CN105394066A - Insecticidal composition containing indoxacarb and cycloxaprid - Google Patents
Insecticidal composition containing indoxacarb and cycloxaprid Download PDFInfo
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- CN105394066A CN105394066A CN201510938382.7A CN201510938382A CN105394066A CN 105394066 A CN105394066 A CN 105394066A CN 201510938382 A CN201510938382 A CN 201510938382A CN 105394066 A CN105394066 A CN 105394066A
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- Prior art keywords
- cycloxaprid
- indoxacarb
- cabbage
- insecticidal composition
- moth
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- CFSFEIZUJGTCRB-UHFFFAOYSA-N CC1CC(C2)C2C1 Chemical compound CC1CC(C2)C2C1 CFSFEIZUJGTCRB-UHFFFAOYSA-N 0.000 description 1
- GDOPTJXRTPNYNR-UHFFFAOYSA-N CC1CCCC1 Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to the pesticide field, and specifically discloses an insecticidal composition containing indoxacarb and cycloxaprid; indoxacarb and cycloxaprid are used as effective components, and the insecticidal composition has an optional dosage form of one of a suspending agent, a microemulsion, an aqueous emulsion, missible oil, a wettable powder and granules. The insecticidal composition is used for prevention and control of beet armyworm, plutella xylostella, cabbage caterpillar, spodoptera litura, cabbage moth, cotton bollworm, oriental tobacco budworm, leaf roller moth, codling moth, leafhoppers, earias, colorado potato beetle and other injurious insects in wild cabbage, broccoli and other crops, has high efficiency on all rice brown planthopper, whitebacked planthopper and small brown planthopper, has good control effect on cabbage aphids and cucumber aphids, also has better assistant prevention effect on rice leaf folder, has the characteristics of high efficiency, low toxicity, low residues, wide insecticidal spectrum, significant synergy, use cost reduction and the like, particularly high efficiency, low toxicity and low residues, and is especially beneficial for production of green foods.
Description
Technical field
The invention belongs to technical field of pesticide, relate to field of pesticides, particularly a kind of Pesticidal combination containing indoxacarb and cycloxaprid.
Background technology
Indoxacarb, chloro-2,3,4a, the 5-tetrahydrochysene-2-of chemical name: 7-[methoxycarbonyl (4-Trifluoromethoxyphen-l) carbamoyl] indeno [1,2-e] [1,3,4-] oxadiazines-4a-carboxylate methyl ester, molecular formula: C
22h
17clF
3n
3o
7relative molecular mass: 527.83, structural formula is as follows:
Main physico-chemical parameter: fusing point: 88.1 DEG C; Vapour pressure: <1.010^-5Pa (20-25 DEG C); Density: 1.03 (20 DEG C); Solvability (20 DEG C): <0.5mg/L in water; Solvability (g/L) in other solvent: methyl alcohol 0.39, acetonitrile 76, acetone 140.Aqueous stability DT50:>30 days (pH=5); 30 days (pH=7), about 2 days (pH=9).
The former medicine of indoxacarb controls usually more than 95%, and moisture requirement is below 1.0%, and pH value is divided into and controls at 4.0-7.0, and acetone insoluble matter requires below 0.5%.Meanwhile, FAO requires that indoxacarb former medicine R body burden will less than 1/3rd of S body.
Indoxacarb has unique mechanism of action, it is converted into DCJW rapidly in insect bodies, insect nerve cell inactivation state Voltage-gated sodium channels is acted on by DCJW, nerve impulse transmission in irreversible blocking-up insect bodies, destruction nerve impulse is transmitted, and causes pest movements to be lacked of proper care, can not take food, benumbs and finally death.In prior art, it is mainly applicable to prevent and treat beet armyworm on the crops such as wild cabbage, flower coconut palm class, cabbage mustard, tomato, capsicum, cucumber, little cucumber, eggplant, lettuce, apple, pears, peach, apricot, cotton, potato, grape, diamond-back moth, cabbage caterpillar, prodenia litura, tomato moth, cotton bollworm, oriental tobacco budworm, leaf rollers, codling moth, leafhopper, spark, colorado potato beetle; Indoxacarb has tags and stomach poison function, all effective to each instar larvae.Medicament enters in insect bodies by contacting and taking food, and in 0-4 hour, namely insect stops taking food, and is benumbed immediately, and the coordination ability of insect can decline (larva can be caused to fall from crop), generally dead in 24-60 hour after medicine; Cross resistance is there is not with other insecticides.
Cycloxaprid, molecular formula: C
14h
15clN
4o
3, structural formula is as follows:
Cycloxaprid cycloxaprid is a kind of state-of-the art anabasine insecticide, it is the antagonist of first nAChR in the world, though there is precedent indoxacarb and other pesticide compositionals being obtained Pesticidal combination in prior art, but do not have indoxacarb and the composite relevant report of cycloxaprid, the effect after also not having corresponding technology to enlighten to determine both composite how.
Summary of the invention
The object of the present invention is to provide a kind of Pesticidal combination containing indoxacarb and cycloxaprid, with indoxacarb and cycloxaprid for active ingredient, optional formulation is the one in suspending agent, microemulsion, aqueous emulsion, missible oil, wetting powder, granule.Pesticidal combination of the present invention is used for preventing and treating and is applicable to prevent and treat the various pests such as beet armyworm, diamond-back moth, cabbage caterpillar, prodenia litura, tomato moth, cotton bollworm, oriental tobacco budworm, leaf rollers, codling moth, leafhopper, spark, colorado potato beetle on the crop such as wild cabbage, flower coconut palm class, all efficient to Brown Planthopper, white-backed planthopper, small brown rice planthopper, also there is good preventive effect to cabbage aphid and Cucumber blight, have to rice leaf roller anti-effect of holding concurrently preferably.Have efficient, low toxicity, low-residual, insecticidal spectrum are wide, synergistic effect significantly and reduce the features such as use cost, particularly its high efficiency, low toxicity, low-residual, is particularly advantageous in the production of pollution-free food.
Concrete technical scheme of the present invention is as follows:
Containing a Pesticidal combination for indoxacarb and cycloxaprid, with indoxacarb and cycloxaprid for active ingredient, in composition, the percentage by weight of active ingredient is 10%-75%, and the weight ratio of indoxacarb and cycloxaprid is 1:10-10:1.
On the basis of technique scheme, inventor, by further to the research of both composite rear relevant effect, obtains more optimal scheme as follows: the weight ratio of described indoxacarb and cycloxaprid is 1:6-6:1, and synergistic function is given prominence to; Further the weight ratio of described indoxacarb and cycloxaprid is 1:2-2.5:1, and control efficiency is best.
Cycloxaprid is a kind of cis oxo bridge heterocycle structure anabasine insecticide, its mechanism of action and other anabasine insecticides different, show that cycloxaprid can be combined with nAChR high-affinity by experiment, the reaction of Agonists Acetylcholine can be suppressed simultaneously.Experiment shows that cycloxaprid is a kind of antagonist of nAChR, is that the mechanism of action of the activator of nAChR is different, is thus not easy to produce cross resistance with other anabasine pesticide from other anabasine insecticide.Due to the mechanism of action of its uniqueness, B and the Q type Bemisia tabaci of cycloxaprid to indoor anti-Diacloden Type B Bemisia tabaci adults, anti-Imidacloprid brown planthopper, anti-Imidacloprid has significant high activity.Therefore, in the inventive solutions, cycloxaprid carries out composite as the substitute species of the anabasine insecticide resistance managements such as Imidacloprid and indoxacarb; Show that cycloxaprid is as very micro-in water flea class, fish, algae, edaphon and other plant impact on non-target organism through biologicall test experiment; In 24h, cycloxaprid will apparently higher than other anabasine insecticide to the safety of honeybee.
The present invention with indoxacarb and cycloxaprid for effective ingredient is undertaken composite by said ratio, there is excellent synergy, cycloxaprid and the dual stomach toxicity of indoxacarb and action of contace poison, the in addition systemic action of cycloxaprid, more accelerate medicament impact on nerve conduction in pest body.Both composite bad reactions accelerating insect, insect is made to stop in advance ingesting and extending action time, therefore be more suitable for for killing the strong insect of short period fertility, be a kind of have efficient, low toxicity, low-residual, insecticidal spectrum are wide, synergistic effect significantly and reduce the Pesticidal combination of use cost, particularly its high efficiency, low toxicity, low-residual, is particularly advantageous in the production of pollution-free food.
Pesticidal combination provided by the invention is carried out toxicity test, rat acute LD50 of passing through mouth > 5000 mg/kg, chmice acute LD50 of passing through mouth > 5000 mg/kg, rabbit is acute is greater than 3000 mg/kg through skin LD50, rat acute is greater than >3000mg/kg mg/kg through skin LD50, skin is had no stimulation, eye is had no stimulation, shows that the Pesticidal combination containing indoxacarb and cycloxaprid of the present invention belongs to low-toxin farm chemicals.
Except above-mentioned active ingredient, in Pesticidal combination of the present invention, also can comprise auxiliary element, mainly comprise acceptable organic solvent, emulsifier, surfactant etc.; Wherein organic solvent comprises fat hydrocarbon organic solvent, arene organic solvent, plant oil solvent, alcohol organic solvent, lipid organic solvent or organic solvent of ketone etc.; Surfactant has anion surfactant, comprising fatty acid salts such as alkylbenzenesulfonate, lignin sulfonate, alkyl sulfate, Alkyl ethoxy carboxylate acid salt, also have phosphate ester salt, sulfosuccinate ester salt, naphthalene sulfonate, sulfonate and formaldehyde condensation product etc.; Cationic surfactant comprises amine salt, quaternary amine, amine oxide etc.; Amphoteric surfactant comprises betain, imidazoline type, Amino acid, phosphine ester etc.; Non-ionic surface active agent comprises the alkoxides such as fatty alcohol ether, alkyl phenol ether, alkyl ether amine, polyethers; Also has the aliphatic alcohol ester such as glyceride, polyol ester; Also have fatty acid alkane ester, alkylamide etc.; Also has the mixed surfactant of alcohol ether type.Other auxiliary element also comprises xanthans, the thickeners such as sodium carboxymethyl starch, the antifreezing agents such as ethylene glycol, glycerine, urea; The fillers such as kaolin, bentonite, attapulgite, charcoal acid calcium, and the acceptable stabilizing agent of other pesticidal preparations, safener, colouring agent etc.
Pesticidal combination of the present invention for main active ingredient, is mixed with different formulations from one or more in above-mentioned auxiliary element according to agricultural chemicals conventional method with indoxacarb and cycloxaprid.The formulation of described Pesticidal combination is missible oil, suspending agent, microemulsion, aqueous emulsion etc., can carry out selection preparation so as required, applied widely, meets the demand of client.
Pesticidal combination of the present invention is used for preventing and treating wild cabbage, paddy rice, brassicaceous vegetable, cotton, corn, potato, Deng vegetables, fruit tree, various pests on the crops such as paddy rice, as: thrips, cabbage caterpillar, beet armyworm, corn borer, cotton bollworm, pink bollworm, imported cabbageworm, tomato moth, diamond-back moth, Hellula undalis, black cutworm, oriental tobacco budworm, codling moth, leafhopper, spark, colorado potato beetle, Brown Planthopper, white-backed planthopper, small brown rice planthopper, rice leaf roller, the various plants insects such as cotton field Bemisia tabaci, on good synergy control efficiency basis, expand the scope of control of insect.
It is 1/10 by weight that inventor passes through former for indoxacarb medicine and the former medicine of cycloxaprid, 1/6,1/2,1/1,2/1,4/1,8/1,10/1 is composite, contrast with the single dose indoxacarb suspending agent of corresponding proportion and cycloxaprid suspending agent respectively, carried out diamond-back moth Toxicity Determination, its co-toxicity coefficient is 186.31-248.76, and result shows: complex preparation is compared with single dose, there is significant synergistic effect, wherein with 1/2 to 2.5/1 successful, when weight ratio is 2/1, synergy is the most obvious, and co-toxicity coefficient is 248.76; With 5-8 gram of active ingredient/mu consumption control Chinese cabbage diamond-back moth, cotton bollworm, rice fulgorid etc., preventive effect, all more than 96%, sprays medicine 2 ~ 5 days, successful.
In sum, Pesticidal combination provided by the invention has efficiently, low toxicity, low-residual, insecticidal spectrum are wide, synergistic effect significantly and reduce the features such as use cost, particularly its high efficiency, low toxicity, low-residual, is particularly advantageous in the production of pollution-free food.
Embodiment
Be further described inventing the technical scheme related to below in conjunction with embodiment, to contribute to understanding of the present invention, but not as the restriction to technical scheme, except mentioning especially, component ratio is all weight percentage.
Embodiment 145% indoxacarb cycloxaprid wettable powder; (8:1)
Raw material consists of the former medicine of 40% indoxacarb, the former medicine of 5% cycloxaprid, 8% naphthalene sulfonate, 2% naphthalenesulfonate formaldehyde condensation compound, 2% lauryl sodium sulfate, and 5% polycarboxylate, all the other supply with white carbon, wetting powder mode of production preparation routinely.
Embodiment 1 sample, contrast medicament is 5% indoxacarb missible oil (self-produced), and 5% cycloxaprid micro emulsion (self-control) carries out comparative efficacy test.Controlling object: beet armyworm.
During medication, mean temperature of air is at 21-25 DEG C, and weather is based on fine, and data show: complex preparation is compared with single dose, and anti-efficiency increases.
Embodiment 210% indoxacarb cycloxaprid microemulsion (1:1)
Raw material consists of 5 grams of former medicines of indoxacarb, 5 grams of former medicines of cycloxaprid, dimethylbenzene 5 grams, 1-METHYLPYRROLIDONE 5 grams, calcium dodecyl benzene sulfonate 4 grams, OPEO 6 grams, phenethyl phenol mela mine-formaldehyde resin APEO 5 grams, glycerine 5 grams, water supplement 100 grams, microemulsion mode of production preparation routinely.
Embodiment 2 sample, contrast medicament is 5% indoxacarb missible oil (self-produced), and 5% cycloxaprid missible oil (self-produced) carries out comparative efficacy test.Controlling object: rice fulgorid.
During medication, mean temperature of air is at 20-25 DEG C, and weather is based on fine to cloudy, and data show: complex preparation is compared with single dose, and anti-efficiency significantly improves.
Embodiment 315% indoxacarb cycloxaprid missible oil (1:2)
Raw material consists of 5 grams of former medicines of indoxacarb, 10 grams of former medicines of cycloxaprid, dimethylbenzene 5 grams, 1-METHYLPYRROLIDONE 10 grams, fatty alcohol-polyoxyethylene ether 7 grams, phenethyl phenol mela mine-formaldehyde resin APEO 4 grams, calcium dodecyl benzene sulfonate 4 grams, mixed benzene are supplemented to 100 grams, missible oil mode of production preparation routinely.
Embodiment 3 sample, contrast medicament is 5% indoxacarb suspending agent (self-produced), and 5% cycloxaprid missible oil (self-control) carries out comparative efficacy test.Controlling object: Brown Planthopper.
During medication, mean temperature of air is at 21-25 DEG C, and weather is based on fine, and data show: complex preparation is compared with single dose, and anti-efficiency significantly improves.
Embodiment 421% indoxacarb cycloxaprid suspending agent (2.5:1)
Raw material consists of 15 grams of former medicines of indoxacarb, 6 grams of former medicines of cycloxaprid, calcium dodecyl benzene sulfonate 1.2 grams, phenethyl phenol mela mine-formaldehyde resin APEO 2 grams, special phenethyl phenol APEO 1 gram, naphthalenesulfonatedispersant dispersant 1 gram, xanthans 0.1 gram, aluminium-magnesium silicate 1 gram, ethylene glycol 5 grams, water supplement 100 grams.Aqueous suspension agent mode of production preparation routinely.
Embodiment 4 sample, contrast medicament is 150g/L indoxacarb suspending agent (self-produced), and 25% cycloxaprid suspending agent (Shengnong Biological-Chemical Products Co., Ltd., Shanghai) carries out comparative efficacy test.Controlling object: cotton bollworm.
During medication, mean temperature of air is at 21-25 DEG C, and weather is based on fine, and data show: complex preparation is compared with single dose, and anti-efficiency significantly improves.
Embodiment 535% indoxacarb cycloxaprid granule (6:1)
Raw material consists of the former medicine of 30% indoxacarb, the former medicine of 5% cycloxaprid, and 12% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 6% naphthalenesulfonate formaldehyde condensation compound, 8% polycarboxylate, all the other are supplied with sodium carboxymethyl starch.Granule mode of production preparation routinely.
Embodiment 5 sample, contrast medicament is 30% indoxacarb granule (self-produced), and 25% cycloxaprid suspending agent (Shengnong Biological-Chemical Products Co., Ltd., Shanghai) carries out comparative efficacy test.Controlling object: rice leaf roller.
During medication, mean temperature of air is at 21-25 DEG C, and weather is based on fine, and data show: complex preparation is compared with single dose, and anti-efficiency significantly improves.
Embodiment 656% indoxacarb cycloxaprid wettable agent (1:6)
Raw material consists of the former medicine of 8% indoxacarb, the former medicine of 48% cycloxaprid, 10% naphthalene sulfonate, 5% naphthalenesulfonate formaldehyde condensation compound, 2% lauryl sodium sulfate, and 5% polycarboxylate, all the other supply with kaolin.Wettable agent mode of production preparation routinely.
Embodiment 6 sample, contrast medicament is 30% indoxacarb granule (self-produced), and 25% cycloxaprid suspending agent (Shengnong Biological-Chemical Products Co., Ltd., Shanghai) carries out comparative efficacy test.Controlling object: cotton field Bemisia tabaci.
During medication, mean temperature of air is at 21-25 DEG C, and weather is based on fine, and data show: complex preparation is compared with single dose, and anti-efficiency significantly improves.
Embodiment 772% indoxacarb cycloxaprid granule (10:1)
Raw material consists of the former medicine of 66% indoxacarb, the former medicine of 6% cycloxaprid, and 15% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 5% naphthalenesulfonate formaldehyde condensation compound, 8% polycarboxylate, all the other are supplied with sodium carboxymethyl starch.Granule mode of production preparation routinely.
Embodiment 7 sample, contrast medicament is 30% indoxacarb granule (self-produced), and 25% cycloxaprid suspending agent (Shengnong Biological-Chemical Products Co., Ltd., Shanghai) carries out comparative efficacy test.Controlling object: diamond-back moth.
During medication, mean temperature of air is at 21-25 DEG C, and weather is based on fine, and data show: complex preparation is compared with single dose, and anti-efficiency significantly improves.
As can be seen from the above embodiments, undertaken composite by former for indoxacarb medicine and the former medicine of cycloxaprid by weight ratio of the present invention, result shows: complex preparation, compared with single dose, has significant synergistic effect and control efficiency, wherein with 1/6 to 6/1 successful, its insecticidal effect is all greater than 90%; Especially when weight ratio is 1/2 to 2.5/1, synergy is the most obvious, anti-efficiency the 9th day time up to more than 95%.
Claims (4)
1. containing a Pesticidal combination for indoxacarb and cycloxaprid, it is characterized in that: with indoxacarb and cycloxaprid for active ingredient, in composition, the percentage by weight of active ingredient is 10%-75%, and the weight ratio of indoxacarb and cycloxaprid is 1:10-10:1.
2. Pesticidal combination according to claim 1, is characterized in that: the weight ratio of described indoxacarb and cycloxaprid is 1:6-6:1.
3. Pesticidal combination according to claim 1, is characterized in that: the weight ratio of described indoxacarb and cycloxaprid is 1:2-2.5:1.
4. Pesticidal combination according to claim 1, is characterized in that: the formulation of said composition is the one in suspending agent, microemulsion, aqueous emulsion, missible oil, wetting powder, granule.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510938382.7A CN105394066A (en) | 2015-12-15 | 2015-12-15 | Insecticidal composition containing indoxacarb and cycloxaprid |
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|---|---|---|---|
| CN201510938382.7A CN105394066A (en) | 2015-12-15 | 2015-12-15 | Insecticidal composition containing indoxacarb and cycloxaprid |
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|---|---|
| CN105394066A true CN105394066A (en) | 2016-03-16 |
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| CN201510938382.7A Pending CN105394066A (en) | 2015-12-15 | 2015-12-15 | Insecticidal composition containing indoxacarb and cycloxaprid |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103843802A (en) * | 2012-12-03 | 2014-06-11 | 上海生农生化制品有限公司 | Cycloxaprid insecticidal composition |
| US20140228213A1 (en) * | 2013-02-11 | 2014-08-14 | Bayer Cropsciene Lp | Compositions comprising a streptomyces-based biological control agent and an insecticide |
| CN104082318A (en) * | 2014-07-18 | 2014-10-08 | 江苏省绿盾植保农药实验有限公司 | Composite insecticide containing ethylicin and cycloxaprid and application of composite insecticide |
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2015
- 2015-12-15 CN CN201510938382.7A patent/CN105394066A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103843802A (en) * | 2012-12-03 | 2014-06-11 | 上海生农生化制品有限公司 | Cycloxaprid insecticidal composition |
| US20140228213A1 (en) * | 2013-02-11 | 2014-08-14 | Bayer Cropsciene Lp | Compositions comprising a streptomyces-based biological control agent and an insecticide |
| CN104082318A (en) * | 2014-07-18 | 2014-10-08 | 江苏省绿盾植保农药实验有限公司 | Composite insecticide containing ethylicin and cycloxaprid and application of composite insecticide |
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Application publication date: 20160316 |