CN105347446A - Ionization type advanced oxidation reactor - Google Patents
Ionization type advanced oxidation reactor Download PDFInfo
- Publication number
- CN105347446A CN105347446A CN201510953432.9A CN201510953432A CN105347446A CN 105347446 A CN105347446 A CN 105347446A CN 201510953432 A CN201510953432 A CN 201510953432A CN 105347446 A CN105347446 A CN 105347446A
- Authority
- CN
- China
- Prior art keywords
- electrode
- housing
- insulation plate
- anodic
- casing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
- C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The invention relates to an ionization type advanced oxidation reactor. The ionization type advanced oxidation reactor comprises an external flange seal cover and an external flange on a casing, wherein the external flange seal cover and the external flange on the casing are in sealed connection into a whole through screws; an electrode seal insulation board and an internal flange in the casing are in sealed connection through screws; a power connection chamber is formed between the external flange seal cover and the electrode seal insulation board; a water inlet and a water outlet in the casing, the electrode seal insulation board and the internal flange in the casing are in sealed connection through screws to form a closed water flow channel; a negative electrode and a positive electrode are fixed in the casing by an electrode fixing guide plate, and wiring lugs of the negative electrode and the positive electrode penetrate through the electrode seal insulation board and are integrally connected in series through a negative electrode terminal and a positive electrode terminal correspondingly, led out by negative and positive electrode wires through a negative and positive electrode wire access port and correspondingly connected with a dedicated direct-current power output end.
Description
Technical field
The present invention relates to a kind of is medium with water, by the energy gesture of the transition of electron at negative and positive the two poles of the earth under extra electric field, ionizing water molecule obtains the efficient oxidation reactor of the oxidizing substance of high density, particularly to the device that the material of polypeptide long-chain ring texture carries out open loop, effective oxygenolysis is carried out in fragmentation, use this device effectively can remove the Algae toxins in water body, viral germ, chemical intermediate, organic compound, peculiar smell, colourity.
Background technology
Reform and open up to the outside world over more than 30 year, economic quick growth causes many environmental pollutions and safe drinking water problem.Such as the middle compound body of scientific and technical innovation organifying work, bio-pharmaceuticals is of a great variety, and these polypeptide ring texture materials enter after in water body, and conventional water technology is difficult to oxygenolysis polluted water resources; Growing process Pesticides is rapidly absorbed in cell paste, causes food poisoning phenomenon to happen occasionally; The eutrophication aggravation at water source, the algae of water body is increased, and it is innumerable to the healthy and safe example of threat etc. that brings of the common people that wide spectrum algicide makes Algae toxins discharge in Drinking w ater.Researching and developing a kind of less energy-consumption general high-level oxidation technology applied widely is the demand improving environmental quality and ensure people's health, and being the top priority realizing national recycling economy, low carbon development, is also the trend of future development.
The present inventor is based on electrochemistry, take materialogy as a kind of multiduty advanced oxidation reactor technologies of point of penetration research and development, use this reactor technology device can carry out effective Strong oxdiative decomposition to the organic pollutant in the waste water of chemical industry, pharmaceutical industry, simultaneously can carry out effective oxygenolysis to the organic contamination in the percolate of high density, Sewage Plant residue water-containing sludge, use this device effectively can also to degrade to the residual organic pesticide in Algae toxins in water body and gourd, fruit and vegetable, grain, tealeaves.
Summary of the invention
The object of the invention is to: for the defect existed in prior art or deficiency; thering is provided a kind of is base material with titanium; surface-coated sintering rare-earth mixes up alloy as catalyst material as positive and negative electrode; be that medium ionizes with water under DC Electric Field; the oxidizing substance producing high density carries out Strong oxdiative decomposition to the organic pollutant in water body; reach protection of the environment, ensure healthy object.
The technical solution used in the present invention is such: a kind of ionization type advanced oxidation reactor, comprise outward flange sealing cover 1 and be tightly connected into an entirety with outward flange 2 screw on housing 5, inside flange 4 in electrode sealed insulation plate 3 and housing 5 is tightly connected with screw, form one between outward flange sealing cover 1 and electrode sealed insulation plate 3 and connect electric room 10, water-in 9 on housing 5, a closed water stream channel is formed after inside flange 4 in water outlet and electrode sealed insulation plate 3 and housing is tightly connected with screw, electrode is fixed flow deflector 7 and is fixed on by anodic-cathodic in housing 2, the wiring ear through electrode sealed insulation plate 3 of anodic-cathodic, the wiring ear of anodic-cathodic is connected into one by cathode connection end 13 and anode connection end 14 correspondence respectively, be connected corresponding with special DC power output end is drawn through anode and cathode wire access port 15 by negative and positive wire.
Further, described electrode sealed insulation plate 3 is nylon material, the sheet fabrication being 10mm by the wall thickness with insulation and anti-pressure ability forms, the wide, long of wire casing wide, long regulating YIN and YANG electrode connection ear penetrated for anodic-cathodic wiring ear is equal to, after anodic-cathodic wiring ear through electrode sealed insulation plate 3, fix with the sealing gap of epoxy resin to its wire casing.
In sum, owing to have employed technique scheme, the invention has the beneficial effects as follows: ionization type advanced oxidation reactor of the present invention, anodic-cathodic have employed rare earth alloy metal oxide doped with rare earth catalytic material as catalytic specie, the turnover ratio of electrode electric current effect under extra electric field is made to reach 85%, comparing efficiency with existing electrochemical techniques improves more than 8 times, be that medium excites the oxidizing substance of generation (OH) concentration to be 14 times of existing electrochemical techniques under equal voltage conditions with water, to the clearance of Organic Pollutants up to 99%, 99.95% is reached to the clearance of bacteriophage.The present invention can be widely used in wastewater from chemical industry, paper waste, percolate, the process at drinking-water water source and disposal, effectively can remove remaining in food pest when using as oxidant generator, may be used for the degraded of melon and fruit, vegetables, tealeaves remains of pesticide simultaneously, also can be used for the exterminating bacterium of medical device.
Accompanying drawing explanation
Examples of the present invention will be described by way of reference to the accompanying drawings, wherein:
Fig. 1 of the present inventionly overlooks end diagrammatic cross-section;
Fig. 2 is interarea sectional view of the present invention.
Embodiment
All features disclosed in this specification sheets, or the step in disclosed all methods or process, except mutually exclusive feature and/or step, all can combine by any way.
Arbitrary feature disclosed in this specification sheets (comprising any accessory claim, summary and accompanying drawing), unless specifically stated otherwise, all can be replaced by other equivalences or the alternative features with similar object.That is, unless specifically stated otherwise, each feature is an example in a series of equivalence or similar characteristics.
A kind of ionization type advanced oxidation reactor as illustrated in figs. 1 and 2, comprise outward flange sealing cover 1 and be tightly connected into an entirety with outward flange 2 screw on housing 5, inside flange 4 in electrode sealed insulation plate 3 and housing 5 is tightly connected with screw, form one between outward flange sealing cover 1 and electrode sealed insulation plate 3 and connect electric room 10, water-in 9 on housing 5, a closed water stream channel is formed after inside flange 4 in water outlet and electrode sealed insulation plate 3 and housing is tightly connected with screw, electrode is fixed flow deflector 7 and is fixed on by anodic-cathodic in housing 2, the wiring ear through electrode sealed insulation plate 3 of anodic-cathodic, the wiring ear of anodic-cathodic is connected into one by cathode connection end 13 and anode connection end 14 correspondence respectively, be connected corresponding with special DC power output end is drawn through anode and cathode wire access port 15 by negative and positive wire.
Further, described housing 5 is Plate Welding or injection molded, its geometrical shape is rectangular parallelepiped or other solid, use inside and outside the housing 5 after steel plate material welding and need to do special anti-corrosive treatment, described outward flange sealing cover 1 needs lining asbestos pad to do insulation layer when being connected with sealed screw with the outward flange 2 on housing 5, inside flange 4 in described electrode sealed insulation plate 3 and housing 5 needs lining silica gel sealing pad to carry out sealed insulation when being tightly connected with screw, the gap formed after the wiring ear through electrode sealed insulation plate 3 of anodic-cathodic need be carried out sealing and curing in proportion by epoxy resin reinforcing agent and be fixed, described electrode is fixed flow deflector 7 and is fixed in housing 5 by anodic-cathodic by certain distance, described cathode connection end 13 and anode connection end 14 process for red copper bar, outside screw is processed at two of cathode connection end 13 and anode connection end 14, so that the connection of negative and positive cable wire, the keep right position of described water-in 9 bottom housing 5, water outlet 6 is in the position that keeps left on the top of housing 5.
Concrete, described electrode sealed insulation plate 3 is nylon material, the sheet fabrication being 10mm by the wall thickness with insulation and anti-pressure ability forms, the wide, long of wire casing wide, long regulating YIN and YANG electrode connection ear penetrated for anodic-cathodic wiring ear is equal to, after anodic-cathodic wiring ear through electrode sealed insulation plate 3, fix with the sealing gap of epoxy resin to its wire casing.
Concrete, described cathode connection end 13 be a red copper bar processed by all cathode connection ear cross-under together, add red copper cap between negative electrode ear to separate, when making the fastened by screw at two ends, negative electrode ear ensures do not offset and be out of shape, and anode connection end 14 is identical with the operating method of cathode connection end 13.
To the experiment of wastewater of chemical industry with high concentration.
Experimental installation:
Sump pump, under meter, ionization type oxidation reactor, direct supply etc.
Experimental procedure:
The container bottom perforate of depositing sewage is connected with sump pump, mounted valve and glass rotameter in sump pump water outlet pipeline, the water-in of ionization type oxidation reactor is connected with sump pump water outlet pipeline, the container that water outlet and another of ionization type oxidation reactor deposit liquid is connected with pipeline, the negative and positive wire of ionization type oxidation reactor is connected with special direct supply correspondence, connects input power.
Start sump pump, regulate flooding velocity, start direct supply, by pollutant concentration index in sewage, waste water body residence time in ionization type oxidation reactor is respectively 10 minutes, 20 minutes.
Detect data sheet: (chemical industry composite wastewater)
| Sample ID | Wastewater from chemical industry | Oxidation in 10 minutes | Clearance | Be oxidized 20 minutes | Clearance |
| CODcr | 1200mg/L | 180mg/L | 85％ | 60mg/L | 95％ |
| TN | 33.5mg/L | 8.4mg/L | 75％ | 5.0mg/l | 85％ |
Above-described specific embodiment, further describes object of the present invention, technical scheme and beneficial effect, and institute it should be understood that and the foregoing is only specific embodiments of the invention, is not limited to the present invention.The present invention expands to any new feature of disclosing in this manual or any combination newly, and the step of the arbitrary new method disclosed or process or any combination newly.
Claims (2)
1. an ionization type advanced oxidation reactor, it is characterized in that: comprise outward flange sealing cover and be tightly connected into an entirety with the outward flange screw on housing, inside flange screw in electrode sealed insulation plate and housing is tightly connected, form one between outward flange sealing cover and electrode sealed insulation plate and connect electric room, water-in on housing, a closed water stream channel is formed after inside flange screw in water outlet and electrode sealed insulation plate and housing is tightly connected, electrode is fixed flow deflector and is fixed in housing by anodic-cathodic, the wiring ear through electrode sealed insulation plate of anodic-cathodic, the wiring ear of anodic-cathodic is connected into one by cathode connection end and anode connection end correspondence respectively, be connected corresponding with special DC power output end is drawn through anode and cathode wire access port by negative and positive wire.
2. ionization type advanced oxidation reactor according to claim 1, it is characterized in that: described electrode sealed insulation plate is nylon material, the sheet fabrication being 10mm by the wall thickness with insulation and anti-pressure ability forms, the wide, long of wire casing wide, long regulating YIN and YANG electrode connection ear penetrated for anodic-cathodic wiring ear is equal to, after anodic-cathodic wiring ear through electrode sealed insulation plate, fix with the sealing gap of epoxy resin to its wire casing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510953432.9A CN105347446A (en) | 2015-12-16 | 2015-12-16 | Ionization type advanced oxidation reactor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510953432.9A CN105347446A (en) | 2015-12-16 | 2015-12-16 | Ionization type advanced oxidation reactor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105347446A true CN105347446A (en) | 2016-02-24 |
Family
ID=55323543
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510953432.9A Pending CN105347446A (en) | 2015-12-16 | 2015-12-16 | Ionization type advanced oxidation reactor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105347446A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1372998A (en) * | 2001-02-28 | 2002-10-09 | 中国科学院生态环境研究中心 | Coiled electrodialyzer |
| CN201169550Y (en) * | 2008-02-22 | 2008-12-24 | 山东良成环保工程有限公司 | Micro-electrolysis dirty-proof bactericidal finishing apparatus |
| CN101462036A (en) * | 2008-12-24 | 2009-06-24 | 常州浩瀚新材料科技有限公司 | Technique and device for preparing pure broad-spectrum insecticide |
| CN101811759A (en) * | 2010-03-23 | 2010-08-25 | 新疆科力新技术发展有限公司 | Electro-flotation testing device for oil field sewage |
| CN103118990A (en) * | 2010-09-30 | 2013-05-22 | 大金工业株式会社 | Electrolysis device and heat-pump-type water heater provided with same |
| CN203144185U (en) * | 2013-01-25 | 2013-08-21 | 北京一水方源科技有限公司 | Electrochemical water treatment device |
| CN203212368U (en) * | 2013-04-24 | 2013-09-25 | 梁凤鸣 | Electrochemical waste water treatment device |
| CN104409783A (en) * | 2014-11-14 | 2015-03-11 | 江苏华富储能新技术股份有限公司 | Method using rare earth for modification of lead storage battery electrode plates |
-
2015
- 2015-12-16 CN CN201510953432.9A patent/CN105347446A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1372998A (en) * | 2001-02-28 | 2002-10-09 | 中国科学院生态环境研究中心 | Coiled electrodialyzer |
| CN201169550Y (en) * | 2008-02-22 | 2008-12-24 | 山东良成环保工程有限公司 | Micro-electrolysis dirty-proof bactericidal finishing apparatus |
| CN101462036A (en) * | 2008-12-24 | 2009-06-24 | 常州浩瀚新材料科技有限公司 | Technique and device for preparing pure broad-spectrum insecticide |
| CN101811759A (en) * | 2010-03-23 | 2010-08-25 | 新疆科力新技术发展有限公司 | Electro-flotation testing device for oil field sewage |
| CN103118990A (en) * | 2010-09-30 | 2013-05-22 | 大金工业株式会社 | Electrolysis device and heat-pump-type water heater provided with same |
| CN203144185U (en) * | 2013-01-25 | 2013-08-21 | 北京一水方源科技有限公司 | Electrochemical water treatment device |
| CN203212368U (en) * | 2013-04-24 | 2013-09-25 | 梁凤鸣 | Electrochemical waste water treatment device |
| CN104409783A (en) * | 2014-11-14 | 2015-03-11 | 江苏华富储能新技术股份有限公司 | Method using rare earth for modification of lead storage battery electrode plates |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1133594C (en) | Method and apparatus for electrocoagulation of liquids | |
| CN104478073B (en) | A kind of device utilizing ABR-bio electricity Fenton coupling technique to process difficult for biological degradation industrial wastewater | |
| CN104310534B (en) | Produce the water treatment system of technology based on ozone and hydrogen peroxide simultaneously | |
| CN104773888A (en) | Iron-carbon inner electrolysis-Fenton oxidation-electrolytic electrocatalytic oxidation combined wastewater treatment method and device | |
| CN212865010U (en) | Electrolytic ozone generator with simple structure | |
| CN105731604A (en) | Advanced treatment method for electroplating wastewater | |
| CN203419777U (en) | Electrochemical device for water treatment | |
| CN102642977B (en) | Waste water treatment system | |
| CN108545812A (en) | Based on electromagnetic field couples photoelectricity Fenton organic waste-water treating apparatus | |
| CN110589938B (en) | Method for treating toxic and nondegradable wastewater by coupling electrolysis-ozone-corrosion inhibitor/electrolysis-ozone-hydrogen peroxide-corrosion inhibitor | |
| CN102603133B (en) | Regeneration and utilization device and method thereof for sludge from sewage plant | |
| CN101712501A (en) | Method for treating waste water containing chlorophenols compounds and special device thereof | |
| CN105498660A (en) | Improved ionization type oxidation reactor | |
| CN105347446A (en) | Ionization type advanced oxidation reactor | |
| CN203048643U (en) | Catalyzed oxidation inertness electrode plate, compound electrode and device for processing high-COD (Chemical Oxygen Demand) sewage | |
| CN209098273U (en) | Apparatus for electrochemical treatment for landfill leachate MBR water outlet | |
| CN209128105U (en) | A kind of high-frequency electromagnetic catalyst reaction device administered for trade effluent | |
| CN103896372B (en) | Glow discharge associated treatment is utilized to contain As (III), the method for Cr (VI) waste water and device thereof | |
| CN110902995A (en) | Biochemical excess sludge and wastewater composite oxidation treatment device and treatment method thereof | |
| CN209815742U (en) | Electrocatalytic oxidation device for electroplating wastewater treatment | |
| CN210214887U (en) | Sewage treatment electrochemical reactor with ultralow power consumption | |
| CN108217861A (en) | A kind of internal-circulation type electrocatalysis oxidation reaction device and method for cleaning treatment of sewage | |
| CN211394248U (en) | Biochemical excess sludge and waste water composite oxidation treatment device | |
| CN106044958B (en) | A kind of plural serial stage spheroidal particle active electrode reaction unit | |
| US10961137B2 (en) | Water treatment system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160224 |
|
| WD01 | Invention patent application deemed withdrawn after publication |