The method that high pressure gas cylinder is prepared with two-phase stainless steel seamless steel tube
Technical field
The invention belongs to the applied technical field of two-phase stainless Steel material, and in particular to a kind of two-phase stainless steel seamless steel tube
Application and preparation method in high pressure gas cylinder is prepared.
Background technology
Two-phase stainless Steel material refers to that its metallographic structure ferrite respectively accounts for 50% with austenite, the content of general less phase
It is minimum be also required to reach 30% stainless steel, the characteristics of such steel has austenite and ferritic stainless steel concurrently, and ferritic phase ratio,
Plasticity, toughness are higher, and no brittleness at room temperature, intergranular corrosion resistance performance and welding performance are significantly increased, while also maintaining iron element
The 475 degrees Celsius of fragility and thermal conductivity factor of body stainless steel are high, the features such as with superplasticity.Compared with austenitic stainless steel, by force
Degree is high and intergranular corrosion resistance and resistance to chloride stress corrosion are significantly improved.Two phase stainless steel has excellent resistance to pitting performance,
It is also a kind of section nickel and stainless steel.Based on above good characteristics, two phase stainless steel has wide in terms of aeronautical material, Marine Materials
General application, but have no the application in high-pressure cylinder at present.
Pressure gas cylinder applies most special equipments as China, is widely applied to fire-fighting, medical treatment, chemical industry section
Grind, food, urban construction, machinery in terms of have a wide range of applications.In early days, high pressure gas cylinder is largely prepared with carbon steel material, carbon
Although the standby high pressure gas cylinder intensity of steel is up to 700MPa, its decay resistance is very poor.Prepare gas bomb at present
What material was commonly used has austenitic stainless steel, manganese steel, chrome-molybdenum steel, and many steel cylinders use austenitic stainless steel material conduct in preparing at present
Steel cylinder prepares material, and austenitic stainless steel strength ratio is relatively low, in order to ensure steel cylinder in the security of high-pressure work situation and make
With the life-span, its thickness will increase by 1.5 ~ 2 times, therefore, and although the application of austenitic stainless steel material improves the corrosion-resistant of steel cylinder
The cleanliness factor of property and inwall, but the thickness of steel cylinder is significantly increased, the consumption of material is added, production cost is added, and
And due to the increase of thickness, steel cylinder quality, which is also greatly increased, improves cost of transportation, reduces operating efficiency.
The content of the invention
In order to solve the above problems, the invention provides a kind of two-phase stainless steel seamless steel tube in high pressure gas cylinder is prepared
Application, the quality of steel cylinder in itself is not only alleviated as the material of high pressure gas cylinder using two-phase stainless Steel material, and drop
Low production cost, improves social benefit.
Present invention also offers a kind of method that use two-phase stainless steel seamless steel tube prepares high pressure gas cylinder, this method is being received
Mechanical polishing processing is carried out before mouth, receipts bottom to steel pipe, it is simple to operate, eliminate defect and the corrosion of inner wall of steel cylinder, it is ensured that steel
The high-pure gas contained in bottle is not contaminated;Solution heat treatment finally is carried out to the steel cylinder of first one-step forming, so that in hot spinning
During the metallographic structure of two-phase stainless Steel material that changes of metallographic structure recovered.
The present invention is realized by following technical scheme
Application of the two-phase stainless steel seamless steel tube in the preparation of high pressure gas cylinder.
The method that above-mentioned two-phase stainless steel seamless steel tube prepares high pressure gas cylinder, comprises the following steps:
(1)Take two-phase stainless steel seamless steel tube, on request, be cut into blank;
(2)By step(1)Steel pipe after cutting is mechanically polished;
(3)To after polishing two-phase stainless steel seamless steel tube blank carry out hot spinning receive bottom, milling bottom of bottle, heating close up,
Bottleneck drills, and obtains steel cylinder bottle;
(4)To step(3)Steel cylinder bottle after drilling carries out solution heat treatment;
(5)Step(4)Steel cylinder after processing rinsed in shoulder inner face processing, screw thread process, bottle, obtains high pressure gas
Steel cylinder.
Described two-phase stainless steel seamless steel tube prepares the method for high pressure gas cylinder, step(1)Described two phase stainless steel
A diameter of 159 ~ 350 mm of seamless steel pipe, thickness is 3 ~ 8mm;The length that cutting obtains blank is 800 ~ 1800mm.
Described two-phase stainless steel seamless steel tube prepares the method for high pressure gas cylinder, step(3)Bottom, milling are received in described heating
Bottom of bottle, heating is closed up, bottleneck drilling concrete operation step is:
A. one end of cleaved two-phase stainless steel seamless steel tube blank is placed in heating furnace, heated length is from end
Mouth starts length at 230 ~ 300mm, and heating-up temperature is 1150 ~ 1350 DEG C, and the heat time is 5 ~ 10min;
B. the blank after heating is subjected to spinning immediately, spinning main shaft rotating speed is 600 ~ 800r/s, once completes to receive
Bottom, the receipts bottom time is 80 ~ 120s;Initial temperature when receiving bottom is 1100 ~ 1200 DEG C, is mended in spinning process with gas nozzle
Air cooling is molded after heat, spinning, last milling bottom of bottle, is repaiied and is cut;
C. repeat step a, b carries out hot spinning to the other end of blank, and heating is closed up;
D. the heating closing in described in step c treats that bottle is cooled to room temperature after completing, and is drilled on bottleneck.
Described two-phase stainless steel seamless steel tube prepares the method for high pressure gas cylinder, the instrument used in spinning described in step b
Device is roller type spinning machine.
The method that described two-phase stainless steel seamless steel tube prepares high pressure gas cylinder, the spinning machine described in step b is revolved
When turning to receive bottom, spinning main shaft rotation is in 100 ° between mould rotation centerline and blank rotation centerline, during mould rotates along mould
Heart line rotates 100 °.
The method that described two-phase stainless steel seamless steel tube prepares high pressure gas cylinder, the combustion gas described in step b is acetylene, day
Right gas or oxygen.
Steel pipe heating receive bottom during, for make up because temperature reduce caused by steel pipe plasticity compromises, with natural gas,
Acetylene or oxygen jet carry out concurrent heating;The rotating speed of spinning main shaft is 600 ~ 800r/s, and the time used in bottom of receiving is 80 ~ 120s.
Described two-phase stainless steel seamless steel tube prepares the method for high pressure gas cylinder, step(4)Described solution heat treatment
Detailed process is:Bottle after bottleneck is drilled is heated in solid solution furnace, and 1050 ~ 1100 were heated to from room temperature with 3 ~ 5 hours
DEG C, 30 ~ 40min of insulation, carries out quick water cooling from 1050 ~ 1100 DEG C immediately after after being heated to 1050 ~ 1100 DEG C.
Compared with prior art, the present invention has following positive beneficial effect
(1)Two-phase stainless steel seamless steel tube is had a wide range of applications based on its excellent mechanical performance and Corrosion Protection,
But without the application found in high pressure gas cylinder is prepared.The high-pressure cylinder prepared at present using austenitic stainless steel surrenders strong
Degree can only achieve 170 ~ 200 MPa, and the high-pressure cylinder prepared using austenitic stainless steel steel pipe will reach pressure requirements, its bottle
Wall thickness will be 1.5 ~ 2 times of manganese steel or chrome-molybdenum steel, and thickness is greatly increased, and is added the usage amount of material, is considerably increased life
Cost is produced, and because the increase of thickness also increases steel cylinder weight, is made troubles to transport, cost of transportation is added.This hair
The conventional austenite of the wall ratio of the high pressure oxygen steel cylinder of bright use two-phase stainless steel making reduces more than 50%, reduces production
Cost also reduces cost of transportation simultaneously, and two-phase stainless steel seamless steel tube intensity is significantly larger than austenitic stainless steel, has
Excellent corrosion resistance.
(2)The present invention is prepared using two-phase stainless steel seamless steel tube during high pressure gas cylinder, carries out machine to steel cylinder first
Tool is polished, and is improved the cleanliness factor of bottle inwall, is greatly reduced the influence to gas purity in steel cylinder;To steel cylinder in preparation process
Solution heat treatment is carried out, to ensure that during hot spinning two phase stainless steel has occurred and that the metallographic structure of change(Austenite,
Ferrite)Recovered, the properties for keeping two phase stainless steel original, that is, reduce quenching, the complex operations step of tempering
The premium properties of prepared steel cylinder is also ensure that simultaneously.
Embodiment
Further description carried out to the present invention with specific embodiment below, but embodiment of the invention is not
It is limited to the following example.
Embodiment 1
Two phase stainless steel used in the embodiment is 2205(Alloy pipe fitting Co., Ltd of nation is reached purchased from Wuxi).
The method that high pressure oxygen steel cylinder is prepared with two-phase stainless steel seamless steel tube, comprises the following steps:
(1)The two phase stainless steel steel pipe for taking a diameter of 159mm, wall thickness to be 5mm, is cut into the short tube that length is 800mm,
And mechanically polished;
(2)To step(1)Bottom, milling bottom of bottle are received in steel pipe progress heating after mechanical polishing, and heating is closed up, bottleneck drills
Processing, obtains steel cylinder bottle;
(3)To step(2)Steel cylinder bottle after drilling carries out solution heat treatment;
(4)To step(3)Steel cylinder shoulder inner face after processing, which is processed, is allowed to smooth, screw thread process, rinses, obtains in bottle
To high pressure gas cylinder.
Wherein step(2)Bottom, milling bottom of bottle are received in described heating, and heating is closed up, bottleneck drilling operation step is as follows:
One end of two-phase stainless steel seamless steel tube blank after polishing is placed in heating furnace, heated length be from
Port starts at length 250mm, and heating-up temperature is 1150 DEG C, and the heat time is 10min;Blank after heating is used into roller immediately
Formula spinning machine carries out spinning, and the roller type spinning machine speed of mainshaft is 600r/s, during mould rotation centerline rotates with blank
It is in 100 ° between heart line, mould rotates 100 ° along mould rotation centerline.Once complete to receive bottom, the time used in spinning is 80s,
Initial temperature when receiving bottom is 1100 ~ 1200 DEG C, and concurrent heating is carried out with natural gas nozzle in spinning process, during being somebody's turn to do with balance
The temperature of reduction;After the completion of spinning air cooling be molded, then milling bottom of bottle, repair and cut;Above step is repeated, the other end of blank is carried out
Heating is closed up, and room temperature is cooled to after the completion of closing in, carries out bottleneck drilling.
Step(3)Steel cylinder after the drilling, which carries out solid hot melt processing, to be carried out in solid solution furnace, is added in solid solution furnace
Heat 3 hours, by room temperature to 1050 ~ 1100 DEG C, be then incubated 30 ~ 40min, quick water cooling carried out immediately after 30 ~ 40min
But.
During bottom is received in heating and heating is closed up, described receipts bottom length is 150mm, and the length for the gained bottleneck that closes up is
24 ~ 26mm, bottleneck a diameter of 46 ~ 48mm of φ.
The volume of the seamless high pressure gas cylinder of two phase stainless steel prepared by the embodiment is that 10L, temperature in use are -20 ~ 60
DEG C, design pressure be 15Mpa.
The performance indications of two phase stainless steel high pressure gas cylinder prepared by the embodiment are as follows:Yield strength is 610 N/mm2,
Tensile strength is 820 N/mm2, elongation after fracture is 28%.
Embodiment 2
Two phase stainless steel used in the embodiment is 2205(Alloy pipe fitting Co., Ltd of nation is reached purchased from Wuxi).
The method that high pressure gas cylinder is prepared with two-phase stainless steel seamless steel tube, comprises the following steps:
(1)The two phase stainless steel steel pipe for taking a diameter of 232mm, wall thickness to be 6mm, it is the short of 1800mm to be cut into length
Pipe, and mechanically polished;
(2)To step(1)Steel pipe after polishing carries out heating and receives bottom, milling bottom of bottle, and heating is closed up, bottleneck drilling processing,
Obtain steel cylinder bottle;
(3)To step(2)Steel cylinder bottle after drilling carries out solution heat treatment;
(4)To step(3)Steel cylinder shoulder inner face after processing, which is processed, is allowed to smooth, screw thread process, rinses, obtains in bottle
To high pressure gas cylinder.
Wherein step(2)Bottom, milling bottom of bottle are received in described heating, and heating is closed up, bottleneck drilling operation step is as follows:
One end of two-phase stainless steel seamless steel tube blank after polishing is placed in heating furnace, heated length be from
Port starts at length 300mm, and heating-up temperature is 1350 DEG C, and the heat time is 5min;Blank after heating is used into roller immediately
Formula spinning machine carries out spinning, and the roller type spinning machine speed of mainshaft is 600r/s, during mould rotation centerline rotates with blank
It is in 100 ° between heart line, mould rotates 100 ° along mould rotation centerline.Once complete to receive bottom, the time used in spinning is
120s, initial temperature when receiving bottom is 1100 ~ 1200 DEG C, carries out concurrent heating to balance the mistake with natural gas nozzle in spinning process
The temperature reduced in journey;After the completion of spinning air cooling be molded, then milling bottom of bottle, repair and cut;Above step is repeated, to the other end of blank
Heating closing in is carried out, room temperature is cooled to after the completion of closing in, bottleneck drilling is carried out.
Step(3)Steel cylinder after the drilling, which carries out solid hot melt processing, to be carried out in solid solution furnace, is added in solid solution furnace
Heat 5 hours, by room temperature to 1050 ~ 1100 DEG C, be then incubated 30 ~ 40min, quick water cooling carried out immediately after 30 ~ 40min
But.
During bottom is received in heating and heating is closed up, described receipts bottom length is 180mm, and the length for the gained bottleneck that closes up is
24 ~ 26mm, the diameter of bottleneck are 46 ~ 48mm of φ.
The volume of the seamless high pressure gas cylinder of two phase stainless steel prepared by the embodiment is that 50L, temperature in use are -20 ~ 60
DEG C, design pressure be 15Mpa.
The performance indications of two phase stainless steel high pressure gas cylinder prepared by the embodiment are as follows:Yield strength is 600N/mm2,
Tensile strength is 810 N/mm2, elongation after fracture is 35%.
Embodiment 3
Two phase stainless steel used in the embodiment is 2205(Alloy pipe fitting Co., Ltd of nation is reached purchased from Wuxi).
The method that high pressure gas cylinder is prepared with two-phase stainless steel seamless steel tube, comprises the following steps:
(1)The two phase stainless steel steel pipe for taking a diameter of 219mm, wall thickness to be 6mm, it is the short of 1400mm to be cut into length
Pipe, and mechanically polished;
(2)To step(1)Steel pipe after polishing carries out heating and receives bottom, milling bottom of bottle, and heating is closed up, bottleneck drilling processing,
Obtain steel cylinder bottle;
(3)To step(2)Steel cylinder bottle after drilling carries out solution heat treatment;
(4)To step(3)Steel cylinder shoulder inner face after processing, which is processed, is allowed to smooth, screw thread process, rinses, obtains in bottle
To high pressure gas cylinder.
Wherein step(2)Bottom, milling bottom of bottle are received in described heating, and heating is closed up, bottleneck drilling operation step is as follows:
One end of two-phase stainless steel seamless steel tube blank after polishing is placed in heating furnace, heated length be from
Port starts at length 230mm, and heating-up temperature is 1350 DEG C, and the heat time is 7min;Blank after heating is used into roller immediately
Formula spinning machine carries out spinning, and the roller type spinning machine speed of mainshaft is 600r/s, during mould rotation centerline rotates with blank
It is in 100 ° between heart line, mould rotates 100 ° along mould rotation centerline.Once complete to receive bottom, the time used in spinning is
100s, initial temperature when receiving bottom is 1100 ~ 1200 DEG C, carries out concurrent heating to balance the mistake with natural gas nozzle in spinning process
The temperature reduced in journey;After the completion of spinning air cooling be molded, then milling bottom of bottle, repair and cut;Above step is repeated, to the other end of blank
Heating closing in is carried out, room temperature is cooled to after the completion of closing in, bottleneck drilling is carried out.
Step(3)Steel cylinder after the drilling, which carries out solid hot melt processing, to be carried out in solid solution furnace, is added in solid solution furnace
Heat 4.5 hours, by room temperature to 1050 ~ 1100 DEG C, be then incubated 30 ~ 40min, quick water cooling carried out immediately after 30 ~ 40min
But.
During bottom is received in heating and heating is closed up, described receipts bottom length is 160mm, and the length for the gained bottleneck that closes up is
24mm, the diameter of bottleneck are φ 46mm.
The volume of the seamless high pressure gas cylinder of two phase stainless steel prepared by the embodiment is that 30L, temperature in use are -20 ~ 60
DEG C, design pressure be 15Mpa.
The performance indications of two phase stainless steel high pressure gas cylinder prepared by the embodiment are as follows:Yield strength is 610N/mm2,
Tensile strength is 820N/mm2, elongation after fracture is 31%.
Embodiment 4
Two phase stainless steel used in the embodiment is 2205(Alloy pipe fitting Co., Ltd of nation is reached purchased from Wuxi).
The method that high pressure gas cylinder is prepared with two-phase stainless steel seamless steel tube, comprises the following steps:
(1)The two phase stainless steel steel pipe for taking a diameter of 350mm, wall thickness to be 8mm, it is the short of 1350mm to be cut into length
Pipe, and mechanically polished;
(2)To step(1)Steel pipe after polishing carries out heating and receives bottom, milling bottom of bottle, and heating is closed up, bottleneck drilling processing,
Obtain steel cylinder bottle;
(3)To step(2)Steel cylinder bottle after drilling carries out solution heat treatment;
(4)To step(3)Steel cylinder shoulder inner face after processing, which is processed, is allowed to smooth, screw thread process, rinses, obtains in bottle
To high pressure gas cylinder.
Wherein step(2)Bottom, milling bottom of bottle are received in described heating, and heating is closed up, bottleneck drilling operation step is as follows:
One end of two-phase stainless steel seamless steel tube blank after polishing is placed in heating furnace, heated length be from
Port starts at length 300mm, and heating-up temperature is 1300 DEG C, and the heat time is 10min;Blank after heating is used into roller immediately
Formula spinning machine carries out spinning, and the roller type spinning machine speed of mainshaft is 560r/s, during mould rotation centerline rotates with blank
It is in 100 ° between heart line, mould rotates 100 ° along mould rotation centerline.Once complete to receive bottom, the time used in spinning is
100s, initial temperature when receiving bottom is 1100 ~ 1200 DEG C, carries out concurrent heating to balance the mistake with natural gas nozzle in spinning process
The temperature reduced in journey;After the completion of spinning air cooling be molded, then milling bottom of bottle, repair and cut;Above step is repeated, to the other end of blank
Heating closing in is carried out, room temperature is cooled to after the completion of closing in, bottleneck drilling is carried out.
Step(3)Steel cylinder after the drilling, which carries out solid hot melt processing, to be carried out in solid solution furnace, is added in solid solution furnace
Heat 5 hours, by room temperature to 1050 ~ 1100 DEG C, be then incubated 30 ~ 40min, quick water cooling carried out immediately after 30 ~ 40min
But.
During bottom is received in heating and heating is closed up, described receipts bottom length is 300mm, and the length for the gained bottleneck that closes up is
24 ~ 26mm, the diameter of bottleneck are 46 ~ 48mm of φ.
The volume of the seamless high pressure gas cylinder of two phase stainless steel prepared by the embodiment is that 50L, temperature in use are -20 ~ 60
DEG C, design pressure be 25Mpa.
The performance indications of two phase stainless steel high pressure gas cylinder prepared by the embodiment are as follows:Yield strength is 620N/mm2,
Tensile strength is 810N/mm2, elongation after fracture is 32%.