CN105222644A - A kind of manufacture method of water gun - Google Patents

A kind of manufacture method of water gun Download PDF

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Publication number
CN105222644A
CN105222644A CN201510560325.XA CN201510560325A CN105222644A CN 105222644 A CN105222644 A CN 105222644A CN 201510560325 A CN201510560325 A CN 201510560325A CN 105222644 A CN105222644 A CN 105222644A
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CN
China
Prior art keywords
tablet
installation portion
effervescent tablet
stopper
loading port
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201510560325.XA
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Chinese (zh)
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CN105222644B (en
Inventor
黄文佳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Shepherd Water Amusement Park Equipment Co Ltd
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Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201610532626.6A priority Critical patent/CN106123684A/en
Priority to CN201510560325.XA priority patent/CN105222644B/en
Priority to CN201610532577.6A priority patent/CN106197143A/en
Priority to CN201610532538.6A priority patent/CN105973065A/en
Publication of CN105222644A publication Critical patent/CN105222644A/en
Application granted granted Critical
Publication of CN105222644B publication Critical patent/CN105222644B/en
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Anticipated expiration legal-status Critical

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41BWEAPONS FOR PROJECTING MISSILES WITHOUT USE OF EXPLOSIVE OR COMBUSTIBLE PROPELLANT CHARGE; WEAPONS NOT OTHERWISE PROVIDED FOR
    • F41B9/00Liquid ejecting guns, e.g. water pistols, devices ejecting electrically charged liquid jets, devices ejecting liquid jets by explosive pressure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41BWEAPONS FOR PROJECTING MISSILES WITHOUT USE OF EXPLOSIVE OR COMBUSTIBLE PROPELLANT CHARGE; WEAPONS NOT OTHERWISE PROVIDED FOR
    • F41B9/00Liquid ejecting guns, e.g. water pistols, devices ejecting electrically charged liquid jets, devices ejecting liquid jets by explosive pressure
    • F41B9/0087Liquid ejecting guns, e.g. water pistols, devices ejecting electrically charged liquid jets, devices ejecting liquid jets by explosive pressure characterised by the intended use, e.g. for self-defence, law-enforcement, industrial use, military purposes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Technology Law (AREA)
  • Cosmetics (AREA)
  • Medicinal Preparation (AREA)
  • Toys (AREA)

Abstract

The invention discloses a kind of manufacture method of water gun, water gun structure includes rifle body, and seal the stopper of grafting with the filling opening of rifle body; Described stopper includes columniform tablet installation portion, and tablet installation portion forms the plural installation storehouse in order to install effervescent tablet, installs side, storehouse and forms the loading port and grid mouth of inserting for effervescent tablet; The position seals of the corresponding loading port of tablet installation portion is connected with fixing seal film, and the position of tablet installation portion sidewall each grid mouth corresponding is sealedly connected with removable diaphragm seal respectively.First described removable diaphragm seal is first connected with the hot pressing of tablet installation portion; Then the effervescent tablet of compression molding being loaded each from loading port installs storehouse; Finally described fixing seal film is connected with the hot pressing of tablet installation portion; Finally by the stopper plug made on the filling opening of rifle body.The hydraulic giant cost that the method obtains is low, safety easy to use.

Description

A kind of manufacture method of water gun
Technical field
The invention belongs to toy art, be specifically related to a kind of manufacture method of water gun.
Background technology
Some water gun is accompanied with by the liquid medicine of alkaline solution, phenolphthalein and/or thymolphthalein furnishing on the market at present, carbon dioxide generation chemical reaction after liquid medicine is penetrated by hydraulic giant and in air makes liquid medicine ph value decline, time outside the color range that ph value drops to phenolphthalein or thymolphthalein, originally to take on a red color or liquid medicine that is blue or purple becomes colourless liquid.This kind of hydraulic giant playability is strong, deeply likes by children.But water gun in transportation and sale because the cause of liquid medicine makes packing instructions higher, liquid medicine itself needs bottle to accommodate, and adds cost, and adds weight, and corresponding cost of transportation also increases.Liquid medicine is made concentrate by Ye You producer in addition, use after pouring a small amount of concentrate into during water gun and add running water, but the concentration of concentrate is higher, and alkalescence is comparatively strong, with it concentrate easily spreads when children use, there is unsafe factor.
Summary of the invention
Technical problem to be solved by this invention is: the deficiency existed for prior art, provides a kind of and sprays red solution and can the manufacture method of water gun of self-discoloration.
For realizing the object of the present invention, being achieved by the following technical solutions: a kind of manufacture method of water gun, water gun structure including rifle body, and seal the stopper of grafting with the filling opening of rifle body;
Described stopper includes a cock body and is shaped in the tablet installation portion of cock body lower end, and periphery, described cock body upper end forms the flanging that external wall offsets with rifle; Described tablet installation portion is cylindrical, tablet installation portion forms the plural installation storehouse in order to install effervescent tablet along its length, the position in the corresponding each installation storehouse of tablet installation portion sidewall forms the loading port of inserting for effervescent tablet, and with loading port just to the grid mouth that the stop effervescent tablet arranged is deviate from;
The position seals of the corresponding loading port of described tablet installation portion sidewall is connected with the fixing seal film that seals all loading ports, the position of described tablet installation portion sidewall each grid mouth corresponding is sealedly connected with removable diaphragm seal respectively, and the side of removable diaphragm seal is one-body molded tears head;
Described effervescent tablet comprises the component of following weight ratio:
Absolute ethyl alcohol 1.5-2.5
Maltodextrin 0.25-0.35
Phenolphthalein 0.03-0.06
Sodium carbonate 7
Tartaric acid 3-4
Superfine silica gel powder 0.05-0.15
Dolomol 0.05-0.15
Talcum powder 0.05-0.15
Sodium chloride 1-2
Sodium acid carbonate 0.5-1.5;
The preparation method of described effervescent tablet comprises the following steps:
1. phenolphthalein is dissolved in absolute ethyl alcohol;
2. sodium carbonate is dried to water content lower than 3%, adds maltodextrin subsequently and mix;
3. step raw material 1. and is 2. mixed;
4. tartaric acid is dried to water content lower than 5%, the superfine silica gel powder adding half weight subsequently mixes;
5. 3. step is mixed with step raw material 4.;
6. in upper step raw material, add talcum powder, sodium chloride, sodium acid carbonate and remaining superfine silica gel powder mix;
7. dolomol is added in upper step raw material before compressing tablet and mix;
8. added in tablet press machine by upper step raw material and carry out compressing tablet, control temperature is lower than 30 DEG C, and relative air humidity is lower than 40%, and tableting pressure is 10-30KN;
9. shaping effervescent tablet is put into drying machine drying, temperature controls at 100-120 DEG C, drying time 10-15min.
The preparation method of described stopper comprises the following steps:
1. described removable diaphragm seal is first connected with the hot pressing of tablet installation portion;
2. then the effervescent tablet of compression molding being loaded each from loading port installs storehouse;
3. described fixing seal film is connected with the hot pressing of tablet installation portion;
Finally by the stopper plug made on the filling opening of rifle body.
Compared with prior art, the invention has the beneficial effects as follows: effervescent tablet forms the alkaline solution that pH value is 8.5-10 after being dissolved in a certain amount of water, with the carbon dioxide reaction in air after solution to be mapped on clothing or wall by hydraulic giant, pH value reduces, solution gradually becomes colourless, and playability is strong.Sell in the lump together with hydraulic giant in the stopper that effervescent tablet is contained in hydraulic giant, tear a removable diaphragm seal during use at every turn, directly add water in hydraulic giant, jam-pack stopper, keeps flat hydraulic giant and running water is poured into from grid mouth, after treat that effervescent tablet dissolves completely and can use, compared to existing technology, eliminate the bottle being specifically designed to and containing liquid medicine, alleviate weight, reduce packaging, transport every cost.Effervescent tablet according to the amount of capacity respective design of hydraulic giant, make hydraulic giant add water after formed solution ph be in required scope.Described sodium carbonate on the one hand and tartaric acid coupling produces acid-base neutralization and reacts and produce carbon dioxide thus produce effervesce effect effervescent tablet is melted rapidly, the excessive sodium carbonate of another aspect forms the alkaline solution that phenolphthalein is developed the color.Described sodium chloride, as drawing humectant, contributes to moisture and infiltrates the thawing accelerating effervescent tablet in effervescent tablet.Described sodium acid carbonate produces carbon dioxide after heating, drying, makes effervescent tablet loose porous, accelerates the thawing speed of effervescent tablet further.Often hydraulic giant can be furnished with multiple stopper, to increase access times.Directly can not touch effervescent tablet in children's use procedure in addition, the raw material of effervescent tablet is all desirable from food grade materials, use safety, and the solution that effervescent tablet is formed after dissolving does not have toxicity, alkalescence is more weak, is sprayed onto mouth and nose on a small quantity and at the moment uses running water to clean, not dangerous property.In addition solution has the bitter taste of sodium carbonate, and children can not eat by mistake, and a small amount of eating also can not work the mischief to health.Although phenolphthalein has laxative action, the content of each effervescent tablet is only about 1 microgram, and eating a small amount of solution can not have an impact to stomach.
Accompanying drawing explanation
Fig. 1 is the structural representation of hydraulic giant of the present invention.
Fig. 2 is the structural representation of stopper.
Fig. 3 is the decomposition texture schematic diagram of stopper.
Fig. 4, Fig. 5 are the structural representations before stopper does not load effervescent tablet.
1, rifle body; 2, stopper; 21, cock body; 211, flanging; 22, tablet installation portion; 220, storehouse is installed; 221, loading port; 222, grid mouth; 23, fixing seal film; 24, removable diaphragm seal; 241, head is torn; 3, effervescent tablet.
Detailed description of the invention
embodiment 1
According to shown in Fig. 1 to Fig. 5, the present embodiment is a kind of manufacture method of water gun, water gun structure includes rifle body 1, and seals the stopper 2 of grafting with the filling opening of rifle body.
Described stopper includes a cock body 21 and is shaped in the tablet installation portion 22 of cock body lower end, and periphery, described cock body upper end forms the flanging 211 that the external wall with rifle offsets; Described tablet installation portion is cylindrical, tablet installation portion forms the plural installation storehouse 220 in order to install effervescent tablet along its length, the position in the corresponding each installation storehouse of tablet installation portion sidewall forms the loading port 221 of inserting for effervescent tablet 3, and with loading port just to the grid mouth 222 that the stop effervescent tablet arranged is deviate from; Described grid mouthpiece has 3-6 width to be the rectangular gap of 0.5-1.0mm.
The position seals of the corresponding loading port of described tablet installation portion sidewall is connected with the fixing seal film 23 that seals all loading ports, the position of described tablet installation portion sidewall each grid mouth corresponding is sealedly connected with removable diaphragm seal 24 respectively, and the side of removable diaphragm seal is one-body molded tears 241.
Described effervescent tablet comprises the component of following weight ratio:
Absolute ethyl alcohol 2
Maltodextrin 0.3
Phenolphthalein 0.05
Sodium carbonate 7
Tartaric acid 3.5
Superfine silica gel powder 0.1
Dolomol 0.1
Talcum powder 0.1
Sodium chloride 1.5
Sodium acid carbonate 1
The preparation method of described toy effervescent tablet comprises the following steps:
1. phenolphthalein is dissolved in absolute ethyl alcohol;
2. sodium carbonate is dried to water content 1%, adds maltodextrin subsequently and mix;
3. step raw material 1. and is 2. mixed;
4. tartaric acid is dried to water content 3%, the superfine silica gel powder adding half weight subsequently mixes;
5. 3. step is mixed with step raw material 4.;
6. in upper step raw material, add talcum powder, sodium chloride, sodium acid carbonate, remaining superfine silica gel powder mix;
7. dolomol is added in upper step raw material before compressing tablet and mix;
8. added in tablet press machine by upper step raw material and carry out compressing tablet, control temperature 20 DEG C, relative air humidity 30%, tableting pressure is 20KN; Shaping effervescent tablet is put into drying machine drying, and temperature controls at 110 DEG C, drying time 13min.
The preparation method of described stopper comprises the following steps:
1. described removable diaphragm seal is first connected with the hot pressing of tablet installation portion;
2. then the effervescent tablet of compression molding being loaded each from loading port installs storehouse;
3. described fixing seal film is connected with the hot pressing of tablet installation portion;
Finally by the stopper plug made on the filling opening of rifle body.
The every sheet 0.2g of effervescent tablet of the present embodiment, hydraulic giant rifle body capacity 55ml, after filling it up with running water, dissolution time is 50-55s, and ejection liquid is aubergine.
embodiment 2
According to shown in Fig. 1 to Fig. 5, the present embodiment is a kind of manufacture method of water gun, water gun structure includes rifle body 1, and seals the stopper 2 of grafting with the filling opening of rifle body.
Described stopper includes a cock body 21 and is shaped in the tablet installation portion 22 of cock body lower end, and periphery, described cock body upper end forms the flanging 211 that the external wall with rifle offsets; Described tablet installation portion is cylindrical, tablet installation portion forms the plural installation storehouse 220 in order to install effervescent tablet along its length, the position in the corresponding each installation storehouse of tablet installation portion sidewall forms the loading port 221 of inserting for effervescent tablet 3, and with loading port just to the grid mouth 222 that the stop effervescent tablet arranged is deviate from; Described grid mouthpiece has 3-6 width to be the rectangular gap of 0.5-1.0mm.
The position seals of the corresponding loading port of described tablet installation portion sidewall is connected with the fixing seal film 23 that seals all loading ports, the position of described tablet installation portion sidewall each grid mouth corresponding is sealedly connected with removable diaphragm seal 24 respectively, and the side of removable diaphragm seal is one-body molded tears 241.
Described effervescent tablet comprises the component of following weight ratio:
Absolute ethyl alcohol 2.5
Maltodextrin 0.35
Phenolphthalein 0.06
Sodium carbonate 7
Tartaric acid 3
Superfine silica gel powder 0.15
Dolomol 0.15
Talcum powder 0.15
Sodium chloride 1
Sodium acid carbonate 0.5
The preparation method of described toy effervescent tablet comprises the following steps:
1. phenolphthalein is dissolved in absolute ethyl alcohol;
2. sodium carbonate is dried to water content 2%, adds maltodextrin subsequently and mix;
3. step raw material 1. and is 2. mixed;
4. tartaric acid is dried to water content 4%, the superfine silica gel powder adding half weight subsequently mixes;
5. 3. step is mixed with step raw material 4.;
6. in upper step raw material, add talcum powder, sodium chloride, sodium acid carbonate, remaining superfine silica gel powder mix;
7. dolomol is added in upper step raw material before compressing tablet and mix;
8. added in tablet press machine by upper step raw material and carry out compressing tablet, control temperature 28 DEG C, relative air humidity 30%, tableting pressure is 30KN; Shaping effervescent tablet is put into drying machine drying, and temperature controls at 120 DEG C, drying time 15min;
The preparation method of described stopper comprises the following steps:
1. described removable diaphragm seal is first connected with the hot pressing of tablet installation portion;
2. then the effervescent tablet of compression molding being loaded each from loading port installs storehouse;
3. described fixing seal film is connected with the hot pressing of tablet installation portion;
Finally by the stopper plug made on the filling opening of rifle body.
The every sheet 0.2g of effervescent tablet of the present embodiment, hydraulic giant rifle body capacity 55ml, after filling it up with running water, dissolution time is 110-120s, and ejection liquid be aubergine and estimates that to compare embodiment 1 color dark.
embodiment 3
According to shown in Fig. 1 to Fig. 5, the present embodiment is a kind of manufacture method of water gun, water gun structure includes rifle body 1, and seals the stopper 2 of grafting with the filling opening of rifle body.
Described stopper includes a cock body 21 and is shaped in the tablet installation portion 22 of cock body lower end, and periphery, described cock body upper end forms the flanging 211 that the external wall with rifle offsets; Described tablet installation portion is cylindrical, tablet installation portion forms the plural installation storehouse 220 in order to install effervescent tablet along its length, the position in the corresponding each installation storehouse of tablet installation portion sidewall forms the loading port 221 of inserting for effervescent tablet 3, and with loading port just to the grid mouth 222 that the stop effervescent tablet arranged is deviate from; Described grid mouthpiece has 3-6 width to be the rectangular gap of 0.5-1.0mm.
The position seals of the corresponding loading port of described tablet installation portion sidewall is connected with the fixing seal film 23 that seals all loading ports, the position of described tablet installation portion sidewall each grid mouth corresponding is sealedly connected with removable diaphragm seal 24 respectively, and the side of removable diaphragm seal is one-body molded tears 241.
Described effervescent tablet comprises the component of following weight ratio:
Absolute ethyl alcohol 1.5
Maltodextrin 0.25
Phenolphthalein 0.03
Sodium carbonate 7
Tartaric acid 4
Superfine silica gel powder 0.05
Dolomol 0.05
Talcum powder 0.05
Sodium chloride 2
Sodium acid carbonate 1.5
The preparation method of described toy effervescent tablet comprises the following steps:
1. phenolphthalein is dissolved in absolute ethyl alcohol;
2. sodium carbonate is dried to water content 2%, adds maltodextrin subsequently and mix;
3. step raw material 1. and is 2. mixed;
4. tartaric acid is dried to water content 4%, the superfine silica gel powder adding half weight subsequently mixes;
5. 3. step is mixed with step raw material 4.;
6. in upper step raw material, add talcum powder, sodium chloride, sodium acid carbonate, remaining superfine silica gel powder mix;
7. dolomol is added in upper step raw material before compressing tablet and mix;
8. added in tablet press machine by upper step raw material and carry out compressing tablet, control temperature 20 DEG C, relative air humidity 20%, tableting pressure is 15KN; Shaping effervescent tablet is put into drying machine drying, and temperature controls at 100 DEG C, drying time 10min;
The preparation method of described stopper comprises the following steps:
1. described removable diaphragm seal is first connected with the hot pressing of tablet installation portion;
2. then the effervescent tablet of compression molding being loaded each from loading port installs storehouse;
3. described fixing seal film is connected with the hot pressing of tablet installation portion;
Finally by the stopper plug made on the filling opening of rifle body.
The every sheet 0.2g of effervescent tablet of the present embodiment, hydraulic giant rifle body capacity 55ml, after filling it up with running water, dissolution time is 30-40s, and it is of light color that embodiment 1 is obviously compared in the range estimation of ejection liquid pinkiness.
The proportioning of embodiment 1 raw material is best, and main acid/base ratio is suitable, and such reaction speed is very fast and can ensure that sodium carbonate dissolves quickly completely, there will not be hard core to remain, and tableting pressure is suitable, makes effervescent tablet hardness moderate.The sodium acid carbonate that adds water makes to form a certain amount of pore in effervescent tablet when drying, and what coordinate sodium chloride when dissolving draws wet effect, makes effervescent tablet dissolve rapidly, effective.Embodiment 2 sodium carbonate is more, and after dissolving, solution colour can be comparatively dark, but need the time of wait longer, and the large percentage of embodiment 3 acid, dissolve rapidly, but make ph value less, solution colour is lighter.

Claims (1)

1. a manufacture method for water gun, is characterized in that: water gun structure includes rifle body, and seals the stopper of grafting with the filling opening of rifle body;
Described stopper includes a cock body and is shaped in the tablet installation portion of cock body lower end, and periphery, described cock body upper end forms the flanging that external wall offsets with rifle; Described tablet installation portion is cylindrical, tablet installation portion forms the plural installation storehouse in order to install effervescent tablet along its length, the position in the corresponding each installation storehouse of tablet installation portion sidewall forms the loading port of inserting for effervescent tablet, and with loading port just to the grid mouth that the stop effervescent tablet arranged is deviate from;
The position seals of the corresponding loading port of described tablet installation portion sidewall is connected with the fixing seal film that seals all loading ports, the position of described tablet installation portion sidewall each grid mouth corresponding is sealedly connected with removable diaphragm seal respectively, and the side of removable diaphragm seal is one-body molded tears head;
Described effervescent tablet comprises the component of following weight ratio:
Absolute ethyl alcohol 1.5-2.5
Maltodextrin 0.25-0.35
Phenolphthalein 0.03-0.06
Sodium carbonate 7
Tartaric acid 3-4
Superfine silica gel powder 0.05-0.15
Dolomol 0.05-0.15
Talcum powder 0.05-0.15
Sodium chloride 1-2
Sodium acid carbonate 0.5-1.5;
The preparation method of described effervescent tablet comprises the following steps:
Phenolphthalein is dissolved in absolute ethyl alcohol;
Sodium carbonate is dried to water content lower than 3%, adds maltodextrin subsequently and mix;
Step raw material 1. and is 2. mixed;
Tartaric acid is dried to water content lower than 5%, the superfine silica gel powder adding half weight subsequently mixes;
3. step is mixed with step raw material 4.;
In upper step raw material, add talcum powder, sodium chloride, sodium acid carbonate and remaining superfine silica gel powder mix;
Dolomol is added in upper step raw material before compressing tablet and mix;
8. added in tablet press machine by upper step raw material and carry out compressing tablet, control temperature is lower than 30 DEG C, and relative air humidity is lower than 40%, and tableting pressure is 10-30KN;
9. shaping effervescent tablet is put into drying machine drying, temperature controls at 100-120 DEG C, drying time 10-15min;
The preparation method of described stopper comprises the following steps:
1. described removable diaphragm seal is first connected with the hot pressing of tablet installation portion;
2. then the effervescent tablet of compression molding being loaded each from loading port installs storehouse;
3. described fixing seal film is connected with the hot pressing of tablet installation portion;
Finally by the stopper plug made on the filling opening of rifle body.
CN201510560325.XA 2015-09-07 2015-09-07 A kind of manufacture method of water gun Active CN105222644B (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN201610532626.6A CN106123684A (en) 2015-09-07 2015-09-07 A kind of manufacture method of water gun
CN201510560325.XA CN105222644B (en) 2015-09-07 2015-09-07 A kind of manufacture method of water gun
CN201610532577.6A CN106197143A (en) 2015-09-07 2015-09-07 A kind of manufacture method of water gun
CN201610532538.6A CN105973065A (en) 2015-09-07 2015-09-07 Manufacturing method for water gun

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510560325.XA CN105222644B (en) 2015-09-07 2015-09-07 A kind of manufacture method of water gun

Related Child Applications (3)

Application Number Title Priority Date Filing Date
CN201610532577.6A Division CN106197143A (en) 2015-09-07 2015-09-07 A kind of manufacture method of water gun
CN201610532626.6A Division CN106123684A (en) 2015-09-07 2015-09-07 A kind of manufacture method of water gun
CN201610532538.6A Division CN105973065A (en) 2015-09-07 2015-09-07 Manufacturing method for water gun

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Publication Number Publication Date
CN105222644A true CN105222644A (en) 2016-01-06
CN105222644B CN105222644B (en) 2016-11-23

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CN201510560325.XA Active CN105222644B (en) 2015-09-07 2015-09-07 A kind of manufacture method of water gun
CN201610532538.6A Pending CN105973065A (en) 2015-09-07 2015-09-07 Manufacturing method for water gun
CN201610532626.6A Pending CN106123684A (en) 2015-09-07 2015-09-07 A kind of manufacture method of water gun

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CN201610532626.6A Pending CN106123684A (en) 2015-09-07 2015-09-07 A kind of manufacture method of water gun

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01155884A (en) * 1987-12-14 1989-06-19 Nippon Fine Chem Kk Composition for water-soluble toy
CN1094510A (en) * 1993-04-20 1994-11-02 完美圈漆球有限公司 Paint ball
CN1355416A (en) * 2000-11-28 2002-06-26 阮志成 Full-automatic mechanical paint bullet gun
CN101195690A (en) * 2008-01-08 2008-06-11 山西大学 Variable multicolor flour mud powder and method for producing the same
CN103591836A (en) * 2013-11-18 2014-02-19 山西大学 Multifunctional children water gun fluid

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1660096A (en) * 2004-02-23 2005-08-31 韩昌栓 Effervescence tablet of fibrauretine and preparation method
CN100341488C (en) * 2005-11-22 2007-10-10 瑞普(保定)生物药业有限公司 Immune effervescent tablets for drinking water and its prepn. method
CN101016108A (en) * 2007-03-06 2007-08-15 王跃进 Magic drinking bottle and healthy effervescence beverage thereof
CN102001714A (en) * 2009-09-01 2011-04-06 天津瑞普生物技术股份有限公司 Effervescent tablet capable of purifying water quality and preparation method thereof
CN101892133B (en) * 2010-07-22 2012-03-21 兰州泰坦生物科技有限责任公司 Effervescent tablet for removing pesticide residue on fruits and vegetables and preparation method and use method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01155884A (en) * 1987-12-14 1989-06-19 Nippon Fine Chem Kk Composition for water-soluble toy
CN1094510A (en) * 1993-04-20 1994-11-02 完美圈漆球有限公司 Paint ball
CN1355416A (en) * 2000-11-28 2002-06-26 阮志成 Full-automatic mechanical paint bullet gun
CN101195690A (en) * 2008-01-08 2008-06-11 山西大学 Variable multicolor flour mud powder and method for producing the same
CN103591836A (en) * 2013-11-18 2014-02-19 山西大学 Multifunctional children water gun fluid

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Publication number Publication date
CN106123684A (en) 2016-11-16
CN105973065A (en) 2016-09-28
CN106197143A (en) 2016-12-07
CN105222644B (en) 2016-11-23

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