CN105368181A - Waterborne fluorocarbon metal baking paint - Google Patents
Waterborne fluorocarbon metal baking paint Download PDFInfo
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- CN105368181A CN105368181A CN201510831212.9A CN201510831212A CN105368181A CN 105368181 A CN105368181 A CN 105368181A CN 201510831212 A CN201510831212 A CN 201510831212A CN 105368181 A CN105368181 A CN 105368181A
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Abstract
The invention discloses a waterborne fluorocarbon metal baking paint comprising the raw materials in parts by weight: 20-50 parts of a waterborne PVDF fluorocarbon emulsion, 5-15 parts of waterborne amino resin, 10-15 parts of a waterborne blocked aliphatic cyanate prepolymer, 5-15 parts of a modified cycloaliphatic epoxy emulsion, 0.5-1.5 parts of benzoyl peroxide, 5-10 parts of N,N-dimethyl ethanolamine, 20-40 parts of benzyl alcohol, 1-2 parts of a pigment, 1-2 parts of an organic zinc chelate anti-flash rust agent, 1-2 parts of modified monoamino monoepoxy silane, 1-2 parts of a wetting dispersant, 0.5-1.5 parts of a defoaming agent, 1-1.5 parts of a levelling agent, 1-3 parts of a thickener, and 20-50 parts of water. The waterborne fluorocarbon metal baking paint has the advantages of weather resistance, water boiling resistance, and strong adhesion force.
Description
Technical field
The present invention relates to metal baking finish technical field, particularly relate to a kind of water-based fluorocarbon metal baking finish.
Background technology
Baking vanish is as a kind of common industrial finish, be widely used in the industries such as machinofacture, electromechanics and five metals, at present for the growing growth in industrial paint market of aluminum veneer metal curtain wall, but the coating of aluminum veneer metal curtain wall mainly solvent based coating on the market, the volatilization of organic solvent brings pollution to environment, and along with the enhancing of people's environmental consciousness, the application of water-based stoving paint is increasingly extensive, but the weathering resistance of current water-based stoving paint, water boiling resistance and sticking power are poor, in urgent need to be improved.
Summary of the invention
A kind of water-based fluorocarbon metal baking finish, goods are weather-proof, water boiling resistance, strong adhesion.
A kind of water-based fluorocarbon metal baking finish that the present invention proposes, its raw material comprises by weight: water-based PVDF fluorine carbon emulsion 20-50 part, water-compatible amino resin 5-15 part, watersoluble closed type aliphatics cyanate prepolymer 10-15 part, modified cycloaliphatic epoxy emulsion 5-15 part, benzoyl peroxide 0.5-1.5 part, N, N-dimethylethanolamine 5-10 part, phenylcarbinol 20-40 part, pigment 1-2 part, organic zinc complex anti-sudden strain of a muscle rust agent 1-2 part, modification mono amino monocycle TMOS 1-2 part, wetting dispersing agent 1-2 part, defoamer 0.5-1.5 part, flow agent 1-1.5 part, thickening material 1-3 part, water 20-50 part.
Preferably, modified cycloaliphatic epoxy emulsion adopts following technique to prepare: by epoxy chloropropane, dihydroxyphenyl propane, methyl methacrylate, vinylbenzenesulfonic acid dimethyl ethanol amine salt, vinylbenzene under initiator effect after polyreaction, add water and be mixed to get modified cycloaliphatic epoxy emulsion, wherein the viscosity of modified cycloaliphatic epoxy emulsion is 500-2000mPa.s, solids content is 35-40%, and pH value is 7-9.
Preferably, modified cycloaliphatic epoxy emulsion adopts following technique to prepare: by weight by 15-20 part epoxy chloropropane, 20-35 part dihydroxyphenyl propane, 5-10 part, 8-14 part methyl methacrylate, 1-2 part vinylbenzenesulfonic acid dimethyl ethanol amine salt, 1-3 part vinylbenzene under the effect of 0.01-0.2 part initiator after polyreaction, add water and be mixed to get modified cycloaliphatic epoxy emulsion, wherein the viscosity of modified cycloaliphatic epoxy emulsion is 500-2000mPa.s, solids content is 35-40%, and pH value is 7-9.
Preferably, pigment is made up of tinting pigment, rust-stabilising pigment and pigment extender;
Wherein tinting pigment is made up of one or more in titanium dioxide, phthalocyanine blue, phthalocyanine green, chrome yellow, toluylene blue amine, loess, chrome green, carbon black;
Rust-stabilising pigment is made up of one or more in red iron oxide, glass flake, zinc phosphate, aluminium triphosphate;
Pigment extender is made up of one or more in calcium carbonate, Magnesium Silicate q-agent, pure aluminium silicate, calcium sulfate, crystalline silica, diatomite, barium sulfate.
Preferably, water-based PVDF fluorine carbon emulsion, water-compatible amino resin, the weight ratio of watersoluble closed type aliphatics cyanate prepolymer, modified cycloaliphatic epoxy emulsion is 40-45:10-12:12-13.5:12-14.5.
Preferably, the weight ratio of benzoyl peroxide, N, N-dimethylethanolamine is 1-1.3:8-8.5.
Preferably, the weight ratio of pigment, water-based PVDF fluorine carbon emulsion is 1.4-1.8:40-45.
Preferably, its raw material comprises by weight: water-based PVDF fluorine carbon emulsion 40-45 part, water-compatible amino resin 10-12 part, watersoluble closed type aliphatics cyanate prepolymer 12-13.5 part, modified cycloaliphatic epoxy emulsion 12-14.5 part, benzoyl peroxide 1-1.3 part, N, N-dimethylethanolamine 8-8.5 part, water 40-46 part, phenylcarbinol 35-38 part, pigment 1.4-1.8 part, organic zinc complex anti-sudden strain of a muscle rust agent 1.4-1.6 part, modification mono amino monocycle TMOS 1.2-1.5 part, wetting dispersing agent 1.6-1.8 part, defoamer 1-1.3 part, flow agent 1.2-1.35 part, thickening material 2-2.6 part.
A kind of water-based fluorocarbon metal baking finish that the present invention proposes adopts following technique to prepare: by water-based PVDF fluorine carbon emulsion, water-compatible amino resin, watersoluble closed type aliphatics cyanate prepolymer, modified cycloaliphatic epoxy emulsion, benzoyl peroxide, phenylcarbinol, pigment, the agent of organic zinc complex anti-sudden strain of a muscle rust, modification mono amino monocycle TMOS, wetting dispersing agent, defoamer, flow agent, thickening material mixes by proportioning, send in reactor and stir, whipping temp is 70-78 DEG C, churning time is 1-2h, be cooled to 40-60 DEG C and add N, N-dimethylethanolamine stirs 20-30min, add water to stir, obtain water-based fluorocarbon metal baking finish.
In the present invention, above-mentioned water-based fluorocarbon metal baking finish has good weather-proof and water boiling resistance, and pollution-free in coating process, can replace traditional solvent-borne type baking vanish, for aluminum veneer metal curtain wall.By adopting water-based PVDF fluorine carbon emulsion, water-compatible amino resin, watersoluble closed type aliphatics cyanate prepolymer, modified cycloaliphatic epoxy emulsion as filmogen, be equipped with benzoyl peroxide, N, N-dimethylethanolamine, goods have good weathering resistance, water boiling resistance, and sticking power is comparatively excellent.In pigment, zinc phosphate can provide good rust inhibition in early stage; in phosphate anion in modification aluminium triphosphate and metal, iron anode reacts; the firm protective membrane formed based on tertiary iron phosphate can provide good later stage rust-proof mechanism, and sticking power is good, and antirust ability is very excellent.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
A kind of water-based fluorocarbon metal baking finish, its raw material comprises by weight: water-based PVDF fluorine carbon emulsion 50 parts, water-compatible amino resin 5 parts, watersoluble closed type aliphatics cyanate prepolymer 10 parts, modified cycloaliphatic epoxy emulsion 15 parts, benzoyl peroxide 0.5 part, N, N-dimethylethanolamine 10 parts, phenylcarbinol 20 parts, pigment 2 parts, the agent 1 part of organic zinc complex anti-sudden strain of a muscle rust, modification mono amino monocycle TMOS 2 parts, wetting dispersing agent 1 part, defoamer 1.5 parts, flow agent 1 part, thickening material 3 parts, 20 parts, water.
Embodiment 2
A kind of water-based fluorocarbon metal baking finish, its raw material comprises by weight: water-based PVDF fluorine carbon emulsion 20 parts, water-compatible amino resin 15 parts, watersoluble closed type aliphatics cyanate prepolymer 15 parts, modified cycloaliphatic epoxy emulsion 5 parts, benzoyl peroxide 1.5 parts, N, N-dimethylethanolamine 5 parts, phenylcarbinol 40 parts, pigment 1 part, the agent 2 parts of organic zinc complex anti-sudden strain of a muscle rust, modification mono amino monocycle TMOS 1 part, wetting dispersing agent 2 parts, defoamer 0.5 part, flow agent 1.5 parts, thickening material 1 part, 50 parts, water.
Embodiment 3
A kind of water-based fluorocarbon metal baking finish, its raw material comprises by weight: water-based PVDF fluorine carbon emulsion 45 parts, water-compatible amino resin 10 parts, watersoluble closed type aliphatics cyanate prepolymer 12 parts, modified cycloaliphatic epoxy emulsion 14.5 parts, benzoyl peroxide 1 part, N, N-dimethylethanolamine 8.5 parts, 40 parts, water, phenylcarbinol 38 parts, pigment 1.4 parts, the agent 1.6 parts of organic zinc complex anti-sudden strain of a muscle rust, modification mono amino monocycle TMOS 1.2 parts, wetting dispersing agent 1.8 parts, defoamer 1 part, flow agent 1.35 parts, thickening material 2 parts.
Modified cycloaliphatic epoxy emulsion adopts following technique to prepare: by weight by 20 parts of epoxy chloropropane, 20 parts of dihydroxyphenyl propanes, 10 parts of butyl acrylates, 8 parts of methyl methacrylates, 2 parts of vinylbenzenesulfonic acid dimethyl ethanol amine salt, 1 part of vinylbenzene under 0.2 part of initiator effect after polyreaction, add water and be mixed to get modified cycloaliphatic epoxy emulsion, wherein the viscosity of modified cycloaliphatic epoxy emulsion is 500mPa.s, solids content is 40%, and pH value is 7.
Pigment is made up of tinting pigment, rust-stabilising pigment and pigment extender;
Wherein tinting pigment is made up of titanium dioxide, phthalocyanine blue, phthalocyanine green;
Rust-stabilising pigment is made up of red iron oxide, glass flake, zinc phosphate;
Pigment extender is made up of calcium carbonate, Magnesium Silicate q-agent, pure aluminium silicate.
Above-mentioned water-based fluorocarbon metal baking finish adopts following technique to prepare: by water-based PVDF fluorine carbon emulsion, water-compatible amino resin, watersoluble closed type aliphatics cyanate prepolymer, modified cycloaliphatic epoxy emulsion, benzoyl peroxide, phenylcarbinol, pigment, the agent of organic zinc complex anti-sudden strain of a muscle rust, modification mono amino monocycle TMOS, wetting dispersing agent, defoamer, flow agent, thickening material mixes by proportioning, send in reactor and stir, whipping temp is 78 DEG C, churning time is 1h, be cooled to 60 DEG C and add N, N-dimethylethanolamine stirs 20min, add water to stir, obtain water-based fluorocarbon metal baking finish.
Embodiment 4
A kind of water-based fluorocarbon metal baking finish, its raw material comprises by weight: water-based PVDF fluorine carbon emulsion 40 parts, water-compatible amino resin 12 parts, watersoluble closed type aliphatics cyanate prepolymer 13.5 parts, modified cycloaliphatic epoxy emulsion 12 parts, benzoyl peroxide 1.3 parts, N, N-dimethylethanolamine 8 parts, 46 parts, water, phenylcarbinol 35 parts, pigment 1.8 parts, the agent 1.4 parts of organic zinc complex anti-sudden strain of a muscle rust, modification mono amino monocycle TMOS 1.5 parts, wetting dispersing agent 1.6 parts, defoamer 1.3 parts, flow agent 1.2 parts, thickening material 2.6 parts.
Modified cycloaliphatic epoxy emulsion adopts following technique to prepare: by weight by 15 parts of epoxy chloropropane, 35 parts of dihydroxyphenyl propanes, 5 parts of butyl acrylates, 14 parts of methyl methacrylates, 1 part of vinylbenzenesulfonic acid dimethyl ethanol amine salt, 3 parts of vinylbenzene under 0.01 part of initiator effect after polyreaction, add water and be mixed to get modified cycloaliphatic epoxy emulsion, wherein the viscosity of modified cycloaliphatic epoxy emulsion is 2000mPa.s, solids content is 35%, and pH value is 9.
Pigment is made up of tinting pigment, rust-stabilising pigment and pigment extender;
Wherein tinting pigment forms by chrome yellow, toluylene blue amine, loess, chrome green, carbon black;
Rust-stabilising pigment is made up of glass flake, zinc phosphate, tripolyphosphate;
Pigment extender is made up of calcium sulfate, crystalline silica, diatomite, barium sulfate.
Above-mentioned water-based fluorocarbon metal baking finish adopts following technique to prepare: by water-based PVDF fluorine carbon emulsion, water-compatible amino resin, watersoluble closed type aliphatics cyanate prepolymer, modified cycloaliphatic epoxy emulsion, benzoyl peroxide, phenylcarbinol, pigment, the agent of organic zinc complex anti-sudden strain of a muscle rust, modification mono amino monocycle TMOS, wetting dispersing agent, defoamer, flow agent, thickening material mixes by proportioning, send in reactor and stir, whipping temp is 70 DEG C, churning time is 2h, be cooled to 40 DEG C and add N, N-dimethylethanolamine stirs 30min, add water to stir, obtain water-based fluorocarbon metal baking finish.
Embodiment 5
A kind of water-based fluorocarbon metal baking finish, its raw material comprises by weight: water-based PVDF fluorine carbon emulsion 42 parts, water-compatible amino resin 11.5 parts, watersoluble closed type aliphatics cyanate prepolymer 13 parts, modified cycloaliphatic epoxy emulsion 13.6 parts, benzoyl peroxide 1.15 parts, N, N-dimethylethanolamine 8.2 parts, 42 parts, water, phenylcarbinol 36 parts, pigment 1.5 parts, the agent 1.5 parts of organic zinc complex anti-sudden strain of a muscle rust, modification mono amino monocycle TMOS 1.35 parts, wetting dispersing agent 1.7 parts, defoamer 1.16 parts, flow agent 1.32 parts, thickening material 2.4 parts.
Modified cycloaliphatic epoxy emulsion adopts following technique to prepare: by weight by 16 parts of epoxy chloropropane, 32 parts of dihydroxyphenyl propanes, 8 parts of butyl acrylates, 10 parts of methyl methacrylates, 1.5 parts of vinylbenzenesulfonic acid dimethyl ethanol amine salt, 1.6 parts of vinylbenzene under 0.08 part of initiator effect after polyreaction, add water and be mixed to get modified cycloaliphatic epoxy emulsion, wherein the viscosity of modified cycloaliphatic epoxy emulsion is 1400mPa.s, solids content is 38%, and pH value is 8.
Pigment is made up of tinting pigment, rust-stabilising pigment and pigment extender;
Wherein tinting pigment is made up of titanium dioxide, phthalocyanine blue, phthalocyanine green, chrome yellow, toluylene blue amine, loess, chrome green, carbon black;
Rust-stabilising pigment is made up of red iron oxide, glass flake, zinc phosphate, aluminium triphosphate;
Pigment extender is made up of calcium carbonate, Magnesium Silicate q-agent, pure aluminium silicate, calcium sulfate, crystalline silica, diatomite, barium sulfate.
Above-mentioned water-based fluorocarbon metal baking finish adopts following technique to prepare: by water-based PVDF fluorine carbon emulsion, water-compatible amino resin, watersoluble closed type aliphatics cyanate prepolymer, modified cycloaliphatic epoxy emulsion, benzoyl peroxide, phenylcarbinol, pigment, the agent of organic zinc complex anti-sudden strain of a muscle rust, modification mono amino monocycle TMOS, wetting dispersing agent, defoamer, flow agent, thickening material mixes by proportioning, send in reactor and stir, whipping temp is 74 DEG C, churning time is 1.5h, be cooled to 55 DEG C and add N, N-dimethylethanolamine stirs 26min, add water to stir, obtain water-based fluorocarbon metal baking finish.
The paint film adhesion 0 grade that the metal baking finish of water-based fluorocarbon described in embodiment 1-5 is obtained, pencil hardness can reach 3H, resistance to 200 DEG C of high temperature 4h without obvious xanthochromia, resistance to 30 non-foaming non-corrosives in the sky and water, and after testing cold cycling and high temperature, salt spray resistance still can reach 96h.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (8)
1. a water-based fluorocarbon metal baking finish, it is characterized in that, its raw material comprises by weight: water-based PVDF fluorine carbon emulsion 20-50 part, water-compatible amino resin 5-15 part, watersoluble closed type aliphatics cyanate prepolymer 10-15 part, modified cycloaliphatic epoxy emulsion 5-15 part, benzoyl peroxide 0.5-1.5 part, N, N-dimethylethanolamine 5-10 part, phenylcarbinol 20-40 part, pigment 1-2 part, organic zinc complex anti-sudden strain of a muscle rust agent 1-2 part, modification mono amino monocycle TMOS 1-2 part, wetting dispersing agent 1-2 part, defoamer 0.5-1.5 part, flow agent 1-1.5 part, thickening material 1-3 part, water 20-50 part.
2. water-based fluorocarbon metal baking finish according to claim 1, it is characterized in that, modified cycloaliphatic epoxy emulsion adopts following technique to prepare: by epoxy chloropropane, dihydroxyphenyl propane, butyl acrylate, methyl methacrylate, vinylbenzenesulfonic acid dimethyl ethanol amine salt, vinylbenzene under initiator effect after polyreaction, add water and be mixed to get modified cycloaliphatic epoxy emulsion, wherein the viscosity of modified cycloaliphatic epoxy emulsion is 500-2000mPa.s, solids content is 35-40%, and pH value is 7-9.
3. water-based fluorocarbon metal baking finish according to claim 1 and 2, it is characterized in that, modified cycloaliphatic epoxy emulsion adopts following technique to prepare: by weight by 15-20 part epoxy chloropropane, 20-35 part dihydroxyphenyl propane, 5-10 part butyl acrylate, 8-14 part methyl methacrylate, 1-2 part vinylbenzenesulfonic acid dimethyl ethanol amine salt, 1-3 part vinylbenzene under the effect of 0.01-0.2 part initiator after polyreaction, add water and be mixed to get modified cycloaliphatic epoxy emulsion, wherein the viscosity of modified cycloaliphatic epoxy emulsion is 500-2000mPa.s, solids content is 35-40%, pH value is 7-9.
4. the water-based fluorocarbon metal baking finish according to any one of claim 1-3, is characterized in that, pigment is made up of tinting pigment, rust-stabilising pigment and pigment extender;
Wherein tinting pigment is made up of one or more in titanium dioxide, phthalocyanine blue, phthalocyanine green, chrome yellow, toluylene blue amine, loess, chrome green, carbon black;
Rust-stabilising pigment is made up of one or more in red iron oxide, glass flake, zinc phosphate, aluminium triphosphate;
Pigment extender is made up of one or more in calcium carbonate, Magnesium Silicate q-agent, pure aluminium silicate, calcium sulfate, crystalline silica, diatomite, barium sulfate.
5. the water-based fluorocarbon metal baking finish according to any one of claim 1-4, it is characterized in that, the weight ratio of water-based PVDF fluorine carbon emulsion, water-compatible amino resin, watersoluble closed type aliphatics cyanate prepolymer, modified cycloaliphatic epoxy emulsion is 40-45:10-12:10-14:12-13.5:12-14.5.
6. the water-based fluorocarbon metal baking finish according to any one of claim 1-5, is characterized in that, the weight ratio of benzoyl peroxide, N, N-dimethylethanolamine is 1-1.3:8-8.5.
7. the water-based fluorocarbon metal baking finish according to any one of claim 1-6, is characterized in that, the weight ratio of pigment, water-based PVDF fluorine carbon emulsion is 1.4-1.8:40-45.
8. the water-based fluorocarbon metal baking finish according to any one of claim 1-7, it is characterized in that, its raw material comprises by weight: water-based PVDF fluorine carbon emulsion 40-45 part, water-compatible amino resin 10-12 part, watersoluble closed type aliphatics cyanate prepolymer 12-13.5 part, modified cycloaliphatic epoxy emulsion 12-14.5 part, benzoyl peroxide 1-1.3 part, N, N-dimethylethanolamine 8-8.5 part, water 40-46 part, phenylcarbinol 35-38 part, pigment 1.4-1.8 part, organic zinc complex anti-sudden strain of a muscle rust agent 1.4-1.6 part, modification mono amino monocycle TMOS 1.2-1.5 part, wetting dispersing agent 1.6-1.8 part, defoamer 1-1.3 part, flow agent 1.2-1.35 part, thickening material 2-2.6 part.
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| CN201510831212.9A CN105368181A (en) | 2015-11-24 | 2015-11-24 | Waterborne fluorocarbon metal baking paint |
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| CN201510831212.9A CN105368181A (en) | 2015-11-24 | 2015-11-24 | Waterborne fluorocarbon metal baking paint |
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| CN110903714A (en) * | 2019-11-08 | 2020-03-24 | 无锡华东锌盾科技有限公司 | High-temperature-resistant water-based fluorocarbon amino baking paint and preparation method thereof |
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