CN105220199B - Improve the method and device of Waste Acid From Hua Cheng Foil presentation quality - Google Patents
Improve the method and device of Waste Acid From Hua Cheng Foil presentation quality Download PDFInfo
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- CN105220199B CN105220199B CN201510740467.4A CN201510740467A CN105220199B CN 105220199 B CN105220199 B CN 105220199B CN 201510740467 A CN201510740467 A CN 201510740467A CN 105220199 B CN105220199 B CN 105220199B
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- bottom roll
- pallet
- waste acid
- hua cheng
- cheng foil
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Abstract
The invention discloses a kind of method and device for improving Waste Acid From Hua Cheng Foil presentation quality, it is related to aluminium electrolutic capacitor medium-high pressure chemical foil production technical field, solves the dregs in electrolyte, crystalline solid and the appearance quality of such as pit, hole print, breach easily is caused to the surface of Waste Acid From Hua Cheng Foil.The technical scheme of use is:The method for improving Waste Acid From Hua Cheng Foil presentation quality, Waste Acid From Hua Cheng Foil is aoxidized by electrolyte, and in electrolyte, the top of Waste Acid From Hua Cheng Foil sets pallet, and pallet is made up of isolation material.Improve the device of Waste Acid From Hua Cheng Foil presentation quality, including electrolytic bath and transmission device, transmission device includes the bottom roll being installed in electrolytic bath and the upper roller being installed on above electrolytic bath, upper roller and bottom roll form roller group, bottom roll is fixed on conductive plate and hung in electrolytic bath, and the pallet is fixedly mounted above bottom roll.Dregs particle, crystalline solid in electrolyte are dropped into pallet, avoid dropping on Waste Acid From Hua Cheng Foil and bottom roll, avoid causing Waste Acid From Hua Cheng Foil appearance quality.
Description
Technical field
The present invention relates to aluminium electrolutic capacitor medium-high pressure chemical foil production technical field, more particularly to aluminium electrolutic capacitor
With the method and device of middle raising Waste Acid From Hua Cheng Foil presentation quality.
Background technology
Aluminium electrolutic capacitor with the primary base material of Waste Acid From Hua Cheng Foil be content be 99.99% high-purity aluminium foil, claim light paper tinsel.
Light paper tinsel carries out corrosion reaming to aluminium foil, accumulates to form etched foil to increase aluminium foil surface, etched foil passes through again through electrochemical production flow
Cross under powerful DC electric field effect, pre-processed in the electrolyte of specified temp, one-level is melted into, two level is melted into, three-level
Into production procedures such as, level Four chemical conversion, Pyatyi chemical conversion, high-temperature process, Passivation Treatment, cleaning, drying, the insulating oxide of densification is formed
Film (Al2O3), obtain Waste Acid From Hua Cheng Foil.
Aluminium electrolutic capacitor is mainly come area with the opering characteristic of electric apparatus, mechanical property and appearance characteristics with the quality standard of Waste Acid From Hua Cheng Foil
Point and final conclusion, and high-quality Waste Acid From Hua Cheng Foil has to meet above three technical conditions simultaneously.
Waste Acid From Hua Cheng Foil is very thin, and thickness is micron-sized, and its thickness is usually 1um or so, hole occurs on so thin thickness
Hole or breakage etc., the unit for electrical property parameters of Waste Acid From Hua Cheng Foil can be directly influenced or cause Waste Acid From Hua Cheng Foil to be scrapped.In the production of Waste Acid From Hua Cheng Foil
Cheng Zhong, because the reason for equipment and electrolyte is easiest to produce the appearance qualities such as hole, cut, breach on Waste Acid From Hua Cheng Foil surface.
Therefore, appearance characteristics are highly important quality metrics for Waste Acid From Hua Cheng Foil.
Existing Waste Acid From Hua Cheng Foil production stage mainly includes:Pre-treatment → level Four or Pyatyi chemical conversion → high-temperature process → are melted into again
The steps such as → post processing → cleaning → drying → heating → circulation → transmission → filtering.Fig. 1 show existing Waste Acid From Hua Cheng Foil production
The schematic diagram of the electrolytic bath of equipment, Waste Acid From Hua Cheng Foil 1 pass through multiple electrolytic baths 2 respectively by transmission device, and transmission device includes upper rolling
Cylinder 3 and bottom roll 4, wherein bottom roll 4 are fixedly installed in electrolytic bath 2 by conductive plate 5, and electrolyte is filled in electrolytic bath 2
6, Waste Acid From Hua Cheng Foil 1 is positioned between roller 3 and bottom roll 4, and is driven and run incessantly by upper roller 3 and bottom roll 4.
Waste Acid From Hua Cheng Foil positively charged, chemical conversion tank liquor (temperature is 85 DEG C or so) is negatively charged, and Waste Acid From Hua Cheng Foil is under the drive of transmission device
Continuous operation, Waste Acid From Hua Cheng Foil form the dielectric oxide film (Al of densification under powerful DC electric field effect in aluminium foil surface2O3), warp
Waste Acid From Hua Cheng Foil is become after over cleaning drying.Electrolyte for producing Waste Acid From Hua Cheng Foil is through high temperature (85 by boric acid, phosphoric acid, adipic acid
DEG C or so) form after dissolving, because boric acid, phosphoric acid and adipic acid are originally solid, although by 85 DEG C of dissolvings, boric acid, phosphorus
The dregs remained in acid and adipic acid are not easily dissolved.In addition, because the temperature of electrolyte change when, particularly when temperature compared with
When low, crystalline polamer occurs in boron phosphoric acid and adipic acid in electrolyte.
The paper tinsel face of Waste Acid From Hua Cheng Foil is to be close to roller and bottom roll operation, when these dregs particle, crystalline solid in electrolyte
It can fall between Waste Acid From Hua Cheng Foil and bottom roll, these dregs particles and crystalline solid are with the rotation of bottom roll, it is easy to Waste Acid From Hua Cheng Foil
Surface cause pit, hole print, problem of appearance, the severe patient such as breach to expose paper tinsel face.Although there is filtering system outside electrolytic bath
System, but due to dregs, particle be in groove caused by, electrolytic bath electrolyte inside be do not arrhea it is dynamic, so this can not be filtered out
A little dregs particles and crystalline solid.Once this phenomenon of generation and problem, it will have a strong impact on the quality of Waste Acid From Hua Cheng Foil, or even cause
Waste Acid From Hua Cheng Foil becomes item for disposal and scrap, increases manufacturing cost.If the product of some bad orders flows to Capacitor manufactures hand
In, the capacitor come out by this product manufacturing easily causes breakdown and influences end-equipment safety, and harm is very huge.
The content of the invention
The present invention provides a kind of method for improving Waste Acid From Hua Cheng Foil presentation quality, and dregs, the crystalline solid solved in electrolyte is easy
The appearance quality of such as pit, hole print, breach is caused to the surface of Waste Acid From Hua Cheng Foil.
The present invention solves the technical scheme that above-mentioned technical problem uses:The method for improving Waste Acid From Hua Cheng Foil presentation quality, chemical conversion
Paper tinsel is aoxidized by electrolyte, and in electrolyte, the top of Waste Acid From Hua Cheng Foil sets pallet, and pallet is made up of isolation material.
Because the top of Waste Acid From Hua Cheng Foil sets pallet, the dregs particle in electrolyte, and because the temperature of electrolyte occurs
Change, especially when the temperature is low, the crystalline solid that boron phosphoric acid and adipic acid in electrolyte occur are dropped into pallet, are avoided
Drop on Waste Acid From Hua Cheng Foil, avoid causing Waste Acid From Hua Cheng Foil appearance quality.
Specifically, Waste Acid From Hua Cheng Foil is aoxidized by multiple electrolytic baths respectively by transmission device, and electrolysis is filled in electrolytic bath
Liquid, transmission device include the bottom roll being installed in electrolytic bath and the upper roller being installed on above electrolytic bath, upper roller and lower rolling
Cylinder forms roller group, and Waste Acid From Hua Cheng Foil fits in the outer surface of roller and bottom roll, and pallet is installed in the top of bottom roll respectively.
It is further that the width of the pallet is identical with the width of bottom roll, the length of pallet is not less than bottom roll
The length direction of length, wherein bottom roll is consistent with the axial direction of bottom roll.
It is further that the bottom roll is installed in electrolytic bath by conductive plate respectively, and pallet is fixedly installed in down
On conductive plate above roller.
It is further that the pallet is made up of FRP material.
It is further that the pallet sets up side shield respectively parallel to the both sides of the length direction of bottom roll, support
Disk perpendicular to the both ends of the length direction of bottom roll without side shield, in open, the U-shaped profile of pallet.
The present invention also provides a kind of device for realizing any one above-mentioned raising Waste Acid From Hua Cheng Foil presentation quality method, solves to pass through
Existing apparatus produces Waste Acid From Hua Cheng Foil, and the dregs, crystalline solid in electrolyte easily cause Waste Acid From Hua Cheng Foil appearance quality.
The technical scheme of use is:Improve the device of Waste Acid From Hua Cheng Foil presentation quality, including electrolytic bath and transmission device, transmission dress
Put and form roller including the bottom roll being installed in electrolytic bath and the upper roller being installed on above electrolytic bath, upper roller and bottom roll
Group, bottom roll are fixed on conductive plate and hung in electrolytic bath, pallet are fixedly mounted above bottom roll, pallet is by insulation material
Matter is made.
It is further that the pallet is fixedly installed on the conductive plate above bottom roll, the width of pallet and lower rolling
The width of cylinder is identical, and the length of pallet is not less than the length of bottom roll, the length direction of bottom roll and the axial direction of bottom roll
Unanimously, the wherein length direction of bottom roll and the axial direction of bottom roll is consistent.
It is further that the pallet is made up of FRP material.
It is further that the pallet sets up side shield respectively parallel to the both sides of the length direction of bottom roll, support
Disk perpendicular to the both ends of the length direction of bottom roll without side shield, in open, the U-shaped profile of pallet.
The beneficial effects of the invention are as follows:Improve the method and device of Waste Acid From Hua Cheng Foil presentation quality, in electrolyte, Waste Acid From Hua Cheng Foil
Top sets pallet, and the dregs particle and/or crystalline solid in electrolyte are fallen into pallet, avoid dropping into the surface of Waste Acid From Hua Cheng Foil,
Appearance quality is caused to the surface of Waste Acid From Hua Cheng Foil.
Pallet sets up side shield respectively parallel to the both sides of the length direction of bottom roll, and pallet vertical is in bottom roll
The both ends of length direction are without side shield, and in open, dregs particle, crystalline solid in electrolyte are dropped into pallet, with electricity
The circulation of solution liquid flows to two of pallet, then the continuously filtration system being discharged into outside groove.Avoid in electrolyte and produce
The infringement to the presentation quality of Waste Acid From Hua Cheng Foil of dregs and crystalline solid, ensure that the apparent parameter and product quality of Waste Acid From Hua Cheng Foil.
Brief description of the drawings
Fig. 1 is the electrolytic bath schematic diagram of existing Waste Acid From Hua Cheng Foil production equipment;
Fig. 2 is the electrolytic bath schematic diagram of the Waste Acid From Hua Cheng Foil production equipment of the present invention.
Parts, position and numbering in figure:Waste Acid From Hua Cheng Foil 1, electrolytic bath 2, upper roller 3, bottom roll 4, conductive plate 5, electrolysis
Liquid 6, pallet 7.
Embodiment
The invention will be further described below in conjunction with the accompanying drawings.
As shown in Fig. 2 the method that the present invention improves Waste Acid From Hua Cheng Foil presentation quality is:Waste Acid From Hua Cheng Foil 1 carries out oxygen by electrolyte 6
Change, in electrolyte 6, the top of Waste Acid From Hua Cheng Foil 1 sets pallet 7, and wherein pallet 7 is made up of isolation material.
Specifically, Waste Acid From Hua Cheng Foil 1 is aoxidized by multiple electrolytic baths 2 respectively by transmission device, and electricity is filled in electrolytic bath 2
Liquid 6 is solved, transmission device includes the bottom roll 4 being installed in electrolytic bath 2 and the upper roller 3 for being installed on the top of electrolytic bath 2, upper roller
3 and bottom roll 4 form roller group, Waste Acid From Hua Cheng Foil 1 fits in the outer surface of roller 3 and bottom roll 4, and by upper roller 3 and under
The cooperation of roller 4 is driven, such as two bottom rolls 4 are set in electrolytic bath 2 shown in Fig. 2, and bottom roll 4 passes through conductive electrode respectively
Plate 5 is installed in electrolytic bath 2.
In electrolyte 6, Waste Acid From Hua Cheng Foil 1 fits in bottom roll 4 and constantly moved, the dregs particle in electrolyte 6, Yi Jiyou
Changed in the temperature of electrolyte 6, especially when the temperature is low, the knot that boron phosphoric acid and adipic acid in electrolyte 6 occur
Crystal can fall into the upper surface of Waste Acid From Hua Cheng Foil 1, then roll between Waste Acid From Hua Cheng Foil 1 and bottom roll 4, and the presentation quality of Waste Acid From Hua Cheng Foil 1 is made
The problems such as into such as pit, hole print, breach.In order to avoid the problem, the top of Waste Acid From Hua Cheng Foil 1 sets pallet 7, and pallet 7 is by insulating
Material is made, and the width of pallet 7 is identical with the width of bottom roll 4, and the length of pallet 7 is not less than the length of bottom roll 4, wherein under
The length direction of roller 4 is consistent with the axial direction of bottom roll 4, and whole bottom roll 4 can be completely covered in such pallet 7, avoid electricity
Dregs particle, crystalline solid in solution liquid 6 are fallen between Waste Acid From Hua Cheng Foil 1 and bottom roll 4.
Pallet 7 is preferably made of FRP material.Pallet 7 is set upwards respectively parallel to the both sides of the length direction of bottom roll 4
Put side shield, pallet 7 is perpendicular to the both ends of the length direction of bottom roll 4 without side shield, and in open, the cross section of pallet 7 is in U
Shape.Dregs particle, crystalline solid in electrolyte 6 are dropped into pallet 7, and two of pallet 7 is flowed to the circulation of electrolyte 6,
It is discharged into again in the continuously filtration system outside groove.Pallet 7 can be in flat row, can also be in the curved surface consistent with bottom roll 4
Shape.The both ends of the length direction of pallet 7 can also set attachment structure, to be fixedly installed on conductive plate 5, in order to strengthen
Steadiness, trivet can be added between conductive plate 5 and pallet 7.
In addition, the present invention also provides a kind of device that above-mentioned raising Waste Acid From Hua Cheng Foil presentation quality method can be achieved.Such as Fig. 2 institutes
Show, improve the device of Waste Acid From Hua Cheng Foil presentation quality, including electrolytic bath 2 and transmission device, electrolytic bath 2 has multiple, and transmission device includes
The bottom roll 4 being installed in electrolytic bath 2 and the upper roller 3 being installed on above electrolytic bath 2, upper roller 3 and bottom roll 4 have more
Individual, upper roller 3 and bottom roll 4 form roller group, and bottom roll 4 is fixed on conductive plate 5 and hung in electrolytic bath 2, lower rolling
Pallet 7 is fixedly mounted in the top of cylinder 4, and pallet 7 is made up of isolation material.For example, pallet 7 is made up of FRP material.
Pallet 7 is installed on the top of bottom roll 4, and is not influenceed on the premise of bottom roll 4 rotates with pallet 7, pallet 7 and lower rolling
Distance as small as possible between cylinder 4.Pallet 2 can be installed on the top of bottom roll 4 by support meanss, can also be directly by pallet
7 are fixedly installed on the conductive plate 5 of the top of bottom roll 4, and the both ends of the length direction of pallet 7 set attachment structure to fix peace respectively
Loaded on conductive plate 5.The width of pallet 7 is identical with the width of bottom roll 4, and the length of pallet 7 is not less than the length of bottom roll 4
Degree, the length direction of bottom roll 4 is consistent with the axial direction of bottom roll 4, wherein the length direction of bottom roll 4 and bottom roll 4
Axial direction is consistent.
In order to avoid the dregs particle on pallet 7, crystalline solid fall into bottom roll 4 from the both sides of the length direction of pallet 7 and change
Into between paper tinsel 1, pallet 7 sets up side shield respectively parallel to the both sides of the length direction of bottom roll 4, and pallet 7 is under
The both ends of the length direction of roller 4 are without side shield, in open, the U-shaped profile of pallet 7.For example, the length of pallet 7 is
600mm, width 120mm, the height of side shield is 60mm.
The present invention improves the method and device of the presentation quality of Waste Acid From Hua Cheng Foil 1, and in electrolyte 6, the top of Waste Acid From Hua Cheng Foil 1 sets support
Disk 7, dregs particle and/or crystalline solid in electrolyte 6 are fallen into pallet 7, avoid dropping into the surface of Waste Acid From Hua Cheng Foil 1, are avoided pair
Appearance quality is caused on the surface of Waste Acid From Hua Cheng Foil 1, ensures the apparent parameter and product quality of Waste Acid From Hua Cheng Foil 1.
Claims (6)
1. improving the method for Waste Acid From Hua Cheng Foil presentation quality, Waste Acid From Hua Cheng Foil (1) is carried out by multiple electrolytic baths (2) respectively by transmission device
Oxidation, electrolytic bath (2) is interior to fill electrolyte (6), and transmission device includes the bottom roll (4) being installed in electrolytic bath (2) and installation
Upper roller (3) above electrolytic bath (2), upper roller (3) and bottom roll (4) form roller group, and Waste Acid From Hua Cheng Foil (1) fits in rolling
The outer surface of cylinder (3) and bottom roll (4), it is characterised in that:In electrolyte (6), pallet is installed in the top of bottom roll (4) respectively
(7), pallet (7) is made up of isolation material, and the width of pallet (7) is identical with the width of bottom roll (4), and the length of pallet (7) is not
It is consistent with the axial direction of bottom roll (4) less than the length of bottom roll (4), the wherein length direction of bottom roll (4);Pallet (7)
Side shield, length of the pallet (7) perpendicular to bottom roll (4) are set up respectively parallel to the both sides of the length direction of bottom roll (4)
The both ends in direction are spent without side shield, and in open, the bottom of pallet (7) is in the curve form consistent with bottom roll (4), electrolyte
(6) dregs particle, crystalline solid in are dropped into pallet (7), as the circulation of electrolyte (6) flows to two of pallet (7), then
It is discharged into the continuously filtration system outside groove.
2. the method for Waste Acid From Hua Cheng Foil presentation quality is improved as claimed in claim 1, it is characterised in that:The bottom roll (4) is respectively
It is installed on by conductive plate (5) in electrolytic bath (2), pallet (7) is fixedly installed in the conductive plate (5) above bottom roll (4)
On.
3. the method for Waste Acid From Hua Cheng Foil presentation quality is improved as claimed in claim 1, it is characterised in that:The pallet (7) is by FRP materials
Material is made.
4. the device of Waste Acid From Hua Cheng Foil presentation quality is improved, including electrolytic bath (2) and transmission device, transmission device include being installed on chemical conversion
Bottom roll (4) in groove (2) and the upper roller (3) being installed on above electrolytic bath (2), upper roller (3) and bottom roll (4) form rolling
Cylinder group, bottom roll (4) are fixed on conductive plate (5) and hung in electrolytic bath (2), it is characterised in that:Above bottom roll (4)
Pallet (7) is fixedly mounted, pallet (7) sets up side shield, pallet respectively parallel to the both sides of the length direction of bottom roll (4)
(7) perpendicular to bottom roll (4) length direction both ends without side shield, in open, the bottom of pallet (7) is in and bottom roll
(4) consistent curve form, the open both ends of pallet (7) are dregs particle, crystalline solid outlet, and with electrolytic bath (2) outside
Filtration system be connected, pallet (7) is made up of isolation material.
5. the device of Waste Acid From Hua Cheng Foil presentation quality is improved as claimed in claim 4, it is characterised in that:The fixed peace of the pallet (7)
Loaded on the conductive plate (5) above bottom roll (4), the width of pallet (7) is identical with the width of bottom roll (4), pallet (7)
Length is not less than the length of bottom roll (4), and the wherein length direction of bottom roll (4) is consistent with the axial direction of bottom roll (4).
6. the device of Waste Acid From Hua Cheng Foil presentation quality is improved as claimed in claim 4, it is characterised in that:The pallet (7) is by FRP materials
Material is made.
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CN201510740467.4A CN105220199B (en) | 2015-11-04 | 2015-11-04 | Improve the method and device of Waste Acid From Hua Cheng Foil presentation quality |
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CN201510740467.4A CN105220199B (en) | 2015-11-04 | 2015-11-04 | Improve the method and device of Waste Acid From Hua Cheng Foil presentation quality |
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CN105220199B true CN105220199B (en) | 2018-02-06 |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5199631A (en) * | 1975-01-27 | 1976-09-02 | Sundstrand Data Control | |
CN200983318Y (en) * | 2006-12-12 | 2007-11-28 | 乳源瑶族自治县东阳光实业发展有限公司 | Electrode foil framework for capacitor |
CN201017773Y (en) * | 2006-12-12 | 2008-02-06 | 乳源瑶族自治县东阳光化成箔有限公司 | Forming device of electric pole foil and forming groove |
CN204102723U (en) * | 2014-08-20 | 2015-01-14 | 吴江飞乐天和电子材料有限公司 | A kind of process units of aluminum electrolysis capacitor formed foil and production line thereof |
-
2015
- 2015-11-04 CN CN201510740467.4A patent/CN105220199B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5199631A (en) * | 1975-01-27 | 1976-09-02 | Sundstrand Data Control | |
CN200983318Y (en) * | 2006-12-12 | 2007-11-28 | 乳源瑶族自治县东阳光实业发展有限公司 | Electrode foil framework for capacitor |
CN201017773Y (en) * | 2006-12-12 | 2008-02-06 | 乳源瑶族自治县东阳光化成箔有限公司 | Forming device of electric pole foil and forming groove |
CN204102723U (en) * | 2014-08-20 | 2015-01-14 | 吴江飞乐天和电子材料有限公司 | A kind of process units of aluminum electrolysis capacitor formed foil and production line thereof |
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