CN105230625A - Antifungal composition - Google Patents
Antifungal composition Download PDFInfo
- Publication number
- CN105230625A CN105230625A CN201510601753.2A CN201510601753A CN105230625A CN 105230625 A CN105230625 A CN 105230625A CN 201510601753 A CN201510601753 A CN 201510601753A CN 105230625 A CN105230625 A CN 105230625A
- Authority
- CN
- China
- Prior art keywords
- group
- alkyl
- halogen
- cycloalkyl
- alkynyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 0 CC(*)(C(*)(*)C(*)(*)C1(*)*C*)c2c1c(*)c(C)c(*)c2* Chemical compound CC(*)(C(*)(*)C(*)(*)C1(*)*C*)c2c1c(*)c(C)c(*)c2* 0.000 description 15
- FQSIMNLLKLPISC-BETUJISGSA-N Bc1cc(N)c(C)nc1CO[C@H](CC1)CC[C@H]1C(C)C Chemical compound Bc1cc(N)c(C)nc1CO[C@H](CC1)CC[C@H]1C(C)C FQSIMNLLKLPISC-BETUJISGSA-N 0.000 description 1
- WAULMCATZWEFMB-CIAFOILYSA-N CCN(C)/C=N/c(c(C)n1)cc(Br)c1/[O]=C(\CC1)/CC[C@H]1C(C)C Chemical compound CCN(C)/C=N/c(c(C)n1)cc(Br)c1/[O]=C(\CC1)/CC[C@H]1C(C)C WAULMCATZWEFMB-CIAFOILYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N CN(CCC1)C1=O Chemical compound CN(CCC1)C1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- RIRARCHMRDHZAR-ULUSZKPHSA-N C[C@H]1C(C)CCC1 Chemical compound C[C@H]1C(C)CCC1 RIRARCHMRDHZAR-ULUSZKPHSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
The invention provides a composition comprising a component A and a component B. The component A is a compound represented by chemical formula (I), and the component B is another fungicide, insecticide or herbicide.
Description
The divisional application of the application's to be female case be Chinese invention patent application 201280061518.5.
The present invention relates to new Fungicidal composition, said composition comprises the Fungicidally active pyridine amidine compound of phytopathogenic disease, the especially phytopathogenic fungi being used for the treatment of useful plant, and relates to a kind of method of the phytopathogenic disease controlled on useful plant.
Some anil as the microbicidal active ingredients in pesticides is described in WO2008/101682.
The invention provides and comprise component A) and B) one combination, wherein component A) be a kind of compound with chemical formula (I)
Wherein
R
1and R
2in each is independently selected from hydrogen, C
1-C
4alkyl, C
3-C
4thiazolinyl, C
3-C
4alkynyl, (R
10) carbonyl and (R
10) oxygen base carbonyl;
Or R
1and R
2the nitrogen-atoms be attached on it with them together form 5 or 6 membered cyclic group, and this group can be saturated or unsaturated, and can containing other hetero atoms being selected from S or O;
R
3represent hydrogen, halogen, cyano group, nitro, sulfydryl, hydroxyl ,-C (=S) NH
2,-SF
5, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl group, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6cycloalkyl, amino, C
1-C
2alkylamino, two (C
1-C
6alkyl) amino, 5 yuan of heterocycles, piperidyl, morpholinyl, thio-morpholinyl, formoxyl, hydroxycarbonyl group, C containing 1-4 nitrogen-atoms
2-C
7alkoxy carbonyl, C
2-C
7halo alkoxy carbonyl, C
4-C
7allyloxycarbonyl, C
4-C
7halo allyloxycarbonyl, C
2-C
7alkyl-carbonyl, C
2-C
7alkyl halide carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl, C
1-C
6haloalkylthio, C
1-C
6alkylsulfinyl, C
1-C
6halogenated alkyl sulfonyl, C
1-C
6hydroxyalkyl, phenyl or benzyl, wherein this phenyl and benzyl are optionally replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: halogen, cyano group, hydroxyl, sulfydryl, amino, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl;
R
4represent hydrogen, halogen, cyano group, amino, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
3-C
6cycloalkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, C
1-C
4alkylthio group, C
1-C
4alkyl sulphinyl, C
1-C
4alkyl sulphonyl, methylamino and dimethylamino;
R
5hydrogen, C
1-C
12alkyl, C
3-C
12thiazolinyl, C
3-C
12alkynyl, C
1-C
12alkyl sulphonyl, C
2-C
12alkenylsufonyl, benzenesulfonyl or benzylsulphonyl, or be independently selected from the substituting group list of lower group to polysubstituted C
1-C
12alkyl, C
2-C
12thiazolinyl, C
2-C
12alkynyl, C
1-C
12alkyl sulphonyl, C
2-C
12alkenylsufonyl, benzenesulfonyl or benzylsulphonyl, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, azido, formoxyl, C
2-C
7alkyl-carbonyl, C
2-C
7alkyl halide carbonyl, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
R
5formoxyl, C
2-C
12alkyl-carbonyl, C
3-C
12alkenyl carbonyl, C
3-C
12alkynylcarbonyl groups, C
4-C
12naphthene base carbonyl, benzyloxycarbonyl group, phenylcarbonyl group, C
2-C
12alkoxy carbonyl, C
4-C
12alkenyloxycarbonyl, C
4-C
12alkynes oxygen carbonyl, C
4-C
12cycloalkoxycarbonyl, benzyloxycarbonyl or phenyloxycarbonyl, or be independently selected from the substituting group list of lower group to polysubstituted C
2-C
12alkyl-carbonyl, C
3-C
12alkenyl carbonyl, C
3-C
12alkynylcarbonyl groups, C
4-C
12naphthene base carbonyl, benzyloxycarbonyl group, phenylcarbonyl group, C
2-C
12alkoxy carbonyl, C
4-C
12alkenyloxycarbonyl, C
4-C
12alkynes oxygen carbonyl, C
4-C
12cycloalkoxycarbonyl, benzyloxycarbonyl or phenyloxycarbonyl, this group is made up of the following: halogen, cyano group, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl; Or
R
5(R
51) (R
52) (R
53) Si-, (R
51) (R
52) (R
53) Si-(C
1-C
12alkyl)-, (R
51) (R
52) (R
53) Si-(C
3-C
8cycloalkyl)-, (R
54o) (R
55o) (R
56o) Si-, (R
54o) (R
55o) (R
56o) Si-(C
1-C
12alkyl)-or (R
54o) (R
55o) (R
56o) Si-(C
3-C
8cycloalkyl)-; Or
R
5c
1-C
6alkyl-B-C
1-C
12alkyl, C
2-C
6thiazolinyl-B-C
1-C
12alkyl, C
2-C
6alkynyl-B-C
1-C
12alkyl, C
3-C
8cycloalkyl-B-C
1-C
12alkyl, benzyl-B-C
1-C
12alkyl, phenyl-B-C
1-C
12alkyl, C
1-C
6alkyl-B-C
2-C
12thiazolinyl, C
2-C
6thiazolinyl-B-C
2-C
12thiazolinyl, C
2-C
6alkynyl-B-C
2-C
12thiazolinyl, C
3-C
8cycloalkyl-B-C
2-C
12thiazolinyl, benzyl-B-C
2-C
12thiazolinyl, phenyl-B-C
2-C
12thiazolinyl, C
1-C
6alkyl-B-C
2-C
12alkynyl, C
2-C
6thiazolinyl-B-C
2-C
12alkynyl, C
2-C
6alkynyl-B-C
2-C
12alkynyl, C
3-C
8cycloalkyl-B-C
2-C
12alkynyl, benzyl-B-C
2-C
12alkynyl, phenyl-B-C
2-C
12alkynyl, C
1-C
6alkyl-B-C
3-C
8cycloalkyl, C
2-C
6thiazolinyl-B-C
3-C
8cycloalkyl, C
2-C
6alkynyl-B-C
3-C
8cycloalkyl, C
3-C
8cycloalkyl-B-C
3-C
8cycloalkyl, benzyl-B-C
3-C
12cycloalkyl or phenyl-B-C
3-C
12cycloalkyl, wherein group B Xuan Zi – C (=O)-,-C (=S)-,-C (=NOR
59)-,-C (R
60)=NO-,-ON=C (R
60-O-C)-, (=O)-,-C (=O)-O-,-O-,-S-,-S (=O)-,-S (=O) 2-,-S (=O) (=NR
13)-,-S (=O) (R
14)=N-,-N=S (=O) (R
14)-,-N (R
62)-C=O)-,-C=O)-N (R
62)-,-N (R
62)-SO
2-or-SO
2-N (R
62)-; Or
R
5c
1-C
6alkyl-B-C
1-C
12alkyl, C
2-C
6thiazolinyl-B-C
1-C
12alkyl-, C
2-C
6alkynyl-B-C
1-C
12alkyl, C
3-C
8cycloalkyl-B-C
1-C
12alkyl, benzyl-B-C
1-C
12alkyl, phenyl-B-C
1-C
12alkyl, C
1-C
6alkyl-B-C
2-C
12thiazolinyl, C
2-C
6thiazolinyl-B-C
2-C
12thiazolinyl, C
2-C
6alkynyl-B-C
2-C
12thiazolinyl, C
3-C
8cycloalkyl-B-C
2-C
12thiazolinyl, benzyl-B-C
2-C
12thiazolinyl, phenyl-B-C
2-C
12thiazolinyl, C
1-C
6alkyl-B-C
2-C
12alkynyl, C
2-C
6thiazolinyl-B-C
2-C
12alkynyl, C
2-C
6alkynyl-B-C
2-C
12alkynyl, C
3-C
8cycloalkyl-B-C
2-C
12alkynyl, benzyl-B-C
2-C
12alkynyl, phenyl-B-C
2-C
12alkynyl, C
1-C
6alkyl-B-C
3-C
8cycloalkyl, C
2-C
6thiazolinyl-B-C
3-C
8cycloalkyl, C
2-C
6alkynyl-B-C
3-C
8cycloalkyl, C
3-C
8cycloalkyl-B-C
3-C
8cycloalkyl, benzyl-B-C
3-C
12cycloalkyl, phenyl-B-C
3-C
12cycloalkyl, all these so that be independently selected from the substituting group list of lower group to polysubstituted, this group is made up of the following: halogen, cyano group, hydroxyl, sulfydryl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, formoxyl, C
2-C
6alkyl-carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
R
5a-, A-(C
1-C
6alkyl)-, A-O-(C
1-C
6alkyl)-, A-(C
3-C
6thiazolinyl)-, A-O-(C
4-C
6thiazolinyl)-, A-(C
3-C
6-alkynyl)-, A-O-(C
4-C
6alkynyl)-, A-(C
3-C
8cycloalkyl)-or A-O-(C
3-C
8cycloalkyl)-;
Wherein A be the monocycle of three to ten yuan or the bicyclic system that condenses, it can be aromatic, fractional saturation or completely saturated and can be selected from the hetero atom of lower group containing 1 to 4, this group is made up of the following: nitrogen, oxygen and sulphur, for each loop systems,-O-O-,-S-S-can not be contained with – O-S-fragment, for this three to ten-ring system, possible self coverlet or polysubstituted
A1) replaced by the substituting group being independently selected from lower group, this group is made up of the following:
Halogen, cyano group, nitro, hydroxyl, sulfydryl, azido, formoxyl, carboxyl ,=O ,=S, C
1-C
6alkyl, C
2-C
6thiazolinyl, C
2-C
6alkynyl, C
3-C
8cycloalkyl, C
1-C
6alkylhalide group, C
2-C
6haloalkenyl, C
2-C
6alkynyl halide, C
3-C
8halogen cycloalkyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6haloalkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
8cycloalkyloxy, benzyl, benzyloxy, phenyl and phenoxy group, wherein this benzyl, benzyloxy, phenyl and phenoxy group and then can be independently selected from the substituting group list of lower group to polysubstituted, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, amino, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
A2) replaced by the substituting group being independently selected from lower group, this group is made up of the following:
Replaced by the substituting group being independently selected from lower group, this group is made up of the following: (R
14) S (=O) (=NR
13)-, (R
14) (R
15) S (=O)=N-;-Si (R
51) (R
52) (R
53), – NR
57r
58,-C (=O) NR
57r
58,-C (=S) NR
57r
58, HC (=NOR
59)-, (C
1-C
6alkyl) C (=NOR
59)-, (C
1-C
6alkylhalide group) C (=NOR
59)-, (C
1-C
6alkyl) C (=NOR
59) C
1-C
6alkyl-, (C
1-C
6alkylhalide group) C (=NOR
59) C
1-C
6alkyl-, N (C
1-C
6alkyl) amino-sulfonyl and N, N-bis-(C
1-C
6alkyl) amino-sulfonyl; Or
A3) replaced by the substituting group being independently selected from lower group, this group is made up of the following:
Formoxyl, C
2-C
7alkyl-carbonyl, C
2-C
7alkyl halide carbonyl, C
3-C
7alkenyl carbonyl, C
3-C
7haloalkenyl carbonyl, C
4-C
9naphthene base carbonyl, C
4-C
9halogenated cycloalkyl carbonyl, C
2-C
7alkoxy carbonyl, C
2-C
7halo alkoxy carbonyl, C
3-C
7alkenyloxycarbonyl, C
3-C
7alkynes oxygen carbonyl, C
4-C
9cycloalkoxycarbonyl, C
2-C
7alkylthiocarbonyl and benzyloxycarbonyl, and be independently selected from the substituting group list of lower group to polysubstituted benzyloxycarbonyl, this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl; Or
A4) replaced by the substituting group being independently selected from lower group, this group is made up of the following:
Hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, halogen, C
1-C
4alkylhalide group, C
2-C
4haloalkenyl, cyano group, benzyl, phenyl ,=C (R
36 ')
2,=N-OH ,=N-O-C
1-C
4-alkyl ,=N-O-C
3-C
4thiazolinyl ,=N-O-C
3-C
4alkynyl ,=N-O-C
1-C
4alkylhalide group ,=N-O-C
3-C
4haloalkenyl ,=N-O-benzyl and=N-O-phenyl, wherein=N-O-benzyl and=N-O-phenyl are optionally selected from one or more groups replacements of lower group, and this group is made up of the following: halogen, methyl, halomethyl; Or
R
5-N=C (R
8) (R
9); Or
R
5the C containing 0,1 or 2 O or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, C
1-C
6alkyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7-alkyl-carbonyl, C
2-C
7-alkoxy carbonyl, C
4-C
7-alkenyloxycarbonyl, C
4-C
7-alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,=O ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2one or more groups replace;
R
6be selected from hydrogen and SH;
R
7hydrogen, halogen or C
1-C
4alkyl;
R
8and R
9hydrogen, halogen, cyano group, C independently of one another
1-C
12alkyl, C
2-C
12thiazolinyl, C
2-C
12alkynyl, C
1-C
12alkoxyl, formoxyl, C
2-C
12alkyl-carbonyl, C
3-C
12alkenyl carbonyl, carboxyl, C
2-C
12alkoxy carbonyl and C
4-C
12alkenyloxycarbonyl, or be independently selected from the substituting group list of lower group to polysubstituted C
1-C
12alkyl, C
2-C
12thiazolinyl, C
2-C
12alkynyl, C
1-C
12alkoxyl, C
2-C
12alkyl-carbonyl, C
3-C
12alkenyl carbonyl, C
2-C
12alkoxy carbonyl and C
4-C
12alkenyloxycarbonyl, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or R
8and R
9form C together
2-C
8alkylidene bridge, its substituting group list that optionally can be selected from lower group is to polysubstituted, and this group is made up of the following: halogen, cyano group, C
1-C
6alkyl and C
1-C
6alkylhalide group; Or R
8and R
9group A-, A-O-or A-(C independently of one another
1-C
6alkyl)-;
R
10h, C
1-C
4alkyl, C
2-C
4thiazolinyl or C
1-C
4alkylhalide group;
R
13hydrogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6thiazolinyl, C
3-C
6haloalkenyl, C
3-C
6alkynyl, C
3-C
8cycloalkyl, C
3-C
8halogen cycloalkyl, phenyl and benzyl, or by halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group or C
1-C
6alkoxyl list is to polysubstituted phenyl and benzyl;
R
14and R
15c independently of one another
1-C
6alkyl, C
3-C
8cycloalkyl, C
1-C
6alkylhalide group, C
3-C
8halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, benzyl or phenyl, or be selected from independently of one another lower group substituting group replace benzyl or phenyl, this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl;
R
51, R
52, R
53halogen, cyano group, C independently of one another
1-C
6alkyl, C
2-C
6thiazolinyl, C
3-C
8cycloalkyl, C
5-C
8cycloalkenyl group, C
2-C
6alkynyl, C
1-C
6alkoxyl, benzyl or phenyl;
R
54, R
55, R
56c independently of one another
1-C
6alkyl, C
3-C
6thiazolinyl, C
3-C
8cycloalkyl, C
3-C
6alkynyl, benzyl or phenyl;
R
57and R
58hydrogen, C independently of one another
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6thiazolinyl, C
3-C
6haloalkenyl, C
3-C
6alkynyl, C
3-C
8cycloalkyl, C
3-C
8halogen cycloalkyl, phenyl or benzyl, wherein phenyl or benzyl can be independently selected from the substituting group list of lower group to polysubstituted for it on the phenyl ring, and this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl, or R
57and R
58aziridinyl, azelidinyl, pyrazolinyl, pyrazolidinyl, pyrrolinyl, pyrrolidinyl, imidazolinyl, imidazolidinyl, triazoline base, tetrazolium quinoline base, piperazinyl, piperidyl, morpholinyl, thio-morpholinyl together with their connection nitrogen-atoms, wherein each and then can be selected from the substituting group list of lower group to polysubstituted, and this group is made up of the following: methyl, halogen, cyano group;
R
59hydrogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6thiazolinyl, C
3-C
6haloalkenyl, C
3-C
6alkynyl, C
3-C
8cycloalkyl, C
3-C
8halogen cycloalkyl, benzyl and phenyl, and by halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group or C
1-C
6alkoxyl list is to polysubstituted benzyl and phenyl;
R
60hydrogen, C
1-C
6alkyl, C
3-C
8cycloalkyl, C
1-C
6alkylhalide group, C
3-C
8halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, benzyl or phenyl, or be independently selected from the substituting group list of lower group to polysubstituted benzyl or phenyl, this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl;
R
62hydrogen, C
1-C
6alkyl, C
3-C
8cycloalkyl, C
1-C
6alkylhalide group, C
3-C
8halogen cycloalkyl, C
3-C
6thiazolinyl, C
3-C
6alkynyl, benzyl or phenyl, or be independently selected from the substituting group list of lower group to polysubstituted benzyl or phenyl, this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl;
Each R
36 'independently be selected from hydrogen, halogen and C
1-C
4alkyl;
And acceptable salt/metal complex on the agronomy of those compounds/metalloid complex compound/isomer/constitutional isomer/stereoisomer/diastereoisomer/enantiomter/dynamic isomer/N-oxide;
And
B component) be strobilurin fungicide, sterol biosynthesis inhibitor fungicide, triazole antifungal agents, or triazole precursor fungicide, or DMI fungicide, or SDHI fungicide, or being selected from a kind of compound of lower group, this group is made up of the following: tpn, fludioxonil, cyprodinil, mandipropamid, fluazinam, procymidone, carbendazim, Avermectin, clothianidin, according to mark's butylbenzene formates, Imidacloprid, tefluthrin, Metalaxyl-M, Orocymedone, Diacloden, λ-three cyhalothrin, γ-three cyhalothrin, Profenofos, lufenuron, diflubenzuron, cypermethrin, Rimon, Biphenthrin, methomyl, Chlorpyrifos, acephatemet, 5a,6,9,9a-hexahydro-6,9-methano-2,4, β-cyhalothrin, desinsection urea, diflubenzuron, sulphur humulone, orthene, glyphosate, grass fourth phosphine, Mesotrione, two ring benzofenaps (Bicyclopyrone), Tembotrione, sulphur humulone, sulphur humulone, auxin class, TrinexAN_SNacethyl ethyl ester, adjust naphthenic acid-Ca, paclobutrazol, my acid benzene-S-methyl, methyl jasmonate, cis-jasmone, manganese, cyflufenamid, isobutyl ethoxyquin (Tebufloquin) and copper.
Other aspects of the present invention provide with component A) and B component) between collaborative effective ratio comprise component A) and a kind of composition of combination B).
Another aspect of the present invention provides a kind of method for controlling the phytopathogenic disease on useful plant or on its propagating materials, and the method comprises to be used with component and B component on these useful plants, its location or its propagating materials) between same cooperative effective quantity and the component A of ratio) and one combination B).
Other aspects of the present invention relate to the noval chemical compound according to chemical formula (I).
Other aspects of the present invention relate to new intermediate to provide the compound according to chemical formula (I).
Preferably, B component is strobilurin fungicide, sterol biosynthesis inhibitor fungicide, triazole antifungal agents, or triazole precursor fungicide, or DMI fungicide, or SDHI fungicide, or be selected from tpn, fludioxonil, cyprodinil, mandipropamid, Metalaxyl-M, Orocymedone, fluazinam, procymidone, carbendazim, Avermectin, clothianidin, according to mark's butylbenzene formates, Imidacloprid, tefluthrin, Diacloden, λ-three cyhalothrin, γ-three cyhalothrin, Profenofos, lufenuron, diflubenzuron, cypermethrin, Rimon, Biphenthrin, methomyl, Chlorpyrifos, acephatemet, 5a,6,9,9a-hexahydro-6,9-methano-2,4, β-cyhalothrin, desinsection urea, diflubenzuron, sulphur humulone, orthene, glyphosate, grass fourth phosphine, Mesotrione, two ring benzofenaps (Bicyclopyrone), Tembotrione, sulphur humulone, sulphur humulone, auxin class, TrinexAN_SNacethyl ethyl ester, adjust naphthenic acid-Ca, paclobutrazol, my acid benzene-S-methyl, methyl jasmonate, cis-jasmone, manganese, and copper.
Preferably, B component is a kind of strobilurin fungicide, sterol biosynthesis inhibitor fungicide, triazole antifungal agents, triazole precursor fungicide, DMI fungicide, SDHI fungicide, or be selected from lower group of a kind of compound, this group is made up of the following: tpn, fludioxonil, cyprodinil, mandipropamid, Metalaxyl-M, Orocymedone, fluazinam, carbendazim, Diacloden, glyphosate, 2,4-D, TrinexAN_SNacethyl ethyl ester, adjust naphthenic acid-Ca, paclobutrazol and cis-jasmone.
In one group of mixture, B component is a kind of strobilurin fungicide.
In another group mixture, B component is a kind of sterol biosynthesis inhibitor.
In another group mixture, B component is a kind of triazole antifungal agents or triazole precursor (protriazole) compound.
In another group mixture, B component is a kind of DMI fungicide.
In another group mixture, B component is a kind of SDHI fungicide.
In another group mixture, B component is the compound that one has chemical formula (III).
Wherein R
70 'be phenyl, it is unsubstituted or is selected from 1,2 or 3 substituting group replacement of halogen, alkylhalide group, halogenated alkoxy and cyano group, and;
Wherein R
71 'be phenyl, it is unsubstituted or is selected from 1,2 or 3 substituting group replacement of halogen, alkylhalide group, halogenated alkoxy and cyano group.
The compound preferably with chemical formula (III) is (S)-[3-(the fluoro-phenyl of the chloro-2-of 4-)-5-(2,4-difluorophenyl)-isoxazole-4-bases]-pyridin-3-yl-methyl alcohol and 3-(the fluoro-phenyl of the chloro-2-of 4-)-5-(2,4-difluorophenyl)-isoxazole-4-bases]-pyridin-3-yl-methyl alcohol.
In another group mixture, B component is selected from lower group, and this group is made up of the following: tpn, fludioxonil, cyprodinil, mandipropamid, fluazinam, procymidone, carbendazim, Avermectin, clothianidin, according to mark's butylbenzene formates, Imidacloprid, tefluthrin, Metalaxyl-M, Orocymedone, Diacloden, λ-three cyhalothrin, γ-three cyhalothrin, Profenofos, lufenuron, diflubenzuron, cypermethrin, Rimon, Biphenthrin, methomyl, Chlorpyrifos, acephatemet, 5a,6,9,9a-hexahydro-6,9-methano-2,4, β-cyhalothrin, desinsection urea, diflubenzuron, sulphur humulone, orthene, glyphosate, grass fourth phosphine, Mesotrione, two ring benzofenaps, Tembotrione, sulphur humulone, auxin class (such as 2,4-D and MCPA), TrinexAN_SNacethyl ethyl ester, adjust naphthenic acid-Ca, paclobutrazol, my acid benzene-S-methyl, methyl jasmonate, cis-jasmone, manganese and copper, be preferably selected from lower group, and this group is made up of the following: tpn, fludioxonil, cyprodinil, fenpropidin, mandipropamid, Metalaxyl-M, Orocymedone, fluazinam, procymidone, carbendazim, Avermectin, clothianidin, according to mark's butylbenzene formates, Imidacloprid, tefluthrin, Diacloden, λ-three cyhalothrin, γ-three cyhalothrin, Profenofos, lufenuron, diflubenzuron, cypermethrin, Rimon, Biphenthrin, methomyl, Chlorpyrifos, acephatemet, 5a,6,9,9a-hexahydro-6,9-methano-2,4, β-cyhalothrin, desinsection urea, diflubenzuron, sulphur humulone, orthene, glyphosate, grass fourth phosphine, Mesotrione, two ring benzofenaps, Tembotrione, sulphur humulone, auxin class, TrinexAN_SNacethyl ethyl ester, adjust naphthenic acid-Ca, paclobutrazol, my acid benzene-S-methyl, methyl jasmonate, cis-jasmone, manganese and copper, be more preferably selected from lower group, and this group is made up of the following: tpn, fludioxonil, cyprodinil fenpropidin, mandipropamid, Metalaxyl-M, Orocymedone, fluazinam, carbendazim, Diacloden, glyphosate 2,4-D, TrinexAN_SNacethyl ethyl ester, adjust naphthenic acid-Ca, paclobutrazol and cis-jasmone.
In a preferred embodiment, B component) be selected from tpn, fludioxonil, cyprodinil, fenpropidin, mandipropamid, butadiene morpholine, fluazinam, procymidone, carbendazim, Avermectin, clothianidin, according to mark's butylbenzene formates, Imidacloprid, tefluthrin, Metalaxyl-M, Orocymedone, Diacloden, λ-three cyhalothrin, γ-three cyhalothrin, Profenofos, lufenuron, diflubenzuron, cypermethrin, Rimon, Biphenthrin, methomyl, Chlorpyrifos, acephatemet, 5a,6,9,9a-hexahydro-6,9-methano-2,4, β-cyhalothrin, desinsection urea, diflubenzuron, orthene, glyphosate, grass fourth phosphine, Mesotrione, two ring benzofenaps (Bicyclopyrone), Tembotrione, sulphur humulone, 2,4-D, MCPA, TrinexAN_SNacethyl ethyl ester, adjust naphthenic acid-Ca, paclobutrazol, my acid benzene-S-methyl, methyl jasmonate, cis-jasmone, manganese, copper, SYP-3375, Dicloaminostrobin, fluorine bacterium mite ester (Flufenoxystrobin), azoles amine bacterium ester (pyrametostrobin), azoles bacterium ester (Pyraoxystrobin), oxime bacterium ester, Fluoxastrobin, pyraclostrobin, ZEN 90160, fragrant bacterium ester (Jiaxiangjunzhi) of first, Enestroburin (Enoxastrobin), chlorine nalidixic bacterium ester (Triclopyricarb), there is the compound of Formulae II, cyproconazole, Difenoconazole, metconazole, propiconazole, oxole bacterium, Tebuconazole, Flutriafol, plant bacterium azoles, prothioconazoles, (S)-[3-(the fluoro-phenyl of the chloro-2-of 4-)-5-(2,4-difluorophenyl)-isoxazole-4-bases]-pyridin-3-yl-methyl alcohol, 3-(the fluoro-phenyl of the chloro-2-of 4-)-5-(2,4-difluorophenyl)-isoxazole-4-bases]-pyridin-3-yl-methyl alcohol, SYP-Z048 (Pyrisoxazole), 3-(difluoromethyl)-N-methoxyl group-1-methyl-N-[1-methyl-2-(2,4,6-trichlorophenyl) ethyl]-1H-pyrazole-4-carboxamide, N-[9-(dichloromethylene)-1,2,3,4-tetrahydrochysenes-Isosorbide-5-Nitrae-endo-methylene group naphthalene-5-base]-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide, isopyrazam (Isopyrazam), ring third pyrrole bacterium amine (Sedaxane), Boscalid, fluorobenzene pyrrole bacterium amine (Fluxapyroxad), pyrrole metsulfovax, penta benzene pyrrole bacterium amine, biphenyl pyrrole bacterium amine (Bixafen) and fluorine pyrrole bacterium acid amides.
For those skilled in the art, term strobilurin fungicide is known, and comprises such as SYP-3375, Dicloaminostrobin, fluorine bacterium mite ester, azoles amine bacterium ester, azoles bacterium ester, oxime bacterium ester, Fluoxastrobin, pyraclostrobin, ZEN 90160, the fragrant bacterium ester of first, Enestroburin, chlorine nalidixic bacterium ester, fluoxastrobin, dimoxystrobin, alkene oxime amine (Fenaminostrobin) and have the compound of chemical formula (II).Preferred strobilurin fungicide is Fluoxastrobin, pyraclostrobin and ZEN 90160.Even preferred strobilurin fungicide is Fluoxastrobin and pyraclostrobin.
For those skilled in the art, term sterol biosynthesis inhibitor fungicide is known, and comprises such as volution bacterium amine, butadiene morpholine, tridemorph, fenpropidin, fenhexamid, Terbinafine, Naftifine.
For those skilled in the art, term triazole antifungal agents is known, and comprise such as cyproconazole, Difenoconazole, metconazole, propiconazole, oxole bacterium, Tebuconazole, Flutriafol, kind bacterium azoles and 1-(2-chlorphenyl)-2-(1-chlorine ring third-1-base)-3-(1,2,4-triazol-1-yl) propan-2-ol [CAS 120983-64-4].Preferred triazole antifungal agents compound is cyproconazole, Difenoconazole, metconazole and Tebuconazole.Even be more preferably cyproconazole.
For those skilled in the art, term triazole precursor fungicide is known, and comprises such as prothioconazoles.
For those skilled in the art, term DMI fungicide is known, and comprise such as (S)-[3-(the fluoro-phenyl of the chloro-2-of 4-)-5-(2,4-difluorophenyl)-isoxazole-4-bases]-pyridin-3-yl-methyl alcohol, 3-(the fluoro-phenyl of the chloro-2-of 4-)-5-(2,4-difluorophenyl)-isoxazole-4-bases-pyridin-3-yl-methyl alcohol and SYP-Z048.Preferred DMI fungicide is (S)-[3-(the fluoro-phenyl of the chloro-2-of 4-)-5-(2,4-difluorophenyl)-isoxazole-4-bases]-pyridin-3-yl-methyl alcohol and 3-(the fluoro-phenyl of the chloro-2-of 4-)-5-(2,4-difluorophenyl)-isoxazole-4-bases]-pyridin-3-yl-methyl alcohol.
For those skilled in the art, term SDHI fungicide is known, and comprises such as N-[9-(dichloromethylene)-1, 2, 3,4-tetrahydrochysene-Isosorbide-5-Nitrae-endo-methylene group naphthalene-5-base]-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide, isopyrazam (Isopyrazam), ring third pyrrole bacterium amine, Boscalid, fluorobenzene pyrrole bacterium amine, pyrrole metsulfovax, penta benzene pyrrole bacterium amine, biphenyl pyrrole bacterium amine, fluorine pyrrole bacterium acid amides, 3-(difluoromethyl)-N-methoxyl group-1-methyl-N-[1-methyl-2-(2, 4, 6-trifluorophenyl) ethyl]-1H-pyrazole-4-carboxamide, preferred SDHI fungicide is N-[9-(dichloromethylene)-1, 2, 3,4-tetrahydrochysene-Isosorbide-5-Nitrae-endo-methylene group naphthalene-5-base]-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide, isopyrazam (Isopyrazam), 3-(difluoromethyl)-N-methoxyl group-1-methyl-N-[1-methyl-2-(2,4,6-trifluorophenyl) ethyl]-1H-pyrazole-4-carboxamide and fluorobenzene pyrrole bacterium amine.
For those skilled in the art, term auxin class is known, and comprise such as 2,4-D2,4-D, MCPA and dicamba.
In a further preferred embodiment, B component is tpn.In a further preferred embodiment, B component is fludioxonil.In a further preferred embodiment, B component is cyprodinil.In a further preferred embodiment, B component is fenpropidin.In a further preferred embodiment, B component is mandipropamid.In a further preferred embodiment, B component is fluazinam.In a further preferred embodiment, B component is procymidone.In a further preferred embodiment, B component is carbendazim.In a further preferred embodiment, B component is Avermectin.In a further preferred embodiment, B component is clothianidin.In a further preferred embodiment, B component is according to mark's butylbenzene formates.In a further preferred embodiment, B component is Imidacloprid.In a further preferred embodiment, B component is tefluthrin.In a further preferred embodiment, B component is Metalaxyl-M.In a further preferred embodiment, B component is Orocymedone.In a further preferred embodiment, B component is Diacloden.In a further preferred embodiment, B component is λ-three cyhalothrin.In a further preferred embodiment, B component is γ-three cyhalothrin.In a further preferred embodiment, B component is Profenofos.In a further preferred embodiment, B component is lufenuron.In a further preferred embodiment, B component is diflubenzuron.In a further preferred embodiment, B component is cypermethrin.In a further preferred embodiment, B component is Rimon.In a further preferred embodiment, B component is Biphenthrin.In a further preferred embodiment, B component is methomyl.In a further preferred embodiment, B component is Chlorpyrifos.In a further preferred embodiment, B component is acephatemet.In a further preferred embodiment, B component is 5a,6,9,9a-hexahydro-6,9-methano-2,4.In a further preferred embodiment, B component is β-cyhalothrin.In a further preferred embodiment, B component is desinsection urea.In a further preferred embodiment, B component is diflubenzuron.In a further preferred embodiment, B component is orthene.In a further preferred embodiment, B component is glyphosate.In a further preferred embodiment, B component is careless fourth phosphine.In a further preferred embodiment, B component is Mesotrione.In a further preferred embodiment, B component is two ring benzofenaps (Bicyclopyrone).In a further preferred embodiment, B component is Tembotrione.In a further preferred embodiment, B component is sulphur humulone.In a further preferred embodiment, B component is 2,4-D.In a further preferred embodiment, B component is MCPA.In a further preferred embodiment, B component is TrinexAN_SNacethyl ethyl ester.In a further preferred embodiment, B component adjusts naphthenic acid-Ca.In a further preferred embodiment, B component is paclobutrazol.In a further preferred embodiment, B component is my acid benzene-S-methyl.In a further preferred embodiment, B component is methyl jasmonate.In a further preferred embodiment, B component is cis-jasmone.In a further preferred embodiment, B component is manganese.In a further preferred embodiment, B component is copper.In a further preferred embodiment, B component is cyflufenamid.In a further preferred embodiment, B component is isobutyl ethoxyquin (Tebufloquin).In a further preferred embodiment, B component is SYP-3375.In a further preferred embodiment, B component is Dicloaminostrobin.In a further preferred embodiment, B component is fluorine bacterium mite ester.In a further preferred embodiment, B component is azoles amine bacterium ester.In a further preferred embodiment, B component is azoles bacterium ester.In a further preferred embodiment, B component is oxime bacterium ester.In a further preferred embodiment, B component is Fluoxastrobin.In a further preferred embodiment, B component is pyraclostrobin.In a further preferred embodiment, B component is ZEN 90160.In a further preferred embodiment, B component is the fragrant bacterium ester of first.In a further preferred embodiment, B component is Enestroburin.In a further preferred embodiment, B component is chlorine nalidixic bacterium ester.In a further preferred embodiment, B component is fluoxastrobin.In a further preferred embodiment, B component is dimoxystrobin.In a further preferred embodiment, B component is alkene oxime amine.In a further preferred embodiment, B component is the compound with Formulae II.In a further preferred embodiment, B component is cyproconazole.In a further preferred embodiment, B component is Difenoconazole.In a further preferred embodiment, B component is metconazole.In a further preferred embodiment, B component is propiconazole.In a further preferred embodiment, B component is oxole bacterium.In a further preferred embodiment, B component is Tebuconazole.In a further preferred embodiment, B component is Flutriafol.In a further preferred embodiment, B component is kind of a bacterium azoles.In a further preferred embodiment, B component is 1-(2-chlorphenyl)-2-(1-chlorine ring third-1-base)-3-(1,2,4-triazol-1-yl) propan-2-ol [CAS 120983-64-4].In a further preferred embodiment, B component is prothioconazoles.In a further preferred embodiment, B component is (S)-[3-(the fluoro-phenyl of the chloro-2-of 4-)-5-(2,4-difluorophenyl)-isoxazole-4-bases]-pyridin-3-yl-methyl alcohol.In a further preferred embodiment, B component is 3-(the fluoro-phenyl of the chloro-2-of 4-)-5-(2,4-difluorophenyl)-isoxazole-4-bases-pyridin-3-yl-methyl alcohol.In a further preferred embodiment, B component is SYP-Z048.In a further preferred embodiment, B component is 3-(difluoromethyl)-N-methoxyl group-1-methyl-N-[1-methyl-2-(2,4,6-trichlorophenyl) ethyl]-1H-pyrazole-4-carboxamide.In a further preferred embodiment, B component is N-[9-(dichloromethylene)-1,2,3,4-tetrahydrochysenes-Isosorbide-5-Nitrae-endo-methylene group naphthalene-5-base]-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide.In a further preferred embodiment, B component is isopyrazam (Isopyrazam).In a further preferred embodiment, B component is ring third pyrrole bacterium amine.In a further preferred embodiment, B component is Boscalid.In a further preferred embodiment, B component is fluorobenzene pyrrole bacterium amine.In a further preferred embodiment, B component is pyrrole metsulfovax.In a further preferred embodiment, B component is penta benzene pyrrole bacterium amine.In a further preferred embodiment, B component is biphenyl pyrrole bacterium amine.In a further preferred embodiment, B component is fluorine pyrrole bacterium acid amides.In a further preferred embodiment, B component is 1-(2-chlorphenyl)-2-(1-chlorine ring third-1-base)-3-(1,2,4-triazol-1-yl) propan-2-ol.
The additional enhancing of the action spectrum relative to the phytopathogen that will control desired in principle can be brought according to mixture of active principles of the present invention, but reach the synergy of the sphere of action expanding component (A) and component (B) in two ways.The first, that can reduce component (A) and component (B) uses ratio, and its effect is simultaneously same keeps good.The second, this mixture of active principles still can reach height phytopathogen control, or even wherein these two kinds of independent components low like this using in ratio ranges become complete invalid time.This just allows, on the one hand, and greatly widening of the phytopathogen spectrum that can control, and on the other hand, add and use safety.
But except the actual synergy to Fungicidally active, pesticides composition according to the present invention can also have other beat all advantageous feature in more broad sense that can further illustrate, as synergistic activity.The example of the such advantageous feature that can mention is: that composes the Fungicidally active of other plant pathogen (such as resistant strain) widens; The minimizing of using ratio of active component, for the synergistic activity of animal pest biology (representative of such as insect or Acarina); Widening of pest activity profile is killed to other animal pest biologies (animal pest such as resistance is biological); Even individually oriented compound completely invalid use ratio under, the sufficient pest under the assistance of composition according to the present invention controls; In preparation and/or when using, such as, favourable behavior in grinding, screening, emulsification, dissolving or when disperseing; The storage stability increased; The photostability improved; More favourable degradability; The toxicology improved and/or ecological toxicology behavior; The improvement feature of useful plant comprises: sprouting, crop yield, more flourishing root system, increase of tillering, the increase of plant height, larger blade, less dead basal leaf, stronger to tiller, greener leaf color, less required fertilizer, less required seed, more voluminous to tiller, blooming more early, kernel maturity early, less plant falls down that (verse) (lodging), the blastogenesis that increases are long, the plant vigor that improves and germinateing morning; Or any other advantage that those skilled in the art are familiar with.
Substituting group on nitrogen-atoms is always different from halogen.Hydroxyl, sulfydryl or amino-substituent are not placed on the heteroatomic α-carbon relative to core fragment.
The alkyl occurred in substituting group definition can be straight chain or side chain, and is such as methyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, sec-butyl, isobutyl group, the tert-butyl group, amyl group, hexyl, heptyl and octyl group and their branched chain isomer.Alkoxyl, thiazolinyl and alkynyl are derived from mentioned alkyl.Thiazolinyl and alkynyl group can be single or polyunsaturated.
The cycloalkyl occurred in substituting group definition is such as cyclopropyl, cyclobutyl, cyclopenta or cyclohexyl.
Halogen is fluorine, chlorine, bromine or iodine generally, preferably fluorine, bromine or chlorine.Correspondingly, also make halogen in conjunction with other implications, such as alkylhalide group or halogenated alkoxy.
Haloalkyl group preferably has a chain length from 1 to 6 carbon atom.Alkylhalide group is, such as methyl fluoride, difluoromethyl, trifluoromethyl, chloromethyl, dichloromethyl, trichloromethyl, 2,2,2-trifluoroethyl, 2-fluoro ethyl, 2-chloroethyl, five fluoroethyl groups, 1,1-bis-fluoro-2,2,2-trichloroethyl, 2,2,3,3-tetra-fluoro ethyl, 2,2,2-trichloroethyl, 5,5,5-trifluoro penta-1-base, 5,5-bis-fluoro-penta-1-bases, 6, own-1-the base of 6,6-trifluoro, 6,6-bis-fluoro-own-1-base, seven fluoro-third-2-bases and the fluoro-third-2-bases of 2-; Preferably trichloromethyl, difluorochloromethyl, difluoromethyl, trifluoromethyl and dichlorofluoromethyl.
The haloalkenyl group be applicable to comprises by halogen list, two or trisubstituted alkenyl group, halogen is fluorine, chlorine, bromine and iodine and particularly fluorine and chlorine, these groups are such as 2,2-bis-fluoro-1-methyl ethylenes, 3-fluorine acrylic, chlorallylene base, 3-bromopropenyl, 2,3,3-trifluoro-propenyl, 2,3,3-tri chloropropene base and 4,4,4 ,-trifluoro but-2-ene-1-bases.
The alkynyl halide group be applicable to is, such as, by halogen list or polysubstituted alkynyl group, halogen is bromine, iodine and particularly fluorine and chlorine, these groups are such as 3-fluorine propinyl, 3-propargyl chloride base, 3-propargyl bromide base, 3,3,3-trifluoropropyl alkynyls and 4,4,4-trifluoro fourth-2-alkynes-1-base.
Alkoxyl is, such as methoxyl group, ethyoxyl, propoxyl group, isopropoxy, n-butoxy, isobutoxy, sec-butoxy and tert-butoxy; Preferably methoxyl group and ethyoxyl.Halogenated alkoxy is, such as fluorine methoxyl group, difluoro-methoxy, trifluoromethoxy, 2,2,2-trifluoro ethoxy, 1,1,2,2-tetrafluoro ethyoxyl, 2-fluorine ethyoxyl, 2-chloroethoxy, 2,2-difluoroethoxies and 2,2,2-tri-chloroethoxy base, preferably difluoro-methoxy, 2-chloroethoxy and trifluoromethoxy.
Alkoxy carbonyl is, such as methoxycarbonyl, ethoxy carbonyl, propoxycarbonyl, isopropoxy carbonyl, n-butoxycarbonyl, isobutoxy carbonyl, s-butoxycarbonyl or tert-butoxycarbonyl, preferably methoxycarbonyl or ethoxy carbonyl.Halo alkoxy group preferably has a chain length from 1 to 6 carbon atom.Halogenated alkoxy is, such as fluorine methoxyl group, difluoro-methoxy, trifluoromethoxy, 2,2,2-trifluoro ethoxy, 1,1,2,2-tetrafluoro ethyoxyl, 2-fluorine ethyoxyl, 2-chloroethoxy, 2,2-difluoroethoxies and 2,2,2-tri-chloroethoxy base, preferably difluoro-methoxy, 2-chloroethoxy and trifluoromethoxy.Alkylthio radicals preferably has a chain length from 1 to 6 carbon atom.
Alkoxyalkyl is, such as methoxy, methoxy ethyl, ethoxyl methyl, ethoxyethyl group, n-propoxymethyl, positive propoxy ethyl, i-propoxymethyl or isopropoxyethyl.
Alkylthio group is, such as methyl mercapto, ethylmercapto group, rosickyite base, isopropyisulfanyl, positive butylthio, isobutylthio, secondary butylthio or tertiary butylthio, preferably methyl mercapto and ethylmercapto group.Alkyl sulphinyl is, such as methylsulfinyl, ethylsulfinyl, propylsulfenyl base, isopropylsulphinyl, n-butylsulfinyl, isobutyl group sulfinyl, sec-butyl sulfinyl, terf-butylsulfinyl; Preferably methylsulfinyl and ethylsulfinyl.Alkyl sulphonyl is, such as methyl sulphonyl, ethylsulfonyl, sulfonyl propyl base base, isopropelsulfonyl, normal-butyl sulfonyl, iso-butylsulfonyl, sec-butylsulfonyl or tert. butylsulfonyl; Preferably methyl sulphonyl or ethylsulfonyl.
C
2-C
6alkyl-carbonyl is, such as methyl carbonyl, ethylcarbonyl group, propyl group carbonyl, Isopropylcarbonyl, n-butylcarbonyl, butylcarbonyl, sec-butylcarbonyl group, tert-butyl carbonyl or n-pentylcarbonyl and their branched chain isomer, preferably methyl carbonyl and ethylcarbonyl group.Alkyl halide carbonyl derivatization is from mentioned alkyl.
In the context of the present invention, " single to polysubstituted " in substituting group definition typically refers to, depends on substituent chemical constitution, mono-substituted to replace for seven times, preferably mono-substituted to five replacements, is more preferably list, two or trisubstituted.
According to the present invention, three to ten yuan of monocycles or the bicyclic system that condenses can be aromatic, fractional saturation or completely saturated, this depends on first number of ring, such as, be selected from the group be made up of the following:
Cyclopropyl, cyclobutyl, cyclopenta, cyclohexyl, wherein said group of naphthene base can be unsubstituted or preferably by C for it
1-C
6alkyl or halogen substiuted, or phenyl, benzyl, naphthyl or following heterocyclic group: pyrrole radicals; Pyridine radicals; Pyrazolyl; Pyrimidine radicals; Pyrazinyl; Imidazole radicals; Thiadiazolyl group; Quinazolyl; Furyl; Oxadiazolyl; Indolizine base; Pyranose; Isobenzofuran-base; Thienyl; Naphthyridines base; (1-methyl isophthalic acid H-pyrazole-3-yl)-; (1-ethyl-1H-pyrazole-3-yl)-; (1-propyl group-1H-pyrazole-3-yl)-; (1H-pyrazole-3-yl)-; (1,5-dimethyl-1H-pyrazole-3-yl)-; (4-chloro-1-methyl isophthalic acid H-pyrazole-3-yl)-; (1H-pyrazol-1-yl)-; (3-methyl isophthalic acid H-pyrazol-1-yl)-; (3,5-dimethyl-1H-pyrazol-1-yl)-; (3-isoxazolyl)-; (5-methyl-3-isoxazolyl)-; (3-methyl-5-isoxazolyl)-; (5-isoxazolyl)-; (1H-pyrroles-2-base)-; (1-methyl isophthalic acid H-pyrroles-2-base)-; (1H-pyrroles-1-base)-; (1-methyl isophthalic acid H-pyrroles-3-base)-; (2-furyl)-; (5-methyl-2-furyl)-; (3-furyl)-; (5-methyl-2-thienyl)-; (2-thienyl)-; (3-thienyl)-; (1-methyl isophthalic acid H-imidazoles-2-base)-; (1H-imidazoles-2-base)-; (1-methyl isophthalic acid H-imidazol-4 yl)-; (1-methyl isophthalic acid H-imidazoles-5-base)-; (4-methyl-2-oxazolyl)-; (5-methyl-2-oxazolyl)-; (2-oxazolyl)-; (2-methyl-5-oxazolyl)-; (2-methyl-4-oxazolyl)-; (4-methyl-2-thiazolyl)-; (5-methyl-2-thiazolyl)-; (2-thiazolyl)-; (2-methyl-5-thiazole base)-; (2-methyl-4-thiazolyl)-; (3-methyl-4-isothiazolyl)-; (3-methyl-5-isothiazolyl)-; (5-methyl-3-isothiazolyl)-; (1-methyl isophthalic acid H-1,2,3-triazole-4-yl)-; (2-methyl-2H-1,2,3-triazole-4-yl)-; (4-methyl-2H-1,2,3-triazole-2-base)-; (1-methyl isophthalic acid H-1,2,4-triazole-3-base)-; (1,5-dimethyl-1H-1,2,4-triazole-3-base)-; (3-methyl isophthalic acid H-1,2,4-triazol-1-yl)-; (5-methyl isophthalic acid H-1,2,4-triazol-1-yl)-; (4,5-dimethyl-4H-1,2,4-triazole-3-base)-; (4-methyl-4H-1,2,4-triazole-3-base)-; (4H-1,2,4-triazole-4-yl)-; (5-methyl isophthalic acid, 2,3-oxadiazole-4-base)-; (1,2,3-oxadiazole-4-base)-; (3-methyl isophthalic acid, 2,4-oxadiazole-5-base)-; (5-methyl isophthalic acid, 2,4-oxadiazole-3-base)-; (4-methyl-3-furazan base)-; (3-furazan base)-; (5-methyl isophthalic acid, 2,4-oxadiazole-2-base)-; (5-methyl isophthalic acid, 2,3-thiadiazoles-4-base)-; (1,2,3-thiadiazoles-4-base)-; (3-methyl isophthalic acid, 2,4-thiadiazoles-5-base)-; (5-methyl isophthalic acid, 2,4-thiadiazoles-3-base)-; (4-methyl isophthalic acid, 2,5-thiadiazoles-3-base)-; (5-methyl isophthalic acid, 3,4-thiadiazoles-2-base)-; (1-methyl isophthalic acid H-tetrazolium-5-base)-; (1H-TETRAZOLE-5-base)-; (5-methyl isophthalic acid H-tetrazolium-1-base)-; (2-methyl-2H-tetrazolium-5-base)-; (2-ethyl-2H-tetrazolium-5-base)-; (5-methyl-2H-tetrazolium-2-base)-; (2H-tetrazolium-2-base)-; (2-pyridine radicals)-; (6-methyl-2-pyridine radicals)-; (4-pyridine radicals)-; (3-pyridine radicals)-; (6-methyl-3-pyridazinyl)-; (5-methyl-3-pyridazinyl)-; (3-pyridazinyl)-; (4,6-dimethyl-2-pyrimidine radicals)-; (4-methyl-2-pyrimidine radicals)-; (2-pyrimidine radicals)-; (2-methyl-4-pyrimidine radicals)-; (the chloro-4-pyrimidine radicals of 2-)-; (2,6-dimethyl-4-pyrimidine radicals)-; (4-pyrimidine radicals)-; (2-methyl-5-pyrimidine radicals)-; (6-methyl-2-pyrazinyl)-; (2-pyrazinyl)-; (4,6-dimethyl-1,3,5-triazines-2-base)-; (4,6-bis-chloro-1,3,5-triazines-2-base)-; (1,3,5-triazines-2-base)-; (4-methyl isophthalic acid, 3,5-triazine-2-base)-; (3-methyl isophthalic acid, 2,4-triazine-5-base)-; (3-methyl isophthalic acid, 2,4-triazine-6-base)-;
Wherein each R
26methyl, each R
27with each R
28hydrogen, C independently
1-C
3alkyl, C
1-C
3alkoxyl, C
1-C
3alkylthio group or trifluoromethyl, X
4be oxygen or sulphur and r=1,2,3 or 4.
Indicate and there is not free valency in those definition, such as
in, connect site and be positioned on the carbon atom that " CH " mark, or such as
situation in, be positioned at lower left instruction binding site on.
Following substituting group definition, comprises preferred definition, can combine by any combination:
R
1and R
2in each is independently selected from hydrogen, C
1-C
4alkyl, C
3-C
4thiazolinyl, C
3-C
4alkynyl, (R
10) carbonyl and (R
10) oxygen base carbonyl;
Or R
1and R
2the nitrogen-atoms be attached on it with them together form 5 or 6 membered cyclic group, and this group can be saturated or unsaturated and can containing other hetero atoms being selected from S or O.
Preferably, R
1and R
2in each is independently selected from hydrogen, C
1-C
4alkyl, C
3-C
4thiazolinyl and C
3-C
4alkynyl;
Or R
1and R
2the nitrogen-atoms be attached on it with them together form pyrrolidines or piperidines.
More preferably, R
1and R
2in each is independently selected from hydrogen or C
1-C
4alkyl;
Or R
1and R
2the nitrogen-atoms be attached on it with them together form pyrrolidines or piperidines.
Even more preferably, R
1and R
2in each is independently selected from hydrogen or C
1-C
4alkyl.
Again more preferably, R
1and R
2in each is C
1-C
4alkyl.
Again more advantageously, R
1and R
2in each is independently selected from methyl, ethyl and isopropyl.
Still more advantageously, R
1be methyl and R
2independently be selected from methyl, ethyl and isopropyl.
Still also more advantageously, R
1be methyl and R
2independently be selected from ethyl and isopropyl.
The most advantageously, R
1be methyl and R
2it is ethyl.
R
3represent hydrogen, halogen, cyano group, nitro, sulfydryl, hydroxyl ,-C (=S) NH
2,-SF
5, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl group, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6cycloalkyl, amino, C
1-C
2alkylamino, two (C
1-C
6alkyl) amino, 5 yuan of heterocycles, piperidyl, morpholinyl, thio-morpholinyl, formoxyl, hydroxycarbonyl group, C containing 1-4 nitrogen-atoms
4-C
7alkoxy carbonyl, C
2-C
7halo alkoxy carbonyl, C
4-C
7allyloxycarbonyl, C
2-C
7halo allyloxycarbonyl, C
2-C
7alkyl-carbonyl, C
2-C
7alkyl halide carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl, C
1-C
6haloalkylthio, C
1-C
6alkylsulfinyl, C
1-C
6halogenated alkyl sulfonyl, C
1-C
6hydroxyalkyl, phenyl or benzyl, wherein this phenyl and benzyl are optionally replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: halogen, cyano group, hydroxyl, sulfydryl, amino, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl.
Preferably, R
3represent hydrogen, halogen, cyano group, sulfydryl, hydroxyl, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4thiazolinyl, C
2-C
4haloalkenyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, C
3-C
6cycloalkyl, amino, C
1-C
2alkylamino, two (C
1-C
6alkyl) amino, pyrrolidinyl, imidazolinyl, triazoline base, tetrazolium quinoline base, formoxyl, C
2-C
5alkyl-carbonyl, C
2-C
5alkyl halide carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl, C
1-C
6haloalkylthio, C
1-C
6alkylsulfinyl, C
1-C
6halogenated alkyl sulfonyl or C
1-C
6hydroxyalkyl.
More preferably, R
3represent hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, amino, C
1-C
2alkylamino, two (C
1-C
6alkyl) amino, pyrrolidinyl, imidazolinyl, triazoline base, formoxyl, phenyl, C
2-C
4alkyl-carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl or C
1-C
6hydroxyalkyl.
Even more preferably, R
3represent hydrogen, halogen, cyano group, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, amino, C
1-C
2alkylamino, two (C
1-C
6alkyl) amino, pyrrolidinyl, imidazolinyl, triazoline base, formoxyl, C
2-C
4alkyl-carbonyl, C
1-C
4alkylthio group, C
1-C
4alkyl sulphinyl, C
1-C
4alkyl sulphonyl, C
1-C
4haloalkylthio, C
1-C
4alkylsulfinyl or C
1-C
4halogenated alkyl sulfonyl or C
1-C
6hydroxyalkyl.
Again more preferably, R
3represent hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
1-C
4alkylthio group, C
1-C
4alkyl sulphinyl or C
1-C
4alkyl sulphonyl.
Advantageously, R
3represent hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
1-C
4alkylthio group, C
1-C
4alkyl sulphinyl or C
1-C
4alkyl sulphonyl.
Even more advantageously, R
3represent hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4alkynyl, C
1-C
4alkoxyl or C
3-C
6cycloalkyl.
More advantageously, R
3represent hydrogen, halogen, C
1-C
4alkyl, C
1-C
4alkylhalide group, cyclopropyl, acetenyl or C
1-C
4alkoxyl.
Still more advantageously, R
3be selected from hydrogen, bromine, iodine, methyl, CHF
2, cyclopropyl, acetenyl and methoxyl group.
Still more advantageously, R
3represent hydrogen, bromine, iodine, methyl, difluoromethyl or methoxyl group.
The most advantageously, R
3represent bromine or methyl.
R
4represent hydrogen, halogen, cyano group, amino, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
3-C
6cycloalkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, C
1-C
4alkylthio group, C
1-C
4alkyl sulphinyl, C
1-C
4alkyl sulphonyl, methylamino or dimethylamino.
Preferably, R
4be selected from hydrogen, fluorine, chlorine, bromine, C
1-C
4alkyl, C
1-C
4thiazolinyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
3-C
6cycloalkyl.
More preferably, R
4be selected from fluorine, chlorine, bromine, C
1-C
4alkyl, C
1-C
4thiazolinyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
3-C
6cycloalkyl.
Even more preferably, R
4be selected from fluorine, chlorine, methyl, ethyl, vinyl, propyl group, acrylic, isopropyl, isopropenyl, cyclopropanyl, methoxyl group, ethyoxyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl.
Again more preferably, R
4be selected from methyl, ethyl, methoxyl group, fluorine and chlorine.
Again more advantageously, R
4be selected from methyl, ethyl, fluorine and chlorine.
Most preferably, R
4it is methyl.
In another group compound, R
4be selected from methoxyl group, fluorine and chlorine.
R
5hydrogen, C
1-C
12alkyl, C
3-C
12thiazolinyl, C
3-C
12alkynyl, C
1-C
12alkyl sulphonyl, C
2-C
12alkenylsufonyl, benzenesulfonyl or benzylsulphonyl, or be independently selected from the substituting group list of lower group to polysubstituted C
1-C
12alkyl, C
2-C
12thiazolinyl, C
2-C
12alkynyl, C
1-C
12alkyl sulphonyl, C
2-C
12alkenylsufonyl, benzenesulfonyl or benzylsulphonyl, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, azido, formoxyl, C
2-C
7alkyl-carbonyl, C
2-C
7alkyl halide carbonyl, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
R
5formoxyl, C
2-C
12alkyl-carbonyl, C
3-C
12alkenyl carbonyl, C
3-C
12alkynylcarbonyl groups, C
4-C
12naphthene base carbonyl, benzyloxycarbonyl group, phenylcarbonyl group, C
2-C
12alkoxy carbonyl, C
4-C
12alkenyloxycarbonyl, C
4-C
12alkynes oxygen carbonyl, C
4-C
12cycloalkoxycarbonyl, benzyloxycarbonyl or phenyloxycarbonyl, or be independently selected from the substituting group list of lower group to polysubstituted C
2-C
12alkyl-carbonyl, C
3-C
12alkenyl carbonyl, C
3-C
12alkynylcarbonyl groups, C
4-C
12naphthene base carbonyl, benzyloxycarbonyl group, phenylcarbonyl group, C
2-C
12alkoxy carbonyl, C
4-C
12alkenyloxycarbonyl, C
4-C
12alkynes oxygen carbonyl, C
4-C
12cycloalkoxycarbonyl, benzyloxycarbonyl or phenyloxycarbonyl, this group is made up of the following: halogen, cyano group, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl; Or
R
5(R
51) (R
52) (R
53) Si-, (R
51) (R
52) (R
53) Si-(C
1-C
12alkyl)-, (R
51) (R
52) (R
53) Si-(C
3-C
8cycloalkyl)-, (R
54o) (R
55o) (R
56o) Si-, (R
54o) (R
55o) (R
56o) Si-(C
1-C
12alkyl)-or (R
54o) (R
55o) (R
56o) Si-(C
3-C
8cycloalkyl)-; Or
R
5c
1-C
6alkyl-B-C
1-C
12alkyl, C
2-C
6thiazolinyl-B-C
1-C
12alkyl, C
2-C
6alkynyl-B-C
1-C
12alkyl, C
3-C
8cycloalkyl-B-C
1-C
12alkyl, benzyl-B-C
1-C
12alkyl, phenyl-B-C
1-C
12alkyl, C
1-C
6alkyl-B-C
2-C
12thiazolinyl, C
2-C
6thiazolinyl-B-C
2-C
12thiazolinyl, C
2-C
6alkynyl-B-C
2-C
12thiazolinyl, C
3-C
8cycloalkyl-B-C
2-C
12thiazolinyl, benzyl-B-C
2-C
12thiazolinyl, phenyl-B-C
2-C
12thiazolinyl, C
1-C
6alkyl-B-C
2-C
12alkynyl, C
2-C
6thiazolinyl-B-C
2-C
12alkynyl, C
2-C
6alkynyl-B-C
2-C
12alkynyl, C
3-C
8cycloalkyl-B-C
2-C
12alkynyl, benzyl-B-C
2-C
12alkynyl, phenyl-B-C
2-C
12alkynyl, C
1-C
6alkyl-B-C
3-C
8cycloalkyl, C
2-C
6thiazolinyl-B-C
3-C
8cycloalkyl, C
2-C
6alkynyl-B-C
3-C
8cycloalkyl, C
3-C
8cycloalkyl-B-C
3-C
8cycloalkyl, benzyl-B-C
3-C
12cycloalkyl or phenyl-B-C
3-C
12cycloalkyl, wherein group B Xuan Zi – C (=O)-,-C (=S)-,-C (=NOR
59)-,-C (R
60)=NO-,-ON=C (R
60-O-C)-, (=O)-,-C (=O)-O-,-O-,-S-,-S (=O)-,-S (=O) 2-,-S (=O) (=NR
13)-,-S (=O) (R
14)=N-,-N=S (=O) (R
14)-,-N (R
62)-C=O)-,-C=O)-N (R
62)-,-N (R
62)-SO
2-or-SO
2-N (R
62)-; Or
R
5c
1-C
6alkyl-B-C
1-C
12alkyl, C
2-C
6thiazolinyl-B-C
1-C
12alkyl-, C
2-C
6alkynyl-B-C
1-C
12alkyl, C
3-C
8cycloalkyl-B-C
1-C
12alkyl, benzyl-B-C
1-C
12alkyl, phenyl-B-C
1-C
12alkyl, C
1-C
6alkyl-B-C
2-C
12thiazolinyl, C
2-C
6thiazolinyl-B-C
2-C
12thiazolinyl, C
2-C
6alkynyl-B-C
2-C
12thiazolinyl, C
3-C
8cycloalkyl-B-C
2-C
12thiazolinyl, benzyl-B-C
2-C
12thiazolinyl, phenyl-B-C
2-C
12thiazolinyl, C
1-C
6alkyl-B-C
2-C
12alkynyl, C
2-C
6thiazolinyl-B-C
2-C
12alkynyl, C
2-C
6alkynyl-B-C
2-C
12alkynyl, C
3-C
8cycloalkyl-B-C
2-C
12alkynyl, benzyl-B-C
2-C
12alkynyl, phenyl-B-C
2-C
12alkynyl, C
1-C
6alkyl-B-C
3-C
8cycloalkyl, C
2-C
6thiazolinyl-B-C
3-C
8cycloalkyl, C
2-C
6alkynyl-B-C
3-C
8cycloalkyl, C
3-C
8cycloalkyl-B-C
3-C
8cycloalkyl, benzyl-B-C
3-C
12cycloalkyl, phenyl-B-C
3-C
12cycloalkyl, all these so that be independently selected from the substituting group list of lower group to polysubstituted, this group is made up of the following: halogen, cyano group, hydroxyl, sulfydryl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, formoxyl, C
2-C
6alkyl-carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
R
5a-, A-(C
1-C
6alkyl)-, A-O-(C
1-C
6alkyl)-, A-(C
3-C
6thiazolinyl)-, A-O-(C
4-C
6thiazolinyl)-, A-(C
3-C
6-alkynyl)-, A-O-(C
4-C
6alkynyl)-, A-(C
3-C
8cycloalkyl)-or A-O-(C
3-C
8cycloalkyl)-; Or
Wherein A be the monocycle of three to ten yuan or the bicyclic system that condenses, it can be aromatic, fractional saturation or completely saturated and can be selected from the hetero atom of lower group containing 1 to 4, this group is made up of the following: nitrogen, oxygen and sulphur, for each loop systems,-O-O-,-S-S-can not be contained with – O-S-fragment, for this three to ten-ring system, possible self coverlet or polysubstituted
A1) replaced by the substituting group being independently selected from lower group, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, nitro, azido, formoxyl, carboxyl ,=O ,=S, C
1-C
6alkyl, C
2-C
6thiazolinyl, C
2-C
6alkynyl, C
3-C
8cycloalkyl, C
1-C
6alkylhalide group, C
2-C
6haloalkenyl, C
2-C
6alkynyl halide, C
3-C
8halogen cycloalkyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6haloalkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
8cycloalkyloxy, benzyl, benzyloxy, phenyl and phenoxy group, wherein this benzyl, benzyloxy, phenyl and phenoxy group and then can be independently selected from the substituting group list of lower group to polysubstituted, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, amino, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
A2) replaced by the substituting group being independently selected from lower group, this group is made up of the following: (R
14) S (=O) (=NR
13)-, (R
14) (R
15) S (=O)=N-;-Si (R
51) (R
52) (R
53), – NR
57r
58,-C (=O) NR
57r
58,-C (=S) NR
57r
58, HC (=NOR
59)-, (C
1-C
6alkyl) C (=NOR
59)-, (C
1-C
6alkylhalide group) C (=NOR
59)-, (C
1-C
6alkyl) C (=NOR
59) C
1-C
6alkyl-, (C
1-C
6alkylhalide group) C (=NOR
59) C
1-C
6alkyl-, N (C
1-C
6alkyl) amino-sulfonyl and N, N-bis-(C
1-C
6alkyl) amino-sulfonyl; Or
A3) replaced by the substituting group being independently selected from lower group, this group is made up of the following: formoxyl, C
2-C
7alkyl-carbonyl, C
2-C
7alkyl halide carbonyl, C
3-C
7alkenyl carbonyl, C
3-C
7haloalkenyl carbonyl, C
4-C
9naphthene base carbonyl, C
4-C
9halogenated cycloalkyl carbonyl, C
2-C
7alkoxy carbonyl, C
2-C
7halo alkoxy carbonyl, C
3-C
7alkenyloxycarbonyl, C
3-C
7alkynes oxygen carbonyl, C
4-C
9cycloalkoxycarbonyl, C
2-C
7alkylthiocarbonyl and benzyloxycarbonyl, and be independently selected from the substituting group list of lower group to polysubstituted benzyloxycarbonyl, this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl; Or
A4) replaced by the substituting group being independently selected from lower group, this group is made up of the following: hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, halogen, C
1-C
4alkylhalide group, C
2-C
4haloalkenyl, cyano group, benzyl, phenyl ,=C (R
36 ')
2,=N-OH ,=N-O-C
1-C
4-alkyl ,=N-O-C
3-C
4thiazolinyl ,=N-O-C
3-C
4alkynyl ,=N-O-C
1-C
4alkylhalide group ,=N-O-C
3-C
4haloalkenyl ,=N-O-benzyl and=N-O-phenyl, wherein=N-O-benzyl and=N-O-phenyl are optionally selected from one or more groups replacements of lower group, and this group is made up of the following: halogen, methyl, halomethyl; Or
R
5-N=C (R
8) (R
9); Or
R
5the C containing 0,1 or 2 O, S or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, C
1-C
6alkyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7-alkyl-carbonyl, C
2-C
7-alkoxy carbonyl, C
4-C
7-alkenyloxycarbonyl, C
4-C
7-alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,=O ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2one or more groups replace.
Preferably, R
5represent hydrogen, C
1-C
12alkyl sulphonyl, C
1-C
12alkyl, C
3-C
12thiazolinyl, C
3-C
12alkynyl or be independently selected from the substituting group list of lower group to polysubstituted C
1-C
12alkyl, C
2-C
12thiazolinyl, C
2-C
12alkynyl, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, azido, formoxyl, C
2-C
7alkyl-carbonyl, C
2-C
7alkyl halide carbonyl, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
R
5(R
51) (R
52) (R
53) Si-, (R
51) (R
52) (R
53) Si-(C
1-C
12alkyl)-, (R
51) (R
52) (R
53) Si-(C
3-C
8cycloalkyl)-, (R
54o) (R
55o) (R
56o) Si-, (R
54o) (R
55o) (R
56o) Si-(C
1-C
12alkyl)-or (R
54o) (R
55o) (R
56o) Si-(C
3-C
8cycloalkyl)-; Or
R
5c
1-C
6alkyl-B-C
1-C
12alkyl, C
2-C
6thiazolinyl-B-C
1-C
12alkyl, C
2-C
6alkynyl-B-C
1-C
12alkyl, C
3-C
8cycloalkyl-B-C
1-C
12alkyl, benzyl-B-C
1-C
12alkyl, phenyl-B-C
1-C
12alkyl, C
1-C
6alkyl-B-C
2-C
12thiazolinyl, C
2-C
6thiazolinyl-B-C
2-C
12thiazolinyl, C
2-C
6alkynyl-B-C
2-C
12thiazolinyl, C
3-C
8cycloalkyl-B-C
2-C
12thiazolinyl, benzyl-B-C
2-C
12thiazolinyl, phenyl-B-C
2-C
12thiazolinyl, C
1-C
6alkyl-B-C
2-C
12alkynyl, C
2-C
6thiazolinyl-B-C
2-C
12alkynyl, C
2-C
6alkynyl-B-C
2-C
12alkynyl, C
3-C
8cycloalkyl-B-C
2-C
12alkynyl, benzyl-B-C
2-C
12alkynyl, phenyl-B-C
2-C
12alkynyl, C
1-C
6alkyl-B-C
3-C
8cycloalkyl, C
2-C
6thiazolinyl-B-C
3-C
8cycloalkyl, C
2-C
6alkynyl-B-C
3-C
8cycloalkyl, C
3-C
8cycloalkyl-B-C
3-C
8cycloalkyl, benzyl-B-C
3-C
12cycloalkyl or phenyl-B-C
3-C
12cycloalkyl, wherein group B Xuan Zi – C (=O)-,-C (=S)-,-C (=NOR
59)-,-C (R
60)=NO-,-ON=C (R
60-O-C)-, (=O)-,-C (=O)-O-,-O-,-S-,-S (=O)-,-S (=O) 2-,-S (=O) (=NR
13)-,-S (=O) (R
14)=N-,-N=S (=O) (R
14)-,-N (R
62)-C=O)-,-C=O)-N (R
62)-,-N (R
62)-SO
2-or-SO
2-N (R
62)-; Or
R
5c
1-C
6alkyl-B-C
1-C
12alkyl, C
2-C
6thiazolinyl-B-C
1-C
12alkyl-, C
2-C
6alkynyl-B-C
1-C
12alkyl, C
3-C
8cycloalkyl-B-C
1-C
12alkyl, benzyl-B-C
1-C
12alkyl, phenyl-B-C
1-C
12alkyl, C
1-C
6alkyl-B-C
2-C
12thiazolinyl, C
2-C
6thiazolinyl-B-C
2-C
12thiazolinyl, C
2-C
6alkynyl-B-C
2-C
12thiazolinyl, C
3-C
8cycloalkyl-B-C
2-C
12thiazolinyl, benzyl-B-C
2-C
12thiazolinyl, phenyl-B-C
2-C
12thiazolinyl, C
1-C
6alkyl-B-C
2-C
12alkynyl, C
2-C
6thiazolinyl-B-C
2-C
12alkynyl, C
2-C
6alkynyl-B-C
2-C
12alkynyl, C
3-C
8cycloalkyl-B-C
2-C
12alkynyl, benzyl-B-C
2-C
12alkynyl, phenyl-B-C
2-C
12alkynyl, C
1-C
6alkyl-B-C
3-C
8cycloalkyl, C
2-C
6thiazolinyl-B-C
3-C
8cycloalkyl, C
2-C
6alkynyl-B-C
3-C
8cycloalkyl, C
3-C
8cycloalkyl-B-C
3-C
8cycloalkyl, benzyl-B-C
3-C
12cycloalkyl, phenyl-B-C
3-C
12cycloalkyl, all these so that be independently selected from the substituting group list of lower group to polysubstituted, this group is made up of the following: halogen, cyano group, hydroxyl, sulfydryl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, formoxyl, C
2-C
6alkyl-carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
R
5a-, A-(C
1-C
6alkyl)-, A-O-(C
1-C
6alkyl)-, A-(C
3-C
6thiazolinyl)-, A-O-(C
4-C
6thiazolinyl)-, A-(C
3-C
6-alkynyl)-, A-O-(C
4-C
6alkynyl)-, A-(C
3-C
8cycloalkyl)-and A-O-(C
3-C
8cycloalkyl)-;
Wherein A be the monocycle of three to ten yuan or the bicyclic system that condenses, it can be aromatic, fractional saturation or completely saturated and can be selected from the hetero atom of lower group containing 1 to 4, this group is made up of the following: nitrogen, oxygen and sulphur, for each loop systems,-O-O-,-S-S-can not be contained with – O-S-fragment, for this three to ten-ring system, possible self coverlet or polysubstituted
A1) replaced by the substituting group being independently selected from lower group, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, nitro, azido, formoxyl, carboxyl ,=O ,=S, C
1-C
6alkyl, C
2-C
6thiazolinyl, C
2-C
6alkynyl, C
3-C
8cycloalkyl, C
1-C
6alkylhalide group, C
2-C
6haloalkenyl, C
2-C
6alkynyl halide, C
3-C
8halogen cycloalkyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6haloalkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
8cycloalkyloxy, C
3-C
8halogen cycloalkyloxy, C
3-C
8cyclenes oxygen base, C
3-C
8halogen cyclenes oxygen base, benzyl, benzyloxy, phenyl and phenoxy group, wherein this benzyl, benzyloxy, phenyl and phenoxy group and then can be independently selected from the substituting group list of lower group to polysubstituted, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, amino, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
A3) replaced by the substituting group being independently selected from lower group, this group is made up of the following: formoxyl, C
2-C
7alkyl-carbonyl, C
2-C
7alkyl halide carbonyl, C
3-C
7alkenyl carbonyl, C
3-C
7haloalkenyl carbonyl, C
4-C
9naphthene base carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
4-C
9cycloalkoxycarbonyl and benzyloxycarbonyl, and be independently selected from the substituting group list of lower group to polysubstituted benzyloxycarbonyl, this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl; Or
A4) replaced by the substituting group being independently selected from lower group, this group is made up of the following: hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, halogen, C
1-C
4alkylhalide group, C
2-C
4haloalkenyl, cyano group, benzyl, phenyl ,=C (R
36 ')
2,=N-OH ,=N-O-C
1-C
4-alkyl ,=N-O-C
3-C
4thiazolinyl ,=N-O-C
3-C
4alkynyl ,=N-O-C
1-C
4alkylhalide group ,=N-O-C
3-C
4haloalkenyl ,=N-O-benzyl and=N-O-phenyl, wherein=N-O-benzyl and=N-O-phenyl are optionally selected from one or more groups replacements of lower group, and this group is made up of the following: halogen, methyl, halomethyl; Or
R
5the C containing 0,1 or 2 O or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, C
1-C
6alkyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7-alkyl-carbonyl, C
2-C
7-alkoxy carbonyl, C
4-C
7-alkenyloxycarbonyl, C
4-C
7-alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,=O ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2one or more groups replace.
More preferably, R
5be selected from G
1, G
2, G
3-G
4, G
5, G
6-G
7, G
8, G
9, G
10-G
11, G
12, G
13, G
14, G
15and G
16.
Again more preferably, R
5be selected from G
1, G
2, G
5, G
6-G
7, G
8, G
9, G
10-G
11, G
12, G
14, G
15and G
16.
Again more preferably, R
5be selected from G
2, G
5, G
6-G
7, G
8, G
9, G
10-G
11, G
14and G
16.
Most preferably, R
5be selected from G
2, G
5, G
8and G
10-G
11.
R
6be selected from hydrogen and SH.
Most preferably, R
6hydrogen.
In one group of compound, R
6sH.
R
7hydrogen, halogen or C
1-C
4alkyl.
Preferably, R
7hydrogen or C
1-C
4alkyl.
Most preferably, R
7hydrogen.
R
8and R
9hydrogen, halogen, cyano group, C independently of one another
1-C
12alkyl, C
2-C
12thiazolinyl, C
2-C
12alkynyl, C
1-C
12alkoxyl, formoxyl, C
2-C
12alkyl-carbonyl, C
3-C
12alkenyl carbonyl, carboxyl, C
2-C
12alkoxy carbonyl and C
4-C
12alkenyloxycarbonyl, or be independently selected from the substituting group list of lower group to polysubstituted C
1-C
12alkyl, C
2-C
12thiazolinyl, C
2-C
12alkynyl, C
1-C
12alkoxyl, C
2-C
12alkyl-carbonyl, C
3-C
12alkenyl carbonyl, C
2-C
12alkoxy carbonyl and C
4-C
12alkenyloxycarbonyl, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or R
8and R
9form C together
2-C
8alkylidene bridge, its substituting group list that optionally can be selected from lower group is to polysubstituted, and this group is made up of the following: halogen, cyano group, C
1-C
6alkyl and C
1-C
6alkylhalide group; Or R
8and R
9group A-, A-O-or A-(C independently of one another
1-C
6alkyl)-.
R
10h, C
1-C
4alkyl, C
2-C
4thiazolinyl or C
1-C
4alkylhalide group.
R
13hydrogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6thiazolinyl, C
3-C
6haloalkenyl, C
3-C
6alkynyl, C
3-C
8cycloalkyl, C
3-C
8halogen cycloalkyl, phenyl and benzyl, or by halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group or C
1-C
6alkoxyl list is to polysubstituted phenyl and benzyl.
R
14and R
15c independently of one another
1-C
6alkyl, C
3-C
8cycloalkyl, C
1-C
6alkylhalide group, C
3-C
8halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, benzyl or phenyl, or be selected from independently of one another lower group substituting group replace benzyl or phenyl, this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl.
R
51, R
52, R
53halogen, cyano group, C independently of one another
1-C
6alkyl, C
2-C
6thiazolinyl, C
3-C
8cycloalkyl, C
5-C
8cycloalkenyl group, C
2-C
6alkynyl, C
1-C
6alkoxyl, benzyl or phenyl.
R
54, R
55, R
56c independently of one another
1-C
6alkyl, C
3-C
6thiazolinyl, C
3-C
8cycloalkyl, C
3-C
6alkynyl, benzyl or phenyl.
R
57and R
58hydrogen, C independently of one another
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6thiazolinyl, C
3-C
6haloalkenyl, C
3-C
6alkynyl, C
3-C
8cycloalkyl, C
3-C
8halogen cycloalkyl, phenyl or benzyl, wherein phenyl or benzyl can be independently selected from the substituting group list of lower group to polysubstituted for it on the phenyl ring, and this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl, or R
57and R
58aziridinyl, azelidinyl, pyrazolinyl, pyrazolidinyl, pyrrolinyl, pyrrolidinyl, imidazolinyl, imidazolidinyl, triazoline base, tetrazolium quinoline base, piperazinyl, piperidyl, morpholinyl, thio-morpholinyl together with their connection nitrogen-atoms, wherein each and then can be selected from the substituting group list of lower group to polysubstituted, and this group is made up of the following: methyl, halogen, cyano group.
R
59hydrogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6thiazolinyl, C
3-C
6haloalkenyl, C
3-C
6alkynyl, C
3-C
8cycloalkyl, C
3-C
8halogen cycloalkyl, benzyl and phenyl, and by halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group or C
1-C
6alkoxyl list is to polysubstituted benzyl and phenyl.
R
60hydrogen, C
1-C
6alkyl, C
3-C
8cycloalkyl, C
1-C
6alkylhalide group, C
3-C
8halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, benzyl or phenyl, or be independently selected from the substituting group list of lower group to polysubstituted benzyl or phenyl, this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl;
R
62hydrogen, C
1-C
6alkyl, C
3-C
8cycloalkyl, C
1-C
6alkylhalide group, C
3-C
8halogen cycloalkyl, C
3-C
6thiazolinyl, C
3-C
6alkynyl, benzyl or phenyl, or be independently selected from the substituting group list of lower group to polysubstituted benzyl or phenyl, this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl.
G
1c
8-C
10the bicyclic system condensed, it can be saturated, or comprises a carbon-to-carbon double bond, and is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
1-C
4alkoxyl, halogen, C
1-C
4one or more groups of alkylhalide group and cyano group replace.
More preferably, G
1c
9-C
10the bicyclic system condensed, it can be saturated, or comprises a carbon-to-carbon double bond, and is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
1-C
4alkoxyl, halogen, C
1-C
4one or more groups of alkylhalide group and cyano group replace.
Again more preferably, G
1c
9-C
10the bicyclic system condensed, it can be saturated, or comprises a carbon-to-carbon double bond, and is optionally independently selected from C
1-C
4alkyl, fluorine, methoxyl group and C
1-C
4one or more groups of fluoroalkyl replace.
More advantageously, G
1saturated C
9-C
10the bicyclic system condensed, it optionally independently can be selected from C
1-C
4alkyl, fluorine, methoxyl group and C
1-C
4one or more groups of fluoroalkyl replace.
Again more advantageously, G
1saturated C
10the bicyclic system condensed, it optionally independently can be selected from C
1-C
4alkyl, fluorine, methoxyl group and C
1-C
4one or more groups of fluoroalkyl replace.
Most preferably, G
1saturated C
10the bicyclic system condensed.
G
2c
3-C
6cycloalkenyl group, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
2-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7alkyl-carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2one or more groups replace;
Again more preferably, G
2c
3-C
6cycloalkenyl group, it is optionally independently selected from halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
2-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6one or more groups of alkylthio group replace.
Advantageously, G
2c
5-C
6cycloalkenyl group, it is optionally independently selected from halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
2-C
6alkylhalide group and C
1-C
6one or more groups of alkoxyl replace.
More advantageously, G
2optionally independently be selected from the C that replaces of one or more groups of fluorine, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group
5-C
6cycloalkenyl groups.
Again more advantageously, G
2optionally by C that one or more fluorine atom replaces
5-C
6cycloalkenyl groups.
Most preferably, G
2c
5-C
6cycloalkenyl groups.
In one group of compound, G
2optionally independently be selected from ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
2-C
6alkylhalide group and C
1-C
6the C of one or more groups replacements of alkoxyl
5-C
6cycloalkenyl groups.
Preferably, in this group compound, G
2optionally independently be selected from the C that replaces of one or more groups of ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group
5-C
6cycloalkenyl groups.
G
3be phenyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4one or more groups of alkoxyl, halogen and cyano group replace, and wherein alkyl is optionally by one or more halogen substiuted.
More preferably, G
3be phenyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
1-C
4fluoroalkyl, C
1-C
4one or more groups of alkoxyl and halogen replace.
Again more advantageously, G
3be phenyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, CHF
2, CF
3, C
1-C
4one or more groups of alkoxyl and halogen replace.
Still more advantageously, G
3be phenyl, it is optionally independently selected from C
1-C
4alkyl, CHF
2, CF
3, C
1-C
4one or more groups of alkoxyl and halogen replace.
Most preferably, G
3it is phenyl.
G
4c
3-C
12cycloalkyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4one or more groups of alkoxyl, halogen and cyano group replace, and wherein these alkyl are optionally by one or more halogen substiuted.
Again more preferably, G
4c
5-C
6cycloalkyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4one or more groups of alkoxyl, halogen and cyano group replace, and wherein alkyl is optionally by one or more halogen substiuted.
Again more advantageously, G
4c
5-C
6cycloalkyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4one or more groups in alkoxyl and halogen replace.
Still more advantageously, G
4c
5-C
6cycloalkyl, it is optionally independently selected from C
1-C
4alkyl, C
1-C
4one or more groups of alkoxyl and halogen replace.
Still more advantageously, G
4cyclohexyl or cyclopenta.
Most preferably, G
4it is cyclohexyl.
G
5c
3-C
7cycloalkyl, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
2-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
2-C
7alkyl-carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl, phenoxy group ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2one or more groups replace.
More preferably, G
5c
3-C
7cycloalkyl, it is optionally independently selected from halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
2-C
6alkylhalide group, C
1-C
6alkoxyl, C
3-C
4alkene oxygen base, phenoxy group and C
1-C
6one or more groups of alkylthio group replace.
Again more preferably, G
5c
3-C
7cycloalkyl, it is independently selected from ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
2-C
6alkylhalide group, C
1-C
6alkoxyl, C
3-C
4alkene oxygen base, phenoxy group and C
1-C
6one or more groups of alkylthio group replace.
Still more preferably, G
5c
5-C
7cycloalkyl, it is independently selected from ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
4alkoxyl, C
3-C
4alkene oxygen base, phenoxy group and C
2-C
6one or more groups of alkylhalide group replace.
Again more advantageously, G
5c
5-C
6cycloalkyl, it is independently selected from ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, and C
2-C
6one or more groups of alkylhalide group replace.
Still more advantageously, G
5c
5-C
6cycloalkyl, it is independently selected from ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, CHF
2and CF
3one or more groups replace.
Most preferably, G
5c
6cycloalkyl, it is independently selected from ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2with-CH (CH
3)-CH (CH
3)
2one or more groups replace.
In another group compound, G
5c
5-C
6cycloalkyl, it is optionally by one or more halogen substiuted.
More preferably, in this set, G
5c
5-C
6cycloalkyl, it is optionally replaced by one or more fluorine.
Even more preferably, in this set, G
5unsubstituted C
5-C
6cycloalkyl.
In another group compound, G
5c
5-C
6cycloalkyl, it is optionally selected from one or more groups replacements of lower group, and this group is made up of the following: C
1-C
4alkoxyl, C
3-C
4alkene oxygen base or phenoxy group.
In another group compound, G
5c
5-C
6cycloalkyl, it is optionally selected from one or more groups replacements of lower group, and this group is made up of the following: methoxyl group, ethyoxyl, C
3-C
4alkene oxygen base and phenoxy group.
G
6be phenyl, it must be replaced by least one fluorine, and is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6one or more groups of halogenated alkyl sulfonyl replace further.
Again more preferably, G
6be phenyl, it must be replaced by least one fluorine, and is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6alkynyloxy group, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6one or more groups of alkyl sulphonyl replace further.
Still more preferably, G
6be phenyl, it must be replaced by least one fluorine, and is optionally independently selected from halogen, CN, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6alkynyl, C
1-C
6alkoxyl, C
3-C
6alkene oxygen base, C
3-C
6alkynyloxy group and C
1-C
6one or more groups of alkylthio group replace further.
Advantageously, G
6be phenyl, it must be replaced by least one fluorine, and is optionally independently selected from halogen, CN, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6one or more groups of alkoxyl replace further.
Again more advantageously, G
6be phenyl, it must be replaced by least one fluorine, and is optionally independently selected from halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
1-C
4one or more groups of alkoxyl replace further.
Still more advantageously, G
6be phenyl, it must be replaced by least one fluorine, and optionally by one or more halogen, CHF
2, CF
3and C
1-C
4alkyl replaces further.
Most preferably, G
6be phenyl, it must be replaced by least one fluorine, and is optionally replaced further by one or more methyl, bromine, iodine or chlorine.
In one group of compound, G
6the phenyl replaced by fluorine in contraposition, and as being further substituted in above figure.
In one group of compound, G
6the phenyl replaced by fluorine at ortho position, and as being further substituted in above figure.
In one group of compound, G
6the phenyl replaced by fluorine in a position, and as being further substituted in above figure.
G
7it is methylene.
G
8be
G
9be
G
10be phenyl, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, phenyl, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl, C
1-C
6one or more groups of halogenated alkyl sulfonyl, phenyl, 2-phenyl-ethynyl and 2-phenyl-ethyl group replace.
Preferably, G
10be phenyl, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, phenyl, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6one or more groups of halogenated alkyl sulfonyl replace.
More preferably, G
10be phenyl, it is optionally independently selected from halogen, CN, OH, SH, CHO, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, phenyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6one or more groups of alkyl sulphonyl replace.
More preferably, G
10be phenyl, it is optionally independently selected from halogen, CN, OH, SH, CHO, methyl, ethyl, n-pro-pyl, isopropyl, phenyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CF
2-CF
3, cyclopropyl, CH=CH
2, C (CH
3)=CH
2, CH=CH (CH
3), C (CH
3)=CH (CH
3), CH=C (CH
3)
2, C (CH
3)=C (CH
3)
2, CH=CF
2, CH=CCl
2, C ≡ CH, methoxyl group, ethyoxyl, isopropoxy, OCHF
2, OCH
2-C ≡ CH, OCH (CH
3)-C ≡ CH, SCH
3, SCH
2cH
3, S (=O) CH
3, S (=O) CH
2cH
3, S (=O)
2cH
3with S (=O)
2cH
2cH
3one or more groups replace.
Again more advantageously, G
10be phenyl, it is optionally independently selected from halogen, CN, OH, methyl, ethyl, n-pro-pyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CF
2-CF
3, CH=CH
2, C (CH
3)=CH
2, CH=CH (CH
3), C (CH
3)=CH (CH
3), CH=C (CH
3)
2, C (CH
3)=C (CH
3)
2, CH=CF
2, CH=CCl
2, C ≡ CH, methoxyl group, phenyl, ethyoxyl, isopropoxy and OCHF
2one or more groups replace.
Still more advantageously, G
10be phenyl, it is optionally independently selected from halogen, CN, methyl, ethyl, n-pro-pyl, isopropyl, vinyl, methoxyl group, ethyoxyl, isopropoxy, phenyl, CHF
2, CF
3, CHF-CH
3and OCHF
2one or more groups replace.
Most preferably, G
10be phenyl, it is optionally independently selected from halogen, CN, methyl, ethyl, n-pro-pyl, isopropyl, vinyl, methoxyl group, phenyl, CHF
2, CF
3and CHF-CH
3one or more groups replace.
G
11independently be selected from C
1-C
4alkyl, C
1-C
4alkylhalide group, CN, C
1-C
4alkoxyl and C
1-C
4the methylene of at least one group replacement of halogenated alkoxy.
Again more preferably, G
11independently be selected from C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4the methylene of at least one group replacement of halogenated alkoxy.
Again more preferably, G
11independently be selected from C
1-C
4alkyl, C
1-C
4alkylhalide group and C
1-C
4the methylene of at least one group replacement of alkoxyl.
Still more advantageously, G
11independently be selected from methyl, ethyl, CHF
2and CF
3at least one group replace methylene.
Still more advantageously, G
11independently be selected from methyl, CF
3with the methylene that at least one group of ethyl replaces.
Most preferably, G
11by the methylene that at least one group being independently selected from methyl and ethyl replaces.
G
12be
G
13the C containing 0,1 or 2 O or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7alkyl-carbonyl, C
2-C
7-alkoxy carbonyl, C
4-C
7-alkenyloxycarbonyl, C
4-C
7-alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,=O ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2one or more groups replace.
Again more preferably, G
13the C containing 0,1 or 2 O or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6one or more groups of alkylthio group and=O replace.
Most preferably, G
13the C containing 0,1 or 2 O or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, C
1-C
4alkyl, C
1-C
4one or more groups of alkoxyl and=O replace.
G
14be
G
15be
G
16be
G
17be five yuan to unite to single six-membered rings heteroaromatic ring system, it can containing 1 to 4 member being selected from lower group, and this group is made up of the following: N, N (R
69 '), O and S (such as pyridine, pyrimidine, furans, pyrroles, thiazole, oxazole, pyrazoles, imidazoles, oxadiazole, thiadiazoles or tetrazolium), for each loop systems,-O-O-,-S-S-can not be contained with – O-S-fragment, and for these five yuan to hexatomic ring system, himself may be selected from the group list or polysubstituted of lower group, this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyl, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl.
Again more advantageously, G
17be five yuan to unite to single six-membered rings heteroaromatic ring system, it can containing 1 to 4 member being selected from lower group, and this group is made up of the following: N, N (R
69 '), O and S, for each loop systems, can not contain-O-O-,-S-S-with – O-S-fragment, and these five yuan may be selected from the group list or polysubstituted of lower group to hexatomic ring system self, this group is made up of the following: halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, phenyl or benzyl, wherein this phenyl or benzyl are optionally by halogen, CN, C
1-C
4alkyl or C
1-C
4alkylhalide group replaces.
Still more advantageously, G
17be five yuan to unite to single six-membered rings heteroaromatic ring system, it can containing 1 or 2 member being selected from lower group, and this group is made up of the following: N, N (R
69 '), O and S, for each loop systems, can not-O-O-,-S-S-be contained with – O-S-fragment, and for these five yuan to hexatomic ring system, himself may be selected from the group list or polysubstituted of lower group, this group is made up of the following: halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, phenyl or benzyl, wherein phenyl or benzyl are optionally by halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group replaces.
Most preferably, G
17be five yuan to unite to single six-membered rings heteroaromatic ring system, it can containing 1 or 2 member being selected from lower group, this group is made up of the following: N, O and S, for each loop systems,-O-O-,-S-S-can not be contained with – O-S-fragment, and for these five yuan to hexatomic ring system, himself may be selected from the group list or polysubstituted of lower group, this group is made up of the following: halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, phenyl or fluorophenyl.
In one group of compound, G
17be selected from pyridine, pyrimidine, furans, pyrroles, thiazole, oxazole, pyrazoles, imidazoles, oxadiazole, thiadiazoles or tetrazolium, wherein each can be selected from one or more groups replacements of lower group, and this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6one or more groups of halogenated alkyl sulfonyl replace further.
Again more advantageously, in this set, G
17be selected from pyridine, pyrimidine, furans, pyrroles, thiazole, oxazole, pyrazoles, imidazoles, oxadiazole, thiadiazoles or tetrazolium, wherein each can be selected from one or more groups replacements of lower group, and this group is made up of the following: halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, phenyl or benzyl, wherein phenyl or benzyl are optionally by halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group replaces.
Still more advantageously, in this set, G
17be selected from pyridine, pyrimidine, furans, pyrroles, thiazole, oxazole, pyrazoles or imidazoles, wherein each can be selected from one or more groups replacements of lower group, and this group is made up of the following: halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, phenyl or benzyl, wherein phenyl or benzyl are optionally by halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group replaces.
Most preferably, in this set, G
17be selected from pyridine, furans, pyrroles, thiazole Huo oxazole or imidazoles, wherein each can be selected from one or more groups replacements of lower group, and this group is made up of the following: halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, phenyl or fluorophenyl.
In another group compound, G
17be five yuan to unite to single six-membered rings heteroaromatic ring system, it can containing 1 member being selected from lower group, this group is made up of (such as pyridine, furans or pyrroles) N and O, these five yuan may be selected from the group list or polysubstituted of lower group to hexatomic ring system self, and this group is made up of the following: halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl or C
1-C
4halogenated alkoxy.
Preferably, in this set, G
17be pyridine, furans or pyrroles, wherein each can be selected from the group list or polysubstituted of lower group, and this group is made up of the following: halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl or C
1-C
4halogenated alkoxy.
In another group compound, G
17be five yuan to unite to single six-membered rings heteroaromatic ring system, it can containing 2 members being selected from lower group, this group is made up of the following: N, O and S (Li is as oxazole or thiazole), for each loop systems,-O-O-,-S-S-can not be contained with – O-S-fragment, and these five yuan may be selected from the group list or polysubstituted of lower group to hexatomic ring system self, and this group is made up of the following: halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, phenyl or fluorophenyl.
Preferably, in this set, G
17shi oxazole or thiazole, wherein each can be selected from the group list or polysubstituted of lower group, and this group is made up of the following: halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, phenyl or fluorophenyl.
R
1 'be selected from lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
2 ', R
3 ', R
4 'and R
5 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4alkylthio group.
Again more preferably, R
1 'be selected from lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl and C
1-C
4fluoroalkyl;
R
2 ', R
3 ', R
4 'and R
5 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4alkylthio group.
Still more preferably, R
1 ', R
2 ', R
3 ', R
4 'and R
5 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, methoxyl group, ethyoxyl and S-CH
3s-CH
2cH
3.
Again more advantageously, R
1 'be selected from lower group, this group is made up of the following: hydrogen, fluorine, methyl, CH
2f and CF
3;
R
2 ', R
3 ', R
4 'and R
5 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, CH
2f, CF
3and methoxyl group.
Most preferably, R
1 ', R
2 ', R
3 ', R
4 'and R
5 'in each is hydrogen.
R
11 ', R
12 ', R
13 'and R
14 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, phenyl, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, benzyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl.
Again more preferably, R
11 ', R
12 ', R
13 'and R
14 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6alkylthio group.
Again more advantageously, R
11 ', R
12 ', R
13 'and R
14 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, CHF
2, CF
3and C
1-C
4alkoxyl.
Most preferably, R
11 ', R
12 ', R
13 'and R
14 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkoxyl.
R
15 'and R
16 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group.
Again more preferably, R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3and CF
2cF
3;
R
23 ', R
24 'and R
25 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group.
Advantageously, R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'independently be selected from lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
23 ', R
24 'and R
25 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group.
More advantageously, R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'independently be selected from hydrogen, fluorine, methyl, ethyl, CH
2f, CHF
2and CF
3and isopropyl;
R
23 ', R
24 'and R
25 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group.
Again more advantageously, R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'independently be selected from hydrogen, fluorine, methyl, ethyl, CH
2f, CHF
2, CF
3and isopropyl;
R
23 ', R
24 'and R
25 'independently be selected from lower group, this group is made up of the following: hydrogen, methyl, fluorine, chlorine, bromine, ethyl, CH
2f, CHF
2and CF
3and isopropyl.
Still more advantageously, R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently selected from hydrogen, fluorine, methyl, ethyl, CH
2f, CHF
2, CF
3and isopropyl;
R
23 ', R
24 'and R
25 'independently be selected from hydrogen, fluorine, chlorine, bromine, methyl, ethyl and isopropyl.
Most preferably, R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 ', R
22 ', R
23 ', R
24 'and R
25 'in each is independently selected from hydrogen, methyl, ethyl and isopropyl.
In one group of compound, R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: hydrogen, methyl, F and CF
3.
In this set, R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is most preferably hydrogen.
In the compound that another is preferably organized, R
15 'as previously discussed, and R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen.
In another group compound, R
23 ', R
24 'and R
25 'independently be selected from lower group, this group is made up of the following: hydrogen, fluorine, chlorine, bromine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3.
R
26 'c (R
36 ')
2, N-OH, N-O-C
1-C
4-alkyl, N-O-C
2-C
4-thiazolinyl, N-O-C
2-C
4alkynyl, N-O-C
1-C
4alkylhalide group, N-O-C
2-C
4haloalkenyl, N-O-benzyl, N-O-phenyl, N-O-halobenzene base, O, wherein N-O-benzyl and N-O-phenyl can be replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: halogen, methyl and halomethyl.
Most preferably, R
26 'n-OH, N-O-C
1-C
4alkyl, N-O-C
2-C
4thiazolinyl, N-O-C
2-C
4alkynyl, N-O-C
1-C
4alkylhalide group, N-O-C
2-C
4haloalkenyl, N-O-benzyl, N-O-phenyl, N-O-halobenzene base, O or C (R
36 ').
R
27 ', R
28 ', R
29 ', R
30 ', R
31 ', R
32 ', R
33 ', R
34 'and R
35 'in each is independently selected from lower group, this group is made up of the following: hydrogen, hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, halogen, C
1-C
4alkylhalide group, C
2-C
4haloalkenyl, cyano group, benzyl and phenyl;
Or R
28 'and R
29 'be attached to them together with two carbon atoms on it and form double bond.
Again more preferably, R
27 ', R
28 ', R
29 ', R
30 ', R
31 ', R
32 ', R
33 ', R
34 'and R
35 'in each is independently selected from lower group, this group is made up of the following: hydrogen, hydroxyl, C
1-C
4alkyl, C
1-C
4alkoxyl and halogen;
Or R
28 'and R
29 'be attached to them together with two carbon atoms on it and form double bond.
Again more advantageously, R
27 ', R
28 ', R
29 ', R
30 ', R
31 ', R
32 ', R
33 ', R
34 'and R
35 'in each is independently selected from lower group, this group is made up of the following: hydrogen, C
1-C
4alkyl and halogen;
Or R
28 'and R
29 'be attached to them together with two carbon atoms on it and form double bond.
Still more advantageously, R
27 ', R
28 ', R
29 ', R
30 ', R
31 ', R
32 ', R
33 ', R
34 'and R
35 'in each is hydrogen or methyl;
Or R
28 'and R
29 'be attached to them together with two carbon atoms on it and form double bond.
Most preferably, R
27 'hydrogen or methyl;
R
28 ', R
29 ', R
30 ', R
31 ', R
32 ', R
33 ', R
34 'and R
35 'in each is hydrogen;
Or R
28 'and R
29 'be attached to them together with two carbon atoms on it and form double bond.
Each R
36 'independently be selected from hydrogen, halogen and C
1-C
4alkyl.
R
37 'and R
38 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group.
Again more preferably, R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl.
Advantageously, R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3.
Again more advantageously, R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 "independently be selected from lower group, this group is made up of the following: hydrogen, fluorine, methyl and trifluoromethyl.
Still more advantageously, R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 "hydrogen or methyl.
Most preferably, R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 "hydrogen.
In one group of compound, R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 "in each is hydrogen, and R
37 'as above definition.
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl.
Again more preferably, R
45 ', R
46 ', R
47 ', R
48 'and R
49 'independently be selected from lower group, this group is made up of the following: hydrogen, fluorine, chlorine, bromine, iodine, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, ethyoxyl, difluoro-methoxy, trifluoromethoxy, methyl mercapto, methylsulfinyl and mesyl.
Most preferably, R
45 ', R
46 ', R
47 ', R
48 'and R
49 'independently be selected from lower group, this group is made up of the following: hydrogen, fluorine, chlorine, methyl, CF
3, CHF
2, CH
2f, methoxyl group, difluoro-methoxy and trifluoromethoxy.
R
50 'be selected from lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
51 ', R
52 ', R
53 ', R
54 ', R
55 'and R
56 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4alkoxyl and C
1-C
4alkylthio group.
Again more preferably, R
50 'be selected from lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl, C
1-C
4alkylhalide group;
R
51 ', R
52 ', R
53 ', R
54 ', R
55 'and R
56 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4alkoxyl and C
1-C
4halogenated alkoxy.
Advantageously, R
50 ', R
51 ', R
52 ', R
53 ', R
54 ', R
55 'and R
56 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, CH
2f, CHF
2, CF
3, CHF-CH
3and CF
2-CH
3.
More advantageously, R
50 ', R
51 ', R
52 ', R
53 ', R
54 ', R
55 'and R
56 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, CH
2f, CF
3.
Most preferably, R
50 ', R
51 ', R
52 ', R
53 ', R
54 ', R
55 'and R
56 'each is hydrogen.
R
57 ', R
58 ', R
59 'and R
60 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
2-C
6alkoxyl, C
2-C
6halogenated alkoxy, phenyl, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, benzyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
Its condition is R
57 ', R
58 ', R
59 'and R
60 'in at least one is not hydrogen.
Again more preferably, R
57 ', R
58 ', R
59 'and R
60 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, C
1-C
6alkyl and C
1-C
6alkylhalide group;
Its condition is R
57 ', R
58 ', R
59 'and R
60 'in at least one is not hydrogen.
Again more advantageously, R
57 ', R
58 ', R
59 'and R
60 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, CHF
2and CF
3;
Its condition is R
57 ', R
58 ', R
59 'and R
60 'in at least one is not hydrogen.
Most preferably, R
57 ', R
58 ', R
59 'and R
60 'be independently from each other lower group, this group is made up of the following: hydrogen and halogen;
Its condition is R
57 ', R
58 ', R
59 'and R
60 'in at least one is not hydrogen.
In another group compound, R
57 ', R
58 ', R
59 'and R
60 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, phenyl and halobenzene base;
Its condition is R
57 ', R
58 ', R
59 'and R
60 'in at least one is not hydrogen.
In another group compound, R
57 ', R
58 ', R
59 'and R
60 'be independently from each other lower group, this group is made up of the following: hydrogen, methyl, ethyl and hydroxyl-C
2-C
4-alkyl;
Its condition is R
57 ', R
58 ', R
59 'and R
60 'in at least one is not hydrogen.
Preferably in this set, R
57 ', R
58 ', R
59 'and R
60 'be independently from each other lower group, this group is made up of the following: hydrogen and ethoxy;
Its condition is R
57 ', R
58 ', R
59 'and R
60 'in at least one is not hydrogen.
R
61 'and R
62 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
63 ', R
64 ', R
65 ', R
66 ', R
67 'and R
68 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group.
Again more preferably, R
61 'and R
62 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
63 ', R
64 ', R
65 ', R
66 ', R
67 'and R
68 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4halogenated alkoxy.
Again more advantageously, R
61 'and R
62 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, CHF
2and CF
3;
R
62 ', R
63 ', R
64 ', R
65 ', R
66 ', R
67 'and R
68 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, methoxyl group, difluoro-methoxy, trifluoromethoxy, CH
2f and CF
3.
Still more advantageously, R
61 ', R
62 ', R
63 ', R
64 ', R
65 ', R
66 ', R
67 'and R
68 "hydrogen, CHF
2, CF
3or methyl.
Still more advantageously, R
61 ', R
62 ', R
63 ', R
64 ', R
65 ', R
66 ', R
67 'and R
68 "hydrogen or methyl.
Most preferably, R
61 ', R
62 ', R
63 ', R
64 ', R
65 ', R
66 ', R
67 'and R
68 "hydrogen.
R
69 'be selected from hydrogen, C
1-C
4alkyl, C
3-C
4thiazolinyl and C
1-C
4alkyl carboxyl.
Again more preferably, R
69 'be selected from hydrogen, C
1-C
4alkyl and C
1-C
4alkyl carboxyl.
Again more preferably, R
69 'be selected from hydrogen and C
1-C
4alkyl.
Most preferably, R
69 'hydrogen.
N is 0 or 1.
In a compound preferably organized, n is 0.
In the compound that another is preferably organized, n is 1.
P and q is independently selected from 0 and 1.
In one group of compound, p and q is 0.
In another group compound, p and q is 1.
In another group compound, p is 1 and q is 0.
R, s and t are independently selected from 0 and 1.
Again more preferably, r and s is 0, and t is 1 or 0.
Most preferably, in r, s and t, each is 0.
Have in the compound of Formula I at one group, R
1and R
2in each independently selected from hydrogen, C
1-C
4alkyl, C
3-C
4thiazolinyl and C
3-C
4alkynyl;
Or R
1and R
2the nitrogen-atoms be attached on it with them together form pyrrolidines or piperidines;
R
3represent hydrogen, halogen, cyano group, sulfydryl, hydroxyl, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4thiazolinyl, C
2-C
4haloalkenyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, C
3-C
6cycloalkyl, amino, C
1-C
2alkylamino, two (C
1-C
6alkyl) amino, pyrrolidinyl, imidazolinyl, triazoline base, tetrazolium quinoline base, formoxyl, C
2-C
5alkyl-carbonyl, C
2-C
5alkyl halide carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl, C
1-C
6haloalkylthio, C
1-C
6alkylsulfinyl, C
1-C
6halogenated alkyl sulfonyl or C
1-C
6hydroxyalkyl;
R
4represent hydrogen, halogen, cyano group, amino, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
3-C
6cycloalkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, C
1-C
4alkylthio group, C
1-C
4alkyl sulphinyl, C
1-C
4alkyl sulphonyl, methylamino and dimethylamino;
R
5represent hydrogen, C
1-C
12alkyl sulphonyl, C
1-C
12alkyl, C
3-C
12thiazolinyl, C
3-C
12alkynyl or be independently selected from the substituting group list of lower group to polysubstituted C
1-C
12alkyl, C
2-C
12thiazolinyl, C
2-C
12alkynyl, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, azido, formoxyl, C
2-C
7alkyl-carbonyl, C
2-C
7alkyl halide carbonyl, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
R
5(R
51) (R
52) (R
53) Si-, (R
51) (R
52) (R
53) Si-(C
1-C
12alkyl)-, (R
51) (R
52) (R
53) Si-(C
3-C
8cycloalkyl)-, (R
54o) (R
55o) (R
56o) Si-, (R
54o) (R
55o) (R
56o) Si-(C
1-C
12alkyl)-or (R
54o) (R
55o) (R
56o) Si-(C
3-C
8cycloalkyl)-; Or
R
5c
1-C
6alkyl-B-C
1-C
12alkyl, C
2-C
6thiazolinyl-B-C
1-C
12alkyl, C
2-C
6alkynyl-B-C
1-C
12alkyl, C
3-C
8cycloalkyl-B-C
1-C
12alkyl, benzyl-B-C
1-C
12alkyl, phenyl-B-C
1-C
12alkyl, C
1-C
6alkyl-B-C
2-C
12thiazolinyl, C
2-C
6thiazolinyl-B-C
2-C
12thiazolinyl, C
2-C
6alkynyl-B-C
2-C
12thiazolinyl, C
3-C
8cycloalkyl-B-C
2-C
12thiazolinyl, benzyl-B-C
2-C
12thiazolinyl, phenyl-B-C
2-C
12thiazolinyl, C
1-C
6alkyl-B-C
2-C
12alkynyl, C
2-C
6thiazolinyl-B-C
2-C
12alkynyl, C
2-C
6alkynyl-B-C
2-C
12alkynyl, C
3-C
8cycloalkyl-B-C
2-C
12alkynyl, benzyl-B-C
2-C
12alkynyl, phenyl-B-C
2-C
12alkynyl, C
1-C
6alkyl-B-C
3-C
8cycloalkyl, C
2-C
6thiazolinyl-B-C
3-C
8cycloalkyl, C
2-C
6alkynyl-B-C
3-C
8cycloalkyl, C
3-C
8cycloalkyl-B-C
3-C
8cycloalkyl, benzyl-B-C
3-C
12cycloalkyl or phenyl-B-C
3-C
12cycloalkyl, wherein group B Xuan Zi – C (=O)-,-C (=S)-,-C (=NOR
59)-,-C (R
60)=NO-,-ON=C (R
60-O-C)-, (=O)-,-C (=O)-O-,-O-,-S-,-S (=O)-,-S (=O) 2-,-S (=O) (=NR
13)-,-S (=O) (R
14)=N-,-N=S (=O) (R
14)-,-N (R
62)-C=O)-,-C=O)-N (R
62)-,-N (R
62)-SO
2-or-SO
2-N (R
62)-; Or
R
5c
1-C
6alkyl-B-C
1-C
12alkyl, C
2-C
6thiazolinyl-B-C
1-C
12alkyl-, C
2-C
6alkynyl-B-C
1-C
12alkyl, C
3-C
8cycloalkyl-B-C
1-C
12alkyl, benzyl-B-C
1-C
12alkyl, phenyl-B-C
1-C
12alkyl, C
1-C
6alkyl-B-C
2-C
12thiazolinyl, C
2-C
6thiazolinyl-B-C
2-C
12thiazolinyl, C
2-C
6alkynyl-B-C
2-C
12thiazolinyl, C
3-C
8cycloalkyl-B-C
2-C
12thiazolinyl, benzyl-B-C
2-C
12thiazolinyl, phenyl-B-C
2-C
12thiazolinyl, C
1-C
6alkyl-B-C
2-C
12alkynyl, C
2-C
6thiazolinyl-B-C
2-C
12alkynyl, C
2-C
6alkynyl-B-C
2-C
12alkynyl, C
3-C
8cycloalkyl-B-C
2-C
12alkynyl, benzyl-B-C
2-C
12alkynyl, phenyl-B-C
2-C
12alkynyl, C
1-C
6alkyl-B-C
3-C
8cycloalkyl, C
2-C
6thiazolinyl-B-C
3-C
8cycloalkyl, C
2-C
6alkynyl-B-C
3-C
8cycloalkyl, C
3-C
8cycloalkyl-B-C
3-C
8cycloalkyl, benzyl-B-C
3-C
12cycloalkyl, phenyl-B-C
3-C
12cycloalkyl, all these so that be independently selected from the substituting group list of lower group to polysubstituted, this group is made up of the following: halogen, cyano group, hydroxyl, sulfydryl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, formoxyl, C
2-C
6alkyl-carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
R
5a-, A-(C
1-C
6alkyl)-, A-O-(C
1-C
6alkyl)-, A-(C
3-C
6thiazolinyl)-, A-O-(C
4-C
6thiazolinyl)-, A-(C
3-C
6-alkynyl)-, A-O-(C
4-C
6alkynyl)-, A-(C
3-C
8cycloalkyl)-and A-O-(C
3-C
8cycloalkyl)-;
Wherein A be the monocycle of three to ten yuan or the bicyclic system that condenses, it can be aromatic, fractional saturation or completely saturated and can be selected from the hetero atom of lower group containing 1 to 4, this group is made up of the following: nitrogen, oxygen and sulphur, for each loop systems,-O-O-,-S-S-can not be contained with – O-S-fragment, for this three to ten-ring system, possible self coverlet or polysubstituted
A1) replaced by the substituting group being independently selected from lower group, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, azido, formoxyl, carboxyl ,=O ,=S, C
1-C
6alkyl, C
2-C
6thiazolinyl, C
2-C
6alkynyl, C
3-C
8cycloalkyl, C
1-C
6alkylhalide group, C
2-C
6haloalkenyl, C
2-C
6alkynyl halide, C
3-C
8halogen cycloalkyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6haloalkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
8cycloalkyloxy, benzyl, benzyloxy, phenyl and phenoxy group, wherein this benzyl, benzyloxy, phenyl and phenoxy group and then can be independently selected from the substituting group list of lower group to polysubstituted, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, amino, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
A3) replaced by the substituting group being independently selected from lower group, this group is made up of the following: formoxyl, C
2-C
7alkyl-carbonyl, C
2-C
7alkyl halide carbonyl, C
3-C
7alkenyl carbonyl, C
3-C
7haloalkenyl carbonyl, C
4-C
9naphthene base carbonyl, C
4-C
9halogenated cycloalkyl carbonyl, C
2-C
7alkoxy carbonyl, C
2-C
7halo alkoxy carbonyl, C
3-C
7alkenyloxycarbonyl, C
3-C
7alkynes oxygen carbonyl, C
4-C
9cycloalkoxycarbonyl, C
2-C
7alkylthiocarbonyl and benzyloxycarbonyl, and be independently selected from the substituting group list of lower group to polysubstituted benzyloxycarbonyl, this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl; Or
A4) replaced by the substituting group being independently selected from lower group, this group is made up of the following: hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, halogen, C
1-C
4alkylhalide group, C
2-C
4haloalkenyl, cyano group, benzyl, phenyl ,=C (R
36 ')
2,=N-OH ,=N-O-C
1-C
4-alkyl ,=N-O-C
3-C
4thiazolinyl ,=N-O-C
3-C
4alkynyl ,=N-O-C
1-C
4alkylhalide group ,=N-O-C
3-C
4haloalkenyl ,=N-O-benzyl and=N-O-phenyl, wherein=N-O-benzyl and=N-O-phenyl are optionally selected from one or more groups replacements of lower group, and this group is made up of the following: halogen, methyl, halomethyl; Or
R
5the C containing 0,1 or 2 O or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, C
1-C
6alkyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7-alkyl-carbonyl, C
2-C
7-alkoxy carbonyl, C
4-C
7-alkenyloxycarbonyl, C
4-C
7-alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,=O ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2one or more groups replace;
R
6hydrogen;
R
7hydrogen or C
1-C
4alkyl.
Have in the compound of Formula I in another group, R
1and R
2in each is independently selected from hydrogen or C
1-C
4alkyl;
Or R
1and R
2the nitrogen-atoms be attached on it with them together form pyrrolidines or piperidines;
R
3represent hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, amino, C
1-C
2alkylamino, two (C
1-C
6alkyl) amino, pyrrolidinyl, imidazolinyl, triazoline base, formoxyl, phenyl, C
2-C
4alkyl-carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl or C
1-C
6hydroxyalkyl;
R
4be selected from fluorine, chlorine, bromine, C
1-C
4alkyl, C
1-C
4thiazolinyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
3-C
6cycloalkyl;
R
5be selected from G
1, G
2, G
3-G
4, G
5, G
6-G
7, G
8, G
9, G
10-G
11, G
12, G
13, G
14, G
15and G
16;
R
6hydrogen;
R
7be selected from hydrogen or C
1-C
4alkyl;
G
1c
8-C
10the bicyclic system condensed, it can be saturated, or comprises a carbon-to-carbon double bond, and is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
1-C
4alkoxyl, halogen, C
1-C
4one or more groups of alkylhalide group and cyano group replace;
G
2c
3-C
6cycloalkenyl group, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
2-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7alkyl-carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2one or more groups replace;
G
3be phenyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4one or more groups of alkoxyl, halogen and cyano group replace, and wherein this alkyl is optionally by one or more halogen substiuted;
G
4c
3-C
12cycloalkyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4one or more groups of alkoxyl, halogen and cyano group replace, and wherein this alkyl is optionally by one or more halogen substiuted;
G
5c
3-C
7cycloalkyl, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
2-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
2-C
7alkyl-carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl, phenoxy group ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2one or more groups replace;
G
6be phenyl, it must be replaced by least one fluorine, and is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6one or more groups of halogenated alkyl sulfonyl replace further;
G
7it is methylene;
G
8be
G
9be
G
10 is phenyl, and it is optionally independently selected hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, phenyl, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl, C
1-C
6one or more groups of halogenated alkyl sulfonyl, phenyl, 2-phenyl-ethynyl and 2-phenyl-ethyl group replace;
G
11independently be selected from C
1-C
4alkyl, C
1-C
4alkylhalide group, CN, C
1-C
4alkoxyl and C
1-C
4the methylene of at least one group replacement of halogenated alkoxy;
G
12be
G
13the C containing 0,1 or 2 O or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7alkyl-carbonyl, C
2-C
7-alkoxy carbonyl, C
4-C
7-alkenyloxycarbonyl, C
4-C
7-alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,=O ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2one or more groups replace;
G
14be
G
15be
G
16be
G
17be five yuan to unite to single six-membered rings heteroaromatic ring system, it can containing 1 to 4 member being selected from lower group, and this group is made up of the following: N, N (R
69 '), O and S (such as pyridine, pyrimidine, furans, pyrroles, thiazole, oxazole, pyrazoles, imidazoles, oxadiazole, thiadiazoles or tetrazolium), for each loop systems,-O-O-,-S-S-can not be contained with – O-S-fragment, and possible these five yuan self to be selected from the group list or polysubstituted of lower group to hexatomic ring system, this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyl, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
1 'be selected from lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl, C
1-C
4alkylhalide group;
R
2 ', R
3 ', R
4 'and R
5 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4alkylthio group;
R
11 ', R
12 ', R
13 'and R
14 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, phenyl, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, benzyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
15 'and R
16 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
R
26 'c (R
36 ')
2, N-OH, N-O-C
1-C
4-alkyl, N-O-C
2-C
4-thiazolinyl, N-O-C
2-C
4alkynyl, N-O-C
1-C
4alkylhalide group, N-O-C
2-C
4haloalkenyl, N-O-benzyl, N-O-phenyl, N-O-halobenzene base, O, wherein N-O-benzyl and N-O-phenyl can be replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: halogen, methyl and halomethyl;
R
27 ', R
28 ', R
29 ', R
30 ', R
31 ', R
32 ', R
33 ', R
34 'and R
35 'in each is independently selected from lower group, this group is made up of the following: hydrogen, hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, halogen, C
1-C
4alkylhalide group, C
2-C
4haloalkenyl, cyano group, benzyl and phenyl;
Or R
28 'and R
29 'be attached to them together with two carbon atoms on it and form double bond;
Each R
36 'independently be selected from hydrogen, halogen and C
1-C
4alkyl;
R
37 'and R
38 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
50 'be selected from lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
51 ', R
52 ', R
53 ', R
54 ', R
55 'and R
56 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4alkoxyl and C
1-C
4alkylthio group;
R
57 ', R
58 ', R
59 'and R
60 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
2-C
6alkoxyl, C
2-C
6halogenated alkoxy, phenyl, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, benzyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
Its condition is R
57 ', R
58 ', R
59 'and R
60 'in at least one is not hydrogen;
R
61 'and R
62 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
63 ', R
64 ', R
65 ', R
66 ', R
67 'and R
68 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group;
R
69 'be selected from hydrogen, C
1-C
4alkyl and C
1-C
4alkyl carboxyl;
N is 0 or 1;
P and q is independently selected from 0 and 1;
R, s and t are independently selected from 0 and 1.
Have in the compound of Formula I in another group, R
1and R
2in each is C
1-C
4alkyl;
R
3represent hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
1-C
4alkylthio group, C
1-C
4alkyl sulphinyl or C
1-C
4alkyl sulphonyl;
R
4be selected from methyl, ethyl, methoxyl group, fluorine and chlorine;
R
6hydrogen;
R
7hydrogen or C
1-C
4alkyl.
In another group compound, R
1and R
2in each is independently selected from methyl, ethyl and isopropyl;
R
3represent hydrogen, halogen, C
1-C
4alkyl, C
1-C
4alkylhalide group, cyclopropyl, acetenyl or C
1-C
4alkoxyl;
R
4be selected from methyl, methoxyl group, fluorine and chlorine;
R
6hydrogen;
R
7hydrogen.
In another group compound, R
1it is methyl;
R
2it is ethyl;
R
3be selected from hydrogen, bromine, iodine, methyl, CHF
2, cyclopropyl, acetenyl and methoxyl group;
R
4it is methyl;
R
6hydrogen;
R
7hydrogen.
In another group compound, G
1c
9-C
10the bicyclic system condensed, it can be saturated, or comprises a carbon-to-carbon double bond, and is optionally independently selected from C
1-C
4alkyl, fluorine, methoxyl group and C
1-C
4one or more groups of fluoroalkyl replace;
G
2c
3-C
6cycloalkenyl group, it is optionally independently selected from halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
2-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6one or more groups of alkylthio group replace;
G
3be phenyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
1-C
4fluoroalkyl, C
1-C
4one or more groups of alkoxyl and halogen replace;
G
4c
5-C
6cycloalkyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4one or more groups of alkoxyl, halogen and cyano group replace, and wherein this alkyl is optionally by one or more halogen substiuted;
G
5c
3-C
7cycloalkyl, it is optionally independently selected from ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
2-C
6alkylhalide group, C
1-C
6alkoxyl, C
3-C
4alkene oxygen base, phenoxy group and C
1-C
6one or more groups of alkylthio group replace;
G
6be phenyl, it must be replaced by least one fluorine, and is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6alkynyloxy group, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6one or more groups of alkyl sulphonyl replace further;
G
10be phenyl, it is optionally independently selected from halogen, CN, OH, SH, CHO, methyl, ethyl, n-pro-pyl, isopropyl, phenyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CF
2-CF
3, cyclopropyl, CH=CH
2, C (CH
3)=CH
2, CH=CH (CH
3), C (CH
3)=CH (CH
3), CH=C (CH
3)
2, C (CH
3)=C (CH
3)
2, CH=CF
2, CH=CCl
2, C ≡ CH, methoxyl group, ethyoxyl, isopropoxy, OCHF
2, OCH
2-C ≡ CH, OCH (CH
3)-C ≡ CH, SCH
3, SCH
2cH
3, S (=O) CH
3, S (=O) CH
2cH
3, S (=O)
2cH
3with S (=O)
2cH
2cH
3one or more groups replace;
G
11independently be selected from C
1-C
4alkyl, C
1-C
4alkylhalide group, CN, C
1-C
4alkoxyl and C
1-C
4the methylene of at least one group replacement of halogenated alkoxy;
G
13the C containing 0,1 or 2 O or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6one or more groups of alkylthio group and=O replace;
G
17be five yuan to unite to single six-membered rings heteroaromatic ring system, it can containing 1 to 4 member being selected from lower group, and this group is made up of the following: N, N (R
69 '), O and S (such as pyridine, pyrimidine, furans, pyrroles, thiazole, oxazole, pyrazoles, imidazoles, oxadiazole, thiadiazoles or tetrazolium), for each loop systems,-O-O-,-S-S-can not be contained with – O-S-fragment, and possible these five yuan self to be selected from the group list or polysubstituted of lower group to hexatomic ring system, this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyl, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
1 'be selected from lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl and C
1-C
4fluoroalkyl;
R
2 ', R
3 ', R
4 'and R
5 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4alkylthio group;
R
11 ', R
12 ', R
13 'and R
14 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3and CF
2cF
3;
R
23 ', R
24 'and R
25 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
R
26 'n-OH, N-O-C
1-C
4alkyl, N-O-C
2-C
4thiazolinyl, N-O-C
2-C
4alkynyl, N-O-C
1-C
4alkylhalide group, N-O-C
2-C
4haloalkenyl, N-O-benzyl, N-O-phenyl, N-O-halobenzene base, O or C (R
36 ')
2;
R
27 ', R
28 ', R
29 ', R
30 ', R
31 ', R
32 ', R
33 ', R
34 'and R
35 'in each is independently selected from lower group, this group is made up of the following: hydrogen, hydroxyl, C
1-C
4alkyl, C
1-C
4alkoxyl and halogen;
Or R
28 'and R
29 'be attached to them together with two carbon atoms on it and form double bond;
Each R
36 'independently be selected from hydrogen, halogen and C
1-C
4alkyl;
R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'independently be selected from lower group, this group is made up of the following: hydrogen, fluorine, chlorine, bromine, iodine, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, ethyoxyl, difluoro-methoxy, trifluoromethoxy, methyl mercapto, methylsulfinyl and mesyl;
R
50 'be selected from lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
51 ', R
52 ', R
53 ', R
54 ', R
55 'and R
56 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4alkoxyl and C
1-C
4halogenated alkoxy;
R
57 ', R
58 ', R
59 'and R
60 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, C
1-C
6alkyl and C
1-C
6alkylhalide group;
Its condition is R
57 ', R
58 ', R
59 'and R
60 'in at least one is not hydrogen;
R
61 'and R
62 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
63 ', R
64 ', R
65 ', R
66 ', R
67 'and R
68 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4halogenated alkoxy;
R
69 'be selected from hydrogen, C
1-C
4alkyl and C
1-C
4alkyl carboxyl;
N is 0 or 1;
P and q is independently selected from 0 and 1;
R and s is 0, and t is 1 or 0.
In another group compound, G
1saturated C
10the bicyclic system condensed, it is optionally independently selected from C
1-C
4alkyl, fluorine, methoxyl group and C
1-C
4one or more groups of fluoroalkyl replace;
G
2optionally by C that one or more fluorine atom replaces
5-C
6cycloalkenyl groups;
G
3be phenyl, it is optionally independently selected from C
1-C
4alkyl, CHF
2, CF
3, C
1-C
4one or more groups of alkoxyl and halogen replace;
G
4c
5-C
6cycloalkyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4one or more groups in alkoxyl and halogen replace;
G
5c
5-C
6cycloalkyl, it is optionally independently selected from ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, and C
2-C
6one or more groups of alkylhalide group replace;
{ 0>g
6isphenyl, whichmustbesubstitutedbyatleastonefluorineandisoptionall yfurthersubstitutedbyoneormoregroupsindependentlyselecte dfromhalogen, CN, C
1-C
4alkyl, C
1-C
4haloalkylandC
1-C
4alkoxy.
<}93{g
6be phenyl, it must be replaced by least one fluorine, and is optionally independently selected from halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
1-C
4one or more groups of alkoxyl replace further.？
<0}
G
7it is methylene;
G
10be phenyl, it is optionally independently selected from hydrogen, halogen, CN, OH, methyl, ethyl, n-pro-pyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CF
2-CF
3, CH=CH
2, C (CH
3)=CH
2, CH=CH (CH
3), C (CH
3)=CH (CH
3), CH=C (CH
3)
2, C (CH
3)=C (CH
3)
2, CH=CF
2, CH=CCl
2, C ≡ CH, methoxyl group, ethyoxyl, isopropoxy, phenyl and OCHF
2one or more groups replace;
G
11independently be selected from C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4the methylene of at least one group replacement of alkoxyl;
G
13the C containing 0,1 or 2 O or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6one or more groups of alkylthio group and=O replace;
G
17be five yuan to unite to single six-membered rings heteroaromatic ring system, it can containing 1 to 4 member being selected from lower group, and this group is made up of the following: N, N (R
69 '), O and S, for each loop systems, can not contain-O-O-,-S-S-with – O-S-fragment, and these five yuan may be selected from the group list or polysubstituted of lower group to hexatomic ring system self, this group is made up of the following: halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, phenyl or benzyl, wherein phenyl or benzyl are optionally by halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group replaces;
R
1 'be selected from lower group, this group is made up of the following: hydrogen, fluorine, methyl, CH
2f and CF
3;
R
2 ', R
3 ', R
4 'and R
5 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, CH
2f, CF
3and methoxyl group;
R
11 ', R
12 ', R
13 'and R
14 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, CHF
2, CF
3and C
1-C
4alkoxyl;
R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'independently be selected from hydrogen, fluorine, methyl, ethyl, CH
2f, CHF
2, CF
3and isopropyl;
R
23 ', R
24 'and R
25 'independently be selected from lower group, this group is made up of the following: hydrogen, methyl, fluorine, chlorine, bromine, ethyl, CH
2f, CHF
2and CF
3and isopropyl;
R
26 'n-OH, N-O-C
1-C
4alkyl, N-O-C
2-C
4thiazolinyl, N-O-C
2-C
4alkynyl, N-O-C
1-C
4alkylhalide group, N-O-C
2-C
4haloalkenyl, N-O-benzyl, N-O-phenyl, N-O-halobenzene base, O, C
2-C
4alkene oxygen base or C (R
36 ');
R
27 ', R
28 ', R
29 ', R
30 ', R
31 ', R
32 ', R
33 ', R
34 'and R
35 'in each is independently selected from lower group, this group is made up of the following: hydrogen, C
1-C
4alkyl and halogen;
Or R
28 'and R
29 'be attached to them together with two carbon atoms on it and form double bond;
Each R
36 'independently be selected from hydrogen, halogen and C
1-C
4alkyl;
R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 "independently be selected from lower group, this group is made up of the following: hydrogen, fluorine, methyl and trifluoromethyl;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'independently be selected from lower group, this group is made up of the following: hydrogen, fluorine, chlorine, bromine, iodine, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
R
50 ', R
51 ', R
52 ', R
53 ', R
54 ', R
55 'and R
56 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, CH
2f and CF
3;
R
57 ', R
58 ', R
59 'and R
60 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, CHF
2and CF
3;
Its condition is R
57 ', R
58 ', R
59 'and R
60 'in at least one is not hydrogen;
R
61 'and R
62 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, CHF
2and CF
3;
R
62 ', R
63 ', R
64 ', R
65 ', R
66 ', R
67 'and R
68 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, methoxyl group, difluoro-methoxy, trifluoromethoxy, CH
2f and CF
3;
R
69 'be selected from hydrogen and C
1-C
4alkyl;
N is 0 or 1;
P and q is independently selected from 0 and 1;
R and s is 0, and t is 1 or 0.
In another group compound, G
1saturated C
10the bicyclic system condensed;
G
2c
5-C
6cycloalkenyl groups;
G
3it is phenyl;
G
4cyclohexyl or cyclopenta;
G
5c
6cycloalkyl, it is independently selected from ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2with-CH (CH
3)-CH (CH
3)
2one or more groups replace;
G
6be phenyl, it must be replaced by least one fluorine, and is optionally replaced further by one or more methyl, bromine, iodine or chlorine;
G
7it is methylene;
G
10be phenyl, it is optionally independently selected from halogen, CN, methyl, ethyl, n-pro-pyl, isopropyl, vinyl, methoxyl group, ethyoxyl, isopropoxy, phenyl, CHF
2, CF
3, CHF-CH
3and OCHF
2one or more groups replace;
G
11independently be selected from methyl, CF
3, and ethyl at least one group replace methylene;
G
13the C containing 0,1 or 2 O or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, C
1-C
4alkyl, C
1-C
4one or more groups of alkoxyl and=O replace;
G
17be five yuan to unite to single six-membered rings heteroaromatic ring system, it can containing 1 or 2 member being selected from lower group, this group is made up of the following: N, O and S, for each loop systems,-O-O-,-S-S-can not be contained with – O-S-fragment, and these five yuan may be selected from the group list or polysubstituted of lower group to hexatomic ring system self, and this group is made up of the following: halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, phenyl or fluorophenyl;
R
1 ', R
2 ', R
3 ', R
4 'and R
5 'in each is hydrogen;
R
11 ', R
12 ', R
13 'and R
14 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkoxyl;
R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 ', R
22 ', R
23 ', R
24 'and R
25 'in each is independently selected from hydrogen, methyl, ethyl and isopropyl;
R
23 ', R
24 'and R
25 'in each is independently selected from hydrogen, fluorine, chlorine, bromine, methyl, ethyl and isopropyl;
R
26 'n-OH, N-O-C
1-C
4alkyl, N-O-C
2-C
4thiazolinyl, N-O-C
2-C
4alkynyl, N-O-C
1-C
4alkylhalide group, N-O-C
2-C
4haloalkenyl, N-O-benzyl, N-O-phenyl, N-O-halobenzene base, O, C
2-C
4alkene oxygen base and C (R
36 ');
R
27 ', R
28 ', R
29 ', R
30 ', R
31 ', R
32 ', R
33 ', R
34 'and R
35 'in each is hydrogen or methyl;
Or R
27 'and R
28 'be attached to them together with two carbon atoms on it and form double bond;
Each R
36 'independently be selected from hydrogen, halogen and C
1-C
4alkyl;
R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'independently be selected from lower group, this group is made up of the following: hydrogen, fluorine, chlorine, methyl, CF
3, CHF
2, CH
2f, methoxyl group, difluoro-methoxy and trifluoromethoxy;
R
50 ', R
51 ', R
52 ', R
53 ', R
54 ', R
55 'and R
56 'each is hydrogen;
R
57 ', R
58 ', R
59 'and R
60 'be independently from each other lower group, this group is made up of the following: hydrogen and halogen;
Its condition is R
57 ', R
58 ', R
59 'and R
60 'in at least one is not hydrogen;
R
61 ', R
62 ', R
63 ', R
64 ', R
65 ', R
66 ', R
67 'and R
68 'hydrogen;
R
69 'hydrogen;
N is 0 or 1;
P and q is independently selected from 0 and 1;
In r, s and t, each is 0.
In the compound that another is preferably organized, R
5g
1.
In the compound that another is preferably organized, R
5g
2.
In the compound that another is preferably organized, R
5g
3-G
4.
In the compound that another is preferably organized, R
5g
5.
In the compound that another is preferably organized, R
5g
6-G
7.
In the compound that another is preferably organized, R
5g
8.
In the compound that another is preferably organized, R
5g
9.
In the compound that another is preferably organized, R
5g
10-G
11.
In the compound that another is preferably organized, R
5g
12.
In the compound that another is preferably organized, R
5g
13.
In the compound that another is preferably organized, R
5g
14.
In the compound that another is preferably organized, R
5g
15.
In the compound that another is preferably organized, R
5g
16.
In the compound of other groups, R
1be selected from R
1aand R
1b;
R
2it is methyl;
R
3be selected from R
3a, R
3b, R
3c, R
3d, R
3e, R
3f, R
3g, R
3h, R
3i, R
3j, R
3k, R
3l, R
3m, R
3n, R
3o, R
3p, R
3q, R
3r, R
3s, R
3t;
R
4be selected from R
4a, R
4b, R
4c, R
4d, R
4e, R
4f;
R
5be selected from R
5a, R
5b, R
5c, R
5d, R
5e, R
5f, R
5g, R
5h, R
5j, R
5k, R
5l, R
5m, R
5n, R
5o, R
5p, R
5q, R
5r, R
5s, R
5t, R
5u, R
5v, R
5x, R
5y, R
5z, R
5ab, R
5ac, R
5ad, R
5ae, R
5af, R
5ag, R
5ah, R
5aj, R
5ak, R
5al, R
5am, R
5aa, R
5bb, R
5cc, R
5dd, R
5ee, R
5ff, R
5gg, R
5hh, R
5jj, R
5kk, R
5ll, R
5mm, R
5nn, R
5oo, R
5pp, R
5qq, R
5rr, R
5ss, R
5tt, R
5uu, R
5vv, R
5ww, R
5xx, R
5zz, R
5ba, R
5bc, R
5bd, R
5be, R
5bf, R
5bg, R
5bh, R
5bi, R
5bj, R
5bk, R
5bl, R
5bm, R
5bn, R
5bo, R
5bp, R
5bq, R
5br, R
5bs, R
5bt, R
5bu, R
5bv, R
5bw, R
5bx, R
5by, R
5bz, R
5ca, R
5cb, R
5cd, R
5ce, R
5cf, R
5cg, R
5ch, R
5ci, R
5cj, R
5ck, R
5cl, R
5cm, R
5cn, R
5co, R
5cp, R
5cq, R
5cr, R
5cs, R
5ct, R
5cu, R
5cv, R
5cw, R
5cx, R
5cy, R
5cz, R
5da, R
5db, R
5dc, R
5de, R
5df, R
5dg, R
5dh, R
5di, R
5dj, R
5dk, R
5dl, R
5dm, R
5dn, R
5do, R
5dp, R
5dq, R
5dr, R
5ds, R
5dt, R
5du, R
5dv, R
5dw, R
5dx, R
5ea, R
5eb, R
5ec, R
5ed, R
5ef, R
5eg, R
5eh, R
5ei, R
5ej, R
5ek, R
5el, R
5em, R
5en, R
5eo, R
5ep, R
5eq, R
5er, R
5es, R
5et, R
5eu, R
5ev, R
5ex, R
5ey, R
5ez, R
5fa, R
5fb, R
5fc, R
5fd, R
5fe, R
5fg, R
5fh, R
5fi, R
5fj, R
5fk, R
5fl, R
5fm, R
5fn, R
5fo, R
5fp, R
5fq, R
5fr, R
5fs, R
5ft, R
5fu, R
5fv, R
5fw;
R
6be selected from R
6a, R
6band R
6c;
R
7h;
R
1abe selected from ethyl and isopropyl;
R
1bit is ethyl;
R
3abe selected from hydrogen, halogen, CN, methyl, ethyl, isopropyl, CCH, CH=CH
2, H
2c=C-(CH
3), cyclopropyl, halomethyl, haloethyl, methoxyl group, halogen methoxyl group, ethyoxyl, halogen ethyoxyl, methyl mercapto, halogen methyl mercapto, methylsulfinyl, halomethyl sulfinyl, mesyl, halogen mesyl, amino, methylamino, dimethylamino, ethylamino, lignocaine, ethylmethylamino, pyrrolidinyl, imidazolinyl, triazoline base, CHO, CH
2oH, CH (OH) Me and CO-Me;
R
3bbe selected from hydrogen, F, Cl, Br, I, cyano group, methyl, ethyl, isopropyl, methyl fluoride, difluoromethyl, trifluoromethyl, (H
3c)-CHF, methoxyl group and ethyoxyl;
R
3cbe selected from hydrogen, F, Br, I, methyl, ethyl, isopropyl, methyl fluoride, difluoromethyl, trifluoromethyl, (H
3c)-CHF, methoxyl group and ethyoxyl;
R
3dbe selected from hydrogen, halogen, cyano group, methyl, ethyl, isopropyl, C ≡ CH, CH=CH
2, H
2c=C-(CH
3), cyclopropyl, halomethyl, haloethyl, methoxyl group, ethyoxyl, methyl mercapto, halogen methyl mercapto, methylsulfinyl, halomethyl sulfinyl, mesyl, halogen mesyl, amino, methylamino, dimethylamino, ethylamino, lignocaine, ethylmethylamino, pyrrolidinyl, imidazolinyl, triazolidinyl, CHO and CO-Me;
R
3bbe selected from hydrogen, F, Cl, Br, I, cyano group, methyl, ethyl, isopropyl, methyl fluoride, difluoromethyl, trifluoromethyl, (H
3c)-CHF, methoxy and ethyoxyl;
R
3cbe selected from hydrogen, F, Br, I, methyl, ethyl, isopropyl, methyl fluoride, difluoromethyl, trifluoromethyl, (H
3c)-CHF, methoxyl group and ethyoxyl;
R
3ebe selected from hydrogen, halogen, CN, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, halomethyl, haloethyl, methoxyl group, ethyoxyl, methyl mercapto, halogen methyl mercapto, methylsulfinyl, halomethyl sulfinyl, mesyl, halogen mesyl, amino, methylamino, dimethylamino, ethylamino, lignocaine, ethylmethylamino, pyrrolidinyl, imidazolinyl, triazoline base, CHO, CH
2oH, CH (OH) Me and CO-Me;
R
3fbe selected from hydrogen, halogen, CN, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, halomethyl, haloethyl, methoxyl group, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
R
3gbe selected from hydrogen, F, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
R
3hbe selected from hydrogen, Br, I, methyl, ethyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f and methoxyl group;
R
3ibe selected from hydrogen, halogen, CN, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, halomethyl, methoxyl group, halogen methoxyl group, ethyoxyl, methyl mercapto, halogen methyl mercapto, methylsulfinyl, halomethyl sulfinyl, mesyl, halogen mesyl, amino, methylamino, dimethylamino, ethylamino, lignocaine, ethylmethylamino, pyrrolidinyl, imidazolinyl, triazoline base, CHO and CO-Me;
R
3jbe selected from hydrogen, halogen, CN, methyl, ethyl, isopropyl, halomethyl, haloethyl, methoxyl group and ethyoxyl;
R
3kbe selected from hydrogen, halogen, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, methoxyl group and ethyoxyl;
R
3lbe selected from hydrogen, halogen, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, methoxyl group and ethyoxyl;
R
3mbe selected from hydrogen, F, Br, I, methyl, ethyl, CHF
2and methoxyl group;
R
3nbe selected from hydrogen, halogen, CN, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, halomethyl, haloethyl, methoxyl group, ethyoxyl, methyl mercapto, halogen methyl mercapto, methylsulfinyl, halomethyl sulfinyl, mesyl, halogen mesyl, amino, methylamino, dimethylamino, ethylamino, lignocaine, ethylmethylamino, pyrrolidinyl, imidazolinyl, triazoline base, CHO, CH
2oH, CH (OH) Me and CO-Me;
R
3obe selected from hydrogen, halogen, CN, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, halomethyl, haloethyl, methoxyl group, ethyoxyl, methyl mercapto, halogen methyl mercapto, methylsulfinyl, halomethyl sulfinyl, mesyl and halogen mesyl;
R
3pbe selected from hydrogen, F, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, halomethyl, haloethyl, methoxyl group and ethyoxyl;
R
3qbe selected from hydrogen, F, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
R
3rbe selected from hydrogen, Br, I, methyl, cyclopropyl, C ≡ CH, CH=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3and methoxyl group;
R
3sbe selected from hydrogen, halogen, CN, methyl, ethyl, isopropyl, cyclopropyl, the tert-butyl group, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, halomethyl, haloethyl, methoxyl group, halogen methoxyl group, ethyoxyl, halogen ethyoxyl, methyl mercapto, halogen methyl mercapto, methylsulfinyl, halomethyl sulfinyl, mesyl, halomethyl sulfonyl, amino, methylamino, dimethylamino, ethylamino, lignocaine, ethylmethylamino, pyrrolidinyl, imidazolinyl, triazoline base, CHO and C (=O) Me;
R
3tbe selected from hydrogen, halogen, CN, methyl, ethyl, isopropyl, cyclopropyl, the tert-butyl group, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, halomethyl, haloethyl, methoxyl group, halogen methoxyl group, ethyoxyl, halogen ethyoxyl, methyl mercapto, halogen methyl mercapto, methylsulfinyl, halomethyl sulfinyl, mesyl, halomethyl sulfonyl, amino, methylamino, dimethylamino, ethylamino, lignocaine, ethylmethylamino, pyrrolidinyl, imidazolinyl, triazoline base, CHO and C (=O) Me;
{ 0>r
4aisselectedfromF, Cl, Br, C
1-C
4alkyl, C
1-C
4alkenyl, C
1-C
4haloalkylandC
1-C
4cycloalkyl;
<}70{r
4abe selected from F, Cl, Br, C
1-C
4alkyl, C
1-C
4thiazolinyl, C
1-C
4alkylhalide group and C
1-C
4cycloalkyl; ?
<0}
R
4bbe selected from F, Cl, methyl, ethyl, vinyl, propyl group, acrylic, isopropyl, isopropenyl, cyclopropyl, methoxyl group, ethyoxyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
4cbe selected from methyl, ethyl, methoxyl group, F and Cl;
R
4dbe selected from methyl, methoxyl group, F and Cl;
R
4ebe selected from methyl;
R
4fbe selected from methoxyl group, F and Cl;
R
5abe 3 to 6 member cycloalkenyl groups, or can be independently selected from the substituting group list of lower group to polysubstituted 3 to 6 member cycloalkenyl groups, this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7alkyl-carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2;
R
5b3 to 6 member cycloalkenyl groups, or can be independently selected from the substituting group list of lower group to polysubstituted 3 to 6 member cycloalkenyl groups, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5c3 to 6 member cycloalkenyl groups, or can be independently selected from the substituting group list of lower group to polysubstituted 3 to 6 member cycloalkenyl groups, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6fluoroalkyl, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5dbe 5 member cycloalkenyl groups, or can be independently selected from the substituting group list of lower group to polysubstituted 5 member cycloalkenyl groups, this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7alkyl-carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2;
R
5e5 member cycloalkenyl groups, or can be independently selected from the substituting group list of lower group to polysubstituted 5 member cycloalkenyl groups, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5f5 member cycloalkenyl groups, or can be independently selected from the substituting group list of lower group to polysubstituted 5 member cycloalkenyl groups, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6fluoroalkyl, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5gbe 6 member cycloalkenyl groups, or can be independently selected from the substituting group list of lower group to polysubstituted 6 member cycloalkenyl groups, this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7alkyl-carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2;
R
5h6 member cycloalkenyl groups, or can be independently selected from the substituting group list of lower group to polysubstituted 6 member cycloalkenyl groups, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5j6 member cycloalkenyl groups, or can be independently selected from the substituting group list of lower group to polysubstituted 6 member cycloalkenyl groups, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6fluoroalkyl, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5kbe 3 to 7 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 3 to 7 yuan of groups of naphthene base, this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7alkyl-carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2;
R
5l3 to 7 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 3 to 7 yuan of groups of naphthene base, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5m3 to 7 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 3 to 7 yuan of groups of naphthene base, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6fluoroalkyl, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5nbe 3 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 3 yuan of groups of naphthene base, this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7alkyl-carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2;
R
5o3 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 3 yuan of groups of naphthene base, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5p3 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 3 yuan of groups of naphthene base, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6fluoroalkyl, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5qbe 4 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 4 yuan of groups of naphthene base, this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7alkyl-carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2;
R
5r4 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 4 yuan of groups of naphthene base, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5s4 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 4 yuan of groups of naphthene base, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6fluoroalkyl, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5tbe 5 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 5 yuan of groups of naphthene base, this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7alkyl-carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2;
R
5u5 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 5 yuan of groups of naphthene base, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5v5 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 5 yuan of groups of naphthene base, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6fluoroalkyl, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5xbe 6 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 6 yuan of groups of naphthene base, this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7alkyl-carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2;
R
5y6 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 6 yuan of groups of naphthene base, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5z6 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 6 yuan of groups of naphthene base, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6fluoroalkyl, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5abbe 7 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 7 yuan of groups of naphthene base, this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7alkyl-carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2;
R
5ac7 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 7 yuan of groups of naphthene base, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5ad7 yuan of groups of naphthene base, or can be independently selected from the substituting group list of lower group to polysubstituted 7 yuan of groups of naphthene base, this group is made up of the following: halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6fluoroalkyl, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5aeg
8, wherein R
1 ', R
2 ', R
3 ', R
4 'and R
5 'in each is independently selected from hydrogen, fluorine, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4alkylthio group;
And wherein R
11 ', R
12 ', R
13 'and R
14 'in each is independently selected from hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
5afg
8, wherein R
1 ', R
2 ', R
3 ', R
4 'and R
5 'in each is independently selected from hydrogen, fluorine, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4alkylthio group;
And wherein R
11 ', R
12 ', R
13 'and R
14 'in each is independently selected from hydrogen, halogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C6 alkoxyl and C
1-C
6alkylthio group;
R
5agg
8, wherein R
1 ', R
2 ', R
3 ', R
4 'and R
5 'independently be selected from hydrogen, fluorine, methyl, methyl, ethyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, methoxyl group, ethyoxyl, S-CH
3and S-CH
2cH
3;
And wherein R
11 ', R
12 ', R
13 'and R
14 'in each is independently selected from hydrogen, halogen, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4alkylthio group;
R
5ahg
8, wherein R
1 ', R
2 ', R
3 ', R
4 'and R
5 'in each is independently selected from hydrogen, fluorine, methyl, CHF
2, CF
3and methoxyl group;
And wherein R
11 ', R
12 ', R
13 'and R
14 'in each is independently selected from hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
5ajg
8, wherein R
1 ', R
2 ', R
3 ', R
4 'and R
5 'in each is independently selected from hydrogen, fluorine, methyl, CHF
2, CF
3and methoxyl group;
And wherein R
11 ', R
12 ', R
13 'and R
14 'in each is independently selected from hydrogen, halogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5akg
8, wherein R
1 ', R
2 ', R
3 ', R
4 'and R
5 'in each is independently selected from hydrogen, fluorine, methyl, CHF
2, CF
3and methoxyl group;
And wherein R
11 ', R
12 ', R
13 'and R
14 'in each is independently selected from hydrogen, halogen, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4alkylthio group;
R
5alg
8, wherein R
1 ', R
2 ', R
3 ', R
4 'and R
5 'in each is hydrogen;
And wherein R
11 ', R
12 ', R
13 'and R
14 'in each is independently selected from hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
5amg
8, wherein R
1 ', R
2 ', R
3 ', R
4 'and R
5 'in each is hydrogen;
And wherein R
11 ', R
12 ', R
13 'and R
14 'in each is independently selected from hydrogen, halogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
5aag
8, wherein R
1 ', R
2 ', R
3 ', R
4 'and R
5 'in each is hydrogen;
And wherein R
11 ', R
12 ', R
13 'and R
14 'in each is independently selected from hydrogen, halogen, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4alkylthio group;
R
5bbbe benzyl, wherein phenyl ring is replaced by least one fluorine and one or more groups of being optionally independently selected from lower group, and this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
5ccbe benzyl, wherein phenyl ring is replaced by least one fluorine and one or more groups of being optionally independently selected from lower group, and this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6alkynyloxy group, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl;
R
5ddbe benzyl, wherein phenyl ring is replaced by least one fluorine and one or more groups of being optionally independently selected from lower group, and this group is made up of the following: hydrogen, halogen, CN, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6alkynyl, C
1-C
6alkoxyl, C
3-C
6alkene oxygen base, C
3-C
6alkynyloxy group and C
1-C
6alkylthio group;
R
5eebe benzyl, wherein phenyl ring is replaced by least one fluorine and one or more groups of being optionally independently selected from lower group, and this group is made up of the following: hydrogen, halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4thiazolinyl, C
3-C
6cycloalkyl and C
1-C
4alkoxyl;
R
5ffbe benzyl, wherein methylene moiety is replaced by least one group being independently selected from lower group, and this group is made up of the following: hydrogen, C
1-C
4alkyl, C
1-C
4alkylhalide group, CN, C
1-C
4alkoxyl and C
1-C
4halogenated alkoxy;
And wherein phenyl ring is optionally replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
5ggbe benzyl, wherein methylene moiety is replaced by least one group being independently selected from lower group, and this group is made up of the following: hydrogen, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
1-C
4alkoxyl;
And wherein phenyl ring is optionally replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
5hhbe benzyl, wherein methylene moiety is replaced by the group being independently selected from lower group, and this group is made up of the following: C
1-C
4alkyl, C
1-C
4alkylhalide group and C
1-C
4alkoxyl;
And wherein phenyl ring is optionally replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
5jjbe benzyl, wherein methylene moiety is replaced by the group being independently selected from lower group, and this group is made up of the following: hydrogen, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
1-C
4alkoxyl;
And wherein phenyl ring is optionally replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
5kkbe benzyl, wherein methylene moiety is replaced by the group being independently selected from lower group, and this group is made up of the following: methyl, ethyl, CHF
2, CF
3and methoxyl group;
And wherein phenyl ring is optionally replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
5llbe benzyl, wherein methylene moiety is replaced by the group being independently selected from lower group, and this group is made up of the following: methyl, ethyl, CHF
2, CF
3and methoxyl group;
And wherein phenyl ring is optionally replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
5mmbe benzyl, wherein methylene moiety is replaced by least one group being independently selected from lower group, and this group is made up of the following: hydrogen, C
1-C
4alkyl, C
1-C
4alkylhalide group, CN, C
1-C
4alkoxyl and C
1-C
4halogenated alkoxy;
And wherein phenyl ring is optionally replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: hydrogen, halogen, CN, OH, SH, CHO, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl;
R
5nnbe benzyl, wherein methylene moiety is replaced by the group being independently selected from lower group, and this group is made up of the following: C
1-C
4alkyl, C
1-C
4alkylhalide group and C
1-C
4alkoxyl;
And wherein phenyl ring is optionally replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: hydrogen, halogen, CN, OH, SH, CHO, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl;
R
5oobe benzyl, wherein methylene moiety is replaced by the group being independently selected from lower group, and this group is made up of the following: methyl, ethyl, CHF
2, CF
3and methoxyl group;
And wherein phenyl ring is optionally replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: hydrogen, halogen, CN, OH, SH, CHO, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl;
R
5ppbe benzyl, wherein methylene moiety is replaced by least one group being independently selected from lower group, and this group is made up of the following: hydrogen, C
1-C
4alkyl, C
1-C
4alkylhalide group, CN, C
1-C
4alkoxyl and C
1-C
4halogenated alkoxy;
And wherein phenyl ring is optionally replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: hydrogen, halogen, CN, OH, SH, CHO, methyl, ethyl, n-pro-pyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CF
2-CF
3, cyclopropyl, CH=CH
2, C (CH
3)=CH
2, CH=CH (CH
3), C (CH
3)=CH (CH
3), CH=C (CH
3)
2, C (CH
3)=C (CH
3)
2, CH=CF
2, CH=CCl
2, C ≡ CH, methoxyl group, ethyoxyl, isopropoxy, OCHF
2, OCH
2-C ≡ CH, OCH (CH
3)-C ≡ CH, SCH
3, SCH
2cH
3, S (=O) CH
3, S (=O) CH
2cH
3, S (=O)
2cH
3with S (=O)
2cH
2cH
3;
R
5qqbe benzyl, wherein methylene moiety is replaced by the group being independently selected from lower group, and this group is made up of the following: C
1-C
4alkyl, C
1-C
4alkylhalide group and C
1-C
4alkoxyl;
And wherein phenyl ring is optionally replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: hydrogen, halogen, CN, OH, SH, CHO, methyl, ethyl, n-pro-pyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CF
2-CF
3, cyclopropyl, CH=CH
2, C (CH
3)=CH
2, CH=CH (CH
3), C (CH
3)=CH (CH
3), CH=C (CH
3)
2, C (CH
3)=C (CH
3)
2, CH=CF
2, CH=CCl
2, C ≡ CH, methoxyl group, ethyoxyl, isopropoxy, OCHF
2, OCH
2-C ≡ CH, OCH (CH
3)-C ≡ CH, SCH
3, SCH
2cH
3, S (=O) CH
3, S (=O) CH
2cH
3, S (=O)
2cH
3with S (=O)
2cH
2cH
3;
R
5rrbe benzyl, wherein methylene moiety is replaced by the group being independently selected from lower group, and this group is made up of the following: methyl, ethyl, CHF
2, CF
3and methoxyl group;
And wherein phenyl ring is optionally replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: hydrogen, halogen, CN, OH, SH, CHO, methyl, ethyl, n-pro-pyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CF
2-CF
3, cyclopropyl, CH=CH
2, C (CH
3)=CH
2, CH=CH (CH
3), C (CH
3)=CH (CH
3), CH=C (CH
3)
2, C (CH
3)=C (CH
3)
2, CH=CF
2, CH=CCl
2, C ≡ CH, methoxyl group, ethyoxyl, isopropoxy, OCHF
2, OCH
2-C ≡ CH, OCH (CH
3)-C ≡ CH, SCH
3, SCH
2cH
3, S (=O) CH
3, S (=O) CH
2cH
3, S (=O)
2cH
3with S (=O)
2cH
2cH
3;
R
5ssg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
R
5ttg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 0 also or 1;
R
5uug
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 0 also or 1;
R
5vvg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 0 also or 1;
R
5wwg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: methyl, F and CF
3;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 0 also or 1;
R
5xxg
9, wherein R
15 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 0 also or 1;
R
5zzg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, methyl fluoride and fluoro ethyl;
R
5bag
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 0 also or 1;
R
5bcg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 0 also or 1;
R
5bdg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen;
R
22 'to R
24 ', be selected from lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 0 also or 1;
R
5beg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: methyl, F and CF
3;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 0 also or 1;
R
5bfg
9, wherein R
15 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 0 also or 1;
R
5bgg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
5bhg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 0 also or 1;
R
5bcg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 0 also or 1;
R
5bjg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 0 also or 1;
R
5bkg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: methyl, F and CF
3;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 0 also or 1;
R
5blg
9, wherein R
15 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen;
R
22 'to R
24 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 0 also or 1;
R
5bmg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 0;
R
5bng
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 0;
R
5bog
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 0;
R
5bpg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 0;
R
5bqg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: methyl, F and CF
3;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 0;
R
5brg
9, wherein R
15 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independent of one another, be selected from the group be made up of hydrogen;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 0;
R
5bsg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 0;
R
5btg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 0;
R
5bug
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 0;
R
5bvg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 0;
R
5bwg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: methyl, F and CF
3;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 0;
R
5bxg
9, wherein R
15 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 0;
R
5byg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 0;
R
5bzg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 0;
R
5cag
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 0;
R
5cbg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 0;
R
5cdg
9, wherein R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: methyl, F and CF
3;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 0;
R
5ceg
9, wherein R
15 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 0;
R
5cfg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 1;
R
5cgg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 1;
R
5chg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 1;
R
5cig
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 1;
R
5cjg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: methyl, F and CF
3;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 1;
R
5ckg
9, wherein R
15 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independent of one another, be selected from the group be made up of hydrogen;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
N is 1;
R
5clg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 1;
R
5cmg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 1;
R
5cng
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 1;
R
5cog
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 1;
R
5cpg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: methyl, F and CF
3;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 1;
R
5cqg
9, wherein R
15 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
N is 1;
R
5crg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 1;
R
5csg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 1;
R
5ctg
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 1;
R
5cug
9, wherein R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 1;
R
5cvg
9, wherein R
15 'and R
16 'be independently from each other lower group, this group is made up of the following: methyl, F and CF
3;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 1;
R
5cwg
9, wherein R
15 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'in each is hydrogen;
R
23 ', R
24 'and R
25 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
N is 1;
R
5cxg
14, wherein G
14be
Wherein R
37 'and R
38 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P and q is independently selected from 0 and 1;
R
5cyg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P and q is independently selected from 0 and 1;
R
5czg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P and q is independently selected from 0 and 1;
R
5dag
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: methyl, ethyl, F and CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P and q is independently selected from 0 and 1;
R
5dbg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P and q is independently selected from 0 and 1;
R
5dcg
14, wherein R
37 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P and q is independently selected from 0 and 1;
R
5deg
14, wherein R
37 'and R
38 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
39 ', R
40 ', R
41 ', R
42 ', R
43 ', and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P and q is independently selected from 0 and 1;
R
5dfg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P and q is independently selected from 0 and 1;
R
5dgg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P and q is independently selected from 0 and 1;
R
5dhg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: methyl, ethyl, F and CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P and q is independently selected from 0 and 1;
R
5dig
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P and q is independently selected from 0 and 1;
R
5djg
14, wherein R
37 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P and q is independently selected from 0 and 1;
R
5dkg
14, wherein R
37 'and R
38 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P and q is independently selected from 0 and 1;
R
5dlg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P and q is independently selected from 0 and 1;
R
5dmg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3,cH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P and q is independently selected from 0 and 1;
R
5dng
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: methyl, ethyl, F and CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P and q is independently selected from 0 and 1;
R
5dog
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P and q is independently selected from 0 and 1;
R
5dpg
14, wherein R
37 'be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P and q is independently selected from 0 and 1;
R
5dqg
14, wherein R
37 'and R
38 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
In p and q, each is 0;
R
5drg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
In p and q, each is 0;
R
5dsg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
In p and q, each is 0;
R
5dtg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: methyl, ethyl, F and CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
In p and q, each is 0;
R
5dug
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
In p and q, each is 0;
R
5dvg
14, wherein R
37 'be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
In p and q, each is 0;
R
5dwg
14, wherein R
37 'and R
37 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
In p and q, each is 0;
R
5dxg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
In p and q, each is 0;
R
5eag
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
In p and q, each is 0;
R
5ebg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: methyl, ethyl, F and CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
In p and q, each is 0;
R
5ecg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
In p and q, each is 0;
R
5edg
14, wherein R
37 'be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
In p and q, each is 0;
R
5efg
14, wherein R
37 'and R
38 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
In p and q, each is 0;
R
5egg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
In p and q, each is 0;
R
5ehg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
In p and q, each is 0;
R
5eig
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: methyl, ethyl, F and CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
In p and q, each is 0;
R
5ejg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
In p and q, each is 0;
R
5ekg
14, wherein R
37 'be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P is 0;
Q is 1;
R
5elg
14, wherein R
37 'and R
38 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P is 0;
Q is 1;
R
5emg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P is 0;
Q is 1;
R
5eng
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P is 0;
Q is 1;
R
5eog
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: methyl, ethyl, F and CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P is 0;
Q is 1;
R
5epg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P is 0;
Q is 1;
R
5eqg
14, wherein R
37 'be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P is 0;
Q is 1;
R
5erg
14, wherein R
37 'and R
38 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P is 0;
Q is 1;
R
5esg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P is 0;
Q is 1;
R
5etg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P is 0;
Q is 1;
R
5eug
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: methyl, ethyl, F and CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P is 0;
Q is 1;
R
5evg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P is 0;
Q is 1;
R
5exg
14, wherein R
37 'be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P is 0;
Q is 1;
R
5eyg
14, wherein R
37 'and R
38 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P is 0;
Q is 1;
R
5ezg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P is 0;
Q is 1;
R
5fag
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P is 0;
Q is 1;
R
5fbg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: methyl, ethyl, F and CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P is 0;
Q is 1;
R
5fcg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P is 0;
Q is 1;
R
5fdg
14, wherein R
37 'be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P is 0;
Q is 1;
R
5feg
14, wherein R
37 'and R
38 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P is 1;
Q is 1;
R
5fgg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P is 1;
Q is 1;
R
5fhg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P is 1;
Q is 1;
R
5fig
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: methyl, ethyl, F and CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P is 1;
Q is 1;
R
5fjg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P is 1;
Q is 1;
R
5fkg
14, wherein R
37 'be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
P is 1;
Q is 1;
R
5flg
14, wherein R
37 'and R
38 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P is 1;
Q is 1;
R
5fmg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P is 1;
Q is 1;
R
5fng
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P is 1;
Q is 1;
R
5fog
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: methyl, ethyl, F and CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P is 1;
Q is 1;
R
5fpg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P is 1;
Q is 1;
R
5fqg
14, wherein R
37 'be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43and R
44 'hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
P is 1;
Q is 1;
R
5frg
14, wherein R
37 'and R
38 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P is 1;
Q is 1;
R
5fsg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P is 1;
Q is 1;
R
5ftg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3,cH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P is 1;
Q is 1;
R
5fug
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: methyl, ethyl, F and CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P is 1;
Q is 1;
R
5fvg
14, wherein R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'in each is hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P is 1;
Q is 1;
R
5fwg
14, wherein R
37 'be selected from hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CH
2-CH
2f, CH
2-CHF
2and CH
2-CF
3;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, F, Cl, methyl, CF
3, CHF
2, CH
2f, methoxyl group and trifluoromethoxy;
P is 1;
Q is 1;
R
6abe selected from hydrogen and SH;
R
6bhydrogen;
R
6csH.
Every a line of table N describes a preferred subgroup of the N1-N757 from this group.For clearly reason, note in these subgroups, R
2always methyl, and R
7always hydrogen.Such as subgroup N1 is one group of compound with chemical formula (I), wherein
R
1r
1b;
R
2it is methyl;
R
3r
3a;
R
4r
4c;
R
5r
5a;
R
6r
6b;
R
7h.
table N
Can by this and as method illustrated in WO2008/101682, the additive method preparation known in many ways together with chemist has the compound of Formula I together with used intermediate and reagent, or they are commercially available.
In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is tpn.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component Shi Fu Evil bacterium.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is cyprodinil.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is fenpropidin.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is mandipropamid.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is fluazinam.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is procymidone.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is carbendazim.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Avermectin.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is clothianidin.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is according to mark's butylbenzene formates.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Imidacloprid.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is many tefluthrins.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Metalaxyl-M.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Orocymedone.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Diacloden.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is λ-three cyhalothrin.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is γ-three cyhalothrin.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Profenofos.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is lufenuron.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is diflubenzuron.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is cypermethrin.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Rimon.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Biphenthrin.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is methomyl.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Chlorpyrifos.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is acephatemet.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is 5a,6,9,9a-hexahydro-6,9-methano-2,4.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is β-cyhalothrin.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is desinsection urea.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is diflubenzuron.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is orthene.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is glyphosate.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is careless fourth phosphine.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Mesotrione.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is two ring benzofenaps (Bicyclopyrone).In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Tembotrione.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is sulphur humulone.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is 2,4-D.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is MCPA.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is TrinexAN_SNacethyl ethyl ester.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component adjusts naphthenic acid-Ca.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is paclobutrazol.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is my acid benzene-S-methyl.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is methyl jasmonate.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is cis-jasmone.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is manganese.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is cyflufenamid.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is isobutyl ethoxyquin (Tebufloquin).In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is copper.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is SYP-3375.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Dicloaminostrobin.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is fluorine bacterium mite ester.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is azoles amine bacterium ester.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is azoles bacterium ester.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is oxime bacterium ester.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Fluoxastrobin.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is pyraclostrobin.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is ZEN 90160.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and the B component fragrant bacterium ester that is first.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Enestroburin.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is chlorine nalidixic bacterium ester.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is fluoxastrobin.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is dimoxystrobin.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is alkene oxime amine.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is the compound with Formulae II.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is cyproconazole.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Difenoconazole.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is metconazole.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is propiconazole.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is oxole bacterium.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Tebuconazole.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Flutriafol.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is kind of a bacterium azoles.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is 1-(2-chlorphenyl)-2-(1-chlorine ring third-1-base)-3-(1,2,4-triazol-1-yl) propan-2-ol [CAS 120983-64-4].In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is prothioconazoles.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is (S)-[3-(the fluoro-phenyl of the chloro-2-of 4-)-5-(2,4-difluorophenyl)-isoxazole-4-bases]-pyridin-3-yl-methyl alcohol [CAS 1229606-46-5].In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is 3-(the fluoro-phenyl of the chloro-2-of 4-)-5-(2,4-difluorophenyl)-isoxazole-4-bases]-pyridin-3-yl-methyl alcohol [CAS 1229605-96-2].In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is SYP-Z048.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is 3-(difluoromethyl)-N-methoxyl group-1-methyl-N-[1-methyl-2-(2,4,6-trichlorophenyl) ethyl]-1H-pyrazole-4-carboxamide [CAS 1228284-64-7].In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is N-[9-(dichloromethylene)-1,2,3,4-tetrahydrochysene-Isosorbide-5-Nitrae-endo-methylene group naphthalene-5-base]-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide [CAS 1072957-71-1].In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is isopyrazam (Isopyrazam).In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is ring third pyrrole bacterium amine.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Boscalid.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is fluorobenzene pyrrole bacterium amine.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is pyrrole metsulfovax.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is Penflufen.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is biphenyl pyrrole bacterium amine.In a further preferred embodiment, component A be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454, and B component is fluorine pyrrole bacterium acid amides.In a further preferred embodiment, the present invention be selected from table 1 to 164 a kind of particular compound, be selected from P.1 to a kind of particular compound P.372 or be selected from Q.001 to a kind of particular compound Q.454.
There is the compound of Formula I, and time suitably, its dynamic isomer, can to exist by the form of one of possible isomer or as these mixture, such as press the form of pure isomer, such as enantiomer and/or diastereoisomer, or as isomer mixture, such as constitutional isomer, stereoisomer, diastereoisomer and enantiomeric mixture, such as raceme, non-enantiomer mixture or racemic mixture, depend on the quantity of the asymmetric carbon atom be present in molecule, absolute with relative configuration, and/or depend on the configuration of the non-aromatic double bond be present in molecule, the present invention relates to pure isomer, and relate to possible all isomer mixtures, and will be understood in above and following often kind situation in this sense, even in each case, when specifically not mentioning stereochemical details.
Similarly, for the compound can selected as B component, when some isomer are possible, then the present invention relates to pure isomer and relate to possible all isomer mixtures.
In order to practical purpose, for for causing the disease protection useful plant that enic microorganisms (such as fungi, bacterium or virus) causes, composition according to the present invention has very favorable activity profile.
The present invention relates to for controlling or preventing useful plant by the method causing enic microorganisms and infect, wherein composition of the present invention is administered to these plants, to it multiple part or on its location.Be the excellent activity under low rate of application according to composition according to the present invention difference, be to be tolerated well by plant, so and in Environmental security.They have very useful treatment, prevention and system performance, and for the protection of multiple useful plant.Composition of the present invention may be used for suppressing or destroying the disease occurring in the plant part (fruit, flower, leaf, stem, stem tuber, root) of the Different Crop of plant or useful plant; also protect those parts of growing plants after a while simultaneously, such as, do not caused enic microorganisms and encroach on.
Also likely use composition of the present invention as the seed dressing (dressingagent) for the treatment of plant propagation material; particularly seed (fruit, stem tuber, grain) and plant cutting (such as rice), for protecting together with for the phytopathogenic fungi appeared in soil for fungal infection.
In addition, composition of the present invention can also be used for the fungi controlling association area, such as, in safeguard industries material, in the protection of (comprising timber and the industrial products relevant with timber), in food preservation or in administration of health.
Composition of the present invention is to being such as effective with the phytopathogenic fungi of infraclass: imperfect fungus (such as Botrytis, Pyricularia Sacc., Helminthosporium, Fusarium, Septoria (Septoria), Cercospora and Alternaria) and basidiomycetes (such as Rhizoctonia, hunchbacked spore Rust (Hemileia), Puccinia).In addition, they are also effective to Ascomycetes (such as Venturia and Erysiphe, Podosphaera (Podosphaera), Mycotoruloides, Uncinula) and Oomycete (such as Phytophthora, pythium, Plasmopara).Observe the excellent activity to powdery mildew (Erysiphe).In addition, composition of the present invention to phytopathogenic bacterium and virus (such as to Xanthomonas, pseudomonas, erwinia amylovora together with to tobacco mosaic virus) effectively.Observe rust, as the excellent activity of leaf rust (Puccinia) and soybean rust (soybean rust bacterium).
Within the scope of the invention, useful plant to be protected is had typically to comprise following plant species: cereal (wheat, barley, rye, oat, rice, corn, Chinese sorghum and relative species); Beet (sugar beet and fodder beet); The operatic circle, drupe and soft water fruit (apple, pears, plum, peach, apricot, cherry, strawberry, raspberry and blackberry); Leguminous plant (beans, shore beans, pea, soybean); Oil crop (rape, leaf mustard, opium poppy, olive, sunflower, coconut, castor oil plant, cocoa bean, peanut); Melon plant (pumpkin, cucumber, muskmelon); Fibre plant (cotton, flax, hemp, jute); Citrus fruit (orange, lemon, grapefruit, oranges and tangerines); Vegetables (spinach, lettuce, asparagus, wild cabbage, carrot, onion, tomato, potato, red pepper); Lauraceae (avocado, Chinese cassia tree, camphor), or plant such as tobacco, nut, coffee, eggplant, sugarcane, tea, pepper, liane, lupulus, banana and natural rubber plant, together with ornamental plants and turf and multiple careless species.
The toxin be included in genetically modified plants gives plant to the tolerance of harmful insect.Such insect can appear in the insect of any taxonomy group, but especially general discovery in beetle (coleoptera), dipteran (diptera) and butterfly (Lepidoptera).
Known containing one or more encodes biocide resistance and the genetically modified plants of gene of expressing one or more toxin and some of them are commercially available.The example of such plant is:
(expressing the corn variety of Cry1Ab toxin); YieldGard
(expressing the corn variety of Cry3Bb1 toxin); YieldGard
(expressing the corn variety of Cry1Ab and Cry3Bb1 toxin);
(expressing the corn variety of Cry9C toxin); Herculex
(express Cry1Fa2 toxin and realize enzyme grass phosphinothricin N acetyl transferase (PAT) of the tolerance to weed killer herbicide grass fourth phosphine ammonium); NuCOTN
(expressing the cotton variety of Cry1Ac toxin); Bollgard
(expressing the cotton variety of Cry1Ac toxin); Bollgard
(expressing the cotton variety of Cry1Ac and Cry2Ab toxin);
(expressing the cotton variety of Vip3A and Cry1Ab toxin);
(expressing the Potato Cultivars of Cry3A toxin);
gTAdvantage (GA21 glyphosate tolerance proterties),
cBAdvantage (Bt11 corn borer (CB) proterties) and
Other examples of such genetically modified crops are:
1.Bt11 corn, from Xian Zhengda seeds company (SyngentaSeedsSAS), Chemindel'Hobit27, F-31790St.Sauveur, France, registration number C/FR/96/05/10.Genetically altered maize, by the Cry1Ab toxin of transgene expression brachymemma, makes it the invasion and attack of resisting European corn borer (corn borer and powder stem snout moth's larva).Bt11 corn also transgene expression PAT enzyme to obtain the tolerance to weed killer herbicide grass fourth phosphine ammonium salt.
2. from from Xian Zhengda seeds company (SyngentaSeedsSAS), Chemindel'Hobit27, F-31790St.Sauveur, the Bt176 corn of France, number of registration C/FR/96/05/10.
Genetically altered maize, by the Cry1Ab toxin of transgene expression brachymemma, makes it the invasion and attack of resisting European corn borer (corn borer and powder stem snout moth's larva).Bt176 corn also transgene expression PAT enzyme to obtain the tolerance to weed killer herbicide grass fourth phosphine ammonium salt.。
3.MIR604 corn from Xian Zhengda seeds company (SyngentaSeedsSAS), Chemindel'Hobit27, F-31790St.Sauveur, France, number of registration C/FR/96/05/10.The corn of insect-resistant is endowed by the Cry3A toxin of transgene expression modification.This toxin is the Cry3A055 by inserting cathepsin-G-protease recognition sequence and modification.The preparation of this kind of transgenic corns is described in WO03/018810.
4.MON863 corn, from Monsanto Company (MonsantoEuropeS.A.) 270-272AvenuedeTervuren, B-1150 Brussels, Belgium, registration number C/DE/02/9.MON863 expresses Cry3Bb1 toxin, and has resistance to some coleopteron.
5.IPC531 cotton, from Monsanto Company (MonsantoEuropeS.A.) 270-272AvenuedeTervuren, B-1150 Brussels, Belgium, registration number C/ES/96/02.
6.1507 corns, from pioneer Worldwide, Inc (PioneerOverseasCorporation) AvenueTedesco, 7B-1160 Brussels, Belgium, registration number C/NL/00/10.Genetically altered corn, marking protein CrylF, to obtain the resistance to some lepidopterous insects, and expresses PAT protein, to obtain the tolerance to weed killer herbicide grass fourth phosphine ammonium salt.
7.NK603 × MON810 corn, from Monsanto Company (MonsantoEuropeS.A.) 270-272AvenuedeTervuren, B-1150 Brussels, Belgium, registration number C/GB/02/M3/03.By genetically altered kind NK603 and MON810 hybridization, be made up of the hybrid corn variety of conventional breeding.NK603 × MON810 corn gene expresses the CP4EPSPS protein obtained by Agrobacterium strains CP4, make it herbicide-resistant Roundup (containing glyphosate), and the Cry1Ab toxin obtained by B. thuringiensis subspecies in addition, make it some lepidopterous insects resistance to, comprise European corn borer.
As used herein, the place that the plant that " location " of term useful plant is intended to include grows thereon, wherein the plant propagation material of this useful plant is sowed or the plant propagation material of wherein this useful plant will be placed in soil.An on-site example is like this field that crop plants grows thereon.
Term " plant propagation material " should be understood to mean the part of the reproduction of plant, and such as seed, these parts can be used to the breeding of the latter, and vegetable matter, such as cutting or stem tuber (such as potato).The part of such as seed (in a strict sense), root, fruit, stem tuber, bulb, rhizome and plant may be mentioned.Plant or the small plants of the germination of transplanting after germination or after emerging from soil can be mentioned.These immature plants can be protected by impregnation process wholly or in part before transplanting.Preferably, " plant propagation material " should be understood to mean seed.
Component A and B can use with unmodified form, or preferably uses together with the carrier that uses conventional in preparation field and adjuvant.
To this, in a known manner component A and B and inert carrier are formulated as missible oil, the cream that can apply, directly can spray or dilution solution, diluting emulsion, wettable powder, soluble powder, dust, particle, and also have encapsulant (such as in polymeric material).According to intended object with account for leading situation and select with regard to types of compositions, to application process (such as spray, be atomized, dusting, broadcast sowing, apply or come down in torrents).These compositions can also contain other adjuvants, and such as stabilizing agent, defoamer, viscosity-controlling agent, adhesive or tackifier are together with fertilizer, micronutrient donors or other are for obtaining the preparation of special-effect.
The carrier be applicable to and adjuvant can be solid or liquid, and are materials useful in preparation technology, the mineral matter of such as natural or regeneration, solvent, dispersant, wetting agent, tackifier, thickener, adhesive or fertilizer.Such as in WO97/33890, describe such carrier.
Composition of the present invention can be applied to plant location or have on pending plant, use simultaneously or sequentially with other compounds.These other compounds can be such as fertilizer or micronutrient donors or other goods affecting plant growth.They can also be the mixture of weed killer herbicide together with insecticide, fungicide, bactericide, nematocide, invertebrate poison or these goods some, if desired, use together with the adjuvant can used with other carriers normally used in preparation field, surfactant or promotion.Other applicable compounds are described in WO2008/101682.
A method for optimizing of the present invention is that foliar spray is used.Frequency of administration and use ratio and will depend on by the risk of corresponding pathogen infection.But, composition of the present invention can also pass through to the liquid formulations perfusion of plant location, or by pressing solid form (such as by particle form) by these compound administration to (soil application) in soil, permeate this plant via soil by root (systemic action).In rice crop, such particle can be applied in paddy field.Can also by flood by the liquid formulations of fungicide seed or stem tuber also or with solid formulation coating they and composition of the present invention is applied to (coating) on seed.
A kind of preparation, i.e. composition of the present invention, and (if desired) comprise a kind of solid or liquid auxiliary agent, can prepare in a known manner, typically via closely mixing and/or grinding this compound and extender, such as solvent, solid carrier, and optionally surface active cpd (surfactant).
These agrochemicals preparations usually containing containing weighing scale from 0.1% to 99%, preferably by weight from 0.1% to 95% active component, by weight from 99.9% to 1%, preferably by weight from 99.8% to 5% solid or liquid auxiliary agent, and by weight from 0% to 25%, preferably by weight from 0.1% to 25% surfactant.
And preferably commodity product(s) being formulated as concentrate, end user will normally use dilution preparation.
Favourable ratio of using is normally active component (a.i.)/hectare (ha) from 1g to 2kg, preferably from 10g to 1kga.i./ha, most preferably from 20g to 600ga.i./ha.When being used as seed wetting agent, use the seed that ratio is the active substance/kg from 10mg to 1g easily.What can determine desired effect by test uses ratio.It depends on the developmental stage of such as type of action, this useful plant and uses (place, arrangement of time, application process), and can change in wide in range restriction due to these parameters.
Described method is effective especially for the phytopathy biology (being commonly referred to rest fungus) that causes of mycota, Basidiomycota, rest fungus guiding principle, rest fungus subclass and Uredinales.Rust species agricultural to king-sized impact comprise layer those of rest fungus section, those of particularly Phakopsora, such as Phakopsora pachyrhizi, it is also called as Asian Soybean rest fungus, and those of handle rest fungus section, those of particularly Puccinia, such as puccinia graminis, also referred to as stem rust or black rust, it is the problem disease in cereal, and Puccinia recondita, also referred to as leaf rust.
To the different microorganisms species of the infected by microbes that can cause in animal, composition of the present invention is effective.The example of such microbial species causes those of aspergillus disease, such as aspergillus fumigatus, aspergillus flavus, Aspergillus terreus, aspergillus nidulans and aspergillus niger; Cause those of blastomycosis, such as Blastomyces dermatitidis; Cause oidiomycotic those, such as Candida albicans, Candida glabrata, Candida tropicalis, Candida parapsilosis (C.parapsilosis), candida krusei and Candida lusitaniae; Cause those of coccidioidomycosis, such as posadasis spheriforme; Cause those of cryptococcosis, such as neogenesis cryptococcus; Cause those of histoplasmosis, such as Histoplasma capsulatum; And cause in conjunction with those of bacterium disease, such as umbrella branch pears head is mould, Rhizomucor pusillus and unrooted rhizopus.Other examples are Fusariums, such as Fusarium oxysporum and Fusarinm solani, and Scedosporium, and such as Scedosporium apiospermum and many births match many pityrosporion ovales.Still other examples are Microsporon, Trichophyton, Epidermophyton, mucor, Sporothrix, Phialophora, Cladosporium, Petriellidium, Paracoccidioides and Histoplasma.
following table provides the selection of compound of the present invention
Table A discloses in the compound with Formula I, variable R
1, R
2, R
5and R
61201 groups of implications.
table A: R
1
, R
2
, R
5
and R
6
implication:
table A: R
1
, R
2
, R
5
and R
6
implication (Continued):
Following table T1 to T151 discloses for comprising as the component A in composition of the present invention, preferably has the compound of Formula I.
table 1:this table discloses 1201 compound T1.1.1 to T1.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.Such as, particular compound T1.1.13 is the compound with chemical formula T1, wherein each variable R
1, R
2, R
5and R
6there is the concrete meaning that the row of Table A is A.1.13 given:
According to identical systems, every other 1201 particular compound disclosed in Table 1 in addition describe in detail similarly together with all particular compound disclosed in table 2 to T151.
table 2:this table discloses 1201 compound T2.1.1 to T2.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 3:this table discloses 1201 compound T3.1.1 to T3.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 4:this table discloses 1201 compound T4.1.1 to T4.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 5:this table discloses 1201 compound T5.1.1 to T5.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 6:this table discloses 1201 compound T6.1.1 to T6.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 7:this table discloses 1201 compound T7.1.1 to T7.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 8:this table discloses 1201 compound T8.1.1 to T8.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 9:this table discloses 1201 compound T9.1.1 to T9.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 10:this table discloses 1201 compound T10.1.1 to T10.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 11:this table discloses 1201 compound T11.1.1 to T11.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 12:this table discloses 1201 compound T12.1.1 to T12.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 13:this table discloses 1201 compound T13.1.1 to T13.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 14:this table discloses 1201 compound T14.1.1 to T14.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 15:this table discloses 1201 compound T15.1.1 to T15.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 16:this table discloses 1201 compound T16.1.1 to T16.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 17:this table discloses 1201 compound T17.1.1 to T17.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 18:this table discloses 1201 compound T18.1.1 to T18.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 19:this table discloses 1201 compound T19.1.1 to T19.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 20:this table discloses 1201 compound T20.1.1 to T20.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 21:this table discloses 1201 compound T21.1.1 to T21.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 22:this table discloses 1201 compound T22.1.1 to T22.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 23:this table discloses 1201 compound T23.1.1 to T23.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 24:this table discloses 1201 compound T24.1.1 to T24.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 25:this table discloses 1201 compound T25.1.1 to T25.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 26:this table discloses 1201 compound T26.1.1 to T26.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 27:this table discloses 1201 compound T27.1.1 to T27.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 28:this table discloses 1201 compound T28.1.1 to T28.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 29:this table discloses 1201 compound T29.1.1 to T29.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 30:this table discloses 1201 compound T30.1.1 to T30.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 31:this table discloses 1201 compound T31.1.1 to T31.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 32:this table discloses 1201 compound T32.1.1 to T32.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 33:this table discloses 1201 compound T33.1.1 to T33.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 34:this table discloses 1201 compound T34.1.1 to T3411201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 35:this table discloses 1201 compound T35.1.1 to T35.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 36:this table discloses 1201 compound T36.1.1 to T36.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 37:this table discloses 1201 compound T37.1.1 to T37.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 38:this table discloses 1201 compound T38.1.1 to T38.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 39:this table discloses 1201 compound T39.1.1 to T39.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 40:this table discloses 1201 compound T40.1.1 to T40.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 41:this table discloses 1201 compound T41.1.1 to T41.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 42:this table discloses 1201 compound T42.1.1 to T42.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 43:this table discloses 1201 compound T43.1.1 to T43.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 44:this table discloses 1201 compound T44.1.1 to T44.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 45:this table discloses 1201 compound T45.1.1 to T45.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 46:this table discloses 1201 compound T46.1.1 to T46.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 47:this table discloses 1201 compound T47.1.1 to T47.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 48:this table discloses 1201 compound T48.1.1 to T48.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 49:this table discloses 1201 compound T49.1.1 to T49.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 50:this table discloses 1201 compound T50.1.1 to T50.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 51:this table discloses 1201 compound T51.1.1 to T51.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 52:this table discloses 1201 compound T52.1.1 to T52.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 53:this table discloses 1201 compound T53.1.1 to T53.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 54:this table discloses 1201 compound T54.1.1 to T54.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 55:this table discloses 1201 compound T55.1.1 to T55.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 56:this table discloses 1201 compound T56.1.1 to T56.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 57:this table discloses 1201 compound T57.1.1 to T57.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 58:this table discloses 1201 compound T58.1.1 to T58.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 59:this table discloses 1201 compound T59.1.1 to T59.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 60:this table discloses 1201 compound T60.1.1 to T60.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 61:this table discloses 1201 compound T61.1.1 to T61.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 62:this table discloses 1201 compound T62.1.1 to T62.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 63:this table discloses 1201 compound T63.1.1 to T63.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 64:this table discloses 1201 compound T64.1.1 to T64.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 65:this table discloses 1201 compound T65.1.1 to T65.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 66:this table discloses 1201 compound T66.1.1 to T66.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 67:this table discloses 1201 compound T67.1.1 to T67.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 68:this table discloses 1201 compound T68.1.1 to T68.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 69:this table discloses 1201 compound T69.1.1 to T69.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 70:this table discloses 1201 compound T70.1.1 to T70.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 71:this table discloses 1201 compound T71.1.1 to T71.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 72:this table discloses 1201 compound T72.1.1 to T72.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 73:this table discloses 1201 compound T73.1.1 to T73.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 74:this table discloses 1201 compound T74.1.1 to T74.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 75:this table discloses 1201 compound T75.1.1 to T75.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 76:this table discloses 1201 compound T76.1.1 to T76.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 77:this table discloses 1201 compound T77.1.1 to T77.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 78:this table discloses 1201 compound T78.1.1 to T78.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 79:this table discloses 1201 compound T79.1.1 to T79.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 80:this table discloses 1201 compound T80.1.1 to T80.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 81:this table discloses 1201 compound T81.1.1 to T81.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 82:this table discloses 1201 compound T82.1.1 to T82.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 83:this table discloses 1201 compound T83.1.1 to T83.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 84:this table discloses 1201 compound T84.1.1 to T84.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 85:this table discloses 1201 compound T85.1.1 to T8511201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 86:this table discloses 1201 compound T86.1.1 to T86.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 87:this table discloses 1201 compound T87.1.1 to T87.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 88:this table discloses 1201 compound T88.1.1 to T88.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 89:this table discloses 1201 compound T89.1.1 to T89.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 90:this table discloses 1201 compound T90.1.1 to T90.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 91:this table discloses 1201 compound T91.1.1 to T91.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 92:this table discloses 1201 compound T92.1.1 to T92.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 93:this table discloses 1201 compound T93.1.1 to T93.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 94:this table discloses 1201 compound T94.1.1 to T9411201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 95:this table discloses 1201 compound T95.1.1 to T95.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 96:this table discloses 1201 compound T96.1.1 to T96.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 97:this table discloses 1201 compound T97.1.1 to T97.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 98:this table discloses 1201 compound T98.1.1 to T98.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 99:this table discloses 1201 compound T99.1.1 to T99.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 100:this table discloses 1201 compound T100.1.1 to T100.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 101:this table discloses 1201 compound T101.1.1 to T101.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 102:this table discloses 1201 compound T102.1.1 to T102.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 103:this table discloses 1201 compound T103.1.1 to T103.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 104:this table discloses 1201 compound T104.1.1 to T104.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 105:this table discloses 1201 compound T105.1.1 to T105.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 106:this table discloses 1201 compound T106.1.1 to T106.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 107:this table discloses 1201 compound T107.1.1 to T107.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 108:this table discloses 1201 compound T108.1.1 to T108.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 109:this table discloses 1201 compound T109.1.1 to T109.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 110:this table discloses 1201 compound T110.1.1 to T110.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 111:this table discloses 1201 compound T111.1.1 to T111.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 112:this table discloses 1201 compound T112.1.1 to T112.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 113:this table discloses 1201 compound T113.1.1 to T113.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 114:this table discloses 1201 compound T114.1.1 to T114.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 115:this table discloses 1201 compound T115.1.1 to T115.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 116:this table discloses 1201 compound T116.1.1 to T116.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 117:this table discloses 1201 compound T117.1.1 to T117.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 118:this table discloses 1201 compound T118.1.1 to T118.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 119:this table discloses 1201 compound T119.1.1 to T119.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 120:this table discloses 1201 compound T120.1.1 to T120.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 121:this table discloses 1201 compound T121.1.1toT121.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 122:this table discloses 1201 compound T122.1.1 to T12211201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 123:this table discloses 1201 compound T123.1.1 to T123.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 124:this table discloses 1201 compound T124.1.1 to T124.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 125:this table discloses 1201 compound T125.1.1 to T125.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 126:this table discloses 1201 compound T126.1.1 to T126.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 127:this table discloses 1201 compound T127.1.1 to T127.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 128:this table discloses 1201 compound T128.1.1 to T128.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 129:this table discloses 1201 compound T129.1.1 to T129.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 130:this table discloses 1201 compound T130.1.1 to T130.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 131:this table discloses 1201 compound T131.1.1 to T131.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 132:this table discloses 1201 compound T132.1.1 to T132.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 133:this table discloses 1201 compound T133.1.1 to T133.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 134:this table discloses 1201 compound T134.1.1 to T134.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 135:this table discloses 1201 compound T135.1.1 to T135.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 136:this table discloses 1201 compound T136.1.1 to T136.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 137:this table discloses 1201 compound T137.1.1 to T137.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 138:this table discloses 1201 compound T138.1.1 to T138.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 139:this table discloses 1201 compound T139.1.1 to T139.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 140:this table discloses 1201 compound T140.1.1 to T140.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 141:this table discloses 1201 compound T141.1.1 to T141.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 142:this table discloses 1201 compound T142.1.1 to T142.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 143:this table discloses 1201 compound T143.1.1 to T143.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 144:this table discloses 1201 compound T144.1.1 to T144.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 145:this table discloses 1201 compound T145.1.1 to T145.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 146:this table discloses 1201 compound T146.1.1 to T146.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 147:this table discloses 1201 compound T147.1.1 to T147.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 148:this table discloses 1201 compound T148.1.1 to T148.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 149:this table discloses 1201 compound T149.1.1 to T149.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 150:this table discloses 1201 compound T150.1.1 to T150.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 151:this table discloses 1201 compound T151.1.1 to T151.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 152:this table discloses 1201 compound T152.1.1 to T152.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 153:this table discloses 1201 compound T153.1.1 to T153.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 154:this table discloses 1201 compound T154.1.1 to T154.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 155:this table discloses 1201 compound T155.1.1 to T155.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 156:this table discloses 1201 compound T156.1.1 to T156.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 157:this table discloses 1201 compound T157.1.1 to T157.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 158:this table discloses 1201 compound T158.1.1 to T158.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 159:this table discloses 1201 compound T159.1.1 to T159.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 160:this table discloses 1201 compound T160.1.1 to T160.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 161:this table discloses 1201 compound T161.1.1 to T161.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 162:this table discloses 1201 compound T162.1.1 to T162.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 163:this table discloses 1201 compound T163.1.1 to T163.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
table 164:this table discloses 1201 compound T164.1.1 to T164.1.1201 with following chemical formula
Wherein for each in these 1201 particular compound, each variable R
1, R
2, R
5and R
6there is concrete meaning given in corresponding line, be suitably selected from 1201 row of Table A A.1.1 to A.1.1201.
In other embodiments, the invention provides novel intermediate to provide the compound according to chemical formula (I), is the compound with chemical formula (IV)
Wherein R
100halogen, SH, C
1-C
4-alkylthio group, C
1-C
4-alkyl sulphinyl, C
1-C
4alkyl sulphonyl, and R
1, R
2, R
3, R
4, R
6and R
7as at this to illustrated by the compound with chemical formula (I).
following table provides the selection of the compound with chemical formula (IV)
The reactive compound of B component is known, such as, from agricultural chemicals handbook (British Crop protective committee).N-[9-(dichloromethylene)-1,2,3,4-tetrahydrochysenes-Isosorbide-5-Nitrae-methyl naphthalene-5-base]-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide has chemical abstracts registry no [1072957-71-1].The compound with chemical formula (II) has chemical abstracts registry no [173662-97-0].Compound (S)-[3-(the fluoro-phenyl of the chloro-2-of 4-)-5-(2 has been found in WO2010069881,4-difluorophenyl)-isoxazole-4-bases]-pyridin-3-yl-methyl alcohol, 3-(the fluoro-phenyl of the chloro-2-of 4-)-5-(2,4-difluorophenyl)-isoxazole-4-bases-pyridin-3-yl-methyl alcohol.
Be selected from the compound with Formula I of table T1 to T164 or be selected from P.1 to P.372 comprising the compound and active component as described above that are selected from and show T1 to T164 with the mixture of active principles of active component described above, the ratio of its mixing is preferably pressed from 100:1 to 1:6000, especially the blending ratio from 50:1 to 1:500, more particularly from 20:1 to 1:200, ratio even more particularly from 10:1 to 1:100, very especially from 5:1 and 1:50, gives to be particularly preferably the ratio from 3:1 to 1:10, and the ratio from 3:1 to 1:5 is same preferred, especially presses 1:1, or 5:1, or 5:2, or 5:3, or 5:4, or 4:1, or 4:2, or 4:3, or 3:1, or 3:2, or 2:1, or 1:5, or 2:5, or 3:5, or 4:5, or 1:4, or 2:4, or 3:4, or 1:3, or 2:3, or 1:2, or 1:600, or 1:300, or 1:150, or 1:35, or 2:35, or 4:35, or 1:75, or 2:75, or 4:75, or 1:6000, or 1:3000, or 1:1500, or 1:350, or 2:350, or 4:350, or 1:750, or 2:750, or 4:750.Those blending ratios are understood to include, and are weight ratios on the one hand, and also have another aspect to be mol ratio.
The compound comprising and there is Formula I can be used, such as be selected from table T1 to T164 or be selected from P.1 to particular compound P.372, and these mixtures of one or more active components as described above, such as with one list " premixing mixture " form, the preparation separated by single active ingredient components form in conjunction with in spraying mixture, such as a kind of " tank mixture ", and (namely once connect applied once using in a sequential manner, there is interval of rational short time interval (such as some hours or some skies)) time, in being combined of single active component.For enforcement the present invention, compound (be such as selected from table T1 to T164 those) and the order of administration of active component described above with Formula I are unimportant.
No matter when there is a kind of synergistic effect, the effect of active ingredient combinations is greater than the effect sum of independent component.
For given active ingredient combinations, the effect E of expection obeys so-called Cole ratio (COLBY) formula and can be carried out as follows calculating (Cole's ratio (COLBY), S.R., " Calculatingsynergisticandantagonisticresponsesofherbicid ecombination ", weeds (Weeds), 15th volume, 20-22 page; 1987):
Ppm=often rises the milligram number of the active component (=a.i.) of spraying mixture
X=uses the active component of pppm by active components A) % effect
Y=uses the active component of qppm by active component B) % effect.
According to Cole's ratio (COLBY), use the active component of p+qppm, (additivity) active components A of expection)+B) effect be
If (O) effect actually observed is greater than the effect (E) of expection, the effect of so this combination is super additivity, namely there is a kind of synergistic effect.With the term of mathematics, the corresponding O/E of synergy factor S F.In agriculture convention, the SF of >=1.2 represents the remarkable improvement of the pure supplementary interpolation to active (expection is active), simultaneously actually using in convention≤SF of 0.9 indicates and the loss of activity of expecting compared with activity.
example
preparation 1-(3,5-difluorophenyl) ethanol
At room temperature, under inert atmosphere (Ar), through the periods of 20 minutes by sodium borohydride (3.41g, 86.47mmol, 0.27 equivalent) be added in the colourless agitating solution of 3 ', the 5 '-difluoro acetophenone (50.00g, 320.24mmol) in methyl alcohol in batches.Then in room temperature, this reactant mixture is stirred 45min, and then carefully carry out cancellation by adding saturated aqueous ammonium chloride solution (150mL).Extract with ethyl acetate (2x200mL).With the organic layer that salt solution (200mL) washing merges, use anhydrous Na
2sO
4dry and filter.Solvent removed in vacuo, to provide title compound (50.29g, 99%), is a kind of colourless oil.This alcohol in statu quo uses in later step.
Thin layer chromatography (TLC): plate: Merck (Merck) thin layer (TLC) chromatosheet, silica gel F
254, the saturated atmosphere in developing tank, UV detect, eluent: heptane/ethyl acetate 4:1 (v/v); The R of title compound
f=0.27.
preparation (-)-(S)-1-(3,5-difluorophenyl) ethanol
To under remaining on inert atmosphere (Ar) and (-)-DIP-Cl ((-)-diisopinocampheylchloroborane base chloroborane) (2.67g be cooled in the THF of-27 DEG C to-25 DEG C, 8.33mmol, 1.3 equivalents) in dropwise add 3 ' through 2min, 5 '-difluoro acetophenone (1.00g, 6.40mmol).Reaction is remained on this temperature 17h.Then acetaldehyde (0.44mL, 7.69mmol, 1.2 equivalents) is used to process this reactant mixture.After this, allowable temperature reaches room temperature and stirred reaction mixture 7h.Then in a vacuum except desolventizing, and the residue segmentation between water and TBME (methyl tertiary butyl ether(MTBE)) (20mL) generated.Again use TBME (20mL) aqueous phase extracted.Use 2NNaOH solution (20mL), salt solution (20mL) wash organic layer, use anhydrous Na
2sO
4dry and filter.Solvent removed in vacuo, to provide a kind of residue, is passed through two column chromatography step purifying subsequently: first by normal phase chromatography (silica gel, heptane/ethyl acetate, v/v=1/0 – 9/1), carry out reversed phase chromatography (90C subsequently
18-silica gel, the acetonitrile for second).These give title compound (0.40g, 40%), for having [α]
25d=-26.66 (c=1.054g/100mL, CH
2cl
2, 589nm) a kind of colourless oil of specific rotation.
preparation cis and trans 4-isopropyl cyclohexanol
4-isopropyl cyclohexanone (10.00g in the methyl tertiary butyl ether(MTBE) being cooled to 7 DEG C (with cyclohexane/liquid nitrogen slurry cooling bath), dropwise added the solution of lithium aluminium hydride reduction in THF (23mL, 22.59mmol, 0.33 equivalent) of 1.00M in agitating solution 68.46mmol) through 35 minutes, maintain the temperature in the scope of 7 DEG C to 10 DEG C simultaneously.Continue under these conditions to stir.Then reactant mixture is allowed to reach room temperature and stir other 40 minutes at this temperature.Passed through slowly to add water (20mL), added the cancellation carefully of one mole of water-based sulfuric acid solution (60mL) subsequently.Extract by t-butyl methyl ether (2x50mL).Use Na
2cO
3solution (80mL), salt solution (80mL) wash organic layer, use anhydrous Na
2sO
4dry and filter.Solvent removed in vacuo, to provide a kind of residue, is passed through column chromatography (silica gel, heptane/ethyl acetate, v/v=1/0 – 9/1) purifying.Collect the part containing pure compound, and Vacuum Concentration is to provide pure trans (6.91g, 71%) and the pure cis-isomer (0.68g, 5%) of 4-isopropyl cyclohexanol, both is all colourless oil.
Thin layer chromatography (TLC): plate: Merck (Merck) thin layer (TLC) chromatosheet, silica gel F
254, the saturated atmosphere in developing tank, by detecting by Mo-Ce reagent spray, eluent: heptane/ethyl acetate 4:1 (v/v); The R of cis 4-isopropyl cyclohexanol
f=0.20; The R of trans 4-isopropyl cyclohexanol
f=0.15.
preparation 3-bromo-2-(cis-4-isopropyl cyclohexyloxy)-6-methyl-5-nitro-pyridine.
At room temperature, under inert atmosphere (Ar), to the bromo-6-methyl-5-nitro of the 3-in THF (180mL)-pyridine-2-alcohol (23.65g, stirred suspension 101.5mmol) adds trans isopropyl cyclohexanol (14.44g, 101.5mmol, 1.0 equivalents) and triphenyl phasphine (32.27g, 121.8mmol, 1.2 equivalents).Dropwise add DIAD (diisopropyl azo-2-carboxylic acid) (25.51mL, 121.8mmol, 1.2 equivalents) through 45 points of these mixtures of clockwise, keep temperature lower than 45 DEG C simultaneously.Then this reactant mixture of stirred at reflux 5h is being heated to.Thin layer chromatography (TLC) indicates starting material to be consumed.Therefore allow this reactant mixture to reach room temperature and pass through to add water (250mL) by its cancellation.Extract with ethyl acetate (3x200mL).Wash organic layer with salt solution (300mL), use anhydrous Na
2sO
4dry and filter.Solvent removed in vacuo, to provide a kind of residue, is passed through column chromatography (silica gel, heptane/ethyl acetate, v/v=1/0 – 98/2) purifying.Collect the part containing pure compound, and Vacuum Concentration is to provide the title compound (22.59g, 62%) of the form being in oil.
Thin layer chromatography (TLC): plate: Merck (Merck) thin layer (TLC) chromatosheet, silica gel F
254, the saturated atmosphere in developing tank, UV detect, eluent: heptane/ethyl acetate 4:1 (v/v); The R of title compound
f=0.64.
preparation 5-bromo-6-(cis-4-isopropyl cyclohexyloxy)-2-methvl-pyridinium-3-amine
At room temperature, under inert atmosphere (Ar), to EtOH/H
2o (600mL/150mL, the bromo-2-of 3-4/1v/v) (cis-4-isopropyl cyclohexyloxy)-6-methyl-5-nitro-pyridine (22.59g, ammonium chloride (3.45g is added in the solution of stirring 63.24mmol), 63.24mmol, 1.0 equivalents) and iron powder (14.27g, 253.0mmol, 4 equivalents).Be heated to this reactant mixture of stirred at reflux 3h.When thin layer chromatography (TLC) has been consumed at this time point instruction starting material, cooling this reactant mixture to room temperature has been filtered by c salt (celite) pad.The filtrate that Vacuum Concentration generates, and residue segmentation between 2 moles of aqueous NaOH solution (100mL) and ethyl acetate (150mL).After phase separation, with ethyl acetate (2x100mL), aqueous phase extracted is once again.Wash organic layer with salt solution (400mL), use anhydrous Na
2sO
4dry and filter.Solvent removed in vacuo, is used for providing title compound (21.01g, 101%) in oily form.
Thin layer chromatography (TLC): plate: Merck (Merck) thin layer (TLC) chromatosheet, silica gel F
254, the saturated atmosphere in developing tank, UV detect, eluent: heptane/ethyl acetate 4:1 (v/v); The R of title compound
f=0.19.
preparation N'-[the bromo-6-of 5-(cis-4-isopropyl cyclohexyloxy)-2-methyl-3-pyridine radicals]-N-ethyl-N-first
base carbonamidine
By at room temperature, by phosphorous oxychloride (7.09mL, 75.89mmol, 1.2 equivalents) be slowly added into N in carrene (75mL), N-ethyl-methyl formamide (6.61g, 75.89mmol, 1.2 equivalents) prepare Wei Ersi Mel (Vilsmeier) reagent in solution freshly.After completing interpolation, at this reactant mixture of stirring at room temperature 1h.Then at room temperature, under inert atmosphere (Ar), through 40min Wei Ersi Mel (Vilsmeier) reagent is dropwise added in the bromo-6-of 5-(cis-4-isopropyl cyclohexyloxy)-2-methvl-pyridinium-3-amine (20.70g, the 63.24mmol) solution in carrene (225mL).Continue at stirring at room temperature 1.5h.Then by adding water (100mL) by this reactant mixture cancellation, and by interpolation 2.0 moles of aqueous NaOH solution (80mL), pH is adjusted to 14.These to be separated and by carrene (2x100mL) aqueous phase extracted.Wash organic layer with salt solution (250mL), use anhydrous Na
2sO
4dry and filter.Solvent removed in vacuo, to provide a kind of residue, is passed through column chromatography (silica gel, heptane/ethyl acetate, v/v=1/0 – 4/1) purifying.Collect the part containing pure compound, and Vacuum Concentration is to provide title compound (20.23g, 81%), is a kind of oil of yellow.
Thin layer chromatography (TLC): plate: Merck (Merck) thin layer (TLC) chromatosheet, silica gel F
254, the saturated atmosphere in developing tank, UV detect, eluent: heptane/ethyl acetate 4:1 (v/v); The R of title compound
f=0.29.
1HNMR (400MHz, CDCl
3): δ (ppm)=7.45-7.30 (wide unimodal, 1H), 7.23 (s, 1H), 5.32-5.28 (m, 1H), 3.55-3.24 (wide unimodal, 2H), 2.98 (s, 3H), 2.35 (s, 3H), 2.04-2.01 (m, 2H), 1.63-1.46 (m, 7H), 1.20 (t, 3H), 1.18-1.10 (m, 1H), 0.91-0.89 (d, 6H).
preparation 3-bromo-2-(trans-4-isopropyl cyclohexyloxy)-6-methyl-5-nitro-pyridine
At room temperature, under inert atmosphere (Ar), to the bromo-6-methyl-5-nitro of the 3-in THF (8.6mL)-pyridine-2-alcohol (2.00g, stirred suspension 8.58mmol) adds cis isopropyl cyclohexanol (1.44g, 8.58mmol, 1.0 equivalents) and triphenyl phasphine (2.73g, 10.30mmol, 1.2 equivalents).Dropwise add DIAD (diisopropyl azo-2-carboxylic acid) (2.16mL, 10.30mmol, 1.2 equivalents) through 10 points of these mixtures of clockwise, keep temperature lower than 40 DEG C simultaneously.Be heated to this reactant mixture of stirred at reflux 1.5h.After this time point, thin layer chromatography (TLC) indicates the consumption of starting material, and allows this reactant mixture to reach room temperature, and carries out cancellation by adding water (20mL).By ethyl acetate (3x20mL) aqueous phase extracted.Wash organic layer with salt solution (35mL), use anhydrous Na
2sO
4dry and filter.Solvent removed in vacuo, to provide a kind of residue, is passed through column chromatography (silica gel, heptane/ethyl acetate, v/v=1/0 – 9/1) purifying.Collect the part containing pure compound, and Vacuum Concentration being to provide title compound (0.94g, 30%), is a kind of oil.
Thin layer chromatography (TLC): plate: Merck (Merck) thin layer (TLC) chromatosheet, silica gel F
254, the saturated atmosphere in developing tank, UV detect, eluent: heptane/ethyl acetate 4:1 (v/v); The R of title compound
f=0.65.
preparation 5-bromo-6-(trans-4-isopropyl cyclohexyloxy)-2-methvl-pyridinium-3-amine
At room temperature, under inert atmosphere (Ar), to EtOH/H
2o (24mL/6mL, the bromo-2-of 3-4/1v/v) (trans-4-isopropyl cyclohexyloxy)-6-methyl-5-nitro-pyridine (0.917g, ammonium chloride (0.109g is added in the solution of stirring 2.00mmol), 2.00mmol, 1.0 equivalents) and iron powder (0.452g, 8.00mmol, 4 equivalents).Be heated to this reactant mixture of stirred at reflux 3h.In this time, thin layer chromatography (TLC) indicates starting material and is consumed.Therefore, allow this reactant mixture to reach room temperature and filtered by a c salt pad.Concentrated filtrate at reduced pressure conditions, and residue segmentation between 2 moles of aqueous NaOH solution (20mL) and ethyl acetate (30mL).These to be separated and by ethyl acetate (2x20mL) aqueous phase extracted.Wash organic layer with salt solution (40mL), use anhydrous Na
2sO
4dry and filter.Solvent removed in vacuo, to provide title compound (0.658g, 100%), is a kind of oil.
Thin layer chromatography (TLC): plate: Merck (Merck) thin layer (TLC) chromatosheet, silica gel F
254, the saturated atmosphere in developing tank, UV detect, eluent: heptane/ethyl acetate 4:1 (v/v); The R of title compound
f=0.19.
preparation 5-bromo-6-(trans-4-isopropyl cyclohexyloxy)-2-methvl-pyridinium-3-amine
By at room temperature, by phosphorous oxychloride (0.101mL, 1.08mmol, 1.2 equivalents) be slowly added into N in carrene (0.5mL), N-ethyl-methyl formamide (0.094g, 1.08mmol, 1.2 equivalents) prepare Wei Ersi Mel (Vilsmeier) reagent in solution freshly.After completing interpolation, at this reactant mixture of stirring at room temperature 1h.Then at room temperature, under inert atmosphere (Ar), Wei Ersi Mel (Vilsmeier) reagent so obtained dropwise is added in the solution of the bromo-6-of 5-(trans-4-isopropyl the cyclohexyloxy)-2-methvl-pyridinium-3-amine (0.295g, 0.90mmol) in carrene (1.0mL).Continue at stirring at room temperature 1.5h.Then by interpolation 2 moles of these reactions of aqueous NaOH solution (5mL) cancellation.These to be separated and by carrene (2x10mL) aqueous phase extracted.Wash organic layer with salt solution (10mL), use anhydrous Na
2sO
4dry and filter.Solvent removed in vacuo, to provide a kind of residue, is passed through column chromatography (silica gel, heptane/ethyl acetate, v/v=1/0 – 4/1) purifying.Collect the part containing pure compound, and Vacuum Concentration is to provide title compound (0.191g, 54%), is the lurid oil of one.
Thin layer chromatography (TLC): plate: Merck (Merck) thin layer (TLC) chromatosheet, silica gel F
254, the saturated atmosphere in developing tank, UV detect, eluent: heptane/ethyl acetate 4:1 (v/v); The R of title compound
f=0.29.
1hNMR (400MHz, CDCl
3): δ (ppm)=7.45-7.30 (wide unimodal, 1H), 7.22 (s, 1H), 4.93-4.85 (m, 1H), 3.55-3.22 (wide unimodal, 2H), 2.98 (s, 3H), 2.35 (s, 3H), 2.19-2.15 (m, 2H), 1.80-1.77 (m, 2H), 1.50-1.09 (m, 5H), 1.28 (t, 3H), 0.88-0.86 (d, 6H).
preparation N-ethyl-N-methyl-formamide
113g (1.912mol) ethylmethylamine is dissolved in the dry toluene of 500mL.The formic acid (92.2g, 2.01mol) of 75.86mL is dropwise added through 20 minutes.Observe exothermic reaction thus.By making temperature keep below 35 DEG C with frozen water cooling bath cooling.Be heated to the solution stirring this muddiness under backflow (the bath temperature of 175 DEG C), and use Dean-Rodney Stark separator except anhydrating.Therefore the aqueous phase of 46mL is separated.With the extraction into ethyl acetate aqueous phase of 50mL.And this ethyl acetate is added in this reactant mixture, allows this mixture to reach room temperature.After solvent evaporation, the liquid of generation stands the still distillation under 80 millibars.Collect the colourless liquid of the 138g of boiling point (bp)=95 DEG C – 96 DEG C.Along with this material is polluted by formic acid, by this Liquid acquisition in the ethyl acetate of 1.0L, and remain on K
2cO
3upper (stir once in a while, amount to 24h).Then filter and wash this solution with water, and the distillation procedure that organic facies is mentioned before standing again.This provides the title compound of 130.4g, is a kind of liquid (bp=95 DEG C-96 DEG C, 80 millibars).
prepare methoxy ethyl methyl-first ammonium methylsulfuric acidester
The N-of 128g ethyl-N-methyl-formamide is slowly added in the dimethyl suflfate of 139mL (185g, 1.469mol) and (is using K
2cO
3after drying, distill in a vacuum fresh for used dimethyl suflfate).Under agitation this colourless solution is heated to 50 DEG C, so start exothermic reaction.Removing heating bath, and reactant mixture reaches the temperature of 86 DEG C.After heat release terminates, at the temperature of 80 DEG C, this reactant mixture is stirred extra 3 hours.After this, this reactant mixture is allowed to reach room temperature.First the liquid of generation is shaken in separatory funnel with the diethyl ether of 100mL after phase separation with the toluene of 100mL.Vacuum (rotary evaporator) removes the solvent of trace, is used for the title compound of the colorless liquid providing 294g.This compound uses same as before in later step.
preparation 5-bromo-2-methyl-3-nitro-6-[the fluoro-1-of 2,2,2-tri-(4-fluorophenyl) ethyoxyl] pyridine
At room temperature, under inert atmosphere (Ar), to the bromo-6-methyl-5-nitro of the 3-in THF (3mL)-pyridine-2-alcohol (0.10g, 2,2,2-tri-fluoro-1-(4-fluorophenyl) ethanol (0.13g is added in stirred suspension 0.43mmol), 0.64mmol, 1.5 equivalents) and triphenyl phasphine (0.17g, 0.64mmol, 1.5 equivalents).In this mixture, dropwise add DIAD (diisopropyl azo-2-carboxylic acid) (0.13mL, 0.64mmol, 1.5 equivalents) through 10 minutes, keep temperature lower than 40 DEG C simultaneously.This reactant mixture 6h is stirred under 60 DEG C of heating.After this time, thin layer chromatography (TLC) indicates starting material to be consumed, and allows this reactant mixture to reach room temperature before with water (10mL) cancellation.By ethyl acetate (3x15mL) aqueous phase extracted.Wash organic layer with salt solution (20mL), use anhydrous Na
2sO
4dry and filter.Solvent removed in vacuo, to provide a kind of brown residue thing, is passed through (combiflash) column chromatography (silica gel, heptane/ethyl acetate, v/v=95/5) purifying fast.Collect the part containing pure compound, and Vacuum Concentration is to provide title compound (0.11g, 62% productive rate), is a kind of oil of yellow.
Thin layer chromatography (TLC): plate: Merck (Merck) thin layer (TLC) chromatosheet, silica gel F
254, the saturated atmosphere in developing tank, UV detect, eluent: heptane/ethyl acetate 4:1 (v/v); The R of title compound
f=0.65.
preparation 2,2,2-tri-fluoro-1-[4-(trifluoroethyl) phenyl] ethanol
In a 50mL two neck flask, under being cooled with an ice bath, by 2,2, the fluoro-1-of 2-tri-[(4-(trifluoroethyl) phenyl] ethyl ketone (2.0g, 8.3mmol) be dissolved in methyl alcohol (8mL), and a point multiple part carefully adds sodium borohydride (0.31g, 8.3mmol).The colourless solution generated is stirred 2 hours under room temperature (RT), and by thin layer chromatography (TLC) monitoring.After all starting materials disappear, saturated for the water-based of 5mL NH4Cl solution is slowly added in this reacted mixture, additionally stir 10min simultaneously.The EtOAc of the latter 20mL extracts 3 times, and organic moiety is merged and with the water washing of 10mL salt, use Na
2sO
4drying, and filter.At reduced pressure conditions except desolventizing, to provide the fluoro-1-of 2,2,2-tri-[4-(trifluoromethyl) phenyl] ethanol (2.13g, quantitative), need not be further purified for a kind of the colourless oil just used.
Thin layer chromatography (TLC): plate: Merck (Merck) thin layer (TLC) chromatosheet, silica gel F
254, the saturated atmosphere in developing tank, UV detect, eluent: heptane/ethyl acetate 4:1 (v/v); The R of title compound
f=0.50.
preparation 5-bromo-2-methyl-3-nitro-6-[the fluoro-1-of 2,2,2-tri-[4-(trifluoromethyl) phenyl] ethyoxyl] pyridine
At room temperature, under inert atmosphere (Ar), to the bromo-6-methyl-5-nitro of the 3-in THF (7mL)-pyridine-2-alcohol (0.25g, 2,2,2 three fluoro-1-[4-(trifluoromethyl) phenyl] ethanol (0.39g is added in stirred suspension 1.07mmol), 1.61mmol, 1.5 equivalents) and triphenyl phasphine (0.42g, 1.61mmol, 1.5 equivalents).In 10 points of these mixtures of clockwise, dropwise add DIAD (diisopropyl azo-2-carboxylic acid) (0.33mL, 1.61mmol, 1.5 equivalents), keep temperature lower than 40 DEG C simultaneously.This reactant mixture 6h is stirred under 60 DEG C of heating.After this time, thin layer chromatography (TLC) indicates starting material to be consumed, and allows this reactant mixture to reach room temperature before with water (10mL) cancellation.By ethyl acetate (2x50mL) aqueous phase extracted.Wash organic layer with salt solution (20mL), use anhydrous Na
2sO
4dry and filter.Solvent removed in vacuo, to provide a kind of brown residue thing, is passed through flash column chromatography (silica gel, heptane/ethyl acetate, v/v=95/5) purifying.Collect the part containing pure compound, and Vacuum Concentration is to provide title compound (0.18g, 41% productive rate), is a kind of oil of yellow.
Thin layer chromatography (TLC): plate: Merck (Merck) thin layer (TLC) chromatosheet, silica gel F
254, the saturated atmosphere in developing tank, UV detect, eluent: heptane/ethyl acetate 2:1 (v/v); The R of title compound
f=0.74.
preparation 1,1,1-trifluoro-6-in heptan alkene-2-alcohol
To the own-5-olefine aldehydr (500mg in THF (10mL), 4.331mmol) with trimethyl (trifluoromethyl) silane (0.74g, 5.13mmol, 1.2 equivalents) ice bath cooling solution in add TBuA hydrofluoride (10mg, 0.04mmol).Removing ice bath, and monitor reaction process via gas chromatography mass spectrometer (GCMS) and 1HNMR.When starting material transforms completely, use 2MHCl reaction mixture, and stir other 2h.Then the Et of 50mL is introduced
2o and being separated.Use Et
2o extracts aqueous fractions again, and and then with saturated water-based NaHCO
3the organic facies that solution, water and salt water washing merge.With MgSO
4dry and after filtering, at reduced pressure conditions except desolventizing, and by the thick residue that generates by column chromatography (silica gel, pentane/Et
2o, v/v=8/2) purifying.Collect the part containing pure compound, and Vacuum Concentration is to provide 1,1,1-trifluoro-6-in heptan alkene-2-alcohol (225mg, 31% productive rate), is a kind of oil of yellow.
Use similar above those technology and other technologies well known by persons skilled in the art, such as occur in WO08/101682 those, be prepared in the compound occurred in table Q.
table Q
biological examples
wheat powdery mildew (Blumeriagraminisf.sp.tritici, original name Erysiphegraminisf.
sp.Tritici)/wheat/leaf dish preventive treatment (powdery mildew on wheat)
Wheat leaf fragment (cv. Kan Sile (Kanzler)) is placed on the agar of porous plate (24 hole gauge lattice), and is used in the test compounds spraying of the preparation of dilution with water.After using 1 day, inoculate leaf dish by the plant shaking powdery mildew infection on these test boards.24h dark be subsequently in the controlled environment chamber in 12h light/12h dark a light scheme under, the leaf dish of inoculation is cultivated under 20 DEG C and 60%rh, and when there is suitable disease destruction level in untreated inspection blade sections (after using after 6-8 days), the activity of assessment compound, as the percentage Disease epizootic compared with untreated.
Time under the same conditions compared with untreated contrast leaf dish (large-scale disease progression is shown), in this test, under 200ppm, following compound provides the Disease epizootic of at least 50%:
Q.001、Q.004、Q.005、Q.006、Q.007、Q.010、Q.011、Q.012、Q.013、Q.014、Q.015、Q.016、Q.017、Q.018、Q.019、Q.020、Q.021、Q.022、Q.023、Q.024、Q.025、Q.026、Q.027、Q.028、Q.029、Q.030、Q.031、Q.032、Q.033、Q.034、Q.035、Q.036、Q.037、Q.038、Q.039、Q.040、Q.041、Q.042、Q.043、Q.044、Q.045、Q.046、Q.047、Q.048、Q.049、Q.050、Q.051、Q.052、Q.053、Q.054、Q.055、Q.057、Q.058、Q.059、Q.060、Q.062、Q.063、Q.064、Q.065、Q.066、Q.067、Q.068、Q.069、Q.070、Q.071、Q.072、Q.073、Q.074、Q.075、Q.076、Q.077、Q.078、Q.079、Q.080、Q.081、Q.082、Q.084、Q.085、Q.086、Q.087、Q.088、Q.089、Q.090、Q.091、Q.092、Q.093、Q.094、Q.095、Q.097、Q.098、Q.099、Q.100、Q.101、Q.102、Q.103、Q.104、Q.105、Q.106、Q.108、Q.109、Q.110、Q.111、Q.112、Q.113、Q.114、Q.115、Q.116、Q.117、Q.118、Q.119、Q.120、Q.121、Q.122、Q.123、Q.124、Q.125、Q.126、Q.127、Q.128、Q.129、Q.130、Q.131、Q.132、Q.133、Q.134、Q.135、Q.136、Q.140、Q.141、Q.142、Q.143、Q.144、Q.145、Q.146、Q.147、Q.148、Q.149、Q.151、Q.152、Q.153、Q.154、Q.155、Q.156、Q.158、Q.160、Q.161、Q.162、Q.163、Q.164、Q.165、Q.166、Q.167、Q.168、Q.170、Q.171、Q.172、Q.174、Q.175、Q.176、Q.177、Q.178、Q.179、Q.180、Q.181、Q.183、Q.184、Q.185、Q.186、Q.187、Q.188、Q.191、Q.192、Q.193、Q.195、Q.196、Q.197、Q.198、Q.199、Q.200、Q.201、Q.202、Q.203、Q.204、Q.205、Q.206、Q.207、Q.208、Q.209、Q.211、Q.212、Q.213、Q.214、Q.215、Q.216、Q.217、Q.218、Q.219、Q.220、Q.221、Q.222、Q.223、Q.224、Q.225、Q.226、Q.227、Q.228、Q.229、Q.230、Q.231、Q.233、Q.235、Q.238、Q.239、Q.240、Q.241、Q.242、Q.243、Q.244、Q.245、Q.246、Q.247、Q.248、Q.249、Q.250、Q.251、Q.255、Q.256、Q.260、Q.261、Q.262、Q.263、Q.265、Q.267、Q.269、Q.270、Q.271、Q.272、Q.273、Q.274、Q.275、Q.276、Q.277、Q.278、Q.280、Q.281、Q.282、Q.283、Q.284、Q.285、Q.286、Q.287、Q.288、Q.289、Q.290、Q.291、Q.292、Q.293、Q.294、Q.296、Q.297、Q.298、Q.299、Q.300、Q.301、Q.302、Q.303、Q.304、Q.305、Q.306、Q.307、Q.308、Q.309、Q.310、Q.312、Q.315、Q.316、Q.317、Q.318、Q.319、Q.320、Q.321、Q.322、Q.323、Q.324、Q.325、Q.326、Q.327、Q.329、Q.330、Q.331、Q.332、Q.333、Q.334、Q.335、Q.336、Q.337、Q.338、Q.339、Q.340、Q.341、Q.342、Q.343、Q.344、Q.345、Q.346、Q.347、Q.349、Q.350、Q.351、Q.352、Q.353、Q.354、Q.355、Q.356、Q.357、Q.358、Q.359、Q.360、Q.361、Q.364、Q.365、Q.367、Q.368、Q.369、Q.370、Q.371、Q.373、Q.374、Q.375、Q.376、Q.378、Q.380、Q.381、Q.382、Q.383、Q.384、Q.385、Q.386、Q.388、Q.389、Q.390、Q.391、Q.392、Q.393、Q.394、Q.397、Q.398、Q.400、Q.401
puccinia recondita f. sp. tritici/wheat/leaf dish preventive treatment (leaf rust)
Wheat leaf fragment (cv. Kan Sile (Kanzler)) is placed on the agar of porous plate (24 hole gauge lattice), and is used in the test compounds spraying of the preparation of dilution with water.After using 1 day, inoculate these leaf dishes with the spore suspension of fungi.Under a light scheme of the 12h light/12h dark in the controlled environment chamber, the blade sections of inoculation is cultivated under 19 DEG C and 75%rh, and when there is suitable disease destruction level in untreated inspection blade sections (after using after 7-9 days), the activity of assessment compound, as the percentage Disease epizootic compared with untreated.
Under the same conditions, time compared with untreated contrast leaf dish (large-scale disease progression is shown), in this test, under 200ppm, following compound provides the Disease epizootic of at least 50%:
Q.001、Q.002、Q.003、Q.004、Q.005、Q.006、Q.007、Q.008、Q.009、Q.010、Q.011、Q.012、Q.013、Q.014、Q.015、Q.016、Q.017、Q.018、Q.019、Q.020、Q.021、Q.022、Q.023、Q.024、Q.025、Q.026、Q.027、Q.028、Q.029、Q.030、Q.031、Q.032、Q.033、Q.034、Q.035、Q.036、Q.037、Q.038、Q.039、Q.040、Q.041、Q.042、Q.043、Q.044、Q.045、Q.046、Q.047、Q.048、Q.049、Q.050、Q.051、Q.052、Q.053、Q.054、Q.055、Q.056、Q.057、Q.058、Q.059、Q.060、Q.061、Q.062、Q.063、Q.064、Q.065、Q.066、Q.067、Q.068、Q.069、Q.070、Q.071、Q.072、Q.073、Q.074、Q.075、Q.076、Q.077、Q.078、Q.079、Q.080、Q.081、Q.082、Q.083、Q.084、Q.085、Q.086、Q.087、Q.088、Q.089、Q.090、Q.091、Q.092、Q.093、Q.094、Q.095、Q.096、Q.097、Q.098、Q.099、Q.100、Q.101、Q.102、Q.103、Q.104、Q.105、Q.106、Q.107、Q.108、Q.109、Q.110、Q.111、Q.112、Q.113、Q.114、Q.115、Q.116、Q.117、Q.118、Q.119、Q.120、Q.121、Q.122、Q.123、Q.124、Q.125、Q.126、Q.127、Q.128、Q.129、Q.130、Q.131、Q.132、Q.133、Q.134、Q.135、Q.136、Q.137、Q.138、Q.140、Q.141、Q.142、Q.143、Q.144、Q.145、Q.146、Q.147、Q.148、Q.149、Q.150、Q.151、Q.152、Q.153、Q.154、Q.155、Q.156、Q.157、Q.158、Q.159、Q.160、Q.161、Q.162、Q.163、Q.164、Q.165、Q.166、Q.167、Q.168、Q.169、Q.170、Q.171、Q.172、Q.173、Q.174、Q.175、Q.176、Q.177、Q.178、Q.179、Q.180、Q.181、Q.182、Q.183、Q.184、Q.185、Q.186、Q.187、Q.188、Q.189、Q.190、Q.191、Q.192、Q.193、Q.194、Q.195、Q.196、Q.197、Q.198、Q.199、Q.200、Q.201、Q.202、Q.203、Q.204、Q.205、Q.206、Q.207、Q.208、Q.209、Q.210、Q.211、Q.212、Q.213、Q.214、Q.215、Q.216、Q.217、Q.218、Q.219、Q.220、Q.221、Q.222、Q.223、Q.224、Q.225、Q.226、Q.227、Q.228、Q.229、Q.230、Q.231、Q.232、Q.233、Q.234、Q.235、Q.236、Q.237、Q.238、Q.239、Q.240、Q.241、Q.242、Q.243、Q.244、Q.245、Q.246、Q.247、Q.248、Q.249、Q.250、Q.251、Q.252、Q.253、Q.254、Q.255、Q.256、Q.257、Q.258、Q.259、Q.260、Q.261、Q.262、Q.263、Q.264、Q.265、Q.266、Q.267、Q.268、Q.269、Q.270、Q.271、Q.272、Q.273、Q.274、Q.275、Q.276、Q.277、Q.278、Q.279、Q.280、Q.281、Q.282、Q.283、Q.284、Q.285、Q.286、Q.287、Q.288、Q.289、Q.290、Q.291、Q.292、Q.293、Q.294、Q.295、Q.296、Q.297、Q.298、Q.299、Q.300、Q.301、Q.302、Q.303、Q.304、Q.305、Q.306、Q.307、Q.308、Q.309、Q.310、Q.311、Q.312、Q.313、Q.314、Q.315、Q.316、Q.317、Q.318、Q.319、Q.320、Q.321、Q.322、Q.323、Q.324、Q.325、Q.326、Q.327、Q.328、Q.329、Q.330、Q.331、Q.332、Q.333、Q.334、Q.335、Q.336、Q.337、Q.338、Q.339、Q.340、Q.341、Q.342、Q.343、Q.344、Q.345、Q.346、Q.347、Q.348、Q.349、Q.350、Q.351、Q.352、Q.353、Q.354、Q.355、Q.356、Q.357、Q.358、Q.359、Q.360、Q.361、Q.362、Q.363、Q.364、Q.365、Q.366、Q.367、Q.368、Q.369、Q.370、Q.371、Q.372、Q.373、Q.374、Q.375、Q.376、Q.377、Q.378、Q.379、Q.380、Q.381、Q.382、Q.383、Q.384、Q.385、Q.386、Q.387、Q.388、Q.389、Q.390、Q.391、Q.392、Q.393、Q.394、Q.397、Q.398、Q.400、Q.401
puccinia recondita f. sp. tritici/wheat/leaf dish cure (leaf rust)
Wheat leaf fragment (cv. Kan Sile (Kanzler)) is placed on the agar in porous plate (24 hole gauge lattice).These blade sections are inoculated with the spore suspension of fungi.Under 19 DEG C and 75%rh, store these plates in the dark.In inoculation after 1 day, be applied in the test compounds of the preparation of dilution with water.Under a light scheme of the 12h light/12h dark in the controlled environment chamber, the blade sections of inoculation is cultivated under 19 DEG C and 75%rh, and when there is suitable disease destruction level in untreated inspection blade sections (after using after 6-8 days), the activity of assessment compound, as the percentage Disease epizootic compared with untreated.
Under the same conditions, time compared with untreated contrast leaf dish (large-scale disease progression is shown), in this test, under 200ppm, following compound provides the Disease epizootic of at least 50%:
Q.001、Q.004、Q.005、Q.006、Q.007、Q.010、Q.011、Q.012、Q.013、Q.014、Q.015、Q.016、Q.018、Q.019、Q.020、Q.021、Q.022、Q.023、Q.024、Q.025、Q.026、Q.027、Q.028、Q.029、Q.030、Q.031、Q.032、Q.033、Q.034、Q.035、Q.036、Q.037、Q.038、Q.039、Q.040、Q.041、Q.042、Q.043、Q.044、Q.045、Q.046、Q.047、Q.048、Q.049、Q.050、Q.051、Q.052、Q.053、Q.054、Q.055、Q.057、Q.058、Q.059、Q.060、Q.062、Q.063、Q.064、Q.065、Q.066、Q.067、Q.068、Q.069、Q.070、Q.071、Q.072、Q.073、Q.074、Q.075、Q.076、Q.077、Q.078、Q.079、Q.080、Q.081、Q.082、Q.084、Q.085、Q.086、Q.087、Q.088、Q.089、Q.090、Q.091、Q.092、Q.093、Q.094、Q.095、Q.096、Q.097、Q.098、Q.099、Q.100、Q.101、Q.102、Q.103、Q.104、Q.105、Q.106、Q.109、Q.110、Q.111、Q.112、Q.113、Q.114、Q.115、Q.116、Q.117、Q.118、Q.119、Q.120、Q.121、Q.122、Q.123、Q.124、Q.126、Q.127、Q.128、Q.129、Q.130、Q.131、Q.132、Q.133、Q.134、Q.135、Q.136、Q.140、Q.141、Q.143、Q.144、Q.145、Q.146、Q.147、Q.148、Q.149、Q.151、Q.152、Q.153、Q.154、Q.155、Q.156、Q.158、Q.159、Q.160、Q.161、Q.162、Q.163、Q.164、Q.165、Q.166、Q.167、Q.168、Q.169、Q.170、Q.171、Q.172、Q.174、Q.175、Q.176、Q.177、Q.178、Q.179、Q.180、Q.181、Q.182、Q.183、Q.184、Q.185、Q.186、Q.188、Q.191、Q.192、Q.193、Q.194、Q.195、Q.196、Q.197、Q.198、Q.199、Q.200、Q.201、Q.203、Q.204、Q.205、Q.206、Q.207、Q.208、Q.209、Q.211、Q.212、Q.213、Q.214、Q.215、Q.216、Q.217、Q.218、Q.219、Q.220、Q.221、Q.222、Q.223、Q.224、Q.225、Q.226、Q.227、Q.228、Q.229、Q.230、Q.231、Q.232、Q.233、Q.235、Q.236、Q.238、Q.239、Q.240、Q.241、Q.242、Q.243、Q.244、Q.246、Q.247、Q.248、Q.249、Q.250、Q.251、Q.253、Q.254、Q.255、Q.256、Q.257、Q.258、Q.260、Q.261、Q.262、Q.263、Q.265、Q.269、Q.270、Q.271、Q.273、Q.274、Q.275、Q.276、Q.277、Q.278、Q.279、Q.280、Q.281、Q.282、Q.283、Q.284、Q.285、Q.286、Q.287、Q.288、Q.289、Q.290、Q.291、Q.292、Q.293、Q.294、Q.296、Q.297、Q.298、Q.299、Q.300、Q.301、Q.302、Q.303、Q.304、Q.305、Q.306、Q.307、Q.308、Q.309、Q.310、Q.311、Q.315、Q.316、Q.317、Q.318、Q.319、Q.320、Q.321、Q.322、Q.323、Q.324、Q.325、Q.326、Q.327、Q.329、Q.330、Q.331、Q.332、Q.333、Q.334、Q.335、Q.336、Q.337、Q.338、Q.339、Q.340、Q.341、Q.342、Q.344、Q.345、Q.346、Q.347、Q.348、Q.349、Q.350、Q.351、Q.352、Q.353、Q.354、Q.355、Q.356、Q.357、Q.358、Q.359、Q.360、Q.361、Q.362、Q.363、Q.364、Q.365、Q.366、Q.367、Q.368、Q.369、Q.370、Q.371、Q.372、Q.373、Q.374、Q.375、Q.376、Q.377、Q.378、Q.380、Q.381、Q.382、Q.383、Q.384、Q.385、Q.386、Q.388、Q.389、Q.390、Q.391、Q.392、Q.393、Q.394、Q.397、Q.398、Q.400、Q.401
net blotch of barley (Pyrenophorateres)/barley/leaf dish preventive treatment (net blotch)
Barley leaves section (cv. breathes out rope (Hasso)) is placed on the agar in porous plate (24 hole gauge lattice), and is used in the test compounds spraying of the preparation of dilution with water.After using 2 days, inoculate these blade sections with the spore suspension of fungi.Under a light scheme of the 12h light/12h dark in the controlled environment chamber, the blade sections of inoculation is cultivated under 20 DEG C and 65%rh, and when there is suitable disease destruction level in untreated inspection blade sections (after using after 5-7 days), the activity of assessment compound, as the percentage Disease epizootic compared with untreated.
Under the same conditions, time compared with untreated contrast leaf dish (large-scale disease progression is shown), in this test, under 200ppm, following compound provides the Disease epizootic of at least 50%:
Q.001、Q.004、Q.005、Q.007、Q.011、Q.012、Q.013、Q.014、Q.015、Q.016、Q.018、Q.019、Q.020、Q.021、Q.022、Q.023、Q.024、Q.025、Q.026、Q.027、Q.028、Q.029、Q.032、Q.033、Q.034、Q.035、Q.038、Q.039、Q.041、Q.042、Q.043、Q.044、Q.046、Q.047、Q.052、Q.053、Q.054、Q.055、Q.057、Q.059、Q.062、Q.063、Q.066、Q.067、Q.069、Q.070、Q.071、Q.074、Q.075、Q.076、Q.079、Q.082、Q.086、Q.087、Q.088、Q.089、Q.090、Q.091、Q.093、Q.095、Q.097、Q.099、Q.100、Q.101、Q.102、Q.103、Q.105、Q.106、Q.110、Q.111、Q.113、Q.115、Q.116、Q.117、Q.118、Q.119、Q.120、Q.121、Q.122、Q.124、Q.125、Q.127、Q.128、Q.129、Q.131、Q.133、Q.136、Q.141、Q.143、Q.144、Q.146、Q.148、Q.153、Q.154、Q.155、Q.158、Q.160、Q.161、Q.162、Q.163、Q.164、Q.166、Q.167、Q.168、Q.169、Q.170、Q.174、Q.175、Q.176、Q.178、Q.180、Q.183、Q.184、Q.186、Q.191、Q.193、Q.195、Q.196、Q.197、Q.198、Q.199、Q.200、Q.201、Q.202、Q.203、Q.204、Q.206、Q.207、Q.208、Q.209、Q.211、Q.212、Q.214、Q.215、Q.216、Q.217、Q.218、Q.219、Q.220、Q.221、Q.222、Q.223、Q.224、Q.225、Q.226、Q.227、Q.228、Q.229、Q.231、Q.232、Q.233、Q.235、Q.236、Q.237、Q.238、Q.240、Q.241、Q.242、Q.243、Q.244、Q.245、Q.246、Q.247、Q.248、Q.249、Q.250、Q.251、Q.252、Q.253、Q.255、Q.256、Q.260、Q.261、Q.262、Q.269、Q.275、Q.277、Q.278、Q.280、Q.282、Q.284、Q.285、Q.286、Q.289、Q.291、Q.292、Q.293、Q.298、Q.299、Q.301、Q.302、Q.304、Q.308、Q.311、Q.315、Q.316、Q.320、Q.322、Q.324、Q.326、Q.329、Q.334、Q.335、Q.336、Q.337、Q.340、Q.344、Q.346、Q.349、Q.352、Q.353、Q.354、Q.355、Q.357、Q.358、Q.361、Q.363、Q.364、Q.366、Q.370、Q.371、Q.375、Q.376、Q.377、Q.378、Q.380、Q.382、Q.386、Q.389、Q.390、Q.391、Q.392、Q.393、Q.394、Q.398、Q.400
In the following table, " active (%) " refers to the assay activity of assessment (under the same conditions, compared with untreated contrast leaf dish time (large-scale disease progression is shown), in this test, % Disease epizootic), and " P " calculates (expectations) activity according to the expected value of Cole's ratio (COLBY) formula (see more than).Column heading " S? " indicate and whether observe synergy, wherein " y " refers to and observes synergy.
In the following table, compound (V) is N-[9-(dichloromethylene)-1,2,3,4-tetrahydrochysene-1,4-endo-methylene group naphthalene-5-base]-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide, compound (VI) is 3-(difluoromethyl)-N-methoxyl group-1-methyl-N-[1-methyl-2-(2,4,6-trichlorophenyl) ethyl]-1H-pyrazole-4-carboxamide, compound (VII) is [3-(the fluoro-phenyl of the chloro-2-of 4-)-5-(2,4-difluorophenyl)-isoxazole-4-bases]-pyridin-3-yl-methyl alcohol.
mould leaf blight (syn.Microdochiumnivale, Fusarium nivale) avenged by wheat, snow mold, paddy
thing root rot
Fungus conidium from stored frozen is directly mixed in nutrient medium (PDB (potato dextrose broth)).After (DMSO) solution of test compounds being placed in microtiter plate (96 hole gauge lattice), add the nutrient medium containing fungal spore.Cultivate these test boards at 24 DEG C, and determine activity from outward appearance after 72hrs.
the pathogen of Botrytis cinerea (gray mold)
Fungus conidium from stored frozen is directly mixed in nutrient medium (PDB (potato dextrose broth)).After (DMSO) solution of test compounds being placed in microtiter plate (96 hole gauge lattice), add the nutrient medium containing fungal spore.Cultivate these test boards at 24 DEG C, and visually determine activity after 72hrs.
wheat septoria (leaf blotch)
Fungus conidium from stored frozen is directly mixed in nutrient medium (PDB (potato dextrose broth)).After (DMSO) solution of test compounds being placed in microtiter plate (96 hole gauge lattice), add the nutrient medium containing fungal spore.Cultivate these test boards at 24 DEG C, and visually determine activity after 72hrs.
oat Pathogen of Take-all (cereal full rot)
Fungi Filamentous fragment from stored frozen is directly mixed in nutrient medium (PDB (potato dextrose broth)).After (DMSO) solution of test compounds being placed in microtiter plate (96 hole gauge lattice), add the nutrient medium containing fungal spore.Cultivate these test boards at 24 DEG C, and visually determine activity after 48hrs.
pythium ultimum (damping off): the fungi Filamentous fragment prepared from fresh liquid culture is directly mixed in nutrient medium (PDB (potato dextrose broth)).After (DMSO) solution of test compounds being placed in microtiter plate (96 hole gauge lattice), add the nutrient containing fungal spore.Cultivate these test boards at 24 DEG C, and visually determine activity after 48hrs.
Fall
ground-peanut ball chamber bacterium (Mycosphaerellaarachidis) (peanut tail spore), peanut (peanut) brown leaf spot: the fungus conidium from stored frozen is directly mixed in nutrient medium (PDB (potato dextrose broth)).After (DMSO) solution of test compounds being placed in microtiter plate (96 hole gauge lattice), add the nutrient containing fungal spore.Cultivate these test boards at 24 DEG C, and visually determined activity after 5-6 days.
wheat septoria (leaf blotch): after the solution (DMSO containing 0.2%) of test compounds is placed in microtiter plate (96 hole gauge lattice), add the nutrient medium (YBG) of equivalent to each hole.Final interpolation fungal spore solution.These test boards are cultivated at 20 DEG C.With photometer determination growth inhibition after 6 days, and relative to untreated contrast calculated activity.
sclerotinite on rape, prevention process
Under the prevention condition of 1 day, test compounds is active.Spray by crawler type sprayer and the 200l/ha sprayed volume with test compounds and there are 3 launch the rapeseed plant of leaves, to be also used alone or in tank mixture as shown in the table.
After using 1 day, infect these plants with sclerotinite mycelium solution.14h white/phytotron in cycle at 10h night in and 15 DEG C at, under these plants are placed in plastic jacket and high humidity.After using 11 days, visually evaluate disease infect, and calculate average activity relative to the disease severity in untreated contrast.
powdery mildew (powdery mildew) on cucumber, prevention process
Under the prevention condition of 2 days, test compounds is active.Spray to have by room spray machine and the sprayed volume of 40ml/4 strain plant with test compounds and launch the cucumber plant of cotyledon, to be also used alone or in tank mixture as shown in the table.
After using 2 days, infect plant with the spore of powdery mildew.70% relative moisture, 22 DEG C and 14h daytime/10h night cycle under, these plants are placed in phytotron.After using 10 days, visually evaluate disease infect, and calculate average activity relative to the disease severity in untreated contrast.
fusarium on wheat, prevention process
Under the prevention condition of 1 day, test compounds is active.Spray the wheat plant of blooming by crawler type sprayer and the 220l/ha sprayed volume with test compounds, to be also used alone or in tank mixture as shown in the table.Prepare these compounds by standard EC100, and be diluted in water to given spraying dosage.
After using one day, infect Hua Sui with the spore mixture of Fusarium graminearum and fusarium culmorum.60% relative moisture and temperature be 23/21 DEG C 14h daytime/10h night cycle under, these plants are placed in phytotron.After using 9 days, visually evaluate disease infect, and calculate average activity relative to the disease severity in untreated contrast.
phakopsora pachyrhizi (Phakopsorapachyrhizi) on soybean, prevention process
Under the prevention condition of 1 day, test compounds is active.Spray by crawler type sprayer and the 50l/ha sprayed volume with test compounds and there is the bean plant of first the tri-lobed leaf launched completely, to be also used alone or in tank mixture as shown in the table.After using 1 day, cut leaf dish from this first tri-lobed leaf, and be placed on the water-agar of porous plate.Each process 5 leaf dishes, wherein infect with the spore of the Phakopsora pachyrhizi bacterial strain of resistance to triazole.These porous plates are sealed, and is placed in incubator, keep 48h dark, and be after this light/dark cycle of 12h.After using 11 days, visually evaluate the rust infection on leaf dish, and calculate average activity relative to the disease severity on untreated contrast leaf dish.
wheat septoria on wheat, prevention process
Each process four basins, wherein have 4 plant of wheat breed Riband, process it after sowing 14 days with the compound provided in result table in each 6.5cm basin.Prepare these compounds by standard EC100, and be diluted in water to given spraying dosage.Using separately and in the mixture these compounds after one day, infect these plants with the spore of wheat septoria.In order to reach good infecting, cover these plant 48h of lid with a plexiglas after inoculation.These plants grow in controlled environment, and daytime is 14h at 21 DEG C, and night is 10h at 19 DEG C.Infecting after 18 days to each plant with using of untreated second leaf, visually evaluating for infecting.Then the activity data in table derives from each separately or the mean value of 4 of mixture process 4 strain plants of repeating and the untreated calculating of infecting of infecting the mean value of 4 the 4 strain plants of repeating contrasted.
Claims (16)
1. a Fungicidal composition, comprises component A) and B) one combination, wherein component A) be the compound that one has chemical formula (I)
Wherein
R
1and R
2in each independently selected from hydrogen, C
1-C
4alkyl, C
3-C
4thiazolinyl, C
3-C
4alkynyl, (R
10) carbonyl and (R
10) oxygen base carbonyl;
Or R
1and R
2be attached to them together with the nitrogen-atoms on it and form 5 or 6 membered cyclic group, this cyclic group can be saturated or unsaturated and can containing other hetero atoms being selected from S or O;
R
3represent hydrogen, halogen, cyano group, nitro, sulfydryl, hydroxyl ,-C (=S) NH
2,-SF
5, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl group, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6cycloalkyl, amino, C
1-C
2alkylamino, two (C
1-C
6alkyl) amino, containing 5 yuan of heterocycles, piperidyl, morpholinyl, thio-morpholinyl, formoxyl, hydroxycarbonyl group, C of 1-4 nitrogen-atoms
2-C
7alkoxy carbonyl, C
2-C
7halo alkoxy carbonyl, C
4-C
7allyloxycarbonyl, C
4-C
7halo allyloxycarbonyl, C
2-C
7alkyl-carbonyl, C
2-C
7alkyl halide carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl, C
1-C
6haloalkylthio, C
1-C
6alkylsulfinyl, C
1-C
6halogenated alkyl sulfonyl, C
1-C
6hydroxyalkyl, phenyl or benzyl, wherein this phenyl and benzyl are optionally replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: halogen, cyano group, hydroxyl, sulfydryl, amino, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl;
R
4represent hydrogen, halogen, cyano group, amino, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
3-C
6cycloalkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, C
1-C
4alkylthio group, C
1-C
4alkyl sulphinyl, C
1-C
4alkyl sulphonyl, methylamino or dimethylamino;
R
5hydrogen, C
1-C
12alkyl, C
3-C
12thiazolinyl, C
3-C
12alkynyl, C
1-C
12alkyl sulphonyl, C
2-C
12alkenylsufonyl, benzenesulfonyl or benzylsulphonyl, or be independently selected from the substituting group list of lower group to polysubstituted C
1-C
12alkyl, C
2-C
12thiazolinyl, C
2-C
12alkynyl, C
1-C
12alkyl sulphonyl, C
2-C
12alkenylsufonyl, benzenesulfonyl or benzylsulphonyl, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, azido, formoxyl, C
2-C
7alkyl-carbonyl, C
2-C
7alkyl halide carbonyl, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
R
5formoxyl, C
2-C
12alkyl-carbonyl, C
3-C
12alkenyl carbonyl, C
3-C
12alkynylcarbonyl groups, C
4-C
12naphthene base carbonyl, benzyloxycarbonyl group, phenylcarbonyl group, C
2-C
12alkoxy carbonyl, C
4-C
12alkenyloxycarbonyl, C
4-C
12alkynes oxygen carbonyl, C
4-C
12cycloalkoxycarbonyl, benzyloxycarbonyl or phenyloxycarbonyl, or be independently selected from the substituting group list of lower group to polysubstituted C
2-C
12alkyl-carbonyl, C
3-C
12alkenyl carbonyl, C
3-C
12alkynylcarbonyl groups, C
4-C
12naphthene base carbonyl, benzyloxycarbonyl group, phenylcarbonyl group, C
2-C
12alkoxy carbonyl, C
4-C
12alkenyloxycarbonyl, C
4-C
12alkynes oxygen carbonyl, C
4-C
12cycloalkoxycarbonyl, benzyloxycarbonyl or phenyloxycarbonyl, this group is made up of the following: halogen, cyano group, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl; Or
R
5(R
51) (R
52) (R
53) Si-, (R
51) (R
52) (R
53) Si-(C
1-C
12alkyl)-, (R
51) (R
52) (R
53) Si-(C
3-C
8cycloalkyl)-, (R
54o) (R
55o) (R
56o) Si-, (R
54o) (R
55o) (R
56o) Si-(C
1-C
12alkyl)-or (R
54o) (R
55o) (R
56o) Si-(C
3-C
8cycloalkyl)-; Or
R
5c
1-C
6alkyl-B-C
1-C
12alkyl, C
2-C
6thiazolinyl-B-C
1-C
12alkyl-, C
2-C
6alkynyl-B-C
1-C
12alkyl-, C
3-C
8cycloalkyl-B-C
1-C
12alkyl-, benzyl-B-C
1-C
12alkyl-, phenyl-B-C
1-C
12alkyl-, C
1-C
6alkyl-B-C
2-C
12thiazolinyl-, C
2-C
6thiazolinyl-B-C
2-C
12thiazolinyl-, C
2-C
6alkynyl-B-C
2-C
12thiazolinyl-, C
3-C
8cycloalkyl-B-C
2-C
12thiazolinyl-, benzyl-B-C
2-C
12thiazolinyl-, phenyl-B-C
2-C
12thiazolinyl-, C
1-C
6alkyl-B-C
2-C
12alkynyl-, C
2-C
6thiazolinyl-B-C
2-C
12alkynyl-, C
2-C
6alkynyl-B-C
2-C
12alkynyl-, C
3-C
8cycloalkyl-B-C
2-C
12alkynyl-, benzyl-B-C
2-C
12alkynyl-, phenyl-B-C
2-C
12alkynyl-, C
1-C
6alkyl-B-C
3-C
8cycloalkyl-, C
2-C
6thiazolinyl-B-C
3-C
8cycloalkyl-, C
2-C
6alkynyl-B-C
3-C
8cycloalkyl-, C
3-C
8cycloalkyl-B-C
3-C
8cycloalkyl-, benzyl-B-C
3-C
12cycloalkyl or phenyl-B-C
3-C
12cycloalkyl-, wherein group B Xuan Zi – C (=O)-,-C (=S)-,-C (=NOR
59)-,-C (R
60)=NO-,-ON=C (R
60-O-C)-, (=O)-,-C (=O)-O-,-O-,-S-,-S (=O)-,-S (=O) 2-,-S (=O) (=NR
13)-,-S (=O) (R
14)=N-,-N=S (=O) (R
14)-,-N (R
62)-C=O)-,-C=O)-N (R
62)-,-N (R
62)-SO
2-or-SO
2-N (R
62)-; Or
R
5c
1-C
6alkyl-B-C
1-C
12alkyl-, C
2-C
6thiazolinyl-B-C
1-C
12alkyl-, C
2-C
6alkynyl-B-C
1-C
12alkyl-, C
3-C
8cycloalkyl-B-C
1-C
12alkyl-, benzyl-B-C
1-C
12alkyl-, phenyl-B-C
1-C
12alkyl-, C
1-C
6alkyl-B-C
2-C
12thiazolinyl-, C
2-C
6thiazolinyl-B-C
2-C
12thiazolinyl-, C
2-C
6alkynyl-B-C
2-C
12thiazolinyl-, C
3-C
8cycloalkyl-B-C
2-C
12thiazolinyl-, benzyl-B-C
2-C
12thiazolinyl-, phenyl-B-C
2-C
12thiazolinyl-, C
1-C
6alkyl-B-C
2-C
12alkynyl-, C
2-C
6thiazolinyl-B-C
2-C
12alkynyl-, C
2-C
6alkynyl-B-C
2-C
12alkynyl-, C
3-C
8cycloalkyl-B-C
2-C
12alkynyl-, benzyl-B-C
2-C
12alkynyl-, phenyl-B-C
2-C
12alkynyl-, C
1-C
6alkyl-B-C
3-C
8cycloalkyl-, C
2-C
6thiazolinyl-B-C
3-C
8cycloalkyl-, C
2-C
6alkynyl-B-C
3-C
8cycloalkyl-, C
3-C
8cycloalkyl-B-C
3-C
8cycloalkyl-, benzyl-B-C
3-C
12cycloalkyl-, phenyl-B-C
3-C
12cycloalkyl, all these so that be independently selected from the substituting group list of lower group to polysubstituted, this group is made up of the following: halogen, cyano group, hydroxyl, sulfydryl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, formoxyl, C
2-C
6alkyl-carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
R
5a-, A-(C
1-C
6alkyl)-, A-O-(C
1-C
6alkyl)-, A-(C
3-C
6thiazolinyl)-, A-O-(C
4-C
6thiazolinyl)-, A-(C
3-C
6-alkynyl)-, A-O-(C
4-C
6alkynyl)-, A-(C
3-C
8cycloalkyl)-or A-O-(C
3-C
8cycloalkyl)-;
Wherein A be the monocycle of three to ten yuan or the bicyclic system that condenses, it can be aromatic, fractional saturation or completely saturated and can be selected from the hetero atom of lower group containing 1 to 4, this group is made up of the following: nitrogen, oxygen and sulphur, for each loop systems,-O-O-,-S-S-can not be contained with – O-S-fragment, for this three to ten-ring system, possible self coverlet or polysubstituted
A1) replaced by the substituting group being independently selected from lower group, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, azido, formoxyl, carboxyl ,=O ,=S, C
1-C
6alkyl, C
2-C
6thiazolinyl, C
2-C
6alkynyl, C
3-C
8cycloalkyl, C
1-C
6alkylhalide group, C
2-C
6haloalkenyl, C
2-C
6alkynyl halide, C
3-C
8halogen cycloalkyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6haloalkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
8cycloalkyloxy, benzyl, benzyloxy, phenyl and phenoxy group, wherein this benzyl, benzyloxy, phenyl and phenoxy group and then can be independently selected from the substituting group list of lower group to polysubstituted, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, amino, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
A2) replaced by the substituting group being independently selected from lower group, this group is made up of the following: (R
14) S (=O) (=NR
13)-, (R
14) (R
15) S (=O)=N-;-Si (R
51) (R
52) (R
53), – NR
57r
58,-C (=O) NR
57r
58,-C (=S) NR
57r
58, HC (=NOR
59)-, (C
1-C
6alkyl) C (=NOR
59)-, (C
1-C
6alkylhalide group) C (=NOR
59)-, (C
1-C
6alkyl) C (=NOR
59) C
1-C
6alkyl-, (C
1-C
6alkylhalide group) C (=NOR
59) C
1-C
6alkyl-, N (C
1-C
6alkyl) amino-sulfonyl and N, N-bis-(C
1-C
6alkyl) amino-sulfonyl; Or
A3) replaced by the substituting group being independently selected from lower group, this group is made up of the following: formoxyl, C
2-C
7alkyl-carbonyl, C
2-C
7alkyl halide carbonyl, C
3-C
7alkenyl carbonyl, C
3-C
7haloalkenyl carbonyl, C
4-C
9naphthene base carbonyl, C
4-C
9halogenated cycloalkyl carbonyl, C
2-C
7alkoxy carbonyl, C
2-C
7halo alkoxy carbonyl, C
3-C
7alkenyloxycarbonyl, C
3-C
7alkynes oxygen carbonyl, C
4-C
9cycloalkoxycarbonyl, C
2-C
7alkylthiocarbonyl and benzyloxycarbonyl, and be independently selected from the substituting group list of lower group to polysubstituted benzyloxycarbonyl, this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl; Or
A4) replaced by the substituting group being independently selected from lower group, this group is made up of the following: hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, halogen, C
1-C
4alkylhalide group, C
2-C
4haloalkenyl, cyano group, benzyl, phenyl ,=C (R
36 ')
2,=N-OH ,=N-O-C
1-C
4-alkyl ,=N-O-C
3-C
4thiazolinyl ,=N-O-C
3-C
4alkynyl ,=N-O-C
1-C
4alkylhalide group ,=N-O-C
3-C
4haloalkenyl ,=N-O-benzyl and=N-O-phenyl, wherein=N-O-benzyl and=N-O-phenyl are optionally selected from one or more groups replacements of lower group, and this group is made up of the following: halogen, methyl, halomethyl; Or
R
5-N=C (R
8) (R
9); Or
R
5the C containing 0,1 or 2 O or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, C
1-C
6alkyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7-alkyl-carbonyl, C
2-C
7-alkoxy carbonyl, C
4-C
7-alkenyloxycarbonyl, C
4-C
7-alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,=O ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2one or more groups replace;
R
6be selected from hydrogen and SH;
R
7hydrogen, halogen or C
1-C
4alkyl;
R
8and R
9hydrogen, halogen, cyano group, C independently of one another
1-C
12alkyl, C
2-C
12thiazolinyl, C
2-C
12alkynyl, C
1-C
12alkoxyl, formoxyl, C
2-C
12alkyl-carbonyl, C
3-C
12alkenyl carbonyl, carboxyl, C
2-C
12alkoxy carbonyl and C
4-C
12alkenyloxycarbonyl, or be independently selected from the substituting group list of lower group to polysubstituted C
1-C
12alkyl, C
2-C
12thiazolinyl, C
2-C
12alkynyl, C
1-C
12alkoxyl, C
2-C
12alkyl-carbonyl, C
3-C
12alkenyl carbonyl, C
2-C
12alkoxy carbonyl and C
4-C
12alkenyloxycarbonyl, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or R
8and R
9form C together
2-C
8alkylidene bridge, its substituting group list that optionally can be selected from lower group is to polysubstituted, and this group is made up of the following: halogen, cyano group, C
1-C
6alkyl and C
1-C
6alkylhalide group; Or R
8and R
9group A-, A-O-or A-(C independently of one another
1-C
6alkyl)-;
R
10h, C
1-C
4alkyl, C
2-C
4thiazolinyl or C
1-C
4alkylhalide group;
R
13hydrogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6thiazolinyl, C
3-C
6haloalkenyl, C
3-C
6alkynyl, C
3-C
8cycloalkyl, C
3-C
8halogen cycloalkyl, phenyl and benzyl, or by halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group or C
1-C
6alkoxyl list is to polysubstituted phenyl and benzyl;
R
14and R
15c independently of one another
1-C
6alkyl, C
3-C
8cycloalkyl, C
1-C
6alkylhalide group, C
3-C
8halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, benzyl or phenyl, or be selected from independently of one another lower group substituting group replace benzyl or phenyl, this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl;
R
51, R
52, R
53halogen, cyano group, C independently of one another
1-C
6alkyl, C
2-C
6thiazolinyl, C
3-C
8cycloalkyl, C
5-C
8cycloalkenyl group, C
2-C
6alkynyl, C
1-C
6alkoxyl, benzyl or phenyl;
R
54, R
55, R
56c independently of one another
1-C
6alkyl, C
3-C
6thiazolinyl, C
3-C
8cycloalkyl, C
3-C
6alkynyl, benzyl or phenyl;
R
57and R
58hydrogen, C independently of one another
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6thiazolinyl, C
3-C
6haloalkenyl, C
3-C
6alkynyl, C
3-C
8cycloalkyl, C
3-C
8halogen cycloalkyl, phenyl or benzyl, wherein phenyl or benzyl can be independently selected from the substituting group list of lower group to polysubstituted for it on the phenyl ring, and this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl, or R
57and R
58aziridinyl, azelidinyl, pyrazolinyl, pyrazolidinyl, pyrrolinyl, pyrrolidinyl, imidazolinyl, imidazolidinyl, triazoline base, tetrazolium quinoline base, piperazinyl, piperidyl, morpholinyl, thio-morpholinyl together with their connection nitrogen-atoms, wherein each and then can be selected from the substituting group list or polysubstituted of lower group, and this group is made up of the following: methyl, halogen, cyano group;
R
59hydrogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6thiazolinyl, C
3-C
6haloalkenyl, C
3-C
6alkynyl, C
3-C
8cycloalkyl, C
3-C
8halogen cycloalkyl, benzyl and phenyl, and by halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group or C
1-C
6alkoxyl list is to polysubstituted benzyl and phenyl;
R
60hydrogen, C
1-C
6alkyl, C
3-C
8cycloalkyl, C
1-C
6alkylhalide group, C
3-C
8halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, benzyl or phenyl, or be independently selected from the substituting group list of lower group to polysubstituted benzyl or phenyl, this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl;
R
62hydrogen, C
1-C
6alkyl, C
3-C
8cycloalkyl, C
1-C
6alkylhalide group, C
3-C
8halogen cycloalkyl, C
3-C
6thiazolinyl, C
3-C
6alkynyl, benzyl or phenyl, or be independently selected from the substituting group list of lower group to polysubstituted benzyl or phenyl, this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl;
Each R
36 'independently selected from hydrogen, halogen and C
1-C
4alkyl;
And acceptable salt/metal complex on the agronomy of those compounds/metalloid complex compound/isomer/constitutional isomer/stereoisomer/diastereoisomer/enantiomter/dynamic isomer/N-oxide;
And
B component) be strobilurin fungicide, sterol biosynthesis inhibitor, triazole antifungal agents, triazole precursor fungicide, DMI fungicide, SDHI fungicide, or a kind of compound being selected from lower group, this group is made up of the following: tpn, fludioxonil, cyprodinil, mandipropamid, fluazinam, procymidone, carbendazim, Avermectin, clothianidin, according to mark's butylbenzene formates, Imidacloprid, tefluthrin, Metalaxyl-M, Orocymedone, Diacloden, λ-three cyhalothrin, γ-three cyhalothrin, Profenofos, lufenuron, diflubenzuron, cypermethrin, Rimon, Biphenthrin, methomyl, Chlorpyrifos, acephatemet, 5a,6,9,9a-hexahydro-6,9-methano-2,4, β-cyhalothrin, desinsection urea, diflubenzuron, sulphur humulone, orthene, glyphosate, grass fourth phosphine, Mesotrione, Tembotrione, sulphur humulone, auxin class, TrinexAN_SNacethyl ethyl ester, adjust naphthenic acid-Ca, paclobutrazol, my acid benzene-S-methyl, methyl jasmonate, cis-jasmone, manganese, cyflufenamid, isobutyl ethoxyquin (Tebufloquin) and copper.
2. Fungicidal composition according to claim 1, wherein component A) be the compound with chemical formula (I), wherein, R
1and R
2each is independently selected from hydrogen, C
1-C
4alkyl, C
3-C
4thiazolinyl and C
3-C
4alkynyl;
Or R
1and R
2pyrrolidines or piperidines is formed together with the nitrogen-atoms that they are connected thereto;
R
3represent hydrogen, halogen, cyano group, sulfydryl, hydroxyl, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4thiazolinyl, C
2-C
4haloalkenyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, C
3-C
6cycloalkyl, amino, C
1-C
2alkylamino, two (C
1-C
6alkyl) amino, pyrrolidinyl, imidazolinyl, triazoline base, tetrazolium quinoline base, formoxyl, C
2-C
5alkyl-carbonyl, C
2-C
5alkyl halide carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl, C
1-C
6haloalkylthio, C
1-C
6alkylsulfinyl, C
1-C
6halogenated alkyl sulfonyl or C
1-C
6hydroxyalkyl;
R
4represent hydrogen, halogen, cyano group, amino, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
3-C
6cycloalkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, C
1-C
4alkylthio group, C
1-C
4alkyl sulphinyl, C
1-C
4alkyl sulphonyl, methylamino or dimethylamino;
R
5represent hydrogen, C
1-C
12alkyl sulphonyl, C
1-C
12alkyl, C
3-C
12thiazolinyl, C
3-C
12alkynyl or be independently selected from the substituting group list of lower group to polysubstituted C
1-C
12alkyl, C
2-C
12thiazolinyl, C
2-C
12alkynyl, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, azido, formoxyl, C
2-C
7alkyl-carbonyl, C
2-C
7alkyl halide carbonyl, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
R
5(R
51) (R
52) (R
53) Si-, (R
51) (R
52) (R
53) Si-(C
1-C
12alkyl)-, (R
51) (R
52) (R
53) Si-(C
3-C
8cycloalkyl)-, (R
54o) (R
55o) (R
56o) Si-, (R
54o) (R
55o) (R
56o) Si-(C
1-C
12alkyl)-or (R
54o) (R
55o) (R
56o) Si-(C
3-C
8cycloalkyl)-; Or
R
5c
1-C
6alkyl-B-C
1-C
12alkyl, C
2-C
6thiazolinyl-B-C
1-C
12alkyl, C
2-C
6alkynyl-B-C
1-C
12alkyl, C
3-C
8cycloalkyl-B-C
1-C
12alkyl, benzyl-B-C
1-C
12alkyl, phenyl-B-C
1-C
12alkyl, C
1-C
6alkyl-B-C
2-C
12thiazolinyl, C
2-C
6thiazolinyl-B-C
2-C
12thiazolinyl, C
2-C
6alkynyl-B-C
2-C
12thiazolinyl, C
3-C
8cycloalkyl-B-C
2-C
12thiazolinyl, benzyl-B-C
2-C
12thiazolinyl, phenyl-B-C
2-C
12thiazolinyl, C
1-C
6alkyl-B-C
2-C
12alkynyl, C
2-C
6thiazolinyl-B-C
2-C
12alkynyl, C
2-C
6alkynyl-B-C
2-C
12alkynyl, C
3-C
8cycloalkyl-B-C
2-C
12alkynyl, benzyl-B-C
2-C
12alkynyl, phenyl-B-C
2-C
12alkynyl, C
1-C
6alkyl-B-C
3-C
8cycloalkyl, C
2-C
6thiazolinyl-B-C
3-C
8cycloalkyl, C
2-C
6alkynyl-B-C
3-C
8cycloalkyl, C
3-C
8cycloalkyl-B-C
3-C
8cycloalkyl, benzyl-B-C
3-C
12cycloalkyl or phenyl-B-C
3-C
12cycloalkyl, wherein group B Xuan Zi – C (=O)-,-C (=S)-,-C (=NOR
59)-,-C (R
60)=NO-,-ON=C (R
60-O-C)-, (=O)-,-C (=O)-O-,-O-,-S-,-S (=O)-,-S (=O) 2-,-S (=O) (=NR
13)-,-S (=O) (R
14)=N-,-N=S (=O) (R
14)-,-N (R
62)-C=O)-,-C=O)-N (R
62)-,-N (R
62)-SO
2-or-SO
2-N (R
62)-; Or
R
5c
1-C
6alkyl-B-C
1-C
12alkyl, C
2-C
6thiazolinyl-B-C
1-C
12alkyl-, C
2-C
6alkynyl-B-C
1-C
12alkyl, C
3-C
8cycloalkyl-B-C
1-C
12alkyl, benzyl-B-C
1-C
12alkyl, phenyl-B-C
1-C
12alkyl, C
1-C
6alkyl-B-C
2-C
12thiazolinyl, C
2-C
6thiazolinyl-B-C
2-C
12thiazolinyl, C
2-C
6alkynyl-B-C
2-C
12thiazolinyl, C
3-C
8cycloalkyl-B-C
2-C
12thiazolinyl, benzyl-B-C
2-C
12thiazolinyl, phenyl-B-C
2-C
12thiazolinyl, C
1-C
6alkyl-B-C
2-C
12alkynyl, C
2-C
6thiazolinyl-B-C
2-C
12alkynyl, C
2-C
6alkynyl-B-C
2-C
12alkynyl, C
3-C
8cycloalkyl-B-C
2-C
12alkynyl, benzyl-B-C
2-C
12alkynyl, phenyl-B-C
2-C
12alkynyl, C
1-C
6alkyl-B-C
3-C
8cycloalkyl, C
2-C
6thiazolinyl-B-C
3-C
8cycloalkyl, C
2-C
6alkynyl-B-C
3-C
8cycloalkyl, C
3-C
8cycloalkyl-B-C
3-C
8cycloalkyl, benzyl-B-C
3-C
12cycloalkyl, phenyl-B-C
3-C
12cycloalkyl, all these so that be independently selected from the substituting group list of lower group to polysubstituted, this group is made up of the following: halogen, cyano group, hydroxyl, sulfydryl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, formoxyl, C
2-C
6alkyl-carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
R
5be selected from A-, A-(C
1-C
6alkyl)-, A-O-(C
1-C
6alkyl)-, A-(C
3-C
6thiazolinyl)-, A-O-(C
4-C
6thiazolinyl)-, A-(C
3-C
6-alkynyl)-, A-O-(C
4-C
6alkynyl)-, A-(C
3-C
8cycloalkyl)-and A-O-(C
3-C
8cycloalkyl)-;
That A is the monocycle of three to ten yuan or condense bicyclic system, it can be aromatic, fractional saturation or completely saturated and can be selected from the hetero atom of lower group containing 1 to 4, this group is made up of the following: nitrogen, oxygen and sulphur, for each loop systems,-O-O-,-S-S-can not be contained with – O-S-fragment, for this three to ten-ring system, possible self coverlet or polysubstituted
A1) replaced by the substituting group being independently selected from lower group, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, nitro, azido, formoxyl, carboxyl ,=O ,=S, C
1-C
6alkyl, C
2-C
6thiazolinyl, C
2-C
6alkynyl, C
3-C
8cycloalkyl, C
1-C
6alkylhalide group, C
2-C
6haloalkenyl, C
2-C
6alkynyl halide, C
3-C
8halogen cycloalkyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6haloalkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
8cycloalkyloxy, C
3-C
8halocycloalkoxy, C
3-C
8cyclenes oxygen base, C
3-C
8halo cyclenes oxygen base, benzyl, benzyloxy, phenyl and phenoxy group, wherein benzyl, benzyloxy, phenyl and phenoxy group and then can be independently selected from the substituting group list of lower group to polysubstituted, this group is made up of the following: halogen, cyano group, nitro, hydroxyl, sulfydryl, amino, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6alkyl sulphonyl; Or
A3) replaced by the substituting group being independently selected from lower group, this group is made up of the following: formoxyl, C
2-C
7alkyl-carbonyl, C
2-C
7alkyl halide carbonyl, C
3-C
7alkenyl carbonyl, C
3-C
7haloalkenyl carbonyl, C
4-C
9naphthene base carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
4-C
9cycloalkoxycarbonyl and benzyloxycarbonyl, and be independently selected from the substituting group list of lower group to polysubstituted benzyloxycarbonyl, this group is made up of the following: halogen, cyano group, hydroxyl, C
1-C
6alkyl, C
1-C
6alkylhalide group and C
1-C
6alkoxyl; Or
A4) replaced by the substituting group being independently selected from lower group, this group is made up of the following: hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, halogen, C
1-C
4alkylhalide group, C
2-C
4haloalkenyl, cyano group, benzyl, phenyl ,=C (R
36 ')
2,=N-OH ,=N-O-C
1-C
4-alkyl ,=N-O-C
3-C
4thiazolinyl ,=N-O-C
3-C
4alkynyl ,=N-O-C
1-C
4alkylhalide group ,=N-O-C
3-C
4haloalkenyl ,=N-O-benzyl and=N-O-phenyl, wherein=N-O-benzyl and=N-O-phenyl are optionally selected from one or more groups replacements of lower group, and this group is made up of the following: halogen, methyl, halomethyl; Or
R
5the C containing 0,1 or 2 O or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, C
1-C
6alkyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7-alkyl-carbonyl, C
2-C
7-alkoxy carbonyl, C
4-C
7-alkenyloxycarbonyl, C
4-C
7-alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,=O ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2one or more groups replace;
R
6hydrogen;
R
7hydrogen or C
1-C
4alkyl.
3. the Fungicidal composition according to any one of the preceding claims, wherein component A) be the compound with chemical formula (I), wherein, R
1and R
2each is independently selected from hydrogen and C
1-C
4alkyl;
Or R
1and R
2pyrrolidines or piperidines is formed together with the nitrogen-atoms that they are connected thereto;
R
3represent hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, amino, C
1-C
2alkylamino, two (C
1-C
6alkyl) amino, pyrrolidinyl, imidazolinyl, triazoline base, formoxyl, phenyl, C
2-C
4alkyl-carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl or C
1-C
6hydroxyalkyl;
R
4be selected from fluorine, chlorine, bromine, C
1-C
4alkyl, C
1-C
4thiazolinyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
3-C
6cycloalkyl;
R
5be selected from G
1, G
2, G
3-G
4, G
5, G
6-G
7, G
8, G
9, G
10-G
11, G
12, G
13, G
14, G
15and G
16;
R
6hydrogen;
R
7be selected from hydrogen and C
1-C
4alkyl;
G
1c
8-C
10the bicyclic system condensed, it can be saturated or comprises a carbon-to-carbon double bond and be optionally independently selected from hydroxyl, C
1-C
4alkyl, C
1-C
4alkoxyl, halogen, C
1-C
4one or more groups of alkylhalide group and cyano group replace;
G
2c
3-C
6cycloalkenyl group, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
2-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7alkyl-carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2one or more groups replace;
G
3be phenyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4one or more groups of alkoxyl, halogen and cyano group replace, and wherein this alkyl is optionally by one or more halogen substiuted;
G
4c
3-C
12cycloalkyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4one or more groups of alkoxyl, halogen and cyano group replace, and wherein this alkyl is optionally by one or more halogen substiuted;
G
5c
3-C
7cycloalkyl, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
2-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
2-C
7alkyl-carbonyl, C
2-C
7alkoxy carbonyl, C
4-C
7alkenyloxycarbonyl, C
4-C
7alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl, phenoxy group ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2one or more groups replace;
G
6be phenyl, it must be replaced by least one fluorine, and is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6one or more groups of halogenated alkyl sulfonyl replace further;
G
7it is methylene;
G
8be
G
9be
G
10be phenyl, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, phenyl, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl, C
1-C
6one or more groups of halogenated alkyl sulfonyl, phenyl, 2-phenyl-ethynyl and 2-phenyl-ethyl group replace;
G
11independently be selected from C
1-C
4alkyl, C
1-C
4alkylhalide group, CN, C
1-C
4alkoxyl and C
1-C
4the methylene of at least one group replacement of halogenated alkoxy;
G
12be
G
13the C containing 0,1 or 2 O or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, COOH, three (C
1-C
6-alkyl) silicyl, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
2-C
7alkyl-carbonyl, C
2-C
7-alkoxy carbonyl, C
4-C
7-alkenyloxycarbonyl, C
4-C
7-alkynes oxygen carbonyl, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl, C
1-C
6alkyl sulphonyl ,=O ,-C (=O) NH
2,-C (=O) NH (CH
3) ,-C (=O) N (CH
3)
2with-C (=S) NH
2one or more groups replace;
G
14be
G
15be
G
16be
G
17be five yuan to unite to single six-membered rings heteroaromatic ring system, it can containing 1 to 4 member being selected from lower group, and this group is made up of the following: N, N (R
69 '), O and S, for each loop systems, can not-O-O-,-S-S-be contained with – O-S-fragment, and likely these five yuan self to be selected from the group list or polysubstituted of lower group to hexatomic ring system, this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
1 'be selected from lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
2 ', R
3 ', R
4 'and R
5 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4alkylthio group;
R
11 ', R
12 ', R
13 'and R
14 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, phenyl, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, benzyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
15 'and R
16 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
3-C
6cycloalkyl;
R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'each is independently from each other lower group, and this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
3-C
6cycloalkyl;
R
23 ', R
24 'and R
25 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
R
26 'c (R
36 ')
2, N-OH, N-O-C
1-C
4-alkyl, N-O-C
2-C
4-thiazolinyl, N-O-C
2-C
4alkynyl, N-O-C
1-C
4alkylhalide group, N-O-C
2-C
4haloalkenyl, N-O-benzyl, N-O-phenyl, N-O-halobenzene base, O, wherein N-O-benzyl and N-O-phenyl can be replaced by the one or more groups being independently selected from lower group, and this group is made up of the following: halogen, methyl and halomethyl;
R
27 ', R
28 ', R
29 ', R
30 ', R
31 ', R
32 ', R
33 ', R
34 'and R
35 'each is independently selected from lower group, and this group is made up of the following: hydrogen, hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, halogen, C
1-C
4alkylhalide group, C
2-C
4haloalkenyl, cyano group, benzyl and phenyl;
Or R
28 'and R
29 'be attached to them together with two carbon atoms on it and form double bond;
Each R
36 'independently be selected from hydrogen, halogen and C
1-C
4alkyl;
R
37 'and R
38 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
50 'be selected from lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
51 ', R
52 ', R
53 ', R
54 ', R
55 'and R
56 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4alkoxyl and C
1-C
4alkylthio group;
R
57 ', R
58 ', R
59 'and R
60 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
2-C
6alkoxyl, C
2-C
6halogenated alkoxy, phenyl, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyloxy, benzyloxy, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
Its condition is R
57 ', R
58 ', R
59 'and R
60 'in at least one is not hydrogen;
R
61 'and R
62 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
63 ', R
64 ', R
65 ', R
66 ', R
67 'and R
68 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, hydroxyl, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy and C
1-C
4alkylthio group;
R
69 'be selected from hydrogen, C
1-C
4alkyl, C
3-C
4thiazolinyl and C
1-C
4alkyl carboxyl;
N is 0 or 1;
P and q is independently selected from 0 and 1;
R, s and t are independently selected from 0 and 1.
4. the Fungicidal composition according to any one of the preceding claims, wherein component A) be the compound with chemical formula (I), wherein, R
1and R
2each is C
1-C
4alkyl;
R
3represent hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
1-C
4alkylthio group, C
1-C
4alkyl sulphinyl or C
1-C
4alkyl sulphonyl;
R
4be selected from methyl, ethyl, methoxyl group, fluorine and chlorine;
R
6hydrogen;
R
7hydrogen or C
1-C
4alkyl.
5. the Fungicidal composition according to any one of the preceding claims, wherein component A) be the compound with chemical formula (I), wherein, R
1and R
2each is independently selected from methyl, ethyl and isopropyl;
R
3represent hydrogen, halogen, C
1-C
4alkyl, C
1-C
4alkylhalide group, cyclopropyl, acetenyl or C
1-C
4alkoxyl;
R
4be selected from methyl, methoxyl group, fluorine and chlorine;
R
6hydrogen;
R
7hydrogen.
6. the Fungicidal composition according to any one of the preceding claims, wherein component A) be the compound with chemical formula (I), wherein
R
1it is methyl;
R
2it is ethyl;
R
3be selected from hydrogen, bromine, iodine, methyl, CHF
2, cyclopropyl, acetenyl and methoxyl group;
R
4it is methyl;
R
6hydrogen;
R
7hydrogen.
7. the Fungicidal composition according to claim 3-6, wherein component A) be the compound with chemical formula (I), wherein R
5be selected from G
1, G
2, G
5, G
6-G
7, G
8, G
9, G
10-G
11, G
12, G
14, G
15and G
16.
8. the Fungicidal composition according to claim 3-7, wherein component A) be the compound with chemical formula (I), wherein R
5be selected from G
2, G
5, G
6-G
7, G
8, G
9, G
10-G
11, G
14and G
16.
9. the Fungicidal composition according to claim 3-8, wherein component A) be the compound with chemical formula (I), wherein R
5be selected from G
2, G
5, G
8and G
10-G
11.
10. the Fungicidal composition according to claim 3-6, wherein component A) be the compound with chemical formula (I), wherein G
1c
9-C
10the bicyclic system condensed, it can be saturated or comprises a carbon-to-carbon double bond and be optionally independently selected from C
1-C
4alkyl, fluorine, methoxyl group and C
1-C
4one or more groups of fluoroalkyl replace;
G
2c
3-C
6cycloalkenyl group, it is optionally independently selected from halogen, ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
2-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6one or more groups of alkylthio group replace;
G
3be phenyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
1-C
4fluoroalkyl, C
1-C
4one or more groups of alkoxyl and halogen replace;
G
4c
5-C
6cycloalkyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4one or more groups of alkoxyl, halogen and cyano group replace, and wherein alkyl is optionally by one or more halogen substiuted;
G
5c
3-C
7cycloalkyl, it is independently selected from ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2, C
2-C
6alkylhalide group, C
1-C
6alkoxyl, C
3-C
4alkene oxygen base, phenoxy group and C
1-C
6one or more groups of alkylthio group replace;
G
6be phenyl, it must be replaced by least one fluorine, and is optionally independently selected from halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6alkynyloxy group, C
1-C
6alkylthio group, C
1-C
6alkyl sulphinyl and C
1-C
6one or more groups of alkyl sulphonyl replace further;
G
10be phenyl, it is optionally independently selected from halogen, CN, OH, SH, CHO, methyl, ethyl, n-pro-pyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CF
2-CF
3, cyclopropyl, CH=CH
2, C (CH
3)=CH
2, CH=CH (CH
3), C (CH
3)=CH (CH
3), CH=C (CH
3)
2, C (CH
3)=C (CH
3)
2, CH=CF
2, CH=CCl
2, C ≡ CH, methoxyl group, ethyoxyl, isopropoxy, phenyl, OCHF
2, OCH
2-C ≡ CH, OCH (CH
3)-C ≡ CH, SCH
3, SCH
2cH
3, S (=O) CH
3, S (=O) CH
2cH
3, S (=O)
2cH
3with S (=O)
2cH
2cH
3one or more groups replace;
G
11independently be selected from C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4the methylene of at least one group replacement of halogenated alkoxy;
G
13the C containing 0,1 or 2 O or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6one or more groups of alkylthio group and=O replace;
G
17be five yuan to unite to single six-membered rings heteroaromatic ring system, it can containing 1 to 4 member being selected from lower group, and this group is made up of the following: N, N (R
69 '), O and S, for each loop systems, can not-O-O-,-S-S-be contained with – O-S-fragment, and may these five yuan self to be selected from the group list or polysubstituted of lower group to hexatomic ring system, this group is made up of the following: halogen, CN, NO
2, OH, SH, CHO, C (=O) NH
2, C (=O) NH (CH
3), C (=O) N (CH
3)
2, C (=S) NH
2, C (=S) NH (CH
3), C (=S) N (CH
3)
2, SO
2nH
2, SO
2nH (CH
3), SO
2n (CH
3)
2, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
3-C
6cycloalkyl, C
2-C
6thiazolinyl, C
2-C
6haloalkenyl, C
2-C
6alkynyl, C
2-C
6alkynyl halide, C
1-C
6alkoxyl, C
1-C
6halogenated alkoxy, C
3-C
6alkene oxygen base, C
3-C
6halogen alkene oxygen base, C
3-C
6alkynyloxy group, C
3-C
6cycloalkyloxy, C
3-C
6halogen cycloalkyl, C
1-C
6alkylthio group, C
1-C
6haloalkylthio, C
1-C
6alkyl sulphinyl, C
1-C
6alkylsulfinyl, C
1-C
6alkyl sulphonyl and C
1-C
6halogenated alkyl sulfonyl;
R
1 'be selected from lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl and C
1-C
4fluoroalkyl;
R
2 ', R
3 ', R
4 'and R
5 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4alkylthio group;
R
11 ', R
12 ', R
13 'and R
14 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl and C
1-C
6alkylthio group;
R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3and CF
2cF
3;
R
23 ', R
24 'and R
25 'independently be selected from lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
3-C
6cycloalkyl, C
3-C
6halogen cycloalkyl and C
1-C
4alkylthio group;
R
26 'n-OH, N-O-C
1-C
4alkyl, N-O-C
2-C
4thiazolinyl, N-O-C
2-C
4alkynyl, N-O-C
1-C
4alkylhalide group, N-O-C
2-C
4haloalkenyl, N-O-benzyl, N-O-phenyl, N-O-halobenzene base, O or C (R
36 ')
2;
R
27 ', R
28 ', R
29 ', R
30 ', R
31 ', R
32 ', R
33 ', R
34 'and R
35 'each is independently selected from lower group, and this group is made up of the following: hydrogen, hydroxyl, C
1-C
4alkyl, C
1-C
4alkoxyl and halogen;
Or R
28 'and R
29 'be attached to them together with two carbon atoms on it and form double bond;
Each R
36 'independently be selected from hydrogen, halogen and C
1-C
4alkyl;
R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, methyl, ethyl, isopropyl, single methyl fluoride, polyfluoro methyl, single fluoro ethyl and polyfluoro ethyl;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'independently be selected from lower group, this group is made up of the following: hydrogen, fluorine, chlorine, bromine, iodine, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, ethyoxyl, difluoro-methoxy, trifluoromethoxy, methyl mercapto, methylsulfinyl and mesyl;
R
50 'be selected from lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
51 ', R
52 ', R
53 ', R
54 ', R
55 'and R
56 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
2-C
4alkoxyl and C
1-C
4halogenated alkoxy;
R
57 ', R
58 ', R
59 'and R
60 'be independently from each other lower group, this group is made up of the following: hydrogen, cyano group, halogen, C
1-C
6alkyl and C
1-C
6alkylhalide group;
Its condition is R
57 ', R
58 ', R
59 'and R
60 'in at least one is not hydrogen;
R
61 'and R
62 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, cyano group, C
1-C
4alkyl and C
1-C
4alkylhalide group;
R
63 ', R
64 ', R
65 ', R
66 ', R
67 'and R
68 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, cyano group, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl and C
1-C
4halogenated alkoxy;
R
69 'be selected from hydrogen, C
1-C
4alkyl and C
1-C
4alkyl carboxyl;
N is 0 or 1;
P and q is independently selected from 0 and 1;
R and s is 0, and t is 1 or 0.
11. Fungicidal compositions according to claim 3-6, wherein component A) be the compound with chemical formula (I), wherein G
1saturated C
10the bicyclic system condensed, it is optionally independently selected from C
1-C
4alkyl, fluorine, methoxyl group and C
1-C
4one or more groups of fluoroalkyl replace;
G
2optionally by C that one or more fluorine atom replaces
5-C
6cycloalkenyl groups;
G
3be phenyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, CHF
2, CF
3, C
1-C
4one or more groups of alkoxyl and halogen replace;
G
4c
5-C
6cycloalkyl, it is optionally independently selected from hydroxyl, C
1-C
4alkyl, C
2-C
4thiazolinyl, C
2-C
4alkynyl, C
1-C
4one or more groups in alkoxyl and halogen replace;
G
5c
5-C
6cycloalkyl, it is optionally independently selected from ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2,-CH (CH
3)-CH (CH
3)
2and C
2-C
6one or more groups of alkylhalide group replace;
G
6be phenyl, it must be replaced by least one fluorine and is optionally independently selected from halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group and C
1-C
4one or more groups of alkoxyl replace further;
G
7it is methylene;
G
10be phenyl, it is optionally independently selected from hydrogen, halogen, CN, OH, methyl, ethyl, n-pro-pyl, isopropyl, CH
2f, CHF
2, CF
3, CHF-CH
3, CF
2-CH
3, CF
2-CF
3, CH=CH
2, C (CH
3)=CH
2, CH=CH (CH
3), C (CH
3)=CH (CH
3), CH=C (CH
3)
2, C (CH
3)=C (CH
3)
2, CH=CF
2, CH=CCl
2, C ≡ CH, methoxyl group, ethyoxyl, isopropoxy, phenyl and OCHF
2one or more groups replace;
G
11independently be selected from C
1-C
4alkyl, C
1-C
4alkylhalide group and C
1-C
4the methylene of at least one group replacement of alkoxyl;
G
13the C containing 0,1 or 2 O or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, C
1-C
6alkyl, C
1-C
6alkylhalide group, C
1-C
6alkoxyl, C
1-C
6one or more groups of alkylthio group and=O replace;
G
17be five yuan to unite to single six-membered rings heteroaromatic ring system, it can containing 1 to 4 member being selected from lower group, and this group is made up of the following: N, N (R
69 '), O and S, for each loop systems, can not contain-O-O-,-S-S-with – O-S-fragment, and these five yuan may be selected from the group list or polysubstituted of lower group to hexatomic ring system self, this group is made up of the following: halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, phenyl or benzyl, wherein phenyl or benzyl are optionally by halogen, CN, C
1-C
4alkyl or C
1-C
4alkylhalide group replaces;
R
1 'be selected from lower group, this group is made up of the following: hydrogen, fluorine, methyl, CH
2f and CF
3;
R
2 ', R
3 ', R
4 'and R
5 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, CH
2f, CF
3and methoxyl group;
R
11 ', R
12 ', R
13 'and R
14 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, CHF
2, CF
3and C
1-C
4alkoxyl;
R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 'and R
22 'independently be selected from hydrogen, fluorine, methyl, ethyl, CH
2f, CHF
2, CF
3and isopropyl;
R
23 ', R
24 'and R
25 'independently be selected from lower group, this group is made up of the following: hydrogen, methyl, fluorine, chlorine, bromine, ethyl, CH
2f, CHF
2, CF
3and isopropyl;
R
26 'be selected from lower group, this group is made up of the following: N-OH, N-O-C
1-C
4alkyl, N-O-C
2-C
4thiazolinyl, N-O-C
2-C
4alkynyl, N-O-C
1-C
4alkylhalide group, N-O-C
2-C
4haloalkenyl, N-O-benzyl, N-O-phenyl, N-O-halobenzene base, O and C (R
36 ');
R
27 ', R
28 ', R
29 ', R
30 ', R
31 ', R
32 ', R
33 ', R
34 'and R
35 'each is independently selected from lower group, and this group is made up of the following: hydrogen, C
1-C
4alkyl and halogen;
Or R
27 'and R
28 'be attached to them together with two carbon atoms on it and form double bond;
Each R
36 'independently be selected from hydrogen, halogen and C
1-C
4alkyl;
R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44" being independently selected from lower group, this group is made up of the following: hydrogen, fluorine, methyl and trifluoromethyl;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'independently be selected from lower group, this group is made up of the following: hydrogen, fluorine, chlorine, bromine, iodine, methyl, ethyl, isopropyl, cyclopropyl, C ≡ CH, CH=CH
2, C (CH
3)=CH
2, CF
3, CHF
2, CH
2f ,-CHF-CH
3,-CF
2-CH
3, methoxyl group, difluoro-methoxy, trifluoromethoxy, ethyoxyl, methyl mercapto, methylsulfinyl and mesyl;
R
50 ', R
51 ', R
52 ', R
53 ', R
54 ', R
55 'and R
56 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, CH
2f and CF
3;
R
57 ', R
58 ', R
59 'and R
60 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl, CHF
2and CF
3;
Its condition is R
57 ', R
58 ', R
59 'and R
60 'in at least one is not hydrogen;
R
61 'and R
62 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, CHF
2and CF
3;
R
62 ', R
63 ', R
64 ', R
65 ', R
66 ', R
67 'and R
68 'be independently from each other lower group, this group is made up of the following: hydrogen, fluorine, methyl, ethyl, methoxyl group, difluoro-methoxy, trifluoromethoxy, CH
2f and CF
3;
R
69 'be selected from hydrogen and C
1-C
4alkyl;
N is 0 or 1;
P and q is independently selected from 0 and 1;
R and s is 0, and t is 1 or 0.
12. Fungicidal compositions according to claim 3-6, wherein component A) be the compound with chemical formula (I), wherein G
1a saturated C
10the bicyclic system condensed;
G
2c
5-C
6cycloalkenyl groups;
G
3it is phenyl;
G
4cyclohexyl or cyclopenta;
G
5c
6cycloalkyl, it is optionally independently selected from ethyl, n-pro-pyl, isopropyl, normal-butyl, isobutyl group, sec-butyl, the tert-butyl group, n-pentyl ,-CH (CH
3)-CH
2-CH
2-CH
3,-CH-CH (CH
3)-CH
2-CH
3,-CH
2-CH
2-CH (CH
3)-CH
3,-CH
2-CH
2-CH (CH
3)
2with-CH (CH
3)-CH (CH
3)
2one or more groups replace;
G
6be phenyl, it must be replaced by least one fluorine, and is optionally replaced further by one or more methyl, bromine, iodine or chlorine;
G
7it is methylene;
G
10be phenyl, it is optionally independently selected from halogen, CN, methyl, ethyl, n-pro-pyl, isopropyl, vinyl, methoxyl group, ethyoxyl, isopropoxy, phenyl, CHF
2, CF
3, CHF-CH
3and OCHF
2one or more groups replace;
G
11independently be selected from methyl, CF
3, and ethyl at least one group replace methylene;
G
13the C containing 0,1 or 2 O or atom N
8-C
11spiral shell second cycle line is united, and wherein there is not adjacent O atom, it is optionally independently selected from halogen, C
1-C
4alkyl, C
1-C
4one or more groups of alkoxyl and=O replace;
G
17be five yuan to unite to single six-membered rings heteroaromatic ring system, it can containing 1 or 2 member being selected from lower group, this group is made up of the following: N, O and S, for each loop systems,-O-O-,-S-S-can not be contained with – O-S-fragment, and these five yuan may be selected from the group list or polysubstituted of lower group to hexatomic ring system self, and this group is made up of the following: halogen, CN, C
1-C
4alkyl, C
1-C
4alkylhalide group, C
1-C
4alkoxyl, C
1-C
4halogenated alkoxy, phenyl or fluorophenyl;
R
1 ', R
2 ', R
3 ', R
4 'and R
5 'each is hydrogen;
R
11 ', R
12 ', R
13 'and R
14 'be independently from each other lower group, this group is made up of the following: hydrogen, halogen, cyano group, C
1-C
4alkyl and C
1-C
4alkoxyl;
R
15 ', R
16 ', R
17 ', R
18 ', R
19 ', R
20 ', R
21 ', R
22 ', R
23 ', R
24 'and R
25 'each is independently selected from hydrogen, methyl, ethyl and isopropyl;
R
26 'n-OH, N-O-C
1-C
4alkyl, N-O-C
2-C
4thiazolinyl, N-O-C
2-C
4alkynyl, N-O-C
1-C
4alkylhalide group, N-O-C
2-C
4haloalkenyl, N-O-benzyl, N-O-phenyl, N-O-halobenzene base, O and C (R
36 ');
R
27 ', R
28 ', R
29 ', R
30 ', R
31 ', R
32 ', R
33 ', R
34 'and R
35 'each is hydrogen or methyl;
Or R
27 'and R
28 'be attached to them together with two carbon atoms on it and form double bond;
Each R
36 'independently be selected from hydrogen, halogen and C
1-C
4alkyl;
R
37 ', R
38 ', R
39 ', R
40 ', R
41 ', R
42 ', R
43 'and R
44 'hydrogen;
R
45 ', R
46 ', R
47 ', R
48 'and R
49 'independently be selected from lower group, this group is made up of the following: hydrogen, fluorine, chlorine, methyl, CF
3, CHF
2, CH
2f, methoxyl group, difluoro-methoxy and trifluoromethoxy;
R
50 ', R
51 ', R
52 ', R
53 ', R
54 ', R
55 'and R
56 'each is hydrogen;
R
57 ', R
58 ', R
59 'and R
60 'be independently from each other lower group, this group is made up of the following: hydrogen and halogen;
Its condition is R
57 ', R
58 ', R
59 'and R
60 'in at least one is not hydrogen;
R
61 ', R
62 ', R
63 ', R
64 ', R
65 ', R
66 ', R
67 'and R
68 'hydrogen;
R
69 'hydrogen;
N is 0 or 1;
P and q is independently selected from 0 and 1;
R, s and t each be 0.
13. 1 kinds of compounds according to chemical formula (IV)
Wherein R
100halogen, SH, C
1-C
4alkylthio group, C
1-C
4-alkyl sulphinyl, C
1-C
4alkyl sulphonyl, or and R
1, R
2, R
3, R
4, R
6and R
7any one of claim 1-12 define.
14. 1 kinds for controlling the method for the phytopathogenic disease on useful plant or on its propagating materials, the method comprises the component A using the cooperative effective quantity according to any one of claim 1 to 12 on these useful plants, its location or its propagating materials) and one combination B) together with a kind of inert carrier and optionally a kind of adjuvant.
15. 1 kinds of Fungicidal compositions, comprise the component A according to any one of claim 1 to 13) and one combination B) together with a kind of inert carrier and optionally a kind of adjuvant, wherein A) and weight ratio B) between 100:1 and 1:6000.
16. 1 kinds for the protection of plant and/or animal origin, the natural material in natural life cycle of taking from them and/or the method for its form processing, the method comprise to the natural material of described plant and/or animal origin or its form processing use cooperative effective quantity, component A according to any one of claim 1 to 12) and combination B).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510601753.2A CN105230625A (en) | 2011-12-14 | 2012-04-09 | Antifungal composition |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011084016 | 2011-12-14 | ||
| CNPCT/CN2011/084016 | 2011-12-14 | ||
| CN201280061518.5A CN104010503A (en) | 2011-12-14 | 2012-04-09 | Fungicidal compositions |
| CN201510601753.2A CN105230625A (en) | 2011-12-14 | 2012-04-09 | Antifungal composition |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280061518.5A Division CN104010503A (en) | 2011-12-14 | 2012-04-09 | Fungicidal compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105230625A true CN105230625A (en) | 2016-01-13 |
Family
ID=51370925
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280061518.5A Pending CN104010503A (en) | 2011-12-14 | 2012-04-09 | Fungicidal compositions |
| CN201510601753.2A Pending CN105230625A (en) | 2011-12-14 | 2012-04-09 | Antifungal composition |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280061518.5A Pending CN104010503A (en) | 2011-12-14 | 2012-04-09 | Fungicidal compositions |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN104010503A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016071239A1 (en) * | 2014-11-06 | 2016-05-12 | Syngenta Participations Ag | Novel fungicidal pyridylamidines |
| JP6469238B2 (en) * | 2015-09-18 | 2019-02-13 | 科研製薬株式会社 | Biaryl derivative and medicament containing the same |
| BR112018007572A2 (en) * | 2015-10-14 | 2018-10-23 | Syngenta Participations Ag | fungicidal compositions |
| BR112018012204B1 (en) * | 2015-12-15 | 2022-03-22 | Syngenta Participations Ag | Compounds derived from phenylamidine microbicides, composition and method of combating, preventing and controlling phytopathogenic diseases |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009088103A1 (en) * | 2008-01-11 | 2009-07-16 | Ishihara Sangyo Kaisha, Ltd. | Pyridylamidine compound or salt thereof, and agricultural or horticultural fungicide composition containing the same as active ingredient |
| CN101657423A (en) * | 2007-02-22 | 2010-02-24 | 先正达参股股份有限公司 | Iminipyridine derivatives and they purposes as microbicide |
-
2012
- 2012-04-09 CN CN201280061518.5A patent/CN104010503A/en active Pending
- 2012-04-09 CN CN201510601753.2A patent/CN105230625A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101657423A (en) * | 2007-02-22 | 2010-02-24 | 先正达参股股份有限公司 | Iminipyridine derivatives and they purposes as microbicide |
| WO2009088103A1 (en) * | 2008-01-11 | 2009-07-16 | Ishihara Sangyo Kaisha, Ltd. | Pyridylamidine compound or salt thereof, and agricultural or horticultural fungicide composition containing the same as active ingredient |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104010503A (en) | 2014-08-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6143775B2 (en) | Fungicidal composition | |
| RU2636978C2 (en) | Methods of controlling soil pests | |
| TWI504350B (en) | Fungicidal pyrazoles and their mixtures | |
| KR20200003787A (en) | Fungicide oxadiazole | |
| MX2014009276A (en) | Fungicidal pyrazole mixtures. | |
| KR20150080498A (en) | Substituted tolyl fungicides | |
| KR102227271B1 (en) | Fungicidal amides | |
| KR102105863B1 (en) | Methods of controlling insects | |
| US10111434B2 (en) | Binary fungicidal mixtures | |
| IL297524A (en) | Substituted tolyl fungicides and their mixtures | |
| CN115460921A (en) | Fungicidal halomethyl ketones and hydrates and mixtures thereof | |
| CN105230625A (en) | Antifungal composition | |
| CN105283450B (en) | Triazole derivative | |
| CN103380123B (en) | Novel carboxamide microbiocides | |
| EA019857B1 (en) | Insecticidal compounds | |
| TWI631897B (en) | Method for protecting useful plants or plant propagation material | |
| CN109890795A (en) | The imdazole derivatives that new 5- replaces | |
| CN109715621A (en) | New triazole derivative | |
| CN109715622A (en) | New triazole derivative and its purposes as fungicide | |
| TW202342431A (en) | Fungicidal halomethyl ketones, hydrates and enol ethers | |
| CN109843065A (en) | Active agent combinations comprising the 5- imdazole derivatives replaced |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160113 |