CN105236684A - Anaerobic bidirectionally-rotatable membrane bioreactor used for treating livestock and poultry breeding wastewater and operation method thereof - Google Patents

Anaerobic bidirectionally-rotatable membrane bioreactor used for treating livestock and poultry breeding wastewater and operation method thereof Download PDF

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CN105236684A
CN105236684A CN201510712197.6A CN201510712197A CN105236684A CN 105236684 A CN105236684 A CN 105236684A CN 201510712197 A CN201510712197 A CN 201510712197A CN 105236684 A CN105236684 A CN 105236684A
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peristaltic pump
membrane
bidirectional rotation
anaerobic
anaerobic reactor
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许美兰
李元高
严滨
叶胜
叶茜
徐苏
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Xiamen University of Technology
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Xiamen University of Technology
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Abstract

The invention discloses an anaerobic bidirectionally-rotatable membrane bioreactor used for treating livestock and poultry breeding wastewater and an operation method thereof. The membrane bioreactor comprises a water inlet box, an influent water peristaltic pump, an anaerobic reactor, a circulation peristaltic pump, a constant-temperature water bath box, a bidirectionally-rotatable membrane assembly and an effluent water peristaltic pump; the water inlet box is connected with the influent water peristaltic pump which is connected with the anaerobic reactor which is respectively connected with the bidirectionally-rotatable membrane assembly and the circulation peristaltic pump; and the circulation peristaltic pump is connected with the constant-temperature water bath box which is connected with the bidirectionally-rotatable membrane assembly which is connected with the effluent water peristaltic pump and comprises a central transmission shaft, a rotatable motor and a plurality of rotatable membranes. The anaerobic bidirectionally-rotatable membrane bioreactor provided by the invention can control the development of a pollution layer on the surface of the membrane, further improves membrane pollution resistant performance, has simple operation steps, can give full play to the technical advantages of the anaerobic membrane bioreactor in the aspect of livestock and poultry breeding wastewater treatment, and also can effectively avoid the problem of membrane pollution of the anaerobic membrane bioreactor at the same time.

Description

A kind of anaerobism bidirectional rotation membrane bioreactor for the treatment of livestock breeding wastewater and operation method thereof
Technical field
The present invention relates to the technical field of livestock breeding wastewater process, refer in particular to a kind of anaerobism bidirectional rotation membrane bioreactor for the treatment of livestock breeding wastewater and operation method thereof.
Background technology
The organism of livestock breeding wastewater, ammonia nitrogen, concentration of suspension are high, and direct discharge can cause serious threat to ecotope, thus needs to process discharge further to livestock breeding wastewater.Anaerobic Methods in Treating can be adopted with the recycling of the process and resource that realize waste water to the process of livestock breeding wastewater.
Anaerobic Methods in Treating is under anaerobic, by the acting in conjunction of obligate and amphimicrobe, is decomposed by organism, reclaims the energy and resource with the form of biogas, natural pond liquid and natural pond slag simultaneously.The development of this technology has over one hundred year history, has occurred a series of high efficiency anaerobic reactor in recent decades, as up-flow anaerobic sludge blanket, anaerobic filter, anaerobic fluidized bed etc.These reactors realize microorganism mainly through granular sludge and the biomembranous mode of formation and retain, and avoid microorganism to run off, improve processing power.When their high suspended matter waste water this kind of for livestock breeding wastewater, affect by suspended substance, easily occur that granular sludge is poor, blocking or the phenomenon such as short stream, processing power declines.Although traditional complete hybrid anaerobic digester is applicable to high suspended matter waste water, due to without microorganism retention functions, make processing efficiency low, take up an area large, capacity of resisting impact load is poor, fluctuation of service.Therefore, for livestock breeding wastewater, exploitation is efficient, stable, practical Novel anaerobic technique is very necessary.
In recent years, flourish along with domestic and international membrane technique, membrane sepn every field application gradually deeply, wherein, anaerobic membrane bioreactor, as the emerging dual-membrane process of one, receives publicity gradually.Anaerobic membrane bioreactor is the composite system that membrane technique combines with anaerobic treatment process.This process application is as follows in the advantage of livestock breeding wastewater:
(1) anaerobic membrane bioreactor operating load is high, takes up an area little.
Anaerobic membrane bioreactor does not rely on granular sludge and biofilm formation to retain microorganism; but rely on the separation of membrane module to realize the effectively catching of microorganism; ensure that microorganism concn higher in reactor, thus improve operating load, reduce reactor volume.
(2) anaerobic membrane bioreactor efficient stable more.
While anaerobic membrane bioreactor can mix between strengthening waste water and microorganism, still ensure comparatively high microorganism concentration and need not worry that microorganism is run off, thus improve processing efficiency and produce the ability of methane, strengthen capacity of resisting impact load, operating performance is stablized, and reduces follow-up management problem.In addition, due to the crown_interception of film, the suspended particulate in waste water and part pollutent can be retained in reactor for a long time, improve wastewater treatment and resource recovery further.
(3) anaerobic membrane bioreactor effluent quality is good.
Membrane module crown_interception can make system effluent quality be better than other anaerobic techniques.
(4) anaerobic membrane bioreactor technique is relatively simple, and can form integration apparatus, later stage running maintenance is easy.
Visible, this technique has significant advantage in livestock breeding wastewater process.But current fouling membrane is still a major reason of puzzlement anaerobic membrane bioreactor development.Fouling membrane can cause flux depression, affects the steady running of whole system.And during by the livestock breeding wastewater of anaerobic membrane bioreactor for the treatment of complicated component, membrane pollution problem may be more outstanding.Therefore, the practical application that the thorough solution that anaerobic membrane is polluted will advance anaerobic membrane bioreactor in livestock breeding wastewater process conscientiously.
At present, domestic and international investigator comprises the measure of control of fouling membrane in anaerobic membrane bioreactor and improves mixed liquor characteristics (as sludge concentration, dissolved organic matter, grain diameter etc.), adjustment operation condition (as membrane flux, transmembrane pressure, cross-flow rate and suction mode etc.), improves mould material and improves its resistance to crocking.
For comparatively traditional common external placed type anaerobic membrane bioreactor, high cross-flow rate is provided to be the mode generally adopted by pump circulation.And in recent years enjoying the immersion type anaerobic film bioreactor that the energy consumption of high praise is lower, investigators then usually consider to adopt the mode of biogas recirculation to carry out disturbance to alleviate fouling membrane on film surface.But, the operation relative complex of biogas recirculation, and the disturbance of biogas likely reduces sludge returning, thus cause negative impact.At present, for the problem of fouling membrane, a kind of novel anaerobic membrane bioreactor---anaerobism rotates membrane bioreactor and attracts attention.
It is exactly have employed the anaerobic membrane bioreactor rotating membrane module that anaerobism rotates membrane bioreactor.Wherein, the turbulent flow that rotation membrane module rotates formation by film self improves hydraulic shear with the formation of controlling diaphragm surface contamination layer.At present, the correlative study of anaerobism rotation membrane bioreactor is less.Rotating Plates membrane module was once used in anaerobic membrane bioreactor by the people such as Jiang, and have studied the start-up course of this reactor Anammox.Find in research, the membrane filtration characteristic that anaerobism rotates membrane bioreactor is better than traditional anaerobic membrane bioreactor.The people such as Bai Ling have developed a kind of immersion dual-axis rotation anaerobic membrane bioreactor and use it for treatment of simulated brewery wastewater.Result of study shows, relies on membrane module dual-axis rotation and the good hydraulics that formed can the development of effective controlling diaphragm pollution.But this immersion dual-axis rotation anaerobic membrane bioreactor is in actual motion, and membrane module easily breakage occurs, high to the requirement of manufacture technics, not easily amplifies popularization.And the above-mentioned rotation membrane module rotated in membrane bioreactor research about anaerobism all adopts single direction rotation mode.
Therefore, in order to improve preventing membrane pollution performance further, the present inventor makes further research this, and develop a kind of anaerobism bidirectional rotation membrane bioreactor for the treatment of livestock breeding wastewater and operation method thereof, this case produces thus.
Summary of the invention
The object of the present invention is to provide a kind of anaerobism bidirectional rotation membrane bioreactor for the treatment of livestock breeding wastewater, the development of controlling diaphragm surface contamination layer, improve preventing membrane pollution performance further.
Another object of the present invention is the operation method providing a kind of anaerobism bidirectional rotation membrane bioreactor for the treatment of livestock breeding wastewater, operation steps is simple, the technical superiority of anaerobic membrane bioreactor in livestock breeding wastewater process can be given full play to, effectively can avoid again the membrane pollution problem of anaerobic membrane bioreactor simultaneously.
For solving the problems of the technologies described above, technical solution of the present invention is:
For the treatment of an anaerobism bidirectional rotation membrane bioreactor for livestock breeding wastewater, comprise inlet chest, water inlet peristaltic pump, anaerobic reactor, circulation peristaltic pump, constant water bath box, bidirectional rotation membrane module and water outlet peristaltic pump;
Inlet chest connects water inlet peristaltic pump, water inlet peristaltic pump connects anaerobic reactor, and anaerobic reactor connects bidirectional rotation membrane module and circulation peristaltic pump respectively, and circulation peristaltic pump connects constant water bath box, constant water bath box connects bidirectional rotation membrane module, and bidirectional rotation membrane module connects water outlet peristaltic pump;
Bidirectional rotation membrane module comprises center driving axle, rotating machine and a plurality of rotating membrane; Rotating machine connects center driving axle, and a plurality of rotating membrane wears and is fixed on center driving axle, by the forward and reverse bidirectional rotation of rotating machine center driving axle driven rotary diaphragm; Center driving axle inside has the hollow channel that filtrate is catchmented;
Waste water in inlet chest is delivered to anaerobic reactor by water inlet peristaltic pump and fully mixes with the anaerobic sludge in anaerobic reactor and to degrade, mud mixed liquid in anaerobic reactor is delivered to after constant water bath box carries out thermostatic control by circulation peristaltic pump and is delivered to bidirectional rotation membrane module again, in bidirectional rotation membrane module, produce filtrate and thickened sludge mixed solution, filtrate enters in center driving axle through rotating membrane and is sucked out under the suction effect of water outlet peristaltic pump; The thickened sludge mixed solution conveying that tunicle retains is back to anaerobic reactor.
Further, also comprise PLC device, PLC device is electrically connected with inlet chest, peristaltic pump of intaking, anaerobic reactor, circulation peristaltic pump, constant water bath box, bidirectional rotation membrane module and water outlet peristaltic pump respectively.
Further, rotating membrane is the disk rotary diaphragm of parallel placement.
Further, rotating membrane spacing is 1cm.
Further, bidirectional rotation membrane module has the outlet of fluid inlet, filtrate outlet and rework solution, fluid inlet and rework solution outlet are positioned at the same side of bidirectional rotation membrane module, fluid inlet is positioned at the below of rotating membrane, rework solution outlet is positioned at the top of rotating membrane, and filtrate outlet is positioned at the below of rotating machine.
For the treatment of an operation method for the anaerobism bidirectional rotation membrane bioreactor of livestock breeding wastewater, comprise the following steps:
The first step, the waste water in inlet chest is delivered to anaerobic reactor by water inlet peristaltic pump;
Second step, waste water fully mixes with the anaerobic sludge in anaerobic reactor and degrades, temperature 30 ~ 35 ° of C in anaerobic reactor, hydraulic detention time 1.6 ~ 3.3d, operating load 0.4 ~ 3.5kgCODm -3d -1;
3rd step, the mud mixed liquid in anaerobic reactor is delivered to constant water bath box by circulation peristaltic pump and carries out temperature control, makes mud mixed liquid temperature control at 30 ~ 35 DEG C;
4th step, is delivered to bidirectional rotation membrane module by mud mixed liquid;
5th step, aspirates 8min at the every 10min of film water outlet suction frequencies; Membrane flux 12.0 ~ 26.8Lm -2h -1; Film rotary rpm 150rpm; Under the condition of bidirectional rotation cycle 0.5h, by the forward and reverse bidirectional rotation of reaction center transmission shaft driven rotary diaphragm of rotating machine in bidirectional rotation membrane module, produce filtrate and thickened sludge mixed solution, filtrate enters in center driving axle through rotating membrane and is sucked out under the suction effect of water outlet peristaltic pump; The thickened sludge mixed solution conveying that tunicle retains is back to anaerobic reactor.
Adopt after such scheme, what adopt due to membrane module in the anaerobism bidirectional rotation membrane bioreactor that the present invention builds is the mode of bidirectional rotation.The velocity of flow of the speed of rotation of film and feed liquid can be made vector superposed by the mode of this forward and reverse reciprocating rotary, improve the velocity slope on film surface, thus the shearing action on reinforced film surface, the development that controlling diaphragm pollutes, delays the decay of membrane flux.By the process of this process application in livestock breeding wastewater, the technical superiority of anaerobic membrane bioreactor in livestock breeding wastewater process can be given full play to, effectively can avoid the membrane pollution problem of anaerobic membrane bioreactor simultaneously.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
Label declaration
Inlet chest 1 peristaltic pump 2 anaerobic reactor 3 of intaking circulates peristaltic pump 4
Constant water bath box 5 bidirectional rotation membrane module 6 rotating membrane 61 rotating machine 62
Center driving axle 63 hollow channel 631 fluid inlet 64 filtrate outlet 65
Rework solution exports 66 water outlet peristaltic pumps 7.
Embodiment
Below in conjunction with the drawings and specific embodiments, the invention will be further described.
Disclosed is a kind of anaerobism bidirectional rotation membrane bioreactor for the treatment of livestock breeding wastewater, as shown in Figure 1, for preferred embodiment of the present invention, comprise inlet chest 1, water inlet peristaltic pump 2, anaerobic reactor 3, circulation peristaltic pump 4, constant water bath box 5, bidirectional rotation membrane module 6 and water outlet peristaltic pump 7.
Inlet chest 1 connects water inlet peristaltic pump 2, water inlet peristaltic pump 2 connects anaerobic reactor 3, anaerobic reactor 3 connects bidirectional rotation membrane module 6 and circulation peristaltic pump 4 respectively, circulation peristaltic pump 4 connects constant water bath box 5, constant water bath box 5 connects bidirectional rotation membrane module 6, and bidirectional rotation membrane module 6 connects water outlet peristaltic pump 7;
Bidirectional rotation membrane module 6 comprises center driving axle 63, rotating machine 62 and a plurality of rotating membrane 61, rotating machine 62 connects center driving axle 63, a plurality of rotating membrane 61 wears and is fixed on center driving axle 63, by rotating machine 62, the forward and reverse bidirectional rotation of center driving axle 63 driven rotary diaphragm 61; Center driving axle 63 inside has hollow channel 631; Hollow channel 631 is filtrate header, so just need not arrange the device collecting filtrate in addition again, be conducive to simplified construction, reduces production cost.
Waste water in inlet chest 1 is delivered to anaerobic reactor 3 by water inlet peristaltic pump 2 and fully mixes with the anaerobic sludge in anaerobic reactor 3 and degrade, mud mixed liquid in anaerobic reactor 3 is delivered to after constant water bath box 5 carries out thermostatic control by circulation peristaltic pump 4 and is delivered to bidirectional rotation membrane module 6 again, in bidirectional rotation membrane module 6, produce filtrate and thickened sludge mixed solution, filtrate enters in center driving axle 63 through rotating membrane 61 and is sucked out under the suction effect of water outlet peristaltic pump 7; The thickened sludge mixed solution conveying that tunicle retains is back to anaerobic reactor 3.
What bidirectional rotation membrane module 6 adopted is that the mode of bidirectional rotation (is namely first rotated forward by rotating machine 62 center driving axle 63 driven rotary diaphragm 61, rotated in the other direction by rotating machine 62 center driving axle 63 driven rotary diaphragm 61 again, this is a period of motion, the length of the period of motion can be different according to the kind of waste water difference of actual treatment), by the mode of this forward and reverse reciprocating rotary, the velocity of flow of the speed of rotation of rotating membrane 61 film and feed liquid can be made vector superposed, improve the velocity slope on rotating membrane 61 film surface, thus the shearing action on strengthening rotating membrane 61 film surface, control the development of rotating membrane 61 fouling membrane, delay the decay of rotating membrane 61 membrane flux.Different greatly from the mechanism of single direction rotation mode, single direction rotation mode cannot reach the effect of this excellence.
Further, also comprise PLC device (not shown in FIG.), PLC device is electrically connected with inlet chest 1, peristaltic pump 2 of intaking, anaerobic reactor 3, circulation peristaltic pump 4, constant water bath box 5, bidirectional rotation membrane module 6 and water outlet peristaltic pump 7 respectively.Like this, overall operation of the present invention is controlled automatically by the PLC device be equipped with, simple to operation.
Further, rotating membrane 61 is the disk rotary diaphragm of parallel placement, and disk rotary diaphragm refers to the rotatable diaphragm of disc-shape, can make by oneself and also can buy from market, as long as can meet disc-shape and these two conditions rotatable.In the present embodiment, disk rotary diaphragm 61 is parallel placement superposition successively, under the condition being spaced apart 1cm, has good effect.
Further, bidirectional rotation membrane module 6 has fluid inlet 64, filtrate outlet 65 and rework solution outlet 66, fluid inlet 64 and rework solution outlet 66 are positioned at the same side of bidirectional rotation membrane module 6, fluid inlet 64 is positioned at the below of rotating membrane 61, rework solution outlet 66 is positioned at the top of rotating membrane 61, and filtrate outlet 65 is positioned at the below of rotating machine 62.This kind of design, can contact with rotating membrane 61 fast and effectively after making mud mixed liquid enter bidirectional rotation membrane module 6, be conducive to the discharge of filtrate and thickened sludge mixed solution.
Operation method of the present invention is elaborated below for Pig raising wastewater (a kind of typical livestock breeding wastewater).Pig raising wastewater is stored in inlet chest.
The first step, is delivered to anaerobic reactor 3 by the Pig raising wastewater in inlet chest 1 by water inlet peristaltic pump 2;
Second step, Pig raising wastewater fully mixes with the anaerobic sludge in anaerobic reactor 3 and carries out degraded and produces, and the temperature in anaerobic reactor 3 is 30 ~ 35 ° of C, hydraulic detention time 1.6 ~ 3.3d, operating load 0.4 ~ 3.5kgCODm -3d -1;
3rd step, is delivered to constant water bath box 5 by the mud mixed liquid produced in anaerobic reactor 3 by circulation peristaltic pump 4 and carries out thermostatic control, make mud mixed liquid temperature control at 30 ~ 35 DEG C;
4th step, is delivered to the mud mixed liquid after thermostatic control in bidirectional rotation membrane module 6;
5th step, aspirates 8min at the every 10min of film water outlet suction frequencies; Membrane flux 12.0 ~ 26.8Lm -2h -1; Film rotary rpm 150rpm; Under the condition of bidirectional rotation cycle 0.5h, by the effect of rotating machine 62 in bidirectional rotation membrane module 6, the forward and reverse bidirectional rotation of center driving axle 63 driven rotary diaphragm 61 produces filtrate and thickened sludge mixed solution, and filtrate enters in center driving axle 63 through rotating membrane 61 and is sucked out under the suction effect of water outlet peristaltic pump 7; The thickened sludge mixed solution conveying that tunicle retains is back to anaerobic reactor 3.
Under these conditions, the COD clearance of Pig raising wastewater reaches 88.2% ~ 97.7%; Resistance of membrane filtration controls 6.0 × 10 9m -1below; Without the need to cleaning in membrane module run at reactor 51 days.This result show the present invention to the treatment effect of Pig raising wastewater and control membrane fouling effect all desirable.By the process of this process application in livestock breeding wastewater, both can give full play to the technical superiority of anaerobic membrane bioreactor in livestock breeding wastewater process, effectively can avoid again the membrane pollution problem of anaerobic membrane bioreactor simultaneously.
The above is only preferred embodiment of the present invention, not imposes any restrictions technical scope of the present invention, therefore the change in every case done according to claim of the present invention and specification sheets or modification, all should belong within scope that patent of the present invention contains.

Claims (6)

1. for the treatment of an anaerobism bidirectional rotation membrane bioreactor for livestock breeding wastewater, it is characterized in that: comprise inlet chest, water inlet peristaltic pump, anaerobic reactor, circulation peristaltic pump, constant water bath box, bidirectional rotation membrane module and water outlet peristaltic pump;
Inlet chest connects water inlet peristaltic pump, water inlet peristaltic pump connects anaerobic reactor, and anaerobic reactor connects bidirectional rotation membrane module and circulation peristaltic pump respectively, and circulation peristaltic pump connects constant water bath box, constant water bath box connects bidirectional rotation membrane module, and bidirectional rotation membrane module connects water outlet peristaltic pump;
Bidirectional rotation membrane module comprises center driving axle, rotating machine and a plurality of rotating membrane; Rotating machine connects center driving axle, and a plurality of rotating membrane wears and is fixed on center driving axle, by the forward and reverse bidirectional rotation of rotating machine center driving axle driven rotary diaphragm; Center driving axle inside has the hollow channel that filtrate is catchmented;
Waste water in inlet chest is delivered to anaerobic reactor by water inlet peristaltic pump and fully mixes with the anaerobic sludge in anaerobic reactor and to degrade, mud mixed liquid in anaerobic reactor is delivered to after constant water bath box carries out thermostatic control by circulation peristaltic pump and is delivered to bidirectional rotation membrane module again, in bidirectional rotation membrane module, produce filtrate and thickened sludge mixed solution, filtrate enters in center driving axle through rotating membrane and is sucked out under the suction effect of water outlet peristaltic pump; The thickened sludge mixed solution conveying that tunicle retains is back to anaerobic reactor.
2. a kind of anaerobism bidirectional rotation membrane bioreactor for the treatment of livestock breeding wastewater according to claim 1, it is characterized in that: also comprise PLC device, PLC device is electrically connected with inlet chest, peristaltic pump of intaking, anaerobic reactor, circulation peristaltic pump, constant water bath box, bidirectional rotation membrane module and water outlet peristaltic pump respectively.
3. a kind of anaerobism bidirectional rotation membrane bioreactor for the treatment of livestock breeding wastewater according to claim 1, is characterized in that: rotating membrane is the disk rotary diaphragm of parallel placement.
4. a kind of anaerobism bidirectional rotation membrane bioreactor for the treatment of livestock breeding wastewater according to claim 1 or 3, is characterized in that: rotating membrane spacing is 1cm.
5. a kind of anaerobism bidirectional rotation membrane bioreactor for the treatment of livestock breeding wastewater according to claim 1, it is characterized in that: bidirectional rotation membrane module has the outlet of fluid inlet, filtrate outlet and rework solution, fluid inlet and rework solution outlet are positioned at the same side of bidirectional rotation membrane module, fluid inlet is positioned at the below of rotating membrane, rework solution outlet is positioned at the top of rotating membrane, and filtrate outlet is positioned at the below of rotating machine.
6., for the treatment of an operation method for the anaerobism bidirectional rotation membrane bioreactor of livestock breeding wastewater, it is characterized in that: comprise the following steps:
The first step, the waste water in inlet chest is delivered to anaerobic reactor by water inlet peristaltic pump;
Second step, waste water fully mixes with the anaerobic sludge in anaerobic reactor and degrades, temperature 30 ~ 35 ° of C in anaerobic reactor, hydraulic detention time 1.6 ~ 3.3d, operating load 0.4 ~ 3.5kgCODm -3d -1;
3rd step, the mud mixed liquid in anaerobic reactor is delivered to constant water bath box by circulation peristaltic pump and carries out temperature control, makes mud mixed liquid temperature control at 30 ~ 35 DEG C;
4th step, is delivered to bidirectional rotation membrane module by mud mixed liquid;
5th step, aspirates 8min at the every 10min of film water outlet suction frequencies; Membrane flux 12.0 ~ 26.8Lm -2h -1; Film rotary rpm 150rpm; Under the condition of bidirectional rotation cycle 0.5h, by the forward and reverse bidirectional rotation of reaction center transmission shaft driven rotary diaphragm of rotating machine in bidirectional rotation membrane module, produce filtrate and thickened sludge mixed solution, filtrate enters in center driving axle through rotating membrane and is sucked out under the suction effect of water outlet peristaltic pump; The thickened sludge mixed solution conveying that tunicle retains is back to anaerobic reactor.
CN201510712197.6A 2015-10-28 2015-10-28 Anaerobic bidirectionally-rotatable membrane bioreactor used for treating livestock and poultry breeding wastewater and operation method thereof Pending CN105236684A (en)

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Application publication date: 20160113