CN105363483A - Preparation method of titanium dioxide nanowire/two-dimensional layered titanium carbide composite material - Google Patents

Preparation method of titanium dioxide nanowire/two-dimensional layered titanium carbide composite material Download PDF

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CN105363483A
CN105363483A CN201510908417.2A CN201510908417A CN105363483A CN 105363483 A CN105363483 A CN 105363483A CN 201510908417 A CN201510908417 A CN 201510908417A CN 105363483 A CN105363483 A CN 105363483A
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mxene
alc
nanowire
preparation
dimensional layer
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朱建锋
吕文静
汤祎
杨晨辉
王芬
曹敏娟
李学林
卫丹
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Shaanxi University of Science and Technology
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Shaanxi University of Science and Technology
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Abstract

The invention provides a preparation method of a titanium dioxide nanowire/two-dimensional layered titanium carbide composite material. The preparation method comprises the following steps: high energy ball milling is carried out on high-purity ternary layered Ti3AlC2 powder for grain refinement; two-dimensional layered nano-material MXene-Ti3C2 is prepared by hydrofluoric acid eroding treatment; and hydro-thermal treatment is carried out on MXene-Ti3C2 and P25 under alkaline condition to make nanowire-type TiO2 to be loaded with MXene-Ti3C2, so as to obtain the nanowire-type TiO2/MXene-Ti3C2 nanocomposite material. Nontoxic raw materials are used, the preparation process is simple, the technology is controllable, and costs are low. The prepared two-dimensional layered MXene-Ti3C2 is uniform, TiO2 nanowires are long and thin and uniformly distributed. Thus, the composite material has large specific surface area, good conductivity, good photocatalytic performance and good biocompatibility, and is applicable to the fields of photocatalysis, wastewater treatment, lithium ion battery, biosensor and the like.

Description

The preparation method of a kind of titanium dioxide nano thread/two-dimensional layer titanium carbide composite
Technical field
The invention belongs to nano-functional material preparing technical field, the preparation method of particularly a kind of titanium dioxide nano thread/two-dimensional layer titanium carbide composite.
Background technology
Two-dimensional layer nano-carbide is the material of a kind graphene-structured, and it is obtained through selective corrosion by ternary layered compound.In recent years, this material is because its electric conductivity is strong, pliability is good, diffusion coefficient is low, and capacitance is high, and has the extensive concern that the advantages such as individual layer atomic sheet structure and good stability receive researcher.Research shows, two-dimensional layer nano titanium carbide has important application prospect in fields such as electrochemical capacitor, lithium battery, Pb atomic adsorption, Chu Qing and precious metal catalyst agent carriers.
Titanium dioxide has wide application in solar cell, photocatalysis, photocatalytic water, sensor, coating, function ceramics, high-grade paint etc.Because photo-generated carrier axially can carry out the migration growing distance at the titanium dioxide of 1-dimention nano line structure, and it is easier from internal migration to surface, decrease the probability of hole and electron recombination, can improve its be applied to photocatalysis, photocatalytic water and solar cell time efficiency.Titanium dioxide nano thread diameter is very thin, and quantum optical field occurs, the bandwidth of titanium dioxide is strengthened, has stronger redox ability, have large specific area, stronger adsorption capacity, and these all contribute to titanium-dioxide photo electrical property and improve.
Single two-dimensional nano MXene-Ti 3c 2specific area is little, and pattern is single, and hydrophily is poor, and photocatalytic degradation difficulty is large.
Summary of the invention
In order to overcome the defect of above-mentioned prior art, the object of the present invention is to provide the preparation method of a kind of titanium dioxide nano thread/two-dimensional layer titanium carbide composite, have technical process simple, be easy to operate control, cost is low, pollution-free, synthesis of titanium dioxide nanowire diameter is little, the feature that is evenly distributed.
To achieve these goals, the technical solution used in the present invention is:
A preparation method for nanowire-type titanium dioxide/two-dimensional layer titanium carbide composite, comprises the steps:
Step one, refinement powder
High-energy ball milling refinement purity is utilized to be greater than the ternary layered Ti of 97wt% 3alC 2ceramic powder batch mixing, ball milling condition: the mass ratio of ballstone, batch mixing and ball-milling medium is 10:1:1, and rotational speed of ball-mill is 400r/min, and High Energy Ball Milling Time is 1h ~ 4h, then gained solid-liquid batch mixing is dried at 40 DEG C ~ 60 DEG C, obtain particle diameter at the Ti of 8 μm-75 μm 3alC 2ceramic powder;
Step 2, two-dimensional layer nano material MXene-Ti 3c 2preparation
By gained Ti in step one 3alC 2ceramic powder is immersed in HF acid solution, wherein 2g ~ 10gTi 3alC 2powder is immersed in 50mL ~ 200mL mass concentration 35wt% ~ 45wt%HF acid solution, reaction 6h ~ 120h; Magnetic agitation, to Ti 3alC 2after ceramic powder carries out corrosion treatmentCorrosion Science, be 5 ~ 7 by deionized water eccentric cleaning to pH, by gained solid sample drying at room temperature, obtain two-dimensional layer nano material MXene-Ti 3c 2;
Step 3, hydrothermal treatment consists
Get step 2 gained two-dimensional layer nano material MXene-Ti 3c 2naOH50 ~ the 70ml of 200 ~ 300mg, P258 ~ 10mg, 10mol/L, is placed in water heating kettle and reacts 18 ~ 24h at 130 ~ 180 DEG C, then use washed with de-ionized water, finally 40 ~ 60 DEG C of oven dry, obtains nanowire-type TiO 2/ MXene-Ti 3c 2nano composite material; Its TiO 2nanowire diameter is less than 10nm, MXene-Ti 3c 2synusia thickness is about 50nm.
Described ball-milling medium is absolute ethyl alcohol.
Beneficial effect of the present invention:
In acid solution after corrosion treatmentCorrosion Science, drying at room temperature removes MXene-Ti 3c 2outermost adsorbed water, and MXene-Ti 3c 2also store the oxygen molecule in a large amount of physical absorption hydrone and the aqueous solution between interlayer, make surperficial Ti terminal generation oxidation reaction under uniform temperature and PH, thus obtain nanowire-type TiO 2, load TiO 2nano wire is to two-dimensional layer material MXene-Ti 3c 2on, the specific area of composite is larger, and has TiO 2some characteristics, as photocatalytic degradation, one's own physical property, pattern is various, therefore nanowire-type TiO 2/ MXene-Ti 3c 2the performance of nano composite material is more better than single MXene-Ti 3c 2, its application will be more extensive.For further in the application in the fields such as ultracapacitor, lithium ion battery, biology sensor, nano adsorber, photocatalysis, wastewater treatment, carry out the preparation work of predecessor.
By Ti 3alC 2in HF acid, carry out chemical etching, Al is etched away by selective, form a kind of two-dimensional layer material MXene-Ti 3c 2, then hydrothermal treatment consists, at two-dimensional layer material MXene-Ti 3c 2upper loaded with nano line style TiO 2, the specific area of stratified material is increased, and makes material have photocatalytic degradation, one's own physical property, the characteristics such as pattern is various, therefore, nanowire-type TiO 2/ MXene-Ti 3c 2the performance of nano composite material is more better than single MXene-Ti 3c 2, its application will be more extensive.
Accompanying drawing explanation
Fig. 1 is Ti 3alC 2before powder corrosion treatmentCorrosion Science, after corrosion treatmentCorrosion Science and corrosion product oxidation XRD collection of illustrative plates.
Fig. 2 is Ti 3alC 2the corrosion product MXene-Ti of powder 3c 2the SEM figure of sample after loaded with nano line style titanium oxide under different enlargement ratio; Fig. 2 a is Ti 3alC 2the corrosion product MXene-Ti of powder 3c 2the SEM figure of sample after loaded with nano line style titanium oxide under 2.00um enlargement ratio; Fig. 2 b is Ti 3alC 2the corrosion product MXene-Ti of powder 3c 2the SEM figure of sample after loaded with nano line style titanium oxide under 1.00um enlargement ratio; Fig. 2 c is Ti 3alC 2the corrosion product MXene-Ti of powder 3c 2the SEM figure of sample after loaded with nano line style titanium oxide under 500nm enlargement ratio.
Detailed description of the invention
Below in conjunction with accompanying drawing and embodiment, the present invention is described in further details.
Embodiment 1
1) refinement powder
High-energy ball milling refinement purity is utilized to be greater than the ternary layered Ti of 97wt% 3alC 2ceramic powder, ball milling condition: the mass ratio of ballstone, batch mixing and absolute ethyl alcohol is 10:1:1, and rotational speed of ball-mill is 400r/min, and High Energy Ball Milling Time is 4h, is then dried at 50 DEG C by gained solid-liquid batch mixing, obtains the Ti that particle diameter is 10 ± 2 μm 3alC 2ceramic powder; See Fig. 1, in Fig. 1, XRD collection of illustrative plates describes the thing of gained powder is Ti mutually 3alC 2crystal, and impurity content is few.
2) two-dimensional layer nano material MXene-Ti 3c 2preparation
By step 1) middle gained Ti 3alC 2ceramic powder is immersed in HF acid solution, wherein 5gTi 3alC 2powder is immersed in 100mL mass concentration 40wt%HF acid solution and reacts 48h; Magnetic agitation, to Ti 3alC 2after ceramic powder carries out corrosion treatmentCorrosion Science, be 5 ~ 6 by deionized water eccentric cleaning to pH, by gained solid sample drying at room temperature, obtain two-dimensional layer nano material MXene-Ti 3c 2; See Fig. 1, wherein XRD collection of illustrative plates indicates Ti 3alC 2the change of diffraction maximum, contrasts with the XRD diffracting spectrum of theory calculate, successfully obtains MXene-Ti 3c 2powder thing phase.
3) hydrothermal treatment consists
Get step 2) gained two-dimensional layer nano material MXene-Ti 3c 2the NaOH60ml of 300mg, P2510mg, 10mol/L, is placed in water heating kettle and reacts 24h at 180 DEG C, spend Ion Cleaning, dry, then 50 DEG C of oven dry.Obtain nanowire-type TiO 2/ MXene-Ti 3c 2nano composite material.See Fig. 1, wherein XRD collection of illustrative plates indicates nanowire-type TiO 2crystal successfully loads to MXene-Ti 3c 2on powder.See Fig. 2, wherein SEM figure shows TiO 2/ MXene-Ti 3c 2the microscopic appearance of composite, its TiO 2nanowire diameter is less than 10nm, and is evenly distributed, and loads to MXene-Ti well 3c 2in two-dimensional layer nano material, form novel Detitanium-ore-type TiO 2/ MXene-Ti 3c 2nano composite material.
Embodiment 2
1) refinement powder
High-energy ball milling refinement purity is utilized to be greater than the ternary layered Ti of 97wt% 3alC 2ceramic powder, ball milling condition: the mass ratio of ballstone, batch mixing and absolute ethyl alcohol is 10:1:1, and rotational speed of ball-mill is 400r/min, and High Energy Ball Milling Time is 2h, is then dried at 50 DEG C by gained solid-liquid batch mixing, obtains the Ti that particle diameter is 56 ± 5 μm 3alC 2ceramic powder;
2) two-dimensional layer nano material MXene-Ti 3c 2preparation
By step 1) middle gained Ti 3alC 2ceramic powder is immersed in HF acid solution, wherein 2gTi 3alC 2powder is immersed in 50mL mass concentration 45wt%HF acid solution and reacts 12h; Magnetic agitation, to Ti 3alC 2after ceramic powder carries out corrosion treatmentCorrosion Science, be 5 ~ 6 by deionized water eccentric cleaning to pH, by gained solid sample drying at room temperature, obtain two-dimensional layer nano material MXene-Ti 3c 2;
3) hydrothermal treatment consists
Get step 2) gained two-dimensional layer nano material MXene-Ti 3c 2the NaOH50ml of 200mg, P2510mg, 10mol/L, is placed in water heating kettle and reacts 24h at 130 DEG C, spend Ion Cleaning, dry, then 40 DEG C of oven dry; Obtain nanowire-type TiO 2/ MXene-Ti 3c 2nano composite material.
Embodiment 3
1) refinement powder
High-energy ball milling refinement purity is utilized to be greater than the ternary layered Ti of 97wt% 3alC 2ceramic powder, ball milling condition: the mass ratio of ballstone, batch mixing and absolute ethyl alcohol is 10:1:1, and rotational speed of ball-mill is 400r/min, and High Energy Ball Milling Time is 2h, is then dried at 50 DEG C by gained solid-liquid batch mixing, obtains the Ti that particle diameter is 75 μm 3alC 2ceramic powder;
2) two-dimensional layer nano material MXene-Ti 3c 2preparation
By step 1) middle gained Ti 3alC 2ceramic powder is immersed in HF acid solution, wherein 2gTi 3alC 2powder is immersed in 40mL mass concentration 49wt%HF acid solution and reacts 6h; Magnetic agitation, to Ti 3alC 2after ceramic powder carries out corrosion treatmentCorrosion Science, be 5 ~ 6 by deionized water eccentric cleaning to pH, by gained solid sample drying at room temperature, obtain two-dimensional layer nano material MXene-Ti 3c 2;
3) hydrothermal treatment consists
Get step 2 respectively) gained MXene-Ti 3c 2the NaOH30ml of 300mg, P2510mg, 10mol/L, is placed in water heating kettle and reacts 24h at 150 DEG C, spend Ion Cleaning, dry, then 40 DEG C of oven dry; Obtain nanowire-type TiO 2/ MXene-Ti 3c 2nano composite material.
Embodiment 4
1) refinement powder
High-energy ball milling refinement purity is utilized to be greater than the ternary layered Ti of 97wt% 3alC 2ceramic powder, ball milling condition: ballstone, the mass ratio of batch mixing and absolute ethyl alcohol is 10:1:1, and rotational speed of ball-mill is 400r/min, and High Energy Ball Milling Time is 2h, is then dried at 50 DEG C by gained solid-liquid batch mixing, obtains the Ti that particle diameter is 56 ± 10 μm 3alC 2ceramic powder;
2) two-dimensional layer nano material MXene-Ti 3c 2preparation
By step 1) middle gained Ti 3alC 2ceramic powder is immersed in HF acid solution, wherein 2gTi 3alC 2powder is immersed in 50mL mass concentration 45wt%HF acid solution and reacts 6h; Magnetic agitation, to Ti 3alC 2after ceramic powder carries out corrosion treatmentCorrosion Science, be 5 ~ 6 by deionized water eccentric cleaning to pH, by gained solid sample drying at room temperature, obtain two-dimensional layer nano material MXene-Ti 3c 2;
3) hydrothermal treatment consists
Get step 2 respectively) gained two-dimensional layer nano material MXene-Ti 3c 2the NaOH60ml of 300mg, P2512mg, 10mol/L, is placed in water heating kettle and reacts 24h at 160 DEG C, spend Ion Cleaning, dry, then 50 DEG C of oven dry; Obtain nanowire-type TiO 2/ MXene-Ti 3c 2nano composite material.
Embodiment 5
1) refinement powder
High-energy ball milling refinement purity is utilized to be greater than the ternary layered Ti of 97wt% 3alC 2ceramic powder, ball milling condition: the mass ratio of ballstone, batch mixing and absolute ethyl alcohol is 10:1:1, and rotational speed of ball-mill is 400r/min, and High Energy Ball Milling Time is 2h, is then dried at 50 DEG C by gained solid-liquid batch mixing, obtains the Ti that particle diameter is 60 ± 10 μm 3alC 2ceramic powder;
2) two-dimensional layer nano material MXene-Ti 3c 2preparation
By step 1) middle gained Ti 3alC 2ceramic powder is immersed in HF acid solution, wherein 5gTi 3alC 2powder is immersed in 100mL mass concentration 40wt%HF acid solution and reacts 48h; Magnetic agitation, to Ti 3alC 2after ceramic powder carries out corrosion treatmentCorrosion Science, be 5 ~ 6 by deionized water eccentric cleaning to pH, by gained solid sample drying at room temperature, obtain two-dimensional layer nano material MXene-Ti 3c 2; See Fig. 1, wherein XRD collection of illustrative plates indicates Ti 3alC 2the change of diffraction maximum, contrasts with the XRD diffracting spectrum of theory calculate, successfully obtains MXene-Ti 3c 2powder thing phase.
3) hydrothermal treatment consists
Get step 2) gained two-dimensional layer nano material MXene-Ti 3c 2the NaOH40ml of 250mg, P2512mg, 10mol/L, is placed in water heating kettle and reacts 20h at 150 DEG C, spend Ion Cleaning, then 60 DEG C of oven dry; Obtain nanowire-type TiO 2/ MXene-Ti 3c 2nano composite material.

Claims (2)

1. a preparation method for nanowire-type titanium dioxide/two-dimensional layer titanium carbide composite, comprises the steps:
Step one, refinement powder
High-energy ball milling refinement purity is utilized to be greater than the ternary layered Ti of 97wt% 3alC 2ceramic powder batch mixing, ball milling condition: the mass ratio of ballstone, batch mixing and ball-milling medium is 10:1:1, and rotational speed of ball-mill is 400r/min, and High Energy Ball Milling Time is 1h ~ 4h, then gained solid-liquid batch mixing is dried at 40 DEG C ~ 60 DEG C, obtain particle diameter at the Ti of 8 μm-75 μm 3alC 2ceramic powder;
Step 2, two-dimensional layer nano material MXene-Ti 3c 2preparation
By gained Ti in step one 3alC 2ceramic powder is immersed in HF acid solution, wherein 2g ~ 10gTi 3alC 2powder is immersed in 50mL ~ 200mL mass concentration 35wt% ~ 45wt%HF acid solution, reaction 6h ~ 120h; Magnetic agitation, to Ti 3alC 2after powder carries out corrosion treatmentCorrosion Science, be 5 ~ 7 by deionized water eccentric cleaning to pH, by gained solid sample drying at room temperature, obtain two-dimensional layer nano material MXene-Ti 3c 2;
Step 3, hydrothermal treatment consists
Get step 2 gained two-dimensional layer nano material MXene-Ti 3c 2naOH50 ~ the 70ml of 200 ~ 300mg, P258 ~ 10mg, 10mol/L, is placed in water heating kettle and reacts 18 ~ 24h at 130 ~ 180 DEG C, then use washed with de-ionized water, finally 40 ~ 60 DEG C of oven dry, obtains nanowire-type TiO 2/ MXene-Ti 3c 2nano composite material; Its TiO 2nanowire diameter is less than 10nm, MXene-Ti 3c 2synusia thickness is about 50nm.
2. the preparation method of a kind of nanowire-type titanium dioxide/two-dimensional layer titanium carbide composite according to claim 1, it is characterized in that, described ball-milling medium is absolute ethyl alcohol.
CN201510908417.2A 2015-12-09 2015-12-09 Preparation method of titanium dioxide nanowire/two-dimensional layered titanium carbide composite material Pending CN105363483A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6517804B1 (en) * 2000-02-29 2003-02-11 Korea Atomic Energy Institute TiO2 ultrafine powder, and process for preparing thereof
CN103545491A (en) * 2013-09-25 2014-01-29 东莞市翔丰华电池材料有限公司 Preparation method of graphene/titanium dioxide composite material for lithium ion battery cathode material
CN104495918A (en) * 2014-12-23 2015-04-08 陕西科技大学 Method for preparing granular titanium dioxide/two-dimensional nano-titanium carbide composite material
CN104529455A (en) * 2014-12-23 2015-04-22 陕西科技大学 Low-temperature preparation method of titanium dioxide/two-dimensional layered titanium carbide composite material
CN104941621A (en) * 2015-05-26 2015-09-30 华南理工大学 Composite photocatalyst for efficiently degrading antibiotics as well as preparation method and application thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6517804B1 (en) * 2000-02-29 2003-02-11 Korea Atomic Energy Institute TiO2 ultrafine powder, and process for preparing thereof
CN103545491A (en) * 2013-09-25 2014-01-29 东莞市翔丰华电池材料有限公司 Preparation method of graphene/titanium dioxide composite material for lithium ion battery cathode material
CN104495918A (en) * 2014-12-23 2015-04-08 陕西科技大学 Method for preparing granular titanium dioxide/two-dimensional nano-titanium carbide composite material
CN104529455A (en) * 2014-12-23 2015-04-22 陕西科技大学 Low-temperature preparation method of titanium dioxide/two-dimensional layered titanium carbide composite material
CN104941621A (en) * 2015-05-26 2015-09-30 华南理工大学 Composite photocatalyst for efficiently degrading antibiotics as well as preparation method and application thereof

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