CN105419295B - 一种耐化学应力耐刮擦pc/pmma合金材料及其制备方法 - Google Patents
一种耐化学应力耐刮擦pc/pmma合金材料及其制备方法 Download PDFInfo
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- CN105419295B CN105419295B CN201511015804.XA CN201511015804A CN105419295B CN 105419295 B CN105419295 B CN 105419295B CN 201511015804 A CN201511015804 A CN 201511015804A CN 105419295 B CN105419295 B CN 105419295B
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- 239000004926 polymethyl methacrylate Substances 0.000 title claims abstract description 79
- 229920003229 poly(methyl methacrylate) Polymers 0.000 title claims abstract description 78
- 239000000956 alloy Substances 0.000 title claims abstract description 36
- 230000003678 scratch resistant effect Effects 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000011347 resin Substances 0.000 claims abstract description 48
- 229920005989 resin Polymers 0.000 claims abstract description 48
- 238000005336 cracking Methods 0.000 claims abstract description 38
- 239000012745 toughening agent Substances 0.000 claims abstract description 38
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 32
- 230000002180 anti-stress Effects 0.000 claims abstract description 30
- 239000000314 lubricant Substances 0.000 claims abstract description 24
- 239000004970 Chain extender Substances 0.000 claims abstract description 22
- 230000002195 synergetic effect Effects 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 15
- 229940008099 dimethicone Drugs 0.000 claims abstract description 15
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 15
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 15
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 15
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 12
- 239000004417 polycarbonate Substances 0.000 claims description 62
- 239000000203 mixture Substances 0.000 claims description 14
- 239000004425 Makrolon Substances 0.000 claims description 10
- 229920000515 polycarbonate Polymers 0.000 claims description 10
- -1 SAG maleic anhydrides Chemical class 0.000 claims description 8
- TXQVDVNAKHFQPP-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO TXQVDVNAKHFQPP-UHFFFAOYSA-N 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 claims description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical class O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 7
- 239000000155 melt Substances 0.000 claims description 7
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical group CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims description 7
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 4
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 4
- 238000005453 pelletization Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 abstract description 7
- 238000005516 engineering process Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
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- 229910052799 carbon Inorganic materials 0.000 description 2
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- 230000035939 shock Effects 0.000 description 2
- 229920005479 Lucite® Polymers 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
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- 239000010775 animal oil Substances 0.000 description 1
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- 238000005660 chlorination reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
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- 239000003502 gasoline Substances 0.000 description 1
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- 230000001050 lubricating effect Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
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- 239000002904 solvent Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
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CN201511015804.XA CN105419295B (zh) | 2015-12-30 | 2015-12-30 | 一种耐化学应力耐刮擦pc/pmma合金材料及其制备方法 |
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CN201511015804.XA CN105419295B (zh) | 2015-12-30 | 2015-12-30 | 一种耐化学应力耐刮擦pc/pmma合金材料及其制备方法 |
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CN105419295A CN105419295A (zh) | 2016-03-23 |
CN105419295B true CN105419295B (zh) | 2017-10-03 |
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Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107629431B (zh) * | 2017-09-21 | 2020-06-16 | 中广核俊尔新材料有限公司 | 一种耐油耐热耐老化的无卤阻燃聚碳酸酯复合材料及其制备方法 |
CN107759998A (zh) * | 2017-11-22 | 2018-03-06 | 南通展鹏塑料有限公司 | 一种高性能聚碳酸酯复合材料 |
CN109438894A (zh) * | 2018-10-30 | 2019-03-08 | 佛山市合宏泰业科技有限公司 | 一种可视反应釜用pc/pmma合金材料 |
CN109852024A (zh) * | 2018-12-19 | 2019-06-07 | 宁波浙铁大风化工有限公司 | 一种新型发泡光扩散pc材料及其制备方法 |
CN110218433A (zh) * | 2019-06-24 | 2019-09-10 | 上海茗露新材料科技有限公司 | 一种仿玻璃高分子复合材料以及制备方法 |
CN111484720A (zh) * | 2019-12-20 | 2020-08-04 | 四川鑫达企业集团有限公司 | 一种耐汽车油漆高韧性pcabs合金材料及其制备方法 |
CN113248892A (zh) * | 2020-04-01 | 2021-08-13 | 东莞市金蚨新材料科技有限公司 | Pc/pmma合金材料的制造方法 |
CN111662528B (zh) * | 2020-07-13 | 2022-07-15 | 西南科技大学 | 一种基于pmma/pc的超薄复合光学膜及其制备方法、应用 |
CN113999513A (zh) * | 2021-11-24 | 2022-02-01 | 青岛国恩科技股份有限公司 | 一种led灯罩用pc/pmma合金材料及其制备方法 |
CN115449208A (zh) * | 2022-10-10 | 2022-12-09 | 安庆会通新材料有限公司 | 一种pc-pmma合金材料及其制备方法及应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102311624A (zh) * | 2010-09-30 | 2012-01-11 | 深圳市科聚新材料有限公司 | 一种耐刮擦聚碳酸酯手机料及其制备方法 |
CN102532853A (zh) * | 2012-01-09 | 2012-07-04 | 东莞劲胜精密组件股份有限公司 | 一种高硬度抗划伤改性pc材料及其制备方法 |
CN103351587A (zh) * | 2013-05-30 | 2013-10-16 | 惠州市昌亿科技股份有限公司 | 一种耐寒抗腐蚀pc/abs合金及其制备方法和应用 |
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2015
- 2015-12-30 CN CN201511015804.XA patent/CN105419295B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102311624A (zh) * | 2010-09-30 | 2012-01-11 | 深圳市科聚新材料有限公司 | 一种耐刮擦聚碳酸酯手机料及其制备方法 |
CN102532853A (zh) * | 2012-01-09 | 2012-07-04 | 东莞劲胜精密组件股份有限公司 | 一种高硬度抗划伤改性pc材料及其制备方法 |
CN103351587A (zh) * | 2013-05-30 | 2013-10-16 | 惠州市昌亿科技股份有限公司 | 一种耐寒抗腐蚀pc/abs合金及其制备方法和应用 |
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Denomination of invention: A kind of chemical stress and scratch resistant PC / PMMA alloy material and its preparation method Effective date of registration: 20200930 Granted publication date: 20171003 Pledgee: China Co. truction Bank Corp Dongguan branch Pledgor: GUANGDONG GUOLI SCIENCE AND TECHNOLOGY Co.,Ltd. Registration number: Y2020980006664 |
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Address after: 523000 No. 1, Nange West Road, Daojiao Town, Dongguan City, Guangdong Province Patentee after: GUANGDONG GUOLI SCIENCE AND TECHNOLOGY CO.,LTD. Address before: 523170 No.8, 5 Rd, daluosha Pioneer Park, Daojiao Town, Dongguan City, Guangdong Province Patentee before: GUANGDONG GUOLI SCIENCE AND TECHNOLOGY CO.,LTD. |
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Date of cancellation: 20221201 Granted publication date: 20171003 Pledgee: China Co. truction Bank Corp Dongguan branch Pledgor: GUANGDONG GUOLI SCIENCE AND TECHNOLOGY CO.,LTD. Registration number: Y2020980006664 |
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Address after: 523000 No. 1, Nange West Road, Daojiao Town, Dongguan City, Guangdong Province Patentee after: Guangdong Quanwei Technology Co.,Ltd. Address before: 523000 No. 1, Nange West Road, Daojiao Town, Dongguan City, Guangdong Province Patentee before: GUANGDONG GUOLI SCIENCE AND TECHNOLOGY CO.,LTD. |
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Effective date of registration: 20230724 Address after: 523000 No. 1, Nange West Road, Daojiao Town, Dongguan City, Guangdong Province Patentee after: Dongguan National Polymer Materials Co.,Ltd. Address before: 523000 No. 1, Nange West Road, Daojiao Town, Dongguan City, Guangdong Province Patentee before: Guangdong Quanwei Technology Co.,Ltd. |