CN105296042A - Compound briquette containing filter mud and biomass fuel - Google Patents
Compound briquette containing filter mud and biomass fuel Download PDFInfo
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- CN105296042A CN105296042A CN201510735525.4A CN201510735525A CN105296042A CN 105296042 A CN105296042 A CN 105296042A CN 201510735525 A CN201510735525 A CN 201510735525A CN 105296042 A CN105296042 A CN 105296042A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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Abstract
The invention discloses a compound briquette containing filter mud and biomass fuel. The compound briquette is prepared from the following raw materials in parts by weight: 40-50 parts of pulverized coal, 5-10 parts of oil shale, 20-25 parts of filter mud in sugar mills, 20-28 parts of biomass fuel powder, 3-6 parts of limestone, 0.8-1.2 parts of magnesium oxide, 0.5-0.9 part of ferrous sulfate, 1-3 parts of silicon carbide and 8-10 parts of molasses, wherein the biomass fuel powder is prepared by drying one or more of soybean straws, corn straws, rice straws, corncobs, eucalyptus barks and eucalyptus branches in the sun and then grinding the materials or by carbonizing and grinding. Adopting the agricultural and forestry residues, such as filter mud in sugar mills, molasses, straws and eucalyptus barks, as the raw materials, the briquette achieves the effects of turning waste into wealth and making the best use of the materials and has positive significance to environmental protection.
Description
Technical field
The present invention relates to moulded coal field, particularly a kind of composite briquette containing filter mud and biomass fuel.
Background technology
Moulded coal take fine coal as main raw material, by the machined compression moulding of proportioning, physical strength and shape size required by concrete purposes, has some strength and size and different coal finished product; Moulded coal has that technique is simple, less investment, cost are low, and can obtain and promote coal-fired quality, improve efficiency of combustion, reduce the advantages such as coal burning pollution, is therefore used widely in people's daily life and industrial production as fuel.But coal resources are fewer and feweri, people start more and more to focus on waste resource to be applied in moulded coal, develop economic model capable of circulation.
In China's sugar industry production process, all inevitably produce the waste pollutants such as the very huge filter mud of quantity, waste molasses and sugarcane marrow every year.Wherein except sugarcane marrow is used (on a small quantity as paper making raw material, other are as boiler oil), other wastes are all less than effectively being utilized, only make some halfway environmental protection treatment, direct discharge, sugar enterprise takes huge expenses of environmental protection, does not produce any economic benefit, and can only process about 1/3 of existing waste pollutant.
In rural area, the agriculture and forestry organic waste materials such as stalk, bark, straw, only have a small amount of for pasture; or be used as farmland fertilizer; but still have a large amount of more than needed, if can filter mud, molasses and agriculture and forestry organic waste material be applied in moulded coal, will to realizing resource circulation utilization, preserve the ecological environment significant.
Summary of the invention
The invention provides a kind of composite briquette containing filter mud and biomass fuel, adopt filter mud of sugar refinery, biomass fuel as moulded coal raw material, achieve the recycling of waste resource.
For achieving the above object, technical scheme of the present invention is:
Contain a composite briquette for filter mud and biomass fuel, be made up by weight ratio of following raw material: 40 ~ 50 parts, fine coal, 5 ~ 10 parts, resinous shale, filter mud of sugar refinery 20 ~ 25 parts, 20 ~ 28 parts, biomass fuel powder, 3 ~ 6 parts, Wingdale, 0.8 ~ 1.2 part, magnesium oxide, 0.5 ~ 0.9 part, ferrous sulfate, 1 ~ 3 part, silicon carbide, 8 ~ 10 parts, molasses;
Wherein: described biomass fuel powder is soybean stalk, one or more in maize straw, straw, corn cob, mallee bark, eucalyptus branch are dried rear pulverizing and made or make through charing pulverizing.
The above-mentioned composite briquette containing filter mud and biomass fuel, is preferably made up of following raw material: 45 parts, fine coal, 8 parts, resinous shale, filter mud of sugar refinery 23 parts, 22 parts, biomass fuel powder, 5 parts, Wingdale, 1 part, magnesium oxide, 0.7 part, ferrous sulfate, 2 parts, silicon carbide, 9 parts, molasses by weight ratio.
Further, described biomass fuel powder is made: 10 ~ 15 parts, soybean stalk powder, corn stalk powder 10 ~ 15 parts, rice straw powder 5 ~ 10 parts and 30 ~ 38 parts, mallee bark powder after shining dry grinding by following raw materials according by weight ratio.
The above biomass fuel powder is made: 12 parts, soybean stalk powder, corn stalk powder 12 parts, rice straw powder 8 parts and 36 parts, mallee bark powder after preferably shining dry grinding by following raw materials according by weight ratio.
Further, described biomass fuel powder is after biomass fuel charring, pulverize the powder made, and its manufacture craft is: biomass fuel is put into charring furnace, ignition, after the charing of 4 ~ 5 days, then the fuel after charing is ground into 20 ~ 30 object powder.
The powder made after the above biomass fuel charring, is carbonized by weight ratio by following raw material and makes: soybean stalk 15 ~ 20 parts, maize straw 15 ~ 20 parts, straw 12 ~ 16 parts, corn cob 6 ~ 10 parts, mallee bark 50 ~ 62 parts, 12 ~ 18 parts, eucalyptus branch.
Above-mentioned biomass fuel is preferably carbonized by weight ratio by following raw material and makes: soybean stalk 17 parts, maize straw 17 parts, straw 14 parts, corn cob 8 parts, mallee bark 56 parts, 15 parts, eucalyptus branch.
The above-described composite briquette containing filter mud and biomass fuel, has following advantage:
(1) described filter mud of sugar refinery is sugar refinery sulfurous method direct production white sugar (single stage method) gained and dry filter mud after deodorizing process, total amount of organic in filter mud can reach 80%, be mainly lipoid (cerosin and sugarcane fat) 5-14%, fiber 15-30%, sugar 5-15%, crude protein 5-15%, total percent of ash 9-20%, this organism is combustible species; In addition, also containing P
2o
5, K
2o, CaO, MgO, can be used as sulphur-fixing agent and combustion synergist uses;
(2) with the addition of resinous shale, resinous shale mainly comprises oil mother, moisture and mineral substance; Wherein, oil is female: content about 10% ~ 50%, is complicated macromolecular organic compound, is rich in aliphatic hydrocarbon structure, and less aromatic hydrocarbons structure; The elementary composition of oil mother is mainly carbon, hydrogen, and a small amount of oxygen, nitrogen, sulphur; Its hydrogen-to-carbon ratio is 1.25 ~ 1.75; For combustible species; Mineral substance: mainly contain quartz, kaolin, clay, mica, carbonatite and sulfurous iron ore etc., containing the alkali and alkaline earth metal ions salt such as potassium, sodium, calcium, magnesium and iron carbonyl aluminum oxide and spinels composition thereof, these compositions improve coal molecular activity, improve the efficiency of combustion of filter mud of sugar refinery and biomass fuel;
(3) apply molasses as binding agent, molasses are byproducts of sugar industry, and viscosity is very high, and bond effect is good, are also the recyclings to waste resource;
(4) add Wingdale as stiffening agent, coordinate molasses to use, accelerate the speed of briquette molding, improve the intensity of moulded coal;
(5) recycle filter mud of sugar refinery, molasses and the agriculture and forestry organic waste material such as stalk and mallee bark, achieving turns waste into wealth, makes the best use of everything, and has positive meaning to environment protection.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, but protection scope of the present invention and range of application are not limited to following examples:
One, prepared by a kind of composite briquette containing filter mud and biomass fuel
Embodiment 1
Contain a composite briquette for filter mud and biomass fuel, be made up by weight ratio of following raw material: 45 parts, fine coal, 8 parts, resinous shale, filter mud of sugar refinery 23 parts, 22 parts, biomass fuel powder, 5 parts, Wingdale, 1 part, magnesium oxide, 0.7 part, ferrous sulfate, 2 parts, silicon carbide, 9 parts, molasses.
Wherein, biomass fuel powder is made: 12 parts, soybean stalk powder, corn stalk powder 12 parts, rice straw powder 8 parts and 36 parts, mallee bark powder after shining dry grinding by following raw materials according by weight ratio.
Above-mentioned raw materials mixes, through forming machine compression moulding, and natural curing 3 ~ 5 days and get final product.
Embodiment 2
Contain a composite briquette for filter mud and biomass fuel, be made up by weight ratio of following raw material: 40 parts, fine coal, 5 parts, resinous shale, filter mud of sugar refinery 25 parts, 28 parts, biomass fuel powder, 6 parts, Wingdale, 1.2 parts, magnesium oxide, 0.9 part, ferrous sulfate, 1 part, silicon carbide, 10 parts, molasses.
Wherein, biomass fuel powder is made: 10 parts, soybean stalk powder, corn stalk powder 10 parts, rice straw powder 10 parts and 38 parts, mallee bark powder after shining dry grinding by following raw materials according by weight ratio.
Above-mentioned raw materials mixes, through forming machine compression moulding, and natural curing 3 ~ 5 days and get final product.
Embodiment 3
Contain a composite briquette for filter mud and biomass fuel, be made up by weight ratio of following raw material: 50 parts, fine coal, 10 parts, resinous shale, filter mud of sugar refinery 20 parts, 20 parts, biomass fuel powder, 3 parts, Wingdale, 0.8 part, magnesium oxide, 0.5 part, ferrous sulfate, 3 parts, silicon carbide, 8 parts, molasses.
Wherein, biomass fuel powder is made: 15 parts, soybean stalk powder, corn stalk powder 15 parts, rice straw powder 5 parts and 30 parts, mallee bark powder after shining dry grinding by following raw materials according by weight ratio.
Above-mentioned raw materials mixes, through forming machine compression moulding, and natural curing 3 ~ 5 days and get final product.
Embodiment 4
Contain a composite briquette for filter mud and biomass fuel, be made up by weight ratio of following raw material: 45 parts, fine coal, 8 parts, resinous shale, filter mud of sugar refinery 23 parts, 22 parts, biomass fuel powder, 5 parts, Wingdale, 1 part, magnesium oxide, 0.7 part, ferrous sulfate, 2 parts, silicon carbide, 9 parts, molasses.
Wherein, biomass fuel powder is after biomass fuel charring, pulverize the powder made, and biomass fuel is made up by weight ratio of following raw material: soybean stalk 17 parts, maize straw 17 parts, straw 14 parts, corn cob 8 parts, mallee bark 56 parts, 15 parts, eucalyptus branch; Its manufacture craft is: biomass fuel is put into charring furnace, ignition, after the charing of 4 ~ 5 days, then the fuel after charing is ground into 20 ~ 30 object powder.
Above-mentioned raw materials mixes, through forming machine compression moulding, and natural curing 3 ~ 5 days and get final product.
Embodiment 5
Contain a composite briquette for filter mud and biomass fuel, be made up by weight ratio of following raw material: 40 parts, fine coal, 5 parts, resinous shale, filter mud of sugar refinery 25 parts, 20 parts, biomass fuel powder, 5.5 parts, Wingdale, 1.1 parts, magnesium oxide, 0.8 part, ferrous sulfate, 1.5 parts, silicon carbide, 10 parts, molasses.
Wherein, biomass fuel powder is after biomass fuel charring, pulverize the powder made, and biomass fuel is made up by weight ratio of following raw material: soybean stalk 15 parts, maize straw 20 parts, straw 12 parts, corn cob 6 parts, mallee bark 60 parts, 18 parts, eucalyptus branch; Its manufacture craft is: biomass fuel is put into charring furnace, ignition, after the charing of 4 ~ 5 days, then the fuel after charing is ground into 20 ~ 30 object powder.
Above-mentioned raw materials mixes, through forming machine compression moulding, and natural curing 3 ~ 5 days and get final product.
Embodiment 6
Contain a composite briquette for filter mud and biomass fuel, be made up by weight ratio of following raw material: 50 parts, fine coal, 10 parts, resinous shale, filter mud of sugar refinery 21 parts, 27 parts, biomass fuel powder, 3.5 parts, Wingdale, 0.9 part, magnesium oxide, 0.8 part, ferrous sulfate, 2.5 parts, silicon carbide, 8.5 parts, molasses.
Wherein, biomass fuel powder is after biomass fuel charring, pulverize the powder made, and biomass fuel is made up by weight ratio of following raw material: soybean stalk 20 parts, maize straw 15 parts, straw 16 parts, corn cob 6 parts, mallee bark 50 parts, 13 parts, eucalyptus branch; Its manufacture craft is: biomass fuel is put into charring furnace, ignition, after the charing of 4 ~ 5 days, then the fuel after charing is ground into 20 ~ 30 object powder.
Above-mentioned raw materials mixes, through forming machine compression moulding, and natural curing 3 ~ 5 days and get final product.
Two, moulded coal performance test
1. strength test
By above-mentioned 6 the embodiment samples prepared, carry out strength test, result shows that moulded coal sample cold strength of the present invention is high, falls not easily broken, refers to table 1.
Table 1 briquette strength table with test results
2. combustionproperty test
Get above-mentioned 6 the embodiment samples prepared respectively, carry out combustion test, measure following test item, test-results refers to table 2.
Table 2 Combustion of Mould Coal the performance test results table
(3) measurement result
Result shows: from inner outside release of heat during the present invention's 6 embodiment sample combustion, ignition temperature is reduced to 160-250 DEG C, speed of igniting is accelerated, flame lengthens, burning is more abundant, adds the internal flame temperature of flame, the bulk temperature of flame is improved, moulded coal thermal value of the present invention, thermo-efficiency are high, SO
2quantity discharged, smoke discharge amount lower, raw material is mainly filter mud, molasses and agriculture production waste, and cost reduces 40-65%.
Claims (7)
1. contain a composite briquette for filter mud and biomass fuel, it is characterized in that:
It is made up by weight ratio of following raw material: 40 ~ 50 parts, fine coal, 5 ~ 10 parts, resinous shale, filter mud of sugar refinery 20 ~ 25 parts, 20 ~ 28 parts, biomass fuel powder, 3 ~ 6 parts, Wingdale, 0.8 ~ 1.2 part, magnesium oxide, 0.5 ~ 0.9 part, ferrous sulfate, 1 ~ 3 part, silicon carbide, 8 ~ 10 parts, molasses;
Wherein: described biomass fuel powder is soybean stalk, one or more in maize straw, straw, corn cob, mallee bark, eucalyptus branch are dried rear pulverizing and made or make through charing pulverizing.
2. the composite briquette containing filter mud and biomass fuel according to claim 1, is characterized in that:
It is made up by weight ratio of following raw material: 45 parts, fine coal, 8 parts, resinous shale, filter mud of sugar refinery 23 parts, 22 parts, biomass fuel powder, 5 parts, Wingdale, 1 part, magnesium oxide, 0.7 part, ferrous sulfate, 2 parts, silicon carbide, 9 parts, molasses.
3. the composite briquette containing filter mud and biomass fuel according to claim 1, is characterized in that:
Described biomass fuel powder is made: 10 ~ 15 parts, soybean stalk powder, corn stalk powder 10 ~ 15 parts, rice straw powder 5 ~ 10 parts and 30 ~ 38 parts, mallee bark powder after shining dry grinding by following raw materials according by weight ratio.
4. the composite briquette containing filter mud and biomass fuel according to claim 3, is characterized in that:
Described biomass fuel powder is made: 12 parts, soybean stalk powder, corn stalk powder 12 parts, rice straw powder 8 parts and 36 parts, mallee bark powder after shining dry grinding by following raw materials according by weight ratio.
5. the composite briquette containing filter mud and biomass fuel according to claim 1, is characterized in that:
Described biomass fuel powder is after biomass fuel charring, pulverize the powder made, and its manufacture craft is: biomass fuel is put into charring furnace, ignition, after the charing of 4 ~ 5 days, then the fuel after charing is ground into 20 ~ 30 object powder.
6. the composite briquette containing filter mud and biomass fuel according to claim 5, is characterized in that:
Described biomass fuel is made up by weight ratio of following raw material: soybean stalk 15 ~ 20 parts, maize straw 15 ~ 20 parts, straw 12 ~ 16 parts, corn cob 6 ~ 10 parts, mallee bark 50 ~ 62 parts, 12 ~ 18 parts, eucalyptus branch.
7. the composite briquette containing filter mud and biomass fuel according to claim 6, is characterized in that:
Described biomass fuel is made up by weight ratio of following raw material: soybean stalk 17 parts, maize straw 17 parts, straw 14 parts, corn cob 8 parts, mallee bark 56 parts, 15 parts, eucalyptus branch.
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CN201510735525.4A CN105296042A (en) | 2015-11-02 | 2015-11-02 | Compound briquette containing filter mud and biomass fuel |
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CN201510735525.4A CN105296042A (en) | 2015-11-02 | 2015-11-02 | Compound briquette containing filter mud and biomass fuel |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109913284A (en) * | 2018-10-22 | 2019-06-21 | 辽宁旭日新能源科技有限公司 | A kind of new energy hybrid fuel |
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CN1629260A (en) * | 2003-12-15 | 2005-06-22 | 昆明炬洁科技有限责任公司 | Clean modified briquette and method for preparing same |
CN101280236A (en) * | 2008-05-23 | 2008-10-08 | 肖国雄 | Clean type coal and fast production method thereof |
CN103113948A (en) * | 2013-03-15 | 2013-05-22 | 广西桂晟新能源科技有限公司 | Filter mud containing clean coal and preparation method thereof |
-
2015
- 2015-11-02 CN CN201510735525.4A patent/CN105296042A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1629260A (en) * | 2003-12-15 | 2005-06-22 | 昆明炬洁科技有限责任公司 | Clean modified briquette and method for preparing same |
CN101280236A (en) * | 2008-05-23 | 2008-10-08 | 肖国雄 | Clean type coal and fast production method thereof |
CN103113948A (en) * | 2013-03-15 | 2013-05-22 | 广西桂晟新能源科技有限公司 | Filter mud containing clean coal and preparation method thereof |
Non-Patent Citations (1)
Title |
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葛岭梅等: "《洁净煤技术概论》", 31 August 1997, 煤炭工业出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109913284A (en) * | 2018-10-22 | 2019-06-21 | 辽宁旭日新能源科技有限公司 | A kind of new energy hybrid fuel |
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Application publication date: 20160203 |