CN105358121B - Skin preparations for extenal use - Google Patents
Skin preparations for extenal use Download PDFInfo
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- CN105358121B CN105358121B CN201480038051.1A CN201480038051A CN105358121B CN 105358121 B CN105358121 B CN 105358121B CN 201480038051 A CN201480038051 A CN 201480038051A CN 105358121 B CN105358121 B CN 105358121B
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- hot spring
- sediment
- alum
- surflaes
- spring sediment
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/965—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
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Abstract
The present invention provides a kind of hot spring sediment progress purifying and liquefying to from the sulphur spring containing alum and the skin preparations for extenal use applied to purposes such as bath agent, toner and alleviation skin diseases.It includes the filtrates obtained as follows：The hot spring sediment for generating sulphur spring steam and the argillic horizon containing alum is dispersed in water, and the surflaes after using in hot spring sediment generation is filtered the dispersion liquid as filtering material.The hot spring sediment is individually red, golden yellow, white hot spring sediment, or be mixture obtained from being suitably combined to these two or more hot spring sediments, it is made and packaging in the non-woven bag of the hot spring sediment when the filtering material can be filled in sale alum hot spring sediment.
Description
Technical field
It is especially more to ferrous components the present invention relates to a kind of hot spring sediment that will derive from the sulphur spring containing alum
And show the red hot spring sediment that general user keeps someone at a respectful distance and carry out purifying and liquefying, and be applied to bath agent, toner, with
And alleviate the skin preparations for extenal use of the purposes such as skin disease.
Background technique
In general, alum spring, iron alum spring are utilized as shoulder stiffness, traumatic injury, contusion, pain in the loins, mind since ancient times
The hot spring treatment method of the hot spring treatment method and eczema of dysmenorrhoea, rheumatism etc., prickly heat, frostbite, hemorrhoid, erosion etc..
Various composition contained by toner is set to infiltrate into deep skin additionally, it is well known that alum or iron alum also have
Effect, and protect the effect etc. of the hair impaired due to ultraviolet light or drying.
In order to which effect of above-mentioned alum spring etc. can be obtained at home, hot spring without removing alum spring etc., generally
The hot spring sediment that the generation of these hot springs can be acquired, is dissolved in home-use water for bathing, is made containing alum, iron alum
Water for bathing.
In addition, so far, proposing：Including the mineral water containing specific ion, containing alum, green vitriol more than one
Hot spring sediment or the hot spring sediment solvent extractable matter more than one, also contain citrate or Vitamin C
The skin preparations for extenal use (patent document 1) of hydrochlorate；It and using hot spring sediment as raw material, and include sulfate ion in particular range
And ferric ion, also comprising the external preparation for skin group selected from one or more of aluminium ion, magnesium ion, sodium ion and calcium ion
At object (patent document 2).
It records in patent document 1：Inhibit test, antibacterial tests it is found that the external preparation stability is good by lipase
It is good, and there is lipase inhibition and antibacterial action, it is disclosed in patent document 2 thin along with the generation of cell factor and fibrous bud
The cell-activating of the proliferation of born of the same parents acts on, it follows that hot spring sediment is effective as skin preparations for extenal use.
The manufacture of the hot spring sediment of the alum hot spring in the city Bie Fu of the county great Fen has carried out from the river family epoch, manufacturing method
It is as follows：In order to prevent wind and weather, be easily formed the environment of hot spring sediment crystallization, and hot spring sediment cabin is built,
It (is acquired inside it from the alum mineral ore near the hot spring of other mansion, band using spray vapour (from the steam of sulphur spring) and blue clay
Have blue) crystallization (referred to as " copiapite ") of manufacture hot spring sediment, the hot spring sediment obtained by the manufacturing method is (referred to as
" alum hot spring sediment ") it can be used as bath agent.
One band of alum hot spring at other mansion, there are warm water (sulphur spring) arteries and veins at the about 30cm of the underground of geothermal area, everywhere
See that the steam of hot spring (sulphur spring origin) rapidly sprays.In hot spring sediment cabin, vapour will be sprayed using scoop or mallet
With the surrounding 60m for the jetted hole that intensity sprays2The smooth reinforcing in left and right, and as ground, it is laid on the surface of the ground
Handstone lays straw so that spray vapour is sprayed with certain intensity on it, and its topmost laying about 15cm thickness from
The blue clay acquired on mountain near the other mansion alum hot spring of Japan and reinforcing.
About alum hot spring sediment crystallization process, firstly, sulphur spring spray vapour in soil, small stone, straw layer on
Water is condensed into the way risen.At the same time, hydrogen sulfide and sulphurous acid gas included in the spray vapour are oxidized into sulfuric acid, are dissolved in
In the water.When it ascends into blue clay layer, is then reacted with aluminium contained in blue clay and iron and become sulfate, and with crystallization
Form occur on the surface.10 days or so, the crystallization of sulfate, i.e. alum hot spring sediment blue clay Surface Creation,
But the hot spring sediment initially generated contains a large amount of impurities, and therefore, first without acquisition, but is carried out by mallet etc. to it
It reinforces.Using 30 days or so, when hot spring sediment generates again, the less white portions such as impurity is only chosen, mud watt is utilized
The scraping such as trowel or wooden stick of craftsman.The hot spring sediment (powdered) of scraping, which is placed into the container of good air permeability, to be saved,
It is provided in the form of parcel packing etc. as washing one's hair baths.
Blue clay used in the manufacture of the alum hot spring sediment can be for 5~6 alum temperature after being applied on the ground
The generating process of spring sediment uses, but iron gradually decreases in clay, and the ratio of aluminium sulfate is increase accordingly, moreover, if aluminium
When inadequate, then silica can preferentially be precipitated.In this way, being extracted to institute's iron content or aluminium etc. in blue clay, and will be used
Blue clay is discarded as blue clay surflaes, the blue clay more renewed.
Further it is proposed that a kind of bath constituted with the filtered fluid obtained as follows is with additive (patent document 3)：It first will be by
The one of " with alum hot spring sediment as main component " and " comprising with the clay of alum hot spring sediment as main component "
Kind or two or more constituted alum contain object into the water, and are filtered to it.Come from the record of patent document 3
It sees, it is difficult to fully understand the overall picture of the technological maheup of the bath additive, lack repeatable (reproducibility, continuity).For example,
It in the document, also describes " comprising with one or two kinds of above institute of the clay of alum hot spring sediment as main component
The alum of composition contains object " it refers to " as to be glued used in the generation method of alum hot spring sediment as main component
Soil " should be interpreted that from the point of view of the record：Alum hot spring sediment is generated on blue clay, but the hot spring of generation is not sunk
Starch is scraped from blue clay, but will adhere to the blue clay of the state of the hot spring sediment into the water, and the water is filtered,
But it can not understand the technical meaning that alum hot spring sediment is further mixed into the blue clay.But 2 (this part of claim
In, as patent《Patent document 4》) and embodiment in, charcoal powder is also mixed with, so there are charcoal powder adsorptions
Whether the possibility for removing the useful component in alum hot spring sediment, be handed down in the filtrate there is also the Congjiang family epoch
The drug effect of alum hot spring sediment is also a query.
Existing technical literature
Patent document
Patent document 1:Special open 2002-326942 bulletin
Patent document 2:Special open 2006-193447 bulletin
Patent document 3:Japanese Laid-Open Patent Publication 9-30955 bulletin
Patent document 4:No. 3105153 bulletins of patent
Summary of the invention
The technical problems to be solved by the invention
As described above, being expected to have medicative alum hot spring sediment (powdered) in the past in home-use bathtub
Water for bathing (generally 2 more than hundred decaliters《Below, it rises and is denoted as L, milliliter is denoted as mL》Left and right) for example come into operation 5g~10g or so.
But direct plunge into the powder of alum hot spring sediment in bathtub in the method for water for bathing, there are the following problems：
Hot spring sediment cannot be fully dispersed, and dissolution cannot obtain sufficient drug effect, or remain in water for bathing after the shower it is heavy
Starch, it is impossible to be used in washing machine, sometimes there is also block the inconvenience such as pipeline due to Shen hall object.
Moreover, making full use of the natural resources as far as possible from the viewpoint of environmental protection, the amount of reduction waste as far as possible
Also it is very important requirement.
The technical problem to be solved in the present invention is that：A kind of skin preparations for extenal use is provided in order to solve problems described above,
Ingredient included in the hot spring sediment can be reliably transferred to water for bathing etc. using alum hot spring sediment as raw material by it
In, while being the liquid being easily processed, and there is reliable reproducibility, due to use as efficiently as possible natural resources from
And discarding amount is greatly decreased.
For solving the technical solution of technical problem
When solving above-mentioned technical problem, the present inventor has obtained following opinion.
(1) include and the spray from sulphur spring using the blue clay (surflaes) finished in the generation of alum hot spring sediment
The reaction product that sulfur component in vapour reacts i.e. sulfuric acid, and be largely discharged, but so far, the utilization of the surflaes
The record of method only has documented method in patent document 3, but has no to repeat continuity.
Present inventor carries out the following studies the residual soil characteristics to make full use of the surflaes.By above-mentioned surflaes
It is dispersed in water on a small quantity, instills ferric chloride solution (commercially available reagent) wherein, as a result, the yellowish-brown moment of iron chloride subsides.
This is because there is the blue clay surflaes strong reducing action to be not only in above patent document 3 about the strong reducing power of the surflaes
And it is unaware that this point, or even be totally unknown in the past.
(2) on the other hand, alum hot spring sediment is generally divided into the white containing less ferrous components, containing more iron point
Red and iron content it is placed in the middle it is golden yellow these three, be dispersed in water, then become it is red, golden yellow needless to say, even white
Colour temperature spring sediment can also make dispersion liquid integral colouring bronzing~yellowish-brown.The bronzing~yellowish-brown ingredient is obviously
From the ingredient of iron compound, using the reducing power of the blue clay surflaes of above-mentioned (1), iron compound is reduced to ferrous chemical combination
Object, bronzing~yellowish-brown, which will fade, even to disappear.
(3) therefore, a large amount of indigo plants are added in the filemot liquid that is formed to water is dispersed by alum hot spring sediment
When clay surflaes, the yellowish-brown for confirming the liquid generated by iron ion is only a little, has faded.But surflaes has in water
There is insoluble or solubility low, surflaes bring brown particle is scattered in liquid, and liquid will not be colorless and transparent.
(4) present inventor conducts in-depth research, in order to attempt to remove above-mentioned brown particulate as a result, it was confirmed that above-mentioned
All there are following situations for three kinds of hot spring sediments：Only to as described in Patent Document 3 into disperse water after investment blue clay surflaes
When liquid is filtered, not only filtering expends the time, but also fading effect is very small.The feelings of especially red hot spring sediment
Under condition, if largely using blue clay surflaes, although fading effect is improved to some extent, but filtering is extremely difficult, very
To be impossible, make blue clay surflaes disperse method, it becomes virtually impossible to so that liquid is become colorless and transparent.
(5) present inventor converts idea, uses using blue clay surflaes as filtering material, to above-mentioned three kinds of hot spring sediments
Disperse water is filtered, and as a result confirming three kinds of hot spring sediments, all there are following situations：Even if the usage amount of blue clay surflaes is not
More, filtered fluid also can sufficiently fade, and become colorless and transparent.
(6) it can be learnt from above-mentioned (3)~(5)：For contained bronzing~yellowish-brown in three kinds of alum hot spring sediments
Ingredient, if carried out using blue clay surflaes as filter material to the dispersion liquid of red, golden yellow, white alum hot spring sediment
When filtering, then it can be sufficiently carried out reduction and fade, and obtain colorless and transparent filtrate.
Skin of the invention with external preparation is completed based on conclusions.
(1) it is characterized in that, it includes the filtrates obtained as follows：
The hot spring sediment for generating sulphur spring steam and the argillic horizon containing alum is dispersed in water, and by the temperature
Surflaes after using in the generation of spring sediment is filtered the dispersion liquid as filter material.
(2) the hot spring sediment is individually red, golden yellow, white hot spring sediment, or is suitably right
Mixture obtained from these two or more hot spring sediments are combined,
(3) clay containing alum is acquired from the other mansion alum hot spring of Japan, and the hot spring sediment is to make day
Individually red as obtained from the argillic horizon, golden yellow, white the temperature of the sulphur spring steam sprayed in this other mansion alum hot spring
Spring sediment or two or more combined mixtures.
(4) in addition, above-mentioned filtering material packs the hot spring sediment when can also be filled in sale alum hot spring sediment
Non-woven fabrics made of in bag.
The effect of invention
If skin of the invention uses external preparation to use as home-use baths of washing one's hair, surely not generating will be existing
It generates when the water for bathing that powdered alum hot spring sediment is put into bathtub to filemot discoloration, without sediment, and can
The same effect of the case where obtaining with by existing powdered alum hot spring sediment investment water for bathing.
In addition, skin preparations for extenal use of the invention, which can also be used as toner, skin disease medicament, their raw material etc., to be made
With all with certain effect in terms of the sterilization of skin and skin makeup effect.
In addition, the raw material of skin external preparation of the invention passes on alum hot spring so far all through the Congjiang family epoch
It, therefore, also can be by using the external preparation extremely in the place far from the hot spring ground obtained by the manufacturing process of sediment
It is readily derived effect same with the alum soup in the city Bie Fu of the county great Fen.
Moreover, in particular, even general user is keeping someone at a respectful distance, reluctant red hot spring sediment, the present invention
Skin also effectively it can be carried out with external preparation using, make full use of i.e. by depleted natural resources in terms of,
With remarkable result.
Specific embodiment
In the present invention, the hot spring sediment of the existing structure used always using the alum hot spring in the city Bie Fu of the county great Fen is small
Substance obtained from the hot spring sediment for generating sulphur spring steam and the argillic horizon containing alum is scraped in room.
In addition, the surflaes finished used in the generation that hot spring sediment cabin acquires the alum hot spring sediment,
Then, in the present invention, the surflaes of solarization usual in the date not rained about one day~after a week is used.At night, in order to prevent
Dew attachment, is put within doors, or the measures such as covering waterproof membrane (water-proofing treatment), in fact, daytime about 7~9
Solarization → night of hour is put into (or water-proofing treatment) within doors, observes the state of surflaes, and repeat about one day~mono- week (plum
When humidity are big after rain period or rain etc., containing many moisture, drying in about one week is needed, but such dry season in winter
In section, drying in one day or so is enough).
Alternatively, the rotation of 1~50rpm or so can be applied, and can root under normal pressure, room temperature (15~35 DEG C or so)
According to needing to be aerated (at normal temperature to the air progress air blast of surrounding) etc., force drying is carried out, to replace solarization.It carries out strong
As long as time when system is dry is set by above-mentioned one day~mono- week and on the basis of 7~9 hours daily.
Drying process in this way, 10~70% of the surflaes weight (average 1~2kg/L) after just acquisition can be reduced
The left and right (average 0.3~1.8kg/L).
In the present invention, to be using the reasons why slow drying means as described above：Because above-mentioned surflaes include sulphur at
Point, the force drying carried out under high temperature and pressure can be such that sulfur component largely evaporates, and react and generate with the moisture in air
Toxic component not only makes a very bad impression to operating environment, also will be greatly reduced the useful properties i.e. reproducibility (reduction of surflaes
Power), this is to remove large quantity of moisture to inhibit sulfur component to spread into atmosphere as far as possible.
In addition, removing moisture from surflaes is to be easier to carry out filter operation when using surflaes as filtering material
(when the amount of moisture of surflaes is more, the rate of filtration is extremely low when being used as filtering material, and filter operation sometimes becomes to can be carried out), and
It is more effectively carried out ingredient in surflaes (especially solid) and the contact of the bronzing in dispersion liquid~yellowish-brown ingredient.
It should be noted that the mentioned component (being speculated as sulfur compound) in solid also exists along with the evaporation of moisture
It distils to a certain extent, this can reduce decolourization caused by the ingredient (being speculated as reduction).Therefore, as described above, it is dry
Dry degree is the 10~70% of the weight of the surflaes after reduction just acquisition.
Above-mentioned alum hot spring sediment (includes the case where individually being red, golden yellow, white and suitable by carrying out
Combination and generate two or more mixtures the case where.Hereinafter, when referring to alum hot spring sediment or hot spring sediment,
If not otherwise specified, be all just identical), with relative to 100 parts by weight of hot spring sediment and water is that 0.1~10L is left
Right ratio, is dispersed in water.
In addition, in the present invention, red refer to total iron according to the measurement of JIS K 010257.4 be about 6800~
The alum hot spring sediment of 7500ppm/L, ferrous iron according to the measurement of 010257.1 remarks 3 of JIS K be about 3000~
The alum hot spring sediment that alum hot spring sediment, the ferric iron of 3700mg/L is about 3100~4500mg/L according to difference meter,
Golden yellow refers to total iron with above-mentioned JIS measurement about the alum hot spring sediment of 4000~4600mg/L, ferrous iron according to upper
Stating JIS measurement is about the alum hot spring sediment of 1600~2200mg/L, ferric iron about 1800~3000mg/L in terms of the difference
Alum hot spring sediment, the alum hot spring that white refers to that total iron is measured as about 1400~2000mg/L according to above-mentioned JIS is heavy
Starch, ferrous iron are measured as the alum hot spring sediment of about 1400~2000mg/L, ferric iron in terms of the difference about according to above-mentioned JIS
For the alum hot spring sediment of 1~9mg/L.
For above-mentioned dispersion liquid, as long as the surflaes for having carried out diminishing processing as described above was carried out as filtering material
Filter.
Above-mentioned surflaes can as described above after slow dry directly in filter device as filtering material carry out using,
But granularity is very small sometimes, or on the contrary, granularity is very big, is not suitable as filtering material sometimes.It is usually used in the present invention
The surflaes obtained as follows：Remove the packaging material i.e. per unit area weight used when can sell by alum hot spring sediment
0.02~0.1g/cm2Non-woven fabrics (the synthetic fibers system such as polyethylene terephthalate) particulate and hole size be 7mm
On the silk screen of × 7mm after remaining big grain.Certainly, after becoming above-mentioned suitable partial size after which is broken,
It may be used as filtering material.
In addition, above-mentioned filtering material can be applied in combination with usually used commercially available sand filtering material.Mode is applied in combination
It is not particularly limited, as long as can be contacted well, filtered well with surflaes, preferably mixing is (uniform
Admixture under use).The suitable mixed proportion of surflaes and sand is surflaes:Sand (weight ratio) ≒ 30:70~70:30.
The mixture of above-mentioned surflaes or the surflaes and commercially available filtering sand can be used as follows：Example
Such as, to used packing timber when alum hot spring sediment collected in the above-mentioned hot spring sediment cabin sold on the market
Material (packaging material of inner wrapping) i.e. non-woven fabrics carry out sewing perhaps by fusion etc. formed it is bag-shaped by above-mentioned surflaes or should
The mixture of surflaes and commercially available filtering sand is enclosed in the bag, and (with dispersion directly in the form of bag or by part of it
The face for the side that liquid contacts at first) it cuts off as filtering material, it is installed on filter device and uses.
Above-mentioned filtering material (includes the case where the case where being only the mixture of surflaes and surflaes and sand.Hereinafter, mentioning filtering
It is all the same when material) usage amount be not particularly limited, generally, it is preferred to which alum hot spring sediment to be dispersed in water and pass through
0.5~10 hour or so the amount that dispersion liquid 1L is filtered.Specifically, it is preferable that alum hot spring sediment 100g is dispersed
Amount i.e. about 100~1500g that dispersion liquid 1L is filtered in 0.1~10L of water and by the above-mentioned time.
In the present invention, it is therefore intended that bronzing will be presented or even colorless and transparent liquid is made in filemot liquid, white
In the case where hot spring sediment, even a small amount of water (specifically, relative to hot spring sediment 100g, water is about 0.1~5L)
Also enough (become hazel muddy water), and by a small amount of surflaes (specifically, relative to above-mentioned dispersion water be about 100~
It 200g) can sufficiently carry out and (obtain colorless and transparent filtrate).
In contrast, preferably a large amount of water is (specifically, relative to hot spring sediment 100g, water 2 in the case where red
~10L or so) and a large amount of surflaes (being specifically, 200~1000g or so relative to the dispersion water), moreover, red feelings
Under condition, preferred cycle filtering (is filtered the obtained filtrate of first filter operation using the surflaes, and by above-mentioned behaviour again
It is repeated 2 times~10 times or so), operation in this way can greatly reduce the turbidity of filtrate, obtain colorless and transparent
Filtrate.
In the case where golden yellow, it can be made colourless with the amount of the water and surflaes placed in the middle of above-mentioned white and red
Bright filtrate.
For the sake of prudent, according to patent document 3, surflaes is dispersed in water together with alum hot spring sediment, and by this point
Dispersion liquid filtering, it is found that when the amount of surflaes is less, will not become it is colorless and transparent, when the amount of surflaes is more, due to filter paper blocking and
It is difficult to be filtered operation, or even operation can not be filtered, this tendency is gradually increased with golden yellow, red sequence.
Therefore, it is found that addition binchotan realization is colorless and transparent from the embodiment of patent document 3.
But as documented by patent document 3, surflaes dissolubility is low, in patent document 3, hot spring sediment and water and residual
When soil is mixed, using the method for being heated to 100 DEG C (in order to improve dissolubility), but hot spring sediment contains a large amount of sulphur
Sulphur ingredient also contains a large amount of sulfur component in surflaes, by 100 DEG C of high-temperature heating, can not only generate a large amount of toxic wave
Hair ingredient, though the unknown brown of reason becomes denseer, is not able to achieve moreover, the experimental result of the present inventor also indicates that
To colourless transparent liquid this purpose.
In the present invention, idea is changed and has learnt：Surflaes is carried out in the form of filtering material, that is, solid using making hot spring
Sediment dispersion liquid normal pressure, room temperature mitigation under the conditions of by solid, the ingredient in solid and the dispersion of hot spring sediment as a result,
(while the reaction, the ultramicron ingredient quilt in the dispersion liquid also has occurred in the contact of brown ingredient and initiation reaction in liquid
Capture the phenomenon on the solid surflaes of the filtering material as similar ingredient composition), and confirming can be by filtered fluid (with solid
The Fluid Contacting of contact) be made it is colorless and transparent.
In order to contact the solid and brown ingredient well, increase circulating filtration number (it is red, with above-mentioned amount into
Row 1~10 time or so；White, 1~3 time or so；Golden yellow number is placed in the middle), preferably make the rate of filtration relatively slowly (it is red, it is above
The amount of stating carries out 1.5~10 hours or so；White, 0.5~3 hour or so；Golden yellow speed is placed in the middle).
The filtering carried out by above-mentioned filtering material is preferably at normal temperatures and pressures the above-mentioned rate of filtration, filtering times, when
So, the filtering being also possible under filtering, pressurization and attraction under the lower filtering of pressurization, attraction are applied in combination.
Think sulfur compound of the reducing power (reduction) of the strength of above-mentioned surflaes in embedment surflaes.This is
By the way that a kind of unique sulfur smoke (Hydrogen Sulphide odour can be issued if being heated as described above to the blue clay surflaes after using
Deng) and confirm.
By the reduction (reduction reaction), the iron compound in alum hot spring sediment becomes ferrous compound, leads to
It crosses the ferrous compound and sulphur is capable of forming colorless and transparent water soluble chelate compound.
Therefore, in skin preparations for extenal use of the invention, a variety of useful components contained in alum hot spring sediment are directly with liquid
The state of body by Household shower bath by comprising that can be readily derived in the other getable function of mansion alum hot spring bath institute of Japan
Effect.
Embodiment
(embodiment 1)
5 alum hot spring sediments are acquired, the blue clay surflaes of scraping is spread out and laid by (blue clay) that should more renew
In on the waterproof cloth on outdoor parking lot (concrete), (am9 is spread out：30) solarization in 5 days has been carried out afterwards.Daily all in pm5：00
Surflaes is covered with waterproof cloth, by all Edge Bends, and is pressed under the waterproof cloth of downside, is fixed with clip.The next morning am9：30
Reinflated carry out solarization, and calculate the removal operation that the time carries out the waterproof cloth.
Further, since being the rainy day between the 4th day and the 5th day, therefore, according to weather forecast in the 4th day, at the 4th day
Solarization after, will be moved within doors together with its waterproof cloth with downside, carry out solarization in the 5th day again every two days.
Blue clay after the solarization for completing the 5th day is struck as blue clay surflaes, and by the big grain of the surflaes with mallet
It is broken, and by the surflaes for the net that the size of through hole is 7mm × 7mm and the surflaes (weight of the net of 0.5mm × 0.5mm only cannot be passed through
35%) weight after amount relatively just acquisition is reduced about to be used as filtering material.
Filtering material 10g is put into filter device, and to buy the applicant alum hot spring sediment (white,
About powdery) 10g is scattered in commercially available distilled water the purified water of manufacture (Shan Rong Co., Ltd.) 0.1L, and obtained liquid is (bright
The concentration of alum hot spring sediment is 9.09wt%, and yellowish-brown is presented) it is filtered at normal temperatures and pressures.It confirmed that filtrate is nothing
Color is transparent.
In addition, the total amount for filtering above-mentioned dispersion liquid about 0.11L takes 14 minutes or so for filtering.
The composition analysis result and pH value of above-mentioned filtrate are shown in table 1.
(embodiment 2)
It is commercially available as filtering material to 5g surflaes identical with the surflaes used in embodiment 1 as filtering material and 5g
Sand (the JWWA A-103 qualified product effective diameter 0.6mm coefficient of uniformity 1.4 of Nihon Raw Material Co., Ltd.'s manufacture) is mixed, and
This is used as filtering material and in addition to this carries out the filtering of white alum hot spring sediment dispersion liquid same as Example 1ly.
Filtration time is about 10 minutes, can be filtered with the time more shorter than embodiment 1, obtained filtrate is
It is bright, but show extremely light yellowish-brown.
The composition analysis result and pH value of above-mentioned filtrate are shown in table 1 together.
(embodiment 3,4)
The per unit area weight that will be used as the packaging material of the commercially available alum hot spring sediment of the applicant
0.09g/cm2Non-woven fabrics (using polyethylene terephthalate as main material and the non-woven fabrics of waterproof processing is not carried out) system
At about 15 × 15cm square it is bag-shaped, be made inside it enclose 10g it is identical with surflaes used in embodiment 1 residual
The bag-like filter material (surrounding fusion) of soil.Equally, the equivalent for having enclosed surflaes and sand prepared in 10g embodiment 2 is made
The bag-like filter material of mixture.
Other than using above two bag-like filter material this point, carry out and embodiment 1,2 identical filterings.
Filtration time (embodiment 3) in the case where only surflaes is about 14.5 minutes, and the equivalent of surflaes and filter sand is mixed
(embodiment 4) is about 10.5 minutes in the case where closing object, and slightly long compared with Examples 1 and 2, obtained filtrate is in embodiment 3
Colorless and transparent, higher compared with 2 transparency of embodiment in embodiment 4, the paler colour of degree same as Example 1.
The composition analysis result and pH value of above-mentioned filtrate are shown in table 1 together.
(embodiment 5)
Commercially available white alum hot spring sediment is replaced using red alum hot spring sediment, and the amount of surflaes is set
It is set to 10g, 30g, 50g, 70g, 100g, in addition to this, with by embodiment 3 (the drying surflaes of respective amount is enclosed and is not carried out
Used in the non-woven fabrics of waterproof processing as filtering material) it is filtered in the same manner.
As a result, the filtrate that the amount of surflaes is set as the alum hot spring sediment of 70g and 100g becomes extremely light yellowish-brown very
To being colorless and transparent.Filtration time is when surflaes amount is 10g about 15 minutes, about 11 minutes when being 30g, about 8 points when 50g and 70g
Clock, about 7 minutes when 100g, the usage amount of surflaes is more, and filtration time is shorter.Although its reason is also fuzzy, supposition be by
When dispersion liquid and dry surflaes contact, moment causes reduction reaction and captures phenomenon, liquid after these reactions or the generation of phenomenon
The decline of body viscosity, accelerates the progress of filtering.
The variation of the pH value of the filtrate of above-mentioned each surflaes amount is shown in table 2 together.
(embodiment 6)
Red alum hot spring sediment is replaced using golden yellow alum hot spring sediment, in addition to this, with embodiment 5
It is filtered in the same manner.
As a result, the filtrate that the amount of surflaes is set as the alum hot spring sediment of 50g, 70g, 100g become it is extremely light yellowish-brown
Color is even colorless and transparent.Filtration time shortens about 1 minute to 1 point half, but basic display goes out same as Example 5 to incline
To.
The variation of the pH value of filtrate in above-mentioned each surflaes amount is shown in table 2 together.
(embodiment 7)
Using the red hot spring sediment dispersion liquid prepared in embodiment 5, surflaes amount is set as 30g, in addition to this, is used
The bag-like filter material manufactured same as Example 3ly is repeated filtering same as Example 3 three times and (filters to first time
Liquid carries out second as filtering material using filtered surflaes for the first time and filters, and is filtered to second of filtrate using second
Surflaes afterwards carries out third time filtering as filtering material).
About filtration time, the time each time substantially with the surflaes amount 30g of embodiment 5 the case where it is identical, filter three times
About 3 times of filtration time.
The case where fading extent and transparency of filtrate first time and the surflaes amount of embodiment 5 are 30g is roughly the same, and second
The case where secondary surflaes amount with embodiment 5 is 70g is close, although third time is without significant change but determines that improving really
?.And confirm pH in first time~third time all without significant change.
The composition analysis result and pH value of the filtrate of above-mentioned third time are shown in table 1 together.
(embodiment 8)
Red hot spring sediment 5g and golden yellow hot spring sediment 5g are used in mixed way, it is in addition to this, same as Example 7
Ground is repeated to be filtered three times.
Time about filtration time, each time is roughly the same with embodiment 7, three times about 3 times of filtering of filtration time.
In first time, second, third time, fading extent, the transparency of filtrate all show same as Example 7
It shows, and confirm pH there is no significant changes in first time~third time.
The composition analysis result and pH value of the filtrate of above-mentioned third time are shown in table 1 together.
(reference example 1)
It disperses the identical surflaes of surflaes used in 10g and embodiment 1 in used in 100mL and embodiment 1
The identical distilled water of distilled water in, be obtained by filtration at normal temperatures and pressures using filter paper filtrate (it is colorless and transparent, in table 1 as ginseng
The composition analysis result examining example 1 and showing) filtrate, is injected the white alum hot spring prepared in embodiment 1 and precipitated by about 90mL
Object dispersion liquid 100mL (alum hot spring sludge concentration 9.09wt%), is stirred at normal temperatures and pressures, fading effect, transparence effect
Fruit all fails to observe by visual observation to be confirmed.
It follows that hot spring sediment dispersion liquid can be made to become the ingredient in the surflaes of colorless and transparent effect, it just has
Slightly solubility is even insoluble (referring to the reference example 1 of table 1), is closed in always in the drying surflaes for reducing moisture, makes this hair
Hot spring sediment dispersion liquid in bright contacts (solid-liquid contact) the drying surflaes under the conditions of slowly, this is for reaching the present invention
Purpose for be very important.
(comparative example 1)
White alum hot spring sediment water (the alum hot spring sludge concentration prepared into 100mL embodiment 1
The drying surflaes prepared in investment 10g embodiment 1 in 9.09wt%), stirring make its dispersion.
The fading effect of the supernatant of the dispersion liquid is not therefore, to put into binchotan powder 20g very well (in bronzing), stir
It mixes after dispersing it, using filter paper identical with filter paper used in embodiment 1, is filtered at normal temperatures and pressures.
As a result, it was confirmed that the colour fading of degree same as Example 1 has occurred, transparent filtrate has been obtained.
[table 2]
| Surflaes amount (g) | 10 | 30 | 50 | 70 | 100 |
| Embodiment 5 (pH) | 1.1 | 0.8 | 0.7 | 0.3 | 0.3 |
| 6 (pH of embodiment | 1.6 | 1.3 | 1.1 | 0.9 | 0.9 |
Above embodiments the result shows that, blue clay surflaes due to being used in the state of drying, powder largely flies
It dissipates, the powder of the dispersion shows very strong acidity due to the moisture (moisture) in air, can promote the gold in operating environment
Belong to getting rusty for control equipment class, therefore, considers from operating environment, blue clay surflaes, which is preferably put into non-woven bag, to be used.
In addition, the alum hot spring sediment of commercially available white is acid also very strong, although even putting into hot spring precipitating
Water for bathing after object will not as alkaline spring (alkali can make proteolytic) have the feeling of stick-slip, and there are sediments to block up
Fill in bathtub, make bath towel dye or use after water for bathing it is unusable in the various problems such as washing machine, especially red is bright
In alum hot spring sediment, these problems can be more prominent, by using skin external preparation of the invention, can completely eliminate these
Problem, especially to red alum hot spring sediment, practicability highly significant.
Industrial applicibility
Skin preparations for extenal use of the invention is right other than it can direct plunge into home-use bathtub and use as bath agent
The effect of various skin diseases also desirable, the utilization of the ingredient as skin disease medicament also very desirable.
In addition, other mansion (other eight soup alum hot spring of mansion) area relies on the alum hot spring sediment of alum mineral ore since ancient times
Resource, that is, blue clay i.e. will be depleted, and under this status, obtained skin external preparation contains this area in the present invention
The identical ingredient of alum hot spring gushed out always since ancient times, is high-quality naturally, and is more tractable liquid
State can be provided largely if water is added.
In addition, the present invention also to the alum hot spring sediment discarded always up to now crystallization acquisition after surflaes into
Effective use is gone, this facilitates the status for succouring resource exhaustion.
Claims (2)
1. a kind of skin preparations for extenal use, it includes the filtrates obtained as follows：
The hot spring sediment for generating sulphur spring steam and the argillic horizon containing alum is dispersed in water, and the hot spring is sunk
Surflaes after using in starch generation is filtered the dispersion liquid as filtering material,
The clay containing alum is acquired from the other mansion alum hot spring of Japan, and the hot spring sediment is to keep the other mansion of Japan bright
Individually red as obtained from the argillic horizon, golden yellow, white the hot spring sediment of the sulphur spring steam sprayed in alum hot spring,
Or two or more combined mixture.
2. skin preparations for extenal use as described in claim 1, wherein the filtering material is heavy by being filled in sale alum hot spring
It packs in bag made of the non-woven fabrics of the hot spring sediment and is made when starch.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013139709 | 2013-07-03 | ||
| JP2013-139709 | 2013-07-03 | ||
| PCT/JP2014/067782 WO2015002267A1 (en) | 2013-07-03 | 2014-07-03 | External preparation for skin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105358121A CN105358121A (en) | 2016-02-24 |
| CN105358121B true CN105358121B (en) | 2018-11-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201480038051.1A Active CN105358121B (en) | 2013-07-03 | 2014-07-03 | Skin preparations for extenal use |
Country Status (5)
| Country | Link |
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| JP (1) | JP6346890B2 (en) |
| KR (1) | KR102189339B1 (en) |
| CN (1) | CN105358121B (en) |
| HK (1) | HK1221643A1 (en) |
| WO (1) | WO2015002267A1 (en) |
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| CA3011271A1 (en) | 2016-01-13 | 2017-07-20 | Specialbandager.Dk A/S | Oedema treatment and monitoring same |
| AU2017206443B2 (en) | 2016-01-13 | 2021-07-08 | Specialbandager.Dk A/S | A device and method for providing a measure of a circumference of a body part |
| JP6749563B2 (en) * | 2016-04-08 | 2020-09-02 | 有限会社岡本屋 | Staphylococcus aureus inhibitor solution, atopic dermatitis treatment solution, cosmetics, cleaning solution and antiseptic solution |
| RU171626U1 (en) * | 2016-09-05 | 2017-06-07 | Общество с ограниченной ответственностью "А энд Ф" | FACING PANEL |
| CN108158863A (en) * | 2018-02-06 | 2018-06-15 | 赵朝民 | Skin activated water and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002326942A (en) * | 2001-05-07 | 2002-11-15 | Nonogawa Shoji Kk | Preparation for external use for skin |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3105153B2 (en) * | 1995-07-17 | 2000-10-30 | 脇屋 洋子 | Bath additives |
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2014
- 2014-07-03 WO PCT/JP2014/067782 patent/WO2015002267A1/en active Application Filing
- 2014-07-03 JP JP2015525272A patent/JP6346890B2/en active Active
- 2014-07-03 CN CN201480038051.1A patent/CN105358121B/en active Active
- 2014-07-03 KR KR1020157036135A patent/KR102189339B1/en active IP Right Grant
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002326942A (en) * | 2001-05-07 | 2002-11-15 | Nonogawa Shoji Kk | Preparation for external use for skin |
Non-Patent Citations (3)
| Title |
|---|
| "‘Yunohana", a traditional industry in Beppu";Sumika Tunematu;《Bulletin of Beppu University Junior College》;20051231;第24卷;第5页 * |
| "Chemical consideration on the formation of Yunohana sinter at the Myoban area, Beppu hot springs";Masami Ichikuni et al;《J. Hot Spring Sci.》;20091231;第59卷;第88页摘要 * |
| "Production of Yunohana sinter with the use of kaolinite clay in the Myoban area, Beppu hot springs";Masami Ichikuni et al;《J. Hot Spring Sci.》;20121231;第62卷;第3页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2015002267A1 (en) | 2015-01-08 |
| CN105358121A (en) | 2016-02-24 |
| KR102189339B1 (en) | 2020-12-11 |
| JP6346890B2 (en) | 2018-06-20 |
| HK1221643A1 (en) | 2017-06-09 |
| JPWO2015002267A1 (en) | 2017-02-23 |
| KR20160029747A (en) | 2016-03-15 |
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