CN105459281A - Novel composite metal fixed abrasive diamond rope and production process thereof - Google Patents
Novel composite metal fixed abrasive diamond rope and production process thereof Download PDFInfo
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- CN105459281A CN105459281A CN201610013043.2A CN201610013043A CN105459281A CN 105459281 A CN105459281 A CN 105459281A CN 201610013043 A CN201610013043 A CN 201610013043A CN 105459281 A CN105459281 A CN 105459281A
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- rope
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- composite metal
- nickel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28D—WORKING STONE OR STONE-LIKE MATERIALS
- B28D5/00—Fine working of gems, jewels, crystals, e.g. of semiconductor material; apparatus or devices therefor
- B28D5/04—Fine working of gems, jewels, crystals, e.g. of semiconductor material; apparatus or devices therefor by tools other than rotary type, e.g. reciprocating tools
- B28D5/045—Fine working of gems, jewels, crystals, e.g. of semiconductor material; apparatus or devices therefor by tools other than rotary type, e.g. reciprocating tools by cutting with wires or closed-loop blades
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- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B5/00—Making ropes or cables from special materials or of particular form
- D07B5/005—Making ropes or cables from special materials or of particular form characterised by their outer shape or surface properties
- D07B5/006—Making ropes or cables from special materials or of particular form characterised by their outer shape or surface properties by the properties of an outer surface polymeric coating
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- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/06—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
- D07B1/0693—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core having a strand configuration
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- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2001—Wires or filaments
- D07B2201/201—Wires or filaments characterised by a coating
- D07B2201/2011—Wires or filaments characterised by a coating comprising metals
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- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2015—Strands
- D07B2201/2023—Strands with core
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- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2015—Strands
- D07B2201/2038—Strands characterised by the number of wires or filaments
- D07B2201/2039—Strands characterised by the number of wires or filaments three to eight wires or filaments respectively forming a single layer
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2015—Strands
- D07B2201/2042—Strands characterised by a coating
- D07B2201/2043—Strands characterised by a coating comprising metals
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2015—Strands
- D07B2201/2046—Strands comprising fillers
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- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2047—Cores
- D07B2201/2052—Cores characterised by their structure
- D07B2201/2055—Cores characterised by their structure comprising filaments or fibers
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2205/00—Rope or cable materials
- D07B2205/20—Organic high polymers
- D07B2205/201—Polyolefins
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2205/00—Rope or cable materials
- D07B2205/20—Organic high polymers
- D07B2205/2032—Polyacrylics
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2205/00—Rope or cable materials
- D07B2205/30—Inorganic materials
- D07B2205/3021—Metals
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2205/00—Rope or cable materials
- D07B2205/30—Inorganic materials
- D07B2205/3021—Metals
- D07B2205/3067—Copper (Cu)
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Polishing Bodies And Polishing Tools (AREA)
Abstract
The invention relates to the technical field of diamond ropes, in particular to a novel composite metal fixed abrasive diamond rope. The novel composite metal fixed abrasive diamond rope comprises a core rope which is prepared by twisting a plurality of copper-plated steel wires and a soft polymer filling strip, wherein an attaching nickel layer for attaching diamond particles is deposited at the outer side of the core rope; the diamond particles are deposited on the attaching nickel layer on the surface of the core rope; and a packaging nickel layer for covering the diamond particles is deposited on the surfaces of the diamond particles. The invention further discloses a production process for the novel composite metal fixed abrasive diamond rope, wherein the production process comprises the following steps: compounding the core rope; carrying out surface pre-treatment; depositing the attaching nickel layer; attaching diamond; and depositing the packaging nickel layer. After the process is adopted, the core part of the core rope is free of a remarkable gap, so that a water-phase electrolyte solution is not remained in the space of the rope core, and therefore, corrosion is avoided; after the rope core is filled with soft stuffing, the diamond rope fracture risk is reduced; besides, by virtue of a buffer layer, slippage among steel wires is restricted, and coating is integrated, so that the coating fracture risk is reduced, and therefore, the line breakage risk in use is further reduced.
Description
Technical field
The present invention relates to line cutting technology field, particularly a kind of NEW TYPE OF COMPOSITE metal concretion abrasive diamond rope and production technology thereof.
Background technology
After current diamond rope is twisted into rope primarily of circular section steel wire, the upper diadust of plating is made, compared with the diamond wire by circular section steel wire Direct Electroplating diadust, have many good qualities, when such as cutting (sapphire, crystal silicon), because the helical form of surperficial self-assembling formation of restricting caves in, extremely be conducive to holding bits chip removal, improve cutting efficiency.
There is following problem in prior art:
1, the rope be twisted into by circular section steel wire, there is cavity in center, soda acid or plating solution can be closed in electroplating process, core steel wire is caused to corrode gradually, thus reduce the rupture pull force of manufactured goods diamond rope, in addition owing to being the process repeatedly bent under high tension in diamond rope use procedure, the corrosion hole of inner surface or spot also can significantly reduce its endurance life.
2, because the cutting of diamond rope is a process repeatedly bent under high tension, part cutting technique adopt tension force can reach 70% of product rope rupture pull force, and its guide wheel diameter used is everlasting 8cm, in whole cutting life on rope same point under high tension 180 ° of bending number of times can reach hundreds thousand of times more than.Because rope body bending Internal and external cycle deflection is different, the friction between steel wire can be there is, thus increase the risk of diamond rope fatigue broken string.
Chinese invention patent CN102555088A discloses the line of cut of a kind of consolidated diamond and cubic boron nitride compound abrasive, comprise: the metal steel wire of concretion abrasive, described abrasive material is diamond and cubic boron nitride compound abrasive, and described diamond and cubic boron nitride compound abrasive are bonded on metal steel wire by the mode of electronickelling.This patent of invention is still circular section steel wire Direct Electroplating diamond, and chip removal ability during its cutting is poor, and cutting efficiency is low.
Summary of the invention
The technical issues that need to address of the present invention are to provide the large composition metal concretion abrasive diamond rope of a kind of rupture pull force and production technology thereof.
For solving above-mentioned technical problem, a kind of NEW TYPE OF COMPOSITE metal concretion abrasive diamond rope of the present invention, comprise and fill the stranded core rope made of bar by multiply coppered steel wire and one soft polymer, the attachment nickel dam of deposition attachment diamond particle outside described core rope, depositing diamond particulate on described core rope surface attachment nickel dam; Diamond particle is buried the parcel nickel dam covered by described diamond particle surface deposition.
Further, described steel wire diameter is d, 0.05mm≤d≤0.2mm.
Further, described soft polymer fills bar diameter is D, 0.01mm≤D≤0.02mm.
Further, described parcel nickel layer thickness is the 20%-50% of diamond grain diameters.
The present invention also comprises a kind of NEW TYPE OF COMPOSITE metal concretion abrasive diamond rope production technology, comprises the following steps,
Core rope compound: filled by multiply coppered steel wire and one soft polymer that bar is stranded prepares core rope;
Surface preparation: by the core rope of above-mentioned preparation through actinobacillus wheel unwrapping wire, successively through 60 ± 5 DEG C of alkaline defatting agent solution, washing water, 10% sulfuric acid solution of 40 ± 5 DEG C and washing water process, obtains the core rope of surface cleaning;
Attachment nickel layer deposition: by the core rope of surface cleaning through dodging nickel plating technology at core rope surface deposition one deck nickel dam medium;
Diamond adheres to: be attached on the nickel dam medium on core rope surface by electrochemical co-deposition technology by diamond particle;
Parcel nickel layer deposition: dc source negative electrode by nickel plating solution connected by the core rope that will be attached with diamond particle, and after applying electric current, diamond particle buries and covers by core rope surface deposition nickel dam;
Post processing: by core rope by blow and heater to dry and to eliminate coating stress.
Further, described step attachment nickel layer deposition SMIS rope walking speed 3-50m/min, plating solution adopts watt nickel or nickel sulfamic acid system, electric current 1-10A, pH value 3-4.5, temperature 40-65 DEG C, agitating mode select that pump circulates, air stirring or mechanical agitation.
Further, described step parcel nickel layer deposition SMIS rope walking speed 3-50m/min, plating solution adopts watt nickel or nickel sulfamic acid system, electric current 1-10A, pH value 3-4.5, temperature 40-65 DEG C, agitating mode select that pump circulates, air stirring or mechanical agitation.
Further, described soft polymer fills the copolymer that bar is thermoplastic polyester or thermoplastic polyester, between the softening point 50 DEG C-150 DEG C of described thermoplastic polyester or its copolymer.
Further, it is ethylene-ethyl acrylate copolymer that described soft polymer fills bar, wherein ethyl acrylate content 20%-30%.
Further, described soft polymer fills bar is ethylene-propylene-butene-1 copolymer.
After adopting said structure, rope body core of the present invention, without remarkable space, can not remain aqueous phase electrolyte solution in rope core space, avoid corrosion.After wire rope core portion filled soft filler, there is between steel wire certain cushion, reduce the mutual friction between steel wire in use procedure when high-tension bends repeatedly, thus reduce the risk of diamond rope fatigue fracture; In addition, cushion can limit the slippage between steel wire and make coating integration, reduces craze of coating risk, thus reduces use interrupt line risk further.
Accompanying drawing explanation
Below in conjunction with the drawings and specific embodiments, the present invention is further detailed explanation.
Fig. 1 is the structural representation of a kind of NEW TYPE OF COMPOSITE metal of the present invention concretion abrasive diamond rope.
In figure: 1 is parcel nickel dam, 2 be the diamond particle of parcel nickel, and 3 be diamond particle, and 4 is adhere to nickel dam, and 5 is layer of brass, and 6 is steel wire, and 7 fill bar for soft polymer
Detailed description of the invention
As shown in Figure 1, a kind of NEW TYPE OF COMPOSITE metal concretion abrasive diamond rope of the present invention, comprise and fill the stranded core rope made of bar 7 by 3 strands of coppered steel wires and one soft polymer, wherein coppered steel wire for be coated with layer of brass 5 outside steel wire 6.Described steel wire 6 diameter is d, 0.05mm≤d≤0.2mm.It is D, 0.01mm≤D≤0.02mm that described soft polymer fills bar 7 diameter, and soft polymer fills bar 7 diameter and steel wire diameter optimal proportion is 0.127822, and other ratios are filled can not enough or spilling.The attachment nickel dam 4 of deposition attachment diamond particle 3 outside described core rope, depositing diamond particulate 3 on described core rope surface attachment nickel dam 4; Diamond particle is buried the parcel nickel dam 1 covered by described diamond particle 3 surface deposition, forms the diamond particle 2 of parcel nickel.
Further, described parcel nickel dam 1 thickness is the 20%-50% of diamond grain diameters.
The present invention also comprises the technique of producing above-mentioned NEW TYPE OF COMPOSITE metal concretion abrasive diamond rope, specifically comprises the following steps,
Core rope compound: prepare core rope with one soft polymer filament is stranded by steel wire strand;
Surface preparation: by the core rope of above-mentioned preparation through actinobacillus wheel unwrapping wire, successively through 60 ± 5 DEG C of alkaline defatting agent solution, washing water, 10% sulfuric acid solution of 40 ± 5 DEG C and washing water process, obtains the core rope of surface cleaning;
Attachment nickel layer deposition: the core rope crossed by surface cleaning is through dodging nickel plating technology at core rope surface deposition one deck nickel dam medium;
Diamond adheres to: be attached on the nickel dam medium on core rope surface by electrochemical co-deposition technology by diamond particle;
Parcel nickel layer deposition: dc source negative electrode by nickel plating solution connected by the core rope that will be attached with diamond particle, and after applying electric current, diamond particle buries and covers by core rope surface deposition nickel dam;
Post processing: by core rope by blow and heater to dry and to eliminate coating stress.
Embodiment one:
(1) core rope compound: filled by 3 strands of φ 0.080mm coppered steel wires and one φ 0.010mm soft polymer that bar is stranded prepares core rope, it is ethylene-ethyl acrylate copolymer that described soft polymer fills bar material, and its ethyl acrylate content is 20-30%.
(2) surface preparation: core rope, through actinobacillus wheel unwrapping wire, respectively through 60 ± 5 DEG C of alkaline defatting agent solution, washing water, 10% sulfuric acid solution of 40 ± 5 DEG C and washing water process, obtains the core rope of surface cleaning.
(3) nickel layer deposition is adhered to: the core rope that surface has been cleaned, through dodging the nickel dam medium that nickel plating technology is high in surface deposition one deck adhesion, crystal grain is careful, adjusts crystallite dimension and the film thickness distribution of nickel coating by parameters such as adjustment metallic cable walking speed, solution formula, electric current, pH value, temperature, stirrings.Present embodiment SMIS rope walking speed 3-50m/min, plating solution adopts watt nickel or nickel sulfamic acid system, electric current 1-10A, pH value 3-4.5, temperature 40-65 DEG C; In addition, agitating mode selects pump circulation, air stirring or mechanical agitation.
(4) diamond attachment: the diamond particle being 22/36 by specification by electrochemical co-deposition technology is attached to attachment nickel dam surface, present embodiment SMIS rope walking speed 3-50m/min, plating solution is be suspended with the watt nickel of diamond particle or nickel sulfamic acid system, electric current 1-10A, pH value 3-4.5, temperature 40-65 DEG C; In addition, agitating mode selects pump circulation, air stirring or mechanical agitation.
(5) nickel layer deposition is wrapped up: dc source negative electrode by nickel plating solution connected by the core rope that will be attached with diamond particle, and after applying electric current, diamond particle buries and covers by metallic cable surface deposition nickel dam.Present embodiment SMIS rope walking speed 3-50m/min, plating solution adopts watt nickel or nickel sulfamic acid system, electric current 1-10A, pH value 3-4.5, temperature 40-65 DEG C; In addition, agitating mode selects pump circulation, air stirring or mechanical agitation.Parcel nickel layer deposition can repeat more than 2 unit according to nickel layer thickness demand, and parcel nickel layer thickness is the 20%-50% of diamond abrasive grain diameter.
(6) post processing: by metallic cable by blow and heater to dry and to eliminate coating stress.Obtain the finished product diamond rope that diameter is 0.250 ± 0.010mm.
Embodiment two:
Difference from Example 1 is, core rope fills bar stranded institute coremaking rope for adding one φ 0.017mm soft polymer by 3 strands of φ 0.130mm coppered steel wires, it is ethylene-propylene-butene-1 copolymer that described soft polymer fills bar material, and described diamond particle specification is 30/40.Other step is all with embodiment 1, and gained finished product diamond rope specification is 0.340 ± 0.015mm.
Embodiment three:
Difference from Example 1 is, core rope fills bar stranded institute coremaking rope for adding one φ 0.020mm soft polymer by 3 strands of φ 0.160mm coppered steel wires, it is ethylene-propylene-butene-1 copolymer that described soft polymer fills bar material, and described diamond particle specification is 40/50.Other step is all with embodiment 1, and gained finished product diamond rope specification is 0.420 ± 0.020mm.
Polymer fiber silk material of the present invention can be the thermoplastic polyesters such as polyethylene, polyvinyl acetate, polyethyl acrylate, polypropylene, polyamide, linear saturated polyester, polyurethane, also can be the copolymer of above-mentioned high molecular polymer, its softening point be between 50-150 DEG C.
Although the foregoing describe the specific embodiment of the present invention; but those skilled in the art are to be understood that; these only illustrate; various changes or modifications can be made to present embodiment; and not deviating from principle of the present invention and essence, protection scope of the present invention is only defined by the appended claims.
Claims (10)
1. a NEW TYPE OF COMPOSITE metal concretion abrasive diamond rope, it is characterized in that: comprise and fill the stranded core rope made of bar by multiply coppered steel wire and one soft polymer, the attachment nickel dam of deposition attachment diamond particle outside described core rope, depositing diamond particulate on described core rope surface attachment nickel dam; Diamond particle is buried the parcel nickel dam covered by described diamond particle surface deposition.
2., according to a kind of NEW TYPE OF COMPOSITE metal concretion abrasive diamond rope according to claim 1, it is characterized in that: described steel wire diameter is d, 0.05mm≤d≤0.2mm.
3., according to a kind of NEW TYPE OF COMPOSITE metal concretion abrasive diamond rope according to claim 1, it is characterized in that: it is D, 0.01mm≤D≤0.02mm that described soft polymer fills bar diameter.
4., according to a kind of NEW TYPE OF COMPOSITE metal concretion abrasive diamond rope according to claim 1, it is characterized in that: described parcel nickel layer thickness is the 20%-50% of diamond grain diameters.
5. a NEW TYPE OF COMPOSITE metal concretion abrasive diamond rope production technology, is characterized in that, comprise the following steps,
Core rope compound: filled by multiply coppered steel wire and one soft polymer that bar is stranded prepares core rope;
Surface preparation: by the core rope of above-mentioned preparation through actinobacillus wheel unwrapping wire, successively through 60 ± 5 DEG C of alkaline defatting agent solution, washing water, 10% sulfuric acid solution of 40 ± 5 DEG C and washing water process, obtains the core rope of surface cleaning;
Attachment nickel layer deposition: by the core rope of surface cleaning through dodging nickel plating technology at core rope surface deposition one deck nickel dam medium;
Diamond adheres to: be attached on the nickel dam medium on core rope surface by electrochemical co-deposition technology by diamond particle;
Parcel nickel layer deposition: dc source negative electrode by nickel plating solution connected by the core rope that will be attached with diamond particle, and after applying electric current, diamond particle buries and covers by core rope surface deposition nickel dam;
Post processing: by core rope by blow and heater to dry and to eliminate coating stress.
6. according to a kind of NEW TYPE OF COMPOSITE metal concretion abrasive diamond rope production technology according to claim 5, it is characterized in that: described step attachment nickel layer deposition SMIS rope walking speed 3-50m/min, plating solution adopt watt nickel or nickel sulfamic acid system, electric current 1-10A, pH value 3-4.5, temperature 40-65 DEG C, agitating mode select that pump circulates, air stirring or mechanical agitation.
7. according to a kind of NEW TYPE OF COMPOSITE metal concretion abrasive diamond rope production technology according to claim 5, it is characterized in that: described step parcel nickel layer deposition SMIS rope walking speed 3-50m/min, plating solution adopt watt nickel or nickel sulfamic acid system, electric current 1-10A, pH value 3-4.5, temperature 40-65 DEG C, agitating mode select that pump circulates, air stirring or mechanical agitation.
8. according to a kind of NEW TYPE OF COMPOSITE metal concretion abrasive diamond rope production technology according to claim 5, it is characterized in that: described soft polymer fills the copolymer that bar is thermoplastic polyester or thermoplastic polyester, between the softening point 50 DEG C-150 DEG C of described thermoplastic polyester or its copolymer.
9., according to a kind of NEW TYPE OF COMPOSITE metal concretion abrasive diamond rope production technology according to claim 8, it is characterized in that: it is ethylene-ethyl acrylate copolymer that described soft polymer fills bar, wherein ethyl acrylate content 20%-30%.
10., according to a kind of NEW TYPE OF COMPOSITE metal concretion abrasive diamond rope production technology according to claim 8, it is characterized in that: it is ethylene-propylene-butene-1 copolymer that described soft polymer fills bar.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610013043.2A CN105459281A (en) | 2016-01-10 | 2016-01-10 | Novel composite metal fixed abrasive diamond rope and production process thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610013043.2A CN105459281A (en) | 2016-01-10 | 2016-01-10 | Novel composite metal fixed abrasive diamond rope and production process thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107199522A (en) * | 2017-06-27 | 2017-09-26 | 盛利维尔（中国）新材料技术股份有限公司 | A kind of modified composition metal concretion abrasive diamond rope and its production technology |
| CN107378814A (en) * | 2017-06-27 | 2017-11-24 | 盛利维尔（中国）新材料技术股份有限公司 | A kind of self-lubricating diamond wire and its production method |
| CN107457926A (en) * | 2017-09-03 | 2017-12-12 | 盛利维尔（中国）新材料技术股份有限公司 | A kind of helical structure diamond wire and its production technology |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107199522A (en) * | 2017-06-27 | 2017-09-26 | 盛利维尔（中国）新材料技术股份有限公司 | A kind of modified composition metal concretion abrasive diamond rope and its production technology |
| CN107378814A (en) * | 2017-06-27 | 2017-11-24 | 盛利维尔（中国）新材料技术股份有限公司 | A kind of self-lubricating diamond wire and its production method |
| CN107457926A (en) * | 2017-09-03 | 2017-12-12 | 盛利维尔（中国）新材料技术股份有限公司 | A kind of helical structure diamond wire and its production technology |
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Application publication date: 20160406 |