A kind of surface of aluminum plate treatment process
Technical field
The invention belongs to field of metal surface treatment, be specifically related to a kind of surface of aluminum plate treatment process.
Background technology
Al and Alalloy be current applications very widely, one of most economical applicable material.World aluminum output occupies first of non-ferrous metal within 1956, beginning to exceed copper output always.The output of current aluminium and consumption (calculating by ton) are only second to steel, become the second largest metal of mankind's application; And the resource of aluminium is very abundant, according to predesigne, the mineral reserve storage capacity of aluminium accounts for more than 8% of earth's crust constitute.Aluminium is of many uses, now needs in use to carry out surface treatment.
Summary of the invention
The object of this invention is to provide a kind of surface of aluminum plate treatment process, surface of aluminum plate is carried out to the process such as passivation, improve the antiseptic property of aluminium sheet.
A kind of surface of aluminum plate treatment process, comprises the following steps:
(1), by surface of aluminum plate put into soaking compartment and use 40 DEG C, the massfraction sodium hydrogen carbonate solution immersion treatment 60-72s that is 3-4%, then use soft cloth wiping surface of aluminum plate, and use clear water to rinse well;
(2), by the surface of aluminum plate that step (1) is handled well dry at 30-40 DEG C of temperature, then evenly spray silver oxide powder in surface of aluminum plate, fountain height is 55-62g/m
2, then use the soft cloth being moistened with kerosene to have the aluminium sheet of silver oxide powder to carry out wiping to sprinkling, pressure during wiping is 0.35-0.42Mpa, and the wiping time is 5-8min;
(3), by the aluminium sheet that step (2) is handled well use 28 DEG C, the massfraction sodium hydrogen carbonate solution immersion treatment 3-5min that is 3-4%, then use washed with de-ionized water, deionized water temperature is 22-28 DEG C;
(4) aluminium sheet, above-mentioned steps handled well uses inactivating treatment liquid at 25-32 DEG C of Passivation Treatment 25-33min;
(5) aluminium sheet, by Passivation Treatment completed uses deionized water rinsing clean, dries at 35-40 DEG C;
(6) epoxy zinc chromate primer, by surface of aluminum plate is used to spray, during spraying, priming paint: solidifying priming paint agent: the part by weight of thinner is 7:2:0.2; Dry at 35 DEG C after spraying;
(7), by aluminium sheet at 50-55 DEG C, 10-15min is processed, then spray paint.
Preferably, described inactivating treatment liquid comprises treatment solution A and treatment solution B, and in treatment solution A, silane coupling agent mass concentration is 1.2-1.5%, mixed amine mass concentration 4.3-5.8%, dimethyl formamide mass concentration 1.5-3% surplus be water; In treatment solution B, the mass concentration of sodium dichromate 99 is 8-15%, and surplus is water, and adjustment PH is 4.5-6; During use, first use treatment solution A process 10-15min, then use treatment solution B process.
Preferably, described finish paint is made up of following composition by weight: urethane acrylate 25-30 part, Hydroxylated acrylic resin 15-22 part, aqueous epoxy resins 12-15 part, ethylene glycol ether acetate 15-20 part, thinner 50-65 part, flow agent 1-2 part, solidifying agent 1-2 part, defoamer 0.5-1 part.The paint spraying of this formula, better with cohesiveness on the aluminium sheet of silver peroxide process post-passivation, can prevent paint bubble, come off.
Described thinner, flow agent, solidifying agent and defoamer can use this area common agents.
Can use a small amount of conventional dissolving adjuvants when in the present invention prepared by reagent, solubility promoter usage quantity is less than 5%.
Beneficial effect of the present invention: method of the present invention is when to aluminium sheet process, first use silver suboxide after cleaning and carry out wiping with kerosene, the foreign matter of surface of aluminum plate can be removed, homogeneity when can promote again follow-up passivation and the density of passivation layer, and after process, the thickness of passivation layer can be increased, greatly promote the planeness of surface of aluminum plate after the Corrosion Protection of aluminium sheet and passivation; Spray paint more after passivation, promotes the preservative property of aluminium further, can also promote its aesthetic property, use silver suboxide and kerosene to process before passivation, can promote the stability of homogeneity and the bonding of spraying paint.
Temperature and time in the present invention in Passivation Treatment step controls, the Passivation Treatment effect of aluminium sheet is had a great impact, the present invention also demonstrates differing temps and time controling, when changing temperature and time, carry out salt-fog test, after result display condition changes, salt-fog test time shorten, within the scope of 100-263h, illustrates that condition of the present invention controls to produce fabulous effect.
Embodiment
Embodiment 1
A kind of surface of aluminum plate treatment process, comprises the following steps:
(1), by surface of aluminum plate put into soaking compartment use 40 DEG C, massfraction be 3.5% sodium hydrogen carbonate solution immersion treatment 65s, then use soft cloth wiping surface of aluminum plate, and use clear water to rinse well;
(2), by the surface of aluminum plate that step (1) is handled well dry at 32 DEG C of temperature, then evenly spray silver oxide powder in surface of aluminum plate, fountain height is 58g/m
2, then use the soft cloth being moistened with kerosene to have the aluminium sheet of silver oxide powder to carry out wiping to sprinkling, pressure during wiping is 0.4Mpa, and the wiping time is 6min;
(3), by the aluminium sheet that step (2) is handled well use 28 DEG C, the massfraction sodium hydrogen carbonate solution immersion treatment 3min that is 3-4%, then use washed with de-ionized water, deionized water temperature is 25 DEG C;
(4) aluminium sheet, above-mentioned steps handled well uses inactivating treatment liquid at 28 DEG C of Passivation Treatment 28min;
(5) aluminium sheet, by Passivation Treatment completed uses deionized water rinsing clean, dries at 36 DEG C;
(6) epoxy zinc chromate primer, by surface of aluminum plate is used to spray, during spraying, priming paint: solidifying priming paint agent: the part by weight of thinner is 7:2:0.2; Dry at 35 DEG C after spraying;
(7), by aluminium sheet at 50-55 DEG C, 10-15min is processed, then spray paint.
Described inactivating treatment liquid comprises treatment solution A and treatment solution B, and in treatment solution A, silane coupling agent mass concentration is 1.5%, mixed amine mass concentration 4.8%, dimethyl formamide mass concentration 2% surplus be water; In treatment solution B, the mass concentration of sodium dichromate 99 is 12%, and surplus is water, regulates PH to be 6; During use, first use treatment solution A process 15min, then use treatment solution B process.
Described finish paint is made up of following composition by weight: urethane acrylate 28 parts, Hydroxylated acrylic resin 20 parts, aqueous epoxy resins 12 parts, ethylene glycol ether acetate 16 parts, thinner 55 parts, flow agent 1.2 parts, 1.5 parts, solidifying agent, defoamer 0.75 part.
Embodiment 2
A kind of surface of aluminum plate treatment process, comprises the following steps:
(1), by surface of aluminum plate put into soaking compartment use 40 DEG C, massfraction be 3.5% sodium hydrogen carbonate solution immersion treatment 64s, then use soft cloth wiping surface of aluminum plate, and use clear water to rinse well;
(2), by the surface of aluminum plate that step (1) is handled well dry at 32 DEG C of temperature, then evenly spray silver oxide powder in surface of aluminum plate, fountain height is 59g/m
2, then use the soft cloth being moistened with kerosene to have the aluminium sheet of silver oxide powder to carry out wiping to sprinkling, pressure during wiping is 0.4Mpa, and the wiping time is 7min;
(3), by the aluminium sheet that step (2) is handled well use 28 DEG C, massfraction be 4% sodium hydrogen carbonate solution immersion treatment 3min, then use washed with de-ionized water, deionized water temperature is 26 DEG C;
(4) aluminium sheet, above-mentioned steps handled well uses inactivating treatment liquid at 28 DEG C of Passivation Treatment 30min;
(5) aluminium sheet, by Passivation Treatment completed uses deionized water rinsing clean, dries at 36 DEG C;
(6) epoxy zinc chromate primer, by surface of aluminum plate is used to spray, during spraying, priming paint: solidifying priming paint agent: the part by weight of thinner is 7:2:0.2; Dry at 35 DEG C after spraying;
(7), by aluminium sheet at 50-55 DEG C, 10-15min is processed, then spray paint.
Preferably, described inactivating treatment liquid comprises treatment solution A and treatment solution B, and in treatment solution A, silane coupling agent mass concentration is 1.5%, mixed amine mass concentration 5%, dimethyl formamide mass concentration 1.8% surplus be water; In treatment solution B, the mass concentration of sodium dichromate 99 is 12%, and surplus is water, regulates PH to be 5.5; During use, first use treatment solution A process 13min, then use treatment solution B process.
Described finish paint is made up of following composition by weight: urethane acrylate 30 parts, Hydroxylated acrylic resin 20 parts, aqueous epoxy resins 14 parts, ethylene glycol ether acetate 18 parts, thinner 60 parts, flow agent 1.5 parts, 1.6 parts, solidifying agent, defoamer 0.8 part.