CN105415215B - A kind of super hard abrasive ordered arrangement method - Google Patents

A kind of super hard abrasive ordered arrangement method Download PDF

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Publication number
CN105415215B
CN105415215B CN201510750409.XA CN201510750409A CN105415215B CN 105415215 B CN105415215 B CN 105415215B CN 201510750409 A CN201510750409 A CN 201510750409A CN 105415215 B CN105415215 B CN 105415215B
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water
super hard
ordered arrangement
hard abrasive
arrangement method
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CN105415215A (en
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马宁
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Funik Ultrahard Material Co Ltd
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Funik Ultrahard Material Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
    • B24D18/0054Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for by impressing abrasive powder in a matrix

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Abstract

The invention discloses a kind of super hard abrasive ordered arrangement method, belong to superhard material process field, comprise the following steps:((1)Pressure sensitive adhesive is laid in metal base surface;(2)The uniform sequential water-soluble film that through hole is distributed with of layer of surface is bonded on pressure sensitive adhesive;(3)After pressure sensitive adhesive enters the through hole of water-soluble film, superabrasive particles are dispensed in film surface, then baking and curing so that abrasive grain fully consolidates;(4)By step(3)In obtained semi-finished product consolidated be placed in water, water-soluble film is fully dissolved and dried.This super hard abrasive ordered arrangement method provided by the invention makes template using water-soluble material, allows template automatic hydrolysis, will not destroy putting in order for super hard abrasive.

Description

A kind of super hard abrasive ordered arrangement method
Technical field
The invention belongs to superhard material process field, and in particular to a kind of super hard abrasive ordered arrangement method.
Background technology
Super hard abrasive instrument is used for shaping cutting, the polishing of the materials such as hard brittle material, sheet metal, its machining accuracy High, efficiency high, application prospect is wide, is a kind of huge instrument of market potential.But consolidation super hard abrasive instrument its cuts main body To be arranged in the super hard abrasive of tool surfaces, the species of super hard abrasive, granularity, crystal formation and its in the arrangement side on tool base surface Formula determines the processing characteristics of instrument.
Super hard abrasive and metallic bond are mixed mostly in existing abrasive material sort method, load in mould Row base and sintering.But there is problems with the technique:(1)Mechanical batch mixing can not ensure that abrasive material mixes in metallic bond Close uniformly, cause subregion abrasive concentration high, subregion abrasive concentration is low, or even some regions do not have abrasive material distribution;(2) Because of abrasive material skewness, saw blade cutting efficiency declines, and the high region Cutting Drag of abrasive concentration is big, and chip easily blocks, cutting Efficiency is low;In abrasive material thinning area, abrasive material can not effectively be cut, and suffered impulsive force is big, and abrasive material is easily broken and comes off;In nothing The region of abrasive material, bonding agent quick abrasion, Cutting Drag are big;(3)Because Cutting Drag is big, cutting temperature is high, and bonding agent is easy with abrasive material Burn.
Diamond order arrangement is applied to saw blade tip by Chinese emery wheel company doctor Song Jianmin in China Taiwan first, its The patented technology (U.S.Patent6039641) of proposition is to implement the ordered arrangement of diamond abrasive with template.The of the method One step, carcass powder is well mixed, and plus the mixture of appropriate organic binder bond and solvent, makes " dough ", Ran Houtong The method for crossing rolling does straticulation;Second step, the template with through hole, hole are made by the particle diameter and arrangement mode of diamond abrasive Footpath is more than single diamond particle diameter, less than two diamond abrasive particle diameters and, it is ensured that single diamond enters in pattern hole, template Thickness is the 1/3-2/3 of diamond average grain diameter;3rd step, diamond is distributed in template through hole;4th step, removes template, Diamond in hole falls on the surface of thin layer, forms ordered arrangement array, and unnecessary diamond is removed together in company with template;5th Step, diamond is pressed into carcass thin layer with plain plate.The technique can accurate ordered arrangement diamond abrasive, but exist following Shortcoming:(1)Per procedure manual operation, waste time and energy, efficiency is low;(2)Emery wheel company is to allow single diamond particles to enter mould Plate, different templates so need to be done for the diamond of variable grain, it is relatively elaborate;(3)Can upset during removing template has The diamond of sequence arrangement.
Because the grinding material sequential arraying technical research time is not grown, existing diamond grinding material sequential arraying technique is clearly present Deficiency, it is mainly manifested in low production efficiency, precision is low for arrangement, equipment is expensive etc..
The content of the invention
It is an object of the invention to provide efficient, accurate, cost-effective super hard abrasive ordered arrangement method.
Based on above-mentioned purpose, the present invention uses following technical scheme:A kind of super hard abrasive ordered arrangement method, including it is following Step:
(1)Pressure sensitive adhesive is laid in metal base surface;
(2)The uniform sequential water-soluble film that through hole is distributed with of layer of surface is bonded on pressure sensitive adhesive;
(3)After pressure sensitive adhesive enters the through hole of water-soluble film, superabrasive particles are dispensed in film surface, are then dried Solidification so that abrasive grain fully consolidates;
(4)By step(3)In obtained semi-finished product consolidated be placed in water, water-soluble film is fully dissolved and dried It is dry.
Preferably, described water-soluble film is polyvinyl alcohol film, polyethylene oxide thin film, water-soluble cellulose film Or water soluble starch class film.
Further, the aperture of through hole is 10-300 mesh, pitch of holes 0.02-10mm.
Further, the thickness of pressure sensitive adhesive and water-soluble film is 0.1-1mm.
Further, the surface of semi-finished after baking and curing is not swept into backwardness by cohesive abrasive grain, then sample is put Yu Shuizhong.
Further, before the pressure sensitive adhesive of metal base surface laying, first metal base surface is put into alcohol ultrasonic Cleaning.
Further, the metal base surface is plane or curved surface.
Further, described super hard abrasive be diamond, electroplated diamond, cubic boron nitride, electroplating cubic boron nitride, One or more in polycrystalline cubic boron nitride and hard alloy crushed particles.
Further, step(3)60 ~ 80 DEG C of the temperature of middle baking and curing, time are 0.5 ~ 1h.
Further, step(4)Middle water temperature is 20 ~ 80 DEG C, and drying temperature is 100 ~ 150 DEG C.
Compared with prior art, super hard abrasive ordered arrangement method provided by the invention has advantages below:
(1)This method is efficient, accurate, saving cost, is easy to industrialization promotion;
(2)The pressure sensitive adhesive allowed in this method on matrix is oozed out by the hole on water-soluble film, forms " the glue of ordered arrangement Point ", each glue point can bond super hard abrasive, not influenceed by what abrasive grain type and granular size were influenceed, versatile;
(3)This method makes template using water-soluble material, allows template automatic hydrolysis, will not destroy the arrangement of super hard abrasive Sequentially;
(4)Water-soluble material that this method utilizes makes template, is fexible film, and matrix can be plane or curved surface, Its ordered arrangement effect is not influenceed.
Brief description of the drawings
Fig. 1 is the schematic flow sheet of the present invention;
Fig. 2 is the photo for the bowl-type grinding disc prepared using the method for embodiment 1.
Embodiment
With reference to embodiment, the present invention is described in detail.
Embodiment 1
A kind of super hard abrasive ordered arrangement method, as shown in figure 1, comprising the following steps:
(1)The a diameter of 10cm manganese steel matrix of bowl-type 65 is taken, matrix is put into 5% ~ 15% alcoholic solution, uses ultrasonic wave Cleaning 3 ~ 5 minutes, be placed in ventilation dry it is standby;The diamond particles of 30-40 mesh are chosen, it is clear to be placed in ultrasonic wave in acetone soln Wash, remove the impurity such as dust and the grease of diamond surface attachment;On the surface of bowl grinding bound abrasive grains, pressure sensitive adhesive, glue are smeared Body thickness is 0.5 ~ 1mm;
(2)The square polyvinyl alcohol film for taking a length of side to be more than 10cm, is carried out at punching on laser-beam drilling machine Reason, the hole of a diameter of 20 mesh is made a call to every 1mm(Pitch of holes can be selected according to the size of superabrasive particles, with particle Between be independent of each other and be advisable);By the matrix surface of porous polyvinyl alcohol film paving after treatment, and press cause pressure sensitive adhesive from Through hole oozes out;
(3)Diamond particles are trickled down into step naturally(2)After the surface of semi-finished of gained, semi-finished product are placed in 60 DEG C of baking 0.5h in case so that pressure-sensitive adhesive curing, diamond particles are fixedly arranged on pressure sensitive adhesive;Using banister brush by not by cohesive abrasive material Particle gently is swept;
(4)The semi-finished product being cured are put into 60 DEG C of water, hydrolyze polyvinyl alcohol film, after its complete hydrolysis (About 5min), taken out from water, drying finished product 1 at 100-150 DEG C.
By one layer of powdered filler metal of the uniform arrangement in the surface of finished product 1, it is then placed in vacuum or controlled atmosphere furnace, is heated to solder Melt, diamond abrasive is fixedly secured in 65 manganese steel matrix surfaces by soldering bonding agent after cooling, forms bowl-type grinding disc, such as Shown in Fig. 2, the abrasive material on grinding disc surface is evenly distributed, and no abrasive material aggregation and the sparse situation of abrasive material occur.
Embodiment 2
A kind of super hard abrasive ordered arrangement method, comprises the following steps:
(1)The a diameter of 8cm manganese steel matrix of circle 65 is taken, matrix is put into 5% ~ 15% alcoholic solution, uses ultrasonic wave Cleaning 3 ~ 5 minutes, be placed in ventilation dry it is standby;Choose the CBN of 50-60 mesh(Cubic boron nitride)The diamond particles of particle, It is placed in ultrasonic wave in acetone soln to clean, removes the impurity such as dust and the grease of the attachment of CBN particle surfaces;Bonded in circle grinding The surface of abrasive particle, pressure sensitive adhesive is smeared, colloid thickness is 0.4 ~ 0.8mm;
(2)The square polyvinyl alcohol film for taking a length of side to be more than 8cm, the thickness and pressure sensitive adhesive of polyvinyl alcohol film Consistency of thickness, punching processing is carried out on laser-beam drilling machine, the hole of a diameter of 40 mesh is made a call to every 0.8mm(Pitch of holes can Selected according to the size of superabrasive particles, being independent of each other between particle is advisable);The porous polyvinyl alcohol film is spread Matrix surface after processing, and press and pressure sensitive adhesive is oozed out from through hole;
(3)CBN particles are trickled down into step naturally(2)After the surface of semi-finished of gained, semi-finished product are placed in 70 DEG C of baking oven Middle 0.5h so that pressure-sensitive adhesive curing, by CBN Particle consolidations on pressure sensitive adhesive;Will be light not by cohesive CBN particles using banister brush Gently sweep;
(4)The semi-finished product being cured are put into 50 DEG C of water, hydrolyze polyvinyl alcohol film, after its complete hydrolysis (About 7min), semi-finished product are taken out, drying finished product 2 at 100-150 DEG C.
By one layer of powdered filler metal of the uniform arrangement in the surface of finished product 2, it is then placed in vacuum or controlled atmosphere furnace, is heated to solder Melt, CBN abrasive grains are fixedly secured in 65 manganese steel matrix surfaces by soldering bonding agent after cooling, form round grinding disc.
Embodiment 3
A kind of super hard abrasive ordered arrangement method, comprises the following steps:
(1)It is 18cm to take external diameter, and internal diameter 3.2cm, width is 2cm grinding wheel base body, and basic material is 45 steel, by matrix Be put into 5% ~ 15% alcoholic solution, cleaned 3 ~ 5 minutes with ultrasonic wave, be placed in ventilation dry it is standby;Choose 20-30 purposes CBN(Cubic boron nitride)Grains, be placed in acetone soln ultrasonic wave and clean, remove the dust of CBN particle surfaces attachment with The impurity such as grease;Cylindrical bound abrasive grains are turned round in grinding wheel base body, smear pressure sensitive adhesive, colloid thickness is 0.6 ~ 1mm;
(2)Take 4 length of sides be more than 5cm square polyethylene oxide thin film, the thickness of polyethylene oxide thin film with it is pressure-sensitive The consistency of thickness of glue, punching processing is carried out on laser-beam drilling machine, the hole of a diameter of 10 mesh is made a call to every 2mm(Pitch of holes can Selected according to the size of superabrasive particles, being independent of each other between particle is advisable);The porous polyethylene alcohol film is layered on Matrix surface after treated, and press and pressure sensitive adhesive is oozed out from through hole, because matrix is circular turned part, when sprawling Using 4 films, base circumferential is all covered;
(3)CBN particles are trickled down into step naturally(2)After the surface of semi-finished of gained, semi-finished product are placed in 80 DEG C of baking oven Middle 0.5h so that pressure-sensitive adhesive curing, by CBN Particle consolidations on pressure sensitive adhesive;Will be light not by cohesive CBN particles using banister brush Gently sweep;
(4)The semi-finished product being cured are put into 70 DEG C of water, hydrolyze polyethylene oxide thin film, after its complete hydrolysis (About 5min), semi-finished product are taken out, drying finished product 3 at 100-150 DEG C.
By one layer of powdered filler metal of the uniform arrangement in the surface of finished product 3, it is then placed in vacuum or controlled atmosphere furnace, is heated to solder Melt, CBN abrasive grains are fixedly secured on 45 steel matrix surfaces by soldering bonding agent after cooling, form CBN emery wheels.
Embodiment 4
A kind of super hard abrasive ordered arrangement method, comprises the following steps:
(1)The a diameter of 8cm manganese steel matrix of circle 65 is taken, matrix is put into 5% ~ 15% alcoholic solution, uses ultrasonic wave Cleaning 3 ~ 5 minutes, be placed in ventilation dry it is standby;Choose the electroplated diamond of 50-60 mesh and the diamond of diamond particles Grain, it is placed in ultrasonic wave in acetone soln and cleans, remove dust and grease of electroplated diamond and diamond particle surfaces attachment etc. Impurity;On the surface of circular grinding bound abrasive grains, pressure sensitive adhesive is smeared, colloid thickness is 0.1 ~ 0.5mm;
(2)The square water-soluble cellulose film for taking a length of side to be more than 8cm, the thickness of water-soluble cellulose film With the consistency of thickness of pressure sensitive adhesive, punching processing is carried out on laser-beam drilling machine, the hole of a diameter of 10 mesh is made a call to every 10mm(Hole Spacing can be selected according to the size of superabrasive particles, and being independent of each other between particle is advisable);The porous water solubility is fine The matrix surface after plain film paving processing is tieed up, and presses and pressure sensitive adhesive is flowed out from hole;
(3)Electroplated diamond and diamond particles are trickled down into step naturally(2)After the surface of semi-finished of gained, by semi-finished product It is placed in 0.5h in 70 DEG C of baking oven so that pressure-sensitive adhesive curing, electroplated diamond and diamond particles are fixedly arranged on pressure sensitive adhesive;Make Gently it will not sweep by cohesive abrasive grain with banister brush;
(4)The semi-finished product being cured are put into 50 DEG C of water, hydrolyze water-soluble cellulose film, treat its complete hydrolysis Afterwards(About 7min), semi-finished product are taken out, drying finished product 4 at 100-150 DEG C.
By one layer of powdered filler metal of the uniform arrangement in the surface of finished product 4, it is then placed in vacuum or controlled atmosphere furnace, is heated to solder Melt, abrasive grain is fixedly secured in 65 manganese steel matrix surfaces by soldering bonding agent after cooling, forms round grinding disc.
Embodiment 5
A kind of super hard abrasive ordered arrangement method, comprises the following steps:
(1)The a diameter of 10cm manganese steel matrix of bowl-type 65 is taken, matrix is put into 5% ~ 15% alcoholic solution, uses ultrasonic wave Cleaning 3 ~ 5 minutes, be placed in ventilation dry it is standby;Choose the electroplating cubic boron nitride and polycrystalline cubic boron nitride of 280-300 mesh Particle, it is placed in ultrasonic wave in acetone soln and cleans, remove electroplating cubic boron nitride and the ash of polycrystalline cubic boron nitride surface attachment The impurity such as dirt and grease;On the surface of bowl grinding bound abrasive grains, pressure sensitive adhesive is smeared, colloid thickness is 0.2-0.41mm;
(2)The square water soluble starch class film for taking a length of side to be more than 10cm, is beaten on laser-beam drilling machine Hole is handled, and the hole of a diameter of 300 mesh is made a call to every 0.2mm(Pitch of holes can be selected according to the size of superabrasive particles, Being independent of each other between particle is advisable);By the matrix surface of porous water soluble starch class film paving after treatment, and pressing makes Pressure sensitive adhesive is obtained to ooze out from through hole;
(3)Electroplating cubic boron nitride and polycrystalline cubic boron nitride particle are trickled down into step naturally(2)The semi-finished product table of gained Behind face, semi-finished product are placed in 0.5h in 80 DEG C of baking oven so that pressure-sensitive adhesive curing, by electroplating cubic boron nitride and polycrystalline cubic nitrogen Change boron particles to be fixedly arranged on pressure sensitive adhesive;Gently it will not sweep by cohesive abrasive grain using banister brush;
(4)The semi-finished product being cured are put into 80 DEG C of water, hydrolyze water soluble starch class film, treat its complete hydrolysis Afterwards(About 7min), taken out from water, drying finished product 5 at 100-150 DEG C.
By one layer of powdered filler metal of the uniform arrangement in the surface of finished product 5, it is then placed in vacuum or controlled atmosphere furnace, is heated to solder Melt, abrasive material is fixedly secured in 65 manganese steel matrix surfaces by soldering bonding agent after cooling, forms bowl-type grinding disc.
Embodiment 6
A kind of super hard abrasive ordered arrangement method, comprises the following steps:
(1)The a diameter of 10cm manganese steel matrix of bowl-type 65 is taken, matrix is put into 5% ~ 15% alcoholic solution, uses ultrasonic wave Cleaning 3 ~ 5 minutes, be placed in ventilation dry it is standby;The hard alloy particle of 80-90 mesh is chosen, is placed in ultrasonic wave in acetone soln Cleaning, remove the impurity such as dust and the grease of carbide surface attachment;On the surface of bowl grinding bound abrasive grains, smear pressure-sensitive Glue, colloid thickness are 0.5 ~ 1mm;
(2)The square polyethylene oxide thin film for taking a length of side to be more than 10cm, is punched on laser-beam drilling machine Processing, the hole of a diameter of 80 mesh is made a call to every 0.5mm(Pitch of holes can be selected according to the size of superabrasive particles, with Being independent of each other between particle is advisable);By the matrix surface of porous polyethylene oxide thin film paving after treatment, and press and cause pressure Quick glue oozes out from through hole;
(3)Hard alloy particle is trickled down into step naturally(2)After the surface of semi-finished of gained, semi-finished product are placed in 60 DEG C 0.5h in baking oven so that pressure-sensitive adhesive curing, hard alloy particle is fixedly arranged on pressure sensitive adhesive;Using banister brush by not by cohesive Abrasive grain gently is swept;
(4)The semi-finished product being cured are put into 20 DEG C of water, hydrolyze polyethylene oxide thin film, after its complete hydrolysis (About 14min), taken out from water, drying finished product 6 at 100-150 DEG C.
By one layer of powdered filler metal of the uniform arrangement in the surface of finished product 6, it is then placed in vacuum or controlled atmosphere furnace, is heated to solder Melt, hard alloy abradant is fixedly secured in 65 manganese steel matrix surfaces by soldering bonding agent after cooling, forms bowl-type grinding disc.
Comparative example
The difference of comparative example and embodiment 1 is:After matrix surface lays pressure sensitive adhesive, directly on pressure sensitive adhesive Abrasive grain and solder flux are dispensed, then solidification, drying sample 7, without using polyvinyl alcohol film.
By one layer of powdered filler metal of the uniform arrangement in the surface of sample 7, it is then placed in vacuum or controlled atmosphere furnace, is heated to solder Melt, diamond abrasive is fixedly secured in 65 manganese steel matrix surfaces by soldering bonding agent after cooling, forms bowl-type grinding disc.Through The abrasive grain skewness that observation understands grinding disc surface is crossed, abrasive material aggregation occur in respective regions, and some regions occur The sparse situation of abrasive material.
Performance test is tested
Performance detection is carried out to the bowl-type grinding disc that the method using embodiment 1 and comparative example is prepared respectively.
The 10cm prepared respectively using embodiment 1 and comparative example bowl-type grinding disc is polished 45 steel, as a result as follows
Using the grinding efficiency of bowl-type grinding disc prepared by the method for comparative example, service life is continuous for 8 ~ 10g/min Polish 6h;Using the grinding efficiency of bowl-type grinding disc prepared by the method for embodiment 1, service life is continuous for 12 ~ 14g/min Polish 8.5h.Compared with comparative example, the grinding efficiency of the bowl-type grinding disc of embodiment 1 improves 40% ~ 50%, and service life improves 42%。

Claims (10)

1. a kind of super hard abrasive ordered arrangement method, it is characterised in that comprise the following steps:
(1)Pressure sensitive adhesive is laid in metal base surface;
(2)The uniform sequential water-soluble film that through hole is distributed with of layer of surface is bonded on pressure sensitive adhesive;
(3)After pressure sensitive adhesive enters the through hole of water-soluble film, superabrasive particles are dispensed in film surface, then drying is solid Change so that abrasive grain fully consolidates;
(4)By step(3)In obtained semi-finished product consolidated be placed in water, water-soluble film is fully dissolved and dried.
2. super hard abrasive ordered arrangement method according to claim 1, it is characterised in that described water-soluble film is poly- Alcohol film, polyethylene oxide thin film, water-soluble cellulose film or water soluble starch class film.
3. super hard abrasive ordered arrangement method according to claim 1 or 2, it is characterised in that the aperture of through hole is 10- 300 mesh, pitch of holes 0.02-10mm.
4. super hard abrasive ordered arrangement method according to claim 3, it is characterised in that pressure sensitive adhesive and water-soluble film Thickness is 0.1-1mm.
5. super hard abrasive ordered arrangement method according to claim 1, it is characterised in that by the semi-finished product after baking and curing Backwardness is not swept in surface by cohesive abrasive grain, then sample is placed in water.
6. super hard abrasive ordered arrangement method according to claim 1, it is characterised in that in metal base surface laying Before pressure sensitive adhesive, first metal base surface is put into alcohol and is cleaned by ultrasonic.
7. super hard abrasive ordered arrangement method according to claim 6, it is characterised in that the metal base surface is flat Face or curved surface.
8. super hard abrasive ordered arrangement method according to claim 1, it is characterised in that described super hard abrasive is Buddha's warrior attendant In stone, electroplated diamond, cubic boron nitride, electroplating cubic boron nitride, polycrystalline cubic boron nitride and hard alloy crushed particles It is one or more.
9. super hard abrasive ordered arrangement method according to claim 1, it is characterised in that step(3)Middle baking and curing 60 ~ 80 DEG C of temperature, time are 0.5 ~ 1h.
10. super hard abrasive ordered arrangement method according to claim 1, it is characterised in that step(4)Middle water temperature be 20 ~ 80 DEG C, drying temperature is 100 ~ 150 DEG C.
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CN105773452B (en) * 2016-05-04 2018-04-13 长沙理工大学 Preparation method of fiber grinding wheel with orderly arranged spiral fibers
CN106925955A (en) * 2017-02-22 2017-07-07 成都青石激光科技有限公司 Sphere material quasi-crystalline lattice is distributed in the processing method in matrix material
CN107030618A (en) * 2017-05-12 2017-08-11 太仓望虞机械科技有限公司 A kind of grinding tool of abrasive particle ordered arrangement
CN108724025B (en) * 2018-05-17 2020-01-31 郑州磨料磨具磨削研究所有限公司 ordered arrangement metal bond diamond grinding wheel and preparation method thereof
CN110370178A (en) * 2019-07-31 2019-10-25 冼国强 A kind of individual particle ordered arrangement electroplating diamond grinding block and preparation method thereof
CN110730607B (en) * 2019-10-16 2021-08-03 湖南飞鸿达新材料有限公司 Heat-conducting wave-absorbing insulating sheet with high heat-conducting performance and preparation method thereof

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CN101797725A (en) * 2010-01-19 2010-08-11 杭州博大金刚石有限公司 Diamond grinding material sequential distributing system and process
CN103056450A (en) * 2011-10-22 2013-04-24 湖南飞越新材料科技有限责任公司 Manufacture method evenly distributing and orderly arranging diamond saw blades
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