CN105473007B - Fruit-vegetable cleaner - Google Patents
Fruit-vegetable cleaner Download PDFInfo
- Publication number
- CN105473007B CN105473007B CN201580001489.7A CN201580001489A CN105473007B CN 105473007 B CN105473007 B CN 105473007B CN 201580001489 A CN201580001489 A CN 201580001489A CN 105473007 B CN105473007 B CN 105473007B
- Authority
- CN
- China
- Prior art keywords
- weight
- parts
- ball
- fruit
- storage box
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23N—MACHINES OR APPARATUS FOR TREATING HARVESTED FRUIT, VEGETABLES OR FLOWER BULBS IN BULK, NOT OTHERWISE PROVIDED FOR; PEELING VEGETABLES OR FRUIT IN BULK; APPARATUS FOR PREPARING ANIMAL FEEDING- STUFFS
- A23N12/00—Machines for cleaning, blanching, drying or roasting fruits or vegetables, e.g. coffee, cocoa, nuts
- A23N12/02—Machines for cleaning, blanching, drying or roasting fruits or vegetables, e.g. coffee, cocoa, nuts for washing or blanching
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Mechanical Engineering (AREA)
Abstract
The present invention relates to fruit-vegetable cleaner, more specifically, it is related to a kind of by being soaked on raw cleaning machine in one-piece type bubble generation cleaning machine or Separated type gas and being provided with storage box, the functional ball with antibacterial and remains of pesticide remove function is filled with the storage box, so as to pass through the bubble as caused by cleaning machine, antibacterial is flowed out from the functional ball and remains of pesticide removes material, thereby, it is possible to effectively clean and remove the fruit-vegetable cleaner of the remains of pesticide being attached on fruits and vegetables and bacterium etc..
Description
Technical field
The present invention relates to fruit-vegetable cleaner, in the fruit-vegetable cleaner, by with antibacterial and removal remains of pesticide function
Functional ball be filled in storage box (Cartridge in), and the storage box is cleaned installed in one-piece type bubble
Machine or Separated type gas are soaked on raw cleaning machine, so as to by the bubble as caused by cleaning machine, be flowed out from the functional ball anti-
Bacterium and remains of pesticide remove material, and thereby, it is possible to effectively clean and removes the remains of pesticide being attached in water fruits and vegetables and carefully
Bacterium etc..
Background technology
Usually, the harmful substances such as remains of pesticide and bacterium are attached with the surface of various fruit or vegetables etc., therefore
It is necessarily required to carry out it washing and cleaning operation before ingesting, is cleaned with hand typically using the water filled in a reservoir and directly, or
Person rinses in flowing water and carries out washing and cleaning operation.
But have a problem that, simply only cleaned with water can not go well divided by curdled appearance be attached to it is various
Remains of pesticide and bacterium of fruit or vegetable surface etc., and it is bent to form part or stem especially for vegetable surface
The trickle part such as end, cleaning performance unobvious.
Therefore, it is used for light in the concern to " safe diet " this recently and requirement increasingly increased period, an urgent demand
Pine and the technology for wholesomely cleaning fruits and vegetables etc..
In addition, as described above in order to solve the problems, such as, proposition has Korean published Patent publication 10-2014-
No. 0020512 " removing greengrocery remains of pesticide, sterilizing, the apparatus and method for extending freshness ", the device has following structure,
Next door E is set among the storage tank of rectangle corner and is separated into oxidation sterilizing chamber T and physiologically active room T-1, physiologically active room T-1
Rear portion be connected with air-supply drying device W, set on oxidation sterilizing chamber T, physiologically active room T-1, air-supply drying device W top
There is the conveyer belt 4 on same line, being respectively arranged with superfine air bubble in sterilizing chamber T and physiologically active room T-1 is aoxidized fills
Put B, B-1 and be configured to master device.Oxidation sterilizing chamber T left upper portion is provided with flows into pipe 26 with water, and left lower is provided with
It is depressurized into the decompressor H of normal pressure, filtering dress with conduit D, by water under high pressure with the filter 1 of water, with water discharge for filtering
Put and circulation pipe 2 is connected with 1, force pipe 3 is connected with decompressor H, circulation pipe is connected with micro-bubble generation device B
2 and force pipe 3, the micro-bubble generation device B that 50 microns (μm) to 3 microns of (μm) bubbles can be produced pass through connecting tube C-
1 is connected on ozone generator C, and ozone generator C is connected on liquid oxygen tank A by supply pipe 23,22.Physiologically active room T-1
Upper side be provided with to be flowed into water and manage, and be provided with the both sides of bottom conduit D and filter for discharge water
1-1, the centre of the conduit D and filter 1-1 are provided with decompressor H-1, for by the decompression of high pressure relief to normal pressure
Device H-1 is connected on force pipe 21, and filter 1-1 is connected on circulation pipe 20 and can filter with water and utilize circulation pipe
20 are circulated, and the circulation pipe 20 and force pipe 21 are connected to the ultra tiny gas for the nano bubble that can produce 200 nanometers (nm)
It is soaked on generating apparatus B-1.In addition, ultramicro air bubble generating means B-1 is connected on liquid oxygen tank A by oxygen feeding pipe 22.Air-supply
Drying device W is by the way that four pillars 18 are fixed in the fixed plate 17 of central portion, so as to be connected on the T-1 of physiologically active room,
Be provided with the fixed plate 17 for dry pressure fan 16, the top of fixed plate 17 be provided be connected to oxidation sterilizing chamber T and
Conveyer belt 4 on physiologically active room T-1 same line, it is provided with the conveyer belt 4 and separates platform 24 and be equipped with netted pallet 25,
The top of the conveyer belt 4 is provided with upper board 14, is provided with the upper board 14 for dry pressure fan 15.
In addition, propose there be No. 10-2003-0072121 " remains of pesticide of fruit crust of Korean published Patent publication
Removal device ", the remains of pesticide removal device of the fruit crust include：Oxidizing agent solution ejection section, oxidizing agent solution injection
Portion be arranged on for transmit fruit conveyer belt line on side, for into transmission fruit spray oxidizing agent solution；With
For irradiating the ultraviolet irradiation portion of ultraviolet.The oxidizing agent solution ejection section and ultraviolet irradiation portion are along the fruit
Transmission route is sequentially arranged, and the ultraviolet irradiation portion is separated into two, is set between two ultraviolet irradiation portions of separation
Single oxidizing agent solution ejection section.
But the Korean published Patent publication the 10-2014-0020512nd " remove greengrocery remains of pesticide,
Sterilizing, extend freshness device " and Korean published Patent publication the 10-2003-0072121st " fruit crust it is residual
Stay pesticides removal device " have a problem that：It is not easy to set in family etc. and uses, and due to its operating cost etc.
Expend greatly, so as to which practicality is very low.
Invention to solve this problem, it is proposed that there is Korean published Patent publication the 10-1993-0009543rd " using ultrasound
The fruit washing apparatus of ripple and bubble ", as shown in figure 1, the fruit washing apparatus includes：Container 2, the container 2 can in body 1
Dismounting, and the fruit to be cleaned can be loaded in container 2；Container support platform 4, the container support platform 4 are fixed on described
While being used to support container 2 on body 1, ultrasonic energy can be transmitted with being filled with to the cleaned material in container 2；It is super
Acoustic vibration 23, the ultrasonic vibrator 23 are arranged on the bottom of the container support platform 4 and can produce ultrasonic wave；Motor
14, the motor 14 makes bubble generating pump 17 carry out up and down reciprocatingly operation according to direction of rotation, so that extraneous air is transferred to appearance
In device 2, the fruit washing apparatus cleans the harmful components being attached on fruit surface using ultrasonic wave and bubble.
In addition, propose there is Korean published Patent publication the 10-2012-0012537th " vegetables and fruit cleaning sterilization
With foam maker ", as shown in Fig. 2 the vegetables and fruit cleaning sterilization are included with foam maker：Air compression unit 1, the sky
Gas compression unit 1 is used to produce compressed air；Foam generating unit 2, the foam generating unit are soaked in water and produce foam；And air
Flexible pipe 3, the air hose 3 connect the air compression unit 1 and foam generating unit 2.The foam generating unit 2 of foam maker is filled
Enter in rinse bath, immersed with vegetables or fruit in the water in the rinse bath, start air pump and pressed with being supplied to foam generating unit 2
Contracting air, so as to producing substantial amounts of bubble in the water of rinse bath, thus, during the bubbles burst moment produce big
Pressure change, so as to clean vegetables and fruit etc..
But the Korean published Patent publication the 10-1993-0009543rd is " using ultrasonic wave and the water of bubble
Fruit cleaning device " and Korean published Patent publication the 10-2012-0012537th " vegetables and fruit cleaning sterilization foam
Generator " has a problem that：Merely using ultrasonic wave and bubble (foam) cleaning fruits and vegetables, due to only by described super
Sound wave and bubble, cleaning efficiency to harmful substances such as remains of pesticide or bacteriums and its faint.
The content of the invention
Technical task
The present invention is as described above in order to solve the problems, such as, a problem of proposition is by with antibacterial and remains of pesticide removal
The functional ball of function is filled into storage box, and the storage box is arranged on into one-piece type bubble cleaning machine or divergence type bubble occurs
On generation cleaning machine, so as to by the bubble as caused by cleaning machine, antibacterial be flowed out from the functional ball and remains of pesticide removes
Material.
Therewith, another problem of proposition is from functional ball by the bubble as caused by the cleaning machine and by the bubble
The antibacterial and remains of pesticide of middle outflow remove material, can not only significantly increase the residual for being attached on fruits and vegetables
The cleaning efficiency of the harmful substance such as agricultural chemicals and bacterium, and use is very simple.
Problem solves method
The present invention is using a kind of fruit-vegetable cleaner as problem solution, the body and bubble generator of the fruit-vegetable cleaner
Be combined as a whole type, wherein, storage box is installed in the upper surface of the bubble generator or the one side of body, filled out in the storage box
Filled with the functional ball with antibacterial and remains of pesticide remove function.
In addition, the present invention is gentle as another solution, the body of the fruit-vegetable cleaner using a kind of fruit-vegetable cleaner
Bubble generator is arranged to divergence type and is connected with each other by connection flexible pipe, wherein, installed on the front end face of the bubble generator
There is storage box, the functional ball with antibacterial and remains of pesticide remove function is filled with the storage box.
Now, the functional ball can be to include the ball that calcium oxide is formed.
Or the functional ball can generate the ball that is formed of composition to include hydroxyl radical free radical, or including super oxygen
The ball that compound generates composition and formed.
Or the functional ball can be to include the ball that antibiotic property metal is formed.
Or the functional ball can be to include the ball that magnesium is formed.
Herein, it is preferable that polyglyceryl fatty acid ester of the ball formed including calcium oxide including 35~45 weight %,
The calcium oxide of 1~5 weight % polysorbate and 50~64 weight %.
Furthermore it is preferred that the ball formed including antibiotic property metal in the mineral matter of 100 parts by weight by mixing
Close 0.1~10 parts by weight antibiotic property metal and formed, the mineral matter by from by zeolite, carclazyte, loess, diatomite,
Select in red soil, the group that is formed of kaolin and clay it is a kind of and formed or by mix it is above-mentioned in it is two or more formed,
The antibiotic property metal uses the one or more in gold, silver, copper, zinc, calcium, platinum and titanium dioxide.
Furthermore it is preferred that in the ball formed including magnesium, by containing 20 in the mineral matter of 100 parts by weight
The magnesium of~60 parts by weight and the antibiotic property metal of 0.1~10 parts by weight and formed, the mineral matter passes through from by zeolite, white
Selected in soil, loess, diatomite, red soil, the group that is formed of kaolin and clay it is a kind of and formed or by mix it is above-mentioned in
Two or more and formed, the antibiotic property metal uses a kind of or more in gold, silver, copper, zinc, calcium, platinum and titanium dioxide
Kind.
Beneficial effect
The present invention has the effect that：By the way that the functional ball with antibacterial and remains of pesticide remove function is filled to storage box
In, and the storage box is soaked on raw cleaning machine installed in one-piece type bubble generation cleaning machine or Separated type gas, so as to by clear
Bubble caused by washing machine, antibacterial and remains of pesticide are flowed out from the functional ball and removes material, and by from the cleaning machine
Caused bubble and the antibacterial flowed out by the bubble from functional ball and remains of pesticide remove material, can not only significantly carry
Principle of readjustment, restructuring, consolidation and improvement is to the cleaning efficiencies of the harmful substances such as the remains of pesticide being attached on fruits and vegetables and bacterium, and use is very simple
It is single.
Meanwhile the present invention has the effect that：In the state of functional ball is filled in storage box as described above, it can make
Antibacterial and remains of pesticide remove material and slowly dissolve and flow out, so as to long-term use, thus, it is possible to eliminate every time often
Change the cumbersome problem with load function ball.
In addition, the effect that the present invention can also realize is：Can remove antibacterial and remains of pesticide by bubble generator
Material promptly dissolves and flowed out, thus, it is possible to further improve cleaning efficiency.
Brief description of the drawings
Fig. 1 is to show that No. 10-1993-0009543 " uses ultrasonic wave and bubble according to Korean published Patent publication
Fruit washing apparatus " fruit washing apparatus figure；
Fig. 2 is to show that " vegetables and fruit cleaning disappear according to Korean published Patent publication the 10-2012-0012537th
The vegetables of poison foam maker " and the figure of fruit cleaning sterilization foam maker；
Fig. 3 is the schematic drawing of fruit-vegetable cleaner according to the first embodiment of the invention；
Fig. 4 is the schematic drawing of fruit-vegetable cleaner second embodiment of the invention；
Fig. 5 is the schematic drawing according to the fruit-vegetable cleaner of third embodiment of the present invention；
Fig. 6 is the photo in kind of the storage box filled with functional ball of the present invention；
Fig. 7 is the photo in kind for showing the oxidation calcisphere for being used as functional ball of the present invention；
Fig. 8 is the flow chart for the manufacture method for showing the oxidation calcisphere for being used as functional ball of the present invention；
Fig. 9 is the schematic drawing for the structure for showing the generation composition of the hydroxyl radical free radical as functional ball of the present invention；
Figure 10 is the flow chart for the manufacture method for showing the generation composition of the hydroxyl radical free radical as functional ball of the present invention；
Figure 11 is the schematic drawing for the structure for showing the generation composition of the superoxides as functional ball of the present invention；
Figure 12 is the flow chart of the manufacture method of the generation composition of the superoxides as functional ball of the present invention.
Embodiment
For reaching the fruit-vegetable cleaner of the present invention of the effect above, wherein should be noted that only for the present invention
Technical pattern understand needed for part be illustrated, the explanation of other parts is entered in order to not obscure idea of the invention
Province omits.
The present invention is by the way that the functional ball with antibacterial and remains of pesticide remove function is filled into storage box, and by the storage
Box is arranged on one-piece type bubble generation cleaning machine or Separated type gas is soaked on raw cleaning machine, so as to by as caused by cleaning machine
Bubble, flows out antibacterial from the functional ball and remains of pesticide removes material, and passes through the bubble as caused by the cleaning machine
Material is removed with the antibacterial and remains of pesticide flowed out by the bubble from functional ball, can be significantly increased for being attached to water
The cleaning efficiency of the harmful substances such as remains of pesticide and bacterium on fruit and vegetables.
Hereinafter, referring to the drawings, illustrate the structure of the fruit-vegetable cleaner according to the present invention first, functional ball is said afterwards
It is bright.
First, as first embodiment, as shown in figure 3, the fruit-vegetable cleaner of the present invention includes, body 30 is gentle to be soaked
Raw device 33, body 30 have upper end 31 and lower end 32, and bubble generator 33 is arranged on the lower end 32 of the body 30, wherein,
Storage box C filled with functional ball B (reference picture 6) is arranged at the upper surface of the bubble generator 33.
Now, common dewatering net 30a or drainage arrangement 30b, the bubble generator are provided with the body 30
33 include common air pump 33a, bubble nozzle 33b, such as PCB control unit and PS 33c etc., and the power supply supplies
It can directly be powered from outside to device 33c, or can be charged and be powered by direct current (DC, Direct Current), separately
Outside, ultrasonic generator etc. can be additionally provided with as needed, because these be known to structural element, therefore omit
Detailed description thereof.In addition, the structure of the bubble generator 33 of the present invention is not limited to said structure, bubble can be produced
A variety of devices are applicable.
In addition, in the case where the storage box C filled with the functional ball B is arranged on the upper surface of bubble generator 33, such as
Shown in Fig. 3, preferably the storage box C is installed as to protrude a part from the inside bottom surface of lower end 32 of body 30, now, the installation can
To be direct to place or can be bolted and realize installation.
In addition, as second embodiment, the present invention has and the first embodiment identical body 30 and bubble
The structure of generator 33, as shown in figure 4, the storage box C filled with functional ball B has the structure on the wall of body 30.
Now, above-mentioned installation can be that link slot is formed on body 30, and be formed on storage box C after connection projection,
Installation is realized by being mutually inserted and connecting, but be not restricted to that this, can use by a variety of installations such as the mountings of hook
Mode.In addition, storage box C shape can use the various shapes such as hexahedron, cylindrical shape.
In addition, as the 3rd embodiment, as shown in figure 5, the body 40 and bubble generator 43 in the present invention each divide
From in the fruit-vegetable cleaner for setting and being connected with each other by connection flexible pipe 42, the storage box C filled with functional ball B is arranged on the gas
The front end face of generator 43 is steeped, i.e., in bubble generating surface.
Now, common display operation unit 40a and power suppling part 40b, the power supply are provided with the body 40
Supply unit 40b can directly power from outside, or can be powered by wireless charging base 40c, the bubble generator 43
Be can be by producing bubble with the first embodiment identical structural element.Furthermore it is possible to it is additionally provided in electrolysis dress
Put, this is in order to be electrolysed as needed to water, to guide the functional materials to be easily attached on fruit or vegetable
On dish, so as to further improve antimicrobial efficiency.This has been known structural element, therefore omits detailed description thereof, institute
State each structure and be also not necessarily limited to this, known various structures are applicable.
That is, as described above, using the storage box C filled with functional ball B as shown in Figure 6 in the present invention.Here, the storage
Box C is not limited to hexahedral shape, can be fabricated to the various shapes such as cylinder.
Now, the storage box C is not limited to the embodiment shown in Fig. 6, and can be substituted for is had by such as non-woven fabrics etc.
The reticulate body in fine and close hole, in the case, except functional ball B described later, can be applicable functional powder.
Here, the functional powder refer to functional ball B described later various species (including calcium oxide and formed
Ball including hydroxyl radical free radical generation composition and the ball that is formed or the ball, the bag that generate composition including superoxides and formed
The ball including magnesium that include antibiotic property metal and formed and the ball formed) carry out crushing the material formed.
That is, the present invention is applicable as shown in Figure 6 fills functional ball B structure and in such as non-woven fabrics etc. in storage box C
Fill the structure of functional powder in reticulate body, but not limited to this, by bubble caused by cleaning machine can flow out antibacterial and
The various structures and mode of remains of pesticide removal material are applicable.
Here, when filling functional powder in the reticulate body in such as described non-woven fabrics etc. is carried out in use, due to passing through
Slowly dissolved from functional powder and flow out antibacterial and remains of pesticide removal material, therefore with being directly added into powder in the past
Mode is compared, and water can be made to keep clean and limpid.
In addition, the functional ball B used in the invention described above can use the ball including calcium oxide formed, be formed
The ball for including hydroxyl radical free radical generation composition, formed the ball for including superoxides generation composition, formed include it is anti-
The ball of bacterium property metal or the ball for including magnesium of formation.
First, the ball B including calcium oxide of formation includes 35~45 weight % polyglyceryl fatty acid ester
(polyglycerine fatty acid esters), 1~5 weight % polysorbate (polysorbates), 50~64
Weight % calcium oxide (calcium oxide).Specifically, as shown in figure 8, manufacturing shape as shown in Figure 7 by following steps
Into the functional ball B including calcium oxide：Step D100, mix 35~45 weight % polyglyceryl fatty acid ester and 1~5 weight %
Polysorbate, and melted at 80~90 DEG C；Step D200 after step D100, mixing 50 wherein~
64 weight % calcium oxide；Step D300, said mixture is shaped in the mould of required shape, and in room temperature (15~25
DEG C) under cool down 25~35 minutes after, be stripped.
Here, the polyglyceryl fatty acid ester and polysorbate may be used as a kind of emulsifying agent and dissolving adjuvant, from
And can not only dissolve and emulsify the calcium oxide and improve forming property, and calcium oxide is easily flowed by the bubble
Go out.When the content of polyglyceryl fatty acid ester and polysorbate each exceeds the scope, may reduce or exceedingly
Show the forming property and outflow performance of calcium oxide.
In addition, the addition of the calcium oxide is to assign antibacterial and remains of pesticide remove function, the oxygen to functional ball B
Change the sterilizing ability that calcium holds 99.9%, it is general to remove in the clean ability of strong basicity caused by water by Calcium oxide dissolution
Viable bacteria, mould, food pathogenic bacteria etc..In particular according to negative (-) ion or mineral matter of calcium oxide, antimicrobial coating can be produced
Effect, so that the freshness of food material can not only be increased substantially, and can largely remove pathogenic Escherichia coli,
Mould (Mycophyta), bacterium, salmonella, staphylococcus aureus, V. parahaemolyticus, Legionella, SARS, bird flu, O-157,
All pathogenic bacteria such as campylobacter, Pseudomonas aeruginosa, norovirus, V. parahaemolyticus, pneumococcus, vibrios.In addition, in the present invention
In, the calcium oxide of outflow is more than removing the various undesirable substances such as remains of pesticide, and it can be decomposed, so that than
Conventional cleaning agent shows higher clearance, and its reason is as shown in table 1 below, utilizes natural calcium component and OH-Free radical is steady
Surely the characteristic combined, OH~When free radical runs into the harmful substances such as remains of pesticide, the C-H-O rings of harmful substance can be destroyedSo as to which harmful substance is decomposed into (alkaline hydrolysis) into CO2、H2O etc., and chlorine or phosphorus composition are carried out with calcium component
Reaction, so as to change into the innocuous substances such as calcium chloride, calcium monohydrogen phosphate.
Table 1
In addition, the functional ball B for including hydroxyl radical free radical generation composition formed or formation include super oxygen
The functional ball B of thing generation composition authorizes " hydroxyl radical free radical generation combination using previously being applied by applicant of the present invention
Thing (Republic of Korea's registered patent the 10-1292009th) " or " superoxides generation composition (Republic of Korea's registered patent the
No. 10-1334145) ".
Specifically, as shown in figure 9, the hydroxyl radical free radical generates composition by coating shell on the outer surface of kernel 100
Layer 200 and formed, wherein, in the first silicon precursor of the kernel 100 Fixation is attached with super oxygen on 10
Compound generates compound 11, fixed on the surface of the second silicon precursor 20 of outer layer 200 to be attached with transistion metal compound 21.
Specifically, as shown in Figure 10, the manufacturing step of the hydroxyl radical free radical generation composition includes：Kernel forming step
S100, the fixed attachment superoxides generation compound on the surface of the first silicon precursor；With outer layer forming step S200, in institute
State and outer layer is coated on the outer surface of kernel, it is fixed on the surface of the second silicon precursor of the outer layer to be attached with transition metal compound
Thing.
The kernel forming step S100 is the step of forming the kernel for generating superoxides, wherein kernel by with
Lower step is formed：Step S110, in the distilled water of 100 parts by weight, mix the first silicon precursor of 30~40 parts by weight
And disperseed；Afterwards, step S120, individually, in the distilled water of 100 parts by weight, 5~10 parts by weight of dissolving surpass
Oxide generates compound；Step S130, in the first silicon precursor for being dispersed with the step S110 of 100 parts by weight
In dispersion liquid, the aqueous solution of the superoxides being dissolved with the step S120 generation compound of 10~30 parts by weight is added
And disperseed.
Here, first silicon precursor, as the presoma for being attached with the superoxides generation compound, it is used
Ludox, the Ludox use the granular size in 20~40 weight % as 0.2~1.0 micron of Powder Oxidation silicon (SiO2)
The Ludox of 60~80 weight % of middle mixing water.Now, when Powder Oxidation silicon granular size is not as good as 0.2 micron or it contains
When amount is not as good as 20 weight %, may result in can not play the presoma as attachment superoxides generation compound well
Effect., may be because of institute when the granular size of the Powder Oxidation silicon is more than 1.0 microns or when its content is more than 40 weight %
Stating presoma can make it that the generation effect of hydroxyl radical free radical is faint on the contrary.
In addition, relative to the distilled water of 100 parts by weight, when the content of first silicon precursor is not as good as 30 parts by weight
When, it may result in play with the aqueous solution dissolved with superoxides generation compound and react well, so that instead
Product yield declines.When the content of first silicon precursor is more than 40 parts by weight, the first silicon precursor may result in not
It can be well dispersed into inside distilled water.
In addition, the superoxides generates compound as the compound that can generate superoxides, nitric acid can be used
Silver (AgNO3), chlorauride (AuCl3、HAuCl4) and platinum chloride (PtCl4) in it is a kind of or shared it is above-mentioned in it is two or more,
, may when the content of superoxides generation compound is not as good as 5 parts by weight relative to the distilled water of 100 parts by weight
It can make it that the generation effect of hydroxyl radical free radical is faint, when more than 10 parts by weight, may result in superoxides generation
Compound can not be well dispersed within inside distilled water.
In addition, relative to the dispersion liquid for being dispersed with first silicon precursor of 100 parts by weight, when dissolved with described super
When the content of the aqueous solution of oxide generation compound is not as good as 10 parts by weight, the generation effect of hydroxyl radical free radical may be such that
It is faint, when more than 30 parts by weight, it may make because it can not be reacted well with first silicon precursor
Reaction yield is obtained to decline.
The outer layer forming step S200 is the step of forming outer layer, and the outer layer is used for the super oxygen generated with the kernel
Compound is reacted and generates hydroxyl radical free radical, and outer layer is formed by following steps：Step S210, in the distilled water of 100 parts by weight
In, the transistion metal compound of 5~10 parts by weight of dissolving；Step S220, in the process of the 100 parts by weight step S130
In the kernel of manufacture, add the aqueous solution of the transistion metal compound dissolved with the step S210 of 1~5 parts by weight and enter
Row is scattered；Afterwards, step S230, in the dispersion liquid by step S220 manufactures of 100 parts by weight, addition 120~
Second silicon precursor of 150 parts by weight and reacted so that its gel (gel) change.
Here, the purpose for adding the transistion metal compound is to produce hydroxyl by the transition metal with oxidisability
Free radical, it is preferable that the transistion metal compound is molysite compound or compound nantokite, specifically, using divalent iron salt
(FeSO4), trivalent iron salt ((FeCl3), cupric salt (CuSO4), trivalent mantoquita (bis (hydrogenperiodato)
cuprate(III)[K5Cu(HIO6)2] etc..
In addition, relative to the distilled water of 100 parts by weight, when the content of transistion metal compound as described above is not as good as 5
During parts by weight, it may be such that the generation effect of hydroxyl radical free radical is faint, when more than 10 parts by weight, may lead
Transistion metal compound is caused to be well dispersed within inside distilled water.
In addition, relative to the kernel manufactured by step S130 of 100 parts by weight, when dissolved with transistion metal compound
The aqueous solution content not as good as 1 parts by weight when, may be such that the generation effect of hydroxyl radical free radical is faint, when more than 5
, may be because can not be reacted well with first silicon precursor, so that reaction yield declines during parts by weight.
In addition, the second silicon precursor is used as the presoma for adhering to the transistion metal compound, tetraethoxy-silicane can be used
Alkane (TEOS, tetraethyl orthosilicate), MTMS (MTMS, methyltrimethoxysilane),
Tetramethoxy-silicane (TMOS, tetramethyl orthosilicate), tetrapropoxysilane (TPOS, tetrapropyl
Orthosilicate), four n-butoxy silanes (TBOS, tetrabutyl orthosilicate), four amoxy silane
(TPEOS,tetrapentoxy orthosilicate,), four diacetylmonoximes
Base silane (Tetra~(methylethylketoxime) silane), vinyl tributyl ketoximyl silane (VOS, vinyl
Oximeino silane), phenyl tributanoximo silane (POS, phenyltris (butanoneoxime) silane), methyl
In tributanoximo silane (MOS, methyl oximeino silane) it is a kind of or shared it is above-mentioned in it is two or more, and
Used with appropriate portfolio ratio.Relative to the dispersion liquid manufactured by the step S220 of 100 parts by weight.Work as institute
When stating the content of the second silicon precursor not as good as 120 parts by weight, may result in transistion metal compound can not coat well
In the outer surface of the kernel, when more than 150 parts by weight, may be such that according to superoxides and transistion metal compound
Reaction hydroxyl radical free radical generation effect it is faint.
In addition, in equipollent as described above, most preferably, second silicon precursor includes 20~40 parts by weight
Tetraethoxysilane (TEOS, tetraethoxysilane) and 100~110 parts by weight MTMS
(MTMS,methyltrimethoxysilane)。
As described above, in the case where the second silicon precursor includes TEOS and MTMS, when TEOS usage amount is not as good as 20 weights
When measuring number, may result in transistion metal compound can not be coated in the outer surface of the kernel well, when more than 40 weights
When measuring number, the generation effect that may result in the hydroxyl radical free radical of the reaction according to superoxides and transistion metal compound becomes
Obtain faint.
Also, when MTMS usage amount is not as good as 100 parts by weight, may result in transistion metal compound can not be good
Ground is coated in the outer surface of the kernel, when more than 110 parts by weight, may result according to superoxides and transition metal
The generation effect of the hydroxyl radical free radical of the reaction of compound is faint.
In addition, as shown in figure 11, the superoxides generation composition is outer by being coated on kernel 100' outer surface
Layer 200' and formed, wherein, it is fixed on kernel 100' the first silicon precursor 10' to be attached with superoxides generation compound
11', it is fixed on outer layer 200' the second silicon precursor 20' surface to be attached with calcium compound 21'.
Specifically, as shown in figure 12, the superoxides generation composition is formed by following steps：Kernel forms step
Rapid S100', the fixed attachment superoxides generation compound on the first silicon precursor 10'；With outer layer forming step S200',
Fixed attachment calcium compound on second silicon precursor 20' surface.
The kernel forming step S100' is that wherein kernel passes through the step of forming the kernel that can produce superoxides
Following steps are formed：Step S110', in the distilled water of 100 parts by weight, mix the first silicon forerunner of 30~40 parts by weight
Body and disperseed；Afterwards, step S120', individually, in the distilled water of 100 parts by weight, 5~10 parts by weight are dissolved
Superoxides generation compound；Step S130', before the first silicon being dispersed with the step S110' of 100 parts by weight
In the dispersion liquid for driving body, the superoxides being dissolved with the step S120' generation compound of 10~30 parts by weight is added
The aqueous solution and disperseed.
Here, first silicon precursor is used as the presoma for adhering to the superoxides generation compound, it uses silicon
Colloidal sol, the Ludox use the granular size in 20~40 weight % as 0.2~1.0 micron of Powder Oxidation silicon (SiO2) in
Mix the Ludox of 60~80 weight % water.Now, when the granular size of Powder Oxidation silicon is not as good as 0.2 micron or its content
During not as good as 20 weight %, the work that can not play the presoma as attachment superoxides generation compound well may result in
With, may be because described when the granular size of the Powder Oxidation silicon is more than 1.0 microns or when its content is more than 40 weight %
Presoma can make it that the generation effect of superoxides is faint on the contrary.
In addition, relative to the distilled water of 100 parts by weight, when the content of first silicon precursor is not as good as 30 parts by weight
When, may result in can not react well with the aqueous solution dissolved with superoxides generation compound, so that reaction production
Rate declines.When the content of first silicon precursor is more than 40 parts by weight, may result in the first silicon precursor can not be good
Attentively it is dispersed in inside distilled water.
In addition, the superoxides generates compound as the compound that can generate superoxides, nitric acid can be used
Silver (AgNO3), chlorauride (AuCl3、HAuCl4) and platinum chloride (PtCl4) in it is a kind of or shared it is above-mentioned in it is two or more,
, may when the content of superoxides generation compound is not as good as 5 parts by weight relative to the distilled water of 100 parts by weight
The generation effect of superoxides can be caused faint, when more than 10 parts by weight, may result in superoxides generationization
Compound can not be well dispersed within inside distilled water.
In addition, relative to the dispersion liquid for being dispersed with first silicon precursor of 100 parts by weight, when dissolved with described super
When the content of the aqueous solution of oxide generation compound is not as good as 10 parts by weight, the generation effect that may result in superoxides becomes
It is faint, when more than 30 parts by weight, may because can not be reacted well with first silicon precursor so that
Reaction yield is obtained to decline.
The outer layer forming step S200' is the step of forming outer layer, and the outer layer is used to surpass with what the kernel was generated
Oxide is reacted and extends the half-life period of superoxides, and outer layer is formed by following steps：Step S210', in 100 parts by weight
Distilled water in, dissolve 5~10 parts by weight calcium compound；Step S220', in the process of the 100 parts by weight step
In the kernel of S130' manufactures, add the aqueous solution of the calcium compound dissolved with the step S210' of 1~5 parts by weight and enter
Row is scattered；Afterwards, step S230', in the dispersion liquid by step S220' manufactures of 100 parts by weight, 120 are added
Second silicon precursor of~150 parts by weight and reacted so that its gel (gel) change.
Here, the purpose for adding the calcium compound is by being carried out instead with the superoxides generated from the kernel
Should and extend the half-life period of superoxides, thus postpone superoxides consumption, the calcium compound can use calcium oxide or
Calcium hydroxideDeng.
In addition, relative to the distilled water of 100 parts by weight, when the content of calcium compound as described above is not as good as 5 parts by weight
During number, it may be such that the effect above is faint, when more than 10 parts by weight, may result in calcium compound can not be good
Ground is scattered in inside distilled water.
In addition, relative to the kernel manufactured by step S130' of 100 parts by weight, when the water dissolved with calcium compound
When the content of solution is not as good as 1 parts by weight, it is faint to may result in effect caused by the calcium compound, when more than 5 weights
, may be because can not be reacted well with the superoxides generated from the kernel, so that reaction when measuring number
Yield declines.
In addition, the second silicon precursor is used as the presoma for adhering to the calcium compound, tetraethoxysilane can be used
(TEOS), MTMS (MTMS), tetramethoxy-silicane (TMOS), tetrapropoxysilane (TPOS), four positive fourth oxygen
Base silane (TBOS), four amoxy silane (TPEOS), four butanone oximino silanes (Tetra~(methylethylketoxime)
Silane), vinyl tributyl ketoximyl silane (VOS), phenyl tributanoximo silane (POS, phenyltris
(butanoneoxime) silane), in methyl tributanoximo silane (MOS) it is a kind of or shared it is above-mentioned in two kinds with
On, and used with appropriate portfolio ratio.Relative to 100 parts by weight by the scattered of step S220' manufactures
Liquid, when the content of second silicon precursor is not as good as 120 parts by weight, may result in calcium compound can not coat well
In the outer surface of the kernel, when more than 150 parts by weight, the reaction institute by superoxides and calcium compound may be such that
The prolongation effect of the half-life period of caused superoxides is faint.
In addition, in equipollent as described above, most preferably, second silicon precursor includes 20~40 parts by weight
Tetraethoxysilane (TEOS, tetraethoxysilane) and 100~110 parts by weight MTMS
(MTMS,methyltrimethoxysilane)。
As described above, in the case where the second silicon precursor includes TEOS and MTMS, when TEOS usage amount is not as good as 20 weights
When measuring number, may result in calcium compound can not be coated in the outer surface of the kernel well, when more than 40 parts by weight
When, may be such that is become as the prolongation effect of the half-life period of the superoxides caused by the reaction of superoxides and calcium compound
It is faint.
Also, when MTMS usage amount is not as good as 100 parts by weight, may result in calcium compound can not coat well
In the outer surface of the kernel, when more than 110 parts by weight, the reaction institute by superoxides and calcium compound may be such that
The prolongation effect of the half-life period of caused superoxides is faint.
In addition, the functional ball B including the antibiotic property metal formed is by the mineral matter of 100 parts by weight, mixing
Close 0.1~10 parts by weight antibiotic property metal and formed, the mineral matter by from by zeolite, carclazyte, loess, diatomite,
Select in red soil, the group that is formed of kaolin and clay it is a kind of and formed or by mix it is above-mentioned in it is two or more formed,
The antibiotic property metal use gold, silver, copper, zinc, calcium, platinum and titanium dioxide in it is a kind of or shared it is above-mentioned in it is a variety of.
Here, when the content of the antibiotic property metal is not as good as 0.1 parts by weight, the work(for showing antibacterial etc. may be such that
Can be faint, when more than 10 parts by weight, fruit or the taste of vegetables itself may be changed.
In addition, the functional ball B including magnesium of the formation is formed as, have 20 in the mineral matter of 100 parts by weight
The antibiotic property metal of the magnesium of~60 parts by weight and 0.1~10 parts by weight, mineral matter and antibiotic property metal can be as above institute
State, mineral matter from the group being made up of zeolite, carclazyte, loess, diatomite, red soil, kaolin and clay by selecting one
Kind and formed or by mix it is above-mentioned in it is two or more and formed, the antibiotic property metal using gold, silver, copper, zinc, calcium, platinum
Gold and titanium dioxide in it is a kind of or shared it is above-mentioned in it is a variety of.
Hereinafter, according to implementation below, present invention will be described in more detail, but the invention is not restricted to following implementations
Mode.
1. the manufacture of functional ball
(embodiment 1)
Functional ball is manufactured by following steps：The mixing of raw material and melting step D100, by 35 weight % polyglycerol ester
Fat acid esters (polyglycerol fatty acid ester) and 1 weight % polysorbate (polysorbate) are added to
Mixed in container, and melted at 80 DEG C；Calcium oxide blend step D200, mix 64 weight % calcium oxide；Into
Shape, cooling and demoulding step S300, the mixture is placed in the mould of cylinder and shaped, is cooled down under room temperature (20 DEG C)
After 25 minutes, it is stripped.
(embodiment 2)
Functional ball is manufactured by following steps：The mixing of raw material and melting step D100, by 45 weight % polyglycerol ester
Fat acid esters and 5 weight % polysorbate, which are added in container, to be mixed, and is melted at 90 DEG C；Calcium oxide mixes
Step D200, mix 50 weight % calcium oxide；Shaping, cooling and demoulding step S300, cylinder is placed in by the mixture
Shape in the mould of shape, after being cooled down 35 minutes under room temperature (20 DEG C), be stripped.
(embodiment 3)
As kernel forming step S100, comprise the following steps：Step S110, in the distilled water of 100 parts by weight, mix
The Ludox as the first silicon precursor of 30 parts by weight is closed, the Ludox passes through in 20 weights that granular size is 0.2 micron
Measure % Powder Oxidation silicon (SiO2) in mixing 80 weight % water and formed；Step S120, individually, in 100 parts by weight
Distilled water in, dissolving 10 parts by weight as superoxides generation compound silver nitrate (AgNO3)；Step S130,
In the dispersion liquid of the first silicon precursor being dispersed with the step S110 of 100 parts by weight, 10~30 parts by weight are added
Be dissolved with the step S120 in superoxides generation compound the aqueous solution and disperseed, so as to produce function
Ball.Afterwards, as outer layer forming step S200, comprise the following steps：Step S210, it is molten in the distilled water of 100 parts by weight
Solve the green vitriol as transistion metal compound of 5 parts by weight；Step S220, described in 100 parts by weight
In kernel, add the aqueous solution of the green vitriol dissolved with the step S210 of 1 parts by weight and disperseed；Step
Rapid S230,100 parts by weight by the dispersion liquid of step S220 manufacture, add 20 parts by weight TEOS and
The MTMS of 100 parts by weight and reacted so that its gel (gel) is changed, afterwards to by the step S230 and gel
The compound of change is filtered, and its is spherically shaped, so as to produce functional ball.
(embodiment 4)
As kernel forming step S100', comprise the following steps：Step S110, in the distilled water of 100 parts by weight,
The 40 weight % Ludox as the first silicon precursor is mixed, the Ludox passes through in 40 weights that granular size is 1.0 microns
Measure the Powder Oxidation silicon (SiO of number2) in mixing 60 weight % water and formed；S120', individually, in 100 parts by weight
In distilled water, the silver nitrate (AgNO as superoxides generation compound of 5 parts by weight of dissolving3)；Step S130', 100
In the dispersion liquid of the first silicon precursor being dispersed with the step S110' of parts by weight, 10~30 parts by weight are added
The aqueous solution of compound is generated dissolved with the superoxides in the step S120' and is disperseed, so as to produce functional ball.
Afterwards, as outer layer forming step S200', comprise the following steps：Step S210', it is molten in the distilled water of 100 parts by weight
Solve the calcium oxide as calcium compound of 5 parts by weight；Step S220', in the kernel of 100 parts by weight, add 5 weights
Measure the aqueous solution of the calcium hydroxide dissolved with the step S210' of number and disperseed；Step S230', in 100 parts by weight
In several dispersion liquids by step S220' manufactures, the tetramethoxy-silicane (TMOS) and 110 weights of 40 parts by weight are added
Measure four butanone oximino silanes of number and reacted, so that its gel (gel) is changed.Afterwards, to passing through the step S230'
The compound of gelation is filtered, and its is spherically shaped, so as to produce functional ball.
(embodiment 5)
In the zeolite of 100 parts by weight, it is formed after the silver of 0.1 parts by weight of mixing, so as to produce function
Ball.
(embodiment 6)
In the loess of 100 parts by weight, the platinum for mixing 10 parts by weight is formed afterwards, so as to produce function
Ball.
(embodiment 7)
In the zeolite of 100 parts by weight, mix 20 parts by weight magnesium and 0.1 parts by weight gold after carry out into
Shape, so as to produce functional ball.
(embodiment 8)
In the diatomite of 100 parts by weight, mix 60 parts by weight magnesium and 10 parts by weight copper after carry out into
Shape, so as to produce functional ball.
(comparative example 1)
Employ common running water.
2. evaluating characteristics
(1) antibacterial tests
Prepare nine 3L container, and added in each container after 2L running water, make bacterial strain respectively
(Escherichia coli, Staphylococcus aureus) suspends into 105~6/ ml, and extract a sample.In addition,
In above-mentioned eight containers, the storage box filled with the functional ball according to embodiment 1 to 8 is installed (in the case of comparative example 1, no respectively
Storage box is installed and only adds running water), after reaction extremely causes PH to be more than 10 for 5 minutes, extraction secondary sample.Afterwards, remove
After storage box, be additionally carried out reacting, and reaction 15 minutes and 30 minute time-division indescribably take sample three times and four samples.Separately
Outside, 10 once are diluted to each sample of four extractions by described respectively using buffer solution2After/ml, culture dish is sub-packed in
On, make plate count agar (PCA, plate count agar) double-layerAnd after solidifying, it is small that 24 are cultivated at 37 DEG C
When, so as to calculate bacterium number respectively, and calculate a sample secondary to the four times samples (5 minutes~30 minutes) of contrast in (0 minute)
In bacterium number slip, its result shows in table 2 below.
Table 2
As shown in upper table 2, it is known that 1 to 8 compared with comparative example 1 according to an embodiment of the invention, and antibacterial effect is excellent, considers
This is arrived, the storage box filled with the functional ball according to the present invention is excellent for the cleaning efficiency for being attached with the harmful substances such as bacterium.
(2) pesticides removal ability test
Using 1L distilled water dilutings 1ml agricultural chemicals (name of product：Swat artistManufacturer：Into the chemical strain of guarantor
Co., Ltd of formula commercial firm (Sungbo Chemicals Co., Ltd.s)) after, dipping circulates in the perillaseed leaf 2 minutes in market, from
And in the darkDry 4 hours.In addition individually, nine fruits and vegetables that the capacity for preparing that bubble can be produced is 3L clean
Machine, added in each cleaning machine after 2L running water, installation is filled with according to implementation respectively on eight cleaning machines
The storage box (in the case of comparative example 1, do not install storage box and only add running water) of the functional ball of example 1 to 8.In addition, each clear
Dry perillaseed leaf is soaked in washing machine respectively, and it is produced bubble and is simultaneously done in the dark to after 5 minutes, taking out perillaseed leaf
It is dry.Afterwards, to using remains of pesticide tools for measurement (ProductName：TK~16, manufacturer：ITS), 3 suppression are determined to perillaseed leaf
Rate (passes through the neurotransmission enzyme of agricultural chemicalsInhibition level grasp the mark of the residual degree of agricultural chemicals
It is accurate), it is averaged, its result is shown in table 3 below.
Table 3
As shown in upper table 3, it is known that 1 to 8 compared with comparative example 1 according to an embodiment of the invention, remains of pesticide removal effect
It is excellent, it is contemplated that this, the storage box filled with the functional ball according to the present invention by caused by cleaning machine bubble and from described
Functional ball flows out antibacterial and remains of pesticide removes material, and thereby, it is possible to learn the residual agriculture for being attached on fruits and vegetables
The cleaning efficiency of the harmful substances such as medicine is excellent.
As described above, according to the above description with illustrated according to the fruits and vegetables of the preferred embodiment of the present invention clean
Machine, but this is merely illustrative, this area it is usual it is to be understood by the skilled artisans that in the technological thought without departing from the present invention
In the range of, a variety of changes and change can be carried out.
Embodiment
As an embodiment of the invention, there is provided a kind of fruit-vegetable cleaner, in the fruit-vegetable cleaner, body and bubble
Generator is combined as a whole type, wherein, the storage box filled with the functional ball with antibacterial and remains of pesticide remove function is arranged on
In the one side of the upper surface of the bubble generator or the body.
In addition, as another embodiment of the invention, there is provided a kind of fruit-vegetable cleaner, in the fruit-vegetable cleaner, this
Body and bubble generator are formed as divergence type and are connected with each other by connection flexible pipe, wherein, filled with antibacterial and residual agriculture
The storage box of the functional ball of medicine remove function is arranged on the front end face of the bubble generator.
Now, the functional ball can be that what is formed include the ball of calcium oxide.
Or the functional ball can be to be formed include hydroxyl radical free radical generation composition ball, or formed bag
Include the ball of superoxides generation composition.
Or the functional ball can be that what is formed include the ball of antibiotic property metal.
Or the functional ball can be that what is formed include the ball of magnesium.
Herein, it is preferable that the ball including calcium oxide of the formation includes 35~45 weight % polyglycerol fatty acid
Ester, 1~5 weight % polysorbate, 50~64 weight % calcium oxide.
It is preferred that the ball including antibiotic property metal of the formation in the mineral matter of 100 parts by weight by mixing
Close the antibiotic property metal of 0.1~10 parts by weight and formed, the mineral matter can be by from zeolite, carclazyte, loess, diatom
It is native, it is red soil, kaolin and clay composition group in select it is a kind of and formed or can by mix it is above-mentioned in it is two or more and
Formed, the antibiotic property metal use gold, silver, copper, zinc, calcium, platinum and titanium dioxide in it is a kind of or shared it is above-mentioned in
It is a variety of.
Furthermore it is preferred that in the ball including magnesium of the formation, have 20~60 for the mineral matter of 100 parts by weight
The antibiotic property metal of the magnesium of parts by weight and 0.1~10 parts by weight, the mineral matter is by from zeolite, carclazyte, loess, diatom
It is native, it is red soil, kaolin and clay composition group in select it is a kind of and formed or mix it is above-mentioned in it is two or more and formed, it is described
Antibiotic property metal use gold, silver, copper, zinc, calcium, platinum and titanium dioxide in it is a kind of or shared it is above-mentioned in it is a variety of.
Industrial utilization
The present invention can fill the functional ball with antibacterial and remains of pesticide remove function into storage box, and by the storage
Box is arranged on one-piece type bubble generation cleaning machine or Separated type gas is soaked on raw cleaning machine, so as to by as caused by cleaning machine
Bubble, flow out antibacterial from the functional ball and remove the material of remains of pesticide.By from bubble caused by the cleaning machine and
The antibacterial and remains of pesticide flowed out by the bubble from functional ball removes material, can significantly increase for being attached to fruit
With the cleaning efficiency of the harmful substance such as the remains of pesticide on vegetables and bacterium, and its use is very simple.Meanwhile in as above institute
In the state of functional ball is filled in storage box with stating, antibacterial and remains of pesticide is set to remove material and slowly dissolve and flow out, from
And can be long-term use of, the cumbersome problem of functional ball is often changed and added every time thus, it is possible to eliminate.In addition, the present invention can
By bubble generator antibacterial and remains of pesticide can be made to remove material and promptly dissolve and flow out, thus, it is possible to further improve
Cleaning efficiency, therefore, expect that the present invention can be industrially widely used.
Claims (2)
1. a kind of fruit-vegetable cleaner, the body and bubble generator of the fruit-vegetable cleaner are combined as a whole type, it is characterised in that institute
State and storage box is installed in the upper surface of bubble generator or the one side of the body, being filled with the storage box has antibacterial and residual
The functional ball of pesticides removal function,
The functional ball is that what is formed include the ball of calcium oxide, and the ball including calcium oxide of the formation includes 35~45 weight %
Polyglyceryl fatty acid ester, 1~5 weight % polysorbate and 50~64 weight % calcium oxide.
2. a kind of fruit-vegetable cleaner, the body and bubble generator of the fruit-vegetable cleaner are arranged to divergence type and pass through connection flexible pipe
It is connected with each other, it is characterised in that storage box is installed on the front end face of the bubble generator, being filled with the storage box has antibacterial
With the functional ball of remains of pesticide remove function,
The functional ball is that what is formed include the ball of calcium oxide, and the ball including calcium oxide of the formation includes 35~45 weight %
Polyglyceryl fatty acid ester, 1~5 weight % polysorbate and 50~64 weight % calcium oxide.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2014-0096527 | 2014-07-29 | ||
| KR1020140096527A KR101470449B1 (en) | 2014-07-29 | 2014-07-29 | Fruit and vegetable washer |
| PCT/KR2015/002364 WO2016017890A1 (en) | 2014-07-29 | 2015-03-11 | Fruit and vegetable washing machine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105473007A CN105473007A (en) | 2016-04-06 |
| CN105473007B true CN105473007B (en) | 2018-01-16 |
Family
ID=52678143
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580001489.7A Active CN105473007B (en) | 2014-07-29 | 2015-03-11 | Fruit-vegetable cleaner |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR101470449B1 (en) |
| CN (1) | CN105473007B (en) |
| WO (1) | WO2016017890A1 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105962007A (en) * | 2016-05-12 | 2016-09-28 | 济南康众医药科技开发有限公司 | Chemical prepared from kaolinite and capable of reducing pesticide residues of fruits and vegetables and using method of chemical |
| CN106010824A (en) * | 2016-05-12 | 2016-10-12 | 济南康众医药科技开发有限公司 | Lotion for reducing fruit and vegetable pesticide residue |
| KR101690004B1 (en) | 2016-05-27 | 2016-12-27 | 차상민 | Direct Injection type cleaning and steam aging device |
| CN106000969A (en) * | 2016-06-29 | 2016-10-12 | 哈尔滨华藻生物科技开发有限公司 | Spiral seaweed cleaning device |
| CN108056485B (en) * | 2017-04-26 | 2020-04-17 | 邢康林 | Continuous ozone microbubble rhizome vegetable cleaning machine |
| CN107470265A (en) * | 2017-09-22 | 2017-12-15 | 上海赛琅医药科技有限公司 | A kind of ultrasonic cleaning equipment |
| KR102025392B1 (en) * | 2018-09-12 | 2019-09-25 | 농업회사법인 주식회사 오케이120 | Clearing method for residual pesticide by treatment with metal ion solution |
| CN117694571B (en) * | 2024-01-10 | 2024-06-04 | 山东京都厨业有限公司 | Efficient energy-saving fruit and vegetable food material purifier |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02203739A (en) * | 1989-02-03 | 1990-08-13 | Toyo Eremento Kogyo Kk | Cleaning and sterilizing apparatus for food |
| CN1931036A (en) * | 2005-09-17 | 2007-03-21 | 覃江碧 | Vegetable washing machine and its method of washing vegetable and fruit and eliminating pesticide and pollutants |
| KR20090003565A (en) * | 2007-07-03 | 2009-01-12 | 민경욱 | Mineral water manufacture feed mechanism for the growth promotion of the fruit or the vegetable type |
| KR20100037798A (en) * | 2008-10-02 | 2010-04-12 | 정운경 | Washing device for sterilizing |
| KR101206227B1 (en) * | 2010-08-02 | 2012-11-29 | 주식회사 텍콤 | Buble Generator for Washing Disinfecting Fruit and Vegetable |
| CN202890422U (en) * | 2012-07-10 | 2013-04-24 | 佛山市顺德区阿波罗环保器材有限公司 | Device capable of degrading fruit and vegetable pesticide residues |
| CN103932358A (en) * | 2014-04-12 | 2014-07-23 | 大连双迪创新科技研究院有限公司 | Fruit and vegetable cleaning machine |
-
2014
- 2014-07-29 KR KR1020140096527A patent/KR101470449B1/en active IP Right Grant
-
2015
- 2015-03-11 CN CN201580001489.7A patent/CN105473007B/en active Active
- 2015-03-11 WO PCT/KR2015/002364 patent/WO2016017890A1/en active Application Filing
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02203739A (en) * | 1989-02-03 | 1990-08-13 | Toyo Eremento Kogyo Kk | Cleaning and sterilizing apparatus for food |
| CN1931036A (en) * | 2005-09-17 | 2007-03-21 | 覃江碧 | Vegetable washing machine and its method of washing vegetable and fruit and eliminating pesticide and pollutants |
| KR20090003565A (en) * | 2007-07-03 | 2009-01-12 | 민경욱 | Mineral water manufacture feed mechanism for the growth promotion of the fruit or the vegetable type |
| KR20100037798A (en) * | 2008-10-02 | 2010-04-12 | 정운경 | Washing device for sterilizing |
| KR101206227B1 (en) * | 2010-08-02 | 2012-11-29 | 주식회사 텍콤 | Buble Generator for Washing Disinfecting Fruit and Vegetable |
| CN202890422U (en) * | 2012-07-10 | 2013-04-24 | 佛山市顺德区阿波罗环保器材有限公司 | Device capable of degrading fruit and vegetable pesticide residues |
| CN103932358A (en) * | 2014-04-12 | 2014-07-23 | 大连双迪创新科技研究院有限公司 | Fruit and vegetable cleaning machine |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2016017890A1 (en) | 2016-02-04 |
| CN105473007A (en) | 2016-04-06 |
| KR101470449B1 (en) | 2014-12-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105473007B (en) | Fruit-vegetable cleaner | |
| JP7082826B2 (en) | Fungicide and its manufacturing method | |
| JP2019162633A (en) | Liquid solution including nano-bubble | |
| JP6122139B2 (en) | Method for producing and using slightly acidic hypochlorous acid aqueous solution containing ultrafine bubbles | |
| JP2012239938A (en) | Water-quality improvement apparatus, water-quality improving method and metal ion water generator | |
| JP6214855B2 (en) | Slightly acidic hypochlorous acid water containing fine bubbles, method for producing and using the same | |
| CN101744004A (en) | Attapulgite chlorine dioxide antiseptic disinfectant | |
| KR101824731B1 (en) | A generator for chlorine dioxide | |
| CN108102801A (en) | A kind of alkalescence fruits and vegetables cleaning agent and preparation method thereof | |
| CN210988071U (en) | Double-tank type electrolytic water food material purifier | |
| KR101625178B1 (en) | Cartridge having antimicrobial function and removal function of remain agriculteral chemical | |
| KR20120051003A (en) | Particulate anti-bacterial agent for treatment of water | |
| CN211532734U (en) | Cattle and sheep feed fermentation device easy to clean | |
| CN111545158A (en) | Reation kettle is used in pesticide production | |
| CN207811737U (en) | A kind of mobile stirring type microalgae cultivating device | |
| JP3280087B2 (en) | Seed immersion / germination method and apparatus | |
| CN108822641A (en) | A kind of nanometer of ordor removing aqueous emulsion and preparation method thereof | |
| CN110367278A (en) | A kind of equipment for producing stable hypochlorite solution | |
| JP3113520U (en) | Pump pressurized gas-liquid dissolution mixer | |
| WO1999019259A1 (en) | Weathered hermatypic coral material | |
| JPH0259719B2 (en) | ||
| CN106540604A (en) | A kind of anti-oxidation homogenizing device of three axles of single drive | |
| KR101976165B1 (en) | Tea bag type net having removal function of bacillus and remain agriculteral chemical | |
| CN213943093U (en) | Activated carbon cleaning and preparing device | |
| CN213608577U (en) | Air disinfection and sterilization device for infection prevention |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |