CN105233988B - Semi-wet electrostatic dust collector - Google Patents

Semi-wet electrostatic dust collector Download PDF

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Publication number
CN105233988B
CN105233988B CN201510593461.9A CN201510593461A CN105233988B CN 105233988 B CN105233988 B CN 105233988B CN 201510593461 A CN201510593461 A CN 201510593461A CN 105233988 B CN105233988 B CN 105233988B
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China
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methylimidazole
plate type
dust collecting
type dust
circular plate
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CN105233988A (en
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刘海弟
李伟曼
李文辉
马翔
陈运法
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Institute of Process Engineering of CAS
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Institute of Process Engineering of CAS
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y02A50/2351Atmospheric particulate matter [PM], e.g. carbon smoke microparticles, smog, aerosol particles, dust

Abstract

The invention discloses a semi-wet electrostatic dust collector and belongs to the technical fields of dust removal, waste gas treatment and environment protection. According to the semi-wet electrostatic dust collector, dust in airflow is charged firstly by means of a pre-charger, and then the airflow is made to flow through round plate type dust collecting electrodes which are vertically arranged in parallel; the lower half portions of the round plate type dust collecting electrodes are soaked in electrolyte solutions; the round plate type dust collecting electrodes rotate continuously under the action of a transmission shaft; the disc surfaces of every two adjacent round plate type dust collecting electrodes are soaked in two separated solution grooves respectively, and the electrolyte water solutions in every two adjacent solution grooves are loaded with voltages with different electric potentials respectively; liquid films exist on the solution grooves continuously along with the continuous rotation of the round plate type dust collecting electrodes, and the round plates with different electric potentials are used for adsorbing dust with different chargers respectively and eluting the adsorbed dust into the electrolyte water solutions continuously. The semi-wet electrostatic dust collector is high in dust removing efficiency, air resistance is quite small, and the semi-wet electrostatic dust collector is extremely suitable for indoor air purification.

Description

A kind of half wet cottrell
Technical field
The present invention relates to a kind of half wet cottrell, belongs to electric precipitation, waste gas pollution control and treatment and environmental protection technical field.
Background technology
With China's rapid development of economy, China big and medium-sized cities, developed area and basic industries close quarters Gray haze air pollution is day by day serious.As China is for SOx and the restriction of NOx emission strict, related green technology and dress increasingly Put and constantly come into operation, the gross contamination emission amplification of SOx and NOx slows down in China's atmospheric environment, however, from current prison Survey result to see, the gray haze pollution of each section of China's Yangtze River Delta, Pearl River Delta and Jing-jin-ji region is on the rise on the contrary, is seriously threatened The healthy and economic sustainable development of the common people.With tracing to the source the going deep into of research currently for gray haze pollution, Ren Menyi It has been observed that PM10 granules share day by day reduces in China Brownish haze, PM2.5 even PM1.0 granules are greatly increased, these Granule comes from VOCs, NOx and SO mostly2Multiple discharge coupling, its extinction capability is strong, toxicity is big, has become me State's air environmental pollution problem the most serious.
It is related to numerous pollution industries due to administering industrial gases discharge, its difficulty of governance is very big, therefore many experts Think, the change of atmospheric air quality needs just see within 10 years improvement at least, therefore, the purification to room air becomes at present The most effective and most direct means of protection Chinese health of human body.
For indoor air purification except haze scheme is typically chosen HEPA filter membranes, this is a kind of very efficient air mistake Filter material material, it might even be possible to remove the subparticle of below PM1.0, is current most ripe also most widely used purification of air side Method, however, the shortcoming of this method is also it will be apparent that the air drag of HEPA films is very big, therefore it is enough in order to obtain Air quantity, HEPA are generally required and are equipped with larger blower fan, this results in bigger power consumption and noise;Additionally, HEPA is effectively being filtered After dust granules, the antibacterial for being attached to dust granules surface in a large number also can be in HEPA surface colonizations, therefore HEPA must be periodically Change, the region serious for air pollution, the life-span of HEPA are very short, and this all brings higher cost.
The technology that indoor air purification is carried out using the scheme of electric precipitation also has certain application, and the technical scheme imitates work The device of industry electric precipitation:First granule in air-flow is carried out using corona discharge electrode charged, electrically contrary dust collector pole is recycled to granule Caught.The method is due to no any filtration material, therefore vapour lock is very low, it is easy to realize the air-treatment of Wind Volume, But its shortcoming is also apparent:First, in this method, corona discharge electrode has the possibility for producing ozone secondary pollution;Second, single area Electric field has been proved to very poorly efficient for PM2.5 and following granule;3rd, multi-region electric field is proved to for sticky particles (such as Smoke from cigarette) there is certain effect, but for dry subparticle effect on driving birds is not good, main cause is subparticle load electric charge Amount is few, and easily loses electric charge and leave dedusting pole, therefore the single technical scheme using common electric precipitation is difficult to room In interior air, subparticle is sufficiently cleaned up.
Wet-esp is to be developing progressively a ripe novel dust removing technology on the basis of dry electric precipitation, the technology with It is the moisture film for forming a laminar flow by the method for overflow or spraying in dust collecting electrode plate face where dry electric precipitation difference, appoints What reaches the granule on dust collector pole surface because of electrostatic force all can be caught by moisture film, in this way greatly improve electricity and remove Dust collecting method is for the seizure effect of subparticle.Yet with high-pressure electrostatic is equally used, so between corona discharge electrode and dust collector pole Must be spaced sufficiently large, both arrangement is also particular about very much, with the accident for avoiding electrical breakdown.Therefore this technical scheme exists Application is not still obtained to equipment volume and the extreme harsh domestic air purification field of security requirement.
It is also a kind of technical scheme for having put into application that the granule in room air is removed using the method for washing, the program It is to blow air over larger wetted surface, by particle adhesion therein on a solid surface, then the method general by washing Grain is removed.This scheme has certain effect for larger dust granule, fiber and pollen, but in current China's air PM2.5 even particles below is then very poorly efficient, because these subparticles are very good with air flow property, using inertial separation Method can hardly be removed.
Spraying washing is also the alternative for removing subparticle in room air, and the program is that water is sprayed mist with nozzle Change, the little droplet of atomization to and particulate matter therein is caught during air contact, finally by demisting by air Grain thing is removed.Rainfall in the much like natural atmosphere of this method disappears the process of haze, but its shortcoming is also clearly:First, it is this Method needs to use nozzle, needs the liquid or gas of certain pressure, and this can bring extra equipment investment, also bring certain Noise;Second, this method can cause the problem of room air " excessively humidifying ", can make one to feel not in humidity higher rainy season It is suitable;3rd, the washings for spraying are often common tap water, for the water more containing mineral, meeting of spraying Water evaporates are forced, is caused water mineral to be changed into the dust granules in air, is increased indoor accelerated test concentration.
The present inventor is it has been suggested that remove in air by the use of bottom rotary turnplate submerged in water as dust collecting electrode The technical scheme (CN201410104461.3) of subparticle, the technical scheme are made using the moisture film of rotating disc surfaces For the medium that gathers dust, dried dust and sticky dust can be effectively fixed, granule easily loses electricity in solving common electric cleaner Lotus and the problem escaped, but the technical scheme also has its obvious defect:Each turn in technical scheme CN201410104461.3 Disk is same potential, can only catch load this granule with dust collecting electrode opposite charges, however, when dust granules are very tiny When, its charging mechanism will be leading from electric-field charge for the leading diffusional charging that is changed into, and the effect of diffusional charging does not have significantly Electric charge selectivity, therefore whether positive corona or negative corona, dust granules will be by load positive electricity and negative electricity simultaneously, and this causes Dust granules removal effect of the technical scheme disclosed in CN201410104461.3 for less than 1.5 microns is less than 80%.
Make a general survey of all these technologies, China's room air is except haze field urgently a kind of low vapour lock, high flux, low noise, no The high-effective dust-removing technical scheme of component need to be changed.
The content of the invention
It is an object of the invention to obtained by a kind of simple method fill with low vapour lock, high-throughout high-effective dust-removing Put.The device possesses the advantage of wet static dedusting, at the same it is simple, liquid dispensing apparatus will not be introduced, is appointed without changing What component, need to only regularly replace aquiform stool in water tank can, will not also occur in addition to humidify excessive situation.
The purpose of the present invention is realized by the following technical solutions:Make dust-laden air flow through be mounted with corona discharge electrode and The pre electrified electric field of dust collector pole, then makes air flow through horizontally arranged vertical circular plate type dust collecting electrode, the number of circular plate type dust collecting electrode , than or equal to 2 pieces, the card of circular plate type dust collecting electrode is parallel with air flow, and the latter half of circular plate type dust collecting electrode is immersed in for amount In aqueous solution containing electrolyte, circular plate type dust collecting electrode is placed on a trunnion axis at the same distance, and trunnion axis is by circle The center of circle of board-like dust collecting electrode, trunnion axis are made circular plate type dust collecting electrode constantly rotate, and are kept circular plate type dust by a Motor drive Extremely aerial surface has one layer of electrolyte aqueous solution film, the lower half sub-dip of the adjacent disc of circular plate type dust collecting electrode all the time Not in two not connected electrolyte aqueous solution liquid baths, with reciprocal bent in a zigzag between the two electrolyte aqueous solution liquid baths The dividing plate of folding is separated, and two electrolyte aqueous solution liquid baths distinguish load zero potentials and positive potential or zero potential and negative electricity Gesture, also load is water-soluble with institute submergence electrolyte to make to be immersed in the electrolyte aqueous solution film of circular plate type dust collecting electrode disc surface therein Liquid identical potential, so that horizontally arranged circular plate type dust collecting electrode presents the form that high and low potential is back and forth arranged, circular plate type collection A diameter of 5cm~100cm of dirt pole, the spacing of circular plate type dust collecting electrode is 0.8cm~10cm, circular plate type dust collecting electrode and electrode drive Trunnion axis between have electrically insulating washer, to realize the electric insulation between trunnion axis and circular plate type dust collecting electrode, from circular plate type collection Charged particle in the air flow through between dirt pole can be attracted and be attached to circular plate type dust collecting electrode table because of the effect of electrostatic force In the electrolyte aqueous solution liquid film in face, and come off by electrolyte aqueous solution washing with the rotation of circular plate type dust collecting electrode.
This air dedusting purifier is further characterized in that:The charged voltage of the pre electrified electric field of depurator front end be 3~ 20kV, the corona extremely round silk of 0.1~1mm of nominal diameter, astroid, helix, die opening are 0.5~10cm;Circular plate type collection The material of dirt pole is rustless steel, steel, ferrum, aluminum and the aluminium alloy of surface granosealing;The material of circular plate type dust collecting electrode can also be Surface does not have the sieve and silica-sesquioxide ceramics of glaze layer, cordierite ceramic, mullite ceramic, SiC ceramic, aluminium oxide ceramics, feldspathic Ceramics, Apatite Ceramic;The material of circular plate type dust collecting electrode or the polrvinyl chloride of surface hydrophilic modification, poly-methyl methacrylate Ester, polypropylene, polyethylene, polyethylene terephthalate, polyformaldehyde, Merlon, phenolic resin or acrylic nitrile-butadiene two Alkene-polyglass;The rotating speed of circular plate type dust collecting electrode is 1rpm~100rpm;The electrolyte of adjacent circular plate type dust collecting electrode institute submergence Solution distinguishes load zero potential and high potential or zero potential and low potential, and the voltage of high potential is+3~+20kV, low potential Voltage is -3~-20kV.
The electrolyte aqueous solution for irrigating in the sink is the aqueous solution of antibacterial, and antibacterial is trimethyl bromination Ammonium, Dodecyl trimethyl ammonium chloride, Tetradecyl Trimethyl Ammonium Bromide, tetradecyl trimethyl ammonium chloride, cetyl three Methyl bromide ammonium, hexadecyltrimethylammonium chloride, Cetyltrimethylammonium bromide, octadecyl trimethyl ammonium chloride, three Chlorine life, chlorhexidine acetate, benzalkonium bromide, benzalkonium chloride, potassium sorbate, sodium pyrithione, Zinc Pyrithione, copper pyrithione, 1-ethyl-3-methyllimidazolium bromide, iodate 1- ethyl-3-methylimidazoles, bromination 1- propyl group -3- Methylimidazole .s, iodate 1- propyl group - 3- Methylimidazole .s, chlorination 1- butyl -3- Methylimidazole .s, 1-butyl-3-methylimidazolium bromide, iodate 1- butyl -3- Methylimidazole .s, Chlorination 1- hexyl -3- Methylimidazole .s, bromination 1- hexyl -3- Methylimidazole .s, iodate 1- hexyl -3- Methylimidazole .s, chlorination 1- octyl groups - 3- Methylimidazole .s, bromination 1- octyl group -3- Methylimidazole .s, iodate 1- hexyl -3- Methylimidazole .s, chlorination 1- decyl -3- Methylimidazole .s, Bromination 1- decyl -3- Methylimidazole .s, iodate 1- decyl -3- Methylimidazole .s, chlorination 1- benzyl -3- Methylimidazole .s, bromination 1- benzyl - 3- Methylimidazole .s, iodate 1- benzyl -3- Methylimidazole .s, chlorination 1- dodecyl -3- Methylimidazole .s, bromination 1- dodecyl -3- Methylimidazole., iodate 1- dodecyl -3- Methylimidazole .s, chlorination 1- myristyl -3- Methylimidazole .s, bromination 1- myristyl - 3- Methylimidazole .s, iodate 1- myristyl -3- Methylimidazole .s, chlorination 1- cetyl -3- Methylimidazole .s, bromination 1- hexadecane Base -3- Methylimidazole .s, iodate 1- cetyl -3- Methylimidazole .s, chlorxylone, DBDMH, bromine chlorine hydantoin, dichloro sea Because of any one in the middle of, 5,5- dimethyl hydantion or the mixture of arbitrarily several arbitrary proportions.
Air dedusting purifier disclosed in this invention, no any filtering material, its vapour lock very little, simultaneously because circle Board-like dust collecting electrode the latter half is immersed under electrolyte aqueous solution liquid level, and circular plate type dust collecting electrode is constantly rotated, it is ensured that Circular plate type dust collecting electrode constantly has moisture film to cover, so as to efficiently catch dust granules, in addition, the dust granules being captured can justified It is washed in tank, for nitrate granules common in current air, sulphuric acid when board-like dust collecting electrode is rotated to liquid level Salt particle, ammonium salt granule all can be dissolved in the aqueous solution in tank immediately, it is to avoid which is escaped and is again introduced in air-flow.This Outward, as the aqueous solution in tank contains antibacterial, the antibacterial for being attached to dust granules surface can be effectively killed, is carried to room For cleaning and the air of bio-safety, and algae will not be produced during antimicrobial can ensure that tank, be easy to grow on antibacterial Raw season will not also produce abnormal flavour and go bad.In the winter time influenza multiple season, a small amount of Tamiflu can be dissolved in water In groove, the risk of population infection influenza in room can be so reduced.
Description of the drawings
In order that the technical program becomes apparent from, list five accompanying drawings and further elucidated with being given.Wherein, Fig. 1 is one Plant front view, top view, dorsal view, side view and two profiles of cleaner unit design;Technical sides of the Fig. 2 for Fig. 1 The solid of case disassembles oblique view;Fig. 3 is a kind of detailed construction schematic diagram of pre electrified electric field;Fig. 4 is a kind of separation side of liquid bath Formula schematic diagram;Fig. 5 is that the solid of the cleaner unit of another kind of difference liquid bath diaphragm structure design disassembles oblique view.
A kind of design of the apparatus module is as shown in figure 1, in Fig. 1, rear views of the A for device, B are the side of device View, C for device front view, D for device top view, E be device B figures in along I I to profile, F be device B figure It is middle along II II to profile, the numeral mark meaning in each figure is as follows:1:Device top cover, 2:Device box, 3:Gas outlet, 4:Circular plate type dust collecting electrode, 5:U-shaped overfall (for the liquid level of a liquid bath in control chamber body), 6:U-shaped overfall (is used for The liquid level of another liquid bath in control chamber body), 7:Dividing plate (for splitting two liquid baths with different potentials), (two U Type overfall is under the jurisdiction of two different liquid baths, and the peak of overfall 1~2cm lower than casing internal partition peak respectively, Can so prevent from adding during liquid feeding overfill and cause two liquid baths connections being mutually separated), 8:Air inlet, 9:Pre electrified electricity The collecting plate of field, 10:The corona discharge electrode of pre electrified electric field, 11:Filling opening (for a liquid bath liquid feeding in casing), 12:Liquid feeding Mouthful (for another liquid bath liquid feeding in casing), two filling openings finish rear enclosed in order to avoid gas leakage in operating process in liquid feeding, 13:Motor, 14:Plate (has two pieces, for the space of sealed horizontal axle to casing upper limb), and 15:Electrode terminal is (for case The liquid applied voltage of an internal liquid bath), 16:Electrode terminal (applies electricity for the liquid to another liquid bath in casing Pressure), 17:Charge air flow, 18:Outlet air-flow, 19:Trunnion axis.
In order that the device represented by Fig. 1 is clearer, Fig. 2A and B sets forth this device from the oblique of rear and front Depending on installation diagram, device box, air inlet/outlet, the corona discharge electrode of pre electrified electric field and pole plate is mainly demonstrated by, in air intake installation casing The reciprocal dividing plate of zigzag, the assembly relation of multiple circular plate type dust collecting electrodes, plate and device top cover disposed on trunnion axis, wherein Numeral mark meaning it is identical with Fig. 1, for the sake of removing, Fig. 2 does not represent filling opening and electrode terminal.
Fig. 3 gives a kind of design pattern of pre electrified electric field, and the pattern adopts the board-like pre-load electric apparatus of line, but not to pre- The form of the composition of charge electric appliance is construed as limiting, and pre-load electric apparatus can also be spool formula, meanwhile, Fig. 3 pre- lotuses also not to the present invention The corona discharge electrode of electric field is electrically construed as limiting, and corona discharge electrode can also load negative electricity with load positive electricity.Fig. 3 emphasis gives placement The configuration of the pre electrified electric field in air inlet, wherein numeral mark meaning are identical with Fig. 1, and which 20 and 21 represents pre electrified respectively The high voltage power supply binding post of device.Wherein Fig. 3 A are the front view of the pre-load electric apparatus constructed in the middle of air inlet, and Fig. 3 B are to construct The dorsal view of the pre-load electric apparatus in the middle of air inlet, Fig. 3 C are the oblique view of the pre-load electric apparatus constructed in the middle of air inlet, and Fig. 3 D are The side view of the pre-load electric apparatus constructed in the middle of air inlet.Fig. 1,2,3 can not be to the quantity of the circular plate type dust collector pole of the present invention The configuration design of equipment box is construed as limiting.
In order to remove the distributed relation for representing two mutually different liquid baths in equipment box, Fig. 4 gives one kind The segmentation design of liquid bath, two wherein with different potentials kind liquid bath fill to distinguish by blank and two point horizontal line, Fig. 4 In also express the electrode terminal of two liquid baths, one of liquid bath is grounded (zero potential), and another liquid bath connects high-tension electricity The negative pole in source, in this case, the pre-load electric apparatus of front end should be positive corona, but this can not be to the electrode of the technical program Installation position and type of electrodes are construed as limiting, the pre-load electric apparatus of leading portion can also be negative corona, then rear end two is not connected One load zero potential (ground connection) of liquid bath, the positive pole of another connection high voltage power supply.Numeral mark meaning in Fig. 4 and Fig. 1 phases Together.
In the device liquid bath that Fig. 1,2,4 are given, the dividing plate form of two kinds of electrolyte aqueous solutions can not be to the technical program structure Into restriction, as long as ensureing that the adjacent plate of circular plate type dust collecting electrode can in being immersed in different electrical not connected different liquid baths So that Fig. 5 gives the design form of another kind of dividing plate, and this is designed with circular-arc bottom face design, it is also possible to complete this technology side The needs of case, as long as ensure that the adjacent plate of adjacent circular plate type dust collecting electrode is immersed in different electrical not connected different liquid Just can be so that the numeral mark meaning in Fig. 4 is identical with Fig. 1 in groove.
Specific embodiment
The purpose of the present invention is realized by the following technical solutions:Make dust-laden air flow through be mounted with corona discharge electrode and The pre electrified electric field of dust collector pole, then makes air flow through horizontally arranged vertical circular plate type dust collecting electrode, the number of circular plate type dust collecting electrode , than or equal to 2 pieces, the card of circular plate type dust collecting electrode is parallel with air flow, and the latter half of circular plate type dust collecting electrode is immersed in for amount In aqueous solution containing electrolyte, circular plate type dust collecting electrode is placed on a trunnion axis at the same distance, and trunnion axis is by circle The center of circle of board-like dust collecting electrode, trunnion axis are made circular plate type dust collecting electrode constantly rotate, and are kept circular plate type dust collecting electrode by a Motor drive Aerial surface has one layer of electrolyte aqueous solution film, the latter half submergence of the adjacent disc of circular plate type dust collecting electrode all the time In two not connected electrolyte aqueous solution liquid baths, with zigzag crippling between the two electrolyte aqueous solution liquid baths Dividing plate separate, two electrolyte aqueous solution liquid baths difference load zero potentials and positive potential or zero potential and negative potential, Make to be immersed in the electrolyte aqueous solution film of circular plate type dust collecting electrode disc surface therein also load and institute's submergence electrolyte aqueous solution Identical potential, so that horizontally arranged circular plate type dust collecting electrode presents the form that high and low potential is back and forth arranged, circular plate type dust A diameter of 5cm~100cm of pole, the spacing of circular plate type dust collecting electrode is 0.8cm~10cm, circular plate type dust collecting electrode and electrode drive There is electrically insulating washer, to realize the electric insulation between trunnion axis and circular plate type dust collecting electrode, from circular plate type dust between trunnion axis Charged particle in the air flow through between pole can be attracted and be attached to circular plate type dust collecting electrode surface because of the effect of electrostatic force Electrolyte aqueous solution liquid film in, and with circular plate type dust collecting electrode rotation and by electrolyte aqueous solution washing shed into electrolysis In matter aqueous solution.
This air dedusting purifier is further characterized in that:The charged voltage of the pre electrified electric field of depurator front end be 3~ 20kV, the corona extremely round silk of 0.1~1mm of nominal diameter, astroid, helix, die opening are 0.5~10cm;Circular plate type collection The material of dirt pole is rustless steel, steel, ferrum, aluminum and the aluminium alloy of surface granosealing;The material of circular plate type dust collecting electrode can also be Surface does not have the sieve and silica-sesquioxide ceramics of glaze layer, cordierite ceramic, mullite ceramic, SiC ceramic, aluminium oxide ceramics, feldspathic Ceramics, Apatite Ceramic;The material of circular plate type dust collecting electrode or the polrvinyl chloride of surface hydrophilic modification, poly-methyl methacrylate Ester, polypropylene, polyethylene, polyethylene terephthalate, polyformaldehyde, Merlon, phenolic resin or acrylic nitrile-butadiene two Alkene-polyglass;The rotating speed of circular plate type dust collecting electrode is 1rpm~100rpm;The electrolysis of adjacent circular plate type dust collecting electrode institute submergence Matter solution distinguishes load zero potential and high potential or zero potential and low potential, and the voltage of high potential is+3~+20kV, low potential Voltage be -3~-20kV.
The electrolyte aqueous solution for irrigating in the sink is the aqueous solution of antibacterial, and antibacterial is trimethyl bromination Ammonium, Dodecyl trimethyl ammonium chloride, Tetradecyl Trimethyl Ammonium Bromide, tetradecyl trimethyl ammonium chloride, cetyl three Methyl bromide ammonium, hexadecyltrimethylammonium chloride, Cetyltrimethylammonium bromide, octadecyl trimethyl ammonium chloride, three Chlorine life, chlorhexidine acetate, benzalkonium bromide, benzalkonium chloride, potassium sorbate, sodium pyrithione, Zinc Pyrithione, copper pyrithione, 1-ethyl-3-methyllimidazolium bromide, iodate 1- ethyl-3-methylimidazoles, bromination 1- propyl group -3- Methylimidazole .s, iodate 1- propyl group - 3- Methylimidazole .s, chlorination 1- butyl -3- Methylimidazole .s, 1-butyl-3-methylimidazolium bromide, iodate 1- butyl -3- Methylimidazole .s, Chlorination 1- hexyl -3- Methylimidazole .s, bromination 1- hexyl -3- Methylimidazole .s, iodate 1- hexyl -3- Methylimidazole .s, chlorination 1- octyl groups - 3- Methylimidazole .s, bromination 1- octyl group -3- Methylimidazole .s, iodate 1- hexyl -3- Methylimidazole .s, chlorination 1- decyl -3- Methylimidazole .s, Bromination 1- decyl -3- Methylimidazole .s, iodate 1- decyl -3- Methylimidazole .s, chlorination 1- benzyl -3- Methylimidazole .s, bromination 1- benzyl - 3- Methylimidazole .s, iodate 1- benzyl -3- Methylimidazole .s, chlorination 1- dodecyl -3- Methylimidazole .s, bromination 1- dodecyl -3- Methylimidazole., iodate 1- dodecyl -3- Methylimidazole .s, chlorination 1- myristyl -3- Methylimidazole .s, bromination 1- myristyl - 3- Methylimidazole .s, iodate 1- myristyl -3- Methylimidazole .s, chlorination 1- cetyl -3- Methylimidazole .s, bromination 1- hexadecane Base -3- Methylimidazole .s, iodate 1- cetyl -3- Methylimidazole .s, chlorxylone, DBDMH, bromine chlorine hydantoin, dichloro sea Because of any one in the middle of, 5,5- dimethyl hydantion or the mixture of arbitrarily several arbitrary proportions.Enumerate below several concrete Embodiment, to further understand the present invention:
Embodiment 1:
Using 3 diameter 0.2mm, length 20cm tinsel as corona discharge electrode, it is respectively placed in four leaf length 20cm width 8cm's Between dust collector pole, Technical Supervision Bureau 2cm makes pre electrified device, and corona discharge electrode connection high-voltage power cathode is set to 5000V, dust collector pole Plate earthing, is placed in the air inlet of cleaner unit, in the gas treatment case of cleaner unit, takes the aluminum disk of 10 a diameter of 20cm As circular plate type dust collecting electrode, it is fixed on a power transmission shaft, is driven shaft diameter 1cm, each disc is spaced 2cm, adjacent disc is placed in point In the different liquid baths for separating, it is 0.5% benzalkonium bromide solution in liquid bath, one of liquid bath ground connection, another liquid bath connect height Voltage source negative pole, voltage is 5000V, and the liquid level of liquid bath is less than demarcation strip upper limb 1cm, circular plate type dust collecting electrode rotating speed 10rpm, just obtains The electrostatic dedusting purifier is obtained, smoke from cigarette can be removed 95% by the device.
Embodiment 2:
Using 12 diameter 0.1mm, length 5cm astroid as corona discharge electrode, 12 are respectively placed in parallel to airflow direction, flat On the center line of the metallic cylinder dust collector pole of the diameter 1cm of row arrangement, pre electrified device, corona discharge electrode connection high voltage power supply negative pole, if 3000V is set to, dust collecting pole plate ground connection is placed in the air inlet of cleaner unit, in the gas treatment case of cleaner unit, takes 15 diameters For 5cm alramenting steel disk as circular plate type dust collecting electrode, be fixed on a power transmission shaft, be driven shaft diameter 0.5cm, respectively Disc is spaced 0.8cm, and adjacent disc is placed in the different liquid baths for separating, and the chlorxylone ammonium in liquid bath for 0.1% is molten Liquid, one of liquid bath ground connection, another liquid bath connect high-voltage power cathode, and voltage is 3000V, and the liquid level of liquid bath is less than separation Plate upper limb 1cm, circular plate type dust collecting electrode rotating speed 100rpm, just obtain the electrostatic dedusting purifier, and the device can be by grain The granule that 2 microns of footpath removes 97%.
Embodiment 3:
Using 1 diameter 1mm, length 20cm spiral filament as corona discharge electrode, it is respectively placed in two leaf length 20cm width 8cm's Between dust collector pole, die opening 10cm makes pre electrified device, and corona discharge electrode connection high-voltage power cathode is set to 20kV, dust collector pole Plate earthing, is placed in the air inlet of cleaner unit, in the gas treatment case of cleaner unit, takes the hydrophilic modifying of 20 a diameter of 30cm PVC disks are fixed on a power transmission shaft as circular plate type dust collecting electrode, are driven shaft diameter 2cm, and each disc is spaced 4cm, adjacent disc It is placed in the different liquid baths for separating, is 0.5% potassium sorbate solution in liquid bath, one of liquid bath ground connection, another liquid Groove connects high voltage power supply negative pole, and voltage is 20kV, and the liquid level of liquid bath is less than demarcation strip upper limb 2cm, circular plate type dust collecting electrode rotating speed 1rpm, Just the electrostatic dedusting purifier is obtained, the device can remove 93% by 2.5 microns in air.
Embodiment 4:
Using 3 diameter 0.2mm, length 50cm astroid as corona discharge electrode, four leaf length 50cm width 10cm are respectively placed in Dust collector pole between, die opening 2.5cm makes pre electrified device, corona discharge electrode connection high-voltage power cathode, is set to 10kV, receives Dirt pole plate is grounded, and is placed in the air inlet of cleaner unit, in the gas treatment case of cleaner unit, takes the parent of 10 a diameter of 100cm Water MODIFIED PP disk is fixed on a power transmission shaft as circular plate type dust collecting electrode, is driven shaft diameter 2cm, and each disc is spaced 5cm, phase Adjacent disc is placed in the different liquid baths for separating, and is 0.5% triclosan-NaOH solution in liquid bath, one of liquid bath ground connection, Another liquid bath connects high voltage power supply negative pole, and voltage is 5000V, and the liquid level of liquid bath is less than demarcation strip upper limb 1cm, circular plate type dust collecting electrode Rotating speed 5rpm, just obtains the electrostatic dedusting purifier, and 3 micron particle can be removed 97% by the device.
Embodiment 5:
Using 4 diameter 0.1mm, length 20cm tinsel as corona discharge electrode, it is respectively placed in four leaf length 20cm width 8cm's Between dust collector pole, die opening 2.5cm makes pre electrified device, and corona discharge electrode connection high voltage power supply negative pole is set to 10kV, gathers dust Pole plate is grounded, and is placed in the air inlet of cleaner unit, in the gas treatment case of cleaner unit, takes the cordierite of 10 a diameter of 20cm Ceramic disks are fixed on a power transmission shaft as circular plate type dust collecting electrode, are driven shaft diameter 1cm, and each disc is spaced 2cm, adjacent disc Piece is placed in the different liquid baths for separating, in liquid bath for 0.1% cetyl trimethylammonium bromide solution, one of liquid bath Ground connection, another liquid bath connect high-voltage power cathode, and voltage is 10kV, and the liquid level of liquid bath is less than demarcation strip upper limb 2cm, circular plate type collection Dirt pole rotating speed 10rpm, just obtains the electrostatic dedusting purifier, and smoke from cigarette can be removed 99% by the device.

Claims (8)

1. a kind of half wet cottrell:The air of dust-laden is made to flow through the pre electrified electric field for being mounted with corona discharge electrode and dust collector pole, Then air is made to flow through horizontally arranged vertical circular plate type dust collecting electrode, the quantity of circular plate type dust collecting electrode is more than 2 pieces, circular plate type dust The card of pole is parallel with air flow, and the latter half of circular plate type dust collecting electrode is immersed in the aqueous solution containing electrolyte, plectane Formula dust collecting electrode is placed on a trunnion axis at the same distance, trunnion axis by the center of circle of circular plate type dust collecting electrode, trunnion axis by One Motor drive, makes circular plate type dust collecting electrode constantly rotate, and keeps the aerial surface of circular plate type dust collecting electrode to have one all the time Layer electrolyte aqueous solution film, the latter half of the adjacent disc of circular plate type dust collecting electrode is immersed in not connected two electrolyte water In solution liquid bath, separated with the dividing plate of zigzag crippling between the two electrolyte aqueous solution liquid baths, two electrolysis Matter aqueous solution liquid bath distinguishes load zero potential and positive potential or zero potential and negative potential, makes to be immersed in circular plate type dust therein The electrolyte aqueous solution film of pole disc surface also load and institute's submergence electrolyte aqueous solution identical potential, so that horizontally arranged Circular plate type dust collecting electrode presents the form that high and low potential is back and forth arranged, a diameter of 5cm~100cm of circular plate type dust collecting electrode, plectane The spacing of formula dust collecting electrode is 0.8cm~10cm, has electrically insulating washer between circular plate type dust collecting electrode and motor-driven trunnion axis, To realize the electric insulation between trunnion axis and circular plate type dust collecting electrode, powered from the air flow through between circular plate type dust collecting electrode Grain can be attracted and is attached in the electrolyte aqueous solution liquid film on circular plate type dust collecting electrode surface because of the effect of electrostatic force, and with The rotation of circular plate type dust collecting electrode and by electrolyte aqueous solution eluting.
2. a kind of half wet cottrell as claimed in claim 1, it is characterised in that:The pre electrified electric field of cleaner unit front end Charged voltage be 3~20kV, the corona extremely round silk of 0.1~1mm of nominal diameter, astroid or helix, die opening is 0.5 ~10cm.
3. a kind of half wet cottrell as claimed in claim 1, it is characterised in that:The material of circular plate type dust collecting electrode is table The parkerized steel in face, ferrum, aluminum or aluminum alloy.
4. a kind of half wet cottrell as claimed in claim 1, it is characterised in that:The material of circular plate type dust collecting electrode is table Face does not have sieve and silica-sesquioxide ceramics, cordierite ceramic, SiC ceramic, aluminium oxide ceramics, feldspathic ceramics or the apatite pottery of glaze layer Porcelain.
5. a kind of half wet cottrell as claimed in claim 1, it is characterised in that:The material of circular plate type dust collecting electrode is table The polrvinyl chloride of face hydrophilic modifying, polymethyl methacrylate, polypropylene, polyethylene, polyethylene terephthalate, poly- first Aldehyde, Merlon, phenolic resin or acrylonitrile-butadiene-styrene (ABS) plastics.
6. a kind of half wet cottrell as claimed in claim 1, it is characterised in that:The rotating speed of circular plate type dust collecting electrode is 1rpm~100rpm.
7. a kind of half wet cottrell as claimed in claim 1, it is characterised in that:The submergence of adjacent circular plate type dust collecting electrode institute Electrolyte solution difference load zero potential and high potential or zero potential and low potential, the voltage of high potential is+3~+20kV, The voltage of low potential is -3~-20kV.
8. a kind of half wet cottrell as claimed in claim 1, it is characterised in that:Electrolyte aqueous solution is antibacterial Aqueous solution, antibacterial are Dodecyl trimethyl ammonium chloride, Dodecyl trimethyl ammonium chloride, tetradecyltrimethylammonium bromination Ammonium, tetradecyl trimethyl ammonium chloride, cetyl trimethylammonium bromide, hexadecyltrimethylammonium chloride, octadecyl three Methyl bromide ammonium, octadecyl trimethyl ammonium chloride, triclosan, chlorhexidine acetate, benzalkonium bromide, benzalkonium chloride, potassium sorbate, Sodium pyrithione, Zinc Pyrithione, copper pyrithione, 1-ethyl-3-methyllimidazolium bromide, iodate 1- ethyl-3-methylimidazoles, Bromination 1- propyl group -3- Methylimidazole .s, iodate 1- propyl group -3- Methylimidazole .s, chlorination 1- butyl -3- Methylimidazole .s, bromination 1- butyl - 3- Methylimidazole .s, iodate 1- butyl -3- Methylimidazole .s, chlorination 1- hexyl -3- Methylimidazole .s, bromination 1- hexyl -3- Methylimidazole .s, Iodate 1- hexyl -3- Methylimidazole .s, chlorination 1- octyl group -3- Methylimidazole .s, bromination 1- octyl group -3- Methylimidazole .s, iodate 1- hexyls - 3- Methylimidazole .s, chlorination 1- decyl -3- Methylimidazole .s, bromination 1- decyl -3- Methylimidazole .s, iodate 1- decyl -3- Methylimidazole .s, Chlorination 1- benzyl -3- Methylimidazole .s, bromination 1- benzyl -3- Methylimidazole .s, iodate 1- benzyl -3- Methylimidazole .s, chlorination 1- 12 Alkyl -3- Methylimidazole .s, bromination 1- dodecyl -3- Methylimidazole .s, iodate 1- dodecyl -3- Methylimidazole .s, chlorination 1- ten Tetraalkyl -3- Methylimidazole .s, bromination 1- myristyl -3- Methylimidazole .s, iodate 1- myristyl -3- Methylimidazole .s, chlorination 1- Cetyl -3- Methylimidazole .s, bromination 1- cetyl -3- Methylimidazole .s, iodate 1- cetyl -3- Methylimidazole .s, to chlorine Between xylenol, DBDMH, bromine chlorine hydantoin, two chlordantoins, in the middle of 5,5- dimethyl hydantion any one or it is arbitrarily several The mixture of arbitrary proportion.
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