CN105348696A - Antibacterial cable material - Google Patents
Antibacterial cable material Download PDFInfo
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- CN105348696A CN105348696A CN201510871243.7A CN201510871243A CN105348696A CN 105348696 A CN105348696 A CN 105348696A CN 201510871243 A CN201510871243 A CN 201510871243A CN 105348696 A CN105348696 A CN 105348696A
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- sericite
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Abstract
The invention relates to an antibacterial cable material which is characterized by comprising the following components in parts by mass: 25-50 parts of PVC resin, 20-30 parts of polyolefin resin, 20-35 parts of linear polyethylene, 0.5-2.5 parts of antimony trioxide, 0.5-2.5 parts of zinc oxide, 5-12 parts of kieselguhr, 0.5-1 part of barite powder, 3-6 parts of talcum powder, 2-5 parts of carbon black, 6-10 parts of fluorite powder, 3-6 parts of calcined kaolin, 3-7 parts of styrene, 3-8 parts of paraffin oil and 10-20 parts of modified sericite.
Description
Technical field
The present invention relates to a kind of CABLE MATERIALS, be specifically related to a kind of antibacterial CABLE MATERIALS.
Background technology
Wire cable insulating and sheath plastics are commonly called as CABLE MATERIALS, which includes the multiple kinds such as rubber, plastics, nylon.CABLE MATERIALS manufacturing enterprise is with cable manufacturing enterprise for user, as long as live wire cabling requirements just has the market of CABLE MATERIALS.Except the bare wire such as Aluminium Cable Steel Reinforced, insulated wire product, insulation layer mouth is nearly all needed in electric wire product.Nearly 5000 of live wire cable manufacturing enterprise of current China, there are again upgrading urban and rural power grids, development of the West Regions and communications facility big area upgrading to the great demand of electric wire product, thus from for some time, CABLE MATERIALS has market development prospect widely in China, CABLE MATERIALS is in the market also varied, wear-resisting, thermal resistance etc., also have fire-retardant, but the poor especially anti-microbial property of the over-all properties of these CABLE MATERIALS is poor, and cost is higher, therefore, a kind of new technical scheme of exigence solves the problems of the technologies described above.
Summary of the invention
In order to solve above-mentioned Problems existing, the invention discloses a kind of antibacterial CABLE MATERIALS, in this technical scheme, antibacterial CABLE MATERIALS production cost is lower, and the germ resistance of this technical scheme, water tolerance and flame retardant resistance improve greatly, and range of application is more extensive.
To achieve these goals, technical scheme of the present invention is as follows, and a kind of antibacterial CABLE MATERIALS, is characterized in that, according to mass fraction, be made up of following: polyvinyl chloride resin 25-50 part, polyolefin resin 20-30 part, linear polyethylene 20-35 part, antimonous oxide 0.5-2.5 part, zinc oxide 0.5-2.5, diatomite 5-12 part, ground barium sulfate 0.5-1 part, talcum powder 3-6 part, carbon black 2-5 part, Fluorspar Powder 6-10 part, calcined kaolin 3-6 part, vinylbenzene 3-7 part, paraffin oil 3-8 part, modification sericite 10-20 parts.
As a modification of the present invention, according to mass fraction, be made up of following: polyvinyl chloride resin 33-40 part, polyolefin resin 22-28 part, linear polyethylene 25-30 part, antimonous oxide 1-2 part, zinc oxide 1-2, diatomite 7-10 part, ground barium sulfate 0.6-0.8 part, talcum powder 4-5 part, carbon black 3-4 part, Fluorspar Powder 7-9 part, calcined kaolin 4-5 part, vinylbenzene 4-6 part, paraffin oil 4-7 part, modification sericite 12-18 parts.
As a modification of the present invention, according to mass fraction, be made up of following: polyvinyl chloride resin 33 parts, polyolefin resin 22 parts, linear polyethylene 25 parts, antimonous oxide 1 part, zinc oxide 1,7 parts, diatomite, ground barium sulfate 0.6 part, talcum powder 4 parts, carbon black 3 parts, Fluorspar Powder 7 parts, calcined kaolin 4 parts, vinylbenzene 4 parts, paraffin oil 4 parts, modification sericite 12 parts.
As a modification of the present invention, according to mass fraction, be made up of following: polyvinyl chloride resin 40 parts, polyolefin resin 28 parts, linear polyethylene 30 parts, antimonous oxide 2 parts, zinc oxide 2,10 parts, diatomite, ground barium sulfate 0.8 part, talcum powder 5 parts, carbon black 4 parts, Fluorspar Powder 9 parts, calcined kaolin 5 parts, vinylbenzene 6 parts, paraffin oil 7 parts, modification sericite 18 parts.
As a modification of the present invention, according to mass fraction, be made up of following: polyvinyl chloride resin 36 parts, polyolefin resin 6 parts, linear polyethylene 28 parts, antimonous oxide 1.5 parts, zinc oxide 1.5,8 parts, diatomite, ground barium sulfate 0.7 part, talcum powder 4.5 parts, carbon black 3.5 parts, Fluorspar Powder 8 parts, calcined kaolin 4.5 parts, vinylbenzene 5 parts, paraffin oil 6 parts, modification sericite 15 parts.
The preparation method of antibacterial CABLE MATERIALS, it is characterized in that: described method is as follows: 1) prepare modification sericite, room temperature be 26-30 spend time ethanol by coupling agent dilution after put into stirrer together with Masterbatch, zinc borate, ultra-fine sericite, stir 30 minutes, wherein the quality proportioning of ethanol, coupling agent, Masterbatch, zinc borate, ultra-fine sericite is: 6-8:0.8-1.2:1-3:7-10, again its mixture ultrasonic wave is disperseed 30 minutes, dry 15 minutes, modification sericite can be obtained;
2) by polyvinyl chloride resin, polyolefin resin, linear polyethylene, modification sericite, Fluorspar Powder are put into high mixer and are stirred 10-20 minute, and rotating speed is 800-1000 rev/min, and Heating temperature is to 10-15 °;
3) add in high mixer by antimonous oxide, zinc oxide, diatomite, ground barium sulfate after continuous heating to 20 °, rotating speed lowers as 500-800 rev/min simultaneously, and churning time 5 minutes, adds appropriate hydrochloric acid, regulates pH value to be 6-7;
4) temperature continues to be heated to 30-35 °, will add talcum powder, carbon black, calcined kaolin, vinylbenzene continuation stirring, and stir 5 minutes;
5) in 5-8 minute, be cooled to 10-15 °, add paraffin oil, fully stir 10 minutes;
6) mixture that step 5 obtains extruded by twin screw extruder, then carry out cooling, pelletizing, dry, obtain CABLE MATERIALS.
Relative to prior art, advantage of the present invention is as follows, 1) whole technical scheme is simple to operate, production cost is lower, reduce enterprise cost: 2) add antimonous oxide, zinc oxide, diatomite, ground barium sulfate, Fluorspar Powder, talcum powder, carbon black, calcined kaolin, vinylbenzene in this technical scheme, these compositions, under a certain amount of mixing, have the effect of well fire-retardant, germ resistance, water tolerance, and without any pollution in preparation process, energy-conserving and environment-protective; 3) sericite adopting modification is proposed first in this technical scheme, greatly improve the fire line of CABLE MATERIALS, germ resistance, water tolerance, mutually to mix with coupling agent, Masterbatch, zinc borate through modification sericite and fully contact, a large amount of fine particle adhered to and is embedded in the composition of CABLE MATERIALS, guaranteeing that CABLE MATERIALS has better fire-retardant and anti-microbial property; 4)) the method operates comparatively safe, has no side effect to operator; 5) this technical scheme further ensure that cable quality in the application, is convenient to apply on a large scale.
Embodiment
In order to deepen, to understanding of the present invention and understanding, below in conjunction with embodiment, to illustrate the present invention further.
embodiment 1:a kind of antibacterial CABLE MATERIALS, according to mass fraction, is made up of following: polyvinyl chloride resin 30 parts, polyolefin resin 20 parts, linear polyethylene 22 parts, antimonous oxide 0.5 part, zinc oxide 0.5,5 parts, diatomite, ground barium sulfate 0.5 part, talcum powder 3 parts, carbon black 2 parts, Fluorspar Powder 6 parts, calcined kaolin 3 parts, vinylbenzene 3 parts, paraffin oil 3 parts, modification sericite 10 parts.
embodiment 2:a kind of antibacterial CABLE MATERIALS, according to mass fraction, is made up of following: polyvinyl chloride resin 45 parts, polyolefin resin 30 parts, linear polyethylene 33 parts, antimonous oxide 2.5 parts, zinc oxide 2.5,12 parts, diatomite, ground barium sulfate 1 part, talcum powder 6 parts, carbon black 5 parts, Fluorspar Powder 10 parts, calcined kaolin 6 parts, vinylbenzene 7 parts, paraffin oil 8 parts, modification sericite 20 parts.
embodiment 3:a kind of antibacterial CABLE MATERIALS, according to mass fraction, is made up of following: polyvinyl chloride resin 33 parts, polyolefin resin 22 parts, linear polyethylene 25 parts, antimonous oxide 1 part, zinc oxide 1,7 parts, diatomite, ground barium sulfate 0.6 part, talcum powder 4 parts, carbon black 3 parts, Fluorspar Powder 7 parts, calcined kaolin 4 parts, vinylbenzene 4 parts, paraffin oil 4 parts, modification sericite 12 parts.
embodiment 4:a kind of antibacterial CABLE MATERIALS, according to mass fraction, is made up of following: polyvinyl chloride resin 40 parts, polyolefin resin 28 parts, linear polyethylene 30 parts, antimonous oxide 2 parts, zinc oxide 2,10 parts, diatomite, ground barium sulfate 0.8 part, talcum powder 5 parts, carbon black 4 parts, Fluorspar Powder 9 parts, calcined kaolin 5 parts, vinylbenzene 6 parts, paraffin oil 7 parts, modification sericite 18 parts.
embodiment 5:a kind of antibacterial CABLE MATERIALS, according to mass fraction, is made up of following: polyvinyl chloride resin 36 parts, polyolefin resin 6 parts, linear polyethylene 28 parts, antimonous oxide 1.5 parts, zinc oxide 1.5,8 parts, diatomite, ground barium sulfate 0.7 part, talcum powder 4.5 parts, carbon black 3.5 parts, Fluorspar Powder 8 parts, calcined kaolin 4.5 parts, vinylbenzene 5 parts, paraffin oil 6 parts, modification sericite 15 parts.
embodiment 6:the preparation method of antibacterial CABLE MATERIALS: described method is as follows: 1) prepare modification sericite, room temperature be 26-30 spend time ethanol by coupling agent dilution after put into stirrer together with Masterbatch, zinc borate, ultra-fine sericite, stir 30 minutes, wherein the quality proportioning of ethanol, coupling agent, Masterbatch, zinc borate, ultra-fine sericite is: 6-8:0.8-1.2:1-3:7-10, be preferably 7:1:2:9, again its mixture ultrasonic wave is disperseed 30 minutes, dry 15 minutes, modification sericite can be obtained;
2) by polyvinyl chloride resin, polyolefin resin, linear polyethylene, modification sericite, Fluorspar Powder are put into high mixer and are stirred 10-20 minute, and rotating speed is 800-1000 rev/min, and Heating temperature is to 10-15 °;
3) add in high mixer by antimonous oxide, zinc oxide, diatomite, ground barium sulfate after continuous heating to 20 °, rotating speed lowers as 500-800 rev/min simultaneously, and churning time 5 minutes, adds appropriate hydrochloric acid, regulates pH value to be 6-7;
4) temperature continues to be heated to 30-35 °, will add talcum powder, carbon black, calcined kaolin, vinylbenzene continuation stirring, and stir 5 minutes;
5) in 5-8 minute, be cooled to 10-15 °, add paraffin oil, fully stir 10 minutes;
6) mixture that step 5 obtains extruded by twin screw extruder, then carry out cooling, pelletizing, dry, obtain CABLE MATERIALS.
It should be noted that, above-described embodiment is only preferred embodiment of the present invention, be not used for limit protection scope of the present invention, the equivalent replacement that the basis of technique scheme is made or substitute, all belong to protection scope of the present invention.
Claims (6)
1. an antibacterial CABLE MATERIALS, is characterized in that, according to mass fraction, be made up of following: polyvinyl chloride resin 25-50 part, polyolefin resin 20-30 part, linear polyethylene 20-35 part, antimonous oxide 0.5-2.5 part, zinc oxide 0.5-2.5, diatomite 5-12 part, ground barium sulfate 0.5-1 part, talcum powder 3-6 part, carbon black 2-5 part, Fluorspar Powder 6-10 part, calcined kaolin 3-6 part, vinylbenzene 3-7 part, paraffin oil 3-8 part, modification sericite 10-20 parts.
2. antibacterial CABLE MATERIALS according to claim 1, is characterized in that, according to mass fraction, be made up of following: polyvinyl chloride resin 33-40 part, polyolefin resin 22-28 part, linear polyethylene 25-30 part, antimonous oxide 1-2 part, zinc oxide 1-2, diatomite 7-10 part, ground barium sulfate 0.6-0.8 part, talcum powder 4-5 part, carbon black 3-4 part, Fluorspar Powder 7-9 part, calcined kaolin 4-5 part, vinylbenzene 4-6 part, paraffin oil 4-7 part, modification sericite 12-18 parts.
3. antibacterial CABLE MATERIALS according to claim 1, according to mass fraction, is made up of following: polyvinyl chloride resin 33 parts, polyolefin resin 22 parts, linear polyethylene 25 parts, antimonous oxide 1 part, zinc oxide 1,7 parts, diatomite, ground barium sulfate 0.6 part, talcum powder 4 parts, carbon black 3 parts, Fluorspar Powder 7 parts, calcined kaolin 4 parts, vinylbenzene 4 parts, paraffin oil 4 parts, modification sericite 12 parts.
4. antibacterial CABLE MATERIALS according to claim 1, according to mass fraction, is made up of following: polyvinyl chloride resin 40 parts, polyolefin resin 28 parts, linear polyethylene 30 parts, antimonous oxide 2 parts, zinc oxide 2,10 parts, diatomite, ground barium sulfate 0.8 part, talcum powder 5 parts, carbon black 4 parts, Fluorspar Powder 9 parts, calcined kaolin 5 parts, vinylbenzene 6 parts, paraffin oil 7 parts, modification sericite 18 parts.
5. antibacterial CABLE MATERIALS according to claim 1, according to mass fraction, is made up of following: polyvinyl chloride resin 36 parts, polyolefin resin 6 parts, linear polyethylene 28 parts, antimonous oxide 1.5 parts, zinc oxide 1.5,8 parts, diatomite, ground barium sulfate 0.7 part, talcum powder 4.5 parts, carbon black 3.5 parts, Fluorspar Powder 8 parts, calcined kaolin 4.5 parts, vinylbenzene 5 parts, paraffin oil 6 parts, modification sericite 15 parts.
6. the preparation method of antibacterial CABLE MATERIALS, it is characterized in that: described method is as follows: 1) prepare modification sericite, room temperature be 26-30 spend time ethanol by coupling agent dilution after put into stirrer together with Masterbatch, zinc borate, ultra-fine sericite, stir 30 minutes, wherein the quality proportioning of ethanol, coupling agent, Masterbatch, zinc borate, ultra-fine sericite is: 6-8:0.8-1.2:1-3:7-10, again its mixture ultrasonic wave is disperseed 30 minutes, dry 15 minutes, modification sericite can be obtained;
2) by polyvinyl chloride resin, polyolefin resin, linear polyethylene, modification sericite, Fluorspar Powder are put into high mixer and are stirred 10-20 minute, and rotating speed is 800-1000 rev/min, and Heating temperature is to 10-15 °;
3) add in high mixer by antimonous oxide, zinc oxide, diatomite, ground barium sulfate after continuous heating to 20 °, rotating speed lowers as 500-800 rev/min simultaneously, and churning time 5 minutes, adds appropriate hydrochloric acid, regulates pH value to be 6-7;
4) temperature continues to be heated to 30-35 °, will add talcum powder, carbon black, calcined kaolin, vinylbenzene continuation stirring, and stir 5 minutes;
5) in 5-8 minute, be cooled to 10-15 °, add paraffin oil, fully stir 10 minutes;
6) mixture that step 5 obtains extruded by twin screw extruder, then carry out cooling, pelletizing, dry, obtain CABLE MATERIALS.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510871243.7A CN105348696A (en) | 2015-12-02 | 2015-12-02 | Antibacterial cable material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510871243.7A CN105348696A (en) | 2015-12-02 | 2015-12-02 | Antibacterial cable material |
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| CN105348696A true CN105348696A (en) | 2016-02-24 |
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| CN201510871243.7A Pending CN105348696A (en) | 2015-12-02 | 2015-12-02 | Antibacterial cable material |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106147309A (en) * | 2016-07-07 | 2016-11-23 | 合肥鼎亮光学科技有限公司 | A kind of road mark paint of antimony oxide doping and preparation method thereof |
| CN106683798A (en) * | 2017-01-12 | 2017-05-17 | 芜湖航天特种电缆厂股份有限公司 | Kaolin modification-based nylon cable protection sleeve and fabrication method thereof |
| CN106800724A (en) * | 2016-12-21 | 2017-06-06 | 马鞍山瑞美塑业有限公司 | A kind of antibacterial wear-resistant plastic |
| CN106810744A (en) * | 2016-12-22 | 2017-06-09 | 瓮安县信达高温线缆有限公司 | A kind of high temperature-resistant cable material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104140617A (en) * | 2014-08-07 | 2014-11-12 | 安徽玉发塑业有限公司 | Aging-resistant PVC tubular product and preparation method thereof |
| CN104194185A (en) * | 2014-07-28 | 2014-12-10 | 安徽威萨重工机械有限公司 | Polyvinyl chloride/rubber composite cable material |
| CN104277378A (en) * | 2014-11-06 | 2015-01-14 | 安徽省三乐门窗幕墙工程有限公司 | Antistatic PVC wood-plastic composite material and preparation method thereof |
-
2015
- 2015-12-02 CN CN201510871243.7A patent/CN105348696A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194185A (en) * | 2014-07-28 | 2014-12-10 | 安徽威萨重工机械有限公司 | Polyvinyl chloride/rubber composite cable material |
| CN104140617A (en) * | 2014-08-07 | 2014-11-12 | 安徽玉发塑业有限公司 | Aging-resistant PVC tubular product and preparation method thereof |
| CN104277378A (en) * | 2014-11-06 | 2015-01-14 | 安徽省三乐门窗幕墙工程有限公司 | Antistatic PVC wood-plastic composite material and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106147309A (en) * | 2016-07-07 | 2016-11-23 | 合肥鼎亮光学科技有限公司 | A kind of road mark paint of antimony oxide doping and preparation method thereof |
| CN106800724A (en) * | 2016-12-21 | 2017-06-06 | 马鞍山瑞美塑业有限公司 | A kind of antibacterial wear-resistant plastic |
| CN106810744A (en) * | 2016-12-22 | 2017-06-09 | 瓮安县信达高温线缆有限公司 | A kind of high temperature-resistant cable material and preparation method thereof |
| CN106683798A (en) * | 2017-01-12 | 2017-05-17 | 芜湖航天特种电缆厂股份有限公司 | Kaolin modification-based nylon cable protection sleeve and fabrication method thereof |
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Application publication date: 20160224 |