CN105419710A - Water-resistant marble adhesive as well as preparation method and application method thereof - Google Patents
Water-resistant marble adhesive as well as preparation method and application method thereof Download PDFInfo
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- CN105419710A CN105419710A CN201510934550.5A CN201510934550A CN105419710A CN 105419710 A CN105419710 A CN 105419710A CN 201510934550 A CN201510934550 A CN 201510934550A CN 105419710 A CN105419710 A CN 105419710A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a water-resistant marble adhesive as well as a preparation method and an application method thereof and belongs to the technical field of building adhesives. The water-resistant marble adhesive comprises a component A and a component B, wherein the component A comprises the following raw materials: 50-80 parts of water-resistant resin, 5-20 parts of a diluent, 0.05-0.4 parts of an inhibitor, 0.03-0.3 parts of an accelerant, 1-3 parts of a thixotropic agent and 20-60 parts of reinforcing filler; the component B comprises the following raw materials: 40-60 parts of a curing agent, 30-50 parts of a plasticizer, 0.5-1.5 parts of an emulsifier and 1-3 parts of a thixotropic agent. According to the application method, the component A and the component B are mixed uniformly in the mass ratio being 100:(1-3) for application. The water resistance is improved remarkably, and extreme chemical corrosion resistance is realized; the adhesive has the high curing speed, high bonding strength, good flexibility and elasticity as well as excellent yellowing resistance and hydrothermal resistance; convenience in use is realized.
Description
Technical field
The invention belongs to adhesive for building technical field, be specifically related to a kind of water-resisting type cloud stone glue, and relate to its preparation and application.
Background technology
Cloud stone glue is widely used in bonding between all kinds of stone material or fills up for the flaw in such as crack, hole, sand holes and so on to stone surface and repairing to stone material mark of break.
Cloud stone glue have single component and two-pack point, the cloud stone glue of single component is as CN102146571B (cloud stone glue and preparation technology thereof) and CN103571422B (a kind of cloud stone glue); The typical document of the cloud stone glue of two-pack is open as CN101735760A (a kind of cloud stone glue and preparation method thereof).The strong point such as have that gelation rate is fast, set time is short due to two-pack cloud stone glue relative to single component cloud stone glue and bonding strength is high, thus generally uses two-pack cloud stone glue at present.
The raw material of the component A of the two-pack cloud stone glue in prior art is mostly: unsaturated polyester resin, stopper, promotor, filler and thickening material; The raw material of B component is mostly solidifying agent, softening agent, filler and thickening material, can be seen in aforesaid CN101735760A to this.During use, component A is mixed by a certain percentage with B component.
By known to the reading of the patent documentation being not limited to exemplify above: why people hanker after adopting unsaturated polyester resin in cloud stone glue raw material, be because the main chain of unsaturated polyester resin has a large amount of ester bonds and double bond, there is higher reactive behavior.But the weakness of unsaturated polyester resin is not often people's enough attention, so-called weakness is as large in shrinking percentage, wet-heat resisting and resistance to acids and bases poor, particularly ester bond easy fracture under long-term hygrothermal environment, just in view of this factor, cloud stone glue containing unsaturated polyester resin can not be used for the structural bonding of material of construction usually, such as because losing toughness and elasticity and dry-hang stone can not being used for, thus have impact on the expansion of its purposes to a certain extent.
Summary of the invention
Task of the present invention is to provide a kind of and contributes to improving water tolerance, be conducive to strengthening chemical resistance, be of value to promoting bonding strength and having and be convenient to embody good toughness and elastic water-resisting type cloud stone glue.
Another task of the present invention is the preparation method providing a kind of water-resisting type cloud stone glue, and the water-resisting type cloud stone glue prepared by the method can ensure that technique effect described in it is able to comprehensive embodiment.
Another task of the present invention is the using method providing a kind of water-resisting type cloud stone glue, and the method has instant allotment and allotment fast and easily strong point.
Task of the present invention has been come like this, a kind of water-resisting type cloud stone glue, comprise component A and B component, described component A is made up of the raw material of following proportioning by weight: water-resisting type resin 50-80 part, thinner 5-20 part, stopper 0.05-0.4 part, promotor 0.03-0.3 part, thixotropic agent 1-3 part and reinforcing filler 20-60 part; Described B component is made up of the raw material of following proportioning by weight: solidifying agent 40-60 part, softening agent 30-50 part, emulsifying agent 0.5-1.5 part and thixotropic agent 1-3 part.
In a specific embodiment of the present invention, described water-resisting type resin is the mixture that the vibrin of organosilicon modifier modification mixes by any weight ratio mutually with vinyl modified epoxy resin; Described organosilicon modifier is one or more the mixture in methyl tributanoximo silane, methyltrimethoxy silane, methyl triacetyl silane, r-aminopropyl triethoxysilane, r-(2,3-epoxy third oxygen) propyl trimethoxy silicane.
In another specific embodiment of the present invention, described vinyl modified epoxy resin is a kind of in acrylic modified bisphenol A type epoxy resin, acrylic modified resol or both mixtures.
In another specific embodiment of the present invention, described thinner is vinylbenzene; Described resist is one or more the mixture in benzoquinones, quinhydrones, toluhydroquinone, t-butyl catechol, tertiarybutylhydroquinone, naphthoquinones.
In another specific embodiment of the present invention, described promotor is one or more the mixture in DMA, N, N-Diethyl Aniline, N, N-dimethyl-p-toluidine; Described thixotropic agent is one or more the mixture in hydrogenated castor oil, aerosil, low molecular polyamides wax, low molecular weight polyethylene, organobentonite.
Also have in a specific embodiment of the present invention, reinforcing filler is one or more the mixture in silicon powder, silica powder, talcum powder, water-ground limestone, calcite in powder, enhancing staple fibre; Described solidifying agent is benzoyl peroxide.
More of the present invention and in a specific embodiment, described softening agent is one or more the mixture in propylene glycol dibenzoate, polyoxyethylene glycol phthalic ester, diphenyl phosphate isodecyl ester, dimethyl phthalate, dibutyl phthalate, dioctyl phthalate (DOP); Described emulsifying agent is one or more the mixture in the special nonionogenic tenside of Tao Shi, sorbester p17, polysorbate60, OP-10.
Another task of the present invention has been come like this, and a kind of preparation method of water-resisting type cloud stone glue, comprises the following steps:
A) component A is prepared: the water-resisting type resin 50-80 part taken by weight, thinner 5-20 part, stopper 0.05-0.4 part and promotor 0.03-0.3 part are dropped into successively in the reaction vessel with agitator and stir, then the thixotropic agent 1-3 part taken by weight is dropped in reaction vessel, high-speed stirring, the reinforcing filler 20-60 part taken by weight is dropped into again in reaction vessel, then stir, vacuumize, blowing, obtain component A;
B) B component is prepared: the solidifying agent 40-60 part taken by weight and softening agent 30-50 part are added successively in the reaction vessel with agitator and stir evenly, then in reaction vessel, add the emulsifying agent 05-1.5 part taken by weight continue to stir, the thixotropic agent 1-3 part taken by weight is added in the most backward reaction vessel, high speed dispersion stirs, discharging, obtains B component.
In an of the present invention and then specific embodiment, steps A) described in the churning time stirred be 10-20min, the time of described high-speed stirring is 10-15min, and the described time of then stirring is 15-30min; Step B) described in the time stirred evenly be 10-15min, the described time of continuing to stir is 5-10min, and the time that described high speed dispersion stirs is 10-15min.
Another task of the present invention has been come like this, a kind of using method of water-resisting type cloud stone glue, and it is that component A 100: 1-3 is mixed rear use in mass ratio with B component.
The technique effect of technical scheme provided by the invention is; Have employed water-resisting type resin due to the unsaturated polyester resin abandoned in prior art, due to water-resisting type resin, there is excellent cross-linking density again and can three-dimensional net structure be formed with, thus can not be hydrolyzed and significantly be improved water tolerance; Ultimate attainment chemical resistance is embodied owing to having excellent acid-proof alkaline; Curing speed is fast, bonding strength is high, snappiness and good springiness, color inhibition and wet-hot aging performance excellent.The preparation method provided can ensure the aforementioned techniques effect of water-resisting type cloud stone glue all sidedly.Component A and B component only need mix by the using method provided, and have and are convenient to embody convenience when using.
Embodiment
Embodiment 1:
The preparation method of water-resisting type cloud stone glue provided by the invention comprises the following steps:
A) component A is prepared: by the water-resisting type resin 50 parts taken by weight, vinylbenzene 15 parts, quinhydrones 0.05 part, tertiarybutylhydroquinone 0.05 part and N, accelerine 0.08 part drops into reaction vessel with agitator successively as stirred in reactor, the time of stirring is 20min, then by hydrogenated castor oil 1 part of input reaction vessel of taking by weight, high-speed stirring 15min, the silicon powder 40 parts and enhancing 10 parts, staple fibre that take by weight is dropped into again in reaction vessel, then 30min is stirred, vacuumize, blowing is also filling, obtain component A, water-resisting type resin described in this step is by 40 parts, vibrin and vinyl modified epoxy resin 10 parts of mixtures mixed mutually of organosilicon modifier modification, described organosilicon modifier is methyltrimethoxy silane, and described vinyl modified epoxy resin is acrylic modified bisphenol A type epoxy resin,
B) B component is prepared: the benzoyl peroxide 60 parts taken by weight and diphenyl phosphate isodecyl ester 30 parts are added successively in the reaction vessel with agitator and stir evenly, the time stirred evenly is 15min, then in reaction vessel, add the polysorbate60 (Tween-60) 0.5 part taken by weight continue to stir with OP-100.5 part, the time of continuing to stir is 10min, the aerosil 3 parts taken by weight is added in the most backward reaction vessel, high speed dispersion stirs 15min, discharging is also filling, obtains B component.
Embodiment 2:
The preparation method of water-resisting type cloud stone glue provided by the invention comprises the following steps:
A) component A is prepared: by the water-resisting type resin 80 parts taken by weight, vinylbenzene 20 parts, toluhydroquinone 0.1 part, naphthoquinones 0.2 part, t-butyl catechol 0.1 part and N, N-Diethyl Aniline 0.2 part and N, N-dimethyl-p-toluidine 0.1 part drops into reaction vessel with agitator successively as stirred in reactor, the time of stirring is 15min, the low molecular weight polyethylene 1 part then will taken by weight, 1 part, low molecular polyamides wax is with in wilkinite 1 part of input reaction vessel, high-speed stirring 10min, the silicon powder 60 parts taken by weight is dropped into again in reaction vessel, then 15min is stirred, vacuumize, blowing is also filling, obtain component A, water-resisting type resin described in this step is by 40 parts, vibrin and vinyl modified epoxy resin 40 parts of mixtures mixed mutually of organosilicon modifier modification, described organosilicon modifier is methyltrimethoxy silane, the mixture of methyl tributanoximo silane and methyl triacetyl silane, and described vinyl modified epoxy resin is the mixture of acrylic modified bisphenol A type epoxy resin and acrylic modified resol,
B) B component is prepared: by the benzoyl peroxide 40 parts taken by weight, dimethyl phthalate 15 parts, dibutyl phthalate 15 parts and dioctyl phthalate (DOP) 20 parts add successively in the reaction vessel with agitator and stir evenly, the time stirred evenly is 10min, then in reaction vessel, add the sorbester p17 (Span-80) 1.5 parts taken by weight continue to stir, the time of continuing to stir is 10min, the hydrogenated castor oil 1 part taken by weight is added successively in the most backward reaction vessel, aerosil 0.5 part and low molecular weight polyethylene 0.5 part, high speed dispersion stirs 10min, discharging is also filling, obtain B component.
Embodiment 3:
The preparation method of water-resisting type cloud stone glue provided by the invention comprises the following steps:
A) component A is prepared: by the water-resisting type resin 65 parts taken by weight, vinylbenzene 5 parts, benzoquinones 0.05 part, N, N-Diethyl Aniline 0.03 part drops into reaction vessel with agitator successively as stirred in reactor, the time of stirring is 10min, then by the low molecular weight polyethylene 1 part that takes by weight and low molecular polyamides wax 1 part of input reaction vessel, high-speed stirring 12min, the talcum powder 10 parts and silica powder 8 parts and hydrogenated castor oil 2 parts that take by weight is dropped into again in reaction vessel, then 20min is stirred, vacuumize, blowing is also filling, obtain component A, water-resisting type resin described in this step is by 35 parts, vibrin and vinyl modified epoxy resin 30 parts of mixtures mixed mutually of organosilicon modifier modification, described organosilicon modifier is r-aminopropyl triethoxysilane and r-(2, 3-epoxy third oxygen) mixture of oxypropyl trimethyl silane, and described vinyl modified epoxy resin is acrylic modified resol,
B) B component is prepared: the benzoyl peroxide 50 parts taken by weight and polyoxyethylene glycol phthalic ester 50 parts are added successively in the reaction vessel with agitator and stir evenly, the time stirred evenly is 12min, then in reaction vessel, add the special nonionogenic tenside of the Tao Shi taken by weight (Tergitol-XD) 1.5 parts continue to stir, the time of continuing to stir is 8min, the aerosil 0.5 part and low molecular weight polyethylene 0.5 part that take by weight is added in the most backward reaction vessel, high speed dispersion stirs 12min, discharging is also filling, obtain B component.
Embodiment 4:
The preparation method of water-resisting type cloud stone glue provided by the invention comprises the following steps:
A) component A is prepared: by the water-resisting type resin 70 parts taken by weight, vinylbenzene 10 parts, tertiarybutylhydroquinone 0.25 part, N, accelerine 0.04 part, N, N-Diethyl Aniline 0.04 part and N, N-dimethyl-p-toluidine 0.04 part drops into reaction vessel with agitator successively as stirred in reactor, the time of stirring is 18min, then by hydrogenated castor oil 2.5 parts of input reaction vessels of taking by weight, high-speed stirring 14min, the water-ground limestone 20 parts and silica powder 20 parts that take by weight is dropped into again in reaction vessel, then 25min is stirred, vacuumize, blowing is also filling, obtain component A, water-resisting type resin described in this step is by 50 parts, vibrin and vinyl modified epoxy resin 20 parts of mixtures mixed mutually of organosilicon modifier modification, described organosilicon modifier is methyl triacetyl silane, and described vinyl modified epoxy resin is acrylic modified bisphenol A type epoxy resin,
B) B component is prepared: by the benzoyl peroxide 55 parts taken by weight, polyoxyethylene glycol phthalic ester 20 parts and propylene glycol dibenzoate 20 parts add successively in the reaction vessel with agitator and stir evenly, the time stirred evenly is 14min, then in reaction vessel, add the polysorbate60 (Tween-60) 0.3 part taken by weight, sorbester p17 (Span-80) 0.4 part and OP-100.3 part continue to stir, the time of continuing to stir is 6min, the aerosil 0.5 part taken by weight is added successively in the most backward reaction vessel, 0.5 part, low molecular polyamides wax and low molecular weight polyethylene 0.5 part, high speed dispersion stirs 14min, discharging is also filling, obtain B component.
Example 1:
The component A obtained by embodiment 1 is mixed rear use in mass ratio with B component at 100: 1.5.
The component A obtained by embodiment 2 is mixed rear use in mass ratio with B component at 100: 2.
The component A obtained by embodiment 3 is mixed rear use in mass ratio with B component at 100: 3.
The component A obtained by embodiment 4 is mixed rear use in mass ratio with B component at 100: 1.
The water-resisting type cloud stone glue obtained by above-described embodiment 1 to 4 has the technique effect shown in following table after tested.
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Presetting period (25 DEG C) | 3′12″ | 2′50″ | 2′25″ | 3′35″ |
| Set time (25 DEG C) | 6′15″ | 5′53″ | 5′16″ | 6′45″ |
| Bending elastic modulus > 5000MPa | 5800MPa | 5500MPa | 5200MPa | 5300MPa |
| Compression shear strength (stone material-stone material) > 14MPa | 15.5MPa | 15.8MPa | 15.9MPa | 14.8MPa |
| 55 degree of hot-water soaks, 7 days intensity > 12MPa | 12.8MPa | 12.5MPa | 12.1MPa | 13.2MPa |
Claims (10)
1. a water-resisting type cloud stone glue, comprise component A and B component, it is characterized in that described component A is made up of the raw material of following proportioning by weight: water-resisting type resin 50-80 part, thinner 5-20 part, stopper 0.05-0.4 part, promotor 0.03-0.3 part, thixotropic agent 1-3 part and reinforcing filler 20-60 part; Described B component is made up of the raw material of following proportioning by weight: solidifying agent 40-60 part, softening agent 30-50 part, emulsifying agent 0.5-1.5 part and thixotropic agent 1-3 part.
2. water-resisting type cloud stone glue according to claim 1, is characterized in that described water-resisting type resin is the mixture that the vibrin of organosilicon modifier modification mixes by any weight ratio mutually with vinyl modified epoxy resin; Described organosilicon modifier is one or more the mixture in methyl tributanoximo silane, methyltrimethoxy silane, methyl triacetyl silane, r-aminopropyl triethoxysilane, r-(2,3-epoxy third oxygen) propyl trimethoxy silicane.
3. water-resisting type cloud stone glue according to claim 2, is characterized in that described vinyl modified epoxy resin is a kind of in acrylic modified bisphenol A type epoxy resin, acrylic modified resol or both mixtures.
4. water-resisting type cloud stone glue according to claim 1, is characterized in that described thinner is vinylbenzene; Described resist is one or more the mixture in benzoquinones, quinhydrones, toluhydroquinone, t-butyl catechol, tertiarybutylhydroquinone, naphthoquinones.
5. water-resisting type cloud stone glue according to claim 1, is characterized in that described promotor is one or more the mixture in DMA, N, N-Diethyl Aniline, N, N-dimethyl-p-toluidine; Described thixotropic agent is one or more the mixture in hydrogenated castor oil, aerosil, low molecular polyamides wax, low molecular weight polyethylene, organobentonite.
6. water-resisting type cloud stone glue according to claim 1, is characterized in that reinforcing filler is one or more the mixture in silicon powder, silica powder, talcum powder, water-ground limestone, calcite in powder, enhancing staple fibre; Described solidifying agent is benzoyl peroxide.
7. water-resisting type cloud stone glue according to claim 1, is characterized in that described softening agent is one or more the mixture in propylene glycol dibenzoate, polyoxyethylene glycol phthalic ester, diphenyl phosphate isodecyl ester, dimethyl phthalate, dibutyl phthalate, dioctyl phthalate (DOP); Described emulsifying agent is one or more the mixture in the special nonionogenic tenside of Tao Shi, sorbester p17, polysorbate60, OP-10.
8. a preparation method for water-resisting type cloud stone glue as claimed in claim 1, is characterized in that comprising the following steps:
A) component A is prepared: the water-resisting type resin 50-80 part taken by weight, thinner 5-20 part, stopper 0.05-0.4 part and promotor 0.03-0.3 part are dropped into successively in the reaction vessel with agitator and stir, then the thixotropic agent 1-3 part taken by weight is dropped in reaction vessel, high-speed stirring, the reinforcing filler 20-60 part taken by weight is dropped into again in reaction vessel, then stir, vacuumize, blowing, obtain component A;
B) B component is prepared: the solidifying agent 40-60 part taken by weight and softening agent 30-50 part are added successively in the reaction vessel with agitator and stir evenly, then in reaction vessel, add the emulsifying agent 05-1.5 part taken by weight continue to stir, the thixotropic agent 1-3 part taken by weight is added in the most backward reaction vessel, high speed dispersion stirs, discharging, obtains B component.
9. the preparation method of water-resisting type cloud stone glue according to claim 8, is characterized in that steps A) described in the churning time stirred be 10-20min, the time of described high-speed stirring is 10-15min, and the described time of then stirring is 15-30min; Step B) described in the time stirred evenly be 10-15min, the described time of continuing to stir is 5-10min, and the time that described high speed dispersion stirs is 10-15min.
10. a using method for water-resisting type cloud stone glue as claimed in claim 1, is characterized in that it is that component A 100: 1-3 is mixed rear use in mass ratio with B component.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510934550.5A CN105419710B (en) | 2015-12-15 | 2015-12-15 | Water-resistant type cloud stone glue and its preparation and application |
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| CN201510934550.5A CN105419710B (en) | 2015-12-15 | 2015-12-15 | Water-resistant type cloud stone glue and its preparation and application |
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| CN105419710A true CN105419710A (en) | 2016-03-23 |
| CN105419710B CN105419710B (en) | 2017-10-17 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107266104A (en) * | 2017-05-18 | 2017-10-20 | 刘冠辰 | A kind of gold copy trailing its repair handicraft repair member |
| CN107964383A (en) * | 2017-11-30 | 2018-04-27 | 安徽坤大化学锚固有限公司 | A kind of cold resisting type cloud stone glue for building and its processing technology |
| CN108841347A (en) * | 2018-07-03 | 2018-11-20 | 杨辉 | A kind of high temperature not increasing any stabilizer not sagging cloud stone glue |
| CN109852316A (en) * | 2018-12-28 | 2019-06-07 | 怀远县赛尔商贸有限公司 | A kind of high-intensitive, water-resistant type cloud stone glue |
| CN110003835A (en) * | 2019-04-22 | 2019-07-12 | 湖北坤能科技有限公司 | Anchor Agent and its preparation and application for railway maintenance |
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| CN101735759A (en) * | 2009-12-10 | 2010-06-16 | 江苏大力士投资有限公司 | High-performance marble glue and preparation method thereof |
| CN101974304A (en) * | 2010-11-08 | 2011-02-16 | 武汉理工大学 | Vinylester resin stone adhesive and preparation method thereof |
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- 2015-12-15 CN CN201510934550.5A patent/CN105419710B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735759A (en) * | 2009-12-10 | 2010-06-16 | 江苏大力士投资有限公司 | High-performance marble glue and preparation method thereof |
| CN101974304A (en) * | 2010-11-08 | 2011-02-16 | 武汉理工大学 | Vinylester resin stone adhesive and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107266104A (en) * | 2017-05-18 | 2017-10-20 | 刘冠辰 | A kind of gold copy trailing its repair handicraft repair member |
| CN107964383A (en) * | 2017-11-30 | 2018-04-27 | 安徽坤大化学锚固有限公司 | A kind of cold resisting type cloud stone glue for building and its processing technology |
| CN108841347A (en) * | 2018-07-03 | 2018-11-20 | 杨辉 | A kind of high temperature not increasing any stabilizer not sagging cloud stone glue |
| CN109852316A (en) * | 2018-12-28 | 2019-06-07 | 怀远县赛尔商贸有限公司 | A kind of high-intensitive, water-resistant type cloud stone glue |
| CN109852316B (en) * | 2018-12-28 | 2021-10-29 | 蚌埠赛尔时代工贸有限公司 | High-strength water-resistant marble adhesive |
| CN110003835A (en) * | 2019-04-22 | 2019-07-12 | 湖北坤能科技有限公司 | Anchor Agent and its preparation and application for railway maintenance |
| CN110003835B (en) * | 2019-04-22 | 2021-06-08 | 湖北坤能科技有限公司 | Anchoring agent for railway maintenance and preparation and application methods thereof |
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| Publication number | Publication date |
|---|---|
| CN105419710B (en) | 2017-10-17 |
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