CN105449144A - PE separator free of coating treatment and production method for PE separator - Google Patents
PE separator free of coating treatment and production method for PE separator Download PDFInfo
- Publication number
- CN105449144A CN105449144A CN201510896187.2A CN201510896187A CN105449144A CN 105449144 A CN105449144 A CN 105449144A CN 201510896187 A CN201510896187 A CN 201510896187A CN 105449144 A CN105449144 A CN 105449144A
- Authority
- CN
- China
- Prior art keywords
- dividing plate
- parts
- oil
- separator
- production method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/403—Manufacturing processes of separators, membranes or diaphragms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
The invention discloses a PE separator free of coating treatment and a production method for the PE separator. The PE separator comprises the following raw materials in parts by mass: 100 parts of UHMW-PE, 260 parts of silica, 460-550 parts of special oil, 5-8 parts of color master, 1-2 parts of antioxidant and 5-10 parts of high-temperature-resistant surfactant; the molecular formula of the high-temperature-resistant surfactant is CH3(CH2)7CH=CH(CH2)12NH(CH2)2N+(CH3)2CH2COO-; the preparation method comprises the steps of a, material mixing, b, extruding and forming; c, oil pumping and steam stripping; d, hot air drying; e, hole detecting and coiling; and f, subsequent processing. The invention aims to provide the PE partition plate without requiring to be processed by pigments and the production method for the PE separator free of coating treatment and the production method for the PE separator; an effect of wetting the finished product PE separator is achieved by adding the high-temperature-resistant surfactant; and two working procedures of coating and hot air drying in the conventional production method are eliminated, so that the production energy consumption can be lowered.
Description
Technical field
The present invention relates to a kind of the PE dividing plate and the production method thereof that do not need paint process.
Background technology
Dividing plate is important composition parts in storage battery, and between the positive/negative plate that it is placed in storage battery, the quality of dividing plate directly affects discharge capacity and charge and discharge cycles useful life of storage battery.Dividing plate has following functions in storage battery, and one is prevent positive/negative plate from contacting with each other and internal short-circuit of battery occurs; Two is to have certain intensity, bears the variable force caused after pole plate distortion, bending and active material come off; Three is the electrolyte that diaphragm internal can store some, to ensure the requirement of cell reaction.Under prior art, dividing plate is in its manufacture process, and need to add paint to ensure the reaching wetting effect of dividing plate, such dividing plate antioxygenic property has much room for improvement, and production method is loaded down with trivial details, is unfavorable for reducing energy consumption.
Summary of the invention
For above-mentioned technical problem, technical purpose of the present invention is open a kind of PE dividing plate and production method not needing paint process, by adding resistant to elevated temperatures surfactant, reach the effect that finished product PE dividing plate is wetting, and paint, heated-air drying two operations of cancelling in conventional production methods, effectively can reduce energy consumption.
Technical scheme of the present invention is as follows:
A kind of PE dividing plate not needing paint process, its raw material comprises according to mass ratio: UHMW-PE100 part, silicon dioxide 260 parts, special oil 460 parts-550 parts, look mother 5 to 8 parts, antioxidant 1-2 part and high temperature resistant surfactant 5-10 part, and the molecular formula of described high temperature resistant surfactant is CH
3(CH
2)
7cH=CH (CH
2)
12nH (CH
2)
2n
+(CH
3)
2cH
2cOO
-.
Preferably, described UHMW-PE particle diameter is 120 ± 15 μm and accounts for 60% ~ 70%, and described silicon dioxide average grain diameter is 10 ~ 25 μm.
Preferably, described special oil is mixed with arbitrary proportion by one or more in straight chain hydrocarbon ils, naphthenic oil, aromatic naphtha.
Preferably, described antioxidant is the one in BHA or BHT.
Prepare in power 1-4 that any one does not need the method for the PE dividing plate of paint process, comprise the following steps:
A. batch mixing: take raw material by proportioning, by the silicon dioxide in raw material, ultra-high molecular weight polyethylene, Masterbatch, antioxidant, joins in batch mixer, first premixed 10 ~ 20 minutes, then slowly add extend oil, limit edged mixing 60 ~ 90 minutes, fully mixes material;
B. extrusion molding: the raw material mixed is transported in extruder by feeder, through double screw extruder extrusion sheet, more compressing, extrusion need add extend oil again, makes oil content in dividing plate reach between 60 ~ 75%;
C. to pump stripping: the PE dividing plate after shaping enters oil pumper and carries out oil pumping process to it, through the PE dividing plate oil content of oil pumping process 10 ~ 20%, product porosity is 60 ± 5%;
D. heated-air drying: by the baffle surface coating high temperature resistant surfactant through oil pumping process, then drying process, make dividing plate water content between 2 ~ 6%;
E. hole winding is examined: the dividing plate after paint carries out inspection hole through optics inspection hole instrument and to process and length is wound into a roll according to the rules after marking;
F. following process: PE dividing plate is carried out cut, make finished product.
Technical purpose of the present invention is open a kind of PE dividing plate and production method not needing paint process, by adding resistant to elevated temperatures surfactant, reach the effect that finished product PE dividing plate is wetting, and cancel paint, heated-air drying two operations in conventional production methods, effectively can reduce energy consumption.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described.
Embodiment 1: first choose raw material according to mass ratio: UHMW-PE100 part, silicon dioxide 260 parts, straight chain hydrocarbon ils 460 parts, look female 5 parts, BHA1 part and high temperature resistant surfactant 5 parts, the molecular formula CH of described high temperature resistant surfactant
3(CH
2)
7cH=CH (CH
2)
12nH (CH
2)
2n
+(CH
3)
2cH
2cOO
-.UHMW-PE particle diameter is 120 ± 15 μm and accounts for 60% ~ 70%, and described silicon dioxide average grain diameter is 10 ~ 25 μm.
A. batch mixing: take raw material by proportioning, by the silicon dioxide in raw material, ultra-high molecular weight polyethylene, Masterbatch, antioxidant, joins in batch mixer, first premixed 10 ~ 20 minutes, then slowly add extend oil, limit edged mixing 60 ~ 90 minutes, fully mixes material;
B. extrusion molding: the raw material mixed is transported in extruder by feeder, through double screw extruder extrusion sheet, more compressing, extrusion need add extend oil again, makes oil content in dividing plate reach between 60 ~ 75%;
C. to pump stripping: the PE dividing plate after shaping enters oil pumper and carries out oil pumping process to it, through the PE dividing plate oil content of oil pumping process 10 ~ 20%, product porosity is 60 ± 5%;
D. heated-air drying: by the baffle surface coating high temperature resistant surfactant through oil pumping process, then drying process, make dividing plate water content between 2 ~ 6%;
E. hole winding is examined: the dividing plate after paint carries out inspection hole through optics inspection hole instrument and to process and length is wound into a roll according to the rules after marking;
F. following process: PE dividing plate is carried out cut, make finished product.
Embodiment 2: first choose raw material according to mass ratio: UHMW-PE100 part, silicon dioxide 260 parts, straight chain hydrocarbon ils 500 parts, look female 4 parts, BHT1 part and high temperature resistant surfactant 6 parts, the molecular formula CH of described high temperature resistant surfactant
3(CH
2)
7cH=CH (CH
2)
12nH (CH
2)
2n
+(CH
3)
2cH
2cOO
-.UHMW-PE particle diameter is 120 ± 15 μm and accounts for 60% ~ 70%, and described silicon dioxide average grain diameter is 10 ~ 25 μm.
A. batch mixing: take raw material by proportioning, by the silicon dioxide in raw material, ultra-high molecular weight polyethylene, Masterbatch, antioxidant, joins in batch mixer, first premixed 10 ~ 20 minutes, then slowly add extend oil, limit edged mixing 60 ~ 90 minutes, fully mixes material;
B. extrusion molding: the raw material mixed is transported in extruder by feeder, through double screw extruder extrusion sheet, more compressing, extrusion need add extend oil again, makes oil content in dividing plate reach between 60 ~ 75%;
C. to pump stripping: the PE dividing plate after shaping enters oil pumper and carries out oil pumping process to it, through the PE dividing plate oil content of oil pumping process 10 ~ 20%, product porosity is 60 ± 5%;
D. heated-air drying: by the baffle surface coating high temperature resistant surfactant through oil pumping process, then drying process, make dividing plate water content between 2 ~ 6%;
E. hole winding is examined: the dividing plate after paint carries out inspection hole through optics inspection hole instrument and to process and length is wound into a roll according to the rules after marking;
F. following process: PE dividing plate is carried out cut, make finished product.
Its cross direction elongation of the product obtained and lateral pull are all better than existing product.
To be apparent for those skilled in the art to the multiple amendment of these embodiments, General Principle as defined herein can without departing from the spirit or scope of the present invention, realize in other embodiments.
Claims (5)
1. one kind does not need the PE dividing plate of paint process, it is characterized in that, its raw material comprises according to mass ratio: UHMW-PE100 part, silicon dioxide 260 parts, special oil 460 parts-550 parts, look mother 5 to 8 parts, antioxidant 1-2 part and high temperature resistant surfactant 5-10 part, and the molecular formula of described high temperature resistant surfactant is CH
3(CH
2)
7cH=CH (CH
2)
12nH (CH
2)
2n
+(CH
3)
2cH
2cOO
-.
2. the PE dividing plate not needing paint process according to claim 1, is characterized in that, described UHMW-PE particle diameter is 120 ± 15 μm and accounts for 60% ~ 70%, and described silicon dioxide average grain diameter is 10 ~ 25 μm.
3. the PE dividing plate not needing paint process according to claim 1, it is characterized in that, described special oil is mixed with arbitrary proportion by one or more in straight chain hydrocarbon ils, naphthenic oil, aromatic naphtha.
4. the PE dividing plate not needing paint process according to claim 1, is characterized in that, described antioxidant is the one in BHA or BHT.
5. prepare in power 1-4 that any one does not need the method for the PE dividing plate of paint process, it is characterized in that, comprise the following steps:
A. batch mixing: take raw material by proportioning, by the silicon dioxide in raw material, ultra-high molecular weight polyethylene, Masterbatch, antioxidant, joins in batch mixer, first premixed 10 ~ 20 minutes, then slowly add extend oil, limit edged mixing 60 ~ 90 minutes, fully mixes material;
B. extrusion molding: the raw material mixed is transported in extruder by feeder, through double screw extruder extrusion sheet, more compressing, extrusion need add extend oil again, makes oil content in dividing plate reach between 60 ~ 75%;
C. to pump stripping: the PE dividing plate after shaping enters oil pumper and carries out oil pumping process to it, through the PE dividing plate oil content of oil pumping process 10 ~ 20%, product porosity is 60 ± 5%;
D. heated-air drying: by the baffle surface coating high temperature resistant surfactant through oil pumping process, then drying process, make dividing plate water content between 2 ~ 6%;
E. hole winding is examined: the dividing plate after paint carries out inspection hole through optics inspection hole instrument and to process and length is wound into a roll according to the rules after marking;
F. following process: PE dividing plate is carried out cut, make finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510896187.2A CN105449144A (en) | 2015-11-27 | 2015-11-27 | PE separator free of coating treatment and production method for PE separator |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510896187.2A CN105449144A (en) | 2015-11-27 | 2015-11-27 | PE separator free of coating treatment and production method for PE separator |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105449144A true CN105449144A (en) | 2016-03-30 |
Family
ID=55559112
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510896187.2A Pending CN105449144A (en) | 2015-11-27 | 2015-11-27 | PE separator free of coating treatment and production method for PE separator |
Country Status (1)
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|---|---|
| CN (1) | CN105449144A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106229449A (en) * | 2016-08-26 | 2016-12-14 | 镇江奥美机电设备有限公司 | battery separator production system |
| CN106299205A (en) * | 2016-08-31 | 2017-01-04 | 江苏神力电源科技有限公司 | The preparation method of superelevation liquid flow energy storage battery barrier film |
| CN106340605A (en) * | 2016-10-17 | 2017-01-18 | 镇江奥美机电设备有限公司 | Novel process for producing storage battery PE partition plate |
-
2015
- 2015-11-27 CN CN201510896187.2A patent/CN105449144A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106229449A (en) * | 2016-08-26 | 2016-12-14 | 镇江奥美机电设备有限公司 | battery separator production system |
| CN106299205A (en) * | 2016-08-31 | 2017-01-04 | 江苏神力电源科技有限公司 | The preparation method of superelevation liquid flow energy storage battery barrier film |
| CN106299205B (en) * | 2016-08-31 | 2018-11-09 | 江苏神力电源科技有限公司 | The preparation method of liquid flow energy storage battery diaphragm |
| CN106340605A (en) * | 2016-10-17 | 2017-01-18 | 镇江奥美机电设备有限公司 | Novel process for producing storage battery PE partition plate |
| CN106340605B (en) * | 2016-10-17 | 2018-10-26 | 镇江奥美机电设备有限公司 | A kind of accumulator PE partition board production technologies |
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| PB01 | Publication | ||
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Application publication date: 20160330 |