetic |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05262622A (en) * | 1991-02-28 | 1993-10-12 | Negami Kogyo Kk | Cosmetic |
| JP2005289935A (en) * | 2004-04-02 | 2005-10-20 | Shiseido Co Ltd | Gel-like composition |
| JP2011105675A (en) * | 2009-11-19 | 2011-06-02 | Mandom Corp | Non-aerosol-type misty hair cosmetic |
| JP5840025B2 (en) * | 2012-02-20 | 2016-01-06 | 株式会社マンダム | Aerosol spray cosmetic for hairdressing |
-
2015
- 2015-03-11 WO PCT/JP2015/057179 patent/WO2015146590A1/en active Application Filing
- 2015-03-11 CN CN201580001646.4A patent/CN105473128B/en not_active Expired - Fee Related
- 2015-03-11 JP JP2015529953A patent/JP5812556B1/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1118249A (en) * | 1994-02-22 | 1996-03-13 | 赫里尼·柯蒂斯公司 | Antiperspirant deodorant compositions |
| CN1530094A (en) * | 2003-03-12 | 2004-09-22 | 花王株式会社 | Deodorization spraying composition |
| CN102333519A (en) * | 2009-01-15 | 2012-01-25 | 小西株式会社 | Cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2015146590A1 (en) | 2017-04-13 |
| WO2015146590A1 (en) | 2015-10-01 |
| CN105473128A (en) | 2016-04-06 |
| JP5812556B1 (en) | 2015-11-17 |
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