CN105235302B - A kind of bistable state merges carbon fibre reinforced composite - Google Patents

A kind of bistable state merges carbon fibre reinforced composite Download PDF

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Publication number
CN105235302B
CN105235302B CN201510752263.2A CN201510752263A CN105235302B CN 105235302 B CN105235302 B CN 105235302B CN 201510752263 A CN201510752263 A CN 201510752263A CN 105235302 B CN105235302 B CN 105235302B
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under
ratio
manufacturing mode
ratio manufacturing
fiber
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CN105235302A (en
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赵中元
邱菁
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QINGDAO ASIDUN ENGINEERING TECHNOLOGY TRANSFER CO., LTD.
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Qingdao Asidun Engineering Technology Transfer Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/12Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by the relative arrangement of fibres or filaments of different layers, e.g. the fibres or filaments being parallel or perpendicular to each other
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/106Carbon fibres, e.g. graphite fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion

Abstract

The present invention provides a kind of bistable state fusion carbon fibre reinforced composite, is formed by being arranged alternately carbon fiber and glass fibre, and there are two types of form, i.e. carbon fiber yarn and glass fiber yarn first presses 1 in the same plane:1 or 3:1 rule is alternately arranged, and warp knitting machine weaves into knitted fabric, according to original 1 in another plane of one fiber thickness distance of distance:1 or 3:1 rule weaves one layer of knitted fabric again, while ensures that the carbon fiber in same plane and glass fibre are mutually parallel, and is mutually perpendicular in two planes, then forms a kind of bistable special structure form.Preparation method is that above-mentioned two layers of the knitted fabric that will have been arranged is evenly distributed with, and composite material is made using thermoplastic precasting process, and curing process is 1 minute lower for 167 degrees Celsius, and temperature declines solidify afterwards shaping, and the resin used is polypropylene PP (Polypropylene;Polypropene) 147 curing agent, quality proportioning 100:28.

Description

A kind of bistable state merges carbon fibre reinforced composite
Technical field
The present invention provides a kind of bistable state fusion carbon fibre reinforced composite, belongs to carbon fibre composite field.
Background technology
In composite material large family, fibre reinforced materials is always focus of concern.From glass fibre with it is organic Since the fiberglass of resin compounded comes out, the composite material of carbon fiber, ceramic fibre and boron fibre enhancing is succeeded in developing in succession, Performance is continuously available improvement, its field of compound material is made to show one vitality.
Carbon fiber can be processed into fabric, felt, seat, band, paper and other materials.Carbon fiber, which removes, in traditional use is used as adiabatic protect It outside adiabator, is not used alone generally, is mostly added to as reinforcing material in the materials such as resin, metal, ceramics, concrete, structure Into composite material.The composite material of fibre reinforced can be used as aircraft construction material, electromagnetic shielding except electric material, artificial ligament etc. Body substitute material and for manufacturing rocket envelope, power ship, industrial robot, leaf springs of car and drive shaft etc..
The content of the invention
In view of the above-mentioned problems, the present invention provides a kind of bistable state fusion carbon fibre reinforced composite, there are two special for tool Different form stable has huge application prospect for fields such as military affairs, aerospace, ground observations.
The technology path that the present invention uses for:
A kind of bistable state merges carbon fibre reinforced composite, and state (i.e. the first stable state) is put in material volume rolling with composite material Material volume axis for lateral shaft, using the pipe axis of composite material extended state (i.e. the second stable state) in a tubular form as longitudinal axis, including: The first manufacture form, 1:Horizontal carbon fiber under 1 ratio manufacturing mode, 1:Horizontal glass fibre under 1 ratio manufacturing mode, 1:1 Longitudinal carbon fiber under ratio manufacturing mode, 1:Longitudinal glass fibre under 1 ratio manufacturing mode, 1:Base to be added is needed under 1 ratio Material one;Second of manufacture form, 3:Horizontal carbon fiber under 1 ratio manufacturing mode, 3:Horizontal glass under 1 ratio manufacturing mode Fiber, 3:Longitudinal carbon fiber under 1 ratio manufacturing mode, 3:Longitudinal glass fibre under 1 ratio manufacturing mode, 3:It is needed under 1 ratio The host material two of addition, it is characterised in that:1:Under 1 ratio manufacturing mode, 1:Under 1 ratio manufacturing mode horizontal carbon fiber and 1:Horizontal glass fibre is alternately arranged in proportion in the same plane under 1 ratio manufacturing mode, and keeps being mutually parallel, and 1:1 ratio Longitudinal carbon fiber and 1 under example manufacturing mode:Longitudinal glass fibre is apart from upper one fiber thickness of a plane under 1 ratio manufacturing mode Another plane of degree is alternately arranged in proportion, and keeps being mutually parallel, while must ensure that the filament between two planes interlocks Vertically, while in the bottom 1 is added:Need host material one to be added under 1 ratio, above-mentioned up of three layers one 1:1 ratio system Make unit;3:Under 1 ratio manufacturing mode, 3:Horizontal carbon fiber and 3 under 1 ratio manufacturing mode:Under 1 ratio manufacturing mode laterally Glass fibre is alternately arranged in proportion in the same plane, and keeps being mutually parallel, and 3:Longitudinal carbon fiber under 1 ratio manufacturing mode With 3:Longitudinal glass fibre replaces in proportion in another plane apart from upper one fiber thickness of a plane under 1 ratio manufacturing mode Arrangement, and keep being mutually parallel, while must ensure the filament serrated vertical between two planes, while add 3 in the bottom: Need host material two to be added under 1 ratio, above-mentioned up of three layers one 3:1 ratio manufacturing cell;
Further, it is the needs of realization material manufacture performance, described 1:Host material one to be added is needed under 1 ratio With 3:Host material to be added is needed under 1 ratio second is that including fragrant adoption fiber, gold using thermoplastic matrix material and addition Belong to the reinforcing fiber of fiber, high density polyethylene (HDPE) series fiber and polymer, including polypropylene fibre, polyester, polyethersulfone resin, poly- Ether ether ketone, Fypro, polyethylene-based, including thermoplastic carbamate thermoplastic matrix material;
Further, for produce proper strength requirement material body, the composite material be by several 1:1 ratio Example manufacturing cell or 3:1 ratio manufacturing cell is formed by stacking.
A kind of bistable state merges carbon fibre reinforced composite, and manufacturing process is:By carbon fiber yarn and glass fiber yarn Proportionally, using different radicals of entrying, warp knitting machine is made into knitted fabric, at the same be maintained in knitted fabric carbon fiber yarn and The equivalent width of glass fiber yarn;Above-mentioned two layers of the knitted fabric arranged is evenly distributed with, composite wood is made using thermoplastic precasting process Material, curing process is 1 minute lower for 167 degrees Celsius, and temperature declines solidify afterwards shaping, and the resin used is polypropylene PP (Polypropylene;Polypropene) 147 curing agent, quality proportioning 100:28.
A kind of bistable state merges carbon fibre reinforced composite, and two kinds of stable states can be reached after manufacture:One kind is composite material State (i.e. the first stable state) is put in material volume rolling, two kinds are composite material extended state (i.e. the second stable states) in a tubular form, and two kinds steady Nature transition is connected between state;Also, composite material is put to stablize in state (i.e. the first stable state) in material volume rolling stores certain energy, Making composite material that can be automatically changeb to composite material after being unfolded under the action of storing energy, (i.e. second is steady for extended state in a tubular form State), and the release of this process storing energy is gentle, will not generate explosive energy release;Meanwhile extend in a tubular form in composite material Under state (i.e. the second stable state), material can be crushed, and be wound into composite material and put state (i.e. the first stable state) in material volume rolling, Smoothly storing energy puts state (i.e. the first stable state) inside in composite material in material volume rolling simultaneously.
The present invention has the following advantages:
1st, following shortcoming and the danger of the element or product of the production of similar technique scheme are overcome
(1), in tubular-type, do not possess thicker, more powerful prestressing force.
(2), the potential energy for being stored in bending apparatus is huge, it may occur that explosion danger.
(3), normal use, when it is released from curved, this element also danger close, it may be with the speed of explosive Rate returns to tubulose.
2nd, the element in material forms a base layer structure, this mechanism is full of elasticity, in this case, the fibre of element Thin hollow form and situation about being compressed are reversible.
3rd, generation potential energy can be resisted under this compression environment or even it should be eliminated.Because this energy is not only Strong element can be made to be stored securely under bending environment, the form of elongated hollow with these elements of safe release, can be formed.
4th, under the form of elongated hollow, enough hard of material supports oneself.Therefore, element can be from compression stroke The length of requirement is promptly extended to, extension illustrates structuring hardness, is truly realized flexible fully merging with hardness.
5th, the fiber that material is implanted into itself is wrapped covering, not only securely and reliably, increase service life, but also save space, make It is easy with replacing, it is significant to long distance construction application and miniature precision equipment.
Description of the drawings
Fig. 1 is the present invention 1:Structure diagram under 1 ratio modeling.
Fig. 2 is the present invention 3:Structure diagram under 1 ratio manufacturing mode.
Fig. 3 is two kinds of stable state schematic diagrames of the material of the present invention.
Drawing reference numeral:1-1:Horizontal carbon fiber under 1 ratio manufacturing mode;2-1:Horizontal glass fibers under 1 ratio manufacturing mode Dimension;3-1:Longitudinal carbon fiber under 1 ratio manufacturing mode;4-1:Longitudinal glass fibre under 1 ratio manufacturing mode;5-1:Under 1 ratio Need host material one to be added;6-3:Horizontal carbon fiber under 1 ratio manufacturing mode;7-3:Horizontal glass under 1 ratio manufacturing mode Glass fiber;8-3:Longitudinal carbon fiber under 1 ratio manufacturing mode;9-3:Longitudinal glass fibre under 1 ratio manufacturing mode;10-3:1 ratio Host material two to be added is needed under example;11- composite materials put state (i.e. the first stable state) in material volume rolling;12- composite materials are in Tubular extension state (i.e. the second stable state).
Specific embodiment
As shown in Figure 1 to Figure 3, a kind of bistable state fusion carbon fibre reinforced composite, is put with composite material in material volume rolling The material volume axis of state (i.e. the first stable state) 11 is lateral shaft, with composite material extended state (i.e. the second stable state) 12 in a tubular form Pipe axis is longitudinal axis, including:The first manufacture form, 1:Horizontal carbon fiber 1,1 under 1 ratio manufacturing mode:1 ratio manufactures mould Horizontal glass fibre 2,1 under formula:Longitudinal carbon fiber 3,1 under 1 ratio manufacturing mode:Longitudinal glass fibre under 1 ratio manufacturing mode 4,1:Host material 1 to be added is needed under under 1 ratio manufacturing mode;Second of manufacture form, 3:It is horizontal under 1 ratio manufacturing mode To carbon fiber 6,3:Horizontal glass fibre 7,3 under 1 ratio manufacturing mode:Longitudinal carbon fiber 8,3 under 1 ratio manufacturing mode:1 ratio Longitudinal glass fibre 9,3 under manufacturing mode:Host material 2 10 to be added is needed under 1 ratio, it is characterised in that:1:1 ratio Under manufacturing mode, 1:Horizontal carbon fiber 1 and 1 under 1 ratio manufacturing mode:Horizontal glass fibre 2 is same under 1 ratio manufacturing mode It is alternately arranged in proportion in plane, and keeps being mutually parallel, 1:Longitudinal carbon fiber 3 and 1 under 1 ratio manufacturing mode:1 ratio manufactures Longitudinal glass fibre 4 is alternately arranged in proportion in another plane apart from upper one fiber thickness of a plane under pattern, and is kept It is mutually parallel, while must ensure the filament serrated vertical between two planes, while 1 is added in the bottom:It is needed under 1 ratio The host material 1 of addition, above-mentioned up of three layers one 1:1 ratio manufacturing cell;3:Under 1 ratio manufacturing mode, 3:1 ratio Horizontal carbon fiber 6 and 3 under manufacturing mode:Horizontal glass fibre 7 replaces cloth in proportion in the same plane under 1 ratio manufacturing mode It puts, and keeps being mutually parallel, 3:Longitudinal carbon fiber 8 and 3 under 1 ratio manufacturing mode:Longitudinal glass fibre under 1 ratio manufacturing mode 9 are alternately arranged in proportion in another plane apart from upper one fiber thickness of a plane, and keep being mutually parallel, while must ensure Filament serrated vertical between two planes, while add 3 in the bottom:Host material 2 10 to be added is needed under 1 ratio, Above-mentioned up of three layers one 3:1 ratio manufacturing cell;
Further, it is the needs of realization material manufacture performance, described 1:Host material one to be added is needed under 1 ratio 5 and 3:Needed under 1 ratio host material 2 10 to be added be using thermoplastic matrix material and addition include fragrance adoption fiber, The reinforcing fiber of metallic fiber, high density polyethylene (HDPE) series fiber and polymer, including polypropylene fibre, polyester, polyethersulfone resin, Polyether-ether-ketone, Fypro, polyethylene-based, including thermoplastic carbamate thermoplastic matrix material;
Further, for produce proper strength requirement material body, the composite material be by several 1:1 ratio Example manufacturing cell or 3:1 ratio manufacturing cell is formed by stacking.
A kind of bistable state merges carbon fibre reinforced composite, and manufacturing process is:By carbon fiber yarn and glass fiber yarn Proportionally, using different radicals of entrying, warp knitting machine is made into knitted fabric, at the same be maintained in knitted fabric carbon fiber yarn and The equivalent width of glass fiber yarn;Above-mentioned two layers of the knitted fabric arranged is evenly distributed with, composite wood is made using thermoplastic precasting process Material, curing process is 1 minute lower for 167 degrees Celsius, and temperature declines solidify afterwards shaping, and the resin used is polypropylene PP (Polypropylene;Polypropene) 147 curing agent, quality proportioning 100:28.
A kind of bistable state merges carbon fibre reinforced composite, and two kinds of stable states can be reached after manufacture:One kind is composite material State (i.e. the first stable state) 11 is put in material volume rolling, two kinds are composite material extended states (i.e. the second stable state) 12, and two in a tubular form Nature transition is connected between kind stable state;Also, composite material is put in material volume rolling stablizes storage one in state (i.e. the first stable state) 11 It surely measures, makes composite material that can be automatically changeb to composite material extended state in a tubular form under the action of storing energy after being unfolded (i.e. the second stable state) 12, and the release of this process storing energy is gentle, will not generate explosive energy release;Meanwhile in composite wood In a tubular form under extended state (i.e. the second stable state) 12, material can be crushed material, and be wound into composite material and put shape in material volume rolling State (i.e. the first stable state) 11, while smoothly storing energy is put in material volume rolling in state (i.e. the first stable state) 11 in composite material Portion.
The application of this material:
1st, integrated design
This material can be showed with a kind of material steel structure simultaneously, flintiness and curvature be had both, so that entirely may be used Winding part becomes a sturdy firm workbench;And can fast and stable formed one without using any additional components While, you can it solves the problems, such as extension and compression, stable and shaping, directly can be changed into another work from a kind of kenel Make kenel.Such as:Antenna equipment is implanted into ATS, communication wire bar can carry, maintenance is with use directly as antenna Become at quarter fast and simple.
2nd, more materials combine
This material can be with optical fiber, cable, and a variety of materials such as antenna and chemical fibre are combined together, can after being implanted into product Increase various functions, realize different attribute superposition.This technology can enable control circuit built in robot arm, accurate to complete Distal end is precisely controlled, and there is no circuit partitioning problems, it is not required that additionally mounted.If accessing visual fiber, then can realize Data transmission, the environment around accurate judgement, without additionally connecting up and can be substantially improved after extension visual range.
3rd, high-performance special fiber
This material working range is not affected by temperature from the Sahara to the Arctic Circle, can be embedded in concrete, anaerobic, high spoke In the space environment penetrated, even if being also applied for the outer space --- in dangerous liquid environment, also response lag, and extremely ring It protects.ATS very fast can produce for storage physical space or be extended into various body of unlimited length.Based on its shape There is significant anisotropy, softness, extremely light, it is easy to which the scheme according to engineers design such as is welded, be bonded at the techniques It is performed.It as antifatigue, corrosion-resistant, rub resistance material, can more apply in oil-gas pipeline, detection is completed by sensing Monitoring task.

Claims (3)

1. a kind of bistable state merges carbon fibre reinforced composite, state (i.e. the first stable state) is put in material volume rolling with composite material (11) material volume axis be lateral shaft, using composite material in a tubular form extended state (i.e. the second stable state) (12) pipe axis as longitudinally Axis, including:The first manufacture form, 1:Horizontal carbon fiber (1) under 1 ratio manufacturing mode, 1:Horizontal glass under 1 ratio manufacturing mode Glass fiber (2), 1:Longitudinal carbon fiber (3) under 1 ratio manufacturing mode, 1:Longitudinal glass fibre (4) under 1 ratio manufacturing mode, 1:1 Host material one (5) to be added is needed under ratio manufacturing mode;Second of manufacture form, 3:Horizontal carbon under 1 ratio manufacturing mode Fiber (6), 3:Horizontal glass fibre (7) under 1 ratio manufacturing mode, 3:Longitudinal carbon fiber (8) under 1 ratio manufacturing mode, 3:1 ratio Longitudinal glass fibre (9) under example manufacturing mode, 3:Host material two (10) to be added, feature are needed under 1 ratio manufacturing mode It is:1:Under 1 ratio manufacturing mode, 1:Horizontal carbon fiber (1) and 1 under 1 ratio manufacturing mode:It is horizontal under 1 ratio manufacturing mode It is alternately arranged in proportion in the same plane to glass fibre (2), and keeps being mutually parallel, 1:Longitudinal direction under 1 ratio manufacturing mode Carbon fiber (3) and 1:Longitudinal glass fibre (4) is apart from the another flat of upper one fiber thickness of a plane under 1 ratio manufacturing mode Face is alternately arranged in proportion, and keeps being mutually parallel, while must ensure the filament serrated vertical between two planes, while Bottom addition 1:Need host material one (5) to be added under 1 ratio, above-mentioned up of three layers one 1:1 ratio manufacturing cell; 3:Under 1 ratio manufacturing mode, 3:Horizontal carbon fiber (6) and 3 under 1 ratio manufacturing mode:Horizontal glass fibers under 1 ratio manufacturing mode Dimension (7) is alternately arranged in proportion in the same plane, and keeps being mutually parallel, and 3:Longitudinal carbon fiber (8) under 1 ratio manufacturing mode With 3:Under 1 ratio manufacturing mode longitudinal glass fibre (9) in another plane apart from upper one fiber thickness of a plane in proportion It is alternately arranged, and keeps being mutually parallel, while must ensure the filament serrated vertical between two planes, while add in the bottom Add 3:Need host material two (10) to be added under 1 ratio, above-mentioned up of three layers one 3:1 ratio manufacturing cell;Above-mentioned 1:1 Ratio and 3:The concrete meaning of 1 ratio refers to that the number ratio of carbon fiber and glass fibre is 1 in approximately the same plane:1 and 3: 1。
2. a kind of bistable state fusion carbon fibre reinforced composite as described in claim 1, it is characterised in that:Described 1:1 Host material one (5) to be added and 3 are needed under ratio:It is to use thermoplasticity that host material two (10) to be added is needed under 1 ratio Host material and addition include the reinforcing fiber of metallic fiber, high density polyethylene (HDPE) series fiber and polymer, fine including polypropylene Dimension, polyester, polyethersulfone resin, polyether-ether-ketone, Fypro, polyethylene-based, including thermoplastic carbamate thermoplasticity Host material.
3. a kind of bistable state fusion carbon fibre reinforced composite as described in claim 1, it is characterised in that:Described is compound Material be by several 1:1 ratio manufacturing cell or 3:1 ratio manufacturing cell is formed by stacking.
CN201510752263.2A 2015-11-06 2015-11-06 A kind of bistable state merges carbon fibre reinforced composite Active CN105235302B (en)

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CN106189234A (en) * 2016-07-13 2016-12-07 温州雏鹰科技有限公司 A kind of high intensity unmanned plane propeller and preparation technology thereof
CN108125731A (en) * 2017-12-26 2018-06-08 复旦大学附属华山医院 Ankle-joint artificial ligament
US11440287B2 (en) 2018-06-07 2022-09-13 Honeywell International Inc. Hybrid fiber multi-axial prepreg
CN109968749B (en) * 2019-04-08 2021-03-05 浙江大学 Prestressed bistable multi-layer composite material and preparation method and application thereof
CN110165362B (en) * 2019-05-24 2021-02-09 北京遥测技术研究所 Portable composite material short wave whip antenna device

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