CN105332321A - Expansion type flame retardant and application thereof to nonwoven foaming inflaming-retarding fireproof wallpaper - Google Patents
Expansion type flame retardant and application thereof to nonwoven foaming inflaming-retarding fireproof wallpaper Download PDFInfo
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Abstract
The invention discloses an expansion type flame retardant and application thereof to a nonwoven foaming inflaming-retarding fireproof wallpaper. The expansion type flame retardant is prepared from the following raw materials in parts by mass: 100 parts of a dehydration catalyst, 0.05 to 10 parts of an expansion carburizing agent, 1 to 50 parts of a foaming carbon forming agent and 1 to 100 parts of an auxiliary foaming and enhancing agent. The expansion type flame retardant is used for replacing part of calcium triple superphosphate and titanium dioxide in foaming slurry to prepare foaming slurry; the heat discharging quantity and a flame transmission speed in a wallpaper combustion process are reduced, and the concentrations of toxic gas and smoke are reduced when the nonwoven paper is combusted.
Description
Technical field
The present invention relates to fire-proof construction material field, relate more specifically to fireproof wallpaper field.
Background technology
Nonwoven foaming wallpaper take non-woven paper as base material, and transfer printing foamed slurry, flower pattern and color, through the ornament materials of high temperature foaming, be widely used in metope and ceiling decoration.
Non-woven paper produces for raw material with xylon or synthetic fiber, belongs to combustible material or combustible material; PVC paste resin P450 in foamed slurry and dioctyl phthalate (DOP), foaming carbon forming agent, microballoon blowing agent (PG20), epoxy soybean wet goods combustible material.Therefore, understand rapid catching fire after fire met by wallpaper, spread and discharge a large amount of pernicious gas and smog, the people's lives and property safety in serious threat.
For eliminating disaster hidden-trouble, the Ministry of Public Security and the Ministry of Construction issued and implemented " code for fire prevention design of interior decoration of buildings " in 1992, State Administration for Quality Supervision and Inspection and Quarantine has issued GB8624-2006 " construction material and product burns grading performance " in 2006, GB/T20284-2006 " the monomer combustion tests of construction material or goods ", five mandatory standards such as GB/T20285-2006 " classification of material producing smoke toxicity risk " and GB20286-2006 " public place fire-retardant product and assembly combustibility require and mark ", concrete regulation has been done to the combustibility of architectural decorative and fitting materials, require that the decorating and renovating material combustibility being applied to public building and high-rise civil building is necessary for incombustible material (A level) or nonflammable material (B1 level).
Therefore, development does not change the technological process of production of wallpaper and performance, cost is low, combustibility meets 8624-2012 " construction material and product burns grading performance " incombustible material (A level) or nonflammable material (B1 level) fire-retardant fireproof wallpaper, to the Application Areas expanding wallpaper, the disaster hidden-trouble reducing wallpaper is significant.Therefore, need to provide a kind of fire retardant, comprise decorating and renovating material that this fire retardant has and have and do not fire or the performance of difficult combustion.
Summary of the invention
First technical problem that the present invention will solve is to provide a kind of fire retardant, comprises decorating and renovating material that this fire retardant has and has and do not fire or the performance of difficult combustion.
Another technical problem that will solve of the present invention is to provide the application of a kind of fire retardant in nonwoven foamed flame retardant fireproof wallpaper.Fire-retardant fireproof wallpaper of the present invention, technique is simple, and cost is low, while imparting wallpaper fire-retardant fireproof function, remains the decorative effect of wallpaper completely.The fire resistance of wallpaper reaches incombustible material (A level) or nonflammable material (B1 level) (GB8624-2012).
For solving the problems of the technologies described above, the present invention adopts following technical proposals:
A kind of expansion type flame retardant, this fire retardant is made up of the raw material of following masses part:
Dehydration catalyst: 100;
Expansion carburization agent: 0.05 ~ 10;
Foaming carbon forming agent: 1 ~ 50;
Auxiliary foaming and reinforcing agent: 1 ~ 100.
Preferably, described expansion type flame retardant is made up of the raw material of following masses part:
Dehydration catalyst: 100;
Expansion carburization agent: 0.1 ~ 2.0;
Foaming carbon forming agent: 10 ~ 30;
Auxiliary foaming and reinforcing agent: 10 ~ 30.
Described dehydration catalyst be selected from boric acid, ammonium hydrogen phosphate, ammonium dihydrogen phosphate (ADP), APP, melamine cyanurate, melamine phosphate, melamine burnt microcosmic salt, melamine Quadrafos, guanyl-urea-phosphate, dicyandiamidines, phosphoguanidine, phosphate Guanoctine and polyphosphoric acid guanidine one or more.
Described expansion carburization agent refers to expanded graphite.
Described foaming carbon forming agent refers to cyanurotriamide modified urea resin rubber powder and/or melamine resin adehsive powder that melamine mass percent is greater than 3.0%.
Described auxiliary foaming and reinforcing agent refers to aluminium hydroxide or/and magnesium hydroxide.
Described fire retardant belongs to expansion type flame retardant.The fire retardant mechanism of expansion type flame retardant is as follows: when wallpaper runs into burning things which may cause a fire disaster or long-time high temperature (>=220 DEG C) effect, expansion carburization agent first expanded by heating, make the coating layer thickness of wallpaper be expanded to 2 ~ 50 times, isolated thermal source is to the transmission of foaming layer and non-woven paper; Dehydration catalyst endothermic decomposition, discharges acid source, as catalyst, the compound of the hydroxyls such as cellulose is dewatered, generates inactive C=C structure, and discharge steam; Foam carbon forming agent in temperature lower than the adhesive as whole system when 300 DEG C; Along with the further raising of system temperature, foaming carbon forming agent decomposes under the effect of dehydration catalyst and temperature, discharges a large amount of non-flammable gases, together with the steam that auxiliary foaming and reinforcing agent pyrolysis discharge, foaming layer is expanded further, the transmission of isolated heat, and produce endothermic effect; Foaming carbon forming agent produce C=C together with expansion carburization agent, as the skeleton of expanding layer; Assist foaming and reinforcing agent and dehydration catalyst to react and generate high temperature adhesive polyphosphoric acids aluminium and magnesium phosphate, cover carbon source surface, play cementation, viscous fluid has cut off the convect h of thermal source.
In expansion type flame retardant system, when the parts by mass of dehydration catalyst is 100, the parts by mass of expansion carburization agent is less than 0.05, and because addition is very few, the effect of the cumulative volume after its expanded by heating to expansion type flame retardant system is ignored substantially; When the mass fraction of expansion carburization agent reaches 0.1 part, when wallpaper coating is subject to burning things which may cause a fire disaster or Source, coating layer thickness is inflatable to 2.0 times; When the mass fraction of expansion carburization agent reaches 10.0 parts, when wallpaper coating is subject to burning things which may cause a fire disaster or Source, coating layer thickness is inflatable to 50.0 times; When the mass fraction of expansion carburization agent is greater than 10.0 parts, when wallpaper coating is subject to burning things which may cause a fire disaster or Source, coating acutely expands, and is difficult to form carburization zone fine and close continuously, reduces the flame retardant effect of fire retardant on the contrary.
In expansion type flame retardant system, when the parts by mass of dehydration catalyst is 100, the mass fraction of foaming carbon forming agent is less than 1.0, because addition is very few, can not play the adhesive effect to system, the effect of the non-flammable compressive gas that its decomposes goes out to expansion type flame retardant system is ignored substantially; When the mass fraction of the carbon forming agent that foams reaches 10 parts, can meet the adhesive effect to system, the combustable gas concentration discharged when the non-flammable compressive gas that pyrolysis discharges effectively can dilute wallpaper burning, makes system expand further; When the mass fraction of the carbon forming agent that foams is greater than 50.0 parts, causes the mass percent of dehydration catalyst in fire retardant systems to reduce, have impact on the dehydration carbonization of methylol, reduce the flame retardant effect of fire retardant on the contrary.
In expansion type flame retardant system, when the parts by mass of dehydration catalyst is 100 parts, the mass fraction of auxiliary foaming and reinforcing agent is less than 1.0, and because addition is very few, the effect of steam to expansion type flame retardant system that its heat absorption and pyrolysis discharge is ignored substantially; When the mass fraction of auxiliary foaming and reinforcing agent reaches 10 parts, heat-absorbing action effectively can reduce the speed that system temperature rises, the combustable gas concentration discharged when the steam that pyrolysis discharges effectively can dilute wallpaper burning; When the mass fraction of auxiliary foaming and reinforcing agent is greater than 100.0, causes the mass percent of dehydration catalyst in fire retardant systems to reduce, have impact on the dehydration carbonization of methylol, reduce the flame retardant effect of fire retardant on the contrary.
Expansion type flame retardant can be applicable to the manufacture of nonwoven foamed flame retardant fireproof wallpaper.
Use the manufacture method of the nonwoven foamed flame retardant fireproof wallpaper of described expansion type flame retardant, comprise the steps:
Non-woven paper is contained on uncoiler;
Allocate flame-retardant expanded slurry;
Flame-retardant expanded slurry is transferred on non-woven paper, dry;
High temperature foaming;
Cooling, cutting edge, block, check, rolling, packaging, make fire-retardant fireproof wallpaper.
Preferably, described transfer printing can according to flower pattern needed for product and color, can repeatedly transfer printing.
Described drying adopts heat-conducting oil heating mode drying air box dry.
Described being cooled to utilizes chill roll to cool.
Described flame-retardant expanded slurry comprises the raw material of following parts by mass:
Polyvinyl chloride (P450): 30 ~ 80;
Dioctyl phthalate (DOP): 30 ~ 80;
Expansion type flame retardant: 15 ~ 110;
Coarse whiting: 5 ~ 50;
Titanium dioxide: 5 ~ 70;
AC foams carbon forming agent: 1 ~ 15;
Microballoon blowing agent (PG20): 2 ~ 20;
Alkane solvents (D80): 0.1 ~ 10;
Epoxidized soybean oil: 0.1 ~ 10;
Stabilizing agent: 0.1 ~ 10.
Preferably, described flame-retardant expanded slurry comprises the raw material of following parts by mass:
P450：45～60；
DOP：40～55；
Expansion type flame retardant: 22 ~ 77;
Coarse whiting: 15 ~ 35;
Titanium dioxide: 10 ~ 20;
AC foams carbon forming agent: 3 ~ 8;
PG20：4～8；
D80：1～3；
Epoxidized soybean oil: 1 ~ 3;
Stabilizing agent: 1 ~ 3.
The method of the flame-retardant expanded slurry of described allotment is: expansion type flame retardant raw material is loaded pulverizer, pulverizes, mixes, by screen clothes more than 80 orders; The raw material of described flame-retardant expanded slurry is mixed, filters in refiner.
By screen clothes more than 80 orders, be to obtain than just by powder that the powder in 80 mesh sieve holes is thinner.
In described flame-retardant expanded slurry, when the quality of expansion type flame retardant is below the 4.0wt% of foamed slurry, because the addition of expansion type flame retardant is not enough, the combustibility of wallpaper only can reach the combustible material (D level) that GB8624 specify and specify; When the quality of expansion type flame retardant is more than the 4.0wt% of foamed slurry, the combustibility of wallpaper reaches flame retardant material (B1-C level) regulation that GB8624 specifies; When the quality of expansion type flame retardant is more than the 10.0wt% of foamed slurry, the combustibility of wallpaper reaches flame retardant material (B1-B level) regulation that GB8624 specifies; When the quality of expansion type flame retardant is more than the 28.0wt% of foamed slurry, the combustibility of wallpaper reaches incombustible material (A level) regulation that GB8624 specifies; In flame-retardant expanded slurry, when the quality of expansion type flame retardant is more than the 40.0wt% of foamed slurry, along with the further raising of mass percent shared by fire retardant, the combustibility of fire-retardant fireproof wallpaper does not change substantially, the corresponding raising of cost of product; When the quality of expansion type flame retardant is more than foamed slurry 60.0wt%, the pliability of product and processing characteristics due to the addition of fire retardant excessive and reduce.
The mass percent difference that expansion type flame retardant is shared in flame-retardant expanded slurry, the burning behavior class of product is also different.When production combustibility meets the fire-retardant fireproof wallpaper of GB8624B1-C level, mass percent employing 4.0wt% ~ 10.0wt% that expansion type flame retardant is shared in flame-retardant expanded slurry; When production combustibility meets the fire-retardant fireproof wallpaper of GB8624B1-B level, mass percent employing 10.0wt% ~ 28.0wt% that expansion type flame retardant is shared in flame-retardant expanded slurry; Production combustibility meets GB8624A level when not firing wallpaper, and the mass percent shared in flame-retardant expanded slurry of expansion type flame retardant adopts 28.0wt% ~ 40.0wt%.
Beneficial effect of the present invention is as follows:
1, use the part coarse whiting in expansion type flame retardant replacement foamed slurry and titanium dioxide, be made into foamed slurry, the toxic gas when thermal discharge during burning of reduction wallpaper and flame propagation velocity, minimizing non-woven paper burn and flue gas concentration.
2, fire-retardant fireproof wallpaper manufacture method provided by the invention, when not changing the nonwoven foaming production technology of wallpaper, flow process and equipment, producing combustibility and flue gas toxity and meeting the fire-retardant fireproof wallpaper that GB8624-2012A level or B1-B level construction material specify.
3, fire-retardant fireproof wallpaper provided by the invention can be widely used in building interior decoration, has good economic benefit and social benefit.
Detailed description of the invention
In order to be illustrated more clearly in the present invention, below in conjunction with preferred embodiment, the present invention is described further.It will be appreciated by those skilled in the art that specifically described content is illustrative and nonrestrictive, should not limit the scope of the invention with this below.
Embodiment 1: the manufacture of expansion type flame-retarding fireproof wallpaper
Use the manufacture method of the nonwoven foamed flame retardant fireproof wallpaper of expansion type flame retardant, comprise the steps:
1) expansion type flame retardant is made up of the raw material of following weight portion:
Miaow base urea phosphate (catalytic dehydration): 70;
Boric acid (catalytic dehydration): 30
Expanded graphite (expansion carburization agent): 0.5;
Melamine resin powder (foaming carbon forming agent): 15;
Aluminium hydroxide (auxiliary foaming and reinforcing agent): 15.
Above-mentioned material loaded pulverizer, pulverizes, mix, for subsequent use by 80 object screen clothes.
2) flame-retardant expanded slurry forms according to following parts by mass:
Polyvinyl chloride (P450): 60;
Dioctyl phthalate (DOP): 55;
Expansion type flame retardant: 15;
Coarse whiting: 30;
Titanium dioxide: 20;
AC foams carbon forming agent: 6;
Microballoon blowing agent (PG20): 6;
Alkane solvents (D80): 2;
Epoxidized soybean oil: 2;
Stabilizing agent: 2.
Above-mentioned material is mixed in refiner, filter after for subsequent use.The mass percent of expansion type flame retardant shared by flame-retardant expanded slurry is 7.6wt%.
3) according to known nonwoven foam production technique and flow process, using is quantitatively that the non-woven paper of 120 grams/m produces fire-retardant fireproof wallpaper.
4) performance test results: gross calorific power 7.3MJ/m
2, HRR peak value 197.0kW/m
2, conclusion is B1-C level nonflammable material.
Comparative example 1
1) according to known nonwoven foam production technique and flow process, using identical with embodiment 1 is quantitatively the non-woven paper of 120 grams/m, produces wallpaper.
2) foamed slurry forms according to the raw material of following parts by mass:
P450：60；
DOP：55；
Fire retardant: 0;
Coarse whiting: 35;
Titanium dioxide: 30;
AC foams carbon forming agent: 6;
PG20：6；
D80：2；
Epoxidized soybean oil: 2;
Stabilizing agent: 2.
3) performance test results: gross calorific power 11.1MJ/m
2, HRR peak value 437.0kW/m
2, conclusion is D level combustible material.
Embodiment 2
Use the manufacture method of the nonwoven foamed flame retardant fireproof wallpaper of expansion type flame retardant, comprise the steps:
1) the raw material composition of the parts by mass of expansion type flame retardant:
Melamine cyanurate (catalytic dehydration): 85;
Ammonium dihydrogen phosphate (ADP) (catalytic dehydration): 15
Expanded graphite (expansion carburization agent): 0.5;
Melamine resin powder (foaming carbon forming agent): 15;
Aluminium hydroxide (auxiliary foaming and reinforcing agent): 15.
Above-mentioned material loaded pulverizer, pulverizes, mix, for subsequent use by 80 object screen clothes.
2) flame-retardant expanded slurry is made up of the raw material of following parts by mass:
P450：60；
DOP：55；
Expansion type flame retardant: 30;
Coarse whiting: 20;
Titanium dioxide: 10;
AC foams carbon forming agent: 6;
PG20：6；
D80：2；
Epoxidized soybean oil: 2;
Stabilizing agent: 2.
Above-mentioned material is mixed in refiner, filter after for subsequent use.The mass percent of expansion type flame retardant shared by flame-retardant expanded slurry is 15.5wt%.
3) according to known nonwoven foam production technique and flow process, using is quantitatively that the non-woven paper of 120 grams/m produces fire-retardant fireproof wallpaper.
4) performance test results: gross calorific power 4.7MJ/m
2, HRR peak value 62.0kW/m
2, conclusion is B1-B level nonflammable material.
Embodiment 3
Use the manufacture method of the nonwoven foamed flame retardant fireproof wallpaper of expansion type flame retardant, comprise the steps:
1) expansion type flame retardant is made up of the raw material of following parts by mass:
APP (catalytic dehydration): 80;
Phosphoguanidine (catalytic dehydration): 20
Expanded graphite (expansion carburization agent): 0.5;
Melamine resin powder (foaming carbon forming agent): 15;
Aluminium hydroxide (auxiliary foaming and reinforcing agent): 15.
Above-mentioned material loaded pulverizer, pulverizes, mix, for subsequent use by 80 object screen clothes.
2) flame-retardant expanded slurry is made up of the raw material of following parts by mass:
P450：55；
DOP：45；
Expansion type flame retardant: 55;
Coarse whiting: 10;
Titanium dioxide: 10;
AC foams carbon forming agent: 6;
PG20：6；
D80：2；
Epoxidized soybean oil: 2;
Stabilizing agent: 2.
Above-mentioned material is mixed in refiner, filter after for subsequent use.The mass percent of expansion type flame retardant shared by flame-retardant expanded slurry is 28.5wt%.
3) according to known nonwoven foam production technique and flow process, using is quantitatively that the non-woven paper of 120 grams/m produces fire-retardant fireproof wallpaper.
4) performance test results: gross calorific power 1.5MJ/m
2, HRR peak value 19.0kW/m
2, conclusion is A level incombustible material.
The product obtained by the embodiment of the present invention and comparative example are compared, can draw the following conclusions: adopt the nonwoven foamed flame retardant fireproof wallpaper that the present invention produces, its combustibility can reach the regulation of GB8624 nonflammable material (B1-B level) and incombustible material (A level), and the combustibility of comparative example is combustible material (D level).
Obviously; the above embodiment of the present invention is only for example of the present invention is clearly described; and be not the restriction to embodiments of the present invention; for those of ordinary skill in the field; can also make other changes in different forms on the basis of the above description; here cannot give exhaustive to all embodiments, every belong to technical scheme of the present invention the apparent change of extending out or variation be still in the row of protection scope of the present invention.
Claims (10)
1. an expansion type flame retardant, is characterized in that, this fire retardant is made up of the raw material of following masses part:
Dehydration catalyst: 100;
Expansion carburization agent: 0.05 ~ 10;
Foaming carbon forming agent: 1 ~ 50;
Auxiliary foaming and reinforcing agent: 1 ~ 100.
2. expansion type flame retardant according to claim 1, is characterized in that, this fire retardant is made up of the raw material of following masses part:
Dehydration catalyst: 100;
Expansion carburization agent: 0.1 ~ 2.0;
Foaming carbon forming agent: 10 ~ 30;
Auxiliary foaming and reinforcing agent: 10 ~ 30.
3. expansion type flame retardant according to claim 1 and 2, it is characterized in that, described dehydration catalyst be selected from boric acid, ammonium hydrogen phosphate, ammonium dihydrogen phosphate (ADP), APP, melamine cyanurate, melamine phosphate, melamine burnt microcosmic salt, melamine Quadrafos, guanyl-urea-phosphate, dicyandiamidines, phosphoguanidine, phosphate Guanoctine and polyphosphoric acid guanidine one or more.
4. expansion type flame retardant according to claim 1 and 2, is characterized in that, described expansion carburization agent refers to expanded graphite.
5. expansion type flame retardant according to claim 1 and 2, is characterized in that, described foaming carbon forming agent refers to cyanurotriamide modified urea resin rubber powder and/or melamine resin adehsive powder that melamine mass percent is greater than 3.0%.
6. expansion type flame retardant according to claim 1 and 2, is characterized in that, described auxiliary foaming and reinforcing agent refers to aluminium hydroxide or/and magnesium hydroxide.
7. use the manufacture method of the nonwoven foamed flame retardant fireproof wallpaper of expansion type flame retardant described in any one of claim 1-6, it is characterized in that, comprise the steps:
Non-woven paper is contained on uncoiler;
Allocate flame-retardant expanded slurry;
Flame-retardant expanded slurry is transferred on non-woven paper, dry.
High temperature foaming;
Cooling, cutting edge, block, check, rolling and packaging, make fire-retardant fireproof wallpaper.
8. manufacture method according to claim 7, is characterized in that, when production combustibility meets the fire-retardant fireproof wallpaper of GB8624B1-C level, and mass percent employing 4.0wt% ~ 10.0wt% that fire retardant is shared in flame-retardant expanded slurry; When production combustibility meets the fire-retardant fireproof wallpaper of GB8624B1-B level, mass percent employing 10.0wt% ~ 28.0wt% that fire retardant is shared in flame-retardant expanded slurry; Mass percent employing 28.0wt% ~ 40.0wt% that fire retardant is shared in flame-retardant expanded slurry.
9. manufacture method according to claim 7, is characterized in that, described flame-retardant expanded slurry comprises the raw material of following parts by mass:
Polyvinyl chloride (P450): 30 ~ 80;
Dioctyl phthalate (DOP): 30 ~ 80;
Expansion type flame retardant: 15 ~ 110;
Coarse whiting: 5 ~ 50;
Titanium dioxide: 5 ~ 70;
AC foams carbon forming agent: 1 ~ 15;
Microballoon blowing agent (PG20): 2 ~ 20;
Alkane solvents (D80): 0.1 ~ 10;
Epoxidized soybean oil: 0.1 ~ 10;
Stabilizing agent: 0.1 ~ 10.
10. manufacture method according to claim 9, is characterized in that, described flame-retardant expanded slurry comprises the raw material of following parts by mass:
P450：45～60；
DOP：40～55；
Expansion type flame retardant: 22 ~ 77;
Coarse whiting: 15 ~ 35;
Titanium dioxide: 10 ~ 20;
AC foams carbon forming agent: 3 ~ 8;
PG20：4～8；
D80：1～3；
Epoxidized soybean oil: 1 ~ 3;
Stabilizing agent: 1 ~ 3.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106676964A (en) * | 2016-11-17 | 2017-05-17 | 浙江大胜达包装有限公司 | Preparation method and application of flame-retardant packaging material |
| CN109423920A (en) * | 2017-08-22 | 2019-03-05 | 颜佳龙 | A kind of novel wallpaper production technology |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08218298A (en) * | 1995-02-14 | 1996-08-27 | Nippon Kakoh Seishi Kk | Wall paper and production thereof |
| CN101333443A (en) * | 2008-08-01 | 2008-12-31 | 浙江大学 | Method for preparing water-dispersed block polymer flame retardants with phosphorus, silicon and nitrogen and uses thereof |
| CN104099810A (en) * | 2014-06-30 | 2014-10-15 | 华南理工大学 | Environment-friendly flame retardant paper and preparation method and application thereof |
| CN204780470U (en) * | 2015-01-10 | 2015-11-18 | 沈阳领拓科技有限公司 | Fire -retardant wall paper of preventing fires |
-
2015
- 2015-11-24 CN CN201510833706.0A patent/CN105332321A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08218298A (en) * | 1995-02-14 | 1996-08-27 | Nippon Kakoh Seishi Kk | Wall paper and production thereof |
| CN101333443A (en) * | 2008-08-01 | 2008-12-31 | 浙江大学 | Method for preparing water-dispersed block polymer flame retardants with phosphorus, silicon and nitrogen and uses thereof |
| CN104099810A (en) * | 2014-06-30 | 2014-10-15 | 华南理工大学 | Environment-friendly flame retardant paper and preparation method and application thereof |
| CN204780470U (en) * | 2015-01-10 | 2015-11-18 | 沈阳领拓科技有限公司 | Fire -retardant wall paper of preventing fires |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106676964A (en) * | 2016-11-17 | 2017-05-17 | 浙江大胜达包装有限公司 | Preparation method and application of flame-retardant packaging material |
| CN109423920A (en) * | 2017-08-22 | 2019-03-05 | 颜佳龙 | A kind of novel wallpaper production technology |
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