CN105419228A - New artware material and preparation method thereof - Google Patents
New artware material and preparation method thereof Download PDFInfo
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- CN105419228A CN105419228A CN201610016525.3A CN201610016525A CN105419228A CN 105419228 A CN105419228 A CN 105419228A CN 201610016525 A CN201610016525 A CN 201610016525A CN 105419228 A CN105419228 A CN 105419228A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/32—Modified amine-aldehyde condensates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/40—Chemically modified polycondensates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to the technical field of chemical materials, in particular to a new artware material. The new artware material is prepared from, by mass, 45-60% of paper pulp, 15-30% of urea, 5-15% of formaldehyde, 10-20% of a solvent, 0.1-5% of toner and 0.5-5% of auxiliaries. The new artware material can be easily processed to form artware, the quality of plastic artware manufactured through the new artware material is high, the plastic artware manufactured through the new artware material has the gloss of jade or marble or the like, the quality of the plastic artware manufactured through the new artware material is nearly equal to that of artware manufactured through jade or marble or other similar materials, customers cannot perceive that the artware is manufactured from plastics, the additional value of the artware is high, ornamental value is high, manufacturing cost is low, the grade of the artware is improved, and economic benefits are good.
Description
Technical field
The present invention relates to chemical material technical field, particularly relate to a kind of artwork novel material and preparation method thereof.
Background technology
The existing material for the manufacture of plastic crafts is general-purpose plastics, utilize this general-purpose plastics produced artwork quality common, there is normal plastics gloss, human consumer knows it is common plastics artwork at a glance, thus cause the added value of artwork low, sight is poor, reduces the class of artwork, deficiency in economic performance.
Thus, a kind of artwork novel material that can improve plastic crafts class is needed in the market badly.
Summary of the invention
The present invention provides a kind of artwork novel material and preparation method thereof for overcoming above-mentioned defect, this artwork novel material is easy to processing and forming technology product, utilize this artwork novel material produced plastic crafts quality high-end, there is the gloss of jade or marble and so on, the artwork quality manufactured with jade or marble and so on material is suitable, human consumer is difficult to discover this artwork and is formed by plastics manufacture, the added value of artwork is high, sight is good, low cost of manufacture, improve the class of artwork, good in economic efficiency; Preparation method's technique of this artwork novel material is simple, and production efficiency is high, and conforming product rate is high, is suitable for large-scale promotion application.
For achieving the above object, the present invention adopts following technical scheme.
A kind of artwork novel material, comprises the raw material of following mass percent:
Preferably, a kind of artwork novel material, comprises the raw material of following mass percent:
Preferably, a kind of artwork novel material, comprises the raw material of following mass percent:
Wherein, described paper pulp is one or more mixture of wood pulp, straw pulp, jute pulp, reed pulp, sugarcane slurry, bamboo pulp, rag stock.
Wherein, described solvent is one or more mixture of water, ethanol, ether, acetone, glycerine.
Wherein, described toner by nano level toner and regular grade toner by 1 ~ 3: 2 ~ 5 mass ratio mix, the particle diameter of described regular grade toner is 50 ~ 100 microns.Utilize little quality and the high surface energy of nano level toner, make nano level toner be attached to regular grade toner surface, formed core the composite structure of shell.In the process of mix and blend, moving together along with regular grade toner in the surface that nano level toner is attached to regular grade toner, effectively prevent the agglomeration of nano level toner; In addition because nano level toner has high surface energy, it is combined tightr with the mixture of other material, therefore regular grade toner can be combined with the mixture of other material by the nano level toner being attached to its surface, finally makes toner can adhere to particulate material outside surface uniformly and stably; The nano level toner not being attached to regular grade toner surface will be filled into the various gaps of the mixture of other material, show the various advantages of nano material, overcome and be used alone the shortcoming that nano level toner and regular grade toner fill other material gap, keep good physical mechanical property.
Wherein, described auxiliary agent comprises solidifying agent, flow agent, brightening agent, oxidation inhibitor and tackiness agent.
Wherein, the consumption of described solidifying agent is 0.1 ~ 1% of total raw material quality, the consumption of described flow agent is 0.1 ~ 1% of total raw material quality, the consumption of described brightening agent is 0.1 ~ 1% of total raw material quality, the consumption of described oxidation inhibitor is 0.1 ~ 1% of total raw material quality, and the consumption of described tackiness agent is 0.1 ~ 1% of total raw material quality.
Wherein, described solidifying agent is one or more mixture of vinyl triamine, diamino-cyclohexane, trimethylhexane diamine, mphenylenediamine, diaminodiphenyl-methane, p-diaminodiphenyl;
Wherein, described flow agent is one or more mixture of silicone oil, polydimethylsiloxane, polyether polyester modified organic silicon oxygen alkane, acrylic resin, urea-formaldehyde resin, terpolycyantoamino-formaldehyde resin;
Wherein, described brightening agent is one or more mixture of benzylideneacetone, polyoxyethylene nonylphenol ether, Sodium Benzoate;
Wherein, described oxidation inhibitor is one or more mixture of pentanoic, 2,6-tri-grades of butyl-4-methylphenols, thio-2 acid dibasic acid esters;
Wherein, described tackiness agent is one or more mixture of starch, water glass, urethane, isoprene-isobutylene rubber, acrylic resin, epoxy resin.
A preparation method for artwork novel material, comprises following procedure of processing:
Steps A, accurately take the material of formula ratio according to formula, be placed in different containers respectively;
Step B, solvent is added reactor, paper pulp and urea, to 70 ~ 80 DEG C, are then added reactor by heated solvent, and limit edged stirs, and makes paper pulp and urea be dissolved in solvent;
Step C, the temperature in reactor is brought up to 190 ~ 210 DEG C, formaldehyde is joined reactor, limit edged stirs, and after adding formaldehyde, keeps whipped state, continues reaction 3 ~ 5 minutes, obtain mixed serum;
Step D, mixed serum is added granulator granulation, obtain particulate material;
Step e, mixer is set hopper in temperature be 40 ~ 50 DEG C, toner is joined together with auxiliary agent hopper to stir 2 ~ 4 minutes, form toner agent mixture, again particulate material is joined in hopper and continue stirring 3 ~ 5 minutes, make toner agent mixture be evenly distributed to particulate material outside surface, then carry out drying to particulate material, drying temperature is 60 ~ 70 DEG C, time of drying is 2 ~ 3 minutes, gets product.
Beneficial effect of the present invention is:
A kind of artwork novel material of the present invention, comprises the raw material of following mass percent: paper pulp 45 ~ 60%, urea 15 ~ 30%, formaldehyde 5 ~ 15%, solvent 10 ~ 20%, toner 0.1 ~ 5%, auxiliary agent 0.5 ~ 5%; This artwork novel material is easy to processing and forming technology product, utilize this artwork novel material produced plastic crafts quality high-end, there is the gloss of jade or marble and so on, the artwork quality manufactured with jade or marble and so on material is suitable, and human consumer is difficult to discover this artwork and is formed by plastics manufacture, and the added value of artwork is high, sight is good, low cost of manufacture, improves the class of artwork, good in economic efficiency; Why the artwork utilizing this novel material to mold forms the characteristic being similar to jade or marble material is because the inside of novel material own is pure white particulate material, particulate material outside surface uniform fold has toner, in shaping process, particulate material is crushed, inner white particle material exposes, the artwork formed out finally is made to occur the special decorative pattern that certain colour (as green) is alternate with white, with jade or marble similarity high, therefore make the artwork formed out similarly be formed by jade or marble manufacture.In addition, also because adopt above-mentioned formula for raw stock, make this artwork have the gloss being similar to stone, finally make the artwork utilizing this novel material to form out have jade or marble appearance.
A preparation method for artwork novel material, comprises following procedure of processing: steps A, accurately take the material of formula ratio according to formula, is placed in different containers respectively; Step B, solvent is added reactor, paper pulp and urea, to 70 ~ 80 DEG C, are then added reactor by heated solvent, and limit edged stirs, and makes paper pulp and urea be dissolved in solvent; Step C, the temperature in reactor is brought up to 190 ~ 210 DEG C, formaldehyde is joined reactor, limit edged stirs, and after adding formaldehyde, keeps whipped state, continues reaction 3 ~ 5 minutes, obtain mixed serum; Step D, mixed serum is added granulator granulation, obtain particulate material; Step e, mixer is set hopper in temperature be 40 ~ 50 DEG C, toner is joined together with auxiliary agent hopper to stir 2 ~ 4 minutes, form toner agent mixture, again particulate material is joined in hopper and continue stirring 3 ~ 5 minutes, make toner agent mixture be evenly distributed to particulate material outside surface, then carry out drying to particulate material, drying temperature is 60 ~ 70 DEG C, time of drying is 2 ~ 3 minutes, gets product; Preparation method's technique of this artwork novel material is simple, and production efficiency is high, and conforming product rate is high, is suitable for large-scale promotion application.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated, and this is preferred embodiment of the present invention.
Embodiment 1.
A kind of artwork novel material of the present invention, comprises the raw material of following mass percent:
The paper pulp of the present embodiment is wood pulp.
The solvent of the present embodiment is ethanol.
The toner of the present embodiment by nano level toner and regular grade toner by 1: 2 mass ratio mix, the particle diameter of described regular grade toner is 100 microns.
The auxiliary agent of the present embodiment comprises solidifying agent, flow agent, brightening agent, oxidation inhibitor and tackiness agent.
The consumption of the solidifying agent of the present embodiment is 1% of total raw material quality, the consumption of described flow agent is 1% of total raw material quality, the consumption of described brightening agent is 1% of total raw material quality, and the consumption of described oxidation inhibitor is 1% of total raw material quality, and the consumption of described tackiness agent is 1% of total raw material quality.
The solidifying agent of the present embodiment is vinyl triamine;
The flow agent of the present embodiment is silicone oil;
The brightening agent of the present embodiment is benzylideneacetone;
The oxidation inhibitor of the present embodiment is pentanoic;
The tackiness agent of the present embodiment is acrylic resin.
A preparation method for artwork novel material, comprises following procedure of processing:
Steps A, accurately take the material of formula ratio according to formula, be placed in different containers respectively;
Step B, solvent is added reactor, paper pulp and urea, to 75 DEG C, are then added reactor by heated solvent, and limit edged stirs, and makes paper pulp and urea be dissolved in solvent;
Step C, the temperature in reactor is brought up to 200 DEG C, formaldehyde is joined reactor, limit edged stirs, and after adding formaldehyde, keeps whipped state, continues reaction 4 minutes, obtain mixed serum;
Step D, mixed serum is added granulator granulation, obtain particulate material;
Step e, mixer is set hopper in temperature be 45 DEG C, toner is joined together with auxiliary agent hopper and stir 3 minutes, form toner agent mixture, again particulate material is joined in hopper and continue stirring 4 minutes, make toner agent mixture be evenly distributed to particulate material outside surface, then carry out drying to particulate material, drying temperature is 65 DEG C, time of drying is 3 minutes, gets product.
Embodiment 2.
A kind of artwork novel material of the present invention, comprises the raw material of following mass percent:
The paper pulp of the present embodiment is the mixture of wood pulp, straw pulp, bamboo pulp.
The solvent of the present embodiment is the mixture of ethanol, glycerine.
The toner of the present embodiment by nano level toner and regular grade toner by 3: 2 mass ratio mix, the particle diameter of described regular grade toner is 50 microns.
The auxiliary agent of the present embodiment comprises solidifying agent, flow agent, brightening agent, oxidation inhibitor and tackiness agent.
The consumption of the solidifying agent of the present embodiment is 0.5% of total raw material quality, the consumption of described flow agent is 0.5% of total raw material quality, the consumption of described brightening agent is 0.5% of total raw material quality, the consumption of described oxidation inhibitor is 0.5% of total raw material quality, and the consumption of described tackiness agent is 0.5% of total raw material quality.
The solidifying agent of the present embodiment is the mixture of diamino-cyclohexane, mphenylenediamine;
The flow agent of the present embodiment is the mixture of polydimethylsiloxane, acrylic resin;
The brightening agent of the present embodiment is the mixture of benzylideneacetone, polyoxyethylene nonylphenol ether, Sodium Benzoate;
The oxidation inhibitor of the present embodiment is the mixture of pentanoic, thio-2 acid dibasic acid esters;
The tackiness agent of the present embodiment is the mixture of starch, water glass.
A preparation method for artwork novel material, comprises following procedure of processing:
Steps A, accurately take the material of formula ratio according to formula, be placed in different containers respectively;
Step B, solvent is added reactor, paper pulp and urea, to 70 DEG C, are then added reactor by heated solvent, and limit edged stirs, and makes paper pulp and urea be dissolved in solvent;
Step C, the temperature in reactor is brought up to 190 DEG C, formaldehyde is joined reactor, limit edged stirs, and after adding formaldehyde, keeps whipped state, continues reaction 5 minutes, obtain mixed serum;
Step D, mixed serum is added granulator granulation, obtain particulate material;
Step e, mixer is set hopper in temperature be 40 DEG C, toner is joined together with auxiliary agent hopper and stir 4 minutes, form toner agent mixture, again particulate material is joined in hopper and continue stirring 5 minutes, make toner agent mixture be evenly distributed to particulate material outside surface, then carry out drying to particulate material, drying temperature is 60 DEG C, time of drying is 3 minutes, gets product.
Embodiment 3.
A kind of artwork novel material of the present invention, comprises the raw material of following mass percent:
The paper pulp of the present embodiment is the mixture of jute pulp, sugarcane slurry, rag stock.
The solvent of the present embodiment is the mixture of water, ether, glycerine.
The toner of the present embodiment by nano level toner and regular grade toner by 1: 1 mass ratio mix, the particle diameter of described regular grade toner is 50 microns.
The auxiliary agent of the present embodiment comprises solidifying agent, flow agent, brightening agent, oxidation inhibitor and tackiness agent.
The consumption of the solidifying agent of the present embodiment is 1% of total raw material quality, the consumption of described flow agent is 0.5% of total raw material quality, the consumption of described brightening agent is 1% of total raw material quality, the consumption of described oxidation inhibitor is 0.5% of total raw material quality, and the consumption of described tackiness agent is 1% of total raw material quality.
The solidifying agent of the present embodiment is the mixture of mphenylenediamine, diaminodiphenyl-methane, p-diaminodiphenyl;
The flow agent of the present embodiment is the mixture of silicone oil, polydimethylsiloxane, acrylic resin;
The brightening agent of the present embodiment is the mixture of polyoxyethylene nonylphenol ether, Sodium Benzoate;
The oxidation inhibitor of the present embodiment is the mixture of pentanoic, 2,6-tri-grades of butyl-4-methylphenols, thio-2 acid dibasic acid esters;
The tackiness agent of the present embodiment is the mixture of urethane, isoprene-isobutylene rubber, epoxy resin.
A preparation method for artwork novel material, comprises following procedure of processing:
Steps A, accurately take the material of formula ratio according to formula, be placed in different containers respectively;
Step B, solvent is added reactor, paper pulp and urea, to 80 DEG C, are then added reactor by heated solvent, and limit edged stirs, and makes paper pulp and urea be dissolved in solvent;
Step C, the temperature in reactor is brought up to 210 DEG C, formaldehyde is joined reactor, limit edged stirs, and after adding formaldehyde, keeps whipped state, continues reaction 3 minutes, obtain mixed serum;
Step D, mixed serum is added granulator granulation, obtain particulate material;
Step e, mixer is set hopper in temperature be 50 DEG C, toner is joined together with auxiliary agent hopper and stir 2 minutes, form toner agent mixture, again particulate material is joined in hopper and continue stirring 3 minutes, make toner agent mixture be evenly distributed to particulate material outside surface, then carry out drying to particulate material, drying temperature is 70 DEG C, time of drying is 2 minutes, gets product.
Finally should be noted that; above embodiment is only in order to illustrate technical scheme of the present invention; but not limiting the scope of the invention; although done to explain to the present invention with reference to preferred embodiment; those of ordinary skill in the art is to be understood that; can modify to technical scheme of the present invention or equivalent replacement, and not depart from essence and the scope of technical solution of the present invention.
Claims (10)
1. an artwork novel material, is characterized in that: the raw material comprising following mass percent:
2. a kind of artwork novel material according to claim 1, is characterized in that: the raw material comprising following mass percent:
3. a kind of artwork novel material according to claim 1, is characterized in that: the raw material comprising following mass percent:
4. a kind of artwork novel material according to claim 1, is characterized in that: described paper pulp is one or more mixture of wood pulp, straw pulp, jute pulp, reed pulp, sugarcane slurry, bamboo pulp, rag stock.
5. a kind of artwork novel material according to claim 1, is characterized in that: described solvent is one or more mixture of water, ethanol, ether, acetone, glycerine.
6. a kind of artwork novel material according to claim 1, is characterized in that: described toner by nano level toner and regular grade toner by 1 ~ 3: 2 ~ 5 mass ratio mix, the particle diameter of described regular grade toner is 50 ~ 100 microns.
7. a kind of artwork novel material according to claim 1, is characterized in that: described auxiliary agent comprises solidifying agent, flow agent, brightening agent, oxidation inhibitor and tackiness agent.
8. a kind of artwork novel material according to claim 7, it is characterized in that: the consumption of described solidifying agent is 0.1 ~ 1% of total raw material quality, the consumption of described flow agent is 0.1 ~ 1% of total raw material quality, the consumption of described brightening agent is 0.1 ~ 1% of total raw material quality, the consumption of described oxidation inhibitor is 0.1 ~ 1% of total raw material quality, and the consumption of described tackiness agent is 0.1 ~ 1% of total raw material quality.
9. a kind of artwork novel material according to claim 7, is characterized in that:
Described solidifying agent is one or more mixture of vinyl triamine, diamino-cyclohexane, trimethylammonium diamines, mphenylenediamine, diaminodiphenyl-methane, p-diaminodiphenyl;
Described flow agent is one or more mixture of silicone oil, polydimethylsiloxane, polyether polyester modified organic silicon oxygen alkane, acrylic resin, urea-formaldehyde resin, terpolycyantoamino-formaldehyde resin;
Described brightening agent is one or more mixture of benzylideneacetone, polyoxyethylene nonylphenol ether, Sodium Benzoate;
Described oxidation inhibitor is one or more mixture of pentanoic, 2,6-tri-grades of butyl-4-methylphenols, thio-2 acid dibasic acid esters;
Described tackiness agent is one or more mixture of starch, water glass, urethane, isoprene-isobutylene rubber, acrylic resin, epoxy resin.
10. the preparation method of a kind of artwork novel material as described in claim 1-9 any one, is characterized in that: comprise following procedure of processing:
Steps A, accurately take the material of formula ratio according to formula, be placed in different containers respectively;
Step B, solvent is added reactor, paper pulp and urea, to 70 ~ 80 DEG C, are then added reactor by heated solvent, and limit edged stirs, and makes paper pulp and urea be dissolved in solvent;
Step C, the temperature in reactor is brought up to 190 ~ 210 DEG C, formaldehyde is joined reactor, limit edged stirs, and after adding formaldehyde, keeps whipped state, continues reaction 3 ~ 5 minutes, obtain mixed serum;
Step D, mixed serum is added granulator granulation, obtain particulate material;
Step e, mixer is set hopper in temperature be 40 ~ 50 DEG C, toner is joined together with auxiliary agent hopper to stir 2 ~ 4 minutes, form toner agent mixture, again particulate material is joined in hopper and continue stirring 3 ~ 5 minutes, make toner agent mixture be evenly distributed to particulate material outside surface, then carry out drying to particulate material, drying temperature is 60 ~ 70 DEG C, time of drying is 2 ~ 3 minutes, gets product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610016525.3A CN105419228B (en) | 2016-01-08 | 2016-01-08 | A kind of craftwork new material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610016525.3A CN105419228B (en) | 2016-01-08 | 2016-01-08 | A kind of craftwork new material and preparation method thereof |
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| Publication Number | Publication Date |
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| CN105419228A true CN105419228A (en) | 2016-03-23 |
| CN105419228B CN105419228B (en) | 2018-06-19 |
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| CN201610016525.3A Expired - Fee Related CN105419228B (en) | 2016-01-08 | 2016-01-08 | A kind of craftwork new material and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110482906A (en) * | 2019-07-16 | 2019-11-22 | 书香门地（上海）美学家居股份有限公司 | A kind of craftwork wood raw material with high-intensitive plasticity |
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| CN1647948A (en) * | 2005-01-01 | 2005-08-03 | 王志深 | Pulp handicraft and its producing method |
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| CN104419116A (en) * | 2013-09-02 | 2015-03-18 | 陈天云 | Environment-friendly amino molding granule and production method thereof |
| CN104761866A (en) * | 2014-01-04 | 2015-07-08 | 陈天云 | Method for rapidly producing amino molded material |
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- 2016-01-08 CN CN201610016525.3A patent/CN105419228B/en not_active Expired - Fee Related
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| CN1647948A (en) * | 2005-01-01 | 2005-08-03 | 王志深 | Pulp handicraft and its producing method |
| CN1686721A (en) * | 2005-06-03 | 2005-10-26 | 潮州市三泰陶瓷有限公司 | Manufacturing method of pottary imitation paper bandicraft article |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110482906A (en) * | 2019-07-16 | 2019-11-22 | 书香门地（上海）美学家居股份有限公司 | A kind of craftwork wood raw material with high-intensitive plasticity |
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| CN105419228B (en) | 2018-06-19 |
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