CN105242338A - Reflective luminous filament and preparation method thereof - Google Patents
Reflective luminous filament and preparation method thereof Download PDFInfo
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- CN105242338A CN105242338A CN201410251824.6A CN201410251824A CN105242338A CN 105242338 A CN105242338 A CN 105242338A CN 201410251824 A CN201410251824 A CN 201410251824A CN 105242338 A CN105242338 A CN 105242338A
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- photocuring
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Abstract
The invention relates to the technical field of reflective materials, and discloses a reflective luminous filament and a preparation method thereof. The reflective luminous filament comprises a PET film (1) and is characterized in that the PET film (1) is coated with a photo-curing agent layer (2), glass micro-beads (3) are uniformly scattered on the photo-curing agent layer (2), and a focus resin layer (4) is arranged between embedded surfaces of the glass micro-beads (3) and the photo-curing agent layer (2), wherein the photo-curing agent layer (2) comprises polyester glue, a diluting agent, an adhesive, a curing agent and a fluorescent illuminating agent. The reflective luminous filament disclosed by the invention has dual effects of self illumination and light reflection simultaneously, and meanwhile, the light reflection effect is enhanced through the diameter of the glass micro-beads, thereby being wider in application, and overcoming defects of the single light reflecting function, poor light reflecting effect and the like in the prior art.
Description
Technical field
The present invention relates to reflectorized material technical field, particularly relate to a kind of reflecting and luminous silk and preparation method thereof.
Background technology
Since reflective membrane technology is born, reflectorized material is widely used in the various industries such as highway, railway, port row, fire-fighting, airport, license plate as a kind of security protection product.Reflectorized material can produce strong reflecting effect under certain light source irradiation, for the pedestrian in dark or night work personnel provide the most effectively, the most reliable safety guarantee.Along with developing rapidly of reflectorized material, its range of application little by little expands, and current reflecting thread is used for the fields such as decoration, building, safety and clothes, plays the effect of decoration and warning.Particularly at night, reflective effect can cause the attention of vehicle driver, improves the security performance of trip at night and plays the effect of beautifying.But at present reflecting thread can only have reflecting effect at night under light-illuminating, plays the effect of warning, when without can not autoluminescence when light.
Summary of the invention
The present invention is directed to shortcoming in prior art, devise and a kind of there is reflecting and luminous silk of autoluminescence and reflective double effects and preparation method thereof simultaneously.
In order to solve the problems of the technologies described above, the present invention is solved by following technical proposals:
A kind of reflecting and luminous silk, comprise PET film, PET film scribbles photocuring oxidant layer, uniform sprinkled with glass microballoon in photocuring oxidant layer, focal resin layer is provided with between glass microballoon embedded surface and photocuring oxidant layer, wherein, photocuring oxidant layer comprises polyester glue, thinning agent, adhesive, hardening agent and fluorescence radiation agent.
Uniform sprinkled with glass microballoon in photocuring oxidant layer, there is material emitting performance, most of light is directly reflected back light source place, there is stronger reflection alarming effect, meanwhile, when night or rather dark, there is regression reflecting effect, the effect of security warning can be played.Containing fluorescence radiation agent in photocuring oxidant layer, when night and rather dark, fluorescence is by glass microballoon, reflecting and luminous silk also has self-luminescence effect, plays good warning function, and the function of reflecting thread is further strengthened, safety is indicative more reliable, and purposes is more extensive.Focal resin layer is provided with between the embedded surface of glass microballoon and photocuring oxidant layer.According to circumstances can increase or not increase focal resin layer, increase focal resin layer and can be applicable to oriented reflection film, focal resin layer has good light transmission rate and refractive index.
As preferably, the diameter of glass microballoon is 30-100 μm.The diameter of glass microballoon and the coverage rate of glass microballoon all can affect the reflecting effect of fabric, wherein the diameter of glass microballoon and the quantity of glass microballoon determine the coverage rate of glass microballoon, and therefore the diameter of glass microballoon is one of key factor affecting reflecting effect.When the diameter of glass microballoon is less, be arranged in the glass microballoon increasing number of reflector layer, between glass microballoon, easy adhesion or appearance are piled up pearl, are lacked the phenomenon of pearl, thus cause glass microballoon skewness, the coverage rate of glass microballoon declines, and the effective reflective area of the low then fabric face of coverage rate of glass microballoon is low, and the less then single glass microballoon luminous intensity of the diameter of glass microballoon is low in addition, synthesis result is that emitted luminescence intensity is low, thus causes the poor effect of reflection; When the diameter of glass microballoon is larger, in reflector layer arrangement evenly, then glass microballoon coverage rate improves glass microballoon, and the intensity of light reflection of fabric strengthens, and reflecting effect is better.
A preparation method for reflecting and luminous silk, comprises the following steps:
Step one: coat photocuring oxidant layer on a pet film, the thickness of photocuring oxidant layer is 25-50 μm;
Step 2: after photocuring oxidant layer stablizes 10 ~ 120min, at photocuring oxidant layer surface application focal resin layer;
Step 3: to the glass microballoon sprinkling monolayer alignment of the focal resin layer surface uniform of step 2, the 1/3-1/2 of glass microballoon is embedded into photocuring oxidant layer, adopts ultraviolet lamp tube to irradiate 5-60 second;
Step 4: exposed glass microballoon face is coated with protection glue-line in step 3.
First be on a pet film coated with light curing agent, then be coated with focal resin layer on photocuring oxidant layer surface, replant pearl, finally plant pearl layer surface coating protectant layer.Resin in focal resin layer has different viscosity and hardness from photocuring oxidant layer, and has good light transmission rate and refractive index, is conducive to fluorescent emission in photocuring oxidant layer to glass microballoon, plays luminous function.
As preferably, also comprise dicing process after step 4 and divest the step protecting glue-line.Protect glue-line to be in subsequent technique, cut shearing cause glass microballoon to peel off at glass microballoon surface application, after having cut, namely can divest protection glue-line; Certainly, also as required, can wouldn't divest protection glue-line, after follow-up technique to be done (such as by reflecting and luminous silk and other material blending), then divest protection glue-line.
As preferably, the thickness of glue-line in step 4, is protected to be 10-30um.Protection glue-line plays a protective role to glass microballoon, and protection glue-line is excessively thin, and do not have effect that is stable and cover glass microballon, protection glue-line is blocked up, comparatively wastes raw material, increases production cost.
As preferably, the weight proportion of polyester glue in photocuring oxidant layer, thinning agent, adhesive, hardening agent and fluorescence radiation agent be 5:1:2:2:3.
According to technical scheme of the present invention, a kind of reflecting and luminous silk and preparation method thereof,
Comprise PET film, PET film scribbles photocuring oxidant layer, uniform sprinkled with glass microballoon in photocuring oxidant layer, be provided with focal resin layer between glass microballoon embedded surface and photocuring oxidant layer, wherein, photocuring oxidant layer comprises polyester glue, thinning agent, adhesive, hardening agent and fluorescence radiation agent.Uniform sprinkled with glass microballoon in photocuring oxidant layer, there is material emitting performance, most of light is directly reflected back light source place, there is stronger reflection alarming effect, simultaneously, when night and rather dark, there is regression reflecting effect under light-illuminating, the effect of security warning can be played; Be provided with focal resin layer between the embedded surface of glass microballoon and photocuring oxidant layer, focal resin layer has good light transmission rate and refractive index, can be applicable to directional reflective; Protection glue-line plays effect that is fixing and protection to glass microballoon; effectively prevent glass microballoon wearing and tearing in subsequent machining technology from coming off; luminescent material is contained in addition in photocuring oxidant layer; when night and rather dark; indicative function is played by glass microballoon self-luminescence; the function of reflecting thread is further strengthened, and safety is indicative more reliable, and purposes is more extensive.The diameter of glass microballoon is 30-100 μm, and the intensity of light reflection of fabric is large with this understanding, and reflecting effect is good.The present invention has reflective and self luminous double effects simultaneously, enhances reflective effect by the diameter of glass microballoon simultaneously, and application is more extensive, overcomes in prior art and only has reflection function, the shortcomings such as reflecting effect is not good.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
The toponym that in accompanying drawing, each number designation refers to is as follows: 1-PET film, 2-photocuring oxidant layer, 3-glass microballoon, 4-focal resin layer, 5-protection glue-line.
Embodiment
Below in conjunction with accompanying drawing and embodiment, the present invention is described in further detail:
embodiment 1
A kind of reflecting and luminous silk and preparation method thereof, as shown in Figure 1, comprises the following steps:
Step one: coat photocuring oxidant layer 2 in PET film 1, the thickness of photocuring oxidant layer 2 is 25 μm, the weight proportion of wherein polyester glue in photocuring oxidant layer 2, thinning agent, adhesive, hardening agent and fluorescence radiation agent be 5:1:2:2:3;
Step 2: after photocuring oxidant layer 2 stablizes 10min, at photocuring oxidant layer 2 surface application focal resin layer 4;
Step 3: to the glass microballoon 3 sprinkling monolayer alignment of focal resin layer 4 surface uniform of step 2, the diameter of glass microballoon 3 is 40 μm, and the 1/3-1/2 of glass microballoon 3 is embedded into photocuring oxidant layer 2, adopts ultraviolet lamp tube to irradiate 5 seconds;
Step 4: be coated with protection glue-line 5 on the face of the glass microballoon 3 in step 3, the thickness of protection glue-line 5 is 15um.
embodiment 2
A kind of reflecting and luminous silk and preparation method thereof, as shown in Figure 1, comprises the following steps:
Step one: coat photocuring oxidant layer 2 in PET film 1, the thickness of photocuring oxidant layer 2 is 50 μm, the weight proportion of wherein polyester glue in photocuring oxidant layer 2, thinning agent, adhesive, hardening agent and fluorescence radiation agent be 5:1:2:2:3;
Step 2: after photocuring oxidant layer 2 stablizes 30min, at photocuring oxidant layer 2 surface application focal resin layer 4;
Step 3: to the glass microballoon 3 sprinkling monolayer alignment of focal resin layer 4 surface uniform of step 2, the diameter of glass microballoon 3 is 30 μm, and the 1/3-1/2 of glass microballoon 3 is embedded into photocuring oxidant layer 2, adopts ultraviolet lamp tube to irradiate 60 seconds;
Step 4: be coated with protection glue-line 5 on the face of the glass microballoon 3 in step 3, the thickness of protection glue-line 5 is 10um.
Wherein, the thickness of protection glue-line 5 is 30um, carries out dicing process again, reflecting and luminous silk is cut into the silk of diameter 1mm after step 4, finally divests protection glue-line 5.
embodiment 3
A kind of reflecting and luminous silk and preparation method thereof, as shown in Figure 1, comprises the following steps:
Step one: coat photocuring oxidant layer 2 in PET film 1, the thickness of photocuring oxidant layer 2 is 30 μm, the weight proportion of wherein polyester glue in photocuring oxidant layer 2, thinning agent, adhesive, hardening agent and fluorescence radiation agent be 5:1:2:2:3;
Step 2: after photocuring oxidant layer 2 stablizes 60min, at photocuring oxidant layer 2 surface application focal resin layer 4;
Step 3: to the glass microballoon 3 sprinkling monolayer alignment of focal resin layer 4 surface uniform of step 2, the diameter of glass microballoon 3 is 50 μm, and the 1/3-1/2 of glass microballoon 3 is embedded into photocuring oxidant layer 2, adopts ultraviolet lamp tube to irradiate 30 seconds;
Step 4: be coated with protection glue-line 5 on the face of the glass microballoon 3 in step 3, the thickness of protection glue-line 5 is 10um.
Wherein, the thickness of protection glue-line 5 is 10um, carries out dicing process again after step 4, finally divests protection glue-line 5.
embodiment 4
A kind of reflecting and luminous silk and preparation method thereof, as shown in Figure 1, comprises the following steps:
Step one: coat photocuring oxidant layer 2 in PET film 1, the thickness of photocuring oxidant layer 2 is 40 μm, the weight proportion of wherein polyester glue in photocuring oxidant layer 2, thinning agent, adhesive, hardening agent and fluorescence radiation agent be 5:1:2:2:3;
Step 2: after photocuring oxidant layer 2 stablizes 30min, at photocuring oxidant layer 2 surface application focal resin layer 4;
Step 3: to the glass microballoon 3 sprinkling monolayer alignment of focal resin layer 4 surface uniform of step 2, the diameter of glass microballoon 3 is 70 μm, and the 1/3-1/2 of glass microballoon 3 is embedded into photocuring oxidant layer 2, adopts ultraviolet lamp tube to irradiate 40 seconds;
Step 4: be coated with protection glue-line 5 on the face of the glass microballoon 3 in step 3, the thickness of protection glue-line 5 is 25um;
Carry out dicing process again after step 4, reflecting and luminous silk is cut into the silk of diameter 2mm, finally divest protection glue-line 5.
embodiment 5
A kind of reflecting and luminous silk and preparation method thereof, as shown in Figure 1, comprises the following steps:
Step one: coat photocuring oxidant layer 2 in PET film 1, the thickness of photocuring oxidant layer 2 is 50 μm, the weight proportion of wherein polyester glue in photocuring oxidant layer 2, thinning agent, adhesive, hardening agent and fluorescence radiation agent be 5:1:2:2:3;
Step 2: after photocuring oxidant layer 2 stablizes 30min, at photocuring oxidant layer 2 surface application focal resin layer 4;
Step 3: to the glass microballoon 3 sprinkling monolayer alignment of focal resin layer 4 surface uniform of step 2, the diameter of glass microballoon 3 is 100 μm, and the 1/3-1/2 of glass microballoon 3 is embedded into photocuring oxidant layer 2, adopts ultraviolet lamp tube to irradiate 50 seconds;
Step 4: be coated with protection glue-line 5 on the face of the glass microballoon 3 in step 3, the thickness of protection glue-line 5 is 20um.
Carry out dicing process again after step 4, reflecting and luminous silk is cut into the silk of diameter 5mm, finally divest protection glue-line 5.
In a word, the foregoing is only preferred embodiment of the present invention, all equalizations done according to the present patent application the scope of the claims change and modify, and all should belong to the covering scope of patent of the present invention.
Claims (6)
1. a reflecting and luminous silk, comprise PET film (1), it is characterized in that: PET film (1) scribbles photocuring oxidant layer (2), photocuring oxidant layer (2) is upper uniform sprinkled with glass microballoon (3), focal resin layer (4) is provided with between glass microballoon (3) embedded surface and photocuring oxidant layer (2), wherein, photocuring oxidant layer (2) comprises polyester glue, thinning agent, adhesive, hardening agent and fluorescence radiation agent.
2. the reflecting and luminous silk of one according to claim 1, is characterized in that: the diameter of glass microballoon (3) is 30-100 μm.
3. a preparation method for reflecting and luminous silk, is characterized in that, comprises the following steps:
Step one: coat photocuring oxidant layer (2) in PET film (1), the thickness of photocuring oxidant layer (2) is 25-50 μm;
Step 2: after photocuring oxidant layer (2) stablizes 10 ~ 120min, at photocuring oxidant layer (2) surface application focal resin layer (4);
Step 3: to the glass microballoon (3) sprinkling monolayer alignment of focal resin layer (4) surface uniform of step 2, adopts ultraviolet lamp tube to irradiate 5-60 second;
Step 4: in step 3, exposed glass microballoon face is coated with protection glue-line (5).
4. the preparation method of a kind of reflecting and luminous silk according to claim 3, is characterized in that: also comprise dicing process after step 4 and divest the step protecting glue-line (5).
5. the preparation method of a kind of reflecting and luminous silk according to claim 3, is characterized in that: protect the thickness of glue-line (5) to be 10-30um in step 4.
6. the preparation method of a kind of reflecting and luminous silk according to claim 3, is characterized in that: the weight proportion of polyester glue in photocuring oxidant layer (2), thinning agent, adhesive, hardening agent and fluorescence radiation agent is 5:1:2:2:3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410251824.6A CN105242338A (en) | 2014-06-09 | 2014-06-09 | Reflective luminous filament and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410251824.6A CN105242338A (en) | 2014-06-09 | 2014-06-09 | Reflective luminous filament and preparation method thereof |
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| CN105242338A true CN105242338A (en) | 2016-01-13 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108535800A (en) * | 2018-05-31 | 2018-09-14 | 苏州苏大维格光电科技股份有限公司 | It can air brushing reflective membrane and preparation method thereof |
| CN108754671A (en) * | 2018-05-03 | 2018-11-06 | 安徽路政通新材料科技有限公司 | A kind of noctilucence silk and preparation method thereof that reflecting effect is good |
| CN114836137A (en) * | 2022-04-27 | 2022-08-02 | 石狮市晓光服饰反光材料有限公司 | Colorful light-reflecting fabric and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2118085U (en) * | 1992-03-10 | 1992-10-07 | 中国科学院安徽光学精密机械研究所 | Engineering grade rear direction reflecting film |
| JP2002323613A (en) * | 2001-04-24 | 2002-11-08 | Shiina:Kk | Fluorescent long after grow photoluminescent reflector |
| CN1958283A (en) * | 2006-11-10 | 2007-05-09 | 贾剑方 | Spray paintable reflective single sided perspective film, and production method |
| TW200821155A (en) * | 2006-11-13 | 2008-05-16 | Hsin-Hui Wu | Manufacturing method of light-reflecting material added with luminous effect |
| CN101369033A (en) * | 2008-09-11 | 2009-02-18 | 常州华日升反光材料有限公司 | Reflecting film and preparation method thereof |
| CN101477218A (en) * | 2009-02-11 | 2009-07-08 | 杭州星华反光材料有限公司 | Special planting-bead film for reflective cloth, and photo-curing reflecting planting-bead cloth composed of the same |
| CN102490510A (en) * | 2011-12-01 | 2012-06-13 | 宁波长阳科技有限公司 | Polyester reflective membrane for printing and preparation method thereof |
| CN103091746A (en) * | 2013-01-23 | 2013-05-08 | 杭州星华反光材料有限公司 | Multifunctional composite reflective cloth and manufacturing method thereof |
-
2014
- 2014-06-09 CN CN201410251824.6A patent/CN105242338A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2118085U (en) * | 1992-03-10 | 1992-10-07 | 中国科学院安徽光学精密机械研究所 | Engineering grade rear direction reflecting film |
| JP2002323613A (en) * | 2001-04-24 | 2002-11-08 | Shiina:Kk | Fluorescent long after grow photoluminescent reflector |
| CN1958283A (en) * | 2006-11-10 | 2007-05-09 | 贾剑方 | Spray paintable reflective single sided perspective film, and production method |
| TW200821155A (en) * | 2006-11-13 | 2008-05-16 | Hsin-Hui Wu | Manufacturing method of light-reflecting material added with luminous effect |
| CN101369033A (en) * | 2008-09-11 | 2009-02-18 | 常州华日升反光材料有限公司 | Reflecting film and preparation method thereof |
| CN101477218A (en) * | 2009-02-11 | 2009-07-08 | 杭州星华反光材料有限公司 | Special planting-bead film for reflective cloth, and photo-curing reflecting planting-bead cloth composed of the same |
| CN102490510A (en) * | 2011-12-01 | 2012-06-13 | 宁波长阳科技有限公司 | Polyester reflective membrane for printing and preparation method thereof |
| CN103091746A (en) * | 2013-01-23 | 2013-05-08 | 杭州星华反光材料有限公司 | Multifunctional composite reflective cloth and manufacturing method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108754671A (en) * | 2018-05-03 | 2018-11-06 | 安徽路政通新材料科技有限公司 | A kind of noctilucence silk and preparation method thereof that reflecting effect is good |
| CN108535800A (en) * | 2018-05-31 | 2018-09-14 | 苏州苏大维格光电科技股份有限公司 | It can air brushing reflective membrane and preparation method thereof |
| CN114836137A (en) * | 2022-04-27 | 2022-08-02 | 石狮市晓光服饰反光材料有限公司 | Colorful light-reflecting fabric and preparation method thereof |
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Application publication date: 20160113 |