CN105348776A - Heat-resistant flame-retardant environmental-friendly plastic used for electric appliance elements - Google Patents
Heat-resistant flame-retardant environmental-friendly plastic used for electric appliance elements Download PDFInfo
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- CN105348776A CN105348776A CN201510779189.3A CN201510779189A CN105348776A CN 105348776 A CN105348776 A CN 105348776A CN 201510779189 A CN201510779189 A CN 201510779189A CN 105348776 A CN105348776 A CN 105348776A
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Abstract
Heat-resistant flame-retardant environmental-friendly plastic used for electric appliance elements is disclosed and comprises following raw materials by weight: 80-120 parts of polyphenyl ether, 30-60 parts of ethylene-vinyl acetate copolymer, 20-50 parts of diethylene glycol polyester, 10-30 parts of diethylenetriamine, 2-8 parts of dolomite powder, 3-9 parts of nanometer titanium dioxide, 2-6 parts of stearic acid, 1-6 parts of zinc borate, 2-8 parts of magnesium aluminate, 5-15 parts of antimonous oxide, 2-6 parts of triphenyl phosphite, 3-9 parts of toluene diisocyanate, 1-5 parts of sarcandra glabra essence oil, 2-6 parts of dioctyl phthalate, 1-4 parts of tricresyl phosphate, 2-5 parts of pentaerythritol stearate and 3-6 parts of auxiliary agents. The plastic is excellent in heat resistance and flame retardance.
Description
Technical field
The present invention relates to a kind of environmentally-friendly plastic, particularly relate to a kind of electric elements heat-proof combustion-resistant environmentally-friendly plastic.
Background technology
Along with the fast development of economy, improving constantly of people's living standard, the requirement of people to the durability of household electrical appliance and heat-proof combustion-resistant performance improves constantly, the safety performance of household electrical appliance, become people on market and selected the major influence factors of household electrical appliance, but in prior art, the plastics that the electric elements of household electrical appliance use not only not environmentally, difficult degradation, and demand when its heat-resisting and flame retardant properties cannot meet actual use.
Summary of the invention
For solving the technical problem existed in background technology, the present invention proposes a kind of electric elements heat-proof combustion-resistant environmentally-friendly plastic, has excellent heat-resisting and flame retardant properties.
A kind of electric elements heat-proof combustion-resistant environmentally-friendly plastic that the present invention proposes, its raw material comprises by weight: polyphenylene oxide 80-120 part, ethylene-vinyl acetate copolymer 30-60 part, benzoic anhydride polyester polyol 20-50 part, diethylenetriamine 10-30 part, ground dolomite 2-8 part, Nano titanium dioxide 3-9 part, stearic acid 2-6 part, zinc borate 1-6 part, magnesium aluminate 2-8 part, antimonous oxide 5-15 part, triphenyl phosphite 2-6 part, tolylene diisocyanate 3-9 part, Sarcandra glabra essential oil 1-5 part, dioctyl ester 2-6 part, Tritolyl Phosphate 1-4 part, pentaerythritol stearate 2-5 part, auxiliary agent 3-6 part.
Preferably, the raw material of auxiliary agent comprises by weight: carbamate 5-15 part, isopropyl acrylate 2-8 part, powdered rice hulls 12-24 part, fire retardant 1-3 part, toughner 2-5 part, wood fibre 3-9 part, attapulgite 1-6 part, water-resisting agent 1-5 part.
Preferably, auxiliary agent is prepared by following technique: attapulgite is put into calcining furnace and calcine 2-5h at 820-920 DEG C, cooling, put into hydrochloric acid soln and soak 1-3h, filter and take out, clean with clear water and dry, pulverizing obtains material a, then material a, carbamate, isopropyl acrylate, powdered rice hulls, fire retardant, toughner, wood fibre, attapulgite and water-resisting agent are mixed, grinding distribution is even, obtains auxiliary agent.
Preferably, the concentration of hydrochloric acid soln is 5-10%.
Preferably, material a is 200-400 order powder.
Preferably, its raw material comprises by weight: polyphenylene oxide 85-115 part, ethylene-vinyl acetate copolymer 35-55 part, benzoic anhydride polyester polyol 25-45 part, diethylenetriamine 15-25 part, ground dolomite 3-7 part, Nano titanium dioxide 4-8 part, stearic acid 3-5 part, zinc borate 2-5 part, magnesium aluminate 3-7 part, antimonous oxide 8-12 part, triphenyl phosphite 3-5 part, tolylene diisocyanate 4-8 part, Sarcandra glabra essential oil 2-4 part, dioctyl ester 3-5 part, Tritolyl Phosphate 2-3 part, pentaerythritol stearate 3-4 part, auxiliary agent 4-5 part.
Preferably, its raw material comprises by weight: polyphenylene oxide 100 parts, ethylene-vinyl acetate copolymer 45 parts, benzoic anhydride polyester polyol 35 parts, diethylenetriamine 20 parts, ground dolomite 5 parts, Nano titanium dioxide 6 parts, stearic acid 4 parts, zinc borate 3.5 parts, magnesium aluminate 5 parts, antimonous oxide 10 parts, triphenyl phosphite 4 parts, tolylene diisocyanate 6 parts, Sarcandra glabra essential oil 3 parts, dioctyl ester 4 parts, Tritolyl Phosphate 2.5 parts, pentaerythritol stearate 3.5 parts, auxiliary agent 4.5 parts.
A kind of electric elements heat-proof combustion-resistant environmentally-friendly plastic of the present invention, its raw material comprises polyphenylene oxide, ethylene-vinyl acetate copolymer, benzoic anhydride polyester polyol, diethylenetriamine, ground dolomite, Nano titanium dioxide, stearic acid, zinc borate, magnesium aluminate, antimonous oxide, triphenyl phosphite, tolylene diisocyanate, Sarcandra glabra essential oil, dioctyl ester, Tritolyl Phosphate, pentaerythritol stearate and auxiliary agent are wherein major ingredient with polyphenylene oxide, for electric elements heat-proof combustion-resistant environmentally-friendly plastic of the present invention provides good heat-resisting and flame retardant properties, and auxiliary interpolation ethylene-vinyl acetate copolymer, benzoic anhydride polyester polyol, diethylenetriamine, ground dolomite, Nano titanium dioxide, stearic acid, zinc borate, magnesium aluminate, antimonous oxide, triphenyl phosphite, tolylene diisocyanate, Sarcandra glabra essential oil, dioctyl ester, Tritolyl Phosphate, pentaerythritol stearate and auxiliary agent as auxiliary material, the ratio between conservative control auxiliary material and major ingredient, further increase heat-resisting and flame retardant properties of the present invention, in auxiliary material, the raw material of auxiliary agent comprises carbamate, isopropyl acrylate, powdered rice hulls, fire retardant, toughner, wood fibre, attapulgite and water-resisting agent, using carbamate as major ingredient, with isopropyl acrylate, powdered rice hulls, fire retardant, toughner, wood fibre, attapulgite and water-resisting agent are as auxiliary material, and the proportioning of conservative control major ingredient and auxiliary material, uses the powdered rice hulls and lignocellulose that can explain, make electric elements heat-proof combustion-resistant environmentally-friendly plastic of the present invention have degradability.Electric elements heat-proof combustion-resistant environmentally-friendly plastic of the present invention has excellent heat-resisting and flame retardant effect, and has environment protecting.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
In embodiment, the weight part of polyphenylene oxide can be 80 parts, 85 parts, 90 parts, 95 parts, 100 parts, 105 parts, 110 parts, 115 parts, 120 parts; The weight part of ethylene-vinyl acetate copolymer can be 30 parts, 35 parts, 40 parts, 45 parts, 50 parts, 55 parts, 60 parts; The weight part of benzoic anhydride polyester polyol can be 20 parts, 25 parts, 30 parts, 35 parts, 40 parts, 45 parts, 50 parts; The weight part of diethylenetriamine can be 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts; The weight part of ground dolomite can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of Nano titanium dioxide can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts; Stearic weight part can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts; The weight part of zinc borate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts; The weight part of magnesium aluminate can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of antimonous oxide can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts; The weight part of triphenyl phosphite can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts; The weight part of tolylene diisocyanate can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts; The weight part of Sarcandra glabra essential oil can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts; The weight part of dioctyl ester can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts; The weight part of Tritolyl Phosphate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts; The weight part of pentaerythritol stearate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts; The weight part of auxiliary agent can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts.
In embodiment, in the raw material of auxiliary agent, the weight part of carbamate can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts; The weight part of isopropyl acrylate can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of powdered rice hulls can be 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts; The weight part of fire retardant can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts; The weight part of toughner can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts; The weight part of wood fibre can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts; The weight part of attapulgite can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts; The weight part of water-resisting agent can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts.
Embodiment 1
A kind of electric elements heat-proof combustion-resistant environmentally-friendly plastic that the present invention proposes, its raw material comprises by weight: polyphenylene oxide 100 parts, ethylene-vinyl acetate copolymer 45 parts, benzoic anhydride polyester polyol 35 parts, diethylenetriamine 20 parts, ground dolomite 5 parts, Nano titanium dioxide 6 parts, stearic acid 4 parts, zinc borate 3.5 parts, magnesium aluminate 5 parts, antimonous oxide 10 parts, triphenyl phosphite 4 parts, tolylene diisocyanate 6 parts, Sarcandra glabra essential oil 3 parts, dioctyl ester 4 parts, Tritolyl Phosphate 2.5 parts, pentaerythritol stearate 3.5 parts, auxiliary agent 4.5 parts.
Auxiliary agent is prepared by following technique: by weight 3.5 parts of attapulgites are put into calcining furnace and calcine 3.5h at 900 DEG C, cooling, put into concentration be 7.5% hydrochloric acid soln soak 2h, filter and take out, clean with clear water and dry, pulverize and obtain 300 order powder material a, then material a, carbamate, isopropyl acrylate, powdered rice hulls, fire retardant, toughner, wood fibre, attapulgite and water-resisting agent are mixed, grinding distribution is even, obtains auxiliary agent.
Embodiment 2
A kind of electric elements heat-proof combustion-resistant environmentally-friendly plastic that the present invention proposes, its raw material comprises by weight: polyphenylene oxide 80 parts, ethylene-vinyl acetate copolymer 60 parts, benzoic anhydride polyester polyol 20 parts, diethylenetriamine 30 parts, ground dolomite 2 parts, Nano titanium dioxide 9 parts, stearic acid 2 parts, zinc borate 6 parts, magnesium aluminate 2 parts, antimonous oxide 15 parts, triphenyl phosphite 2 parts, tolylene diisocyanate 9 parts, Sarcandra glabra essential oil 1 part, dioctyl ester 6 parts, Tritolyl Phosphate 1 part, pentaerythritol stearate 5 parts, auxiliary agent 3 parts.
Auxiliary agent is prepared by following technique: by weight 6 parts of attapulgites are put into calcining furnace and calcine 5h at 820 DEG C, cooling, put into concentration be 5% hydrochloric acid soln soak 3h, filter and take out, clean with clear water and dry, pulverize and obtain 200 order powder material a, then material a, carbamate, isopropyl acrylate, powdered rice hulls, fire retardant, toughner, wood fibre, attapulgite and water-resisting agent are mixed, grinding distribution is even, obtains auxiliary agent.
Embodiment 3
A kind of electric elements heat-proof combustion-resistant environmentally-friendly plastic that the present invention proposes, its raw material comprises by weight: polyphenylene oxide 120 parts, ethylene-vinyl acetate copolymer 30 parts, benzoic anhydride polyester polyol 50 parts, diethylenetriamine 10 parts, ground dolomite 8 parts, Nano titanium dioxide 3 parts, stearic acid 6 parts, zinc borate 1 part, magnesium aluminate 8 parts, antimonous oxide 5 parts, triphenyl phosphite 6 parts, tolylene diisocyanate 3 parts, Sarcandra glabra essential oil 5 parts, dioctyl ester 2 parts, Tritolyl Phosphate 4 parts, pentaerythritol stearate 2 parts, auxiliary agent 6 parts.
Auxiliary agent is prepared by following technique: by weight 6 parts of attapulgites are put into calcining furnace and calcine 5h at 820 DEG C, cooling, put into concentration be 5% hydrochloric acid soln soak 3h, filter and take out, clean with clear water and dry, pulverize and obtain 200 order powder material a, then material a, carbamate, isopropyl acrylate, powdered rice hulls, fire retardant, toughner, wood fibre, attapulgite and water-resisting agent are mixed, grinding distribution is even, obtains auxiliary agent.
Embodiment 4
A kind of electric elements heat-proof combustion-resistant environmentally-friendly plastic that the present invention proposes, its raw material comprises by weight: polyphenylene oxide 85 parts, ethylene-vinyl acetate copolymer 55 parts, benzoic anhydride polyester polyol 25 parts, diethylenetriamine 25 parts, ground dolomite 3 parts, Nano titanium dioxide 8 parts, stearic acid 3 parts, zinc borate 5 parts, magnesium aluminate 3 parts, antimonous oxide 12 parts, triphenyl phosphite 3 parts, tolylene diisocyanate 8 parts, Sarcandra glabra essential oil 2 parts, dioctyl ester 5 parts, Tritolyl Phosphate 2 parts, pentaerythritol stearate 4 parts, auxiliary agent 4 parts.
Auxiliary agent is prepared by following technique: by weight 5 parts of attapulgites are put into calcining furnace and calcine 4h at 830 DEG C, cooling, put into concentration be 6% hydrochloric acid soln soak 2.5h, filter and take out, clean with clear water and dry, pulverize and obtain 250 order powder material a, then material a, carbamate, isopropyl acrylate, powdered rice hulls, fire retardant, toughner, wood fibre, attapulgite and water-resisting agent are mixed, grinding distribution is even, obtains auxiliary agent.
Embodiment 5
A kind of electric elements heat-proof combustion-resistant environmentally-friendly plastic that the present invention proposes, its raw material comprises by weight: polyphenylene oxide 115 parts, ethylene-vinyl acetate copolymer 35 parts, benzoic anhydride polyester polyol 45 parts, diethylenetriamine 15 parts, ground dolomite 7 parts, Nano titanium dioxide 4 parts, stearic acid 5 parts, zinc borate 2 parts, magnesium aluminate 7 parts, antimonous oxide 8 parts, triphenyl phosphite 5 parts, tolylene diisocyanate 4 parts, Sarcandra glabra essential oil 4 parts, dioctyl ester 3 parts, Tritolyl Phosphate 3 parts, pentaerythritol stearate 3 parts, auxiliary agent 5 parts.
Auxiliary agent is prepared by following technique: by weight 2 parts of attapulgites are put into calcining furnace and calcine 3h at 910 DEG C, cooling, put into concentration be 9% hydrochloric acid soln soak 1.5h, filter and take out, clean with clear water and dry, pulverize and obtain 350 order powder material a, then material a, carbamate, isopropyl acrylate, powdered rice hulls, fire retardant, toughner, wood fibre, attapulgite and water-resisting agent are mixed, grinding distribution is even, obtains auxiliary agent.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (7)
1. an electric elements heat-proof combustion-resistant environmentally-friendly plastic, it is characterized in that, its raw material comprises by weight: polyphenylene oxide 80-120 part, ethylene-vinyl acetate copolymer 30-60 part, benzoic anhydride polyester polyol 20-50 part, diethylenetriamine 10-30 part, ground dolomite 2-8 part, Nano titanium dioxide 3-9 part, stearic acid 2-6 part, zinc borate 1-6 part, magnesium aluminate 2-8 part, antimonous oxide 5-15 part, triphenyl phosphite 2-6 part, tolylene diisocyanate 3-9 part, Sarcandra glabra essential oil 1-5 part, dioctyl ester 2-6 part, Tritolyl Phosphate 1-4 part, pentaerythritol stearate 2-5 part, auxiliary agent 3-6 part.
2. electric elements heat-proof combustion-resistant environmentally-friendly plastic according to claim 1, it is characterized in that, the raw material of auxiliary agent comprises by weight: carbamate 5-15 part, isopropyl acrylate 2-8 part, powdered rice hulls 12-24 part, fire retardant 1-3 part, toughner 2-5 part, wood fibre 3-9 part, attapulgite 1-6 part, water-resisting agent 1-5 part.
3. electric elements heat-proof combustion-resistant environmentally-friendly plastic according to claim 1, it is characterized in that, auxiliary agent is prepared by following technique: attapulgite is put into calcining furnace and calcine 2-5h at 820-920 DEG C, cooling, put into hydrochloric acid soln and soak 1-3h, filter and take out, clean with clear water and dry, pulverizing obtains material a, then material a, carbamate, isopropyl acrylate, powdered rice hulls, fire retardant, toughner, wood fibre, attapulgite and water-resisting agent are mixed, grinding distribution is even, obtains auxiliary agent.
4. the heat-proof combustion-resistant environmentally-friendly plastic of the electric elements according to any one of claim 1-3, is characterized in that, the concentration of hydrochloric acid soln is 5-10%.
5. the heat-proof combustion-resistant environmentally-friendly plastic of the electric elements according to any one of claim 1-4, is characterized in that, material a is 200-400 order powder.
6. the heat-proof combustion-resistant environmentally-friendly plastic of the electric elements according to any one of claim 1-5, it is characterized in that, its raw material comprises by weight: polyphenylene oxide 85-115 part, ethylene-vinyl acetate copolymer 35-55 part, benzoic anhydride polyester polyol 25-45 part, diethylenetriamine 15-25 part, ground dolomite 3-7 part, Nano titanium dioxide 4-8 part, stearic acid 3-5 part, zinc borate 2-5 part, magnesium aluminate 3-7 part, antimonous oxide 8-12 part, triphenyl phosphite 3-5 part, tolylene diisocyanate 4-8 part, Sarcandra glabra essential oil 2-4 part, dioctyl ester 3-5 part, Tritolyl Phosphate 2-3 part, pentaerythritol stearate 3-4 part, auxiliary agent 4-5 part.
7. the heat-proof combustion-resistant environmentally-friendly plastic of the electric elements according to any one of claim 1-6, it is characterized in that, its raw material comprises by weight: polyphenylene oxide 100 parts, ethylene-vinyl acetate copolymer 45 parts, benzoic anhydride polyester polyol 35 parts, diethylenetriamine 20 parts, ground dolomite 5 parts, Nano titanium dioxide 6 parts, stearic acid 4 parts, zinc borate 3.5 parts, magnesium aluminate 5 parts, antimonous oxide 10 parts, triphenyl phosphite 4 parts, tolylene diisocyanate 6 parts, Sarcandra glabra essential oil 3 parts, dioctyl ester 4 parts, Tritolyl Phosphate 2.5 parts, pentaerythritol stearate 3.5 parts, auxiliary agent 4.5 parts.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510779189.3A CN105348776A (en) | 2015-11-13 | 2015-11-13 | Heat-resistant flame-retardant environmental-friendly plastic used for electric appliance elements |
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| CN201510779189.3A CN105348776A (en) | 2015-11-13 | 2015-11-13 | Heat-resistant flame-retardant environmental-friendly plastic used for electric appliance elements |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106750924A (en) * | 2016-12-12 | 2017-05-31 | 天长市康宁塑胶科技有限公司 | A kind of thermal resistance and acid-alkali resistance modified plastic rubber material |
| CN106750861A (en) * | 2016-12-14 | 2017-05-31 | 天长市康宁甘油科技有限公司 | A kind of abrasion resistant fire blocking decorative plastic material |
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Patent Citations (3)
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106750924A (en) * | 2016-12-12 | 2017-05-31 | 天长市康宁塑胶科技有限公司 | A kind of thermal resistance and acid-alkali resistance modified plastic rubber material |
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