CN105348627A - Ceramifying polyolefin fireproof cable material - Google Patents
Ceramifying polyolefin fireproof cable material Download PDFInfo
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- CN105348627A CN105348627A CN201510776332.3A CN201510776332A CN105348627A CN 105348627 A CN105348627 A CN 105348627A CN 201510776332 A CN201510776332 A CN 201510776332A CN 105348627 A CN105348627 A CN 105348627A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical Kinetics & Catalysis (AREA)
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- Spectroscopy & Molecular Physics (AREA)
- Insulated Conductors (AREA)
Abstract
The invention provides a ceramifying polyolefin fireproof cable material. The material is prepared by the following components in parts by weight: 40-100 parts of polyolefin; 1-30 parts of a compatilizer; 350-450 parts of ceramifying powder; 20-200 parts of a flux; 20-90 parts of a fire retardant; 2-20 parts of a lubricant; and 1-10 parts of an anti-oxidant. Polyolefin is selected from one or more of an ethane-vinyl acetate copolymer, polypropylene, polystyrene, polyethylene and a polyolefin elastomer. The ceramifying powder is selected from one or more of pottery clay, powdered steatile, mica powder, pyrophillite, ascharite, datolite, calcite, limestone, spodumene and clay. The ceramifying polyolefin fireproof cable material has the advantages of good fireproof performance, environmental protection, low cost, easy processing and good application prospect.
Description
Technical field
The present invention relates to field of new, particularly a kind of cable material, more specifically relate to a kind of ceramic polyolefine flame resistant cable material.
Background technology
Along with society, expanding economy, electric wire becomes integral part stealthy in people's daily life.In case of fire, ensure that the normal operation of circuit is very important, therefore, at some large-scale tall buildings, crowded place, fire-resistant wire and cable becomes the selection of people's subjectivity.The cable that existing refractory materials can be made mainly contains: mica tape flame resistant cable, magnesium oxide mineral insulation cable, flexible fire-proof cable and fire-proof mud inorganic mineral fireproof cable etc., there is various shortcoming in these cables above-mentioned, such as: mica tape flame resistant cable flexibility is poor, thickness is restricted, wrapped speed is slow and production efficiency is low, thus causes processing, human cost high; Moisture absorption is strong, and store 3-6 month, after making moist, insulating property decline rapidly; In addition, price is high, particularly synthetic mica.Magnesium oxide mineral insulation cable is expensive, complex manufacturing and to lay difficulty large.Thus, market is badly in need of a kind of novel material that can overcome above-mentioned flame resistant cable material Problems existing and defect.
Summary of the invention
For overcoming the problems referred to above of the prior art, the invention provides a kind of ceramic polyolefine flame resistant cable material, its fire performance is good, environmental protection, cost be low and easy to process.
Present invention employs following technical scheme:
A kind of ceramic polyolefine flame resistant cable material, by weight, it is mixed obtained by following component:
Polyolefine, 40-100 part;
Compatilizer, 1-30 part;
Vitrified powder, 350-500 part;
Fusing assistant, 20-200 part;
Fire retardant, 20-100 part;
Lubricant, 2-20 part;
Oxidation inhibitor, 1-10 part.
Wherein, polyolefine is selected from one or more in ethylene-vinyl acetate copolymer, polypropylene, polystyrene, polyethylene and polyolefin elastomer.
Vitrified powder is selected from one or more in potter's clay, talcum powder, mica powder, agalmatolite, szaibelyite, datolite, calcite, Wingdale, wollastonite, triphane and clay.
Preferably, by weight, above-mentioned ceramic polyolefine flame resistant cable material comprises following component:
Polyolefine, 60-100 part;
Compatilizer, 1-20 part;
Vitrified powder, 350-450 part;
Fusing assistant, 100-200 part;
Fire retardant, 50-90 part;
Lubricant, 5-10 part; And
Oxidation inhibitor, 1-10 part.
In a specific embodiment, by weight, ceramic polyolefine flame resistant cable material of the present invention comprises following component:
Polyolefine, 70 parts;
Compatilizer, 7.5 parts;
Vitrified powder, 400 parts;
Fusing assistant, 140 parts;
Fire retardant, 70 parts;
Lubricant, 5 parts; And
Oxidation inhibitor, 1 part.
In another specific embodiment, by weight, ceramic polyolefine flame resistant cable material of the present invention comprises following component:
Polyolefine, 40 parts;
Compatilizer, 30 parts;
Vitrified powder, 350 parts;
Fusing assistant, 20 parts;
Fire retardant, 20 parts;
Lubricant, 2 parts; And
Oxidation inhibitor, 5 parts.
In another specific embodiment, by weight, ceramic polyolefine flame resistant cable material of the present invention comprises following component:
Polyolefine, 100 parts;
Compatilizer, 1 part;
Vitrified powder, 500 parts;
Fusing assistant, 200 parts;
Fire retardant, 100 parts;
Lubricant, 20 parts; And
Oxidation inhibitor, 10 parts.
Preferably, compatilizer is selected from one or more in grafted maleic anhydride compatilizer, acrylic type compatilizer, epoxide resin type compatilizer, the polystyrene (RPS) of oxazoline grafting, modified polyacrylate type compatilizer and m-pseudoallyl-2,2-methyl benzoyl isocyanic ester.
Preferably, fusing assistant is selected from one or more in glass powder, ceramics powder, glass fibre.
Preferably, fire retardant is selected from one or more in antimonous oxide, aluminium hydroxide, magnesium hydroxide, magnesium basic carbonate, kaolin, zinc borate, ammonium polyphosphate and red phosphorus.
Preferably, lubricant is selected from one or more in stearylamide, amine hydroxybenzene, calcium stearate, Zinic stearas, lipid acid, methyl-silicone oil and whiteruss.
Preferably, oxidation inhibitor is selected from one or more in antioxidant 1010, antioxidant 300, irgasfos 168, oxidation inhibitor 2264, antioxidant 264, anti-oxidant DLTP and oxidation inhibitor ODP.
Compared with prior art, the present invention has the following advantages: the first, and ceramic polyolefine flame resistant cable material of the present invention is containing any halogen composition, nontoxic, harmless, low cigarette and not containing heavy metal, meet the requirement of national security environmental protection; The second, ceramic polyolefine flame resistant cable material of the present invention, through high temperature or flame, can form hard ceramic package and cover on cable, thus can improve the fire resistance rating of electric wire; 3rd, ceramic polyolefine flame resistant cable material of the present invention does not need special extrusion equipment in the cable course of processing, can use common extruding machine, easy to process; 4th, the cost ratio of ceramic polyolefine flame resistant cable material of the present invention exist in the market fire-resistant, fp cable material is low.In sum, ceramic polyolefine flame resistant cable material price of the present invention is low, complete processing is simple, nontoxic, harmless, low cigarette, not containing heavy metal, have a good application prospect.
Accompanying drawing explanation
Fig. 1 is the cable cross-sectional schematic using cable material of the present invention.
In figure: 1, conductor; 2, internal shield; 3, crosslinked polyetylene insulated layer; 4, external shielding layer; 5, copper strip shielding layer; 6, alkali-free glass yarn packing layer; 7, glass band; 8, oxygen barrier layer; 9, fireproof oxygen-separation layer; 10, glass band; 11, steel-tape armouring layer; 12, low smoke and zero halogen oversheath.
Embodiment
Below in conjunction with specific embodiments and the drawings, the present invention is described in further detail.
Embodiment 1
A kind of ceramic polyolefine flame resistant cable material, by weight, it is prepared from by following component (table 1).
Table 1
The test result of the cable material obtained by the present embodiment 1 is as following table 2.
Table 2
Embodiment 2
A kind of ceramic polyolefine flame resistant cable material, by weight, it is prepared from by following component (table 3).
Table 3
The test result of the cable material obtained by the present embodiment 2 is as following table 4.
Table 4
Embodiment 3
A kind of ceramic polyolefine flame resistant cable material, by weight, it is prepared from by following component (table 5).
Table 5
The test result of the cable material obtained by the present embodiment 3 is as following table 6.
Table 6
The preparation method of ceramic fire-resistant polyolefin cable material of the present invention is as follows: polyolefine, compatilizer, fire retardant and oxidation inhibitor are added banburying in Banbury mixer, Vitrified powder is added and lubricant continues banburying about banburying to 100 DEG C, fusing assistant is added about banburying to 125 DEG C, and stop banburying about banburying to 175 DEG C, then cut into pellet with twin-screw extrusion above-mentioned materials.
Can be learnt by above embodiment, the hardness of ceramic polyolefine flame resistant cable material of the present invention, tensile strength and elongation are good, and flame retardant rating is high, at 950 DEG C of burnings, 3 hours ceramics, hard, loud and clear, still can ensure fundamental property.Thus, ceramic polyolefine flame resistant cable material various aspects of performance of the present invention is excellent, has a good application prospect.
Ceramic polyolefine flame resistant cable material of the present invention can be used in the construction of cable, such as, the construction of cable shown in Fig. 1.A kind of construction of cable is illustrated in Fig. 1, wherein be coated with internal shield 2 outside conductor 1, the crosslinked polyetylene insulated layer 3 of external parcel, external shielding layer 4, copper strip shielding layer 5 and alkali-free glass fiber yarn packing layer 6 is provided with outside insulation layer 3, be enclosed with glass band 7, oxygen barrier layer 8(thickness 2-4mm subsequently from inside to outside successively), fireproof oxygen-separation layer 9(thickness 5.5-6.5mm, thickness >=8mm without steel armour), glass band 10, steel-tape armouring layer 11 and low smoke and zero halogen oversheath 12(do not drip, do not drop, complete after burning).Wherein, fireproof oxygen-separation layer 9 and low smoke and zero halogen oversheath 12 adopt ceramic polyolefine flame resistant cable material of the present invention, make cable have good fire performance, and environmental protection.
Ceramic polyolefine flame resistant cable material of the present invention is when high temperature, fire by polyolefin plastics Low fire ceramic shape supporter, and after burning, resistates forms cellular hard ceramic protective layer.On the one hand, this ceramic-like supporter can play the effect of heat insulation, thermal insulation, gear fire, can also bear spray, vibrations, thus protection electric wire ensures that circuit is unimpeded in the case of fire; On the other hand, the ceramic-like supporter of compact and firm does not drip, and does not prolong combustion, the intensity of a fire can be suppressed to spread, play well fire-retardant, fire-resistant effect.
The invention solves following problem: one, during existing electric wire burning, cannot continue to keep basic function; Two, refractory materials is processed into the complex process of cable in the market, and material cost is expensive.
Above specific embodiment of the present invention is illustrated; but protection content of the present invention is not only limited to above embodiment; in art of the present invention, the usual knowledge of a GPRS, just can carry out diversified change within the scope of its technology main idea.
Claims (10)
1. a ceramic polyolefine flame resistant cable material, is characterized in that: by weight, is made up of following component:
Polyolefine, 40-100 part;
Compatilizer, 1-30 part;
Vitrified powder, 350-500 part;
Fusing assistant, 20-200 part;
Fire retardant, 20-100 part;
Lubricant, 2-20 part; And
Oxidation inhibitor, 1-10 part;
Wherein, described polyolefine is selected from one or more in ethylene-vinyl acetate copolymer, polypropylene, polystyrene, polyethylene and polyolefin elastomer;
Described Vitrified powder is selected from one or more in potter's clay, talcum powder, mica powder, agalmatolite, szaibelyite, datolite, calcite, Wingdale, wollastonite, triphane and clay.
2. ceramic polyolefine flame resistant cable material according to claim 1, is characterized in that: by weight, comprises following component:
Polyolefine, 60-100 part;
Compatilizer, 1-20 part;
Vitrified powder, 350-450 part;
Fusing assistant, 100-200 part;
Fire retardant, 50-90 part;
Lubricant, 5-10 part; And
Oxidation inhibitor, 1-10 part.
3. ceramic polyolefine flame resistant cable material according to claim 1, is characterized in that: by weight, comprises following component:
Polyolefine, 70 parts;
Compatilizer, 7.5 parts;
Vitrified powder, 400 parts;
Fusing assistant, 140 parts;
Fire retardant, 70 parts;
Lubricant, 5 parts; And
Oxidation inhibitor, 1 part.
4. ceramic polyolefine flame resistant cable material according to claim 1, is characterized in that: by weight, comprises following component:
Polyolefine, 40 parts;
Compatilizer, 30 parts;
Vitrified powder, 350 parts;
Fusing assistant, 20 parts;
Fire retardant, 20 parts;
Lubricant, 2 parts; And
Oxidation inhibitor, 5 parts.
5. ceramic polyolefine flame resistant cable material according to claim 1, is characterized in that: by weight, comprises following component:
Polyolefine, 100 parts;
Compatilizer, 1 part;
Vitrified powder, 500 parts;
Fusing assistant, 200 parts;
Fire retardant, 100 parts;
Lubricant, 20 parts; And
Oxidation inhibitor, 10 parts.
6. the ceramic polyolefine flame resistant cable material according to any one of claim 1-5, it is characterized in that: described compatilizer is selected from one or more in grafted maleic anhydride compatilizer, acrylic type compatilizer, epoxide resin type compatilizer, the polystyrene of oxazoline grafting, modified polyacrylate compatilizer and m-pseudoallyl-2,2-methyl benzoyl isocyanic ester.
7. the ceramic polyolefine flame resistant cable material according to any one of claim 1-5, is characterized in that: described fusing assistant is selected from one or more in glass powder, ceramics powder, glass fibre.
8. the ceramic polyolefine flame resistant cable material according to any one of claim 1-5, is characterized in that: described fire retardant is selected from one or more in antimonous oxide, aluminium hydroxide, magnesium hydroxide, magnesium basic carbonate, kaolin, zinc borate, ammonium polyphosphate and red phosphorus.
9. the ceramic polyolefine flame resistant cable material according to any one of claim 1-5, is characterized in that: described lubricant is selected from one or more in stearylamide, amine hydroxybenzene, silicone adhesive, calcium stearate, Zinic stearas, lipid acid, methyl-silicone oil and whiteruss.
10. the ceramic polyolefine flame resistant cable material according to any one of claim 1-5, is characterized in that: described oxidation inhibitor is selected from one or more in antioxidant 1010, antioxidant 300, irgasfos 168, oxidation inhibitor 2264, antioxidant 264, anti-oxidant DLTP and oxidation inhibitor ODP.
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Cited By (25)
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CN105761839A (en) * | 2016-04-29 | 2016-07-13 | 东莞市民兴电缆有限公司 | High-flexibility fireproof cable and preparation method thereof |
CN106009140A (en) * | 2016-06-24 | 2016-10-12 | 安徽宜德电子有限公司 | Environment-friendly type ultra-hard ceramization polyolefin cable material formula |
CN106800692A (en) * | 2016-12-20 | 2017-06-06 | 安徽华天电缆有限公司 | A kind of good waterproof polyethylene cable material of heat endurance |
CN107017043A (en) * | 2017-05-18 | 2017-08-04 | 无锡市新阳光电缆有限公司 | Fire proof power cable is pressed in one kind |
CN107221376A (en) * | 2017-06-23 | 2017-09-29 | 安徽华通电缆集团有限公司 | A kind of environment-friendly type railway station building low-voltage-powered cable of fire resisting |
CN108648868A (en) * | 2018-05-10 | 2018-10-12 | 江苏亨通线缆科技有限公司 | A kind of fiber reinforced fireproof cable |
CN109102929A (en) * | 2018-08-02 | 2018-12-28 | 安徽扬子线缆有限公司 | A kind of resistance to oxidation cable and its production method |
CN109243682A (en) * | 2018-09-04 | 2019-01-18 | 江苏华远电缆有限公司 | Resistance to 500 DEG C of high-temperature cables and preparation method thereof |
CN109320844A (en) * | 2018-10-11 | 2019-02-12 | 安庆市泽烨新材料技术推广服务有限公司 | Halogen-free flame-proof reinforced polypropylene composite material and preparation method thereof |
CN109319805A (en) * | 2017-08-01 | 2019-02-12 | 江苏宝源高新电工有限公司 | A kind of preparation method of ceramics fluxing agent and ceramic fluxing agent and its application |
CN109337206A (en) * | 2018-10-11 | 2019-02-15 | 安庆市泽烨新材料技术推广服务有限公司 | Reinforced polypropylene compound material and preparation method thereof |
CN109810371A (en) * | 2017-11-22 | 2019-05-28 | 宝胜科技创新股份有限公司 | A kind of thermoplastic halogen-free and low-smoke flame-retardant can ceramic polyolefin oxygen barrier material |
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CN112759822A (en) * | 2020-12-28 | 2021-05-07 | 苏州铂玛新材料有限公司 | Fireproof fire-resistant ceramic flame-retardant low-smoke halogen-free polyolefin composition and application thereof |
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CN116144091A (en) * | 2022-08-29 | 2023-05-23 | 广东安迪新材料科技有限公司 | Ceramic refractory polyolefin material |
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