CN105251677A - Coating method and application of anion functional coating - Google Patents
Coating method and application of anion functional coating Download PDFInfo
- Publication number
- CN105251677A CN105251677A CN201510708346.1A CN201510708346A CN105251677A CN 105251677 A CN105251677 A CN 105251677A CN 201510708346 A CN201510708346 A CN 201510708346A CN 105251677 A CN105251677 A CN 105251677A
- Authority
- CN
- China
- Prior art keywords
- negative ion
- ion powder
- anion
- surface modification
- paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a coating method and application of an anion functional coating. The coating method is characterized in that firstly, anion UV primer with the modified surface is sprayed to a material, and after photocuring, anion UV finishing coat with the surface modified or not modified is sprayed. By means of the coating method and the application, ceramic tiles, stone, organic panels, cloth and other building materials can have the function of releasing anions, meanwhile, the surface glossiness is not affected, operation is convenient, and environment friendliness is achieved.
Description
Technical field
The present invention relates to technical field of coatings, relate to a kind of coating process of anion function coating and the application on the building material surfaces such as ceramic tile, stone material, organic board, cloth more specifically.
Background technology
Air ambient is deteriorated mainly because positive and negative ion concentration ratio in air is unbalance, containing pernicious gas and smog, dust, virus, bacterium etc. in air.And negative aeroion can regulate positive and negative ion concentration ratio on the one hand, the effect purified air can be played again on the other hand, the drift dirt that anion can make micron order in air invisible, form micel sink to landing by negative ions attraction, collision, and anion can make bacterioprotein two-stage put upside down, and make bacterial viability decline or lethal.The feature of anion fine-purification air is that deactivation speed is fast, and inactivation ratio is high, all has deactivation to the microorganism of air, article surface, bacterium, virus.The peculiar smell that in the irritative gas such as the benzene that the art work used in interior decoration process evaporates, formaldehyde, ketone, ammonia and daily life, the acid smell, cigarette etc. of leftovers leftovers are harmful, negative aeroion can be eliminated effectively.Ceramic tile is important decoration material, if can produce negative aeroion, can improve the living environment of people well.Utilize the negative ion releasing function of Ceramic Tiles to increase indoor air-anion concentration, not consuming any energy, is a kind of health building materials of environmental protection.
Give an example, in prior art, the preparation method of the ceramic tile of energy anion releasing mainly adopts following two kinds of modes: (1) adds anion material in ceramic body.(2) in ceramic glaze, anion material is added.But in actual industrial production, when anion material joins in ceramic body or ceramic glaze formula, anion material addition can be made comparatively large, and production cost is too high; And in process of producing product, easily there is the glaze planar defects such as glaze splits, pin hole, contracting glaze, the problems such as wastage of material, production efficiency are low can be caused.Although in recent years along with the progressively popularization of ceramic ink jet printing technology, those skilled in the art also attempt adding anion material in ceramic ink, but because general negative ion powder all has the characteristic of hydrophilic oleophobic, if directly adopt the ceramic functional ink of general interpolation anion material as tourmaline, medical stone, strange ice stone, opal, Qi Caishi and hornblend to print ceramic tile patterns, not only can affect the surperficial glaze colours of ceramic tile, but also the anion-generating capacity of ceramic tile can be affected, waste resource.
For this reason, be necessary the coating process inquiring into out a kind of anion function coating, can be applied on the building material surfaces such as ceramic tile, stone material, organic board, cloth, while not changing building material product colour properties, its anion-generating capacity can be improved greatly.
Summary of the invention
Object of the present invention is exactly deficiency in order to solve prior art and the coating process of the anion function coating of a kind of simple, convenient, the environmental protection provided.
Another object of the present invention is to provide a kind of application of coating process of anion function coating.
The present invention adopts following technical solution to realize above-mentioned purpose:
A coating process for anion function coating, is characterized in that, it is the anion UV priming paint first spraying surface modification in material, after photocuring, and then spray through or not through the UV finish paint of surface modification anion.
Further illustrating as such scheme, the anion UV priming paint of described surface modification is the negative ion powder adding surface modification in UV priming paint; The UV finish paint of surface modification anion is the negative ion powder adding surface modification in UV finish paint.
Described material is not having on figuratum basis, is after the operation of carrying out photocureable priming coat, is placed on ink jet printer and carries out pattern in ink-jet; Material, on figuratum basis, is the anion UV priming paint directly spraying modification at patterned material surface.
It comprises following concrete steps:
A, primer spray, add the negative ion powder of surface modification to UV priming paint, after stirring, to material surface spray painting UV primer equably;
B, the material having sprayed priming paint is carried out photocuring;
C, in UV finish paint, add the negative ion powder of surface modification, after stirring, in ink-jet after pattern or spraying priming paint and the material surface spray paint equably solidified;
D, the material having sprayed finish paint is carried out photocuring.
In described step a, the addition of negative ion powder is the 1-30% of the weight sum accounting for UV priming paint and negative ion powder.
In described steps d, the addition of negative ion powder is the 1-30% of the weight sum accounting for UV finish paint and negative ion powder.
The negative ion powder of described surface modification first toward water in, adds surfactant, heating after stirring, then add negative ion powder and obtain mixed liquor; Then mixed liquor is carried out thermostatic ultrasonic process or high-speed stirred in supersonic wave cleaning machine, then constant temperature stirring reaction, filter after get solid and dry, pulverize and sieve and obtain.
The preparation process of the negative ion powder of described surface modification comprises following concrete steps:
A, in 100g water, add the surfactant of 0.5-30g, electric power stirs, and mixing speed is 100-5000 rev/min, is heated to reaction temperature 60-100 DEG C, then adds 500-8000 object negative ion powder 10-60g, obtains mixed liquor;
B, mixed liquor is carried out thermostatic ultrasonic process 10-25min or high-speed stirred in supersonic wave cleaning machine, mixing speed is 1000-5000 rev/min;
C, continuation constant temperature electric power stirring reaction 0.5-1h, mixing speed is 100-1500 rev/min;
D, reacted after, mixed liquor is filtered, gets solid, dry to constant weight at 100-150 DEG C, pulverize, cross 80-8000 mesh sieve.
In described ultrasonication, the frequency 20-100KHz that supersonic wave cleaning machine adopts.
Described surfactant adopts the mixed solution mixed by span 20-80 and silicone oil and silicone oil ester, stearic acid and salt thereof, senior amine salt, unsaturated organic acid.
Described surfactant adopts the mixed solution mixed by sorbester p18 and silicone oil and silicone oil ester, stearic acid and salt thereof, senior amine salt, unsaturated organic acid.
The formula of described surfactant comprises span 20-8045-80%, silicone oil and silicone oil ester 1-10%, stearic acid and salt 15-30% thereof, senior amine salt 1-10%, unsaturated organic acid 1-10% by weight percentage.
A kind of application of coating process of anion function coating, it is characterized in that, it is by negative ion powder or covers through the negative ion powder of surface modification and be loaded in building material product surface, if ceramic tile and other inorganic are as stone material, organic board, cloth, allows building material product have the function of anion releasing.
The beneficial effect that the present invention adopts above-mentioned technical solution to reach is:
The present invention adopts such as ceramic tile, stone material, the building material products such as organic board are added with the priming paint of negative ion powder or the negative ion powder through surface modification successively through spray, photocuring, ink-jet is painted, spray is added with the finish paint of negative ion powder or the negative ion powder through surface modification, the operation of photocuring, load is covered on product by negative ion powder or through the negative ion powder of surface modification, by the function allowing product have anion releasing, and do not affect product surface color and luster, especially with the addition of the priming paint of the negative ion powder through surface modification, after testing, when its negative ion powder content is the half of the content of negative ion powder without modification, its anion burst size is also higher, the demand of use can be met completely, greatly reduce production cost, environmental protection and energy saving.
Detailed description of the invention
Below in conjunction with specific embodiment, the technical program is explained in detail.
The present invention is a kind of coating process of anion function coating, and it is the anion UV priming paint first spraying surface modification in material, after photocuring, and then spray through or not through the UV finish paint of surface modification anion.The anion UV priming paint of surface modification is the negative ion powder adding surface modification in UV priming paint; The UV finish paint of surface modification anion is the negative ion powder adding surface modification in UV finish paint.
Not having in figuratum situation in material, is after the operation of carrying out photocureable priming coat, increases and is placed on the operation of ink jet printer carrying out pattern in ink-jet; In material in figuratum situation, be the anion UV priming paint directly spraying modification at patterned material surface.
It comprises following concrete steps:
A, primer spray, add the negative ion powder of surface modification to UV priming paint, after stirring, to material surface spray painting UV primer equably;
B, the material having sprayed priming paint is carried out photocuring;
C, in UV finish paint, add the negative ion powder of surface modification, after stirring, in ink-jet after pattern or spraying priming paint and the material surface spray paint equably solidified;
D, the material having sprayed finish paint is carried out photocuring.
Embodiment 1
In the present embodiment, the coating process of anion function coating is applied in ceramic tile processing, forms anion function ceramic tile.
Before interpolation anion material, the preparation process of ceramic tile comprises preparation ceramic raw material, mix and blend, cloth, compressing, body drying successively, executes cover-coat enamel, what adopt due to described processing step is method comparatively conventional in current ceramic tile production industry, therefore, the present invention is not described further at this.
The preparation process of anion function ceramic tile, it comprises following concrete steps:
A, primer spray, add the negative ion powder of surface modification to UV priming paint, after stirring, to ceramic tile surface spray painting UV primer equably;
B, the ceramic tile having sprayed priming paint is carried out photocuring;
C, in UV finish paint, add the negative ion powder of surface modification, after stirring, in ink-jet after pattern or spraying priming paint and the ceramic tile surface spray paint equably solidified;
D, the ceramic tile having sprayed finish paint is carried out photocuring.
In described step a, the addition of negative ion powder is 2.5% of the weight sum accounting for UV priming paint and negative ion powder; In described steps d, the addition of negative ion powder is 2.5% of the weight sum accounting for UV finish paint and negative ion powder.
The negative ion powder of surface modification first toward water in, adds surfactant, heating after stirring, then add negative ion powder and obtain mixed liquor; Then mixed liquor is carried out thermostatic ultrasonic process or high-speed stirred in supersonic wave cleaning machine, then constant temperature stirring reaction, filter after get solid and dry, pulverize and sieve and obtain.
Further, the preparation process of the negative ion powder of described surface modification comprises following concrete steps:
A, in 100g water, add the surfactant of 2g, electric power stirs, and mixing speed is 500 revs/min, is heated to reaction temperature 65 DEG C, then adds 1000 object negative ion powder 15g, obtains mixed liquor;
B, by mixed liquor in frequency be 30KHz supersonic wave cleaning machine in carry out thermostatic ultrasonic process 13min or high-speed stirred, mixing speed is 1490rpm;
C, continuation constant temperature electric power stirring reaction 0.5h, mixing speed is 1200 revs/min;
D, reacted after, mixed liquor is filtered, gets solid, 120 DEG C dry to constant weight, pulverize, cross 150 mesh sieves.
Further, described surfactant adopts the mixed solution mixed by span 20 and silicone oil and silicone oil ester, stearic acid and salt thereof, senior amine salt, unsaturated organic acid.
More specifically, the formula of surfactant comprises span 20 70%, silicone oil and silicone oil ester 8%, stearic acid and salt thereof 16%, senior amine salt 4%, unsaturated organic acid 2% by weight percentage.
Embodiment 2
In the present embodiment, the coating process of anion function coating is applied in processing of stone, forms anion function stone material.
The preparation process of anion function stone material, it comprises following concrete steps:
A, primer spray, add the negative ion powder of surface modification to UV priming paint, after stirring, to stone surface spray painting UV primer equably;
B, the stone material having sprayed priming paint is carried out photocuring;
C, in UV finish paint, add the negative ion powder of surface modification, after stirring, in ink-jet after pattern or spraying priming paint and the stone surface spray paint equably solidified;
D, the stone material having sprayed finish paint is carried out photocuring.
In the step a of the preparation process of anion function stone material, the addition of negative ion powder is 5% of the weight sum accounting for UV priming paint and negative ion powder; In described steps d, the addition of negative ion powder is 5% of the weight sum accounting for UV finish paint and negative ion powder.
The preparation process of the negative ion powder of surface modification comprises following concrete steps:
A, in 100g water, add the surfactant of 3g, electric power stirs, and mixing speed is 800 revs/min, is heated to reaction temperature 70 DEG C, then adds 1200 object negative ion powder 30g, obtains mixed liquor;
B, by mixed liquor in frequency be 35KHz supersonic wave cleaning machine in carry out thermostatic ultrasonic process 13min or high-speed stirred, mixing speed is 1500rpm;
C, continuation constant temperature electric power stirring reaction 0.8h, mixing speed is 1000 revs/min;
D, reacted after, mixed liquor is filtered, gets solid, 130 DEG C dry to constant weight, pulverize, cross 500 mesh sieves.
Further, wherein, the formula of surfactant comprises sorbester p18 65%, silicone oil and silicone oil ester 5%, stearic acid and salt thereof 20%, senior amine salt 5%, unsaturated organic acid 5% by weight percentage.
Embodiment 3
In the present embodiment, the coating process of anion function coating is applied in organic board processing, forms anion function organic board.
The preparation process of anion function organic board, it comprises following concrete steps:
A, primer spray, add the negative ion powder of surface modification to UV priming paint, after stirring, to organic board uniformly spray painting UV primer;
B, the organic board having sprayed priming paint is carried out photocuring;
C, in UV finish paint, add the negative ion powder of surface modification, after stirring, in ink-jet after pattern or spraying priming paint and the organic board uniformly spray paint solidified;
D, the organic board having sprayed finish paint is carried out photocuring.
In the step a of the preparation process of anion function organic board, the addition of negative ion powder is 4% of the weight sum accounting for UV priming paint and negative ion powder; In described steps d, the addition of negative ion powder is 4% of the weight sum accounting for UV finish paint and negative ion powder.
Wherein, the preparation process of the negative ion powder of surface modification, comprises following concrete steps:
A, in 100g water, add the surfactant of 9g, electric power stirs, and mixing speed is 3000 revs/min, is heated to reaction temperature 90 DEG C, then adds 3000 object negative ion powder 50g, obtains mixed liquor;
B, mixed liquor is carried out thermostatic ultrasonic process 20min in supersonic wave cleaning machine, the frequency 35KHz that supersonic wave cleaning machine adopts;
C, continuation constant temperature electric power stirring reaction 0.9h, mixing speed is 1350 revs/min;
D, reacted after, mixed liquor is filtered, gets solid, 130 DEG C dry to constant weight, pulverize, cross 600 mesh sieves.
Wherein, the formula of surfactant comprises sorbester p17 50%, silicone oil and silicone oil ester 9%, stearic acid and salt thereof 25%, senior amine salt 8%, unsaturated organic acid 8% by weight percentage.
Embodiment 4
In the present embodiment, be to the ceramic tile surface fired successively through spray be added with negative ion powder without modification priming paint, photocuring, ink-jet colouring, spray the finish paint of negative ion powder, the operation of photocuring that are added with without modification, negative ion powder is covered and is loaded on ceramic tile.
Technical scheme of the present invention adopts and building material product surface is added with to negative ion powder through spray or is added with negative ion powder or through the finish paint of the negative ion powder of surface modification, the operation of photocuring through the priming paint of the negative ion powder of surface modification, photocuring, ink-jet colouring, spray successively, load is covered on building material product by negative ion powder or through the negative ion powder of surface modification, by the function allowing building material product have anion releasing, and do not affect building material product surface color, especially with the addition of the priming paint of the negative ion powder through surface modification, its anion burst size increases with several times.Below anion release test data:
Detection method: at 0.73m
3in climate box, place ceramic tile, and place anionic textiles instrument simultaneously, close climate box.Open anionic textiles instrument, the reading of record and video recording anionic textiles instrument, 1 minute detection time, takes out detector.
After testing, although adding negative ion powder content in the priming paint of the negative ion powder of surface modification is add the half without the priming paint of the negative ion powder of modification, but its anion burst size is also higher, the demand of use can be met completely, greatly reduce production cost, environmental protection and energy saving are technical progress.Further, can see from the situation at ceramics factory scene, spray the finish paint that with the addition of modified negative-ion powder, the pattern color of ceramic tile is had no impact.
Above-described is only the preferred embodiment of the present invention, it should be pointed out that for the person of ordinary skill of the art, and without departing from the concept of the premise of the invention, can also make some distortion and improvement, these all belong to protection scope of the present invention.
Claims (10)
1. a coating process for anion function coating, is characterized in that, it is the anion UV priming paint first spraying surface modification in material, after photocuring, and then spray through or not through the UV finish paint of surface modification anion.
2. the coating process of anion function coating according to claim 1, is characterized in that, the anion UV priming paint of described surface modification is the negative ion powder adding surface modification in UV priming paint; The UV finish paint of surface modification anion is the negative ion powder adding surface modification in UV finish paint.
3. the coating process of anion function coating according to claim 1, is characterized in that, described material is not having on figuratum basis, is after the operation of carrying out photocureable priming coat, is placed on ink jet printer and carries out pattern in ink-jet; Material, on figuratum basis, is the anion UV priming paint directly spraying modification at patterned material surface.
4. the coating process of the anion function coating according to Claims 2 or 3, is characterized in that, it comprises following concrete steps:
A, primer spray, add the negative ion powder of surface modification to UV priming paint, after stirring, to material surface spray painting UV primer equably;
B, the material having sprayed priming paint is carried out photocuring;
C, in UV finish paint, add the negative ion powder of surface modification, after stirring, in ink-jet after pattern or spraying priming paint and the material surface spray paint equably solidified;
D, the material having sprayed finish paint is carried out photocuring.
5. the coating process of anion function coating according to claim 4, is characterized in that, in described step a, the addition of negative ion powder is the 1-30% of the weight sum accounting for UV priming paint and negative ion powder.
6. the coating process of anion function coating according to claim 4, is characterized in that, in described step c, the addition of negative ion powder is the 1-30% of the weight sum accounting for UV finish paint and negative ion powder.
7. the coating process of anion function coating according to claim 2, is characterized in that, the negative ion powder of described surface modification first toward water in, adds surfactant, heating after stirring, then adds negative ion powder and obtain mixed liquor; Then mixed liquor is carried out thermostatic ultrasonic process or high-speed stirred in supersonic wave cleaning machine, then constant temperature stirring reaction, filter after get solid and dry, pulverize and sieve and obtain.
8. the coating process of the anion function coating according to claim 2 or 7, is characterized in that, the preparation process of the negative ion powder of described surface modification comprises following concrete steps:
A, in 100g water, add the surfactant of 0.5-30g, electric power stirs, and mixing speed is 100-5000 rev/min, is heated to reaction temperature 60-100 DEG C, then adds 500-8000 object negative ion powder 10-60g, obtains mixed liquor;
B, mixed liquor is carried out thermostatic ultrasonic process 10-25min or high-speed stirred in supersonic wave cleaning machine, mixing speed is 1000-5000 rev/min;
C, continuation constant temperature electric power stirring reaction 0.5-1h, mixing speed is 100-1500 rev/min;
D, reacted after, mixed liquor is filtered, gets solid, dry to constant weight at 100-150 DEG C, pulverize, cross 80-8000 mesh sieve.
9. the coating process of anion function coating according to claim 8, is characterized in that, in described ultrasonication, and the frequency 20-100KHz that supersonic wave cleaning machine adopts.
10. the coating process of anion function coating according to claim 2, is characterized in that, described surfactant adopts the mixed solution mixed by span 20-80 and silicone oil and silicone oil ester, stearic acid and salt thereof, senior amine salt, unsaturated organic acid;
The formula of described surfactant comprises span 20-8045-80%, silicone oil and silicone oil ester 1-10%, stearic acid and salt 15-30% thereof, senior amine salt 1-10%, unsaturated organic acid 1-10% by weight percentage.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510708346.1A CN105251677A (en) | 2015-10-24 | 2015-10-24 | Coating method and application of anion functional coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510708346.1A CN105251677A (en) | 2015-10-24 | 2015-10-24 | Coating method and application of anion functional coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105251677A true CN105251677A (en) | 2016-01-20 |
Family
ID=55091774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510708346.1A Pending CN105251677A (en) | 2015-10-24 | 2015-10-24 | Coating method and application of anion functional coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105251677A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109487971A (en) * | 2018-12-29 | 2019-03-19 | 山东鲁泰建筑产业化材料有限公司 | A kind of energy health decoration plate and preparation method thereof |
| WO2021253620A1 (en) * | 2020-06-19 | 2021-12-23 | 浙江冠峰新材料有限公司 | Negative ion ultraviolet light curing paint for polyvinyl chloride plastic floor and production process therefor |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1986473A (en) * | 2005-12-22 | 2007-06-27 | 深圳市海川实业股份有限公司 | Tourmaline powder modifying process |
| CN104479440A (en) * | 2014-12-22 | 2015-04-01 | 东莞市罗曼罗兰电器科技有限公司 | Paint capable of releasing negative ions as well as preparation method and spraying technology thereof |
-
2015
- 2015-10-24 CN CN201510708346.1A patent/CN105251677A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1986473A (en) * | 2005-12-22 | 2007-06-27 | 深圳市海川实业股份有限公司 | Tourmaline powder modifying process |
| CN104479440A (en) * | 2014-12-22 | 2015-04-01 | 东莞市罗曼罗兰电器科技有限公司 | Paint capable of releasing negative ions as well as preparation method and spraying technology thereof |
Non-Patent Citations (1)
| Title |
|---|
| 刘瑄等: ""电气石粉表面改性工艺条件试验研究"", 《矿产保护与利用》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109487971A (en) * | 2018-12-29 | 2019-03-19 | 山东鲁泰建筑产业化材料有限公司 | A kind of energy health decoration plate and preparation method thereof |
| WO2021253620A1 (en) * | 2020-06-19 | 2021-12-23 | 浙江冠峰新材料有限公司 | Negative ion ultraviolet light curing paint for polyvinyl chloride plastic floor and production process therefor |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104151978B (en) | Aqueousance artificial granite coating | |
| CN101289595A (en) | Process for adhering tourmaline powder on surface of objects | |
| CN102585634B (en) | Coating with imitative ceramic effect and spraying process thereof | |
| CN102002298A (en) | Aqueous antifouling adhesive preventing coating and production method thereof | |
| CN105907294A (en) | Preparation method of water-borne inorganic paint and method for preparation of inorganic coating from water-borne inorganic paint | |
| CA2849758C (en) | Treated inorganic pigments having improved dispersability and use thereof in coating compositions | |
| CN102002295A (en) | Process for preparing liquid marble paint | |
| CN105131747A (en) | Weak solvent type inkjet media and preparation method thereof | |
| CN107141919B (en) | A kind of photosensitive coating and its preparation process | |
| CN105251677A (en) | Coating method and application of anion functional coating | |
| CN102492337A (en) | Latex paint and preparation method thereof | |
| CN103396727B (en) | Water-based first bone line paint and preparation method thereof | |
| CN108264782A (en) | A kind of Dry powder type shell powder coating and preparation method thereof | |
| CN109020443A (en) | Imitative rust stone effect dry powder paint and preparation method thereof | |
| JP2005526168A5 (en) | ||
| TWI538967B (en) | Nano - Anion Functional Water - in - Water Interior Wall Coating and Its Preparation | |
| CN114195480B (en) | Fine and smooth anti-fouling antibacterial brick and preparation method thereof | |
| CN102910915A (en) | Composite starch solution used for ceramic grinding ball rolling and moulding and preparation method thereof | |
| CN106189517A (en) | A kind of photochromic ceramic ink with leather pattern effect and preparation method thereof | |
| CN105199446B (en) | Nano titanium oxide functional coating, its preparation method, the preparation method of base material prepared therefrom and the base material | |
| KR101910284B1 (en) | Preparing method of coating agent glue for dog skin | |
| CN106366707B (en) | Inorganic crosslinking type nanometer coating varnish and preparation method thereof | |
| CN109610160A (en) | A kind of preparation method of the silk fabric with excellent hydrophobic performance | |
| CN109233485A (en) | A kind of water-soluble colorful coating and preparation method thereof | |
| CN107488030A (en) | A kind of imitative stone product with air-cleaning function and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160120 |
|
| RJ01 | Rejection of invention patent application after publication |