Summary of the invention
The object of this invention is to provide a kind of chlorinated rubber coating for maritime environment and manufacture method.Coating, have good sticking power, snappiness, high gloss the strong UV-light in resistance to sea be exposed to the sun, the coating of seawater corrosion resistance and manufacture method.
A kind of chlorinated rubber coating for maritime environment of the present invention, it is by 1 part by weight modified chlorinated rubber resin, 0.01 ~ 0.07 part by weight modified A Hydrogenated Bisphenol A F type epoxy resin, 0.03 ~ 0.6 parts by weight epoxy soybean oil, 0.01 ~ 0.02 weight part fluorine richness organo-siloxane, 0.01 ~ 0.03 weight part fluorine richness urethane, 0.1 ~ 0.2 weight part hydroxyl pyrrolotriazine derivatives, 0.2 ~ 0.5 parts by weight of xylene, 0.3 ~ 0.8 parts by weight solvent oil, 0.02 ~ 0.2 part by weight modified titanium dioxide, 0.04 ~ 0.1 mica powder, 0.05 ~ 0.3 weight part talcum powder, 0.04 ~ 0.2 weight part Feldspar Powder, 0.06 ~ 0.3 weight part phthalein is dark green, 0.03 ~ 0.2 weight part clorafin, 0.01 ~ 0.04 weight parts of polyamide wax, 0.01 ~ 0.03 parts by weight epoxy chloropropane, 0.03 ~ 0.2 weight part chrome yellow, 0.1 ~ 0.5 weight part silicon powder composition, stir during use.
A kind of chlorinated rubber coating for maritime environment of excellent performance, it is by 1 part by weight modified chlorinated rubber resin, 0.04 part by weight modified A Hydrogenated Bisphenol A F type epoxy resin, 0.04 parts by weight epoxy soybean oil, 0.015 weight part fluorine richness organo-siloxane, 0.025 weight part fluorine richness urethane, 0.1 weight part hydroxyl pyrrolotriazine derivatives, 0.3 parts by weight of xylene, 0.5 parts by weight solvent oil, 0.07 part by weight modified titanium dioxide, 0.075 parts by weight mica powder, 0.10 weight part talcum powder, 0.12 weight part feldspar, 0.35 weight part silicon powder, 0.17 weight part phthalein is dark green, 0.15 weight part chrome yellow, 0.02 parts by weight epoxy chloropropane, 0.23 weight part clorafin, 0.026 weight parts of polyamide wax composition, during use, coating is stirred.
For a manufacture method for the chlorinated rubber coating of maritime environment, it is that 1 part by weight modified chlorinated rubber resin is joined 0.2 ~ 0.5 parts by weight of xylene, dispersing and dissolving in 0.2 ~ 0.4 parts by weight solvent oil mixing solutions, adds 0.01 ~ 0.04 weight parts of polyamide wax under agitation after being uniformly dissolved, 0.01 ~ 0.02 weight part fluorine richness organo-siloxane, 0.01 ~ 0.03 weight part fluorine richness urethane, after stirring, adds 0.02 ~ 0.2 part by weight modified titanium dioxide, 0.04 ~ 0.1 mica powder, 0.05 ~ 0.3 weight part talcum powder, 0.04 ~ 0.2 weight part Feldspar Powder, 0.06 ~ 0.3 weight part phthalein is dark green, 0.03 ~ 0.2 weight part chrome yellow, 0.1 ~ 0.5 weight part silicon powder, high-speed stirring temperature reaches 50 ± 10 DEG C, keeps this temperature range to stir more than 0.5h, adds 0.01 ~ 0.07 part by weight modified A Hydrogenated Bisphenol A F type epoxy resin, 0.03 ~ 0.6 parts by weight epoxy soybean oil, 0.03 ~ 0.2 weight part clorafin, 0.1 ~ 0.2 weight part hydroxyl pyrrolotriazine derivatives, 0.01 ~ 0.03 parts by weight epoxy chloropropane, 0.1 ~ 0.4 parts by weight solvent oil, after high-speed stirring 0.5h, then makes coating with sand mill grinding 0.5 ~ 1h, stirs and directly apply during use.
Preferably for chlorinated rubber coating and the manufacture method of maritime environment, it is that 1 part by weight modified chlorinated rubber resin is joined 0.5 parts by weight of xylene, in addition dispersing and dissolving in 0.2 parts by weight solvent oil mixed solvent, adds 0.013 weight parts of polyamide wax when stirring, 0.012 weight part fluorine richness organo-siloxane, 0.015 weight part fluorine richness urethane, after stirring, adds 0.07 part by weight modified titanium dioxide, 0.075 parts by weight mica powder, 0.1 weight part talcum powder, 0.12 weight part Feldspar Powder, 0.17 weight part phthalein is dark green, 0.15 weight part chrome yellow, 0.35 weight part silicon powder, high-speed stirring temperature reaches 50 ± 10 DEG C, keeps this temperature range to stir more than 0.5h, adds 0.03 part by weight modified A Hydrogenated Bisphenol A F type epoxy resin, 0.04 parts by weight epoxy soybean oil, 0.23 weight part clorafin, 0.1 weight part hydroxyl pyrrolotriazine derivatives, 0.02 parts by weight epoxy chloropropane, 0.3 parts by weight solvent oil, after high-speed stirring 0.5h, then makes coating with sand mill grinding 0.5 ~ 1h, stirs and directly apply during use.
A kind of chlorinated rubber coating for maritime environment of the present invention and manufacture method, by modified chlorinated rubber resin solution, add a small amount of film forming matter stablizer, auxiliary agent, and the ultraviolet absorbers of some amount, protection against corrosion color stuffing are formulated.Active group is had in the modified chlorinated rubber resin used in the fabrication process and modified hydrogenated bisphenol f type epoxy resin molecular structure, can react with atoms metal and form very firmly chemical bond, enhance the sticking power of coating and base material, and make that coating is hard, snappiness good.The crystal structure of modifications rutil type titanium dioxide, usable reflection ultraviolet, hydroxyl pyrrolotriazine derivatives absorbs UV-light effectively, block ultraviolet is to the destruction of coating, flaky mica powder is isolated UV-light and is extended the permeation pathway of liquid medium, improve the ultraviolet resistance of paint film, resistant to chemical media and salt spray resistance, the parent that fluorine richness urethane contains is inorganic can form chemical bond with inorganic filler surface and organic resin respectively with organic group, enhance the interface compatibility of mineral filler and organic resin, improve the glossiness of chlorinated rubber resin coating.Ground barium sulfate, feldspar, silicon powder, talcum powder have good chemical stability, acid-alkali-corrosive-resisting, the hardness excellent performance such as large, can improve the hardness of paint film, resistant to chemical media corrodibility further.Fluorine richness organo-siloxane reduces the surface tension of coating system, improves flowing and levelling property and the bubble contributed in elimination coating.The polyamide wax used improves the thixotropy of coating, settleability and application property, improves the stability in storage of coating.
The present invention's beneficial effect compared with prior art
1. the present invention is used for the chlorinated rubber coating of maritime environment, its coating has excellent difficult resistance to UV aging, high-luster, sticking power, resistant to chemical media and salt fog resistance, especially the slight efflorescence of ultraviolet resistance 1000h, glossiness 60 ° is greater than 80, salt fog resistance 1000h coating non-corroding, nothing are bubbled, and sticking power is greater than 7MPa.Can be used for the protection against corrosion of boats and ships, ocean platform and offshore structure etc.
2. the present invention is used for the high light weather resistant chlorinated rubber coating of maritime environment and manufacture method, and technique is simple, need not specific installation, and price is low.