CN105255076A - Weather-proof and water-proof cable sheathing material - Google Patents
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Abstract
The invention discloses a weather-proof and water-proof cable sheathing material. The weather-proof and water-proof cable sheathing material comprises raw materials as follows: polyvinylidene fluoride, polymethyl methacrylate, polyvinyl chloride, acrylonitrile-styrene-butyl acrylate copolymer, nitrile rubber, nano titanium dioxide, nano silica, carbon nano tubes, mica powder, zinc stearate, calcium stearate, zinc oxide, stearic acid, dibutyl phthalate, acetyl trihexyl citrate, triethyl citrate, coumarone resin, an anti-ageing agent, polyvinyl butyral and a silane coupling agent. The weather-proof and water-proof cable sheathing material has high strength, good water resistance and weather resistance and excellent processing performance.
Description
Technical field
The present invention relates to cable material technical field, particularly relate to a kind of weather-proof water tolerance cable sheath material.
Background technology
In recent years, along with the development of national communication engineering, oceanographic engineering etc., electrical control equipment gets more and more, and its cabling requirements amount is inevitable to be increased thereupon, simultaneously also thereupon more and more stricter to the performance requriements of cable material.Particularly in some harsh environment, not only require that cable used has good thermotolerance, moisture resistance, sunlight resistance, also require that it has excellent intensity, thermotolerance and weathering resistance, but current its weathering resistance of existing CABLE MATERIALS and water tolerance not very desirable, need to carry out modification.
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes a kind of weather-proof water tolerance cable sheath material, its intensity is high, water tolerance and good weatherability, and processing characteristics is excellent.
The weather-proof water tolerance cable sheath material of one that the present invention proposes, its raw material comprises following component by weight: polyvinylidene difluoride (PVDF) 100 parts, polymethylmethacrylate 20-40 part, polyvinyl chloride 20-40 part, acrylonitrile-styrene-butyl acrylate copolymer 10-30 part, paracril 2-10 part, nano titanium oxide 10-25 part, nano silicon 3-15 part, carbon nanotube 5-15 part, mica powder 2-10 part, Zinic stearas 2-6 part, calcium stearate 3-10 part, zinc oxide 2-5 part, stearic acid 1-2.5 part, dibutyl phthalate 5-15 part, ATHC 2-10 part, triethyl citrate 2-10 part, coumarone indene resin 2-5 part, anti-aging agent 1-2 part, polyvinyl butyral acetal 1-3 part, silane coupling agent 0.5-3 part.
In a particular embodiment, the weather-proof water tolerance cable sheath material of one that the present invention proposes, in its raw material, the weight part of polyvinylidene difluoride (PVDF) is 100 parts; The weight part of polymethylmethacrylate can be 20,21,23,25,26,28,29,30,32,33,34,35,36.8,39,39.3,40 parts; The weight part of polyvinyl chloride can be 20,23,25,28,29,30,32,34,35,37,38,39,39.4,40 parts; The weight part of acrylonitrile-styrene-butyl acrylate copolymer can be 10,12,15,18,19,20,21,23,24,25,28,29,29.3,30 parts; The weight part of paracril can be 2,3,4,5,6,6.3,6.5,7,8,8.5,9,9.3,10 parts; The weight part of nano titanium oxide can be 10,12,13,15,18,19,20,21,23,24,24.6,25 parts; The weight part of nano silicon can be 3,4,5,6,6.3,7,7.3,8,8.6,9,9.3,10,12,13,13.5,14,14.6,15 parts; The weight part of carbon nanotube can be 5,6,6.8,7,8,8.6,9,9.3,10,12,13,13.5,14,14.6,15 parts; The weight part of mica powder can be 2,3,4,5,5.2,6,6.3,7,8,8.6,9,9.3,10 parts; The weight part of Zinic stearas can be 2,3,4,4.5,4.6,5,5.2,5.6,6 parts; The weight part of calcium stearate can be 3,4,5,6,6.3,7,7.2,7.8,8,8.5,9,9.3,9.8,10 parts; The weight part of zinc oxide can be 2,2.3,2.8,3,3.2,3.8,4,4.5,4.8,5 parts; Stearic weight part can be 1,1.2,1.5,1.6,1.7,2,2.1,2.3,2.45,2.5 part; The weight part of dibutyl phthalate can be 5,6,7,8,9,9.3,10,11,12,13,13.5,14,14.6,15 parts; The weight part of ATHC can be 2,3.2,4,4.6,5,5.3,5.8,6,6.3,6.8,7,7.5,9,9.3,10 parts; The weight part of triethyl citrate can be 2,3,4,5,5.8,5.9,6,6.3,7,8,8.6,9,9.3,10 parts; The weight part of coumarone indene resin can be 2,2.6,3,3.5,4,4.2,4.8,5 parts; The weight part of anti-aging agent can be 1,1.2,1.3,1.5,1.6,1.8,1.9,2 part; The weight part of polyvinyl butyral acetal can be 1,1.3,1.8,2,2.6,2.8,3 part; The weight part of silane coupling agent can be 0.5,0.8,0.9,1,1.2,1.8,1.9,2,2.3,2.5,2.8,3 part.
Preferably, in its raw material, the weight ratio of polyvinylidene difluoride (PVDF), polymethylmethacrylate, polyvinyl chloride, acrylonitrile-styrene-butyl acrylate copolymer, paracril is 100:25-35:30-38:15-25:4-9.
Preferably, its raw material comprises following component by weight: polyvinylidene difluoride (PVDF) 100 parts, polymethylmethacrylate 30-33 part, polyvinyl chloride 32-37 part, acrylonitrile-styrene-butyl acrylate copolymer 18-21 part, paracril 6-7 part, nano titanium oxide 18-21 part, nano silicon 5-8 part, carbon nanotube 6-8 part, mica powder 4-6 part, Zinic stearas 4.5-5.2 part, calcium stearate 7-7.8 part, zinc oxide 3.2-4 part, stearic acid 1.6-2 part, dibutyl phthalate 10-12 part, ATHC 5.8-6.3 part, triethyl citrate 5.8-7 part, coumarone indene resin 3.5-4.2 part, anti-aging agent 1.3-1.8 part, polyvinyl butyral acetal 2.6-3 part, silane coupling agent 1.9-2.5 part.
Preferably, its raw material comprises following component by weight: polyvinylidene difluoride (PVDF) 100 parts, polymethylmethacrylate 32 parts, polyvinyl chloride 35 parts, acrylonitrile-styrene-butyl acrylate copolymer 20 parts, paracril 6.3 parts, nano titanium oxide 20 parts, nano silicon 7.3 parts, carbon nanotube 6.8 parts, mica powder 5.2 parts, Zinic stearas 4.6 parts, calcium stearate 7.2 parts, 3.8 parts, zinc oxide, stearic acid 1.7 parts, dibutyl phthalate 11 parts, ATHC 6 parts, triethyl citrate 5.9 parts, coumarone indene resin 4 parts, 1.6 parts, anti-aging agent, polyvinyl butyral acetal 2.8 parts, silane coupling agent 2 parts.
Preferably, described polyvinyl chloride is modified polyvinyl chloride, described modified polyvinyl chloride is prepared according to following technique: by weight 20-40 part polyvinyl chloride is mixed rear swelling 5-10h with 5-15 part diethylenetriamine, then 10-30 part water is added, at 85-100 DEG C, react 5-8h, reaction terminates rear filtration, washing, drying, then immerses in the saturated solution of Perfluorocaprylic Acid, at room temperature soak 5-10h, reaction terminates to obtain modified polyvinyl chloride through washing, drying.
Preferably, described polyvinyl chloride is modified polyvinyl chloride, described modified polyvinyl chloride is prepared according to following technique: by weight 35 parts of polyvinyl chloride are mixed rear swelling 8h with 12 parts of diethylenetriamines, then 25 parts of water are added, at 90 DEG C, react 6h, reaction terminates rear filtration, washing, drying, then immerses in the saturated solution of Perfluorocaprylic Acid, at room temperature soak 8h, reaction terminates to obtain modified polyvinyl chloride through washing, drying.
Preferably, the median size of described nano titanium oxide is 20-50nm; The median size of described nano silicon is 40-70nm.
Preferably, described anti-aging agent is one or more the mixture in antioxidant MB, antioxidant A W, antioxidant A, antioxidant 4020, antioxidant H.
Preferably, described silane coupling agent is one or more the mixture in silane coupling A-151, silane coupling agent KH-551, silane coupling agent KH-602, silane coupling agent KH-792.
The weather-proof water tolerance cable sheath material that the present invention proposes can polyvinylidene fluoride composite material preparation technology conveniently be prepared from.
In the present invention, have selected polyvinylidene difluoride (PVDF) is major ingredient, give the weathering resistance of sheath material excellence, resistance to crocking and chemical stability, but its processibility is not very desirable, coordinates and add polymethylmethacrylate and polyvinyl chloride, and have adjusted the ratio of each material, the performance of each material is worked in coordination with, greatly improve the microtexture of polyvinylidene difluoride (PVDF), improve the processing characteristics of sheath material, further increase weathering resistance and the erosion resistance of sheath material simultaneously; Paracril adds in system, good with the consistency of each material, improves the thermotolerance of sheath material, wear resistance, oil-proofness and weathering resistance; Acrylonitrile-styrene-butyl acrylate copolymer adds in system, can improve the ultraviolet-resistant aging performance of sheath material, prevents because polyvinyl chloride adds the shortcoming that the UV resistant that causes reduces; Nano titanium oxide, nano silicon, carbon nanotube, mica powder add in system, under the effect of silane coupling agent, be uniformly dispersed in system, improve the cross-linking set in system, improve weathering resistance and the water tolerance of sheath material, coordinate with dibutyl phthalate, ATHC, triethyl citrate, coumarone indene resin, polyvinyl butyral acetal and stearic acid simultaneously, there is the effect that lubrication is toughness reinforcing, improve the shock resistance of sheath material, avoid the defect adding the shock resistance difference caused because of polyvinyl chloride; In optimal way, described polyvinyl chloride is modified polyvinyl chloride, in the preparation process of modified polyvinyl chloride, first have selected polyvinyl chloride and diethylenetriamine reacts, chlorine atom in polyvinyl chloride and the amino in diethylenetriamine are reacted, immerse after in the saturated solution of Perfluorocaprylic Acid, the remaining amino of diethylenetriamine can react with the carboxyl in Perfluorocaprylic Acid, thus Perfluorocaprylic Acid is introduced in polyvinyl chloride, add in system, improve the water tolerance of sheath material, erosion resistance and weathering resistance.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
The weather-proof water tolerance cable sheath material of one that the present invention proposes, its raw material comprises following component by weight: polyvinylidene difluoride (PVDF) 100 parts, polymethylmethacrylate 32 parts, polyvinyl chloride 35 parts, acrylonitrile-styrene-butyl acrylate copolymer 20 parts, paracril 6.3 parts, nano titanium oxide 20 parts, nano silicon 7.3 parts, carbon nanotube 6.8 parts, mica powder 5.2 parts, Zinic stearas 4.6 parts, calcium stearate 7.2 parts, 3.8 parts, zinc oxide, stearic acid 1.7 parts, dibutyl phthalate 11 parts, ATHC 6 parts, triethyl citrate 5.9 parts, coumarone indene resin 4 parts, antioxidant A 1 part, antioxidant 4020 0.6 part, polyvinyl butyral acetal 2.8 parts, silane coupling A-1512 parts,
Wherein, described polyvinyl chloride is modified polyvinyl chloride, described modified polyvinyl chloride is prepared according to following technique: by weight 35 parts of polyvinyl chloride are mixed rear swelling 8h with 12 parts of diethylenetriamines, then 25 parts of water are added, at 90 DEG C, react 6h, reaction terminates rear filtration, washing, drying, then immerses in the saturated solution of Perfluorocaprylic Acid, at room temperature soak 8h, reaction terminates to obtain modified polyvinyl chloride through washing, drying.
Embodiment 2
The weather-proof water tolerance cable sheath material of one that the present invention proposes, its raw material comprises following component by weight: polyvinylidene difluoride (PVDF) 100 parts, polymethylmethacrylate 20 parts, polyvinyl chloride 40 parts, acrylonitrile-styrene-butyl acrylate copolymer 10 parts, paracril 10 parts, nano titanium oxide 10 parts, nano silicon 15 parts, carbon nanotube 5 parts, mica powder 10 parts, Zinic stearas 2 parts, calcium stearate 10 parts, 2 parts, zinc oxide, stearic acid 2.5 parts, dibutyl phthalate 5 parts, ATHC 10 parts, triethyl citrate 2 parts, coumarone indene resin 5 parts, antioxidant MB 0.2 part, antioxidant A W0.3 part, antioxidant A 0.1 part, antioxidant 4020 0.2 part, antioxidant H 0.2 part, polyvinyl butyral acetal 1 part, silane coupling agent KH-5511 part, silane coupling agent KH-6020.5 part, silane coupling agent KH-7921.5 part,
Wherein, described polyvinyl chloride is modified polyvinyl chloride, described modified polyvinyl chloride is prepared according to following technique: by weight 20 parts of polyvinyl chloride are mixed rear swelling 5h with 15 parts of diethylenetriamines, then 30 parts of water are added, at 85 DEG C, react 8h, reaction terminates rear filtration, washing, drying, then immerses in the saturated solution of Perfluorocaprylic Acid, at room temperature soak 5h, reaction terminates to obtain modified polyvinyl chloride through washing, drying.
Embodiment 3
The weather-proof water tolerance cable sheath material of one that the present invention proposes, its raw material comprises following component by weight: polyvinylidene difluoride (PVDF) 100 parts, polymethylmethacrylate 40 parts, polyvinyl chloride 20 parts, acrylonitrile-styrene-butyl acrylate copolymer 30 parts, paracril 2 parts, nano titanium oxide 25 parts, nano silicon 3 parts, carbon nanotube 15 parts, mica powder 2 parts, Zinic stearas 6 parts, calcium stearate 3 parts, 5 parts, zinc oxide, stearic acid 1 part, dibutyl phthalate 15 parts, ATHC 2 parts, triethyl citrate 10 parts, coumarone indene resin 2 parts, antioxidant 4020 1 part, antioxidant H 1 part, polyvinyl butyral acetal 3 parts, silane coupling agent KH-6020.4 part, silane coupling agent KH-7920.1 part,
Wherein, the median size of described nano titanium oxide is 30nm; The median size of described nano silicon is 55nm; Described polyvinyl chloride is modified polyvinyl chloride, described modified polyvinyl chloride is prepared according to following technique: by weight 40 parts of polyvinyl chloride are mixed rear swelling 10h with 5 parts of diethylenetriamines, then 10 parts of water are added, 5h is reacted at 100 DEG C, reaction terminates rear filtration, washing, drying, then immerse in the saturated solution of Perfluorocaprylic Acid, at room temperature soak 10h, reaction terminates to obtain modified polyvinyl chloride through washing, drying.
Embodiment 4
The weather-proof water tolerance cable sheath material of one that the present invention proposes, its raw material comprises following component by weight: polyvinylidene difluoride (PVDF) 100 parts, polymethylmethacrylate 30 parts, polyvinyl chloride 37 parts, acrylonitrile-styrene-butyl acrylate copolymer 18 parts, paracril 7 parts, nano titanium oxide 18 parts, nano silicon 8 parts, carbon nanotube 6 parts, mica powder 6 parts, Zinic stearas 4.5 parts, calcium stearate 7.8 parts, 3.2 parts, zinc oxide, stearic acid 2 parts, dibutyl phthalate 10 parts, ATHC 6.3 parts, triethyl citrate 5.8 parts, coumarone indene resin 4.2 parts, antioxidant A W1 part, antioxidant A 0.3 part, polyvinyl butyral acetal 3 parts, silane coupling agent KH-7921.9 part,
Wherein, the median size of described nano titanium oxide is 50nm; The median size of described nano silicon is 40nm; Described polyvinyl chloride is modified polyvinyl chloride, described modified polyvinyl chloride is prepared according to following technique: by weight 28 parts of polyvinyl chloride are mixed rear swelling 6h with 12 parts of diethylenetriamines, then 25 parts of water are added, 7h is reacted at 90 DEG C, reaction terminates rear filtration, washing, drying, then immerse in the saturated solution of Perfluorocaprylic Acid, at room temperature soak 6h, reaction terminates to obtain modified polyvinyl chloride through washing, drying.
Embodiment 5
The weather-proof water tolerance cable sheath material of one that the present invention proposes, its raw material comprises following component by weight: polyvinylidene difluoride (PVDF) 100 parts, polymethylmethacrylate 33 parts, polyvinyl chloride 32 parts, acrylonitrile-styrene-butyl acrylate copolymer 21 parts, paracril 6 parts, nano titanium oxide 21 parts, nano silicon 5 parts, carbon nanotube 8 parts, mica powder 4 parts, Zinic stearas 5.2 parts, calcium stearate 7 parts, 4 parts, zinc oxide, stearic acid 1.6 parts, dibutyl phthalate 12 parts, ATHC 5.8 parts, triethyl citrate 7 parts, coumarone indene resin 3.5 parts, antioxidant MB 1.8 parts, polyvinyl butyral acetal 2.6 parts, silane coupling agent KH-5512 part, silane coupling agent KH-6020.5 part,
Wherein, the median size of described nano titanium oxide is 20nm; The median size of described nano silicon is 70nm; Described polyvinyl chloride is modified polyvinyl chloride, described modified polyvinyl chloride is prepared according to following technique: by weight 36 parts of polyvinyl chloride are mixed rear swelling 8h with 8 parts of diethylenetriamines, then 18 parts of water are added, 6h is reacted at 98 DEG C, reaction terminates rear filtration, washing, drying, then immerse in the saturated solution of Perfluorocaprylic Acid, at room temperature soak 9h, reaction terminates to obtain modified polyvinyl chloride through washing, drying.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (9)
1. a weather-proof water tolerance cable sheath material, it is characterized in that, its raw material comprises following component by weight: polyvinylidene difluoride (PVDF) 100 parts, polymethylmethacrylate 20-40 part, polyvinyl chloride 20-40 part, acrylonitrile-styrene-butyl acrylate copolymer 10-30 part, paracril 2-10 part, nano titanium oxide 10-25 part, nano silicon 3-15 part, carbon nanotube 5-15 part, mica powder 2-10 part, Zinic stearas 2-6 part, calcium stearate 3-10 part, zinc oxide 2-5 part, stearic acid 1-2.5 part, dibutyl phthalate 5-15 part, ATHC 2-10 part, triethyl citrate 2-10 part, coumarone indene resin 2-5 part, anti-aging agent 1-2 part, polyvinyl butyral acetal 1-3 part, silane coupling agent 0.5-3 part.
2. weather-proof water tolerance cable sheath material according to claim 1, it is characterized in that, in its raw material, the weight ratio of polyvinylidene difluoride (PVDF), polymethylmethacrylate, polyvinyl chloride, acrylonitrile-styrene-butyl acrylate copolymer, paracril is 100:25-35:30-38:15-25:4-9.
3. weather-proof water tolerance cable sheath material according to claim 1 or 2, it is characterized in that, its raw material comprises following component by weight: polyvinylidene difluoride (PVDF) 100 parts, polymethylmethacrylate 30-33 part, polyvinyl chloride 32-37 part, acrylonitrile-styrene-butyl acrylate copolymer 18-21 part, paracril 6-7 part, nano titanium oxide 18-21 part, nano silicon 5-8 part, carbon nanotube 6-8 part, mica powder 4-6 part, Zinic stearas 4.5-5.2 part, calcium stearate 7-7.8 part, zinc oxide 3.2-4 part, stearic acid 1.6-2 part, dibutyl phthalate 10-12 part, ATHC 5.8-6.3 part, triethyl citrate 5.8-7 part, coumarone indene resin 3.5-4.2 part, anti-aging agent 1.3-1.8 part, polyvinyl butyral acetal 2.6-3 part, silane coupling agent 1.9-2.5 part.
4. weather-proof water tolerance cable sheath material according to any one of claim 1-3, it is characterized in that, its raw material comprises following component by weight: polyvinylidene difluoride (PVDF) 100 parts, polymethylmethacrylate 32 parts, polyvinyl chloride 35 parts, acrylonitrile-styrene-butyl acrylate copolymer 20 parts, paracril 6.3 parts, nano titanium oxide 20 parts, nano silicon 7.3 parts, carbon nanotube 6.8 parts, mica powder 5.2 parts, Zinic stearas 4.6 parts, calcium stearate 7.2 parts, 3.8 parts, zinc oxide, stearic acid 1.7 parts, dibutyl phthalate 11 parts, ATHC 6 parts, triethyl citrate 5.9 parts, coumarone indene resin 4 parts, 1.6 parts, anti-aging agent, polyvinyl butyral acetal 2.8 parts, silane coupling agent 2 parts.
5. weather-proof water tolerance cable sheath material according to any one of claim 1-4, it is characterized in that, described polyvinyl chloride is modified polyvinyl chloride, described modified polyvinyl chloride is prepared according to following technique: by weight 20-40 part polyvinyl chloride is mixed rear swelling 5-10h with 5-15 part diethylenetriamine, then 10-30 part water is added, 5-8h is reacted at 85-100 DEG C, reaction terminates rear filtration, washing, dry, then immerse in the saturated solution of Perfluorocaprylic Acid, at room temperature soak 5-10h, reaction terminates through washing, drying obtains modified polyvinyl chloride.
6. weather-proof water tolerance cable sheath material according to any one of claim 1-5, it is characterized in that, described polyvinyl chloride is modified polyvinyl chloride, described modified polyvinyl chloride is prepared according to following technique: by weight 35 parts of polyvinyl chloride are mixed rear swelling 8h with 12 parts of diethylenetriamines, then 25 parts of water are added, 6h is reacted at 90 DEG C, reaction terminates rear filtration, washing, drying, then immerse in the saturated solution of Perfluorocaprylic Acid, at room temperature soak 8h, reaction terminates to obtain modified polyvinyl chloride through washing, drying.
7. weather-proof water tolerance cable sheath material according to any one of claim 1-6, is characterized in that, the median size of described nano titanium oxide is 20-50nm; The median size of described nano silicon is 40-70nm.
8. weather-proof water tolerance cable sheath material according to any one of claim 1-7, is characterized in that, described anti-aging agent is one or more the mixture in antioxidant MB, antioxidant A W, antioxidant A, antioxidant 4020, antioxidant H.
9. weather-proof water tolerance cable sheath material according to any one of claim 1-8, it is characterized in that, described silane coupling agent is one or more the mixture in silane coupling A-151, silane coupling agent KH-551, silane coupling agent KH-602, silane coupling agent KH-792.
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| CN106243897A (en) * | 2016-08-24 | 2016-12-21 | 安徽美景工艺品有限公司 | A kind of sericin polyurethane composite stalk treatment fluid and preparation method thereof |
| CN106543764A (en) * | 2016-10-19 | 2017-03-29 | 安徽吉思特智能装备有限公司 | A kind of high-tension cable cable material |
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| CN106543593A (en) * | 2016-10-28 | 2017-03-29 | 苏州富通高新材料科技股份有限公司 | A kind of nano-PVC drinking-water pipe material and preparation method thereof |
| CN107325461A (en) * | 2017-07-12 | 2017-11-07 | 合肥东恒锐电子科技有限公司 | A kind of anti-interference water-proof climate resisting data cable material and preparation method thereof |
| CN108250782A (en) * | 2017-12-06 | 2018-07-06 | 淮北市天相电缆有限责任公司 | A kind of anti-water erosion external sheath layer cable material |
| CN108676211A (en) * | 2018-05-04 | 2018-10-19 | 苏州耐思特塑胶有限公司 | A kind of cable sheathing material and preparation method thereof of addition coumarone-indene resin |
| CN110204820A (en) * | 2019-07-12 | 2019-09-06 | 常州轻工职业技术学院 | Kynoar-composite polyethylene material and preparation method thereof, insulator sheath |
| CN113462046A (en) * | 2021-07-29 | 2021-10-01 | 北京市城南橡塑技术研究所 | NBR-ECTFE-ACS oil-resistant cold-resistant rubber and preparation method thereof |
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