CN105287246A - Hair dye mixture containing monomer - Google Patents
Hair dye mixture containing monomer Download PDFInfo
- Publication number
- CN105287246A CN105287246A CN201510230626.6A CN201510230626A CN105287246A CN 105287246 A CN105287246 A CN 105287246A CN 201510230626 A CN201510230626 A CN 201510230626A CN 105287246 A CN105287246 A CN 105287246A
- Authority
- CN
- China
- Prior art keywords
- implement
- mixture
- monomer
- hair
- dyeing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to a hair dye mixture, containing following components: a monomer having a weight percent of 1-15t% and having a following chemical formula: H2C=C(X)-C(=O)OR<a>OH, wherein X is hydrogen or CH3, R<a> is alkyl, and the monomer is water-soluble; an oxidant dye precusor, containing at least one coupler and at least one primary intermediary; wherein pH of the mixture is 8-12 and the mixture has no oxidant. The invention also relates to a kit for hair dyeing, containing the hair dye mixture and an oxide preparation containing a monoxide agent, wherein the mixture and the preparation are packaged separately.
Description
Technical field
The present invention relates to the dyeing mixture containing a monomer and oxidation dye precursors.
Background technology
The interior zone chemically modifying hair shaft position is announced in the prior art.Patent documentation WO2009/088520A, WO2012/100006A, WO2012/100007A, EP2772246A1 and EP2295029A describes the interior zone using vinyl monomer chemical modification hair shaft position---especially, ethylene molecule can be connected with hair and/or be connected to form macromole, as polymer with other ethylene molecules in hair.Can be increased the hardness of hair like this by the internal structure of modifying hair shaft, advantage can be brought for forming hair like this, such as easily shape, or increase hair volume and make shaping time more permanent.Methacrylic acid 3-sulphur methacrylate potassium salt (3-SPA) is the monomer being used to chemical modification hair shaft interior zone, and has molal weight M.Wt.232.2g/mol.US3,472,243 disclose the process by being polymerized the stretching and hair conditioning of a water-soluble monomer in hair, and described monomer is the vinyl compound containing acid group, is connected thus reduce its water solublity between polymer by bridging agent.
Hair-dyeing or painted be hair dye be used on hair thus make hair coloring.The hair color of whole head can have trickle or significantly change.Root dyes and other part colours of itself and hair is coincide.And introduce glittering, choose the effect of dyeing hair bundle or region hair, or upgrade same color and be used for for fade and/or color is washed off.The reason of hair dyeing may be only the change in season---a lot of women client wishes that the color of their hair is more shallow color when summer, skin color after can setting off its Exposure to Sunlight like this---or reason is only mood, image, the change of dress or hair style.For old a little client, it is its main worry that hair bleaches, and impels it often to use root of hair polishing.Now, client's (no matter be in or in hairdressing place) is using the direct hair dye that can wash off relatively fast, uses luminous effect, and chooses dye input aspect and hold staining technique relative to tradition (partly), or acceleration developer, as
perfect10, has and selects widely.
A common drawback of tradition hair dyeing is hair structure damage.Many clients worries to cross multiprocessing to hair, and the professional hairstylist of hairdressing place then opposes further chemical treatment, and as curly hair, bleaching, or dye lastingly, these process can make the over-drying or bifurcated of hair.The hair damaged may more difficult moulding and arranging---and for example, dry hair easily flies up and easy roll set.Hair bifurcated and drying affect hair microstructure, cause irregular horny layer spacing.Micro-aspect can be regarded as the hair brightness reduced.
As a result, need to provide a kind of hair coloring mixture improved, the hair dye of hair healthy especially can be improved.
Summary of the invention
Above-mentioned drawback can be overcome by following hair dye mixture, a hair dye mixture, containing following composition:
?weight content be 1 to 15wt% monomer, described monomer has following chemical formula:
H
2C＝C(X)-C(＝O)OR
aOH
Wherein X is hydrogen or CH
3, R
abe alkyl, and monomer have water solublity;
?antioxidant dye precursor, this oxidant-precursor contains at least one couplant and at least one elementary mediator;
Wherein, the pH value of described mixture is 8 to 12, and oxygen-free agent.
Another aspect of the invention is, containing a kind of a kind of hair heat-tinting agent composition of monomer, the molecular weight of described monomer is less than 200g/mol, and described monomer has following chemical formula:
H
2C＝C(X)-C(＝O)ORaOH
Wherein X is hydrogen or CH
3, Ra is C1 ~ C4 alkyl, and monomer has water solublity has peculiar advantage.
In addition, the invention still further relates to the test kit for hair-dyeing, this test kit contains: above-mentioned arbitrary described mixture; And the oxidation recipes containing an oxidant, wherein said mixture separates with described oxidation recipes to be packed.
The invention further relates to, a kind of method of hair dyeing, comprise and said mixture and the oxidation recipes containing an oxidant are mixed to form an intermixture, and described intermixture is used on hair.
The invention further relates to, one is operable hair dye formulas at any time, contains:
The monomer of-percentage by weight between 1.0wt% to 5wt%, and described monomer has following chemical formula: H
2c=C (X)-C (=O) OR
aoH; Wherein X is hydrogen or CH
3, R
abe C1 ~ C4 alkyl, and monomer have water solublity;
-oxidation dye precursors, this oxidation dye precursors has at least one couplant and at least one elementary mediator;
-one oxidant;
The pH value of wherein said mixture is 8 to 12.
According to observations, (methyl) acrylate is a nucleopilic reagent at a high ph, so can the additive reaction that participate in colour coupler and elementary mediator the same as nucleopilic reagent, thus hinders a dyestuff reaction path and promotes another fuel reaction approach.Generally speaking, dyestuff enters the speed of hair faster than the response speed between dyestuff.When (methyl) acrylate exists, we observe ring dye not aberration, and this illustrates that the speed of producing same color is faster, and the speed of reacting between dyestuff is faster than its seepage velocity.This makes dyestuff more concentrated around hair shaft, thus client is felt, and dyeing is more deep.
The present invention is relative to the advantage of prior art:
-low dye demand;
-stronger Color;
-no color differnece;
-save cost;
-less contact dyestuff;
-contaminate effect at the ring of hair shaft tangent plane.
Details of the present invention and preferred details are described below:
First content of the present invention is " hair dye mixture ", is called as " mixture ".Described mixture is used for having hair dyed, and is used to the mixture of mixing, provides an intermixture in other words for mixing with an oxidation recipes, namely described " at any time operable hair dye formulas ".
Implement in example at least one, described mixture is liquid.Liquid mixture is very useful because it easily mixes with the oxidation recipes being usually also liquid.
It is 1 to 15wt% that mixture of the present invention contains mass percent, and the chemical formula of described monomer is:
H
2C＝C(X)-C(＝O)OR
aOH；
Wherein X is hydrogen or CH
3, Ra is C1 ~ C4 alkyl, and monomer has water solublity.Described monomer contains vinyl.Described monomer contains acrylic acid alkali or methacrylic acid alkali.Acrylate base refers to H
2c=CH-C (O) O
-.Methacrylic acid alkali refers to H
2c=C (CH
3)-C (O) O
-.
Implement in example at least one, described monomer contains following chemical formula
H
2C＝C(CH
3)-C(＝O)OR
aOH
Wherein R
abe alkyl, and the molecular weight of monomer is less than 200g/mol.Implement in example at least one, the weight percent monomer content of mixture of the present invention is 0.1 to 15%, or 0.1 to 10%, or 1 to 5%.
Described monomer is polymerized under alkaline ph values.But, guarantee that monomer only has superiority with monomer and the existence of undersaturated form by introducing polymerization inhibitor.Implement in example at least one, described mixture contains a polymerization inhibitor.Implement in example at least one, the level of inhibitor of mixture of the present invention is the polymerization inhibitor that each kilogram of monomer contains 1 milligram to 1000 milligrams.
Implement in example at least one, described polymerization inhibitor is 4-methoxyphenol.Implement in example at least one, described polymerization inhibitor is Nitrobenzol or 1,1-diphenyl-2-trinitrophenyl-hydrazine (DPPH).Such as, the antioxidant of BASF AG can be used
1330 is 1,3,5-trimethyl-2,4,6-tri-(3,5-di-t-butyl-4-hydroxyl benzyl) benzene.The antioxidant Ethanox of Sheng Laikete global group one does not dye, tasteless antioxidant.ETHANOX330 or 330G all can use.
Implement in example at least one, described polymerization inhibitor is a benzyl ether compounds.Implement in example at least one, described polymerization inhibitor selects in 2-tertiary butyl-4-hydroxy methoxybenzene, 3-t-Butyl-4-hydroxyanisole, with and composition thereof.About use methoxybenzene as polymerization inhibitor, at (methyl) acrylate Zhong – C (Z)=CH
2(wherein Z is H or CH
3) formation carbon atom group of place, this polymerization inhibitor can contribute a proton on the free radical of vinyl monomer from its hydroxyl.The compound formed can not be polymerized, because it no longer has free radical.Butyl on polymerization inhibitor as to electronics group for being stabilized in the free radical formed in phenyl ring.
Implement in example at least one, the initiator of described mixture substantially not containing any Raolical polymerizable.The advantage of the initiator of mixture substantially not containing any Raolical polymerizable is the danger that can reduce described monomer self-polymerization.
Implement in example at least one, described mixture is not substantially containing poly-(methyl) acrylic polymer.In granule, except poly-(methyl) acrylic polymer in capsule.
Described mixture contains oxidation dye precursors, and described precursor contains at least one couplant and at least one elementary mediator.
Be applicable to oxidation dye of the present invention, if alkali, can with free alkali or the acid of itself and organic or inorganic, example hydrochloric acid, hydrobromic acid, acetic acid, lactic acid, succinic acid, tartaric acid or sulphuric acid, the physiology salt of formation, or as long as this alkali has aromatic hydroxyl, its salt, as alkali phenates.
Oxidation dye compound comes forth in the prior art, comprise aromatic diamine, amino phenols, aromatic diol, and its derivant (Sagarin, CosmeticScienceandTechnology, and Interscience, SpecialEdn.Vol.2, as the representative example of oxidation dye precursors, but wherein can not contain all oxidation dye compounds for 308 to 310 pages).Canadian patent application CA2576189A1 also discloses operable oxidation dye compound, the dye combinations announced in form 1 especially wherein, 1 to 2394,49 to 238 pages.It is pointed out that the following elementary mediator that exemplifies and the citing of colour coupler (being referred to as oxidation dye precursors) knowledge, not restriction effect.These elementary mediator and colour coupler can with salt, and the form as sulfate uses.
Implement in example at least one, described elementary mediator is: Toluene-2,4-diisocyanate, 5-diamidogen, p-phenylenediamine (PPD), N-phenyl-p-diaminophenol, N, two (2-the ethoxy)-p-phenylenediamine (PPD) of N-, 2-ethoxy p-phenylenediamine (PPD), two (N-ethoxy-P-the phenylenediamine of hydroxypropyl, 2-methoxy p-phenylenediamine (PPD), 2-(1, 2-dihydroxy ethyl)-p-phenylenediamine (PPD), 2, 2 '-(2-(4-ADPA)-ethyl-urea two base)-diethanol, 2-(2, 5-diaminourea-4-methoxyphenyl)-propane-1, 3 glycol, 2-(7-amino-2H-benzo [b] [1, 4] oxazines-3 (4H) ethanol, 2-chloro-1, 4-phenylenediamine, para-aminophenol, paramethylaminophenol, 4-amino-3-methylphenol, the amino metacresol of 6-, 5-ethyl o-aminophenol, 2-methoxyl group P-pHENYLENE dI AMINE, 2, 2'-di-2-ethylhexylphosphine oxide PAP, 2, 4, 5, 6-tetraminopyrimidine, 2, 5, 6-triamido-4-ancymidol, 4, 5-diaminostilbene-(2-ethoxy) pyrazoles sulfate, 4, 5-diaminostilbene-methylpyrazole, 4, 5-diaminostilbene-ethylpyrazol, 4, 5-diaminostilbene-isopropylpyrazol, 4, 5-diaminostilbene-propylpyrazol, 4, 5-diaminostilbene-pentyl pyrazoles, 4, 5-diaminostilbene-Phenylpyrazole, 2, 3-diaminourea-6, 7-dihydro-pyrazolo [1, 2-a] pyrazoles-1 (5H)-dimethyl sulfate, 4, 5-diaminostilbene-hexyl pyrazoles, 4, 5-diaminostilbene-heptyl pyrazoles, methoxyl methyl-1, 4-diaminobenzene, with and composition thereof.
Implement in example at least one, described elementary mediator is 2-methoxyl methyl-Isosorbide-5-Nitrae-diamidogen benzene.2-methoxyl methyl-Isosorbide-5-Nitrae-diamidogen benzene has good sensibilization (such as, can reduce the probability of scalp skin reaction).Implement in example at least one, described elementary mediator is 4,5-diaminostilbene-hexyl pyrazoles.Implement in example at least one, the sulfate of described 4,5-diaminostilbenes-hexyl pyrazoles is used.Implement in example at least one, described elementary mediator is: 4,5-diaminostilbene-butyl pyrazoles, 4,5-diaminostilbene-amyl group pyrazoles, 4,5-diaminostilbene-Phenylpyrazole, 2,3-diaminourea-6,7-pyrazoline [1,2-a] pyrazoles-1 (5H) dimethyl sulfate, 4,5-diaminostilbene-hexyl pyrazoles, 4,5-diaminostilbene-heptyl pyrazoles, methoxyl methyl-Isosorbide-5-Nitrae-diaminobenzene, and its salt, especially as its chloride, sulfate, and Hemisulphate.
Implement in example at least one, described colour coupler is a compound at least containing a phenyl ring, and described phenyl ring has at least one hydroxyl substituent.Implement in example at least one, the described quality phase is: resorcinol, 4-chloro resorcinol, 2-chloro resorcinol, 2-methylresorcinol, 4, 6-bis-chloro resorcinol, 4, 6-dichloro resorcinol, 2, 4-dimethyl-1, 3-Benzodiazepines, m-aminophenol, 4-amino-2-hydroxy-methylbenzene, 2-methyl-5-Hydroxyalkyl ethylamino phenol, 3-amino-2, 6-xylenol, 3-amino-2, 4-chlorophenesic acid, the amino orthoresol of the chloro-5-of 6-, the amino orthoresol of the chloro-5-of 4-, oxybenzene morpholine, 2-amino-5-ethyl-phenol, 2-amino-5-xenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol, 2-amino-5-thanatol, 5-methyl-2-methylamino phenol, 2, 4-diaminourea-phenoxyethanol, 2-amino-4-hydroxyethylaminoanisole, 1, 3-two-(2, 4-diamino phenoxy) propane, N, N-bis-(2-ethoxy)-2-methyl isophthalic acid, 3-phenylenediamine, 1, 3-phenylenediamine, 2, 2 '-(4, 6-diaminostilbene, 3-phenylene), 2, 2'-(4, 6-diaminostilbene, 3-phenylene) two (oxygen)-diethanolamine, 3-(1-pyrrolidinyl) aniline, 1-(3-(dimethylamino) phenyl) carbamide, 1-(3-aminobenzene) carbamide, naphthols, 2-methyl naphthols, 1, 5-dihydroxy naphthlene, 2, 7-dihydroxy naphthlene, or, 2-methyl naphthols-1-acetas, 4-chloro-2-methyl naphthalene, 4-methoxyl group-2-methyl naphthalene, 2, 6-dihydroxy-3, 4-lutidines, 2, 6-dimethoxy-3, 5-diamino-pyridine, 3-amino-2-methylamine-6-methoxypyridine, 2-amino-3-pyridone, 2, 6-diamino-pyridine, 2, 6-dihydroxy-pyridine, 5, 6-dihydroxy indole, 6-oxyindole, 5, 6-dihydroxy indole quinoline, 3-methyl isophthalic acid-phenyl-1H pyrazoles-5 (4H)-quinoline ketone, 1, 2, 4-benzenetriol, ethoxy-3, 4-methylene dioxo group aniline, with and composition thereof.
Implement in example at least one, described oxidation dye precursors is: naphthols, 2,4-diamino phenoxy ethanol, sulphuric acid-2,5-diaminotoluene, resorcinol, to amino metacresol, the chloro-4-nitrophenol of 2-amino-6-, 2-amino-4-N-(beta-ethoxy) aminobenzoic ether sulfate, N-ethoxy-3,4-methylene dioxo group aniline hydrochlorate, 4,5-diaminostilbene-(2-ethoxy) pyrazoles sulfate, 4-amino-2-hydroxy-methylbenzene, 2-methylresorcinol, m-aminophenol, 2-methyl-5-N-hydroxyethylaminophenol with and composition thereof.
Implement in example at least one, described oxidation dye precursors contains 5-amino-4-chlorine orthoresol and 2-methoxyl methyl-Isosorbide-5-Nitrae-two phenalgin.Implement in example at least one, described oxidation dye precursors contains DAP and 2-methoxyl methyl-Isosorbide-5-Nitrae-diaminobenzene.Implement in example at least one, described oxidation dye precursors contains 2,6-dihydroxy ethyl ammonia toluene and 2-methoxyl methyl-Isosorbide-5-Nitrae-diaminobenzene.Implement in example at least one, described oxidation dye precursors contains 2-methoxyl methyl-Isosorbide-5-Nitrae-diaminobenzene and p-phenylenediamine (PPD) and/or toluenediamine.
Implement in example at least one, the content altogether of described oxidation dye precursors and colour coupler is 0.001% to 12%, or 0.01% to 10%, or 0.05% to 9%, or 1% to 6%.
Implement in example at least one, described mixture is further containing a direct dyes.Described direct dyes is preferably an oxidation-stabilized direct dyes.Implement in example at least one, described dye mixture contain direct dyes altogether content be 0.001% to 4%, or 0.005% to 3%, or 0.01% to 2%.The use of direct dyes can strengthen Color, especially strengthens staining power.
Implement in example at least one, described mixture dye mixture does not have direct dyes substantially.In fact, a lot of client is partial to the dye mixture without direct dyes.
Implement in example at least one, described direct dyes contains provides blue, red, and the nitro dye of yellow, quinone dyestuff, base dye, neutral azo dye, acid stain, with and composition thereof.Implement in example at least one, described direct dyes is a nitro dye providing blue.Implement in example at least one, described direct dyes is a nitro dye providing red.Implement in example at least one, described direct dyes is a nitro dye providing yellow.Implement in example at least one, described direct dyes is a quinone dyestuff.Implement in example at least one, described direct dyes is a base dye.Implement in example at least one, described direct dyes is the azo dye of a neutrality.Implement in example at least one, described direct dyes is an acid stain.Implement in example at least one, described direct dyes is selected from following fuel: Indian yellow 1, acid orange 3, acid black 1, acid black 52, acid orange 7, Xylene Red 33, acid yellow 23, acid blue 9, acid violet 43, Blue VRS 6, Acid blue 62, acid blue 25, Xylene Red 4, base dye, such as bismarck brown 17, safranine 118, Basic Orange 69, safranine 76, bismarck brown 16, basic yellow 57, basic violet 14, Blue 7, alkali blue 26, safranine 2, alkali blue 99, basic yellow 29, safranine 51, Basic Orange 31, basic yellow 87, 4-(3-(4-amino-9, 10-dioxy base-9, 10-dihydroanthracene-1-amido) propyl group)-4-methyl morpholine base-4-cation-dimethyl sulfate, (E)-1-(2-(4-(4, 5-dimethyl azo azoles) diazenyl) phenyl (ethyl) amino) ethyl)-3-methyl isophthalic acid H-imidazoles-3-cation hydrochloric acid, (E)-4-(2-(4-(dimethylamino) phenyl) diazenyl)-1-methyl isophthalic acid H-imidazoles-3-cation) butyl-1-sulphonic acid ester, (E)-4-(2-(4-(dimethylamino) phenyl) diazenyl)-1-methyl isophthalic acid H-imidazoles-3-cation) butane-1-sulphonic acid ester, (E)-4-(4-(2-methyl-2-phenyl hydrazono-) methyl) pyridine) butyl-1-sulphonic acid ester, N, N-dimethyl-3-(4-(methylamino)-9, 10-dioxy base-4a, 9, 9a, 10-tetrahydrochysene anthracene-amine)-N-propyl group propane-1-ammonium bromide.Disperse dyes, such as Red-1 200 7, disperse violet 1, Red-1 200 5, disperse violet 1, disperse black 9, disperse blue 3, disperse blue 23, disperse blue 377, nitro dye, such as 1-(2-(4-Nitrobenzol is amino) ethyl) carbamide, 2-(4-methyl-2-Nitrobenzol is amino) ethanol, 4-Nitrobenzol-1, 2-diaminourea, 2-Nitrobenzol-1, 4-diaminourea, 4,6-dinitro-2-aminophenol., HC red 13, 2, 2 '-(2-nitro-1, 4-phenylene) two (urea two base) diethanol, HC Huang 5, HC red 7, HC indigo plant 2, HC Huang 4, HC Huang 2, HC orange 1, HC red 1, 2-(the chloro-5-Nitrobenzol of 4-amino-2-is amino) ethanol, HC red 3, 4-amino-3-nitrophenols, 4-(2-hydroxyethylamino)-3-nitrophenols, 2-amino-3-nitrophenols, 2-(3-(methyl ammonia)-4-nitrophenoxy) ethanol, 3-(3-amino-4-nitrophenols) propane-1, 2-glycol, HC Huang 11, HC purple 1, HC orange 2, HC orange 3, HC Huang 9, HC red 10, HC red 11, 2-(2 hydroxy ethylamine base)-4, 6-dinitrophenol, HC indigo plant 12, HC Huang 6, HC Huang 12, HC indigo plant 10, HC Huang 7, HC Huang 10, HC indigo plant 9, the chloro-6-of 2-(ethylamino-)-4-nitrophenols, 6-nitropyridine-2, 5-diamidogen, HC purple 2, the chloro-4-nitrophenols of 2-amino-6-, HC Huang 13, 6-nitro-1, 2, 3, 4-tetrahydroquinoxaline, HC red 14, HC Huang 15, HC Huang 14, N2-methyl-6-nitropyridine-2, 5-diamidogen, N1-pi-allyl-2-Nitrobenzol-1, 4-diamidogen, HC red 8, HC green 1, HC indigo plant 14, and natural dye, such as cheese is yellow, anthocyanidin, beet root, carotene, capsanthin, lycopene, chlorophyll, henna, bipseudoindoxyl dye, alkermes.
Implement in example at least one, described dye mixture contains cosmetics acceptable carrier.Implement in example at least one, described cosmetics acceptable carrier is a water-solubility carrier.Implement in example at least one, described dye mixture contains water.Water extraction for an aqueous favoring, the hydrophilic group in other compositions can with aqueous phase mutual effect.Water also provides a mobile phase, this means that mix ingredients can be liquid, and easy and other liquid mixing, such as oxidation recipes.Implement in example at least one, described mixture contains 50% to 85%, or the water of 65% to 75%.
Implement in example at least one, described cosmetics acceptable carrier active component can be made into the carrier that can use on hair arbitrarily.Implement in example at least one, described cosmetics acceptable carrier is aqueous medium or ethanol-water mixed solvent medium.Implement in example at least one, when described carrier is water-ethanol mixed solvent medium, described carrier contains water and a kind of ethanol.Effect is actually, it can affect the viscosity of mix ingredients on a large scale, such as, may be present in the polymer in mixture.Implement in example at least one, to be describedly selected from actually: ethanol, isopropyl alcohol, propanol and their mixture.Implement in example at least one, when described carrier is aqueous medium, described carrier forms primarily of water, and does not substantially have ethanol.Implement in example at least one, described mixture contains content safety and effective cosmetics acceptable carrier.Implement in example at least one, it is 0.1% to 99% that described mixture contains content, or 1% to 98%, or 10% to about 97%, or the water of 30% to 95%.
Implement in example at least one, described mixture does not have ethanol substantially, as volatile actually (e.g., ethanol, isopropyl alcohol, propanol).Advantage is not actually had to be reduce abnormal smells from the patient and/or flammability issues.
Implement in example at least one, described cosmetics acceptable carrier is an oiliness compound.Implement in example at least one, this oiliness compound is selected from following composition: circulation silica gel and volatile Hydrocarbon.Circulation silica gel can have been bought from Dow Corning Corporation.Implement in example at least one, described circulation silica gel has at least 3 silicon atoms or at least 5 silicon atoms, but is no more than 7 or 6 silicon atoms.Implement in example at least one, the structure of circulation silica gel is as follows:
Wherein, n is at least 3, or is at least 5, but is not more than 7 or be not more than 6.Implement in example at least one, the dynamic viscosity of described circulation silica gel is less than 10cSt at 23 DEG C.One suitable circulation silica gel includes, but are not limited to, cyclomethicone D5 (trade name is G.E. silica gel).Implement in example at least one, described mixture is not containing silica gel.
Volatile Hydrocarbon, as Isopars can obtain from Exxon Mobil petrochemical industry.Implement in example at least one, described oiliness compound is Dormant oils.The trade name of suitable Dormant oils comprises Benol, Blandol, Hydrobrite, Kaydol (SonnebornLLCRefinedProducts, this company limited of Sohne purified product), ChevronSuperlaWhiteOil (Chevron Corporation's product), Drakeol, Parol (CalumetPenrecoLLC), Peneteck (CalumetPenrecoLLC), Marcol and Primol352 (Exxon Mobil petrochemical industry).
Implement in example at least one, described mixture contains a hydrophobic phase.Implement in example at least one, describedly hydrophobicly to contain mutually: fatty alcohol, fatty acid, or its mixture.Implement in example at least one, described fatty alcohol and/or fatty acid contain 10 to 30, or 12 to 20, or 16 to 18 carbon atoms.Implement in example at least one, described hydrophobic mutually containing two kinds of different fatty alcohol.Implement in example at one, described hydrophobic mutually containing two kinds of different fatty alcohol, wherein often kind of fatty alcohol is all containing 10 to 14 carbon atoms.
The dynamic viscosity of described mixture is 0.5cSt to 1500cSt at 23 DEG C." viscosity " can refer to dynamic viscosity (weighing under mPas) or the dynamic viscosity (measuring in units of centistoke, cSt) of liquid under 23 DEG C and ambient conditions.Dynamic viscosity can pass through use one rotary viscosity measuring, such as, can strangle the Brookfield dial reading viscometer flying engineering experiment room (U.S.) and obtain, model 1-2RVT, and model known in other industry from the U.S. is rich.Operable typical Brookfield spindle wave includes, but are not limited to, and axle rotating speed is the RV-7 of 20rpm.Concrete axle rotating speed is determined by technical staff.Dynamic viscosity can be obtained divided by fluid density (23 DEG C and ambient conditions) by dynamic viscosity.
Described viscosity can make described mixture easily use on fiber-such as, dispersed on hair.Viscosity can be subject to the impact of cosmetics acceptable carrier and thickening agent in mixture.
Implement in example at least one, the dynamic viscosity of described mixture is 1 to 1000cSt.Implement in example at least one, the dynamic viscosity of described mixture is 1.5 to 500cSt, or 2cSt to 350cSt, or 2.5cSt to 200cSt, or 3cSt to 150cSt, measures in 23 DEG C.1cSt equals 1x10
-6m
2/ s.
Implement in example at least one, the dynamic viscosity of described mixture is 1mPas to 5000mPas.Implement in example at least one, the dynamic viscosity of described mixture is 2mPas to 400mPas, or 3mPas to 100mPas.Or implement in example at least one, the dynamic viscosity of described mixture is 30mPas to 250mPas, or 100mPas to 200mPas.
Described viscosity scope helps prevent mixture to drip.When viscosity is too high, described mixture is not easy to mix with such as cosmetics acceptable carrier.
In at least one enforcement example, described mixture does not have vapour pressure substantially lower than 0.01mmHg or the compound lower than 0.001mmHg, and measuring condition is 23 DEG C and 1atm.Low volatility can reduce abnormal smells from the patient and safer.
The pH value of described mixture is 8 to 12.Implement in example at least one, pH value is 8.0 to 9.0, or 9.1 to 10.0, or 10.1 to 11.0, or 11.1 to 12.0.
Described mixture can contain a pH value regulator and/or buffer agent, and its content enough effectively regulates the pH value of mixture/formula, makes it fall into specified scope.Suitable pH value regulator and/or buffer agent comprise, but be not limited to, ammonia, alkanolamine, such as monoethanolamine, diethanolamine, triethanolamine, propanol ammonia, two propanol ammonia, three propanol ammonia, 2-amino-2-methyl-1-propanol, 2-amino-2-methylol-1, ammediol, guanidinesalt salt, alkali metal, ammonium hydroxide and ammonium carbonate, preferred sodium hydroxide, sodium silicate, unit's sodium silicate, ammonium carbonate, and acidulant, such as inorganic and organic salt, such as, phosphoric acid, acetic acid, ascorbic acid, citric acid, or tartaric acid, hydrochloric acid, with and composition thereof.Implement in example at least one, pH value is regulated by ammonia or ethanolamine.
Implement in example at least one, described mixture contains an alkaline agent.Alkaline agent refers to one or more compounds for improving pH value.Generally speaking, the alkaline agent the most often used is ammonia.Non-ammonia alkaline agent is also helpful for reduction olfactory stimulation.Such as, take monoethanolamine as the alkanolamine of representative.Described non-ammonia alkanolamine is selected from following compound: monoethanolamine (MEA), sodium silicate, first sodium silicate, diethanolamine, triethanolamine, propanol ammonia, two propanol ammonia, three propanol ammonia, 2-amino-2-methyl-1, ammediol, 2-amino-2-methyl-1-propanol (also known as, aminomethyl propanol, AMP), TRIS, with and composition thereof.Monoethanolamine (MEA) or aminomethyl propanol (AMP) are generally used in without in ammonia hair dyeing product, and as alkaline agent separately or use together with other alkaline agents.Particularly be preferably, monoethanolamine is independent or use together with other non-ammonia alkaline agents.Mixture described herein can also contain ammonia except non-ammonia alkaline agent, such as, be less than the ammonia of 0.5%.In a case study on implementation, alkaline agent is monoethanolamine (MEA).
Implement in example one, the alkaline agent that described mixture contains is monoethanolamine (MEA), and its elementary mediator contained is 2-methoxyl methyl-Isosorbide-5-Nitrae-diamidogen benzene.
Implement in example at least one, described mixture contains at least one antiseptic and/or a preservative blends.Implement in example at least one, described mixture contains 0.01% to 1%, or the antiseptic of 0.1% to 0.5%.Implement in example at least one, antiseptic is selected from: benzylalcohol, phenoxyethanol, 1,3-dihydroxymethyl-5,5-dimethyl hydantion, with and composition thereof.Implement in example at least one, described mixture contains at least one antiseptic, and described antiseptic is selected from: benzylalcohol, phenoxyethanol with and composition thereof, or described antiseptic is the mixture of benzylalcohol and phenoxyethanol.Only at least one is implemented in example, described mixture does not have benzoic acid salt compound substantially.Benzoic acid salt compound is not preferred in the stability and/or precipitation of mixture.Implement in example at least one, described mixture does not have nipalgin substantially.Some client does not like nipalgin.
Implement in example at least one, described mixture has a chelating agen.Implement in example at least one, the content of described chelating agen enough reduce can with other compositions, such as oxidant in mixture, be peroxide in particular, tenor.Implement in example at least one, described chelating agen is selected from: diamidogen-N, N-bis-polyacid, monoamine, monoamides-N, N,-two polyacid, and N, N-bis-(2-hydroxy phenyl) ethylene diamine-N, N'-diacetin hydrochlorate chelating agen (such as EDDS (ethylene diamine disuccinic acid)), carboxylic acid (such as amino carboxylic acid), phosphoric acid (phosphoramidic acid), polyphosphoric acid (straight polyphosphoric acid), its salt and its derivant, and play mixture.Because described mixture has alkaline pH, so there is (losing proton) with the form of anion or exist in a salt form in the acid mentioned herein.Implement in example at least one, described chelating agen is edetate, a kind of salt of ethylenediaminotetraacetate (edetate) (EDTA) and/or a kind of salt of etidronic acid.Implement in example at one, described chelating agen is a kind of salt of EDDS or EDDS.
Implement in example at least one, described mixture contains at least one peroxycarbonic acid ion source.Peroxycarbonic acid ion is obtained by hydrogen peroxide and carbonate ions.Implement in example at least one, described mixture contains carbonate ions source, or carbamate ions, or heavy carbonic ion source, or its mixture.Implement in example at least one, described peroxycarbonic acid ion source is selected from sodium, potassium, guanidine, arginine, lithium, calcium, magnesium, barium, the carbonate of ammonium, carbaminate and heavy carbonate, with and composition thereof.Implement in example at least one, described peroxycarbonic acid ion source is selected from sodium carbonate, sodium bicarbonate, potassium carbonate, potassium bicarbonate, guanidine carbonate, bicarbonate guanidine, lithium carbonate, calcium carbonate, magnesium carbonate, brium carbonate, ammonium carbonate, ammonium bicarbonate, with and composition thereof.Percarbonate also can be used to provide carbonate ions source and oxidant source.Carbonate ions source, carbamate ions, and heavy carbonic ion source can be selected from: sodium bicarbonate, potassium bicarbonate, aminoquinoxaline with and composition thereof.
Implement in example at least one, described mixture contains a free radical scavenger.Implement in example at least one, the amount that described free radical scavenger exists enough reduces the infringement to hair in hair dyeing or bleaching process.Described free radical scavenger is preferably different from alkaline agent.Described free radical scavenger can react with carbonate radical and convert not it to so activated kind of tool by a series of fast reaction.Described free radical scavenger can be selected from: alkanolamine, amino sugar, aminoacid, with and composition thereof.Described free radical scavenger can be selected from:
Monoethanolamine, 3-amino-1-propanol, 4-amino-n-butyl alcohol, 5-amino-1-amylalcohol, 1-amino-2-propanol, 1-amino-2-butanols, 1-amino-2-amylalcohol, 1-amino-3-amylalcohol, 1-amino-4-amylalcohol, 3-amino-2-methyl-1-propanol, 1-amino-2-methyl-2-propanol, 3-amino-1,2-PD, glucamine, N-acetyl-glucosamine, glycine, arginine, lysine, proline, glutamic acid, histidine, serine, tryptophan, and its potassium salt, sodium salt and ammonium salt, with and composition thereof.Implement in example at one, described free radical scavenger can be selected from: benzylamine, paddy aminoacid, imidazoles, di-t-butyl hydroxyl cresol, hydroquinone, catechol with and composition thereof.
Implement in example at least one, described mixture has cried out a surfactant.Surfactant helps to form Emulsion.Implement in example at least one, described mixture is Emulsion.Implement in example at least one, described mixture is a butterfat or glue.Implement in example at least one, described mixture has one deck striated structure and/or becomes gel network.Implement in example at least one, described mixture contains the micelle wrapping up hydrophobic phase.
Implement in example at least one, described mixture contains 0.001% to 10%, or 0.1% to 8%, or 0.5% to 5%, or 0.4% to 2%, or the surfactant of 0.8% to 1.5%.
Implement in example at least one, the surfactant that described mixture contains is selected from: anion surfactant, amphoteric surfactant, zwitterionic surfactant, ionic surfactant, non-ionic surface active agent with and composition thereof.Described surfactant is used for the hydrophobic phase in stabilized mixture, such as stabilized zone striated structure and/or one-tenth gel network.
Implement in example at least one, described mixture contains an anionic surfactant.Implement in example at least one, described anionic surfactant is sodium lauryl sulphate or sodium laureth sulfate.
Implement in example at least one, described surfactant is non-ionic surface active agent.Described non-ionic surface active agent is selected from: lanolin alcohol, and the polyoxyethylene ether of fatty alcohol, with and composition thereof.Implement in example at one, described non-ionic surface active agent is ceteareth-n, and wherein n is 2 to 100, or 10 to 30.The advantage of non-ionic surface active agent is used to be that any electric charge or salt can cause the sedimentation of other compositions.Implement in example at least one, described mixture contains 0.001% to 5%, or 0.01% to 3%, or 0.01% to 1%, or 0.05 to 1%, or 0.1% to 0.5%, or the non-ionic surface active agent of 0.1% to 0.3%.Described non-ionic surface active agent is selected from lanolin alcohol, and the polyoxyethylene ether of fatty alcohol, with and composition thereof.Implement in example at one, described non-ionic surface active agent is ceteareth-n, and wherein n is 2 to 100, or 10 to 30.Implement in example at least one, described non-ionic surface active agent is an Oleum Ricini containing polyethylene glycol ether group or glycol polypropylene ether group.Implement in example at least one, described polyethylene glycol ether group is the ether of PEG-n, and wherein n is 2 to 12, or 2 to 10, or the integer between 3 to 8.The molecular weight being preferably described polyethylene glycol ether group is less than 400Da thus easily changes mixing.Implement in example at least one, described polyethylene glycol ether group is the ether of PEG-n, and wherein n is 2 to 60, or 10 to 50, or the integer between 20 to 40.Implement in example at least one, described polyethylene glycol ether group or glycol polypropylene ether group are selected from: PPG-4, PPG-6, PEG-5, PEG-6, PEG-8, with and composition thereof.Implement in example at least one, described mixture contains the Oleum Ricini of hydrogenation PEG-40 and/or PEG-60 Oleum Ricini and/or Cremophor ELP as non-ionic surface active agent.
Implement in example at least one, described mixture contains a thickening agent.The effect of thickening agent is to provide the mobility required for mixture, this to mixing with prevent from dripping very important.Implement in example at least one, described mixture contains the thickening agent of 0.01% to 5%.Implement in example at least one, described thickening agent is the thickening agent of a polymerization or the polymer of thickening.Implement in example at least one, described mixture contains the polymer of the thickening of 0.1% to 2%.Implement in example at least one, the polymer of described thickening is selected from association polymer, cross-linked acrylic acid homopolymer, (methyl) crosslinked acrylic copolymer and (C1-C6) alkyl acrylate cross-linked copolymer or polysaccharide.Described polymer is also used as regulator.
Implement in example at least one, described mixture contains a regulator.Implement in example at least one, described regulator is selected from: silicone material, amido silicon oil, fatty alcohol, polymeric resin, polyol carboxylate, cationic polymer, cationic surfactant, insoluble oil and oily derived material with and composition thereof.Implement in example at least one, described regulator is selected from mineral oil, glycerol, and sorbitol.
Implement in example at least one, described mixture contains 0.05% to 20%, or 0.1% to 15%, or 0.2% to 10%, or the regulator of 0.2% to 2%.Particularly usefully, regulator is cationic polymer and silicones.Those skilled in the art can select cationic polymer regulator for improving the characteristic of the keratin fiber of mixed thing process.Cationic polymer can be selected from the compound containing an amino, and described amino can be primary amine, secondary amine, tertiary amine and quaternary amine, and these amino can form a part for main chain, or is arranged in the side chain be directly connected with main chain.
Implement in example at least one, described regulator is a silicones.Implement in example at least one, described silicones is selected from poly-alkylsiloxane oil, linear polydimethylsiloxanes containing TMS or hydroxyl dimethyl siloxane terminal groups is oily, PSI oil, polydimethyl phenyl siloxane or poly-and methyldiphenyl radical siloxane, silicones, has the siloxanes of one or more identical or different organo-functional group in its structural formula, and these functional groups are directly connected with siloxane chain.Described organo-functional group is selected from: polyoxyethylene, and/polyoxypropylene group, (one) fluorine group, mercapto, the amino being substituted or not being substituted, carboxylate group, hydroxylation base, alkoxyl, quaternary ammonium group, both sexes and betaine group.Described silicones can use with clean and tidy fluid or with preformed Emulsion.
Implement in example at least one, described mixture contains spice.Implement in example at least one, described mixture contains the spice of 0.001% to 2%.The existence of spice can improve use procedure, and/or brings the mood conformed to visual effect---such as loosen or exciting taste.
Implement in example at least one, described mixture does not have spice and/or fragrance substantially.Some clients tendency does not have the formula of spice.It should be noted that the possibility that will reduce when selecting spice as far as possible and react with the elementary mediator used and colour coupler.
Also can pass through to use flavor capsule, as being wrapped in the spice in tiny capsules.Implement in example at least one, described mixture contains flavor capsule.
Implement in example at least one, described capsule has friction and triggers release tech, and the implant namely in capsule is released when capsule is subject to rubbing.Described friction can be spread upon by dyeing mixture of the present invention on hair or be applied on combing hair after on hair at mixture.Implement in example at least one, described tiny capsules is frangible microcapsule.When the outer casing rupture of tiny capsules, implant is wherein released.Implement in example at least one, described microcapsule has a shell be made up of synthesizing polymeric material.Implement in example at least one, described microcapsule contains a center material and wraps up the shell of this center material, wherein said shell contains: multiple amine monomers, be selected from acrylate, alkyl acrylate, two alkyl acrylate, aminoalkyl methacrylates, alkylamino aminoalkyl methacrylates, two alkyl aminoalkyl methacrylates, tert-butyl group aminoethyl methacrylate, diethyl amino ethyl group methacrylate, dimethylaminoethyl methacrylate, dipropyl aminoethyl methacrylate, with and composition thereof, and multiple polyfunctional monomer or polyfunctional group oligomer.Implement in example at least one, described shell is made up of polyacrylate, as polyacrylate random copolymer.Implement in example at least one, described microcapsule has humidity and triggers release tech, and namely described microcapsule discharges its inclusions once touching moisture.Implement in example at least one, described microcapsule contains the few candy of ring-type, or the shell of described microcapsule is made up of the few candy of ring-type." ring-type few candy " refers to a circulus containing six or more sugar units.Implement in example at least one, the few candy of described ring-type contains 6,7 or 8 sugar units or its combination.Hexa-atomic, the few candy of seven yuan and octatomic ring shape is known as α, β, and γ.Implement in example at least one, the few candy of described ring-type is selected from cyclodextrin: methyl-alphacyclodextrin, methyl-B-cyclodextrin, Hydroxyproply-α-cyclodextrin, HP-β-CD, with and composition thereof.Described cyclodextrin can be the form of granule.Described cyclodextrin also can be spray dried.
Implement in example at least one, described spice is an animal or plant spice.Implement in example at least one, described animal perfume material is selected from Moschus oil, civet, castoreum, Ambra Grisea with and composition thereof.Implement in example at least one, described plant perfume is selected from Semen Myristicae extract, Fructus Amomi Rotundus extract, Rhizoma Zingiberis Recens extract, Cortex Cinnamomi extract, patchouli oil, Herba Erodii oil, orange peel oil, mandarin oil, the extraction of Fructus Citri tangerinae flower, Lignum seu Ramulus Cunninghamiae Lanceolatae, cus-cus hay-scented, Garden lavender, fragrant cananga extract, tuberous extraction, Oleum Santali albi, bergamot oil, oil of rosemary, Oleum Menthae Rotundifoliae, Oleum menthae, Fructus Citri Limoniae oil, Essential lavender oil, citronella oil, chamomile oil, Oleum Caryophylli, sage oil, bitter orange flower oil, labdanum oil, eucalyptus oil, Herba Verbenae oil, wattle extract, narcissus extract, carrot seed extract, Flos Jasmini Sambac extract, Olibanum extract, rose extract, with and composition thereof.Implement in example at least one, described spice is selected from acetophenone, A Daoke aldehyde, aldehyde C-12, aldehyde C-14, aldehyde C-18, allyl octanoate, dragon saliva furan, pentyl acetate, dimethyl indene derivative, α amyl cinnamic aldehyde, anethole, anisaldehyde, benzaldehyde, benzyl acetate, benzyl alcohol and ester derivant, benzyl propionate, benzyl salicylate, Borneolum Syntheticum, butyl acetate, Camphora, carbitol, cinnamic aldehyde, cinnamyl acetate, cinnamyl alcohol, the derivant of Cis-3-hexenol and ester, cis-3-hexenol methyl carbonate, citral, citronellol and ester derivant, cumal, cyclamen aldehyde, cyclogalbanate, damascenone, decalactone, Decanol, chavicol methyl ether, dihydromyrcenol, dimethyl benzyl carbinol, 6, 8-dimethyl-2-nonyl alcohol, butanoic acid dimethyl benzyl carbinol ester, ethyl acetate, methylpropanoate, ethyl n-butyrate., ethyl propionate, ethyl caprilate, ethyl cinnamate, ethyl hexylate, ethyl vanillin, acetaminol, pentadacanolide, fenchone, fruit ester, such as ethyl 2-methylbutyrate, galaxolid, geraniol and ester derivant, helional, 2-heptanone oxime, hexenol, jasminolene, hydroxycitronellal, indole, isoamyl acetate, isoeugenol acetale, ionone, isoeugenol, iso-amyl iso-valeriate, ambrotone, limonene, linalool, lilestralis, linalyl acetate, LYRAL, alcohol grinds in U.S.A, May convallarol, melonal, menthol, melilotal, methyl 2-aminobenzoate, vertofix coeur, MDJ, Allylveratrole, methyl ionone, methyl-Alpha-Naphthyl ketone, acetic acid benzene Zhong Yi (base) ester, 1-(4-isopropyl cyclohexyl)-ethanol, arbricolin, octanal, phenethyl acetate, acetic acid benzene second dimethyl, phenoxyethyl isobutyrate, phenethanol, pinene, sandalidol, santalol, greenolivetone, thymol, terpenes, ligustral, triethyl citrate, 3, 3, 5-trimethyl-cyclohexane, gamma-undecalactone, vanillin, vanillin, all roads ketone, verdox with and composition thereof.
Implement in example at least one, described mixture contains pigment.Implement in example at least one, described pigment makes product have color and makes hair-dyeing, or mixture or keratin fiber have required gloss.The effect of described color and gloss is preferably temporary, and namely these lasts are to having one's hair wash and can remove by using shampoo next time.
Implement in example at least one, described mixture does not have pigment substantially.Sometimes, client's deflection does not have the dyeing mixture of pigment, thus avoids hair there is sensation that is residual and/or hair coarse.
Implement in example at least one, the pigment granule that dyeing mixture of the present invention contains has D
50diameter is 5 to 60 microns.D
50particle diameter refers to the median diameter of volume.D
50measured by Malvern Particle Size Analyzer 2000, this instrument is laser diffraction particle size analyzer, and measure according to Hydro2000G or Hydro2000SISO13320:2009 (en), wherein dispersant is water or ethanol.Measuring range is 0.02micron to 2000 micron.D
50with the x of ISO13320:2009 (en)
50express.Laser diffraction is by measuring the light intensity angle measure of the change granular size when a laser passes through the particulate samples analyser of dispersion, and granular size is expressed with volume equivalent diameter scope.D
50the discussion of measurement ask for an interview Barberetal, PharmaceuticalDevelopmentandTechnology, 3 (2), 153-161 (1998), this book is listed in list of references at this.
Implement in example at least one, the pigment that dyeing mixture of the present invention contains has D
50particle diameter 10 to 40 microns.Implement in example at least one, described pigment exists with undissolved form.Implement in example at least one, described mixture contains 0.01% to 25%, or 0.1% to 20% pigment, or 1% to 15%, or 4% to 10% pigment.These pigments can be organic compound can be also inorganic compound, does not substantially dissolve in the mixture.Inorganic-organic hybrid pigment also can use.Implement in example at least one, described mixture contains inorganic pigment.Use the advantage of inorganic pigment be its to light, the toleration of weather and temperature.Implement in example at least one, described inorganic pigment has natural source, comes from, such as, chalk rock, Haematitum, dark brown, seladonit, burnt ochre, and graphite.Implement in example at least one, described pigment is white pigment, e.g., and titanium dioxide, zinc oxide, black pigment, as iron oxide black, or other color color pigments, such as, ultramarine, iron oxide red, colour lustre pigments, metal effect pigments, pearlescent pigment, fluorescence or phosphorescent pigment.Implement in example at least one, described pigment has nonwhite color.Implement in example at least one, described pigment is selected from: metal-oxide, metal hydroxides, metal oxide hydrate, hybrid pigment, sulfur-bearing silicate, sulfide, complicated metal cyanides, metal sulfate, metal dichromate, and metallographic phase hydrochlorate, and metal itself (bronze pigments).Implement in example at least one, described pigment is selected from titanium dioxide (CI77891), Black Rouge (CI77499), yellow ferric oxide (CI77492), red and brown iron oxide (CI77491), manganese violet (CI77742), ultramarine (lagoriolite, CI77007, pigment indigo plant 29), Prussian blue (ferric ferrocyanide, CI77510), carmine (alkermes), and its combination.
Implement in example at least one, described pigment is pearl, and based on Muscovitum, and the color of matel coated oxide or metal acyl chlorides thereon, such as titanium dioxide or bismuth oxychloride, and other coloring matters selectable, such as ferrum oxide, Prussian blue, carmine, and alkermes.The color that pigment presents can by its thickness adjusted.These pigments are sold under following brand name,
and
it is the product of Darmstadt, Germany Merck & Co., Inc..Such as,
be color tourism pigment, be presented at flip-flop color change effect under different visual angle, color basis is natural mica, and silicon dioxide or calcium aluminoborosilicate sheet, scribble the TiO of different-thickness
2.U.S. Plain town KoboProducts, Inc., 3474So.ClintonAve., So.'s
product line is also used, and especially its surface is treated
margarita pigment.The said firm
fINEWHITE (Muscovitum and TiO
2) there is D
50particle diameter 5 to 25 microns, and
cELESTIALLUSTER (Muscovitum and TiO
2, 10 to 60 microns), and
cLASSICWHITE (Muscovitum and TiO
2, 10 to 60 microns), these products all have use value very much.Like that the SynCrystalSapphire of card effect pigment is also very useful.This product is blue powder, containing synthesis fluorophologopite thin slice, and scribbles titanium dioxide, ferric ferrocyanide and a small amount of tin ash.Like another product of card, SYNCRYSTALAlmond, also very useful.This product is Beige powder, and has copper reflection colour, containing synthesis fluorophologopite thin slice, scribbles titanium dioxide and ferrum oxide.Bath good fortune
rV524C is also very useful.This product because containing Muscovitum, titanium dioxide and carmine and two kinds of colors having by shinny red powder and purple reflection powder.
Implement in example at least one, described pigment is organic pigment.Implement in example at least one, described organic pigment is selected from natural pigment Ink sepiellae seu sepiae, Resina garciniae, bone carbon black, and you are brown, indigo for jam, chlorophyll and other plant dyestuff.Implement in example at least one, described synthesis organic pigment is selected from AZOpigments, anthraquinone, indigo, dioxazines, quinoline a word used for translation, PHTHALOCYANINE GREEN 7, isoindolinone, perylene, and cyclic ketones dyestuff, metal complex, alkali blue, pyrrolo-pyrrole-dione, and its combination.
Implement in example at least one, described pigment is selected from ferrum oxide, titanium dioxide, Muscovitum, borosilicate, and its combination.Implement in example at least one, described pigment contains ferrum oxide (Fe
2o
3) pigment.Implement in example at least one, described pigment contains the mixture of Muscovitum and titanium dioxide.
Implement in example at least one, described mixture contains colored materials.Implement in example at least one, described coloured material exists in granular form.Implement in example at least one; described colored materials is colored fibre; colored bead; coloured particle is nano-particle such as, and colored polymeric contains the dyestuff connected by chemical bond, liquid crystal; granule containing diffraction property; UV absorbers and photoprotective substances, pressure-sensitive or phytochrome, and its combination.
Implement in example at least one, described mixture does not have colored materials substantially.Sometimes, client's deflection does not have the mixture of colored materials, thus reduces the possibility having residue and sedimentation.
Implement in example at least one, described colored materials can change color by following mechanism: thermochromism, photochromism, wet sensitive colour changing, magneto discoloration, electrochromism, piezochromism, chemical stain, mechanical optics principle (mechano-optics).Suitable material comprises three-dimensional magnetic pigment, light dirt, fluorochrome, hot dust, camouflage paint and other sun color dirt SolarColorDust (
http:// solarcolordust.com/) the material of change color.
Implement in example at least one, described mixture contains photoprotective substances.Implement in example at least one, described mixture contains 0.01 to 10%, or 0.1 to 5%, or the photoprotective substances of 0.2 to 2%.Useful photoprotective substances § 0036 to § 0053 in European patent application EP 1084696A1 sets forth, and is cited as list of references at this.Implement in example at least one, described photoprotective substances is selected from 2-ethylhexyl-4-methoxy cinnamic acid, methyl methoxy base Cortex Cinnamomi; 2-hydroxyl-4-methoxy benzophenone-5-sulfonic acid; polyoxyethylene ether-p-p-aminobenzoate, dibutyl benzylalcohol (BHT), with and composition thereof.
Implement in example at least one, described mixture contains 0.01% to 10%, or the particulate matter of 0.05% to 5%.Implement in example at least one, described particulate matter for being solid and existing in the form of granules under room temperature (23 DEG C).Implement in example at least one, described particulate matter is selected from silicon dioxide, silicate, aluminate class, clay, Muscovitum and insoluble salt.In at least one enforcement example, described particulate matter is selected from insoluble inorganic metal salt, metal-oxide, mineral, and insoluble polymer granule.Implement in example at least one, described particulate matter is titanium dioxide.
Implement in example at least one, described particulate matter, not dissolve or the form of stable dispersion is present in mixture, after for hair and solvent volatilization, can be deposited on hair in solid form.
Implement in example at least one, described particulate matter is selected from tripoli (silica gel, silicon dioxide) and slaine.Implement in example at least one, described particulate matter is tripoli.Implement in example at least one, described particulate matter is selected from alkali metal or alkaline-earth halide, such as sodium chloride or potassium chloride, alkali metal or alkali earth metal sulfate, such as sodium sulfate or magnesium sulfate.
Another aspect of the invention is the use of a kind of monomer in a kind of hair heat-tinting agent composition, the molecular weight of described monomer is less than 200g/mol, and described monomer has following chemical formula:
H
2C＝C(X)-C(＝O)OR
aOH
Wherein X is hydrogen or CH
3, R
abe C1 ~ C4 alkyl, and monomer have water solublity.
Implement in example at least one, the use of described monomer improves mechanical performance and its color effects of hair.
Another aspect of the invention is the test kit for hair-dyeing, this test kit contains: a) said mixture; B) and containing the oxidation recipes of an oxidant, wherein said mixture a) with described formula b) separate and pack.
Implement in example at least one, described test kit is further containing (d) thickening agent formula.The thickening agent sold in the market is " Colorid " brand under the hair caring of Wella specialty.Implement in example at least one, described thickening agent formula contains the thickening polymer that can react with hydrophobic phase and aqueous favoring, and wherein said thickening agent to contain in thickening formula 0.001% to 10.0%, or 0.01%, or 0.05%, or 0.1%, or 0.15%, or 0.25%, or 0.6%, or 1%, or 2%, or 2.5% to 8%, or 7%, or 6%, or 5%, or 4%, or 3%, or 2%, or the thickening polymer of 1%.Implement in example at least one, described thickening polymer is association's thickening poly thing (associativethickeningpolymer).
Implement in example at least one, described test-run a machine box is further containing mixer and/or a hybrid instrument.Implement in example at least one, described hybrid instrument is a spatula.Implement in example at least one, described mixer is one bowl.
Described oxidation recipes has an oxidant.The oxidation recipes of hair-dyeing agent is mixed in this field and is called as " exploitation agent ", because it can start the chemical reaction that can make hair-dyeing.The amount that oxidant exists enough can be bleached the melanin in hair and/or be caused dye chromophore by the generation in oxidation dye compound.Implement in example at least one, described oxidation recipes contains 0.1% to 20%, or 0.5% to 12%, or 1% to 10%, or 3% to 10%, or the oxidant of 5% to 10%.In at least one utility model, it is 0.1% to 20% that described oxidation recipes contains content altogether, or 1% to 10%, or the oxidant of 2% to 5%.The inorganic peroxide material be dissolved in water that can form hydrogen peroxide can be used.Implement in example at least one, described oxidant is selected from: hydrogen peroxide, inorganic base metal peroxide, (e.g., sodium metaperiodate and sodium peroxide), organic hydroperoxide is (as urea peroxide, melamine peroxides), Inorganic perhydrate bleaching salt compound (e.g., perboric acid, percarbonic acid, peroxophosphoric acid, the alkali metal salt of persilicate persulfuric acid, especially its sodium salt), can with monohydrate, the form of tetrahydrate etc. uses, alkali metal bromate, enzyme, with and composition thereof.Implement in example at least one, described oxidant is a percarbonate (such as, SODIUM PERCARBONATE, percarbonic acid ammonium, potassium percarbonate).Implement in example at least one, described oxidant is SODIUM PERCARBONATE.
Implement in example at least one, described oxidizer formula does not have persulfate substantially.
Implement in example at least one, composition (a) and formula (b) separately independent packaging.
Implement in example at least one, described mixture is packaged in pliable and tough test tube, and described test tube is by metal, and plastics or its mixture form.
Implement in example at least one, described oxidizer formula is packaged in squeezable packing box.Implement in example at least one, described squeezable packing box has the headroom of at least 50%.Implement in example at least one, the volume of the headroom of described squeezable packing box is the volume of composition (a).Implement in example at least one, described oxidation recipes is packaged in one according to the plastic packing box described in European patent application EP 2801281A1 (number of patent application is 13191005.1), described packing box contains two symmetrical not folding compressible rear plates of folding side plate and, wherein, the ratio of the average thickness of described header board and/or rear plate and side plate is to 2:1.EP2801281A1 paragraph [0025] to [0044] and its accompanying drawing are the most with reference to being cited.The advantage of described packing box is that it is for random, and the immense pressure of uncontrolled distortion and environment and internal tank difference has certain toleration, but its production cost can accept and outward appearance can be easily accepted by a user simultaneously.
Further content of the present invention is a kind of method of hair dyeing, and comprise (a) and said mixture and the oxidation recipes containing an oxidant are mixed to form an intermixture, described intermixture is used on hair by (b).Step (a) and step (b) are carried out successively.
Implement in example at least one, described mixture is by mixing said mixture and oxidation recipes with the ratio of weight ratio 1:1.Implement in example at least one, described mixture is an operable dye method formula at any time.
The invention further relates to one operable hair dye formulas at any time, contain:
The monomer of-percentage by weight between 1.0% to 5%, and described monomer has following chemical formula:
H
2C＝C(X)-C(＝O)OR
aOH
Wherein X is hydrogen or CH
3,r
ac
1-C
4alkyl, and monomer has water solublity;
-oxidation dye precursors, this oxidation dye precursors has at least one couplant and at least one elementary mediator;
-one oxidant;
The pH value of wherein said mixture is 8 to 12.
Implement in example at least one, described operable hair dye formulas at any time contains a hydrophobic phase further, an aqueous favoring, one surfactant, and the thickening agent that can react with hydrophobic and aqueous favoring, wherein said mixture contains at least 3000Pa, or at least 3300Pa, or at least 3500Pa, or at least 4000Pa, or at least 4500Pa, or the storage modulus of at least 5000Pa, at being used in 23 DEG C, angular frequency is that the frequency scanning of 0.6rad/s records.Wherein, described thickening agent is association's thickening poly thing (associativethickeningpolymer), and containing hydrophobic group and hydrophilic group.Implement in example one, described storage modulus is not higher than 10kPa, or 9kPa, or 8kPa, or 7kPa, or 6kPa, and at being used in 23 DEG C, angular frequency is that the frequency scanning of 0.6rad/s records.Implement in example one, described hydrophilic group contains polyurethane unit.
Conforming to a fifth aspect of the present invention of every other aspect.
The formula that a sixth aspect of the present invention relates to use fifth aspect present invention makes hair-dyeing, or oxidation hair-dye.
Embodiment
Enforcement example of the present invention sets forth the example in scope.These examples are illustrational effect purely, do not have restriction effect to the present invention.Can slightly make an amendment these examples, but still within protection scope of the present invention.
hair dye mixture embodiment 1 to 7
hair dye mixture embodiment A is to P
All example A to P contain 12% acrylic acid.
crucial:* react on hair after mixing with a heat of oxidation.
oxidation recipes I to V
thickening agent formula 1 to 6
Crucial:
1=be sodium acrylate/substrate thickening agent containing 45% active component, hydrogenated polydecene, sorbitan laurate, and trideceth, can obtain from ArchPersonalCareProducts;
2=be acrylate/ceteth-20 itaconate copolymer containing 30% active component, originate from Dutch Akzo Nobel N.V.;
3=be polyurethane-39 containing 20% active component, Bath good fortune product;
4=be acrylate/behenyl alcohol polyethers-25 methacrylate copolymer containing 20% active component, originate from ROHM AND HAAS;
5=cetearyl alcohol-25 (chemical name), PEG-25 (chemical name), cetyl octadecyl ether.
Claims (14)
1. a dyeing mixture, is characterized in that, containing following composition:
-weight percentage is the monomer of 1 ~ 15%, and described monomer has following chemical formula:
H
2C＝C(X)-C(＝O)OR
aOH
Wherein X is hydrogen or CH
3, R
abe alkyl, and monomer have water solublity;
-antioxidant dye precursor, this antioxidant dye precursor contains at least one couplant and at least one elementary mediator;
Wherein, the pH value of described dyeing mixture is 8 to 12, and oxygen-free agent.
2. dyeing mixture according to claim 1, is characterized in that, described monomer has following chemical formula: H
2c=C (CH
3)-C (=O) OR
aoH; Wherein, R
abe C2 ~ C3 alkyl, and the molecular weight of described monomer is less than 200g/mol.
3. the dyeing mixture according to above-mentioned arbitrary claim, is characterized in that, it is 0.1 ~ 15% that described dyeing mixture contains percentage by weight, or 0.1 ~ 10%, or 1 ~ 5%.
4. the dyeing mixture according to above-mentioned arbitrary claim, is characterized in that, the pH value of described dyeing mixture is 8.0 ~ 9.0, or 9.1 ~ 10.0, or 10.1 ~ 11.0, or 11.1 ~ 12.0.
5. the dyeing mixture according to above-mentioned arbitrary claim, is characterized in that, the pH value ammonia of described dyeing mixture or monoethanolamine regulate.
6. the dyeing mixture according to above-mentioned arbitrary claim, is characterized in that, described dyeing mixture is not containing any initiator causing Raolical polymerizable.
7. the dyeing mixture according to above-mentioned arbitrary claim, is characterized in that, described dyeing mixture is not containing poly-(methyl) acrylic polymer.
8. the dyeing mixture according to above-mentioned arbitrary claim, is characterized in that, described mixture contains a polymerization inhibitor.
9. the dyeing mixture according to above-mentioned arbitrary claim, is characterized in that, described dyeing mixture has a direct dyes.
10. the dyeing mixture according to above-mentioned arbitrary claim, is characterized in that, described dyeing mixture contains one for the carrier of cosmetics.
11. containing the hair heat-tinting agent composition of monomer, and it is characterized in that, the molecular weight of described monomer is less than 200g/mol, and described monomer has following chemical formula:
H
2C＝C(X)-C(＝O)OR
aOH；
Wherein, X is hydrogen or CH
3, R
abe C1 ~ C4 alkyl, and monomer have water solublity.
12. for the test kit of hair-dyeing, and it is characterized in that, this test kit contains: the mixture in claim 1 to 11 described in arbitrary claim; And the oxidation recipes containing an oxidant, wherein, described mixture separates with described oxidation recipes to be packed.
The method of 13. 1 kinds of hair dyeings, is characterized in that, comprise the steps:
A mixture described in claim arbitrary in claim 1 to 11 and the oxidation recipes containing an oxidant are mixed to form an intermixture by ();
B described intermixture is used on hair by ().
14. 1 kinds of operable hair dye formulas at any time, is characterized in that, contain:
The monomer of-percentage by weight between 1.0 ~ 5%, and described monomer has following chemical formula: H
2c=C (X)-C (=O) OR
aoH; Wherein X is hydrogen or CH
3, R
abe C1 ~ C4 alkyl, and monomer have water solublity;
-oxidation dye precursors, this oxidation dye precursors has at least one couplant and at least one elementary mediator;
-one oxidant;
The pH value of described hair dye formulas is 8 to 12.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510230626.6A CN105287246A (en) | 2015-05-07 | 2015-05-07 | Hair dye mixture containing monomer |
| PCT/CN2016/081209 WO2016177344A1 (en) | 2015-05-07 | 2016-05-06 | Monomer-containing hair dye mixture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510230626.6A CN105287246A (en) | 2015-05-07 | 2015-05-07 | Hair dye mixture containing monomer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105287246A true CN105287246A (en) | 2016-02-03 |
Family
ID=55185547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510230626.6A Pending CN105287246A (en) | 2015-05-07 | 2015-05-07 | Hair dye mixture containing monomer |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN105287246A (en) |
| WO (1) | WO2016177344A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111936117A (en) * | 2017-11-17 | 2020-11-13 | 生活实验公司 | Covalent treatment of keratin-containing materials |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102018221959A1 (en) | 2018-12-17 | 2020-06-18 | Henkel Ag & Co. Kgaa | Oxidation colorants in red shades with improved fastness and improved homogeneity |
| DE102018222222A1 (en) | 2018-12-19 | 2020-06-25 | Henkel Ag & Co. Kgaa | Oxidation colorants in red shades with reduced color shift due to copper ions |
| FR3117829B1 (en) * | 2020-12-17 | 2024-04-05 | Oreal | Composition comprising the combination of two specific oxidation coloring precursors and an alkyl(poly)glycoside. |
| FR3117835B1 (en) * | 2020-12-17 | 2024-04-05 | Oreal | Composition comprising the combination of two specific oxidation coloring precursors and an alkyl(poly)glycoside. |
| CN115414341B (en) * | 2022-09-14 | 2023-04-11 | 中国农业大学 | Composition containing alpha-ionone for resisting kidney injury caused by ultraviolet exposure |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3472604A (en) * | 1965-09-27 | 1969-10-14 | Clairol Inc | Retarding damage to hair on the head with polymerizable vinyl monomers in bleaching or dyeing processes |
| CN103391763A (en) * | 2011-01-19 | 2013-11-13 | 宝洁公司 | Method for chemically modifying the internal region of a hair shaft |
| EP2772246A1 (en) * | 2013-03-01 | 2014-09-03 | The Procter and Gamble Company | Acidic composition for modifying the internal region of a hair shaft |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3633591A (en) * | 1969-05-29 | 1972-01-11 | Colgate Palmolive Co | Treatment of keratinous substrates with a reducing agent and thereafter an oxidizing solution of a vinyl monomer |
| US3634022A (en) * | 1969-05-29 | 1972-01-11 | Colgate Palmolive Co | Form-setting keratin substrates by a chemical treatment involving a vinyl monomer |
| EP2561857B1 (en) * | 2011-01-19 | 2017-10-11 | The Procter and Gamble Company | Composition for chemically modifying the internal region of a hair shaft |
-
2015
- 2015-05-07 CN CN201510230626.6A patent/CN105287246A/en active Pending
-
2016
- 2016-05-06 WO PCT/CN2016/081209 patent/WO2016177344A1/en active Application Filing
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3472604A (en) * | 1965-09-27 | 1969-10-14 | Clairol Inc | Retarding damage to hair on the head with polymerizable vinyl monomers in bleaching or dyeing processes |
| CN103391763A (en) * | 2011-01-19 | 2013-11-13 | 宝洁公司 | Method for chemically modifying the internal region of a hair shaft |
| EP2772246A1 (en) * | 2013-03-01 | 2014-09-03 | The Procter and Gamble Company | Acidic composition for modifying the internal region of a hair shaft |
Non-Patent Citations (1)
| Title |
|---|
| 邓创等: "《发型师专业技术160问》", 30 April 2006, 辽宁科学技术出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111936117A (en) * | 2017-11-17 | 2020-11-13 | 生活实验公司 | Covalent treatment of keratin-containing materials |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2016177344A1 (en) | 2016-11-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105287246A (en) | Hair dye mixture containing monomer | |
| CN104023695A (en) | Compositions And Methods For Altering The Appearance Of Hair | |
| JP6436496B2 (en) | Hair treatment method and kit | |
| CN101848695A (en) | Oxidizing hair colourant compositions | |
| MX2014010077A (en) | Hair colouring methods and compositions thereof. | |
| CN101360475A (en) | Hair colouring kits and methods of use thereof | |
| US20170165173A1 (en) | Hair Coloring Composition Comprising One or More Acrylic Compounds | |
| CN104066423A (en) | Compositions and methods for altering the appearance of hair | |
| JP2018138540A (en) | Hair dyeing method and kit thereof | |
| US9901531B2 (en) | Cosmetic composition comprising a thickening polymer having hydrophobic and hydrophilic portions | |
| US11090513B2 (en) | Method for treating hair, kit, and use of the kit | |
| CN105287239A (en) | Hair dye mixture containing (methyl)acrylate compound | |
| CN104168876B (en) | Hair colourant compositions, method and the box set for including the composition comprising the xylenol of 3 amino 2,6 and 1,4 paraphenylene diamine type developers | |
| JP6434902B2 (en) | Hair dye composition comprising 3-amino-2,6-dimethylphenol, method and kit comprising the composition | |
| CN108883314A (en) | The method for handling hair | |
| JP2022516249A (en) | A cosmetic composition comprising at least one hydrophobic film-forming polymer and at least one aminosilicone. | |
| DE102021214419A1 (en) | Process for the production of hair treatment agents by mixing organic C1-C6 alkoxy silanes and alkalizing agents in specific molar ratios | |
| DE102023108291A1 (en) | A method of coloring hair comprising applying a composition A comprising an alkoxysilane and applying a composition B comprising a film-forming polymer | |
| EP3388050A1 (en) | Method for treating hair, kit, and use of the kit |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160203 |
|
| WD01 | Invention patent application deemed withdrawn after publication |