CN105419812B - Application of soil raising agent in saline-alkali soil improvement - Google Patents
Application of soil raising agent in saline-alkali soil improvement Download PDFInfo
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- CN105419812B CN105419812B CN201510867806.5A CN201510867806A CN105419812B CN 105419812 B CN105419812 B CN 105419812B CN 201510867806 A CN201510867806 A CN 201510867806A CN 105419812 B CN105419812 B CN 105419812B
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- alkali
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- 239000002689 soil Substances 0.000 title claims abstract description 192
- 230000006872 improvement Effects 0.000 title claims abstract description 45
- 239000003513 alkali Substances 0.000 title claims abstract description 43
- 235000010855 food raising agent Nutrition 0.000 title claims abstract description 7
- 239000000126 substance Substances 0.000 claims abstract description 31
- 241000196324 Embryophyta Species 0.000 claims abstract description 19
- 239000000843 powder Substances 0.000 claims abstract description 15
- 229920000742 Cotton Polymers 0.000 claims abstract description 13
- 240000008042 Zea mays Species 0.000 claims abstract description 13
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims abstract description 13
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 11
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 239000010457 zeolite Substances 0.000 claims abstract description 11
- 241000233866 Fungi Species 0.000 claims abstract description 10
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims abstract description 5
- 235000005822 corn Nutrition 0.000 claims abstract description 5
- 239000010902 straw Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 83
- 239000003795 chemical substances by application Substances 0.000 claims description 63
- 238000002156 mixing Methods 0.000 claims description 9
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 claims description 8
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 claims description 8
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims description 8
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 8
- 239000011790 ferrous sulphate Substances 0.000 claims description 8
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 8
- 239000002509 fulvic acid Substances 0.000 claims description 8
- 229940095100 fulvic acid Drugs 0.000 claims description 8
- 239000010440 gypsum Substances 0.000 claims description 8
- 229910052602 gypsum Inorganic materials 0.000 claims description 8
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 8
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 8
- 235000009973 maize Nutrition 0.000 claims description 8
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 claims description 7
- 235000019691 monocalcium phosphate Nutrition 0.000 claims description 7
- 229920002401 polyacrylamide Polymers 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 108010064470 polyaspartate Proteins 0.000 claims description 4
- 239000010907 stover Substances 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 2
- 239000001506 calcium phosphate Substances 0.000 claims 1
- 235000011010 calcium phosphates Nutrition 0.000 claims 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims 1
- 230000035699 permeability Effects 0.000 abstract description 5
- 238000012271 agricultural production Methods 0.000 abstract description 4
- 239000003337 fertilizer Substances 0.000 abstract description 3
- 229910001415 sodium ion Inorganic materials 0.000 abstract description 3
- 238000010612 desalination reaction Methods 0.000 abstract description 2
- 238000005342 ion exchange Methods 0.000 abstract description 2
- 230000009467 reduction Effects 0.000 abstract description 2
- 239000013589 supplement Substances 0.000 abstract description 2
- 239000004067 bulking agent Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000003607 modifier Substances 0.000 abstract 1
- 235000002639 sodium chloride Nutrition 0.000 description 122
- 150000003839 salts Chemical class 0.000 description 115
- 238000007599 discharging Methods 0.000 description 28
- 238000002386 leaching Methods 0.000 description 19
- 238000012360 testing method Methods 0.000 description 12
- 238000005070 sampling Methods 0.000 description 11
- 230000001976 improved effect Effects 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 238000001514 detection method Methods 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- 238000009395 breeding Methods 0.000 description 5
- 230000001488 breeding effect Effects 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 238000003973 irrigation Methods 0.000 description 5
- 230000002262 irrigation Effects 0.000 description 5
- 239000002681 soil colloid Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000004745 nonwoven fabric Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000013459 approach Methods 0.000 description 3
- 239000003673 groundwater Substances 0.000 description 3
- 230000008595 infiltration Effects 0.000 description 3
- 238000001764 infiltration Methods 0.000 description 3
- 239000003621 irrigation water Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000002352 surface water Substances 0.000 description 3
- DWNBOPVKNPVNQG-LURJTMIESA-N (2s)-4-hydroxy-2-(propylamino)butanoic acid Chemical compound CCCN[C@H](C(O)=O)CCO DWNBOPVKNPVNQG-LURJTMIESA-N 0.000 description 2
- 241000432824 Asparagus densiflorus Species 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 235000003704 aspartic acid Nutrition 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910001414 potassium ion Inorganic materials 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- -1 salt ion Chemical class 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 239000012945 sealing adhesive Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 206010047289 Ventricular extrasystoles Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002362 mulch Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000002688 soil aggregate Substances 0.000 description 1
- 238000011895 specific detection Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01B—SOIL WORKING IN AGRICULTURE OR FORESTRY; PARTS, DETAILS, OR ACCESSORIES OF AGRICULTURAL MACHINES OR IMPLEMENTS, IN GENERAL
- A01B79/00—Methods for working soil
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2109/00—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Environmental Sciences (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
The invention belongs to the field of soil improvement, and particularly relates to an application of a soil bulking agent in saline-alkali soil improvement. The soil leavening agent is prepared from the following raw materials in parts by mass: 25-28 parts of crushed corn straw; 25-28 parts of crushed cotton straw; 20-22 parts of edible fungus residues; turfy soil: 5-10 parts; 5-8 parts of plant ash; 5-8 parts of zeolite powder; the soil bulking agent provided by the invention can improve the soil structure, increase the soil air permeability and supplement organic matters; the compound fertilizer is combined with a chemical modifier, can perform the functions of alkali reduction and desalination by ion exchange of sodium ions in soil, and can thoroughly modify saline-alkali soil on the premise of not changing soil, so that the compound fertilizer can be used for agricultural production or urban greening.
Description
Technical field
The invention belongs to soil improvement field, in particular to application of a kind of loosening of soil agent in terms of the reclamation of salinep-alkali soil.
Background technique
Salt-soda soil is a type of salt aggregation, refers to that salinity contained by soil the inside influences the normal life of crop
It is long.The salinization of soil is a global problem, and whole world saline-alkali soil area is 1,000,000,000 hectares about nearly, and there are 99,130,000 public affairs in China
Hectare, it is roughly equal to 14.7 hundred million mu, nearly more than the 100 a city in the whole nation is seated saline-alkali soil distributed area, and agriculture plantation caused by salinization of soil because subtracting
It produces, nearly 500,000,000 mu of old-field, is concentrated mainly on these arid and semi-arid lands of North China, northwest and northeast.In addition cultivation
In, chemical fertilizer is excessively applied for a long time, and Pedotransfer function is caused to aggravate, it is hardened serious, expand salinization, alkali-affected soil constantly
Greatly.In addition, China, there are also more than 18000 kilometers of long mainland coastlines, the seashores such as Bohai and Yellow Seas and East Sea littoral plain divide
It is furnished with the coastal saline-alkali soil based on chloride of large area, the common feature in these areas is that soil property salt content is all high, mostly
It is the barren land that plant is not easy to grow.Perniciousness harm causes in a large amount of, low-yield land and peasant are poor, makes large area soil resource
It is difficult to be utilized.Saline-alkali soil has 80% or so utilization, the exploitation in large area salt marsh wasteland is not yet received as a kind of resource, in China
It will be the important channel for solving 1,600,000,000 population food problem of 21 century China with the prevention and treatment of Irrigated Area Soils salinization of soil.Especially exist
China's arid, semiarid zone Utilizing question, to Agriculture Production, management of national land, ecological environmental protection etc. has extremely
Important meaning.
The salt-soda soil in China is varied, and distribution is wider, about 100,000,000 hectares of the area of saline-alkali soil, is equivalent to China ten
800000000 mu of cultivated area, it can be realized that it has very big developing and utilizingpotentiality.Wherein, beach saline land is that China is important
Salt-soda soil land type, existing more than 18,000 kilometers of coastline, distributing position is wider, and Bohai Rim is distributed with greatly
The beach saline land of amount.China saline-alkali soil distributed area is determined according to the variation of its soil types and weather conditions, and shore is divided into
Sea salt stain area, Huang-Huai-Hai plain salt marsh area, desert and desert steppe salt marsh area, the big type in four, grassland salt marsh area.
The reclamation of salinep-alkali soil is a universal problem along with the 4000 years agro-farming processes in China.Now saline and alkaline both at home and abroad
Native improving technology and product are varied.
At present the country alkaline land improving using methods and techniques be summed up substantially there are four types of:Physically improved, water conservancy improvement,
Chemical modifying and biological modification.The above method all once played important work to improvement salt-soda soil, agricultural production aspect
With with bring biggish benefit, but single reclamation of salinep-alkali soil mode all have the defects that it is various.For example, biological modification
Be the salinity in soil is fixed using biological (plant or microorganism) perhaps absorb in plant but be fixed or
The salinity of absorption is there is also in this soil region, if will lead to the wind of Pedotransfer function at any time without follow-up
Danger;Physically improved is the porosity for increasing soil in the way of deep ploughing, chesson etc., is conducive to salinity and removes, but if does not have
There is chemical modifying method (substitutional ion), is difficult to be removed by the salt ion that soil colloid adsorbs, chesson is also temporary
?.
Summary of the invention
It is an object of the invention to overcome the shortcomings that cannot effectively improveing saline-alkali soil in the prior art, a kind of soil is provided
Application of the leavening agent in terms of improveing saline-alkali soil passes through addition loosening of soil agent and others under the premise of being changed without soil
Chemical improvement agent combines, and mixes by engineering, after the operation for salt discharge of pouring water, thoroughly improves saline-alkali soil, makes it for agricultural
Production or urban afforestation.
The technical solution adopted to achieve the purpose of the present invention is:
A kind of loosening of soil agent, is made of the raw material of following mass parts:25-28 parts of crushing maize stalk;Crush cotton straw
25-28 parts of stalk;20-22 parts of edible fungi residues;Turfy soil:5-10 parts;5-8 parts of plant ash;5-8 parts of zeolite powder.
Preferably, it is made of the raw material of following mass parts:Crushing maize stalk:28kg;Crush cotton stalk:28 parts;Food
Use bacteria residue:22 parts;Turfy soil:10 parts;Plant ash:5 parts;Zeolite powder:7 parts.
The production method of the loosening of soil agent comprises the steps of:1) corn stover is uniformly ground into of length no more than
0.5cm powder;2) cotton stalk is uniformly ground into of length no more than 0.5cm powder;3) by the corn stover of crushing, cotton straw
Stalk and edible fungi residues uniformly mix in proportion, and crush again by pulverizer;4) by turfy soil, plant ash, zeolite powder press than
Example uniformly mixing, and spray water on a small quantity, is dust-proof;5) by above-mentioned steps 3) and the product of step 4) uniformly mix in proportion.
Application of the loosening of soil agent in terms of alkaline land improving, further includes a kind of chemical improvement agent, by following quality
The raw material of part is made, and 55-60 parts of desulfurized gypsum;17-20 parts of calcium superphosphate;20-25 parts of fulvic acid;0.1-0.5 parts of ferrous sulfate;
0.5-1 parts of poly-aspartate;0.5-1 parts of polyacrylamide.Loosening of soil agent additive amount and saline-alkali soil are 5%- by volume
20%;It is 0.5kg/m that the chemical improvement agent additive amount and saline-alkali soil, which are pressed,2-5kg/m2;
The production method of the chemical improvement agent comprises the steps of:1) first by ferrous sulfate, poly-aspartate, polypropylene
Amide crushes after mixing;2) by above-mentioned steps 1) product mixed with fulvic acid after crush;3) by above-mentioned steps 2) production
Object crushes after mixing with desulfurized gypsum, calcium superphosphate.
A method of using the loosening of soil agent, using following steps in sequence:
1) plot site inspection is improved:The plot that first improve to needs before reclamation of salinep-alkali soil solution formulation is surveyed
It visits, including soil types, topography, slope aspect, groundwater depth, periphery can utilize greening irrigation water (municipal water, surface water), row
Water route line, road of marching into the arena etc.;
2) soil sample:Original-state soil is sampled, carries out soil profile sampling and surface area respectively;
3) water sampling:Surrounding with clean container respectively in plot takes surface water and groundwater water sample;
4) soil sample is analyzed:Soil sample is carried out after air-drying pulverization process in laboratory, measures the total salt, potassium ion, sodium of soil sample
Ion, calcium ion, magnesium ion, chloride ion, sulfate ion, bicarbonate ion, carbanion, pH value and permeability;
5) water sample analysis:Salinity, total salt are measured, to determine whether to be used as watering pours water;
6) design of evolutionary approach:The test result of step 4) and step 5) measurement is analyzed, by soil saliferous
Amount is down to 0.3%, and hereinafter, pH value is down to 9, the following are Breeding objectives, determine loosening of soil agent and the addition of saline-alkali soil modifying agent ratio
Example.Ratio according to the corresponding addition loosening of soil agent of China's saline-alkali soil grade scale is as follows:Slight saline-alkali soil loosening of soil agent
Adding proportion is 5-8% (volume ratio), and the adding proportion of chemical improvement agent is 0.5-1.5kg/m2;Moderate saline-alkali soil adding proportion
Adding proportion for 8-15% (volume ratio) chemical improvement agent is 1.5-2.5kg/m2;Heavy salinized soil adding proportion is 15-
20%, the adding proportion of chemical improvement agent is 2.5-5kg/m2。
7) indoor leaching test:The soil that will be fetched, according to the evolutionary approach that step 6) is formulated, by loosening of soil agent, salt
Alkali soil improvement agent is sufficiently puddled with original soil, is packed into earth pillar, and watering carries out leaching test, observes watering pours water infiltration rate, detection leaching
Molten water salt content and variation, soil salt content variation in layered weighting earth pillar, verify improved effect;
8) raw material is uniformly mixed with saline-alkali soil:Loosening of soil agent and chemical improvement agent are uniformly sprinkling upon in proportion and need to improve
The surface of soil, in a manner of mixing dirt, the depth that improves as required is by saline-alkali soil and loosening of soil agent and the reclamation of salinep-alkali soil
Agent is sufficiently mixed, and after mixing uniformly, is mixed again after mixed material is stacked 3 days primary;Earth's surface is flattened, improvement work in next step is prepared
Sequence;
9) setting of salt discharge ditch:In conjunction with the depth and groundwater depth for carrying out improvement soil, the depth of salt discharge ditch is determined
Degree and width, are arranged the trend of main salt discharge ditch and branch salt discharge ditch;
10) salt discharge device is buried:Non-woven fabrics is laid in salt discharge ditch first, then (rubble is straight in the rubble for being laid with 5cm thickness
Diameter is less than 3cm), main salt discharging pipe and branch salt discharging pipe are secondly laid on metalling, main salt discharging pipe and branch salt discharging pipe infall need
It connects, and is sealed with sealing adhesive waterproof tape, so that water is discharged in time;The clean broken of 15cm is covered on the salt discharging pipe completed again
Stone finally lives rubble and salt discharging pipe with non-woven wraps, prevents silt by salt discharging pipe silting;It, will after salt discharge device is embedded
Salt discharge ditch landfill, flattens earth's surface;
11) it pours water, salt discharge:After flattening earth's surface, according to plot ridging, compacting, broad irrigation salt discharge;In main salt discharging pipe and branch
The water intaking of salt discharge nozzle, keep sample detection.
12) physical and chemical index of leaching water, soil is surveyed:The soil sample taken and water sample are subjected to pre-treatment, and measure soil sample
Total salt, potassium ion, sodium ion, calcium ion, magnesium ion, chloride ion, sulfate ion, bicarbonate ion, carbanion, pH
Value and permeability;The salinity of water sample, total salt;
13) according to above-mentioned steps 12) measured as a result, if conditioned soil total salt be lower than 0.3%, pH value be lower than 9, reach
Expected Breeding objectives, are improved successfully;If soil total salt or pH value, which are not up to Breeding objectives, needs to carry out step 11) filling again
Water, salt discharge.
Preferably, the step 2) section is sampled as:Base area block size sets 3 points per acre and carries out section sampling, every
20cm sampling, depth selection 1m;Surface area is:Base area block size at least sets 5 point samplings per acre, to reject surface layer
20cm soil sample.
Preferably, main salt discharge ditch spacing 18-20m, depth 80-90cm, width 45-50cm in the step 9), and to row
There are 3 ‰ gradient, main salt discharge ditches to intersect vertically with branch salt discharge ditch for ditch side.
Preferably, branch salt discharge ditch spacing 4-6m, depth 50-60cm, width 45-50cm in the step 9), and to two sides
There are 3 ‰ gradient, main salt discharge ditches to intersect vertically with branch salt discharge ditch for main salt discharge ditch.
Preferably, salt discharge of being poured water three times is needed in the step 11);After needing to wait the completely lower infiltration of water every time, then the
It is poured water for the second time within two days;It needs to fetch water in main blind pipe and branch blind pipe mouth when pouring water every time, keep sample detection.
Preferably, main salt discharging pipe is the external form adding other auxiliary agents by high density polyethylene (HDPE) and being formed in the step 10)
Corrugated novel infiltration draining.
Compared with prior art, the beneficial effects of the invention are as follows:
Loosening of soil agent provided by the invention can improve soil texture, increase soil aeration, supplement organic matter;With
Chemical improvement agent commonly used in the prior art combines, and can play drop alkali desalination by the sodium ion in ion exchange soil
Effect, under the premise of being changed without soil, can thoroughly improve saline-alkali soil, make it for agricultural production or urban afforestation.
Detailed description of the invention
Fig. 1 is to use loosening of soil agent flow chart;
Fig. 2 is salt discharge ditch distribution map.
Specific embodiment
In order to make those skilled in the art more fully understand technical solution of the present invention, with reference to the accompanying drawing and most
The present invention is described in further detail for good embodiment.
1. experimental material
Engineering test place is located at Tianjin production area adjacent to prot, and soil belongs to strand clay, and salt content average value is 17 ‰, pH
Value is 8.23, and soil water permeability is close to 0.Engineering test ground 224m long from south to north, thing wide 30.5m, area 6832m2.In plot
Between set the sidewalk of a wide 3.5m of running due north and due south plot be divided into two pieces of thing, the wide 14m in east plot, area 3136m2;West
The wide 13m in portion plot, area 2912m2。
Thing plot is respectively divided into 11 plot, every piece of 200m by north orientation south by this test2, number is respectively east 1-
11, west 1-11;
Embodiment one:
Loosening of soil agent:Crushing maize stalk:28kg;Crush cotton stalk:28kg;Edible fungi residues:22kg;Turfy soil:
10kg;Plant ash:5kg;Zeolite powder:7kg.
Chemical improvement agent:Desulfurized gypsum 55kg;Calcium superphosphate 20kg;Fulvic acid 20kg;Ferrous sulfate 0.5kg;Poly- asparagus fern
Propylhomoserin 1kg;Polyacrylamide 1kg.
Embodiment two:
Loosening of soil agent:Crushing maize stalk:25kg;Crush cotton stalk:25kg;Edible fungi residues:20kg;Turfy soil:
10kg;Plant ash:8kg;Zeolite powder:8kg.
Chemical improvement agent:Desulfurized gypsum 60kg;Calcium superphosphate 17kg;Fulvic acid 25kg;Ferrous sulfate 0.3kg;Poly- asparagus fern
Propylhomoserin 1kg;Polyacrylamide 0.5kg.
Embodiment three:
Loosening of soil agent:Crushing maize stalk:26kg;Crush cotton stalk:28kg;Edible fungi residues:22kg;Turfy soil:
10kg;Plant ash:5kg;Zeolite powder:7kg.
Chemical improvement agent:Desulfurized gypsum 57.5kg;Calcium superphosphate 20kg;Fulvic acid 22kg;Ferrous sulfate 0.1kg;Poly- day
Aspartic acid 0.5kg;Polyacrylamide 0.7kg.
Example IV:
Loosening of soil agent:Crushing maize stalk:28kg;Crush cotton stalk:28kg;Edible fungi residues:22kg;Turfy soil:
10kg;Plant ash:5kg;Zeolite powder:7kg.
Chemical improvement agent:Desulfurized gypsum 57.5kg;Calcium superphosphate 20kg;Fulvic acid 25kg;Ferrous sulfate 0.5kg;Poly- day
Aspartic acid 1kg;Polyacrylamide 1kg.
2. being illustrated by taking embodiment one as an example:
Experimental method and interpretation of result:
It is required according to field condition with construction unit, test reclamation of salinep-alkali soil depth 80cm.
The exploration of 2.1 plot
Scene is reconnoitred, plot is more smooth, in the low trend in the high south in north.
Plot thing wide 30.5m, 224m long from south to north, there is the temporarily road in a north-south among plot, and plot north section is tight
Adjacent highway, plot east, west, three face of south be gutter, 1.5 meters of ditch depth.
Underground water buried depth 1.25m;Road northernmost in plot has upper well, belongs to municipal tap water pipe network, can be with
As greening irrigation water.
2.2 soil sample
The soil for taking 5 points at random in plot, marks each sample point, needs to take label after improvement
Sampling point carries out sub-sampling again.Soil profile observation also is carried out to 5 sample points simultaneously, on-site soil is ooze barged-in fill, is not had
Apparent physical structure.
2.3 water sampling
With clean mineral water bottle by plot gutter water sampling, and take underground water 1.5m deep water sample.
The analysis of 2.4 soil samples
Soil sample is carried out after air-drying pulverization process in laboratory, measures the total salt and pH value of soil sample, specific measurement number is such as
Under:
5 sample point solubility total salts (g/kg) and pH value in 1 plot of table
Soil sample is analyzed, it can be seen that the total salt content in plot is exceeded very serious, it is not possible to directly be afforested
Transplanted seedling tree, it is necessary to be improved.
2.5 water sample analysis
The plot belongs to ooze land reclamation, and underground water substantially belongs to seawater, it is not possible to it is used as greening irrigation water,
So not being sampled chemical examination to the surface water around underground water and plot.
The design of 2.6 evolutionary approach:The test result of the above soil sample is analyzed, total soil phosphorus is in 8-11g/kg
Between, belong to heavy salinizedly according to China's saline-alkali soil grade scale, if soil salt content is down to 0.3% hereinafter, pH value drops
To 9 the following are Breeding objectives, the additive amount of loosening of soil agent is 0.18m3/m2, the additive amount of chemical improvement agent is 5kg/m2。
Leaching is tested in Room 2.7:The soil that will be fetched, according to adding for loosening of soil agent determined above and chemical improvement agent
Dosage sufficiently puddles loosening of soil agent, saline-alkali soil modifying agent and original soil, is packed into the earth pillar of high 90cm.
Leaching of being poured water three times test, the water of filling foot, completely penetrates water outside bottom, Surface mulch every time
The water of 5cm.After impregnating 24 hours, apopore is opened, the water being completely exhausted out in earth pillar, keep sample detection;It is carried out again after 12 hours
It pours water next time, operating method is identical as first time.
After pouring water three times, leaching water salinity and pH value three times are measured respectively, soil in point three layers of detection earth pillar
Salt content and pH value, specific determination data are as follows:
Table 2 leaching water salinity and pH value three times
3 layered weighting soil total salt (g/kg) of table and pH value
By table 2, table 3 it is found that the loosing soil agent and chemical improvement agent of addition fully achieve Modified Standard, after improvement
Soil reach planting requirement, outdoor improvement engineering test can be carried out.
2.8 raw materials are uniformly mixed with saline-alkali soil
The area for improveing plot as required, buys raw material, carries out crushing as requested and puddle, loosening of soil agent is made
And chemical improvement agent, and the leavening agent made and modifying agent are transported in field.
The surface that loosening of soil agent and chemical improvement agent are uniformly sprinkling upon to plot in proportion is mixed in a manner of mixing dirt
Saline-alkali soil, loosening of soil agent and chemical improvement agent are sufficiently mixed by the depth of 90cm, are mixed three times repeatedly, are flattened earth's surface.
The setting of 2.9 salt discharge ditches
Buried depth in conjunction with underground water is 1.25m, and it is 80cm that Construction Party, which requires improvement depth, main salt discharge trench depth setting
For 90cm, in east-west, to the gradient of discharge outlet side setting 3 ‰, main salt discharge ditch width 50cm, main salt discharge ditch spacing 20m,
11 main salt discharge ditches are respectively arranged in the east and west sides in plot.
Branch salt discharge ditch is arranged in the north-south in plot, and 3 branch salt discharge ditches are respectively arranged in the east and west sides in plot, and 6 branch are arranged altogether
Salt discharge ditch.High two sides are low among branch salt discharge ditch between two main salt discharge ditches, and the gradient is 3 ‰, make the leaching water flow in branch salt discharge ditch
To main salt discharge ditch, plot is excluded;The depth 60cm of branch salt discharge ditch, width 50cm.(see Figure of description 2)
2.10 embedded salt discharge device:
Before embedded salt discharge device, rubble, non-woven fabrics and salt discharging pipe (main salt discharging pipe and branch salt discharging pipe), the grain of rubble are first bought
Diameter will be between 2-3cm;The wide cut of non-woven fabrics is 1.2m, specification 200g/m2, good water permeability;The material of salt discharging pipe is PVC's
Screwed pipe is evenly arranged drainage hole in the ditch of screw thread, can make leaching water smoothly collect enter salt discharging pipe, main salt discharging pipe it is straight
Diameter is 80mm, and the diameter of branch salt discharging pipe is 60mm, and salt discharging pipe is required to by non-woven wraps.Salt discharge dress is buried after buying material
It sets:
It is laid with non-woven fabrics in main salt discharge ditch and branch salt discharge ditch respectively first, is then laid with rubble, laying depth 5cm;
Secondly main salt discharging pipe and branch salt discharging pipe are laid on metalling, main salt discharging pipe connects with branch salt discharging pipe infall needs
It is logical, and sealed with sealing adhesive waterproof tape, so that water is discharged in time;
Rubble is covered on the salt discharging pipe completed again, rubble is with a thickness of 15cm;
Non-woven wraps are finally lived into rubble and salt discharging pipe, prevent silt by salt discharging pipe silting;Salt discharge device is embedded to be finished
Afterwards, salt discharge ditch is filled, flattens earth's surface.
It 2.11 pours water, salt discharge
After flattening earth's surface, first by two plot surrounding ridgings of thing, compacting in plot;Then respectively by two plot of thing
It is divided into the small plot of width 20m, east side is divided into 11 plot, and number is respectively eastern 1, eastern 2, eastern 3 ... east 11 by north to south,
West side is also divided into 11 plot, and number is respectively west 1, west 2, west 3 ... west 11, and plot is arranged by this can be under each small plot
A salt discharging pipe is all buried.
5 sample points marked when marching into the arena and sampling are corresponded to respectively at plot after dividing plot, corresponding sample point 1 is east
3, corresponding sampling second is east 9, and corresponding sample point three is east 11, and corresponding sample point 4 is west 7, and sample point 5 is corresponding to be
West 11.Hereinafter land used block number replaces sample point to carry out analytic explanation.
Broad irrigation plot is carried out after dividing plot, after salt discharging pipe water outlet, it is 5cm that earth's surface, which overflows water depth, is poured water twice
It at least needs to be spaced 24 hours, pouring water to the last time can just be poured water after all permeating next time, need 3 fillings altogether
Water needs to take leaching water at corresponding salt discharging pipe after pouring water every time, and keep sample detection.After 3 times are poured water, according to exploration of marching into the arena
Corresponding 5 points go the soil sample after improvement respectively, are detected.
2.12 survey the physical and chemical index of leaching water, soil
The soil sample taken and water sample are subjected to pre-treatment, and measure the total salt of soil sample, pH value;The salinity of water sample, total salt.
Specific detection data is as follows:Soil physico-chemical index
5 sample point topsoil solubility total salts (g/kg) and pH value after table 4 is improved
As can be seen from Table 4, the soluble total salt after same plot salt discharge is average to reduce than there is apparent reduction before salt discharge
To 2.197g/kg, and the standard of Tianjin Urban Greening soil plant has all been reached (soil salt content is less than 3g/kg).
Soluble total salt content is declined in each plot soil, and 11 plot of Chinese and Western declines 8.355g/kg;West 7
Plot declines 6.485g/kg;Eastern 11 plot decline 8.065g/kg;Eastern 9 plot decline 7.905g/kg;Eastern 3 plot decline
5.885g/kg, 5 plot averagely decline 7.339g/kg.
PH value after improveing as can be seen from Table 4 in soil also all meets Tianjin Urban Greening plant standard (pH value is less than 9).
But the pH value in all plot is all in raising trend, maximum elevation amplitude is eastern 9 plot, and pH value increases 1, elevation amplitude
The smallest is eastern 11 plot, and pH value increases 0.3,5 plot pH value and averagely increases 0.6.
Cause above-mentioned pH value raised the reason is that:With the progress of washing salinity by irrigation, the Na being adsorbed on soil colloid+It is dissolved in
Water, and the soil body is discharged with water, soil colloid then adsorbs the H in fixed water+, the OH of free state-Make the aobvious alkalinity of soil, so pH
It is increased before value ratio.With continuing for soil improvement, soil colloid is destroyed, and soil aggregate structure increases, the pH of soil
Value can be in again downward trend.
The content of the soluble total salt (g/kg) of each sample point different depth soil after table 5 is improved
Soluble total salt content after improveing as can be seen from Table 5 in soil gradually decreases from deep to shallow, 11 ground of the Middle East
Block improved effect is best, underground 20,60, at 80cm soil soluble total salt content all below 3 ‰;The 20cm of other sample points
With 60cm total salt 3 ‰ hereinafter, the total salt content of only 80cm sample point is slightly above 3 ‰, this may be due to 80cm depth
Identical as main salt discharging pipe depth, underground sea water is reverse osmosis, and total salt content is caused to rise.
PH value after table 6 is improved in each plot different depth soil
Show that the pH value after the improvement of same plot in different depth soil all meets Tianjin afforestation to plant by table 6
The standard requirements of soil.
Different soil depth pH value does not change much, and is in alkalescent.The reason is that soil colloid adsorbs the H being fixed in water+, so the OH of free state-Make the aobvious alkalinity of soil.
Leaching water physical and chemical index:
5 plot in salt discharge of pouring water three times of table 7 keep sample the salinity (mg/L) of leaching water
It learns that the salinity in same plot discharge water sample in decreasing trend, meets salt discharge rule by table 7, and wherein occurs
Amplitude be and to pour water that be spaced number of days be by need to improve soil and leavening agent, modifying agent due to caused by irrigation period interval
Between puddle uniformity coefficient influence, the soil of outdoor large-engineering amount is mixed and is wanted relative to testing indoor soil-column test and mix difficulty
Much larger, part is unevenly within the error range.
8 each plot watering time interval (day) of table
It is learnt according to table 7 and table 8, interval and the brine rate of irrigation period are closely connected, and interval time length can make to pour
It pours water and sufficiently impregnates soil, the salinity in soil can be made preferably to be dissolved in and retained in watering pours water in the soil, convenient for next time
It pours water and reaches better desalting effect, such as eastern 9 plot;And interval time of pouring water every time is grasped also can make salt discharge effect more
It is good, it is that it tapers off state, such as western 9 plot.
Table 9 is poured water the pH value that different plot leaching water keeps sample in salt discharge three times
The same plot pH value to keep sample of pouring water three times is substantially unchanged as can be seen from Table 9, is in neutrality, the reason is that leaching out
Watering pours water in saliferous main component be NaCl, be in neutrality.
2.13 analyze according to above-mentioned soil sample as a result, the soil sample total salt after improveing is lower than 0.3%, and pH value is lower than 9, reaches expected
Breeding objectives, improve successfully.Specific conclusion is as follows:
3. conclusion
The variation of 3.1 soil salt contents:Soluble total salt content is all decreased significantly in soil after improvement, is all dropped to
3g/kg is hereinafter, fully meet the standard of Tianjin Urban Greening soil plant.
3.2 changes of pH:PH value is below 9 in soil after improvement, fullys meet the plant of Tianjin Urban Greening soil
Standard.
The variation of 3.3 leaching water salinities:The salinity to keep sample of pouring water three times in improvement is all on a declining curve, meets salt discharge rule
Rule.
The pH value of 3.4 leaching water changes:The pH value to keep sample of pouring water three times in improvement is substantially unchanged, is in neutrality, be due to
The main component of saliferous is NaCl in leaching water, is in neutrality.
In summary:Improvement, which has successfully reached, can transplant condition, and carrying out saline-alkali soil with this method, improvement can reach in situ
To good effect.
The embodiment of invention is described in detail above, but content is only the preferred embodiment of the present invention, no
It can be believed to be used to limit the scope of the invention.Any changes and modifications in accordance with the scope of the present application,
It should still fall within the scope of the patent of the present invention.
Claims (5)
1. a kind of application of loosening of soil agent in terms of the reclamation of salinep-alkali soil, which is characterized in that the loosening of soil agent is by following matter
The raw material of amount part is made:25-28 parts of crushing maize stalk;Crush cotton stalk 25-28 parts;20-22 parts of edible fungi residues;Turf
Soil:5-10 parts;5-8 parts of plant ash;5-8 parts of zeolite powder.
2. application of the loosening of soil agent according to claim 1 in terms of the reclamation of salinep-alkali soil, which is characterized in that the soil
Leavening agent is made of the raw material of following mass parts:It is made of the raw material of following mass parts:Crushing maize stalk:28 parts;Crush cotton
Chopped straw stalk:28 parts;Edible fungi residues:22 parts;Turfy soil:10 parts;Plant ash:5 parts;Zeolite powder:7 parts.
3. application of the loosening of soil agent according to claim 1 in terms of the reclamation of salinep-alkali soil, which is characterized in that the soil
Leavening agent is made by following step:1) corn stover is uniformly ground into of length no more than 0.5cm powder;2) by cotton stalk
Uniformly it is ground into of length no more than 0.5cm powder;3) corn stover of crushing, cotton stalk and edible fungi residues are uniform in proportion
Mixing, and crushed again by pulverizer;4) turfy soil, plant ash, zeolite powder are uniformly mixed in proportion, and sprays water, is dust-proof;
5) by above-mentioned steps 3) and the product of step 4) uniformly mix in proportion.
4. application of the loosening of soil agent in terms of the reclamation of salinep-alkali soil described in one of -3 according to claim 1, which is characterized in that also
In terms of being applied to soil improvement together with a kind of chemical improvement agent, wherein loosening of soil agent additive amount and saline-alkali soil press volume
Than for 5%-20%;Additive amount of the chemical improvement agent in saline-alkali soil is 0.5kg/m2-5kg/m2;Chemical improvement agent is under
The raw material for stating mass parts is made, and 55-60 parts of desulfurized gypsum;17-20 parts of calcium superphosphate;20-25 parts of fulvic acid;Ferrous sulfate 0.1-
0.5 part;0.5-1 parts of poly-aspartate;0.5-1 parts of polyacrylamide.
5. loosening of soil agent according to claim 4 is in the application in terms of the reclamation of salinep-alkali soil, which is characterized in that describedization
The production method for learning modifying agent comprises the steps of:1) first by ferrous sulfate, poly-aspartate, polyacrylamide after mixing
It crushes;2) by above-mentioned steps 1) product mixed with fulvic acid after crush;3) by above-mentioned steps 2) product and desulfurized gypsum, mistake
Calcium phosphate crushes after mixing.
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CN106396883A (en) * | 2016-08-30 | 2017-02-15 | 山东胜伟园林科技有限公司 | Saline and alkaline soil improvement agent including soil loosening agent, and preparation method of soil improvement agent |
CN107189781A (en) * | 2017-04-28 | 2017-09-22 | 哈尔滨明慧生物技术开发有限公司 | Soil remediation composite bacteria agent and its soil remediation method |
CN109997443A (en) * | 2019-04-18 | 2019-07-12 | 农安县春江堰家庭农场 | A kind of saline-alkali soil improvement method |
CN112207123B (en) * | 2020-09-25 | 2022-06-28 | 连云港金海岸开发建设有限公司 | Soil salt washing device and method |
CN113439498B (en) * | 2021-06-17 | 2023-03-17 | 广西壮族自治区自然资源生态修复中心 | Method for stripping plough layer in karst rocky mountain area |
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