A kind of preparation method of fuel activating agent
Technical field
The present invention relates to the preparation method of energy-saving and emission-reduction fuel activating additive, and in particular to a kind of system of fuel activating agent
Preparation Method.
Background technology
Energy-saving and emission-reduction are the task of top priority of world today's energy scarcity, and the efficiency of combustion of fuel oil directly affects energy-conservation and subtract
The effect of row, fuel activating agent can improve oil, promote fuel oil fully to burn, and improve efficiency of combustion, save fuel oil;It can carry
Its high atomization quality, makes fuel oil fully burn reduction noxious gas emission, reaches the purpose of energy-saving and emission-reduction.
In field of internal combustion engine, in order to improve fuel economy, increase power output, reduction oil consumption, decarbonizing reduction
Noxious gas emission, mainly there is two technological approaches at present:One is addition or reforming equipment(Such as various fuel-economizings, reinforcement, purification
Device), two be to put into additive to fuel oil.First approach investment is big, program is cumbersome, also increase car and boat deadweight and maintenance difficulty,
So second approach more people is received.But one that the fuel oil additive delivered at present has the following disadvantages mostly
Or it is several:First, save fuel oil, lifted power effect it is undesirable, what is had also reduces power performance, and this is that current fuel oil adds
Plus agent can not be the generally accepted main cause of users;2nd, engine noise can not be substantially reduced, what is had also add hair
Motivation noise;3rd, easily cause " secondary pollution " ----additive worked by chemical reaction, playing the same of efficiency
When, may generate some aroused attention or not yet arouse attention, the public hazards thing that is more difficult to natural degradation so that as business
Family and the hidden danger of the public, such as famous additive MTBE (methyl tertiary butyl ether(MTBE)) are found its meeting after being passed unimpeded in the U.S. 20 years
Increase oxynitride discharge, especially seriously can permanent polluted source(Or even deep phreatic water), thus made by limitation
With;4th, efficiency is unstable:Because the component of fuel oil is extremely complex, the same label fuel oil of different manufacturers production is in production process
In technique and adding ingredient be different, or even the same label product of same producer, due to the raw material sources of different batches
Difference will also result in the difference of product composition, formally uncertain make it that to rely primarily on that chemical agent works adds due to this
Plus agent can not often stablize performance efficiency, and easily produce the adverse consequences such as " secondary pollution " and parts corrosion.
Current existing fuel oil anti-knock agent unit cost is too high and addition is excessive when using(Often between 5 ~ 15%), cause
The price ratio of anti-knock agent in high standard fuel price is set to remain high.In the case where current fuel price increasingly rises violently, reduction
One of effective way of fuel price is the cost for substantially reducing the additive for lifting gasoline label and diesel cetane-number.
The content of the invention
The purpose of the present invention is exactly that there is provided a kind of system of fuel activating agent in order to overcome the defect of above-mentioned prior art presence
Preparation Method, fuel activating agent of the invention can improve oil, promote fuel oil fully to burn, and improve efficiency of combustion, save fuel oil;
Its atomization quality can be improved, fuel oil is fully burnt reduction noxious gas emission, reaches the purpose of energy-saving and emission-reduction.
In order to realize foregoing invention purpose, technical scheme is as follows:
The preparation method of the tourmaline fuel activating agent of the present invention, is by rare earth waste dopen Nano TiO2, then with electrically
Stone nano powder, spinel ferrite bluk recombination, are made solid mixture, then add water, dispersant, surfactant, form solid
Liquid mixing slurry;Described rare earth waste, nano-TiO2, tourmaline mineral powder, ferrospinel mass ratio be 2 ~ 5:1~
3:60~80:5~9;The input amount of water is the 10 ~ 90% of mixing slurry;The input amount of dispersant is the 2 ~ 10% of mixing slurry;Surface-active
The input amount of agent is the 5 ~ 28% of mixing slurry.
Described rare earth waste is the waste residue containing lanthanum, cerium or thorium.
The ferrospinel is one kind in Fe-Mn-Cu and Fe-Mn-Cu-Co ferrospinels.
The water is pure water, mineral water or other clean waters.
Described dispersant is low alkali value synthesized calcium alkyl benzene sulfonate, high base number linear alkyl benzene calcium alkylbenzenesulfonate, long-chain
Linear alkyl benzene high base number calcium alkylbenzenesulfonate, high base number synthesis dialkyl benzene sulfonic acids calcium, the synthesis of long-chain linear alkyl benzene high base number
Sulfonic acid magnesium, SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, polyisobutylene succinamide, boronation polyisobutylene succinamide, high score
It is more than the one or two kinds of in son amount polyisobutylene succinamide, boronation high molecular weight polyisobutylene base succimide
Mixing.
The surfactant is emulsifying agent or micro-emulsifier, specially neopelex, cocinic acid alkanol
One kind in acid amides, monoglyceride, Span 80.
The preparation method of described fuel activating agent, comprises the following steps:
(1)By TiO2, tourmaline mineral powder, ferrospinel be polished into nanometer grade powder respectively, in proportion by electricity
Gas stone mineral dust and ferrospinel are mixed, and are sintered in reducing atmosphere, obtain solid mixture A;
(2)Rare earth mixing with nano TiO is prepared using sol-gel process2Colloidal sol, in rare earth mixing with nano TiO2Pressed in colloidal sol
Ratio adds solid mixture A, stirs, and standing obtains gel, and drying, calcining obtain mixture B;
(3)Water, dispersant, surfactant are mixed in proportion, stirred, mixed liquor C is obtained;
(4)By step(2)In mixture B input step(3)In mixed liquor C in, stirring be allowed to be completely dispersed, i.e.,
.
The sintering temperature is 500 ~ 600 DEG C, and sintering time is 1 ~ 3 hour.
The fuel activating agent of the present invention has strong characteristic nmr, and nuclear magnetic resonance makes in fuel containing H atom
Molecule is provided with both positive and negative polarity feature, and molecules align becomes uniform from confusing, and the electric conductivity of fuel is greatly reinforced, because
And be uniformly under fire, the ability of synchronousing combustion is strengthened.Two factors all promote fuel synchronously outburst, simultaneously progress, and so expect
The inevitable outcome of synchronous outburst is that pinking is eliminated, and pinking is eliminated, and the in-fighting problem of engine is also just solved.Equal to increase
30% useful work, that is, reduce by 30% fuel consumption.It can be seen that, tourmaline composition has greatly reinforced the energy-conservation effect of additive
Really, the consumption of fuel declines, and the discharge capacity of pernicious gas is also accordingly reduced.
Titanium dioxide is a kind of strong oxidability, chemical property stabilization and nontoxic photochemical catalyst, is entrained in rare earth
It is combined in element with tourmaline, spinelle, with the stronger ability for producing free radical and anion, TiO2Doping can be with bright
The aobvious infrared emittance for improving spinelle, meanwhile, through TiO2Spinel after doping can obviously reduce the surface of diesel oil
Power and viscosity.
The addition of water is to be used for fried scattered fuel molecule group as " microexplosion explosive ", and water can also be straight in the presence of tourmaline
Connect and be cracked into hydrogen-oxygen, oxygen supply is hydrogenated with to fuel.With carbon water gas reaction, decarbonizing can also occur for the effect of water.In this hair
In bright, water is also as preferred catalyst, and nuclear magnetic resonance delivery agent, and the H atom in water occurs by, after far infrared radiation
Strong nuclear magnetic resonance, so that as the outstanding vibration source for triggering fuel nuclear magnetic resonance, therefore, expanding the ratio of water in the product can
To strengthen its effect and reduce product cost.And the presence of surfactant, water can be promoted to be mixed with the uniform of fuel, help it to send out
Wave optimal catalytic action.
Dispersant can adsorb the solid particulate matter in fuel oil, be scattered in oil, so that solid, liquid and fuel oil
Between have bigger contact area so that be uniformly heated.
Beneficial effects of the present invention are as follows:
1st, with tourmaline nano powder etc. for main functional component, a kind of significant energy-saving fuel activator of effect is have developed,
Fuel oil efficiency of combustion can be effectively improved, noxious gas emission, energy-conserving and environment-protective is reduced.
2nd, by ferrospinel and tourmaline Material cladding, it compensate for that electric stone material heat endurance is poor, at high warm
Low band after reason(3~5 μm)The shortcoming of infrared emittance reduction.
3rd, it is theoretical based on nuclear magnetic resonance, activator is transmitted as nuclear magnetic resonance with water, makes uniform atomizing before fuel oil resonance, into
Complicated each component is divided to resonate, fuel oil is disorderly arranged to become orderly, the surface area of increase fuel droplet and air contact is carried
High burning efficiency;Water gas reaction can also occur with carbon for the water high-temperature vapor that microexplosion is produced at high temperature, and generation one is aoxidized
Carbon and hydrogen, decarbonizing further are while provide fuel and heat.
4th, the tourmaline fuel activating agent for preparing the present invention is applied in fuel activating device, with important use value
And economic benefit.
Embodiment
With reference to specific embodiment, the present invention is described in detail.
Embodiment 1
1st, the preparation method of fuel activating agent of the invention, comprises the following steps:
(1)By 1kg TiO2, 60kg tourmaline minerals powder, 5kg Fe-Mn-Cu ferrospinels be polished into receive respectively
Nanoscale powder, tourmaline mineral powder and ferrospinel are mixed, and are sintered at 500 DEG C in reducing atmosphere
1 hour, obtain solid mixture A;
(2)Rare earth mixing with nano TiO is prepared using sol-gel process2Colloidal sol, rare earth waste is waste residue containing lanthanum, and quality is
2kg, in rare earth mixing with nano TiO2Solid mixture A is added in colloidal sol, is stirred, stands and obtains gel, drying,
Calcining obtains mixture B;
(3)By 7kg water, 0.4kg low alkali values synthesized calcium alkyl benzene sulfonate, 1kg high base numbers linear alkyl benzene synthesis sulfonic acid
The neopelex mixing of calcium, 4kg, stirs, obtains mixed liquor C;
(4)By step(2)In mixture B input step(3)In mixed liquor C in, stirring be allowed to be completely dispersed, i.e.,
.
2nd, by fuel weight than 0.02% by tourmaline fuel activating agent obtained above be directly appended to vehicle fuel live
Change and used in device.
3rd, experiment shows:Often 100 kilometers of row can save gasoline 18.0% to car, reduce CO emission 2.5%, reduction
Hydrocarbon emission amount 7.8%.
Embodiment 2
1st, the preparation method of fuel activating agent of the invention, comprises the following steps:
(1)By 2kg TiO2, 70kg tourmaline minerals powder, 7kg Fe-Mn-Cu-Co ferrospinels polish respectively
Into nanometer grade powder, tourmaline mineral powder and ferrospinel are mixed, carried out at 520 DEG C in reducing atmosphere
Sintering 1.5 hours, obtains solid mixture A;
(2)Rare earth mixing with nano TiO is prepared using sol-gel process2Colloidal sol, rare earth waste is waste residue containing cerium, and quality is
3kg, in rare earth mixing with nano TiO2Solid mixture A is added in colloidal sol, is stirred, stands and obtains gel, drying,
Calcining obtains mixture B;
(3)By 40kg water, 1kg high base numbers synthesis dialkyl benzene sulfonic acids calcium, the synthesis of 1kg long-chain linear alkyl benzenes high base number
Sulfonic acid magnesium, 1kg SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBERs, 4kg cocinic acid alkanolamide, 4kg Spans 80 are mixed, and are stirred, are obtained
Mixed liquor C;
(4)By step(2)In mixture B input step(3)In mixed liquor C in, stirring be allowed to be completely dispersed, i.e.,
.
2nd, by fuel weight than 0.02% by tourmaline fuel activating agent obtained above be directly appended to vehicle fuel live
Change and used in device.
3rd, experiment shows:Often 100 kilometers of row can save gasoline 21.5% to car, reduce CO emission 2.7%, reduction
Hydrocarbon emission amount 9.1%.
Embodiment 3
1st, the preparation method of fuel activating agent of the invention, comprises the following steps:
(1)By 3kg TiO2, 80kg tourmaline minerals powder, 9kg Fe-Mn-Cu ferrospinels be polished into receive respectively
Nanoscale powder, tourmaline mineral powder and ferrospinel are mixed, and are sintered at 560 DEG C in reducing atmosphere
2 hours, obtain solid mixture A;
(2)Rare earth mixing with nano TiO is prepared using sol-gel process2Colloidal sol, rare earth waste is thoriated waste residue, and quality is
5kg, in rare earth mixing with nano TiO2Solid mixture A is added in colloidal sol, is stirred, stands and obtains gel, drying,
Calcining obtains mixture B;
(3)80kg water, 5kg polyisobutylene succinamide, 5kg boronation polyisobutenyl succinyl is sub-
Amine, 5kg high molecular weight polyisobutylene base succimide, 5kg boronation high molecular weight polyisobutylene base succimide,
25kg monoglyceride mixing, stirs, obtains mixed liquor C;
(4)By step(2)In mixture B input step(3)In mixed liquor C in, stirring be allowed to be completely dispersed, i.e.,
.
2nd, by fuel weight than 0.02% by tourmaline fuel activating agent obtained above be directly appended to vehicle fuel live
Change and used in device.
3rd, experiment shows:Often 100 kilometers of row can save gasoline 24.0% to car, reduce CO emission 3.2%, reduction
Hydrocarbon emission amount 9.6%.
Embodiment 4
1st, the preparation method of fuel activating agent of the invention, comprises the following steps:
(1)By 3kg TiO2, 70kg tourmaline minerals powder, 8kg Fe-Mn-Cu ferrospinels be polished into receive respectively
Nanoscale powder, tourmaline mineral powder and ferrospinel are mixed, and are sintered at 580 DEG C in reducing atmosphere
2.5 hours, obtain solid mixture A;
(2)Rare earth mixing with nano TiO is prepared using sol-gel process2Colloidal sol, rare earth waste is waste residue containing lanthanum, and quality is
3.5kg, in rare earth mixing with nano TiO2Solid mixture A is added in colloidal sol, is stirred, standing obtains gel, then through overdrying
Dry, calcining obtains mixture B;
(3)76kg water, 3kg high molecular weight polyisobutylene base succimide, 4kg boronation high-molecular-weight poly is different
Cyclobutenyl succimide, 6kg neopelex, 6kg cocinic acid alkanolamide, 5kg Span 80 are mixed,
Stir, obtain mixed liquor C;
(4)By step(2)In mixture B input step(3)In mixed liquor C in, stirring be allowed to be completely dispersed, i.e.,
.
2nd, by fuel weight than 0.02% by tourmaline fuel activating agent obtained above be directly appended to vehicle fuel live
Change and used in device.
3rd, experiment shows:Often 100 kilometers of row can save gasoline 22.9% to car, reduce CO emission 3.3%, reduction
Hydrocarbon emission amount 9.3%.
Embodiment 5
1st, the preparation method of fuel activating agent of the invention, comprises the following steps:
(1)By 2kg TiO2, 65kg tourmaline minerals powder, 6kg Fe-Mn-Cu ferrospinels be polished into receive respectively
Nanoscale powder, tourmaline mineral powder and ferrospinel are mixed, and are sintered at 600 DEG C in reducing atmosphere
3 hours, obtain solid mixture A;
(2)Rare earth mixing with nano TiO is prepared using sol-gel process2Colloidal sol, rare earth waste is thoriated waste residue, and quality is
4kg, in rare earth mixing with nano TiO2Solid mixture A is added in colloidal sol, is stirred, stands and obtains gel, drying,
Calcining obtains mixture B;
(3)23kg water, 2kg high base number linear alkyl benzene calcium alkylbenzenesulfonate, 2kg long-chain linear alkyl benzene is high-alkali
It is worth calcium alkylbenzenesulfonate boronation polyisobutylene succinamide, 2kg high molecular weight polyisobutylene base succimide, 20kg
Monoglyceride is mixed, and is stirred, is obtained mixed liquor C;
(4)By step(2)In mixture B input step(3)In mixed liquor C in, stirring be allowed to be completely dispersed, i.e.,
.
2nd, by fuel weight than 0.02% by tourmaline fuel activating agent obtained above be directly appended to vehicle fuel live
Change and used in device.
3rd, experiment shows:Often 100 kilometers of row can save gasoline 21.7% to car, reduce CO emission 2.2%, reduction
Hydrocarbon emission amount 9.1%.